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Chemistry-FUNGAT/ECAT: (Chapter 10+11+12 B-II)

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Chemistry–FUNGAT/ECAT

(Chapter 10+11+12 B-II)

1. How alkyl halide can be converted into alkene?


(a) Dehydration (b) Substitution (c) Elimination (d) Addition
2. Which of the following is an electrophile?
(a) NH 3 (b) H 2O (c) BF3 (d) Cl2
3. Which of the following does not form Grignard reagent?
(a) CH 3Cl (b) CH 3 F (c) CH 3 Br (d) CH 3 I
4. The common name of 2 – methyl – 2 chloropropane is:
(a) t – butyl chloride (b) Isobutyl chloride
(c) Secondary butyl chloride (d) n – butyl chloride
5. When formaldehyde reacts with ethyl magnesium iodide followed by hydrolysis, the
product formed is:
(a) 2 – propanol (b) propanoic acid (c) 1 – butanol (d) 1 – propanol
6. Point out the hybridization of oxygen in ethers:
(a) sp 2 (b) sp (c) dsp 2 (d) sp 3
7. The percentage of formaldehyde in a solution of formalin is:
(a) 10% (b) 20% (c) 40% (d) 60%
8. Cannizzaro’s reaction is not given by:
(a) Formaldehyde (b) Acetaldehyde
(c) Benzaldehyde (d) Trimethyl acetaldehyde
9. Ketones are prepared by the oxidation of:
(a) Primary alcohol (b) Secondary alcohol
(c) Tertiary alcohol (d) None of these
10. According to Lewis concept ether behaves as:
(a) acid (b) base
(c) acid base (d) neither acid nor base
11. Aldehydes and ketones have higher boiling points than corresponding compounds of
the following except:
(a) alkane (b) alkene (c) ether (d) alcohol
12. In an acid catalyzed reaction of carbonyl compounds, the acid increases:
(a) electrophilic character of the carbonyl carbon atom
(b) nucleophilic character of the carbonyl oxygen atom
(c)electrophilic character of the carbonyl oxygen atom
(d) nucleophilic character of the carbonyl carbon atom
13. Acetone and acetaldehyde can be distinguished by:
(a) R  Mg  X  OH  (b) NaOH  I 2
(c) NH 2  OH (d) AgNO3  NH 4OH
14. The mechanism involved the reaction, KOH + C2H5Br →C2H4+KBr+H2O, is:
(a) SN1 (b) E1 (c) SN2 (d) E2
15. An organic compound A when treated with NaBH4 forms B, which is used in
denaturing of the spirit. The compound A is:
(a) ethanol (b) methanal (c) methanol (d) ethanal
16. Which enzyme is used to convert molasses into glucose?
(a) zymase (b) invertase (c) diastase (d) maltase
17. An organic compound has IUPAC name 2-Isopropoxy propane, its common name is:
(a) diethyl ether (b) di n-propyl ether
(c) di isopropyl ether (d) ethyl isopropyl ether
18. If an electrophile attacks alcohols, which bond will break:
(a) C – O (b) C – H (c) O – H (d) C – C

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19. Which of the following is not a condition for alcoholic fermentation?
(a) optimum temperature (b) proper dilution
(c) preservative (d) none of these
20. What is the order of acidic strength?
(a) RCOOH <PhOH< HOH < ROH (b) RCOOH <PhOH> HOH < ROH
(c) RCOOH >PhOH> HOH > ROH (d) RCOOH >PhOH< HOH > ROH
21. 3-Pentanone forms a yellow precipitate with 2,4-dinitrophenyl hydrazine but does not
form white crystalline precipitate with:
(a) ammonical silver nitrate solution (b) aqueous NaOH and iodine
(c) saturated NaHSO3 solution (d) aqueous Na2CO3 and iodine
22. Which is correct order of reactivity of alcohols with ZnCl2 and HCl?
(a) tertiary alcohol > primary alcohol > secondary alcohol
(b) tertiary alcohol > secondary alcohol > primary alcohol
(c) tertiary alcohol < secondary alcohol < primary alcohol
(d) tertiary alcohol > secondary alcohol > primary alcohol
23. In the following reaction, C and D are:
CH3 – CO – CH2 – CH2 – CH3 + [O] → C + D
(a) 2 moles of CH3COOH (b) CH3COOH + CH3CH2CH3
(c) CH3COOH + CH3CH2COOH (d) HCHO+2CH3COOH
24. Reaction of CO2 with R-Mg-X is an example of
(a) electrophilic substitution reaction (b) nucleophilic addition reaction
(c) electrophilic addition reaction (d) nucleophilic substitution reaction
25. -
Alkyl halides react with SH to produce
(a) H2O+H2S (b) (C2H5)2S (c) C2H5SH (d) C2H5SO4H
26. In SN2 reaction the percentage of retention of configuration
(a) 0% (b) 100% (c) 50% (d) 66%
27. Oxidation of 3-hexanone by acidified K2Cr2O7 produces
(a) two moles of propanoic acid (b) pentanoic acid and formic acid
(c) butanoic acid and ethanoic acid (d) all these are possible
28. Which one of the following is better reducing agent?
(a) C3H8 (b) C3H7OH (c) CH2O (d) CH3COCH3
29. The monomer for the Bakelite is
(a) phenol (b) hydroxy benzyl alcohol
(c) formaldehyde (d) both a and c
30. A convenient method to convert ketones to a carboxylic acid containing one carbon
less than the parent compound is
(a) Iodoform reaction (b) Oxidation
(c) Hydrogen cyanide addition reaction (d) Reduction with Grignard reagent

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