D 3935 - 94 Rdm5mzutotq - 3
D 3935 - 94 Rdm5mzutotq - 3
D 3935 - 94 Rdm5mzutotq - 3
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D 3935
TABLE PC Polycarbonate Materials and Detail Requirements
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D 3935
TABLE Continued
Note— The values are for naturals; colors may be different.
Izod Tensile Elongation Flexural Deflection
Flow Rate,B Specific Impact,C Yield at Modulus,E Tempera-
Group Description Class Description Grade DescriptionA
Test Method Gravity, Test Test StrengthD BreakD Test ture, Test
D 1238, Method Methods Methods Method
g/10 min D 792 D 256, Test Method D 638, D 790, D 648,F
J/m, min MPa, min MPa, min °C, min
2 UVH stabilized 1 TBD 1.18–1.22 480 65 60 1900 136
0 other ... ... ... ... ... ... ...
3 impact-modified 1 TBD use Table B
0 other ... ... ... ... ... ... ...
4 FDAJ compliant 1 TBD 1.18–1.22 480 65 60 1900 138
formulation 0 other ... ... ... ... ... ... ...
0 other 0 other ... ... ... ... ... ... ...
05 PC copolymer 1 general purpose 1 >50 1.18–1.22 use Table B
low-heat 2 nominal 45 1.18–1.22 570 50 100 2070 104
standard flow 3 nominal 29 1.18–1.22 620 50 100 2070 106
4 nominal 18 1.18–1.22 770 50 100 2160 107
5 nominal 10 1.18–1.22 810 50 100 2200 108
0 other ... ... ... ... ... ... ...
2 UVH stabilized 1 >50 1.18–1.22 use Table B
2 nominal 45 1.18–1.22 570 50 100 2070 102
3 nominal 29 1.18–1.22 620 50 100 2070 104
4 nominal 18 1.18–1.22 770 50 100 2160 105
5 nominal 10 1.18–1.22 810 50 100 2200 106
0 other ... ... ... ... ... ... ...
3 impact-modified 0 other ... ... ... ... ... ... ...
4 FDAJ compliant 1 >50 1.18–1.22 use Table B
formulations 2 nominal 45 1.18–1.22 570 50 100 2070 104
3 nominal 29 1.18–1.22 620 50 100 2070 106
4 nominal 18 1.18–1.22 770 50 100 2160 107
5 nominal 10 1.18–1.22 810 50 100 2200 108
0 other ... ... ... ... ... ... ...
5 flame-retardedG 1 TBD 1.18–1.22 use Table B
0 other ... ... ... ... ... ... ...
0 other 0 other ... ... ... ... ... ... ...
06 PC copolymer 1 general purpose 1 TBD 1.18–1.22 use Table B
low-heat easy 0 other ... ... ... ... ... ... ...
H
flow 2 UV stabilized 1 TBD 1.18–1.22 ... ... use Table B
0 other ... ... ... ... ... ... ...
3 impact-modified 1 TBD 1.17–1.22 use Table B
0 other ... ... ... ... ...
4 FDAJ compliant 1 TBD 1.18–1.22 use Table B
formulations 0 other ... ... ... ... ... ... ...
5 flame-retardedG 1 TBD 1.18–1.22 use Table B
0 other ... ... ... ... ... ... ...
0 other 0 other ... ... ... ... ... ... ...
99 PC otherI 0 other 0 other ... ... ... ... ... ... ...
A
All grades are listed by performance requirements.
B
Use condition 300/1.2 for Groups 01, 02, and 05. Define the conditions for other groups in the suffixes as needed.
C
Test specimens are 3.2 mm thick, with a notch radius of 0.25 mm, tested by Method A.
D
Test specimens are Type I tensile bars, 3.2 mm thick, tested at a crosshead speed of 50 mm/min.
E
Test specimens are 3.2 by 12.7 mm, tested by Method I, Procedure A (Tangent), at a crosshead speed of 1.3 mm/min and a span-to-depth ratio of 16 to 1.
F
Test specimens are 3.2 mm thick, tested at 1820 kPa, and are not annealed before testing.
G
Use suffix letter F, with the appropriate digits allowed in Classification D 4000, to define specific requirements.
H
Refer to Practices E 169 for testing procedure. Specific requirements shall be stated in the purchase order or contract.
I
Test specimens for Group 1, Class 4, Grade 1 are 6.4 mm thick with a notch radius of 0.25 mm and are tested by Method A.
J
Manufactured in compliance with Food Additive Regulation 21CFR177.1580 governing polycarbonate resins for food-contact applications..
NOTE 2—An example of this classification system is as follows: the 4.2 Reinforced, pigmented, filled, and lubricated versions of
designation PC0214 indicates: polycarbonate materials may be classified in accordance with
PC 5 polycarbonate as found in Terminology D 1600, Tables PC and A, B, or R. Table PC is used to specify basic
02 5 polycarbonate copolymer-flame retarded (group),
1 5 general purpose (class), and materials, and Tables A or B are used to specify the property
4 5 requirements given in Table PC. requirements after the addition of reinforcement, pigments,
4.1.1 To facilitate the specification of new, special, or fillers, or lubricants at the nominal level indicated (see 4.2.1).
recycled materials, the “other” category (0) for class or grade, Table R is used for recycled materials.
or both, may be used as indicated in Table PC. The properties 4.2.1 A single letter shall be used to indicate the major
of these materials may be specified using Tables A, B, or R as category of the reinforcement, along with two numbers indi-
they apply. cating the nominal percentage of additive(s) by mass, with the
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D 3935
tolerances as tabulated as follows: 0 5 unspecified.
Tolerance 4.4 The short- and long-term mechanical properties of
Category Material
(Based on the Total Mass)
C carbon and graphite fiber- 62 percentage points polycarbonate materials can be affected adversely by their prior
reinforced processing as well as end-use exposure to chemicals, weather-
G glass-reinforced ing, and secondary finishing steps. Efforts to reuse materials
<15 % glass content 62 percentage points
>15 % glass content 63 percentage points may include direct feedback into the system from which they
L lubricants (such as PTFE, depends on material and are generated, or they could involve isolation for reuse at other
graphite, silicone, and molyb- process—to be specified times into other processes or parts. Most manufacturer’s
denum disulfide)
M mineral-reinforced 62 percentage points literature contains recommendations regarding direct feedback
R combination/mixtures of rein- 63 percentage points based on practices to aid the user in maintaining the properties of the
forcements or other fillers/ total reinforcement original materials as much as possible. When polycarbonate
reinforcements
resins are isolated and reprocessed in conjunction with fillers,
NOTE 3—If necessary, additional requirements may be specified using additives, colorants, etc., there is a special risk that the
suffixes, in accordance with Section 5. Special agreements on tolerances properties of the final products may not be equal to those
may be required when levels are below 5 %. The ash content of filled or
reinforced materials may be determined using Test Method D 2584 where
obtained when “virgin” resins are used. While the test speci-
applicable. men properties called out in this specification may be used to
screen these materials, the user should take precautions to
4.2.2 Specific requirements for reinforced, filled, or lubri- ensure that parts made from these materials meet the desired
cated polycarbonate materials shall be shown by a six- parameters. Group and class designations from Table PC, used
character designation that will consist of the letter A or B and in conjunction with Grade Designation 0, allow line callouts to
the five digits comprising the cell numbers for the property be defined for recycled resins. The group, class, and grades
requirements in the order in which they occur in Tables A or B. given should be used with the property ranges from Table R, as
4.2.2.1 Although the values listed in Tables A and B are appropriate. Table R lists two impact and two tensile properties
necessary to include the range of properties available in to allow callouts for both filled and unfilled resins. It is
existing materials, users should not infer that every possible intended that only one be used in a given callout and that the
combination of the properties exists or can be obtained. unused properties be given an 0, “unspecified,” cell designa-
4.2.3 When the grade of the basic material is not shown, or tion.
is not important, a “0” grade classification shall be used for 4.5 When property requirements involving ISO criteria are
reinforced materials in this system. to be specified, cell Tables C through H, as defined in
NOTE 4—An example of this classification system for reinforced Classification D 4000, should be used. Appropriate suffixes,
polycarbonate material is as follows: the designation PC0110G10A22230 detailing specimen dimensions, test speeds, etc., must also be
indicates: defined when using these tables.
PC0110 5 general-purpose polycarbonate from Table PC,
G10 5 glass reinforced at nominal 10 % level, 5. Suffixes
A 5 Table A property requirements,
2 5 60-MPa tensile strength, min, 5.1 When requirements not covered by the basic cell tables
2 5 3000-MPa flexural modulus, min, need to be specified, suffixes shall be defined in accordance
2 5 80-J/m Izod impact strength, min,
3 5 125°C deflection temperature, min, and with Classification D 4000.
0 5 unspecified. 5.2 Requirements specified by suffix references always take
If no properties are specified, the designation is PC0110G10A00000. precedence over values from the property or cell tables for the
4.3 Table B has been incorporated into this specification to same properties.
facilitate the classification of special materials where Table PC
or Table A do not reflect the required properties. Table B shall 6. General Requirements
be used in the same manner as Table A. 6.1 The plastic compositions shall be uniform and shall
NOTE 5—The mechanical properties of polycarbonates can be affected conform to the requirements herein.
by the amounts and types of additives and colorants used. The most often
observed effect is a change in the ductility of the material as evidenced in 7. Detail Requirements
reductions of up to 90 % in Izod impact strength and 25 % or more in
7.1 Test specimens for the various materials shall conform
tensile elongation. A classification using Table PC and Table B should be
used if properties of pigmented or specially formulated polycarbonates to the requirements in accordance with Tables PC, A, B, and R
need to be specified. and the suffix requirements, as they apply.
NOTE 6—An example of this classification system for a special poly- 7.2 For the purpose of determining conformance with the
carbonate material is as follows: the designation PC0110B34720 indi- requirements of this specification, all specified limits in this
cates: specification are absolute limits in accordance with Practice
PC0110 5 general-purpose polycarbonate from Table PC, E 29.
B 5 Table B property requirements, 7.2.1 With the absolute method, an observed or calculated
3 5 60-MPa tensile strength, min,
4 5 2100-MPa flexural modulus, min, value is not rounded but is compared directly with the specified
7 5 640-J/m Izod impact strength, min, limiting value. Conformance, or lack thereof, is based on this
2 5 150°C deflection temperature, min, and comparison.
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D 3935
TABLE A Reinforced Polycarbonate Materials, Detail Requirements
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D 3935
Mold Temperature, Material Melt Temperature, tion using the referenced test methods.
°C °C
Unfilled and 70–95 275–290
unreinforced 13. Inspection and Certification
(when MF> 8 g/10 min) (when MF >8 g/10 min)
Unfilled and 80–115 290–345
13.1 Inspection and certification of the materials supplied in
unreinforced reference to this specification shall be for conformance to the
(when MF <8 g/10 min) (when MF <8 g/10 min) requirements specified therein.
Filled and 80–115 300–350
reinforced 13.2 Lot acceptance inspection shall be the basis on which
acceptance or rejection of a lot is made and shall consist of the
10.1.1 All materials classifiable into Groups 01 and 02
test listed as it applies:
should be dried for at least 3 h at 125°C before molding.
10.2 Unless otherwise specified, test specimens for materi- 2 Flow Rate
als classifiable into Groups 03 and 04 shall be prepared by 13.3 To ensure certifiability in accordance with 13.5, peri-
injection molding in accordance with Practice D 1897 using odic check inspection shall consist of tests for all of the
the following conditions: requirements specified using the classification system in this
Mold Temperature, Material Melt Temperature, specification.
°C °C
Unfilled and 80–100 330–375 13.4 A report of the test results shall be furnished when
unreinforced requested by the purchaser and shall consist of the lot accep-
Filled and consult manufacturer for recommended molding conditions
reinforced
tance inspection results in accordance with 13.2. The results of
the most recent periodic check inspection shall also be fur-
10.2.1 All materials classifiable into Groups 03 and 04 nished whenever requested by the purchaser.
should be dried for at least 3 h at 130°C before molding. 13.5 Certification shall be that the material was manufac-
10.3 Test specimens for materials not classifiable into tured, sampled, inspected, and tested in accordance with this
Groups 01, 02, 03, or 04 should be prepared by injection specification and that the average values meet the requirements
molding, as prescribed by the manufacturer. at a 95 % confidence level.
10.3.1 Materials not classifiable into Groups 01, 02, 03, or
04 should be dried in accordance with the recommendations of 14. Packing, Packaging, and Package Marking
the manufacturer.
14.1 The provisions of Practice D 3892 apply for the
11. Conditioning packaging, packing, and marking of containers for plastics
materials.
11.1 Condition test specimens at 23 6 2°C and 50 6 5 %
relative humidity for not less than 40 h prior to testing.
15. Keywords
12. Test Methods 15.1 line-callout specification; plastics; polycarbonate res-
12.1 Determine the properties enumerated in this specifica- ins; recycled plastics; specification
APPENDIX
(Nonmandatory Information)
X1.1 The cross references in Table X1.1 between the designations of government specifications and this specifica-
tion are provided for information only.
TABLE X1.1 Cross-Reference Designations for This Specification and Government Specifications
Government Specifications Previous Line Callout, Specification D 3935 (1987) Revised Specification D 3935-94 Line Callout
General purpose
L-P-393A PC110B30720E01F02 PC0110B30740EB140ED030EE150EG010FL012
Glass reinforced
MIL-P-81390
Type I PC110G40A60840E02F01 PC0110G40A60840EB150ED037EE150EG001FL024
Type II PC110G20A50640E02F01 PC0110G20A50640EB150ED037EE150EG001FL024
Type III PC110G20A50340E02F01 PC0110G20A50340EB150ED037EE150EG001FL024
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D 3935
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