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Chapter-10

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-: Chapter-8 :-

-: Aldehydes, Ketones and Carboxylic Acids :-


 Multiple choice question :-
Q.1. Which of the following compounds does not reduce Fehling’s solution? [2018, 22]

(a) CH3COOH (b) HCOOH


(c) HCHO (d) CH3CHO

Q.2. The reagent with which both acetaldehyde and acetone readily react is :

(a) Fehling’s solution (b) Grignard’s reagent


(c) Schiff’s reagent (d) Tollen’s reagent

Q.3. Rosenmund reduction yields [2020]

(a) Aldehyde (b) Ether


(c) Carboxylic acid (d) hydrocarbon

Q.4. An alkene C7H14 forms aldehyde (C3H6O) and ketone by ozonolysis, that ketone is

(a) 2-butanone (b) 2-pentanone


(c) 3-pentanone (d) Propanone

Q.5. A reagent used for the distinction between acetaldehyde and acetone is

(a) Hinsberg reagent (b) Lucas reagent


(c) Schiff reagent (d) None of these

Q.6. The compound formed when acetic acid reacts with diazomethane is [2017]

(a) methyl acetate (b) ethyl acetate


(c) methane (d) methyl amine

Q.7. Fehling’s solution does not reduce

(a) Formic acid (b) acetic acid


(c) Formaldehyde (d) acetaldehyde

Q.8. Chlorine gas on reaction with benzaldehyde gives

(a) benzyl chloride (b) benzal chloride


(c) benzoyl chloride (d) chlorobenzene
NaoH
Q.9. The reaction C6H5CHO + CH3CHO C6H5HO + CHCHO + H2O is called

(a) benzoin condensation (b) klagen condensation


(c) aldol condensation (d) condensation

Q.10. Condensation product of acetaldol are

(a) Two molecules of ethanol


(b) Two molecules of propanone
(c) ethanol and methanol
(d) ethanol and propanone
Q.11. Methyl ketone is recognized by

(a) Tollens reagent (b) Iodoform test


(c) Schiff test (d) benedict solution

Q.12. Acetone on heating in ammonia produces

(a) Acetaldehyde (b) Diacetone alcohol


(c) Diacetone amine (d) Hydroxy benzamide

Q.13. Formalin is an aqueous solution of

(a) Formaldehyde (b) Formic acid


(c) Fluorescein (d) Acetaldehyde

Q.14. Which of the following is the strongest acid?

(a) CH3COOH (b)ClCH2COOH


(c) Cl2CHCOOH (d) Cl3COOH

Q.15. Carboxylic acid are easily ionized because

(a) absence od α-hydrogen


(b) resonance stabilization of the carboxylate ion
(c) a high reactivity of hydrogen
(d) hydrogen bonding

Q.16. When acetic acid P2O5 is heated then which is formed

(a) (CH3CO)2O (b) CH3COCH3


(c) CH3CHO (d) CH4

Q.17. Which of the following is prepared by HVX reaction

(a) 𝜷 haloacid
(c) α, 𝜷 unsaturated
(b) α haloacids
(d) None of these

Q.18. This acid does not form acid anhydride

(a) formic acid (b) acetic acid


(c) propionic acid (d) n-butyric acid

Q.19. On Tollen’s test RCHO produces [2021]

(a) R-O-R (b) Ag


(c) Ag2O (d) RCH2OH

Q.20. On nitration in the presence of sulphuric acid benzaldehyde forms [2022]

(a) o-nitrobenzaldehyde (b) p-nitrobenzaldehyde


(c) m-nitrobenzaldehyde (d) None of these

Q.21. Canninzaro reaction presents [2023]

(a) Benzoic acid (b) Toluene


(c) Benzaldehyde (d) Formic acid
Q.22. This forms formaldehyde from cannizaro reaction [2023]

(a) Methane (b) Methyle alcohol


(c) Methyle cynide (d) Ethyl amine

Q.23. Formaline is the aquous solution of [2023]

(a) Fluoaresine (b) Formaldehyde


(b) Formic acid (d) Acetic acid

Q.24. In Etards reaction, toluene is oxidized to benzaldehyde by [2024]

(a) H2O (b) CrO2Cl2


(c) Cl2 (d) KMnO4

Q.25. Which of the following is obtained by Rosenmund’s reduction of acyl chloride? [2024]

(a) Aldehyde (b) Alcohol


(c) Hydrocarbon (d) Alkyl chloride

Q.26. Which of the following compound is identified by Tollen’s Reagent? [2024]

(a) Alcohol (b) Aldehyde


(c) Ketone (d) Carboxylic acid

~ By P. K. Sir
Mob : 9956864000

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