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    Chapter 14 HOME WITH ANS

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    Serpico
    The document contains 12 chemistry problems related to reaction rates and rate constants. The problems ask students to determine overall reaction orders, calculate rate constants from initial rate data, predict rate laws from reaction mechanisms, and calculate changes in concentration over time given rate constants and orders. The final problem asks students to determine the rate law predicted by a two-step reaction mechanism where the first step is slow and the second is fast.

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    Chapter 14 HOME WITH ANS

    Uploaded by

    Serpico
    90 views7 pages
    The document contains 12 chemistry problems related to reaction rates and rate constants. The problems ask students to determine overall reaction orders, calculate rate constants from initial rate data, predict rate laws from reaction mechanisms, and calculate changes in concentration over time given rate constants and orders. The final problem asks students to determine the rate law predicted by a two-step reaction mechanism where the first step is slow and the second is fast.

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    The document contains 12 chemistry problems related to reaction rates and rate constants. The problems ask students to determine overall reaction orders, calculate rate constants from initial rate data, predict rate laws from reaction mechanisms, and calculate changes in concentration over time given rate constants and orders. The final problem asks students to determine the rate law predicted by a two-step reaction mechanism where the first step is slow and the second is fast.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    90 views7 pages

    Chapter 14 HOME WITH ANS

    Uploaded by

    Serpico
    The document contains 12 chemistry problems related to reaction rates and rate constants. The problems ask students to determine overall reaction orders, calculate rate constants from initial rate data, predict rate laws from reaction mechanisms, and calculate changes in concentration over time given rate constants and orders. The final problem asks students to determine the rate law predicted by a two-step reaction mechanism where the first step is slow and the second is fast.

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    CHEM 1412 solution of homework chap14

    1. The rate of the following reaction in terms of bromate is _____.


    . 5Br¯(aq) + BrO3¯(aq) + 6H+(aq)  3Br2(aq) + 3H2O(l)
    A)

    B)

    C)

    D)

    2. The correct relation between the rates of the reaction: 2H2 + O2  2H2O is _____.
    A)

    B)

    C)

    D)

    3. The rate at which hydrogen reacts in the reaction N2 + 3H2  2NH3 is 0.074 Ms–1. The
    rate of formation of ammonia is _____ Ms–1.
    A) 0.148
    B) 0.049
    C) 0.111
    D) 0.222
    4. Determine the rate constant for the reaction A +B Products from the following initial
    rate data:
    [A] [B] Rate(M/s)
    1.50 1.50 3.20  10–1
    1.50 2.50 3.20  10–1
    3.00 1.50 6.40  10–1

    The rate constant is _____.


    A) 0.213 s–1
    B) 0.0825 M–1s–1
    C) 3.2  10–2 s–1
    D) 0.525 s–1

    5. The rate of the reaction A  B when [A] = 0.35 M is 1.6  10–2 Ms–1. If the reaction is
    second order in A, the rate constant is _____ M–1s–1.
    A) 1.3
    B) 2.6
    C) 26
    D) 0.13

    6. The reaction 4PH3(g)  P4(g) + 6H2(g) is a second-order reaction with a half-life of 35


    s. The rate constant of the reaction is _____ s–1.
    A) 1.12  10–4
    B) 1.98  10–2
    C) 1.98  10–3
    D) 3.16  10–2

    7. The rate constant of the second-order reaction 2NOBr(g)  2NO(g) + Br2(g) is 0.80 M–
    1 –1
    s . Starting with a concentration of NOBr of 0.086 M, the concentration of NOBr after
    22 seconds is _____.
    A) 0.022 M
    B) 0.076 M
    C) 0.062 M
    D) 0.034 M.
    8. The rate constant of the zero order reaction A  product is 0.54 M.s–1. The time taken
    for the concentration of A to decrease from 0.62 M to 0.28 M is _____ seconds.
    A) 6.3
    B) 21
    C) 3.6
    D) 15

    9. The rate constant of a reaction is 4.60  10–4 s–1 at 350 C. The temperature at which the
    rate constant will be 8.80  10–4 s-1 is _____. [The activation energy is 104 kJ mol–1].
    A) 461 C
    B) 371 C
    C) 417 C
    D) 392 C
    29.The following data were obtained for the hypothetical reaction 2A + B  products.
    [A]0 (M) [B]0 (M) Initial Rate (M/s)
    0.2 0.1 5
    0.2 0.2 20
    0.6 0.1 45
    What is the overall order of this reaction?
    A) 3
    B) 1/2
    C) 0
    D) 4
    E) 1
    ANS: D
    10. The rate constant for a reaction at 305.0 K is two times the rate constant at 295.0 K. The
    activation energy of the reaction is _____ kJ mol–1.
    A) 36.2
    B) 21.7
    C) 72.9
    D) 51.8
    11. The reaction 2 NO + Cl2  2NOCl is thought to follow the mechanism:
    NO + Cl2  NOCl2 (slow)
    NOCl2 + NO  2NOCl (fast).
    The Rate Law of the reaction is ______.
    A) rate = k [NO]2 [Cl2]
    B) rate = k [NO] [Cl2]
    C) rate = k [NO] [Cl2] 2
    D) rate = k [NO]

    12. A catalyst will change the ______ of the reaction.


    A) activation energy
    B) enthalpy
    C) entropy
    D) free energy

    24.The balanced chemical equation and rate law for the reaction between NO(g) and H2(g) at a particular
    temperature are
    2NO(g) + 2H2(g)  N2(g) + 2H2O(g)
    Rate = k[NO]2[H2]
    What is the reaction order with respect to hydrogen?

    A) 4
    B) 0
    C) 2
    D) 3
    E) 1
    ANS: E

    53.A reaction that is second-order in one reactant has a rate constant of 2.2  10–2 L/(mol · s). If the initial
    concentration of the reactant is 0.360 mol/L, how long will it take for the concentration to
    become 0.180 mol/L?
    A) 320 s
    B) 63 s
    C) 1300 s
    D) 32 s
    E) 130 s
    ANS: E

    99.The complete mechanism for a reaction is considered to occur in two steps, one of which is slow and
    the other fast:
    A + 2B  C + D slow
    A+CE+F fast
    What is the rate law predicted by this mechanism?
    A) Rate = k[A]2[B]
    B) Rate = k[A]2[B][C]
    C) Rate = k[A][C]
    D) Rate = k[A][B][C]
    E) Rate = k[A][B]2
    ANS: E

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