Paper 11
Paper 11
Paper 11
(b)
(i) What volume of air (containing 20% of O 2 by vol.) will be required to burn [3]
completely 10cm3 each of methane and acetylene.
(ii) The compound A has the following percentage composition by mass. Carbon [3]
26.7%, oxygen 71.1%, hydrogen 2.2%. Determine the empirical formula of A.
(H = 1, C = 12, O - 16) if the relative molecular mass of A is 90, what is the
molecular formula of A ?
MC 17 C - 11 269
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(f) Define Ionisation potential. Give its trend across the period and down the group. [2]
SECTION - II
(Attempt any four questions)
Question 2.
(a) Complete the following :
(i) Zn + O2 A + H2SO4 [3]
B + NH4OH
NH4OH in
excess
C + (NH4)2SO4 D + H2O
(b) Give a test each to prove that hydrochloric acid contains hydrogen gas and [3]
chlorine gas. (other than electrolysis)
(c) For each substance listed below, explain its significance in the extraction of [4]
Aluminium.
(i) Bauxite (ii) Sodium hydroxide
(iii) Cryolite (iv) Graphite
Question 3.
(a) Give reasons :- [4]
(i) Commercial concentrated Nitric acid is yellow in colour, but when it is diluted
with water, it turns colourless.
(ii) Red brown vapours are produced when concentrated sulphuric acid is added
to potassium bromide.
(c) Find the odd out and explain your choice. (note : valency is not a criterion) [2]
(i) Al(OH)3, Pb(OH)2, Mg(OH)2, Zn(OH)2
(ii) Formic acid, Nitric acid, Acetic acid, Propanoic acid.
(d) How does the chemical reactivity vary down the [3]
(i) Alkali metals ? (ii) Halogens ?
(iii) Inert Gases ?
Question 5.
(a) Give the Electron dot representation of [2]
(i) CCl4 (ii) CO2
(iii) H3O+
(iv) CH4
(b) Write the chemical equation for conversions as shown below with the help [6]
of a diagram.
ZnCO3
(B)
A
Zn(NO3)2
(C) E
ZnSO4 Zn(OH) 2
(D)
F
ZnO
(c) Name the product at the Cathode and Anode during the electrolysis of [2]
(i) Acidulated water with inert electrodes.
(ii) Acidified copper sulphate with inert electrodes.
Question 6.
(a)
(i) Name the ore of Zinc containing its sulphide. [4]
(ii) In the proccess of extracting Zn, the above named ore is roasted. Write the
equation for the reaction which takes place when the sulphide ore is roasted.
(iii) Name the substance used to reduce the roasted ore. Write the equation for the
reaction.
(iv) Iron is removed from a blast furnace generally as a liquid. State how zinc could
have been removed from the furnace.
H H O
| | ||
(ii) H – C – C – C
| | |
H H OH
MC 17 C - 11 271
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Question 7. [3]
(a) Define Isomerism. How many Isomers are possible for an alkane having
molecular formula C4H10
272 MC 17 C - 11