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    Carbonyl Compounds

    Uploaded by

    Palash Debnath

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Carbonyl Compounds

    Uploaded by

    Palash Debnath
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    © © All Rights Reserved

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    Carbonyl Compounds

    Uploaded by

    Palash Debnath

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    Aldehydes, Ketones & Carboxylic acids

    1. Which of the following can be (a) I (b) II


    used for the synthesis of 3- (c) III (d) I–V
    methyl-1-butanol? 6. The oxidation of 2-hexanol with
    (a) n-C3H7MgBr + CH3CHO H2CrO4 gives
    (b) (CH3)2CHCH2MgBr + CH2O (a) CH3COOH
    (c) C2H5MgBr + CH3COCH3 (b) CH3CH2CH2COOH
    (d) (CH3)3CMgBr + CH2O (c) CH3(CH2)3COCH3
    2. Among the following, which will (d) CH3(CH2)4COOH
    react most rapidly with HBr? 7. The order of reactivity towards
    (a) C6H5CH2CH2CH2OH Nucleophilic addition in CH2O (I),
    (b) C6H5CH(OH)CH2CH3 CH3CHO (II) and CH3COCH3 (III) is
    (c) C6H5CH2CH(OH)CH3 (a) I > II > III (b) III > II > I
    (d) (CH3)3CCH2OH (c) II > I > III (d) III > I > II
    3. The conversion 8. The trans-hydroxylation of cyclo
    hexene can be done by
    (a) dilute KMnO4
    (b) using OsO4
    (c) converting cyclo hexene into an
    epoxide and then opening the
    epoxide ring
    (d) none of these
    Can be effected by using the 9. The reaction
    reagent
    (a) H2O, H2SO4 (b) O2
    (c) C6H5CO3H (d) CrO3, H2SO4
    4. The major product obtained in the
    reaction is known as
    (a) Aldol condensation
    (b) Cannizzaro reaction
    (c) Internal Cannizzaro reaction
    is (d) Benzilic acid rearrangement
    (a) (CH3)3C-CH2COCH3 10. Reaction of formaldehyde and
    (b) (CH3)2C=CHC(OH)-(CH3)2 ammonia gives
    (c) (CH3)2CH-CH(CH3)COCH3 (a) Hexamethylene tetramine
    (d) (CH3)2C=CH-CH(OH)(CH3) (b) Bakelite
    5. Which of the following hydrogen (c) Urea
    will be the most acidic? (d) Triethylene tetramine
    11. Which of the following does not
    undergo benzoin condensation?
    (a) Benzene carbaldehyde
    (b) P-toluene carbaldehyde
    (c) Phenylethanal
    (d) 4-methoxy benzaldehyde
    12. The common name of
    hexamethylene tetramine is
    (a) Nylon-6, 6
    (b) Urotropine

    Provided by – Palash Debnath


    Aldehydes, Ketones & Carboxylic acids

    (c) Formaldehyde resin (a) I < II < III (b) III < II < I
    (d) Acetamide (c) I < III < II (d) II < III < I
    13. Which of the following is 21. An organic compound reduces
    constituent of oil of winter green? Tollen’s reagent and Fehling’s
    (a) Aspirin (b) Salol solution. It can be
    (c) Methyl Salicylate (a) CH3CH2CHO (b) C6H5CHO
    (d) None of these (c) CH3COCH2CH3 (d) (CH3)3CCOCH3
    14. A mixture of benzaldehyde and 22. Acetyl bromide reacts with excess
    formaldehyde on heating with of CH3MgI followed by treatment
    aqueous NaOH solution gives: with a saturated solution of NH4Cl
    (a) Benzyl alcohol & sodium formate gives
    (b) Sodium benzoate & methyl (a) 2-methyl-2-propanol
    alcohol (b) Acetamide
    (c) Sodium benzoate & sodium (c) Acetone (d) Acetyl iodide
    formate 23. Silver mirror test is given by
    (d) Benzyl alcohol & methyl alcohol
    which one of the following
    15. Aldehydes and ketones form
    compounds?
    hydrocarbons by
    (a) Acetaldehyde (b) Acetone
    (a) Clemmensen reduction
    (c) Formaldehyde
    (b) Cannizzaro reaction
    (d) Benzophenone
    (c) Rosenmund reduction
    24. In the reaction:
    (d) Aldol Condensation
    16. Which of the following respond
    positively to the iodoform test? the product C is
    (a) 2-Pentanone (b) 1-Pentanal (a) Acetaldehyde (b) Acetylene
    (c) 3-Pentanone (d) Pentanol (c) Ethylene
    17. Paraldehyde is a (d) Acetyl chloride
    (a) dimer of formaldehyde 25. The best oxidising agent for
    (b) trimer of acetaldehyde oxidation of CH3-CH=CH-CHO to
    (c) hexamer of formaldehyde CH3- CH=CH-COOH is
    (d) hexamer of acetaldehyde (a) Baeyer’s Reagent
    18. The conversion of acetone into (b) Tollens’ Reagent
    diacetone alcohol is carried out in (c) Schiff’s Reagent
    the presence of (d) Acidified dichromate
    (a) Dry HCl(g) (b) Conc. H2SO4 26. Hydrocarbons are formed when
    (c) Ba(OH)2 (d) Heat aldehydes and ketones are
    19. Meso tartaric acid and d-tartaric reacted with amalgamated Zn and
    acid are conc. HCl. The reaction is called
    (a) Diastereomers (a) Cannizaro reaction
    (b) racemic mixtures (b) Clemmensen reaction
    (c) enantiomers (c) Rosenmund reaction
    (d) position isomers (d) Wolff-Kishner reaction
    20. The boiling points of acetic 27. Which of the following carboxylic
    anhydride (I), propionic acid is highly insoluble in water?
    anhydride (II) and butyric (a) Propanoic acid
    anhydride (III) follow the order (b) Butanoic acid

    Provided by – Palash Debnath


    Aldehydes, Ketones & Carboxylic acids

    (c) Pentanoic acid (R): The >C=O bond is present in


    (d) Decanoic acid carbonyl compounds & carboxylic
    28. Which of the following statement acid while C—O bond is in alcohols.
    is correct regarding formic acid? 32. (A): Cannizzaro reaction converts
    (a) It is a reducing agent HCHO into HCOO-Na+ and CH3OH.
    (b) It is a weaker acid than acetic
    (R): It is a proton-hydride transfer
    acid
    (c) It is an oxidising agent reaction.
    (d) When its calcium salt is heated, it 33. (A): Protonation of the carbonyl
    forms acetone group increases its electrophilic
    29. Which of the following will not nature.
    undergo HVZ reaction? (R): This is an example of
    (a) Propanoic acid electrophilic addition on
    (b) Ethanoic acid Nucleophilic oxygen.
    (c) 2-methylpropanoic acid 34. (A): In aliphatic carboxylic acids,
    (d) 2, 2-dimethylpropanoic acid
    presence of strong electron-
    Directions (Q. Nos. 30 – 34). This
    withdrawing groups on hydrocarbon
    section contains Assertion (A) and Reason
    chain increases the acidity.
    (R) type questions. Each question has 4 (R): Chloroacetic acid is stronger
    choices (a), (b), (c) and (d), out of which than acetic acid.
    only one is correct. 35. Formalin is used
    (a) For the preservation of biological
    (a) Both Assertion & Reason are specimens
    correct, and reason is the correct (b) As a disinfectant
    explanation of Assertion. (c) As a germicide
    (d) All of the above
    (b) Both Assertion & Reason are 36. DiBAL – H reacts with cyanide to
    correct, but reason is not the form an intermediate known as
    correct explanation of Assertion. (a) Amide (b) Aldehyde
    (c) Assertion is correct but Reason is (c) Imine (d) Amine
    37. Schiff’s reagent is
    incorrect.
    (a) Rosanilin hydrochloride solution
    (d) Assertion is incorrect but Reason (b) Alkaline KMnO4 solution
    is correct. (c) Sodium amalgam in HCl
    (d) None of these
    30. (A): Carbonyl compounds are more 38.
    soluble in water than the
    corresponding alkanes.
    (R): H-bonding between carbonyl
    oxygen and water renders carbonyl
    compounds more water soluble than
    hydrocarbon.
    31. (A): The >C=O bond (0.122nm) is
    shorter than the C—O bond
    (0.141nm).

    Provided by – Palash Debnath

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