VIBRANT ACADEMY INORGANIC CHEMISTRY

IRP Home Test-2

(India) Private Limited Target IIT ADVANCE-2020

Single Choice Questions :

1. Complexes [Ni(dmg)2] and [Ni(NH3)6]2+ are simmilar in following characteristics
(A) Colour (B) Stability
(C) Geometry
(D) Maximum number of nitrogen atoms that can lie in a plane

2. Which oxide is most basic ?

(A) P2O5 (B) MnO (C) CrO3 (D) Mn2O7

3. In which of the following silicates, only two corners per tetrahedron are shared :
(i) Pyrosilicate (ii) Cyclic silicate
(iii) Double chain silicate (iv) Single chain silicate
(v) 3 D silicate (vi) Sheet silicate
(A) (i), (ii) and (v) (B) (iv) and (vi) only (C) (i) and (vi) only (D) (ii) and (iv) only

4. In which of the following structure, the number of shared O-atom per tetrahedron is two and half.
(A) Pyroxene chain silicate (B) Amphibole chain silicate
(C) Cyclic silicate (D) Sheet silicate

5. The compound is having shortest S – O bond length is

(A) SO3F– (B) SO42– (C) SOF4 (D) SOCl2

6. Which of the following salt does not give NO2 gas on heating ?
(A) Pb(NO3)2 (B) Zn(NO3)2 (C) AgNO3 (D) KNO3

7. Which of the following compound show colour due to ligand to metal charge transfer spectrum.
(A) Fe4[Fe(CN)6]3 (B) KMnO4 (C) Cr(CO)6 (D) All of these

8. The spin only magnetic moment (in B.M.) value of [FeF6]3– and [Cr(CN)6]3– respectively are
(A) 0 and 1.73 (B) 5.92 and 1.73 (C) 4.47 and 1.73 (D) 5.92 and 3.87

9. The compound which has four metal-metal bonds is :

(A) Fe2(CO)9 (B) Co2(CO)8 (C) [Re2Cl8]2– (D) Ru3(CO)12

10. A colourless water soluble salt (X) when treated with AgNO3 solution gives black ppt, which is not soluble in
excess conc. NH3solution and salt (X) gives coloured flame test then ‘X’ is :
(A) NaBr (B) CaC2O4 (C) BaS (D) K2CrO4

11. [CoBr(NO2)(H2O)(NH3)3]Cl does not exhibit.

(A) Linkage isomerism (B) Geometrical isomerism (C) Optical isomerism (D) Hydrate isomerism

12. Correct order of wavelength of light absorbed in visible region of spectra for the following complex ions is
(I) [Co(H2O)6 ]3 (II) [Co(CN)6 ]3 – (III) [Co(ox)3]3– (IV) [Co(en)3 ]3 
(A) III > I > IV > II (B) II > IV > I > III (C) III > I > II > IV (D) I > III > IV > II

1
13. Which of the following is most likely formula of CrCl3·6H2O, if of total water of the compound is lost on
3
treatment with conc. H2SO4.
(A) CrCl3·6H2O (B) [Cr(H2O)3Cl3] (H2O)3
(C) [CrCl2(H2O)4]Cl·2H2O (D) [CrCl · (H2O)5]Cl2·H2O

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14. Which of the following compound does not give precipitate with solution of chrome alum :
(A) BaCl2 (B) Na2CO3 (C) (NH4)2S (D) excess KOH

15. In photography, unexposed AgBr is washed away by complexation of Ag(I) by sodium thiosulphate solution.
These washings are often disposed of as waste. However, meltallic silver can be recovered from them by
adding cyanide, followed by zinc. What is the hybridisation of zinc in the complex formed during the
recovery of silver?
(A) sp3d2 (B) d2sp3 (C) sp3 (D) dsp2

Na CO
16. Cu 2 (aq) 2
3
 ' X' 
solution Green ppt

Formula of ‘X’ is
(A) CuCO3·Cu(OH)2 (B) CuCO3 (C) Cu(OH)2 (D) [CuO2(OH)2]4–

17. Cu2+(aq) + K3[Fe(CN)6]  X 

ppt

The correct statement regarding ‘X’ is

(A) Oxidation state of copper in complex ‘X’ is +1 (B) Colour of ‘X’ is chocolate brown
(C) Colour of ‘X’ is green (D) ‘A’ and ‘B’ are correct
18. Which of the following does not have metal-metal bond?
(A) Mn2(CO)10 (B) Hg2Cl2 (C) K2Re2Cl8 (D) Al2Cl6
19. Which of the following species is not blue in colour.
(A) [Cu(H2O)6]2+ (B) [Cu(NH3)4]2+ (C) [CuCl4]2– (D) CuSO4 · 5H2O

20. What is correct order of C–O bond length

(A) (C–O)Fe(CO)5 > (C–O)CO > (C–O)CO+ (B) (C–O)Fe(CO)5 > (C–O)CO+ > (C–O)CO
(C) (C–O)CO+ > (C–O)CO > (C–O)Fe(CO)5 (D) (C–O)CO+ > (C–O)Fe(CO)5 > (C–O)CO

21. Select correct pair of co-ordination compounds in which first complex compound/ion is more stable than
second compound/ion.
(A) [Ni(CN)4]2–, [Ni(NH3)6]2+ (B) [PdBr2(NH3)2], [PdBr(ONO)(NH3)2]
2–
(C) [Co(SCN)4] , [CoF6] 3– (D) [Cr(NH3)2(en)2]3+ [Cr(en)3]3+

22. Complex compound/ion which exhibits optical activity.

(A) [CoBr3(H2O)2(NH3)] (B) [IrBr4(en)]–
(C) [PtBr2(NO2)2(en)] (D) [Cr(CN)3(NO2)(en)]–

23. Which of the following compound undergoes disproportionation in presence of SO3 gas.
(A) K2MnO4 (B) K2CrO4 (C) I2 (D) Hg(NO3)2

24. Select CORRECT Match

(A) NCS– Bidentate ligand
(B) CO Ambidentate ligand
(C) N2H4 Monodentate ligand
(D) NH4+ Flexidentate ligand

25. Consider the following reactions

4 K [Fe(CN) ]
6 
X(aq.)  Chocolate brown ppt
3AgNO
X(aq.)  White ppt (insoluble in dil. HNO3)
Then 'X' will be :
(A) ZnSO4 (B) CuCl2 (C) FeSO4 (D) FeCl3

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26. Statement-1 : Acidified solution of [Cu(NH3)4]2+ react with K4[Fe(CN)6] and brown ppt is formed.
Statement-2 : Both complexes are blue in colour and dsp2 hybridized.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

27. Statement-1 : [Fe(H2O)5(NO)]SO4 is paramagnetic complex.

Statement-2 : The Fe in [Fe(H2O)5(NO)]SO4 has three unpaired electrons.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true
28. Parke’s process is used
(A) to extract Ag using NaCN (B) to extract Ag from argentiferous lead
(C) to extract Ag by forming amalgam (D) to extract Ni using carbonyls
29. Statement-1 : Nitrate ores are rarely found in earth crust
Statement-2 : Metal nitrates are water soluble.
(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True ; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
30. Which compound on heating finally produces coloured metal oxide
(A) Al2(SO4)3 (B) HgCO33Hg(OH)2 (C) Cu(NO3)2 (D) Ba(OH)2
31. Which of the following metal is extracted by pyrometallurgy and its electrolytic refining is not carried out at
commercial level.
(A) Ag (B) Fe (C) Cu (D) Al
32. Which of the following reagents are used in Bayer's process for dissolution of Al2O3 and for precipitation of
Al(OH)3 respectively.
(A) Fe2O3, SiO2 (B) NaOH, CO2 (C) NaOH, SiO2 (D) Fe2O3, CO2
33. Softening of lead means
(A) conversion of lead to PbO (B) conversion of lead to Pb3O4
(C) removal of impurities from lead (D) washing lead with HNO3 followed by alkali solution
34. The metal, which is directly extracted by roasting its sulphide ore :
(A) Pb (B) Cu (C) Ag (D) Hg
35. Select correct match :
List-I List-II
(P) Hydrate isomerism (1) [CrBr(SCN)(H2O)(NH3)3]NO3
(Q) Linkage isomerism (2) [CoBr(en)2(H2O)]Br2
(R) Optical isomerism (3) [Ir(NO2)2(H2O)4]Br
(S) Geometrical isomerism (4) [Fe(CN)5(NOS)]2–
Code : P Q R S
(A) 1 4 3 2
(B) 2 4 3 1
(C) 2 4 3 1
(D) 2 4 1 3

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More then one correct :
36. Choose correct IUPAC name(s) of give set of compounds :
(A) [PtCl2(NH3)4][PtCl4] – Tetraamminedichloridoplatinum (IV) tetrachloridoplatinate(II)
(B) K4[Fe(CN)6] – Potassiumhexacyanidoferrate(II)
(C) [Co(NH3)6][Co(ONO)6] – Hexaamminecobalt(III)hexanitrito-O-cobaltate(III)
(D) Na3[Fe(CN)5NO] – sodiumpentacyanidonitrosoniumferrate(II)

37. Select the INCORRECT chemical change

(A) Cu + dil. H2SO4  CuSO4 + H2(g)
(B) Cu + dil. HNO3  Cu(NO3)2 + N2O(g)
(C) CuSO4(aq) + KCN (excess)  K2[Cu(CN)4]
(D) CuSO4(aq) + NH4OH  Cu(OH)2

38. Select correct statement for K4[Fe(CN)6] and K3[Fe(CN)6]

(A) Both are inner orbital complexes
(B) Hybridization of both central metal cations : d2sp3
(C) Both are paramagnetic
(D) Both are low spin complexes

39. Select the complex compound which does/do not show stereo isomerism M = any metal
(A) [M(en)2] (B) [M(en) (Gly)] (C) [M (Gly) (NH3)2] (D) [M (Gly)2]

40. If all ligands of complex ion [PdCl4]2– are replaced by NCS– then which of the following statement is/are for
the formed new complex ion.
(A) Its magnetic moment remains same as that of [PdCl4]2–
(B) It exhibits structural isomerism
(C) It doesn’t exhibit cis-trans isomerism
(D) Its geometry is different from that of [PdCl4]2–

41. Select correct match for froth floatation process

(A) Depressant : NaCN (B) Activator : CuSO4
(C) Froth stabilizer : Cresol (D) Collector : Aniline

42. Which of the following low spin complex ions is/are diamagnetic :
(A) [Co(H2O)6]3+ (B) [Fe(SCN)6]4– (C) [Ni(H2O)6]4+ (D) [Co(ox)3]3–

43. Choose the correct statement :

(A) In sp3d2 hybridization participation of dyz and dxz orbitals is essential
(B) All octahedral complexes of Ni2+ are outer orbital complexes
(C) All octahedral complexes of Cr3+ are inner orbital complexes
(D) Temperature independent spin only magnetic moment of [MnBr4]2– is 5.92 BM.

KCN Excess KCN

44. Aqueous solution of Metal Cation  ' X'    So lub le complex
( ppt)

Then the metal cation that can follow the given reaction :
(A) Ag+(aq) (B) Pb2+ (aq) (C) Hg2+ (aq) (D) Cr3+ (aq)

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45. In the extraction of respective metal correct match is/are
Metals Process
(A) Pb Pattinson’s Process
(B) Cu Bessemerisation
(C) Ag Pyrometallurgy
(D) Zn Carbon Reduction

46. Correct reduction process(es) is/are

(A) Fe2O3 + C  Fe (B) Ca3(PO4)2 + C  Ca
(C) ZnO + C  Zn (D) PbO + C  Pb

47. Correct match is

Ore Commerical extraction of metal
(A) ZnS : Carbon reduction
(B) HgS : Metal displacement
(C) CuFeS2 : Self reduction
(D) Al2O3  2H2O : Electrolytic reduction

48. Which of the following reaction(s) is/are thermodynomically feasible


(A) 2PbS + C  Pb + CS2

(B) PbS + 2O2  PbSO4

(C) PbS + 2PbO  3Pb + SO2

(D) PbS + PbSO4  2Pb + 2SO2

49. When excess potassium iodide is added to the freshly precipitated mercury (II) iodide, then which of the
following is/are correct statement(s)
(A) The precipitate will be dissolved
(B) The anion present in solution is [HgI4]2–
(C) Nessler’s reagent will be formed by adding KOH solution
(D) Coloured solution is formed

50. Extraction of silver from argentiferrous lead (Pb + Ag) involves

(A) distillation method (B) cupellation
(C) Pattinson’s process (D) Parke’s process

51. Hg and Pb are comercially extracted from their respective sulphide ores by Pyrometallurgy whereas
Pyrometallurgy is not applied in the extraction of Ag from Ag2S because
(A) Roasting of PbS is thermodynamically feasible below its melting point
(B) Roasting of Ag2S is not thermodynamically feasible
(C) Roasting of HgS is feasible at low temperature
(D) Gf of Ag2O becomes positive on increasing temperature

52. Which of the following complex(es) exhibit geometrical isomerism?

(A) [PtCl2Br2]2– (B) [Pt(gly)2] (C) [Pt(NH3)2Cl2] (D) [Pt(en)2]Cl2

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53. Aqueous solution of which of the following compound(s) is acidic.
(A) HgCl2 (B) MnO2 (C) VCl5 (D) FeCl3

54. Roasting of which of the following sulphide ores is/are thermodynamically feasible :
(A) FeS2 (B) Cu2S (C) Ag2S (D) ZnS

55. Select correct match

Compounds Gases liberated on heating
(A) PbO2 O2
(B) Ag2CO3 O2 and CO2
(C) MgCO3 O2 and CO2
(D) Hg(NO3)2 O2 and NO2

56. Which of the following ore(s) form water soluble complex with NaCN solution in absence of air
(A) Ag2S (B) PbS (C) Au (D) ZnS

57. Which of the following statements about the advantage of roasting of sulphide ore before smelting is/are
true?
(A) fGº of the sulphide is more negative than that of CS2
(B) fGº is negative for roasting of sulphide ore to oxide
(C) fG of carbon reduction of metal oxide to free metal is more negative at higher temperature
(D) Carbon and hydrogen are suitable reducing agents for metal sulphides

58. Which of the following co-ordination ion(s)/compound(s) exhibit structural isomerism.

(A) [PtBrCl(H2O)4]SO4 (B) [CoBr(NH3)5][Cd(CN)4]
(C) [Co(ox)(H2O)4]Br (D) [Ir(ONO)3(H2O)3]

59. CORRECT statement(s) for leaching is/are

(A) It is commercially used for ores of Ag, Au, Al.
(B) Silver and gold ores are leached out in the form of water soluble complex ions
(C) In Bayer's process Fe2O3 does not react with leaching reagent
(D) Complete precipitate of Al(OH)3 is obtained by adding conc. HCl into NaAlO2 solution

60. Which of the following step(s) is/are involved in the extraction of metal from galena
(A) Electrolytic reduction (B) Froth floatation
(C) Roasting (D) Self reduction

61. Which of the following extraction process require reducing agent?

(A) Iron from hematite (B) Tin from cassiterite
(C) Mercury from cinnabar (D) Zinc from zinc blende

62. Refining of tin involve :

(A) Cupellation (B) Liquation (C) Poling (D) Electrorefining

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63. 
Compound (X)   Y
 + Z

Coloured (Gaseous product)
water insoluble

If product ‘Z’ forms precipitate with Ba(OH)2 solution, then which of the following compound(s) can follow
given reation conditions
(A) Cu(OH)2.CuCO3 (B) Fe2(SO4)3 (C) FeCO3 (D) Cu(NO3)2

64. Spin only magnetic moment of which of the following complex ion(s) is different from 4.9 B.M.
(A) [Cr(NH3)6]2+ (B) [Fe(NH3)6]2+ (C) [Co(H2O)6]3+ (D) [NiF6]2–

65. Select correct order(s) :

(A) (PtCl4 · 5NH3) < (PtCl4 · 6NH3) : molar conductivity
(B) [Ir(H2O)6]3+ < [Ir(ox)3]3– < [Ir(acac)3] : stability
(C) [Co(H2O)6]3+ < [Ni(NH3)6]2+ < [Fe(NH3)6]2+ : Paramagnetc character
(D) [Ni(en)3]2+ < [Ni(dmg)2] : Kf values

66. Ionic equilibrium : Hg2+(aq) + Hg Hg22 (aq)

can shift into backward direction in the presence of

(A) excess KI solution (B) H2S gas (C) Na2CO3 solution (D) SnCl2 solution

67. Correct statement(s) about use of cyclic polyphosphates as water softening agents is/are
(A) They form soluble complexes with Ca2+, Mg2+ ions present in hard water
(B) They precipitate anionic species
(C) Complex ion formed by Ca2+ and Mg2+ with cyclic polyphosphate is more stable than with EDTA4–
(D) cyclic phosphates and EDTA4– both act as hexadentate in water softening process

68. Which chemical reaction(s) contain CORRECT products


(A) CoO(s) + ZnO(s)  CoZnO2


(B) CrSO4 (s) + Na2CO3 (s)   Na2CrO2 + SO2(g)


(C) P4O10(s) + CaO(s)  Ca3(PO4)2


(D) Cr2O3 (s)+ Na2CO3 (s) 
molten state
 NaCrO2 + CO2

69. All decomposition product(s) of which salt can react with NaOH solution
(A) BeCO3 (B) FeCO3 (C) CrSO4 (D) NH4Cl

70. Select correct match :

(A) Bessemerisation : Impurity is more oxidizable than the metal to be refined
(B) Mond’s process : Thermal decomposition of volatile compound
(C) Parke's Process : Solvent extraction
(D) Zone refing : Ultrapure refinement of element from its impure form.

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71. Which of the following statement is/are correct?
(A) Liquation is applied when the metal has low melting point than those of impurities associated with
extracted metal.
(B) Presence of carbon in steel makes it hard due to formation of cementite.
(C) Less reactive metals like Hg, Pb and Cu are obtained by self reduction from their sulphide ores.
(D) Amalgamation is used for purification of mercury

72. Lead is extracted by heating concentrated galena with which of the following substance(s) at required
temperature
(A) PbSO4 (B) Coke (C) PbO (D) All

O2  CO 2
CO +
G
C+O
Kj/mole 2  CO
73. of O2
M2O x

T1 T2 Temp
Correct option(s) for above Ellingham diagram is/are

(A) M2Ox + C(s)  M + CO is feasible above T2 temperature
(B) Metal is obtained in vapour phase
(C) Metal ‘M’ is extracted by rapid cooling
(D) Reduction of M2OX by coke is more economical than with CO

Comprehension (Q.74 to Q.76)

Iron forms iron halide salts by reacting the metal directly with halogen. FeI3 does not exist. FeF3 is white
solid inspite of five unpaired eectrons with d5 configuration. FeCl3 is soluble in water and is used as a
mordant in dyeing industry.

74. FeI3 does not exist because.

(A) of large size
(B) Fe3+ oxidises I– to I2
(C) of low lattice energy
(D) iodine is not highly electronegative enough to oxidise Fe to Fe3+

75. Anhydrous FeCl3 can be prepared by reaction of :

(A) Fe with dry chlorine (B) Fe with dil. HCl in the presence of O2
(C) Fe(OH)3 with conc. HCl (D) Fe2O3 with conc. HCl
76. FeCl3 solution added to K4[Fe(CN)6] gives A, while with KSCN gives B. A and B respectively are :
(A) Fe3[Fe(CN)6]2, Fe(CNS)3 (B) Fe4[Fe(CN)6]3, KFe(CNS)3
(C) Fe4[Fe(CN)6]3, K3[Fe(CNS)6 (D) Fe4[Fe(CN)6]3, [Fe(SCN) (H2O)5]2+

Comprehension (Q.77 to Q.79)

Aluminium is the most abundant metal in earth crust. It exists in combine state like oxide, fluoride, sulphates,
silicates, phosphate etc. Aluminium is mainly extracted by bauxite ore which is generally contaminated by
ferric oxide (red bauxite) and silica (white bauxite).
77. Which of the following can be used to separate chief impurity in red bauxite other than NaOH?
(A) Conc. nitric acid (B) Solid sodium carbonate
(C) Conc. ammonia solution (D) None of these

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78. If white bauxite is treated with conc. solution of sodium hydroxide silica present in bauxite
(A) Ramains unaffected (B) Forms soluble silicate
(C) Forms insoluble silicate (slag) (D) None of these

79. Which of the following step is not involved in the metallurgy of aluminium from red bauxite?
(A) Electrolytic reduction (B) Leaching
(C) electrolytic refining (D) None of these

Match the column :

80. Column-I Column-II
(Same characteristics of given (Pair of complexes)
pair of complex compound)
(A) Hybridization of central metal (P) [NiCl4]2– and [Co(SCN)4]2–
(B) Low spin complex (Q) [IrF6]3– and [Co(ox)3]3–
(C) Geometry of complex (R) [Cr(en)3]3+ and [Fe(NH3)6]2+
(D) Magnetic behaviour (S) [Ni(dmg)2] and [AgF4]–
(T) [Co(NH3)6]2+ and [Mn(H2O)6]2+

81. Column-I Column-II

(A) [Pt(NO2)2(en)]2+ (P) Stable according to E.A.N. rule
(B) [Cr(-C6H6)(NO)2] (Q) Ligand acts as ambidetate
(C) [Ir(SCN)(SO4)(NH3)4] (R) Bond order of M–L bond > 1.0
(D) [Cr(C2H4)(CO)5] (S) Bond order of ligand decreases
(T) Co-ordination number of central metal is six

82. Column I Column II

(A) Dithionous acid (P) S–O–S bond is not present

(B) Thiosulphuric acid (Q) All S atom in the molecule has oxidation
state +3

(C) Caro's acid (R) Acidic strength of –OH groups present in the
molecule is different

(D) Pyrosulphurous acid (S) at least one S atom has oxidation state +5 in
molecule

83. Column-I (Complex ion) Column-II (CFSE and hybridisation)

(A) [Co(NO2)6]3– (P) – 2.4 0, d2sp3- hybridisation
(B) [NiF6]4– (Q) –1.2 0 , d2sp3 - hybridisation
(C) [Cr(ox)3]3– (R) –1.2 0, sp3d2 - hybridisation
(D) [PtCl2(NH3)4]2+ (S) Diamagnetic
(T) Paramagnetic

84. Column-I Column-II

(Common characteristics present (Pair of complexes)
in given pair of complexes)
(A) Hydribization of central metal is same (P) Fe[Fe(CN)6], Cu3[Fe(CN)6]2
(B) Observed colour is due to charge transfer spectra (Q) K2Cr2O7, KMnO4
(C) Exhibits oxidizing character (R) Na4[Fe(CN)5(NOS)], [Fe(H2O)5(NO)]SO4
(D) d-d electronic transition occurs (S) [Fe(H2O)6]3+, [Cu(H2O)6]2+
(T) [Cr(NH3)6]3+, [Co(H2O)6]3+

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Subjective :
85. Number of stereoisomers possible for bis(benzoylacetanato)beryllium are :

86. In IF6– and TeF5– , sum of axial d-orbitals which are used in hybridisation in both species

87. Find the value of expression (x + y) for complexes :

(i) [Fe(CO)x]2– (ii) [Mn(NO)y(CO)]

88. Find out maximum number of carbon atoms that can lie in a plane in the [Cu(gly)2].

89. A weak field octahedron complex of Ni2+ has magnetic moment value of 2.82 B.M. The number of electrons
in the t2g level of Ni2+ will be :

90. Calcaulte the magnetic moment of a high-spin octahedral complex that has six electrns in 3d-orbitals

91. There are some species given below.

(i) O2+ (ii) CO (iii) B2 (iv) O2– (v) NO+ (vi) He2+ (vii) C2++ (viii) CN– (ix) N2–

Total number of species which have their fractional bond order.

92. Find out total number of paramagnetic inner orbital complex

K2[NiCl 4], K3[Fe(CN)6], K3[Cr(CN)6], K2[PtCl 4], Na2[Fe(CN)5NO], [Fe(H2O)NO]SO 4, K3[Co(C2O 4)3],
K4[Co(CN)6], [Cu(NH3)4]SO4.

93. Find out the value of expression |x + y| for complex ion [Co(EDTA)]–
Where, x = Total number of six membered ring(s)
y = Total number of five membered ring(s) having oxygen donor atom(s).

94. When B2H6 is allowed to react with following lewis bases, then how many given lewis bases form adduct
through unsymmetrical cleavage of B2H6 ?
NH3, MeNH2, Pyridine, CO, T.H.F., PH3, PF3, Me3N, Me2NH

95. Find out value of expression |x – y|, for complex compound. [Ni(dmg)2]
where ; x = Total number of carbon atom(s) that are sp3 hybridized.
y = Total number of atomic orbitals of valence shell of Ni2+ that participate in hybridization in the
complex compound formation

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 ANSWER KEY
(IRP HOME TEST-2)
1. D 2. B 3. D 4. B 5. C 6. D 7. B
8. D 9. C 10. C 11. D 12. D 13. C 14. D
15. C 16. A 17. C 18. D 19. C 20. A 21. A
22. C 23. A 24. C 25. B 26. C 27. A 28. B
29. A 30. C 31. B 32. B 33. C 34. D 35. D
36. ABC 37. ABC 38. ABD 39. ABC 40. ABC 41. ABC 42. ACD
43. BCD 44. AD 45. ABD 46. ACD 47. ACD 48. BCD 49. ABC
50. ABCD 51. ABCD 52. ABC 53. CD 54. ABD 55. ABD 56. AD
57. ABC 58. ABD 59. ABC 60. BCD 61. ABD 62. BCD 63. ABC
64. ACD 65. ABCD 66. BC 67. ACD 68. ACD 69. AC 70. ABC
71. ABC 72. AC 73. ABCD 74. B 75. A 76. D 77. B
78. B 79. D 80. A – P, Q, S ; B – Q, S ; C – P, Q, R, S, T ; D – P, Q, R, S, T
81. A – P,R,S,T ; B – P, R, S ; C – P, Q,R,S, T ; D – P, R, S, T
82. (A) P,Q; (B)P; (C) P,R; (D) P,R,S 83. A – P,S ; B – R, T ; C – Q, T ; D – P, S
84. A – P, Q, S, T ; B – P, Q, R ; C – P, Q, S ; D – P, R, S, T
85. 2 86. 4 87. 7 88. 4 89. 6 90. 5 91. 4
92. 4 93. 4 94. 3 95. 1

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