Date Printed: 04/15/2020 Product: 1000B1NL

Safety Data Sheet

Prepared in Accordance with HCS 29
C.F.R. 1910.1200

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 1000B1NL

Product Name: CARBOGUARD 893 SG PART B Revision Date: 04/15/2020

Supercedes Date: 12/06/2018
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - ehs@stoncor.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 4

Hazardous to the aquatic environment, Chronic, category 2
Carcinogenicity, category 1A
Flammable Liquid, category 3
STOT, repeated exposure, category 1
Skin Corrosion, category 1
Skin Sensitizer, category 1

2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

ORTHO-XYLENE, ETHYL BENZENE, PARA-XYLENE, META-XYLENE, MICROCRYSTALLINE SILICA, TOFA, REACTION
PRODUCTS WITH TEPA

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HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Corrosion, category 1 H314-1 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Carcinogenicity, category 1A H350-1A May cause cancer.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment, H411 Toxic to aquatic life with long lasting effects.
Chronic, category 2
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P3 IF IN EYES: Rinse cautiously with water for several minutes.
38 Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous Ingredients
CAS-No. Chemical Name %
14808-60-7 MICROCRYSTALLINE SILICA 50 - <75
108-38-3 META-XYLENE 2.5 - <10
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA 2.5 - <10
106-42-3 PARA-XYLENE 2.5 - <10
100-41-4 ETHYL BENZENE 2.5 - <10
64742-95-6 AROMATIC HYDROCARBON 2.5 - <10
67-63-0 ISOPROPANOL 2.5 - <10
64-17-5 ETHYL ALCOHOL 2.5 - <10
95-47-6 ORTHO-XYLENE 2.5 - <10

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

14808-60-7 GHS08 H341-350-372 0
108-38-3 GHS02-GHS07 H312-315-332 0
68953-36-6 GHS05-GHS07-GHS09 H314-317-400-410 0
106-42-3 GHS02-GHS07-GHS08 H304-312-315-332-335-371 0
100-41-4 GHS02-GHS07-GHS08 H225-304-315-319-332-351-373-412 0
64742-95-6 GHS02-GHS07-GHS08-GHS09 H226-304-315-319-332-335-336-411 0

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67-63-0 GHS02-GHS07 H225-319-336 0
64-17-5 GHS02 H225 0
95-47-6 GHS02-GHS07 H312-315-332 0
Remarks: CASStatement

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions

Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).

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6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal protection. Wash thoroughly after
handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Ingredients with Occupational Exposure Limits

(US)

Name CAS-No. ACGIH TWA ACGIH STEL ACGIH Ceiling

MICROCRYSTALLINE SILICA 14808-60-7 0.025 MGM3 N/E N/E
META-XYLENE 108-38-3 100 PPM 150 PPM N/E
TOFA, REACTION PRODUCTS WITH TEPA 68953-36-6 N/E N/E N/E
PARA-XYLENE 106-42-3 100 PPM 150 PPM N/E
ETHYL BENZENE 100-41-4 20 PPM 125 ppm
AROMATIC HYDROCARBON 64742-95-6 300.0 PPM N/E N/E
ISOPROPANOL 67-63-0 200 PPM 400 PPM N/E
ETHYL ALCOHOL 64-17-5 N/E 1000 PPM N/E
ORTHO-XYLENE 95-47-6 100 PPM 150 PPM N/E

Name CAS-No. OSHA PEL OSHA STEL

MICROCRYSTALLINE SILICA 14808-60-7 0.05 MGM3 N/E

META-XYLENE 108-38-3 100.00 PPM N/E

TOFA, REACTION PRODUCTS WITH TEPA 68953-36-6 N/E N/E

PARA-XYLENE 106-42-3 100.00 PPM N/E

ETHYL BENZENE 100-41-4 435 MGM3, 100 545 MGM3, 125

PPM PPM

AROMATIC HYDROCARBON 64742-95-6 500.0 PPM N/E

ISOPROPANOL 67-63-0 980 MGM3, 400 1225 MGM3,

PPM 500 PPM

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ETHYL ALCOHOL 64-17-5 1900 MGM3,

N/E
1000 PPM

ORTHO-XYLENE 95-47-6 100.00 PPM N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Brown, Viscous Liquid

Physical State Liquid

Odor Solvent

Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range 149 F (65 C) - 500 F (260 C)
Flash Point 75F (24C)
Evaporation rate Slower than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.9 - 36.0

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

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VOC Content g/l: 324

Specific Gravity (g/cm3) 1.45

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Skin Corrosion: category 1

Sensitization: Skin Sensitization: Category 1

Repeated dose toxicity: STOT Repeated Dose (lungs): Category 1

Carcinogenicity: Category 1A

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

STOT-single exposure: No Information

STOT-repeated exposure: No Information

Aspiration hazard: No Information

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
CAS-No.
LC50
14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available 0.000 0.000

108-38-3 META-XYLENE Not Available Not Available Not Available 0.000 0.000

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TOFA, REACTION 4750 mg/kg

68953-36-6 Not Available 0.000 0.000
PRODUCTS WITH TEPA oral, rat

106-42-3 PARA-XYLENE Not Available Not Available Not Available 0.000 0.000

3500 mg/kg >5000 mg/l, 17.2 mg/L

100-41-4 ETHYL BENZENE rat, oral dermal rabbit
0.000 0.000
Inh, Rat, 4Hr
3670 ppm/8
4700 mg/kg,
64742-95-6 AROMATIC HYDROCARBON oral, rat
Not Available hours, rat, 0.000 0.000
inhalation
22500
4720 mg/kg 12800 mg/kg,
67-63-0 ISOPROPANOL rat, oral dermal, rabbit
ppm/8hrs rat, 0.000 0.000
inhalation
20000
7060 mg/kg,
64-17-5 ETHYL ALCOHOL oral, rat
ppm/10 hrs, 0.000 0.000
rat, inhalation

95-47-6 ORTHO-XYLENE Not Available Not Available Not Available 0.000 0.000

Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals.

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

108-38-3 META-XYLENE No information No information No information
68953-36-6 TOFA, REACTION PRODUCTS WITH TEPA No information No information No information
106-42-3 PARA-XYLENE No information No information No information
1.8 mg/l (Daphnia
100-41-4 ETHYL BENZENE Magna)
4.6 mg/l (Green Algae) 4.2 mg/l (Rainbow Trout)

64742-95-6 AROMATIC HYDROCARBON No information No information No information

>1000 m/gL
13299 mg/l (Daphnia 9640 mg/L (pimphales
67-63-0 ISOPROPANOL Magna)
(desmodesmus
promelas)
subspicatus)
64-17-5 ETHYL ALCOHOL 2 mg/l (Daphnia Magna) No information 42 mg/l (fish)
95-47-6 ORTHO-XYLENE No information No information No information

13. Disposal Considerations

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13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A

14.4 Packing group III

14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Flammable (gases, aerosols, liquids, or solids), Carcinogenicity, Acute Toxicity (any route of exposure), Skin Corrosion or
Irritation, Respiratory or Skin Sensitization, Specific target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
META-XYLENE 108-38-3
PARA-XYLENE 106-42-3
ETHYL BENZENE 100-41-4
ISOPROPANOL 67-63-0
ORTHO-XYLENE 95-47-6
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

POLYAMIDE RESIN TRADE SECRET
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

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POLYAMIDE RESIN TRADE SECRET

CALIFORNIA PROPOSITION 65

WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov

International Regulations: As follows -

* Canadian DSL:

All chemical ingredients included on inventory (DSL)

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H351 Suspected of causing cancer.
H371 May cause damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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