Kvpy Past Year

Join Telegram-@mainchannelpdf
Included
5 Practice Sets
Join Telegram-@mainchannelpdf
Kishore Vaigyanik Protsahan Yoiana
12 YEARS'
SOLVED PAPERS
2020-2009
STREAM SA
Authors
Lakshman Prasad (Mathematics)
Deepak Paliwal, Mansi Garg (Physics)
Neha Minglani Sachdeva (Chemistry)
Sanubia Saleem (Bialagy)
,:,arihant
ARI HANT PRAKASHAN (Series), MEERUT
,:carihant
ARIHANT PRAKASHAN (Series), MEERUT
All Rights Reserved
© Publishers
No part of this publication may be re-produced, stored in a retrieval system or distributed in
any form or by any means, electronic, mechanical, photocopying, recording, scanning, web
or otherwise without the written permission of the publisher. Arihant has obtained all the
information in this book from the sources believed to be reliable and true. However, Arihant
or its editors or authors or illustrators don't take any responsi bility for the absolute accuracy
of any information published and the damages or loss suffered there upon.
All disputes subject to Meerut (UP) jurisdiction only.
!Ii Administrative & Production Offices

Regd. Office
'Ramchhaya' 4577/15, Agarwal Road, Darya Ganj, New Delhi -110002
Tele: 01 1- 47630600, 43518550; Fax: 01 1- 23280316
!Ii Head Office

Kalindi, TP Nagar, Meerut (UP ) - 250002
Tel: 0121-7156203, 7156204
!Ii Sales & Support Offices

Agra, Ahmedabad, Bengaluru, Bareilly, Chennai, Delhi, Guwahati,
Hyderabad, Jaipur, Jhansi, Kolkata, Lucknow, Nagpur & Pune.
Yi ISBN : 978-93-25298-22-4
!Ii
PO No: TXT-XX-XXXXXXX-X-XX
Published by Arihant Publications (India) Ltd.

For further information about the books published by Arihant
log on to www.arihantbooks.com or email to info@arihantbooks.com
Followuson O @ a@)
Kishore Vaigyanik Protsahan Yojana
ABOUTTHE EXAM
KVPY i.e. Kishore Vaigyanik Protsahan Yojana is a National Level Fellowship (scholarship) Program in
Basic Science (Physics, Chemistry, Mathematics & Biology) upto Pre-Phd Level, run by Department of
Science & Technology, Government ofIndia and Conducted by I/SC (Indian Institute ofScience)
Bangalore, Karnataka Annually.
It Was Started in 1999 to Encourage Basic Sciences Students to take up Research Career in Sciences.
The Objective ofthe Exam is to Encourage Talented Students for Research Career in Sciences.
ELIGIBILITY CRITERIA
KVPY scholarships are given only to Indian Nationals to study in India. There are three
streams in KVPY; SA, SB & SX. Eligibility criteria for different streams is discussed below;
• For SA Class 11 Students who passed class 10 with minimum 75% (65% for SC/ST/PWD)
marks in Mathematics & Science.
The fellowship of students selected in SA will be activated only if they pursue
undergraduate courses in Basic Sciences (B.Sc./B.S./B.Stat./B.Math/lntegrated M.Sc. or
M.S.) and have secured a minimum of 60% (50% for SC/ST/PWD) marks in science
subjects in class 12th.
• For SX Class 12 Students aspiring to pursue undergraduate program (B.Sc. etc ) with
basic sciences (Physics, Chemistry, Mathematics & Biology) who passed class 10 with
minimum 75% (65% for SC/ST/PWD) marks in Mathematics & Science.
The fellowship of students selected in SX will be activated only if they pursue
undergraduate courses in Basic Sciences (B.Sc./B.S./B.Stat./B.Math/lntegrated M.Sc. or
M.S.) and have secured a minimum of 60% (50% for SC/ST/PWD) marks in science
subjects in class 12th.
• For SB B.Sc. 1st year Students who passed class 12 with 60% marks in Maths & Sciences
(PCMB) & class 10 with minimum 75% marks in Mathematics & Science.
In order to activate fellowship, in the first year of undergraduate course they should
secure minimum 60% (50% for SC/ST/PWD) marks.
Those students who are intending or pursuing undergraduate program under distance
education scheme or correspondence course of any university are not eligible.
SYLLABUS OF KVPY
There is no prescribed syllabus for KVPY aptitude test, it aims to assess the understanding &
analytical ability of the students than his/her factual knowledge. However questions are
framed from syllabus upto class 10/12/lst Year of Undergraduate Courses in basic sciences, as
applicable. There are two Questions Papers in KVPY; one for stream SA & Other for SB/SX
(Question Paper is same for SB & SX).
QUESTION PAPERS PATTERN

There are two Questions Papers in KVPY; one for stream SA & Other for SX/SB
(Question Paper is same for SB & SX).
• Question Paper for SA Stream caries 80 Questions for 100 marks. There are Two Parts in
the Question Paper; Part I has 15 Questions of 1 mark each for Mathematics, Physics,
Chemistry & Biology while Part II has 5 Questions of 2 marks each for Mathematics,
Physics, Chemistry & Biology.
• Question Paper for SB/SX Stream caries 120 Questions for 160 marks. There are Two
Parts in the Question Paper; Part I has 20 Questions of 1 mark each for Mathematics,
Physics, Chemistry & Biology while Part II has 10 Questions of 2 marks each for
Mathematics, Physics, Chemistry & Biology.
MODE OF EXAM
KVPY is conducted in Online Mode in English & Hindi Medium.
TIME OF EXAM
• Normally the notification or advertisement for KVPY appear in National Newspapers on
May 11 (Technology Day) and Second Sunday of July every year.
• Generally the exam is conducted in the month of November.
SELECTION PROCESS
After scrutiny of application forms on the basis of eligibility criteria for various streams all
eligible students are called for Aptitude Test conducted in English & Hindi Medium at
different centers across the country. On the basis of performance in aptitude test shortlisted
students are called for an interview, which is the final stage of selection procedure.
FELLOWSHIPS
The selected students are eligible to receive KVPY fellowship after class 12th/1st Year of
Undergraduate course only if they pursue Undergraduate Courses in Basic Science, upto Pre
PhD or 5 Years whichever is earlier.
Details of fellowships are listed below;
Monthly Annual
Basic Science
Fellowship Contingency Grant
SNSX/SB during 1st to lllrd year

of B.Sc./B.S./BB.Stat./B.Math/ Rs. 5000 Rs. 20000
Integrated M.Sc or M.S.
SNSX/SB during M.Sc. / IVth to Vth
years of Integrated M.Sc /M.S./ Rs. 7000 Rs. 28000
M.Math/ M.Stat.
CONTINUATION/ RENEWAL OF FELLOWSHIP

• The fellow should continue to study basic science and should also maintain a minimum
level of academic performance as 1st division or 60% (50% for SC/ST/PWD) marks in
aggregate. Also the fellow has to pass all the subjects prescribed for that particular year.
• In each year marks are to be certified by the Dean or Head of the Institution.
• The fellowship will be discontinued if above marks are not obtained. However if fellow
passed all the subjects & obtain marks more than 60% (50% for SC/ST/PWD) in
subsequent year, the fellowship can be renewed only for that year onwards.
• If KVPY fellow opts out of the basic science at any stage then monthly fellowship and
contingency grant will be forfeited from him.
KVPY Timeline 2021

IMPORTANT DATES
Opening of Application Portal 2nd Week of July 2021
Last Date of Submission of Online Application 1st Week of September 2021
KYPY Aptitude Test 1st Week of November 2021
APPLICATION FEE
For General Category Rs. 1000/
For SC/ST/PWD (Bank charges extra) Rs. 500/-
For more details visit:www.kvpy.iisc.ernet.in
CONTENTS
KVPY SA QUESTION PAPERS (2020-2009)
QUESTION PAPER QUESTION PAPER QUESTION PAPER

2020 2019 2018
Pg. No. 1-16 Pg. No. 1-16 Pg. No. 1-15

2017 (19Nov) 2017 (05 Nov) 2016
Pg. No. 16-31 Pg. No. 32-47 Pg. No. 48-62

2015 2014 2013
Pg. No. 63-76 Pg. No. 77-92 Pg. No. 93-107

2012 2011 2010
Pg. No. 108-122 Pg. No. 123-137 Pg. No. 138-150
QUESTION PAPER
2009
Pg. No. 151-164
KVPY PRACTICE SETS (1-5) 167-232

KVPY
KISHORE VAIGYANIK PROTSAHAN YOJANA
OUESTION PAPER 2020

Stream :SA
MM: 100
Instructions
1. There are 80 questions in this paper.
2. This question paper contains two parts; Part I and Part II. There are four sections; Mathematics, Physics, Chemistry
and Biology in each part.
3. Out of the four options given with each question, only one is correct.
� PART-I (1 Mark Questions)
MATHEMATICS (b) .fiiq ,.fiir, .fqr are rational, but .Jp, .Jq, .Jr are
irrational
1. Let [x] be the greatest integer less than or equal to :1; (c) .Jp, .Jq, .Jr are rational
for a real number x. Then the equation [x2] = x + 1 has (d) .fiiq, .fiir, .fqr are irrational
(a) two solutions (b) one solution
(c) No solution (d) More than two solutions 4. Let A, B, C be three points on a circle of radius 1 such
2. Let Pi (x) = i3 - 2020x2 + b1x + s and that L ACB = �- Then, the length of the side AB is
4
p2 (x) = i3 - 202 lx2 + b2x + c2 be polynomials having (a) J3 (b) � (c) � (d) -J2
two common roots a and�- Suppose there exist 3 v2
polynomials Qi (x) and qix) such that 5. Let x and y be two positive real numbers such that
Pi (X)Qi (x) + p2 (x)q2 (x) = x2 - 3x + 2. Then the correct x + y = 1. Then, the minimum value of! + ! is
identity is X y
(a) A (3) + p2(1) + 4028 = 0
(b) A (3) + p2(1) + 4026 = 0
(a) 2 (b) � (c) 3 (d) 4
2
(c) A (2) + p2(1) + 4028 = 0 6. Let ABCD be a quadrilateral such that there exists a
(d) A (1) + pi2) + 4028 = 0 point E inside the quadrilateral satisfying
AE=BE=CE=DE. Suppose LDAB, LABC, LBCD
3. Suppose p, q, rare positive rational numbers such is an arithmetic progression. Then the median of the
that ✓P + ,[<i + ✓r is also rational. Then set {LDAB, LABC, LBCD} is
(a) ✓P , .Jq, .Jr are irrational w�6 ��4 ��3 oo�2
2 KVPY Question Paper 2020 Stream : SA
7. The number of ordered pairs (x, y) of positive integers 17. Consider two wires of same material having their
x
satisfying 2 + 3Y = 5xy is ratio of radii to be 2 : 1. If these two wires are
(a) 1 (b) 2 (c) 5 (d) Infinite stretched by equal force, then the ratio of stress
produced in them is
8. If theintegers from 1 to 2021 are written as a single 3
integer like 123 ... 91011 ... 20202021, then the (a) _! (b) _! (c) - (d) 1
4 2 4
2021st digit (counted from the left) in the resulting
number is 18. A submarine has a window of area 30 x 30 cm 2 on its
(a) 0 (b) 1 (c) 6 (d) 9
ceiling and is at a depth of 100 m below sea level in a
sea. If the pressure inside the submarine is
9. In a MBC, a point D is chosen on BC such that maintained at the sea-level atmosphere pressure,
BD : DC= 2 : 5. Let P be a point on the circumcircle then the force acting on the window is (consider
ABC such that LPDB = LBAC. Then PD : PC is density of sea water= 1.03 x 10 3 kg/m3 , acceleration
(a) -J2: -If, (b) 2 : 5 (c) 2 : 7 (d) -J2: -J7 due to gravity= 10 m/s 2)
10. Let [x] be the greatest integer less than or equal to x, (a) 0.93 x Hf N (b) 0.93 x l(r N
for a real number x. Then the following sum (c) 1.86 x Hf N (d) 1.86 x l(r N
22020 + 1 + 32020 + 1 + 42020 + 1 19. A spacecraft which is moving with a speed u relative
[ 2018 + ] [ 2018 + ] [ 2018 + ]
2 1 3 1 4 1 to the earth in the x-direction, enters the
2020 + l 2020 + l gravitational field of a much more massive planet
+ 5 + 6
[ 2018 + ] [ 2018 + ]is which is moving with a speed 3u in the negative
5 1 6 1
x-direction. The spacecraft exits following the
(a) 80 (b) 85 (c) 90 (d) 95 trajectory as shown below.
2020
11. Let r be the remainder when 2021 is divided by u
:
2020 2 • Then r lies between ----➔---------------------
:)
(a) 0 and 5 (b) 10 and 15
_____
(c) 20 and 100 (d) 107 and 120
12. In a MBC, the altitude AD and the median AE _________________ __
divide LA into three equal parts. If BC= 28, then the
The speed of the spacecraft with respect to the earth
nearest integer to AB + AC is
a long a time after it has escaped the planet's gravity
(a) 38 (b) 37 (c) 36 (d) 33
is given by
13. The number of permutations of the letters (a) u (b) 4u (c) 2u (d) 7u
a1 , a2 , a3 , a4 , a5 in which the first letter a1 does not
20. The earth's magnetic field was flipped by 180° a
occupy the first position (from the left) and the
million years ago. This flip was relatively rapid and
second letter a2 does not occupy the second position
took 10 5 yrs. Then, the average change in orientation
(from the left) is
per year during the flip was closest to
(a) 96 (b) 78 (c) 60 (d) 42
(a) 1 s (b) 5 s
14. There are m books in black cover and n books in blue (c) 10 s (d) 30 s
cover, and all books are different. The number of
ways these (m + n) books can be arranged on a shelf 21. The platelets are drifting with the blood flowing in a
so that all the books in black cover are put side by streamline flow through a horizontal artery as shown
side is below
(a) m!n! (b) m!(n + 1)!
() ()
(c) (n + 1)! (d) (m+ n)! ---+
II Ill
15. A 5-digit number abcde, when multiplied by 9, gives
the 5-digit number edcba. The sum of the digits in Artery is contracted in region II. Choose the correct
the number is
statement.
(a) 18 (b) 27 (c) 36 (d) 45
(a) As the platelets enter a constriction, the platelets get
squeesed closer together in the narrow region and
PHYSICS hence the fluid pressure must rise there
(b) As the platelets enter a constriction, pressure is lower
16. A mouse jumps off from the 15th floor of a high-rise there
building and lands 12 m from the building. Assume (c) The artery's cross-section area is smaller in the
that, each floor is of 3 m height. The horizontal speed constriction and thus the pressure must be larger
with which the mouse jumps is closest to there because pressure equals the force divided by
(a) zero (b) 5 km/h area
(c) 10 km/h (d) 15 km/h (d) Pressure is same in all the parts of the artery
WWW.JEEBOOKS.INl
KVPY Question Paper 2020 Stream : SA 3
22. Which of the following colourful patterns is due to 0 c::··c,_ i,c- "-""--·' :::1..-,c: -: ·q, '""1-'lf-j' ::/?ti"."
•:c.,,· I
::p::. .: 1:c 1,; ·: :·· s:i. ,+i,:� :: ,; . l: :! l "J. 2+ .h

diffraction of light?
=T,.,... n i , · "'1 :r "ii' ·2 1r ,-
-50 '+ '--'- + :..1.. ,��
(a) Rainbow 11 :: :! 7J.':J;_·,, 4�17'
(b) White light dispersed using a prism d.T: � Fl' t:: ,: :,· ,: .:=i i:_,_ ==· tf',:i! :fr, -=tt=rf
;.1 j;;_" - : 1: 1::, ':,: ', :'l H ·:: ..;�· I:· i w: il 1;
C
(c) Colours observed on compact disc 0
(d) Blue colour of sky ,cj 11 :,I : I:!', ':'. " ::1 ,1/.·a,J: J.c.,J '!I II 11:
23. Two balls are projected with the same velocity but
� -100
�
C
,:, 1 . 1 ;,-,r 1,;-,, ,: -,,.;,ri.1-- ;,-1;- i -w,
1J ;;t ,'!' I!' =--!�I?:. 2..±:! -: :: : I I '1- 'jf ' 'u �
11:
with different angles with the horizontal. Their � '4 1
:+L:: Ee!�-,;,,'.::_,.:: .i4.J:'. :: 111 j '. :) :�_, _ j.h

'1 r : 1-;.z - :·, ., ,r!· r �: !-1 -nII~! ,II:1 1
ranges are equal. If the angle of projection of one is -150 -
30° and its maximum height is h, then the maximum ', '!
41__,,.�J�� ' ::_,
height of other will be 'l-- 'J; � '"'=l iJ: c-:' ::· C:-:j ",- '-':-- + ' · i '- -� Tr 'ii---!Hi:
0 1
(a) h (b) 3 h -250 �',1 ' - 'TI;'"� '; : il i;'..' 'I.· I;. 'ii •i! :11- ii 11\
(c) 6 h (d) 10 h -1--0.8 -0.6 --0.4 --0.2 0
24. Figure below shows a shampoo bottle in a perfect Distance between the object and the lens
cylindrical shape. (a) 250 m (b) 0.004 m
(c) 125 m (d) 0.002 m
27. In a circus, a performer throws an apple towards a
hoop held at 45 m height by another performer
standing on a high platform (see figure). The thrower
In a simple experiment, the stability of the bottle aims for the hoop and throws the apple with a speed
filled with different amount of shampoo volume is of 24 mis. At the exact moment that the thrower
observed. The bottle is tilted from one side and then releases the apple, the other performer drops the
released. Let the angle 0 depicts the critical angular hoop. The hoop falls straight down. At what height
displacement resulting, in the bottle losing its above the ground does the apple go through the hoop?
stability and tipping over. Choose the graph correctly
depicting the fraction f of shampoo filled (f = 1
corresponds to completely filled) versus the tipping
angle 0.
0 0
(a) (b)
(a) 21 m (b) 22 m
(c) 23 m (d) 24 m
28. A student was trying to construct the circuit shown
0 in the figure below marked (a), but ended up
0
constructing the circuit marked (b). Realising her
mistake, she corrected the circuit, but to her surprise,
(c) (d)
the output voltage (across RJ did not change.
100n 200n
10VC=f fH
25. At a height of 10 km above the surface of earth, the
value of acceleration due to gravity is the same as (a)
that of a particular depth below the surface of earth.
Assuming uniform mass density for the earth, the
depth is
(a) 1 km (b) 5 km
(c) 10 km (d) 20 km
26. The following graph depicts the inverse of
(b)
magnification versus the distance between the object
and lens data for a setup. The focal length of the lens The value of resistance R is
used in the setup is (a) 100 Q (b) 150 Q (c) 200 Q (d) 300 Q
WWW.JEEBOOKS.INl
29. The ratio of gravitational force and electrostatic The compounds which can exhibit optical activity are
repulsive force between two electrons is (a) only II, IV and V (b) only IV and V
approximately (gravitational constant = 6. 7 x 10-11 (c) only I, II and V (d) only I, II and IV
Nm 2/kg 2 , mass of an electron = 9. 1 x 10-31 kg, charge 33. A molecule which has 1°, 2 ° and 3° carbon atoms is
on an electron = 1.6 x 10-19 C) (a) 2,3,4-trimethylpentane (b) chlorocyclohexane
36
(a) 24 X 10-24 (b) 24 X 10- (c) 2,2-dimethylcyclohexane (d) methylcyclohexane
(c) 24 x 10-44 (d) 24 x 10-54
34. The organic compound which can be purified by
30. A monochromatic beam of light enters a square steam distillation is
enclosure with mirrored interior surfaces at an angle
of incidence 0; (;c 0) (see figure). For some value(s) of
(a) acetone (b) aniline (c) glucose (d) ethanol
0;, the beam is reflected by every mirrored wall (other 35. Among the following, the most acidic compound is
than the one with the opening) exactly once and exits
the enclosure through the same hole. Which of the
following statements about this beam is correct?
36. A closed 10 L vessel contains 1 L water gas

(1 : 1 CO: H 2 ) and 9 L air (20% 0 2 by volume) at
STP. The contents of the vessel are ignited. The
number of moles of CO2 in the vessel is closest to
(a) 0.22 mol (b) 0.022 mol (c) 0.90 mol (d) 3.60 mol
(a) The beam will not come out of the enclosure for any 37. A certain metal has a work function of = 2 eV. It is
value of0i. irradiated first with 1 W of 400 nm light and later
(b) The beam will come out for more than two values of0i. with 1 W of 800 nm light. Among the following, the
(c) The beam will come out only at 0i = 45. correct statement is
[Given: Planck constant (h) = 6.626 x 10-34 m 2 kg s-1;
(d) The beam will come out for exactly two values of0i.
CHEMISTRY
Speed oflight (c) = 3 x 10 8 ms-1]
(a) both colours of light give rise to same number of
photoelectrons.
31. The acidity of (b) 400 nm light gives rise to less energetic photoelectrons
¢ ¢
than 800 nm light.
OH (c) only 400 nm light leads to ejection of photoelectrons.
(d) 800 nm light leads to more photoelectrons.
38. Among the following, the correct statement about the
OMe N02 chemical equilibrium is
(a) equilibrium constant is independent of temperature.
Ill IV
(b) equilibrium constant tells us how fast the reaction
follows the order reaches equilibrium.
(a) I >II >III>IV (b) IV>III>II>I (c) at equilibrium, the forward and the backward
reactions stop so that the concentrations of reactants
(c) III >IV>I> II (d) III>II>IV>I and products are constant.
32. Among the following, (d) equilibrium constant is independent of whether you
start the reaction with reactants or products.
Ph 39. Among the following, the plot that shows the correct
marking 0' most probable velocity (Vmp), average
Ph velocity (V), and root mean square velocity (Vrms) is
v v,ms
Ill en en
Q) Q)
"S "S
2 () ()
Q)
o+- 0
Q)
H : (a) E (b) �
z z
Ho--t-H 15 15
ci ci
CH20H
IV V Veloc ity (m/s) Veloc ity ( m/s)
WWW.JEEBOOKS.INl
45. The first ionisation potential (IP) of the elements Na,

en
Q)
"S
v en
Q)
"S Mg, Si, P, Cl and Ar are 5.14, 7.65, 8.15, 10.49, 12.97
()
()
Q) and 15.76 eV, respectively. The IP (in eV) of K is
0
Q)
0
(c) 0
E (d) � closest to
z z
(a) 13.3 (b) 18.2 (c) 4.3 (d) 6.4
ci
BIOLOGY
ci
Velocity (m/s) Veloc ity (m/s)
40. The correct set of quantum numbers for the unpaired 46. Which one of the following chemicals serves as a
electron of Cu atom is substrate for carbonic anhydrase?
(a) n = 3, l = 2, m = -2, s = + 1 (a) 0 2 (b) CO 2 (c) NO 2 (d) CO
2
1 47. Which one of the following is not a function of the
(b) n = 3, l = 2, m = +2, s = - small intestine?
2
(a) Absorption of end products of digestion
(c) n = 4, l = 0, m = 0, s = + 1
2 (b) Digestion of proteins
(d) n = 4, l = 1, m = + 1, s = + � (c) Digestion of lipids
2 (d) Acidification of ingested food
41. Among the following, the most polar molecule is 48. Insulin stimulates the conversion of glucose to
(a) A1Cl3 (b) CC1 4 (c) SeC1 6 (d) AsC13 (a) fructose (b) glycogen
42. The covalent characters of CaCl 2, BaC1 2 , SrC1 2 and (c) sucrose (d) starch
MgC1 2 follow the order 49. Which one of the following statements about
(a) CaC1 2 < BaC1 2 < SrC1 2 < MgC1 2 ecosystem energetics is incorrect?
(b) BaC1 2 < SrC1 2 < CaC1 2 < MgC1 2 (a) The metabolic requirements of poikilotherms are
(c) CaC1 2 < BaC1 2 < MgC1 2 < SrC1 2 higher than that of homeotherms.
(d) SrC1 2 < MgC1 2 < CaC1 2 < BaC1 2 (b) Autotrophs form the base of the food chain in natural
ecosystems.
43. Among the following, the correct statement is (c) In terrestrial ecosystems, most of the primary
(a) 100. has four significant figures. production is consumed by detritivores and not
(b) 1 .00 x 10 2 has four significant figures. herbivores.
(c) 2.005 has four significant figures. (d) Approximately 10% energy of one trophic level is
(d) 0.0025 has four significant figures. transferred to the next level.
44. A thermodynamic cycle in the pressure (p) - volume 50. Proton motive force is created by pumping protons
(V) plane is given below across the
(a) trans-Golgi network
(b) endoplasmic reticulum
(c) mitochondrial inner membrane
(d) early endosomal membrane
p� 51. Which one of the following Mendelian diseases is an
AB and CD are isothermal processes while BC and

example ofX-linked recessive disorder?
(a) Haemophilia (b) Phenylketonuria
temperature (T) - entropy (S) plane is

DA are adiabatic processes. The same cycle in the (c) Sickle-cell anaemia (d) Beta thalassemia
52. Which one of the following pair gives rise to fruit and
seed, respectively, in a typical angiosperm plant?
(a) Ovule and ovary (b) Ovary and pollen
(c) Pollen and anther (d) Ovary and ovule
53. The concept of vaccination arose from Edward
Jenner's observation that
(a) injecting inactivated anthrax spores in sheep protected
them from anthrax
(b) injecting humans with tuberculosis-infected lung
extracts protected them from tuberculosis
(c) milk-maids previously infected with cowpox did not
contract smallpox
(d) injecting inactivated rabies virus in humans protected
them from rabies
WWW.JEEBOOKS.INl
54. A plant with genotype AABBCC is crossed with Column I Column II

another plant with aabbcc genotype. How many P. (i) Pseudocoelom
Mollusca
different genotypes of pollens is possible in an F 1
plant if these three loci follow independent Q. Annelida (ii) Radula
assortment? R. Nematoda (iii) Radial symmetry
(a) 8 s. Echinodermata (iv) Segmentation
(b) 4
(c) 2 Choose the correct combination.
(d) 1 (a) P-(ii), Q-(i), R-iv, S-(iii) (b) P-(ii), Q-(iv), R-i, S-(iii)
(c) P-(iii), Q-(iv), R-i, S-(ii) (d) P-(iv), Q-(iii), R-ii, S-(i)
55. Which one of the following sequences of events
correctly represents mitosis? 58. Who among the following scientists proposed the
(a) Metaphase, telophase, prophase, anaphase theory of natural selection independently of Charles
(b) Anaphase, prophase, metaphase, telophase Darwin?
(c) Prophase. anaphase, metaphase, telophase (a) Alfred Russel Wallace (b) Carl Linnaeus
(d) Prophase, metaphase, anaphase, telophase (c) Georges Cuvier (d) Jean-Baptiste Lamarck
56. The amount of air that is left behind in lungs after 59. The maximum concentration of harmful chemicals is
expiratory reserve volume has been exhaled is expected to be found in organisms
(a) inspiratory reserve volume (a) at the bottom of a food chain.
(b) tidal volume (b) at the middle of a food chain.
(c) residual volume (c) at the top of a food chain.
(d) vital capacity (d) at any level in a food chain.
57. Match the species in Column I with their respective 60. The genome of SARS-CoV-2 is composed of
feature of body organisation in Column II. (a) double-stranded DNA (b) double-stranded RNA
(c) single-stranded DNA (d) single-stranded RNA
� PART-II ( 2 Mark Questions)
MATHEMATICS a h 1s
61. Let A denote the set of all 4-digit natural numbers
. Then the rat10
- units. . - .
4 a
with no digit being 0. Let B c A consist of all
1 + -185 1 -185 1 + ./65 1
numbers x such that no permutation of the digits of x
(a) (b) + (c) (d) + ./65
4 8 4 8
gives a number that is divisible by 4. Then the 65. Consider the following two statements :
probability of drawing a number from B with all even I. If n is a composite number, then n divides
digits is (n - 1) !.
II. There are infinitely many natural numbers n
�
(a) 625 (d) 1000
such that n3 + 2n2 + n divides n!
(b) (c) �
62. Let ABC be a triangle such that AB = 4, BC = 5 and

1641 641 1641 1641
CA = 6. Choose points D, E, F on AB, BC, CA

(a) I and II are true (b) I and II are false
respectively, such that AD = 2, BE = 33, CF = 4. Then

(c) I is true and II is false (d) I is false and II is true
11 DEF PHYSICS
area MBC
-
area - - �-
66. A charge + q is situated at a

distance d away from both the
1
(b) 3
4
(a) 4 (c) - (d) .2_
15 15 30
L shaped sheet as shown in the

sides of a grounded conducting
63. The number of ordered pairs (x, y) of integers
satisfying i3 + y3 = 65 is figure.
wo �2 �4 00 6 The force acting on the charge
height h contains some water. When its base is

64. A bottle in the shape of a right-circular cone with + q is
2
(a) towards 0, magnitude q (2-/2 + 1)
the water level is a units. When it is kept upside
placed on a flat surface, the height of the vertex from 32 1te0 d 2
(b) away from 0, magnitude q2 (2-/2 + 1)
down, the height of the base from the water level is
32 1tE0 d 2
WWW.JEEBOOKS.INl
(c) towards 0, magnitude <l (W - 1) 69. A wide bottom cylindrical massless plastic container
321te0d 2 of height 9 cm has 40 identical coins inside it and is
floating on water with 3 cm inside the water. Ifwe
(d) away from 0, magnitude <l 2 (2--/2 - 1) start putting more ofsuch coins on its lid, it is
321te0 d
observed that after N coins are put, its equilibrium
67. Three balls, A, B and C are released and all reach the changes from stable to unstable. Equilibrium in
point X (shown in the figure). Balls A and B are floating is stable if the geometric centre of the
released from two identical structures, one kept on submerged portion is above the centre of the mass of
the ground and the other at height h, from the the object). The value of N is closed to
ground as shown in the figure. They take time tA and
tB respectively to reach X (time starts after they
leave the end of the horizontal portion of the
structure). The ball C is released from a point at
height h, vertically above X and reaches X in time tc .
Choose the correct option.
(a) 6 (b) 10
�
·ll
(c) 16 (d) 24
·c 70. A small coin is fixed at the centre ofthe base ofan empty
cylindrical steel container having radius R = 1 m and
height d = 4 m. At time t = 0, the container starts
getting filled with water at a flowrate of
Q = 0. 1 m3 /s without disturbing the coin. Find the
Ground
X
(a) tc < tA < tc (b) tc = tA = tc approximate time when the coin will first be seen by
(c) tc = tA < tc (d) tB < tA = tc the observer O from the height of H = 5.75 m above
and L = 1.5 m radially away from the coin as shown in
68. Four bulbs, red, green, white and blue (denoted by R, the figure. (Take, refractive index of water, n = 1.33)
G, W and B respectively) are kept in front of a
converging lens (as shown in the figure below). The
observer sees that the green and blue bulbs are kept
to the left ofthe principal axis, while the red and white
bulbs are kept to the right ofthe principal axis. He also L
sees that the red and green bulbs are above principal
11
axis, while the white and blue bulbs are below the
principal axis. The screens 81 and 82 are set � D
appropriate positions for the focusing to view the images.
G B
�-----
--�
R-�
)I
(a) Zero (b) 32 s

(c) 63 s (d) 150 s
Choose the figure that correctly represents the
CHEMISTRY
images as seen by the observer.
W G
0 0
o B OR 71. A hydrocarbon X with molecular formula C 4H 6
decolourises bromine water and forms a white
precipitate in ethanolic AgNO3 solution. Treatment
o o o
( a) R o (b ) B
w ofX with HgC1 2 in aqueous H 2 SO4 produces a
compound, which gives a yellow precipitate when
treated with 1 2 and NaOH. The structure ofX is
R B
o G
0 0
0 w ( a) � ( b) c�Me
H2C�
(d) G o o
R
0 o Me H
(c) w B (c)
#
(d) Et
#
Me
WWW.JEEBOOKS.INl
72. 0.102 g of an organic compound X was oxidised with (c) arthropod radiation was highest
fuming nitric acid. The resulting solution, after (d) arthropod radiation significantly influenced climate
reaction with excess of aqueous BaC1 2 , produce 0.233 and environment
g ofBaSO4 as a precipitate. Compound X is likely to 77. Match the vitamins listed in Column I with the
be [Given: Atomic wt. of Ba = 137] diseases caused due to their deficiency in Column II.
( a) s�
rs Column I Column II
0
P. Vitamin-A (i) Pellegra
(c) ( d) Q. Vitamin-B 2 (ii) Rickets
� SH
R. Vitamin-D (iii) Ariboflavinosis
73. The specific heat of a certain substance is 0.86 J g-1 s. Vitamin-B12 (iv) Night blindness
K-1 . Assuming ideal solution behaviour, the energy
required (in J) to heat 10 g of 1 molal of its aqueous (v) Pernicious anaemia
solution from 300 K to 310 K is closest to
Codes
[Given: Molar mass of the substance = 58 g mol-1; (a) P-(iv), Q-(ii), R-(iii), 8-(v)
specific heat of water = 4.2 J g-1 K-1] (b) P-(i), Q-(ii), R-(iv), S-(iii)
(a) 401.7 J (b) 424.7 J (c) 420.0 J (d) 86.0 J (c) P-(iv) , Q-(iii), R-(ii), 8-(v)
74. Strength of a H 20 2 solution is labelled as 1. 79 N. Its (d) P-(iii), Q-(iv), R-(v), 8-(i)
strength can also be expressed as closest to 78. An adult mammal with 50 kg body weight has the
(a) 20 volume (b) 5 volume (c) 10 volume (d) 15 volume following functional parameters of its lungs.
75. The isotherms of a gas are shown below: Inspiratory reserve volume = 40 mL/kg body weight
Expiratory reserve volume = 15 mL/kg body weight
Vital capacity = 60 mL/kg body weight
Breathing rate = 20/min
The volume (in litre) of air that its lungs displaces in
24 hours is
�
(a) 72,000 (b) 7,200
CJ)
CJ)
Cl.. (c) 3,600 (d) 1,200

(Critical temperature)
79. In a breed of dog, long-haired phenotype is recessive
to short-hair. In a litter one pup is short haired and
its sibling is long-haired. Consider the following
Volume possible phenotypes of the parents.
Among the following I. Both parents are short-haired.
(i) At ½, the gas cannot be liquefied. II. Both parents are long-haired.
(ii) At point B, liquid starts to appear at T2 • III. One parent is short-haired and one is
(iii) Tc is the highest temperature at which the gas long-haired.
can be liquefied. Choose the correct combination of the possible
(iv) At point A, a small increase in pressure parental phenotypes.
condenses the whole system to a liquid. (a) Only I (b) Only II
The correct statements are (c) Only III (d) I and III
(a) only (i) and (ii) (b) only (i), (iii) and (iv) 80. In medical diagnostics for a disease, sensitivity
(c) only (ii), (iii) and (iv) (d) (i), (ii), (iii) and (iv) (denoted by a) of a test refers to the probability that a
test result is positive for a person with the disease,
BIOLOGY
whereas specificity (denoted by b) refers to the
probability that a person without the disease tests
negative. A diagnostic test for COVID-19 has the
76. Anthropocene refers to the geological age during
values of a = 0.99 and b = 0.99. If the prevalence of
which
COVID-19 in a population is estimated to be 10%,
(a) the earliest hominids radiated from their ancestral what is the probability that a randomly chosen
forms
person tests positive for COVID-19?
(b) human activity significantly influenced climate and
environment (a) 0.099 (b) 0.10
(c) 0. 108 (d) 0. 1 1
WWW.JEEBOOKS.INl
Answers
PART-I
1 (c) 2 (a) 3 (c) 4 (d) 5 (d) 6 (d) 7 (a) 8 (b) 9 (d) 10 (b)
11 (a) 12 (a) 13 (b) 14 (b) 15 (b) 16 (d) 17 (a) 18 (a) 19 (d) 20 (b)
21 (b) 22 (c) 23 (b) 24 (d) 25 (d) 26 (b) 27 (b) 28 (a) 29 (c) 30 (c)
31 (c) 32 (a) 33 (d) 34 (b) 35 (b) 36 (b) 37 (c) 38 (d) 39 (d) 40 (c)
41 (d) 42 (b) 43 (c) 44 (a) 45 (c) 46 (b) 47 (d) 48 (b) 49 (a) 50 (c)
51 (a) 52 (d) 53 (c) 54 (a) 55 (d) 56 (c) 57 (b) 58 (a) 59 (c) 60 (d)
PART-II
61 (c) 62 (c) 63 (b) 64 (b) 65 (d) 66 (c) 67 (*) 68 (a) 69 (b) 70 (c)
71 (d) 72 (d) 73 (a) 74 (c) 75 (d) 76 (b) 77 (c) 78 (b) 79 (d) 80 (c)
Solutions
1 . (c) We have, [x2] = x + 1 . . . (i) From Eq. (i), ✓P (.J<i + -Jr ) E Q 5. (d) We know that, AM � HM
x2 - {x2} = x + 1
Clearly, Eq. (i) ⇒ x is an integer . . . (ii) rational x + y � _2_ _! _!
⇒ (x + y) ( + ) � 4
which is contradiction. y
⇒ x2 - x - 1 = {x2}
2 _l: + ..'._ X
(iii) Case II Let exactly two out of ✓P , .J<i , -Jr X y
[·: (x + y = 1)]
are irrational.
Eq.(iii) ⇒ x2 - x - 1 < 1 ⇒
✓P , .J<i � Q but -Jr E Q
6. (d) Since, LDAB, LABC and LBCD
⇒ -l< x < 2 . . . (iv)
✓fJ ✓<J + ✓r ✓fJ + ✓r✓<J + (✓r)2 E Q

From Eq. (i),
are in AP :. Let LDAB = 0 - a, LABC = 0

From Eqs. (ii) and (iv) ⇒ possible values
and LBCD = 0 + a
of x are O and 1.
⇒ (✓fJ + ✓r ) (✓<J + ✓r ) E Q
:. Equation [x2] = x + lhas no soltuion. :. Median of LDAB, LABC and LBCD = 0
But O and 1 do not satisfy Eq. (i).
·: Both ✓P + -Jr and .J<i + -Jr are irrational.
2. (a) Let JJi (x) = i3 - 2020x2 + qx + Ci From point E all the vertices are at equal
Hence, they must be conjugate of each
= (x - a) (x - �) (x - y)
other. Which is contradiction.
distance.
:.ABCD is cyclic.
Case III Let all ✓P , .J<i , -Jr are
P2 (X) = i3 - 202 lx + br + C2
Let ✓P + .J<i + -Jr = x, when x E Q+
2 irrational.
= (x - a) (x - �) (x - o)
and
D
Since, A (x) · CJi (x) + p2 (x) · qix) From Eq. (i), jp(x - jp) + .J<i -Jr E Q
= x2 - 3x + 2 ⇒ ✓fJ + ✓<J ✓r E Q
X
CJi (x) = - q2 (x) = q(x) (say)

On comparing the coefficient of i3 , we get Which is contradiction.
Hence, all ✓P , .J<i and -Jr must be
··-- - ----�
= (x - 1) (x - 2)
So, (x - a) (x - �) [q (x) (o - y)] rational.
4. (d)
and LADC = 2 1t - (0 - a + 0 + 0 + a)
A
:. a = 1, � = 2 , y = 2017 and o = 2018
B
A (x) = (x - 1) (x - 2) (x - 2017) = 2 1t - 30
⇒ A (3) = - 4028 and LADC + LABC = 1t
⇒ 2 1t - 30 + 0 = 1t
p2 (1) = 0
pix) = (x - 1) (x - 2) (x - 2018)
0= �
So, A (3) + p2 (1) + 4028 = 0
⇒
= 5xy
2
3. (c) ·: p, q, r E Q and ✓P + .J<i + -Jr E Q

7 • (a) ·: Z" + 3Y
LAOB = 2LACB When x = y = 1 , then 2 + 3 = 5

⇒ (✓fJ + ✓<J + ✓r)2 E Q
(�5 ) • _!_� + (�5 ) • _!_5 = lhere for any
(·: The angle subtended by an arc at the
x Y
⇒ .fiiq + .jqr + ✓7P E Q (i) and x
x, y E z LHS is not equal to 1 as both

centre is double the angle subtended by
Case I Let exactly one of ✓P , .J<i , -Jr is the arc in the remaining part of the circle). +
ln i'!.AOB,
irrational.
AB2 = 12 + 12 = 2
are less than �-
✓P , � Q but -Jr , .J<i E Q 2
AB = -J2 :. Only one ordered pair (1, 1) is possible.
WWW.JEEBOOKS.INl
8 . (b) Total number of digits used till 1 1 . (a) We have, (a - 1) - 0 = O ⇒la = 11

99 = 9 + 90 x 2 = 189 (202 1)2020 = (1 + 2020) 2020 10- e = a ⇒le = 91
The digits use in next 610 three digit =2020 Co + 2021 cl . 2020 + 2020 C2 . (2020) 2 + ... b - a = e ⇒lb = 01
numbers = 1830 = 1 + (2020)2 + (2020)2 X A, where A, E z+ (e - 1) - d = b ⇒ld = SI
d - c = c ⇒lc = 41
:. Total digit used till the number when divided by (2020) remainder will
abcde = 10989
be 1.
1 2. (a) Let AD = h and BD = x
710 = 189 + 1830 = 2019
Next three digits are 711
:. Sum of digits = 27
: . 2021st digit is 1.
9. (d) Given,
A 1 6. (d) Given, distance ofland from the
building, s = 12 m
Height of each floor, h = 3 m
Total height of building,
H = 15 x 3 = 45 m
14
The situation can be shown as,
B C
In MED, tan0 = �
h
. . . (i)
and in MDE, tan0 = -

14- x
h
. . . (ii)
LPDB = LBAC = A (let)
-
LBPC = A
14- x ⇒ x = 7
h h
From Eqs. (i) and (ii), � =
Let LBPD = x
LDPC = A - Now in ti.ADC, tan 20 =
28-
h
and in --- 1 2 m --
⇒
LPBD = 180° - - A MED, tan0 = �
Using second equation of motion for
LPDC = 180° - A h motion under gravity,
LPCD = tan 20 28 - x H = ut + I gt 2 = O + � gt 2
ti.PDE - ti.CPB (by AA similarity) tan0 x 2 2
PB BD PD ⇒ 2tan0 28- 7 ⇒ t=�

BC PB PC
- - - --
1 - tan 20 7
⇒ PB2 = BD - BC = � x - x
tan0 = ✓2 x 45 = 3 s
__2__ 10
⇒ =3
PB = R x
1 - tan 2 0 If v be the horizontal speed, then
s= v x t
⇒
⇒ 3 - 3tan 2 0 = 2
PD -J2Ptx � s
PC
= = ⇒ tan 2 0 = � or v=-
x V7 3
1 0. (b) -� 2 18 -- 2� 018� -
12 = 4 ms-1
l+ x2020 = x2 (l + x2018 ) + l- x2 ⇒ tan0 = ---1:_ ⇒ 0 = 30° =
-J3 3
l+ x 0 1+ x 18 "" 15 kmh-1
:. sin 30° = 7 /AB ⇒AB = 14
and sin 60° = 14/AC ⇒AC = 1 4-13
2 = 4x
1- x
= X2 + --- 5
l + x2018 :. AB + AC = 14(1 + -13) = 38. 248 1 7. (a) Let r1 and r2 be the radii of two
Put x = 2
r4 + <-3) 1
J=3 1 3. (b) Number of ways wires, then
l 1 + 22018 _Ii = � (given)
= 5!( 1 - � + _!_ - _!_ + _!_ - _!_ )
r2 1
Put x = 3 :. J-7 _ 8
1 _ 1! 2! 3! 4! 5!
8
9 F
A
l l + 32018 + 4! 3 (7i ( 1 - _!_ + _!_ - _!_ + _!_ ) We know that,stress = -
+ 3! 3 c2 ( 1 - � + _!_ - _!_ ) + 3 0a - 1
1! 2! 3! 4!
r 15 l = 15 As force applied is same, so
similarly for x = 4, 16 -
l 1 + 42018 J 1! 2! 3! (Stress)1 A2 rcr}
r
= =
24 1
J = 44 + 27 + 6 + 1 = 78 (Stress)2 A1 rcr/
1 4. (b) Here, m books will be considered
For x = 5 , 25 - = 24
l 1 + 52018 1
r one thing. So, total (n + 1) things to
For x = 6 , 36 -
l
35
1 + 62018 J1 = 35 arrange.
:. Required number of ways = (n + 1) ! m!
4
1 8. (a) Given, area, A = 30 x 30 cm2
:. Required sum 1 5. (b) abcde x 9 = abcde (10- 1) = abcde0 = 900 x 10-4 m2
= 3 + 8 + 15 + 24 + 35 = 85 -0abcde Depth, h = 100 m
0edcba Density of water, p = 1.03 x lo'3 kg/m3
WWW.JEEBOOKS.INl
25. (d) The value of acceleration due to

2
Acceleration due to gravity, g = 10 m/s (b) When white light passes through a
prism, the colourful pattern formed is due gravity at a height h is
= g (l-
As we know that,
pressure, p = - -
to dispersion of light.
Force (F)
-
Area (A) (d) Blue colour of the sky is due to
gh �)
F = p x A = pghA
scattering of light.
23. (b) As ranges are equal, so the angles
and at depth d is
=g
or
= 1.03 X Hf
= 9.27 X 10
4
X
""
10 X 100 X 900 X 10
9.3 X 104
-4
of projection of two balls must be
gd (1- �)
complementary.
= 0.93 X 10 5 N 01 + 02 = 90°
1 9. (d) Initially, relative speed of
i.e.,
Given, 01 = 30°
(u sE )i = u
spacecraft w.r.t. earth,
0 2 = 90° - 30° = 60°
R R
2
h d
⇒ - - -
Maximum height of projectile (ball),
(u pE )i = - 3u Hmax = - - -
Relative speed of planet w.r.t. earth, 2 2
u sin 0
⇒ d = 2h = 2 X 10 (·: h = 10 km)
2g
= 20 km
26. (b) Using lens formula,
:. Initially, relative speed of spacecraft 'f sin 2
_ � u --�01 �
H1 - 2g
(vsp )i = u - (-3u) = 4u
- -� -
w.r.t. planet, X
H2 2g u'f sin 2 02 1 1 1
2
sin (30° ) V U /
rnr�r-3_
Final relative speed of spacecraft w.r.t. =
sin 1 (60° )
(Vsp )/ = - (Vsp )i = - 4u
planet, ⇒ !±. - 1= !±.
V /
:. Finally, relative speed of spacecraft h _ 1 ⇒ m - 1= !±.

- f
= (vsp )/ + (u pE )i
becomes, H2
m
or _!_ = !±. + 1
= - 4u - 3u = - 7u
(vsE )/ (
f
I VsE I = 7 u
= 3h
line y = nx + c, where n is the slope of
or Comparing this with equation of straight
24. (d) The situation can be depicted as
H2
20. (b) As, 1° = (60 x 60) s

or
line, we get
It is given that in Hf year, flip is 180°. Slope of given graph � versus u ) = l
(
:. Average change in orientation per
Hf
180 1 250 - 200
year = - degree ⇒
/ 1- 0.8
Hf
180 50
= x 60 x 60 s = 6.48 s = = 250
0.2
It is closest to 5 s. 1
2 1 . (b) Let A1 be the area of region I and
or f = -- = 0.004 m
250
Vi 27. (b) Given, velocity of projection of

apple, v = 24 mis
be the velocity of blood in this region. mg
Similarly, A2 and v2 be the area and where, hb = height of bottle,
velocity in region IL C
h8 = height of shampoo
Using equation of continuity,
For critical angular displacement, mg

and R = radius of bottle.
A1 V1 = A2V2
As, A1 > A2, so v2 > Vi would pass through tilted side as shown V 45 m
Now, using Bernoulli's theorem, above.
p + � p v = constant
2
From the above figure,
2 A -<--'---------'H
tan 0 = B._
As, v2 > Vi hs 25 m
P2 < Pi h Distance between point of projection and
Also, fraction of shampoo, / = s
hoop is given by
AC = �
Hence, the pressure is lower in region II, hb
= fhb ✓-_ 2_
--- 2
when platelets enters a constriction.
22. (c) Among given patterns, the colour
⇒ h. (2 5) + (45) = .J2650 m
tan 0 = � So, time taken by the ball to the hoop,

observed on compact disc is due to
fhb .J2650
diffraction of light. t= s
1 24
The cause of rest of patterns are as or 0 = tan- (
(a) Rainbow occurs because of refraction, 1 :b ) The distance covered by hoop is
2
total internal reflection and dispersion of :. If / increases, then 0 will increase upto 2
S = � gt = � X ✓
10 X ( 265 0 )
light. 0.5 / and afterward it decreases. It is 2 2 24
correctly shown in graph (d).
WWW.JEEBOOKS.INl
= 5 X 2650 =
13250 Electrostatic repulsive force, 33. (d) A molecule which has 1° , 2° and
576 576
FE = K<Ji2q2 3° carbon atoms is methylcyclohexane.
:. Height above the ground where apple go r
H
through the hoop is 9 x 109 x (1.6 x 10-19 )2 110
=
H = 45 _ 13250 .2
, H-C-H
2° � 20
576
12670 "" 22 m Fa 6.7 x 10-11 x (9. l x 10-31 )2
=
2° U 20
= FE 9 X 109 X (16 X 10-19 )2
20
576
28. (a) For circuit (a), the equivalent = 24 X 10-44
resistance is 30. (c) The situation for given question So, number of 1 ° carbon atom = 1
300 + R
300 x R can be shown as, number of 2° carbon atoms = 5
Req = + (100 + 200)
number of 3° carbon atom = 1
300R + 300R + 90000 34. (b) Aniline compound can be purified
(300 + R) by steam distillation. This method is used
to separate the compounds which are
The current through the circuit,
steam volatile and are insoluble in water.
l= � In this method, steam from a steam
Req generator is passed through a heating
(300 + R) x 10 flask containing the liquid to be distilled.
(600R + 90000) The mixture of steam and the volatile
organic compound is condensed and
across R for circuit (a),
Using voltage division rule, voltage From symmetry, collected in a receiver.
(300+ R) x 10 x 300R
e = 0; ⇒ 20; = 90° 35. (b) The most acidic compound is
Va = or 0; = 45° cyclopent-1, 3-diene (option-b). More the
(600R + 90000) (300+ R)
Hence, the beam will come out only at stability of conjugate base formed by the
lOR 0; = 45° . hydrocarbon more will be acidic nature of
(2R + 300)
31 . (c) The correct acidity order is hydrocarbon.
III > IV > I > IL In substituted phenols,
Req = (200 + R) x 300 + lOO
For circuit (b), the equivalent resistance is 0-H - o + H�
the presence of electron withdrawing
(500 + R) groups such as nitro (-NO� group 6 1te8
(Aromatic species
500 + R
1 10000 + 400R enhances the acidic strength due to the (highly stable)
36. (b) 1 L of water gas has 1 : 1 CO and
effective delocalisation of negative charge
in phenoxide ion. IV is stronger than III
The current in circuit (b) is as (-NO� group at para position has H 2 gases. So, volume of hydrogen gas is
equal to the carbon monoxide gas.
I = � = (500 + R) x 10 more electron withdrawing effect due to
R0q (1 10000 + 400R) i.e. VH2 = Vco = 0.5 L
Again, voltage across R for circuit (b),
(-R) effect.
On the other hand, electron releasing So, volume of oxygen (V02 ) in the vessel
groups, such as - OMe group, do not 9 x 20
v;b = (500 + R) x 10 x 300R favour the formation of phenoxide ion
=
100
= 1. S L
(110000 + 400R) (500 + R)
resulting in decrease in acidic strength.
32. (a) Optical activity is shown by
30R Following reaction takes place on ignition
(1100 + 4R)
compounds that have an asymmetric 2CO(g) + 02 (g) ---t 2C0ig) at STP
According to question, carbon atom or the chiral carbon atom. It 0.5 L 1.8 L 0.5 L
must have non-superimposable mirror · O 5
Va = Vb :. Number of moles of CO 2 formed = --
lOR 30R image. It should not contain any element 224
of symmetry. So, compounds II, IV and V = 0.022 mol
37. (c) Given, Work function () = 2 eV
(2R + 300) (1100 + 4R)
exhibit optical activity whereas
1 100 + 4R = 6R + 900 compounds I and III does not.
tz/
⇒ R = lOOQ Wavelength 0"1 ) = 400 nm
29. (c) Given, gravitational constant
Ph COOH
Wavelength 0"2) = 800 nm
= 6.7 x 10-11 Nm-2 /kg 2 Planck constant (h)
Mass of an electron = 9.1 x 10-31 kg = 6.626 x 10-34 m 2kg s-1
Charge of an electron = 1.6 x 10-19 C Speed of light (c) = 3 x 108 ms-1
G HOOC Ph
Gravitational force, Fa = 7ni211½ II Energy associated with 1 W of 400 nm
he _ 6.626 x 10-34 x 3 x 108
r (Possess centre (Possess plane . ht IS
11g _-
. E- -- - - - -9 - - J
6.7 x 10-11 x (9. l x 10-3 1 )2 of symmetry) of symmetry) A-1 400 x 1 0-
=
r2 = 3.leV
WWW.JEEBOOKS.INl
Similarly, energy associated with 1 W of zero dipole moment. Structures as follows: interconversion between carbon dioxide
E = he
800 nm light is and the dissociated ions of carbonic
Cl Cl
CO 2 + H2O � H2CO3� HCO3 + Ir

I Cl c1 '-..... I .,..,,.....c1
Cl
acid. The active site of most carbonic
A-2 '-..... C/ anhydrases contain a zinc ion.
Al Se
6.626 X 10-34 X 3 X 108 Cl/ '-.....c1 Cl / '-.....c1 c1 / I '-..... c1
Substrate
800 X 1 ()- !I Cl
(µ =0) (µ =0) (µ =0) 47. (d) The small intestine is the part
= 1.5 eV of the inestine where 90% of the
The dipole moment of AsC13 is non-zero.
Since, work function () of the metal= 2 eV digestion of carbohydrates, proteins and
So, it is a polar molecule.
42. (b) The correct order of covalent
Therefore, only 400 nm light gives rise to lipids, etc. and the adsorption of food
ejection of photoelectrons. occurs. The other 10% take place in the
character is BaC1 2 < SrC1 2 < CaC1 2 stomach and large intestine. The main
38. (d) Statement (d) is correct whereas < MgC1 2• It can be explained by the function of the small intestine is
all other statements are incorrect. Fajan's rule. On moving down the group absorption of nutrients and minerals
Corrected statements are: size of ion increases. With increase in size from food. Acidification of digested food
(a) Equilibrium constant is temperature of cation, their polarising power decreases occurs in stomach due to the secretion
dependent having one unique value for a hence covalent character of chlorides also of HCl from parietal cells.
decreases.
48. (b) Insulin is a pancreatic hormone
43. (c) Statement (c) is correct whereas
particular reaction.
(b) It does not tells us how fast the that regulates blood glucose level by the
reaction reaches equilibrium. statement (a), (b) and (d) are incorrect. stimulating the conversion of glucose to
(c) At equilibrium, the rates of forward 2.005 has four significant figures. Zeros glycogen (this process is called
and reverse reactions are equal, dynamic between two non-zero digits are significant. glycogenesis).
and there is no net change in composition. Corrected statements 49. (a) Poikilotherms are also called
39. (d) Expression for most probable • 100. has three significant figures. 'ectotherms' cold blooded animals. Such
velocity (Vmp), average velocity (V) and 2 creatures are the thermoregulatory
• 1.00 x 10 has three significant figures.
root mean square velocity <Vrms ) is as opposite of 'endotherms' or
Vrms = PRT
• 0.0025 has two significant figures.
44. (a) Thermodynamic cycle in pV plane
follows : 'homeothermic'. Since thermoregulation
M
is energetically expensive, so
when plotted under T-S plane is shown as homeotherms have relatively higher
V = SRT
✓ follows: metabolic requirements than
rcM
Vmp = PRT
poikilotherms.
50. (c) The chemiosmotic hypothesis
tj
T
M
was proposed by Peter Mitchell. This
hypothesis stated that a proton motive
molecular speeds is Vrms >V > Vmp

So, the decreasing order of various D C force was responsible for driving the
s synthesis of ATP. In this hypothesis
Step 1 (A ➔ B) : Process involved is

Hence, the correct plot is (d). protons would be pumped across the
isothermal expansion, i.e. TA = TB .

inner mitochondrial membrane as
electrons went through the electron
en Here, volume increases and p decreases. transfer chain.
5 1 . (a) Haemophilia is an X-linked
(I)
Step 2 (B ➔ C) : Process involved is

=i So, entropy will increase.
(.)
(I) recessive disorder that is passed
0
0 Therefore, TB > Tc,

E adiabatic expansion, so cooling occur. through generation and can be traced
ci Step 3 ( C ➔ D) : Process involved is

z
by using a pedigree.
isothermal compression, i.e. Tc = Tn , Here,

Phenylketonuria, sickle-cell anaemia
and �-thalassemia are autosomal
1 volume decreases and p increases. So, recessive disorder.
Velocity (ms- )
40. (c) Electronic configuration of Step 4 (D ➔ A) : Process involved is

entropy will decrease. 52. (d) The seeds and fruits are the
results of fertilisation or sexual
Cu (29) is 1s2, 2s2, 2p 6, 3s2, 3p 6, 3d10, 481 .
and TA > Tn , For adiabatic process, t.S = 0
adiabatic compression, so heating occur reproduction in plants. The ovary in
Only one unpaired electron is present angiosperms develops into the fruit
in 4s1 . where as ovules become the seed.
53. (c) Edward Jenner observed that
means entropy remains same.
45. (c) On moving down in a group,
n = 4, l = 0, m = 0, s = + - .
So, the correct set of quantum number is
1 milk maids who had getten cowpox did
ionisation potential generally (IP)
2
4 1 . (d) The most polar molecule is AsC13
decreases. So, ionisation potential of K not show any symptoms of smallpox
should be less than that of Na. Hence, after variolation. This is a case of active
option (c) is correct. immunity in which infection of cowpox
46. (b) The carbonic anhydrases form a
whereas AlC13 , CC1 4 and SeC1 6 are
non-polar molecules since they possess virus (similar to smallpox virus) in
family of enzymes that catalyse the milkmaid stimulate the immunity
WWW.JEEBOOKS.INl
system of milk maids against smallpox concentration is found in top consumers 64. (b)
virus. that occupy top of a food chain.
54. (a) Independent assortment states 60. (d) Seveure acute respiratory
�R�
that the alleles of two (or more) different syndrome corona virus-2 (SARS-CoV-2)
genes get sorted into gametes has a positive sense single-stranded
independently of one another. genomic RNA as a genetic material.
Parents AABBCC aabbcc 61 . (c) For number not divisible by 4 and
I\ AaBbCc not having zero can be formed as
(Here n heterozygous locus = 3) Number of ways to form
Gametes = 2n = (2)3 = 8 All digits odd numbers = 54
Therefore, 8 different genotypes of pollen 3 digits odd numbers + 1 even numbers Volume of water in both the cases will be
i i
is possible in I\ plant, when these three (4 or8) = 53 . 2. 4 equal i.e.,
loci follow independent assortment. nr/( h - �) = 1 nR2h - nr 2a . . . (i)
55. (d) Mitosis is a process of cell
2 digits odd numbers + 2 even numbers
(4 or 8) = 0
duplication, in which one cell divides into 1 digits odd numbers + 3 even numbers r R . . . (ii)
a h
R(h - 1)
two genetically identical daughter cells. =0
The correct sequence of events of mitosis All even numbers = 24 (only 2 or 6 can be and r1 h = . . . (iii)
IS used)
Prophase � Metaphase � Anaphase 24 From Eqs. (i), (ii) and (iii), we get
� Telophase
56. (c) The residual volume (RV) is the
:. Required probability =
5 + 53 . 8 + 24
4
16
rn ( � r - 4 ( � ) - 2 1 = 0 ⇒ � = l + '[85
65. (d) Since, Statement I does not hold
amount of air that is left in the lungs
1641
62. (c)
even after maximum forceful expiration.
And this forceful expiration is the for n = 4
A
expiratory reserve volume. It is about ⇒ Statement I is false.
1000-l l00 mL. For Statement II,
57. (b) The radula is the anatomical n (n + 1)2 1 n !
structure used for feeding in most species ⇒ (n + 1) 2 1 (n - 1) !
of Mollusca. Let n = 3k - ], k > 3, k E N
Metameric segmentation is true n + 1 = 3k, n - 1 = 3k - 2
Here, a = BC = 5, b = CA = 6 and
B C
(n - 1)! = (3k - 2)!
segmentation in which external
c = AB = 4
= (3k - 2) x (3(k - 1)) x ...x (2k + 1) (2k)
segmentation corresponds to the internal
Area of /J.ADF = (2k - 1)...x (k + 1) k (k - 1) ... 3 x 2 x 1
segmentation and the body is divided into
a number of segments Animals belong to .! • 2- 2 sinA = 2 sinA
Since, RHS contains 32 , k2
2
Area of /J.BDF =
phylum-Annelida and Arthropoda
exhibit metameric segmentation. .! • 2- 3 sin B = 3 sin B Hence, it is divisible by (3k) 2•
2
And area of /J.CEF =
The pseudocoelom is a fluid filled body ⇒ (n - 1) ! is divisible by (n + 1) 2
cavity lying inside the external body wall .! • 2- 4 sin C = 4sin C
2
And area of /J.ABC = /J.
⇒ Statement II is true.
66. (c) The given diagram can be shown
of the nematode that baths the internal
Area of /J. DEF
organs, including the alimentary system
Area of /J.ABC
and reproductive system. by symmetry of four charges as,
Radial symmetry is the arrangement of
body parts around a central axis, animals /J. - (2sinA + 3 sin B + 4sin C)
have top and bottom surface but no left /J.
and right sides or front or back. It is u u + 4 . 2/J.
present in adult echinoderms. = 1 - I(2 - + 3.
58. (a) Alfred Russel Wallace who
)
/J. be ac ab
2(2a + 3b + 4c)
worked first in Amazon River basin and = 1_
then in Malay Archipelago had also come abc
.-- ------- o · · !
+q_ ___ __
2 (10 + 18 + 16) 16 __!
��
- -- ·------- - .___ id
to similar conclusions as that of Charles = 1- = =
5 . 6- 4 -
--
60 15
63. (b) x3 + y3 = 65
Darwin for natural selection in the year
1858 independently. This pushed him to
Let O be the centre and 2d be the
publish his book on the origin of species.
59. (c) Biomagnification also known as
Let x, y> 0
Clearly, (1, 4) and (4, 1) holds for x or distance between charges.
bioamplification or biological y � 6 difference of two cubes is always
magnification is any concentration of a Forces between -q and + q is
= F2 (attractive)
greater than or equal to 91. Hence, only 2
4d 2
Kq2
toxin in the tissue of tolerant organisms ordered pair possible. 1\ = --
along the food chain. The maximum
WWW.JEEBOOKS.INl
and force between + q and + q is 68. (a) As the images are formed on the 4x � - 1
R3 = Kl = Kl (repulsive) screen, so they are real and inverted (due
2
7
3
= 1.92 m
(Wd)2 8d2 to converging lens).
Since the blue and white bulbs are below 7 ,/203
So, net force acting on the charge is Volume of water filled = rcR2h
the principle axis, so their image should
Fnet = 1\2 - Fa = -J2 1\ - Fa be above and similarly as the green and = rt X 12 X 1.92
✓
(·: 1\2 = 1\ + F.; = ✓
2 2
'M\ ) red are above, so their image should be or Q t = 6.0288 (where, Q = flow rate)
below the principle axis. Also, the blue 6 0288 = 60.288 s , which i s close
F 2Kq2 Kq2 ⇒ t= ·
= and white bulbs are neares to lens, so
4d � 8d 2 0. 1
= q Lr\/ "' 2 towards 0

image will be far from lens compared to to 63 s.
2 (" '2 - I)
that of red and green bulbs. Hence,
option (a) is correct. 7 1 . (d) The hydrocarbon (X) is butyne
32m:0 d
(Et = H). It decolourises bromine water
67. (*) For ball A, the vertical velocity is 69. (b) Let m be the mass of each coin. and forms a white precipitate in ethanolic
zero, when it leaves the structure. So, The centre of mass on N coins kept on lid AgNO3 solution.
IS Br Br
CM =
40m x 0 + Nm x 9 = _!!!!__ cm Br2 water I I
(40 + N) m N + 40 Et = H -- Et- Q - Q -H
Butyne brown colour
I I
The geometric centre of submerged part (X) Br Br
after keeping N coins will be
Ethanolic 8 (j)
h 3(40 + N) Et = H CiJ,, -C = CAg
GC = cm AgNO3 White ppt.
(X)
40
For equilibrium, CM = GC Butyne (X) on treatment with HgC1 2 in
---- x ---.... ⇒ _!!!!__ = (40 + N) 3 aqueous H2SO4 produces butanone which
gives yellow ppt. of CHI3 on treatment
N + 40 40
tA = � . . . (i) with 1 2 and NaOH as follows
Ci\ -C-Cli.3
2
⇒ 3N - 480N + 4800 = 0 HgCl2 /H�04
This gives, N = 10.72, which is closed Et = H
0
Also, tA
�
l1
=
(X)
VA to 10.
where, vA = horizontal velocity of ball A. 70. (c) The situation can be shown as,
CHl3 -,1,I + Ci\ coo-
0·
I 2
�
From energy conservation, 0 NaOH Yellow
PE of A at height hi = KE of A 72. (d) Compound X is likely to be
⇒ ,,, = 1 mv2
mg," % of S in compound
- A
:r I
1 2
l
32 x mass of BaSO 4 formed x 100
=
r ···-····-····-·-1···-·· :� x··- l
⇒ VA = ,J2ghi H
233 x mass of organic compound
tA = _X_ . . . (ii) 32 X 0.233 X lO0 = 3 1.37%
)2gh l h : i: 1
l
233 X 0. 102
73. (a) Given, specific heat of a
For ball B, using energy conservation, 1
lf---R�
---- ----+1 substance = 0.86 Jg-1 K-1
Here, R = l m, L = 1.5 m, d = 4 m and As, 1000 g solution has 1 mole (or 58 g)
substance.
L-R
H = 5.75
,,, = -1 mv2 L So, 10 g solution will have 0.58 g
mg," 1 B
2 tan r = = 1.5 - 1 substance
H - d 5.75 - 4
= 0.5 = � = _ x_
⇒ VB = ,J2ghi and 10 g solution will have (1�.58) g
X X . . . (i) water = 9.42 g water.
tB = - = - - . . . (iii) 1.75 7 d - h
and tan i = R - x
VB ✓ 2ghl So, the energy required = heat required to
h
. . . (ii) raise the temperature of sample + heat
So, tA = tB [using Eqs. (ii) and (iii)]
required to raise the temperature of water.
For ball C, the time can be given for From Snell's law,
motion under gravity, = (0.58 X 0.86 X 10) + (9.42 X 4.2 X 10)
µ sin i = sin r = 400.628 J = 401.7 J
tc = � . . . (iv) . 3
⇒ tan i = -= 74. (c) Given,
v' 20:-!
Strength of a H 2O 2 = 1.79 N
From Eqs. (i) and (iv), we get Using Eqs. (i) and (ii)
x = (d - h) tan r = R - h tan i
Volume strength (H 2OJ = 1 1.2 x molarity
tc = tA = tB
d tan r - R . = -normality
For H 2O 2, molarity - - -
Note Correct option can be (b) for ⇒ h= 2
t A = t a = tc . tan r - tan i
WWW.JEEBOOKS.INl
So, volume strength (H20:J symptom of vitamin-A deficiency. (i) Parents Short hair x Short hair
= 5.6x normality = 5.6 x 1.79 Ariboflavinosis is caused by deficiency of Ll Ll
= 10.024 = 10 volume vitamin-B2 (riboflavin) and is
75. (d) All given statements are correct.
characterised by soreness of the mouth.)
In the graph, at Ti , the gas cannot be

Rickets is the softening and weakening of L 1
liquefied. In curve, T2, at point B liquid of
bones in children, usually because of an L�
extreme and prolonged vitamin-D
a particular volume appears. Further deficiency. Deficiency of vitamin-Bi2
compression does not change the 1�
causes pernicious anaemia. Pellagra is a
pressure. Liquid and gaseous state disease caused by a lack of the vitamin-Ba (ii) Parents Short hair x Long hair
coexist and further application of
l
(niacin). Ll 11
78. (b) Vital capacity is the maximum
pressure results in the condensation of
Tc is the highest temperature at which

more gas until the point A is reached.
amount of air a person can expel from the
lungs after a maximum inhalation L 1
the gas can be liquefied. Above critical
temperature (Tc ) gas cannot liquefy even Vital capacity (VC) - IRV + ERV + TV L � Short hair
applying high pressure. It can be shown TV = VC - (IRV + ERV)
as follows. ! � Long hair
= 60 mL/kg - (40 mL/kg + 15 mL/kg)
= 5 mL/kg So both (i) and (iii) are possible.
80. (c) Probablity of getting positive
TV of an adult mammal of 50 kg body
T
weight = 5 mL/kg x 50 kg
report = P (PR )
= 250 mL
p Probability of actual Covid-19 positive
TV/min = 250 mL x 20 = 500 mL = P(PA )
Volume of air that lungs displace in Probability of not actually Covid-19
24 hours (TV/day) positive = P(PA )
= TV/min x 60 x 24
= 5000 mL x 60 x 24 P(PR ) = P ( : ) · P(PA ) + P ( ; ) · P(PA )
: :
v- = 7,200,000 mL
99 10 1 90
76. (b) Anthropocene epoch is an
= 7200 L =( X )+ ( X )
79. (d) Since long-haired phenotype is
100 100 100 100
informal geologic time internal used to 990 + 90
recessive to short hair 10,000
describe the most recent period in earth's
history when human activity started to Genotype, Long haired dog = 11 108
Short haired dog = LL = + 0. 108
have a significant impact on the earth's 1000
climate and ecosystem. One pup is short haired that can be = LL
77. (c) Impaired dark adaptation of the
P(PR ) = 0. 108.
or Ll and its sibling is long haired = 11
eyes, can lead to night blindness. It is a
WWW.JEEBOOKS.INl
KVPY
OUESTION PAPER 20 1 9
Stream :SA
M M : 100
Instructions
MATHEMATICS Then, which of the following statements are true?

1. Let ABC be an equilateral triangle with side length I. g has exactly two distinct real roots.
a. Let R and r denote the radii of the circumcircle and II. g can have more than two distinct real roots.
the incircle of triangle ABC respectively. Then, as a III. There exists a real number a such that g(x) ;::>: a
function of a, the ratio !!_ for all real x.
(a) Only I (b) Both I and III
(a) strictly increases (b) strictly decreases (c) Only II (d) Both II and III
4. Let an , n ;::>: 1, be an arithmetic progression with first
(c) remains constant
(d) strictly increases for a < l and strictly decrease for a > 1
term 2 and common difference 4. Let Mn be the
10
average of the first n terms. Then the sum
2. Let b be an non-zero real number. Suppose the
quadratic equation 2x2 + bx + ..!_ = 0 has two distinct
I, M n is
b n=1
real roots. Then (a) 1 10 (b) 335
(a) b + -1 > -5 (b) b + -1 < -5 (c) 770 (d) 1100
b 2 b 2 5. In a triangle ABC, LBAC = 90°; AD is the altitude
(c) b2 - 3b > - 2 (d) b2 + ---1:_2 < 4 from A on to BC. Draw DE perpendicular to AC and
b
DF perpendicular to AB. Suppose AB = 15 and
3. Let p(x) = x2 + ax + b have two distinct real roots, BC = 25. Then the length ofEF is
where a, b are real number. Define g(x) = p(i3 ) for all (a) 12 (b) 10
real number x. (c) 5,/3 (d) 5J5
WWW.JEEBOOKS.INl
2 KVPY Question Paper 201 9 Stream : SA
6. The sides a, b, c of a triangle satisfy the relations (b) given any positive real number a, we can choose C and
is less than a
Area (C)
c2 = 2ab and a 2 + c2 = 3b2 • Then the measure of
LBAC, in degrees, is
T as above such that ratio
Area (T )
Area ( )
(a) 30 (b) 45
(c) give any C and T as above, the ratio C is
Area (T )
(c) 60 (d) 90
independent of C and T
7. Let N be the least positive integer such that (d) there exist real numbers a and b such that for any
whenever a non-zero digit c is written after the last
digit of N, the resulting number is divisible by c. The
circle C and triangle T as above, we must have
Area (C)
a<- - -< b
sum of the digits of N is Area (T )
(a) 9 (b) 18 15. The number of three digit numbers abc such that the
(c) 27 (d) 36 arithmetic mean of b and c and the square of their
8. Let 4, �, . . . , 4 1 be 11 distinct positive integers. Ifwe geometric mean are equal is
replace the largest ofthese integers by the median of (a) 9 (b) 18
the other 10 integers, then (c) 36 (d) 54
PHYSICS
(a) the median remains the same
(b) the mean increases
(c) the median decreases
16. Various optical processes are involved in the
9. The number of cubic polynomials P(x) satisfying
(d) the mean remains the same
formation of a rainbow. Which of the following
provides the correct order in time in which these
P(l) = 2, P(2) = 4, P(3) = 6, P(4) = 8 is processes occur?
(a) 0 (a) Refraction, total internal reflection, refraction.
(b) 1
(b) Total internal reflection, refraction, total internal
(c) more than one but finitely many reflection.
(d) infinitely many (c) Total internal reflection, refraction, refraction.
10. A two-digit number ab is called almost prime if one (d) Refraction, total internal reflection, total internal
obtains a two-digit prime number by changing at reflection.
most one of its digits a and b. (For example, 18 is an 17. A specially designed Vernier calliper has the main
almost prime number because 13 is a prime number). scale least count of 1 mm. On the Vernier scale, there
Then the number of almost prime two-digit numbers are 10 equal divisions and they match with 11 main
lS scale divisions. Then, the least count of the Vernier
(a) 56 (b) 75 (c) 87 (d) 90 calliper is
11. Let P be an interior point of a convex quadrilateral (a) 0.1 mm
ABCD and K, L, M, N be the mid-points of AB, BC,
(b) 0.909 mm
(c) 1.1 mm (d) 0.09 mm
CD, DA respectively. IfArea (PKAN) = 25, Area
(PLBK) = 36, and Area (PMDN) = 41 then Area
18. A steel ball is dropped in a viscous liquid. The
(PLCM) is
distance of the steel ball from the top of the liquid is
shown below. The terminal velocity of the ball is
(a) 20 (b) 29 (c) 52 (d) 54 closest to
12. The number of non-negative integer solutions of the
equations 6x + 4y + z = 200 and x + y + z = 100 is 0.4 I
/
55
(a) 3 (b) 5 (c) 7 (d) Infinite /
13. Let N1 = 2 + 1 and N2 = 165. 0. 3 /
I/
/
Then Q)
u ,I
(a) N1 and N2 are coprime ffi 0.2 /
(b) the HCF (Highest Common Factor) of N1 and N2 is 55 t5 /
(c) the HCF of N1 and N2 is 11

0.1
�
(d) the HCF of N1 and N2 is 33
14. Let l > 0 be a real number, C denote a circle with
circumference l and T denote a triangle with 0 ---
0 2
perimeter l. Then
0.5 1 .5
Time (s)
(a) given any positive real number a, we can choose C and
(a) 0.26 mis (b) 0.33 mis
T as above such that ratio Area (C) is greater than a (c) 0.45 mis (d) 0.21 mis
Area (T )
WWW.JEEBOOKS.INl
19. A student in a town in India, where the price per unit hemisphere at a height h from the horizontal surface,
(1 unit = 1 kWh) of electricity is � 5.00, purchases a then the speed of the particle is
1 kVA UPS (uninterrupted power supply) battery. A (a) ,J(2g(R - h))
day before the exam, 10 friends arrive to the (b) ,J(2g(R + h))
student's home with their laptops and all connect (c) .J2gR
their laptops to the UPS. Assume that each laptop
24. The nuclear radius is given by R = r0All3 , where r0 is
(d) .J2gh
has a constant power requirement of
90 W. Consider the following statements.
constant and A is the atomic mass number. Then, the
I. All the 10 laptops can be powered by the UPS, if
nuclear mass density of U238 is
connected directly.
(a) twice that ofSn119
II. All the 10 laptops can be powered, if connected (b) thrice that ofSn119
using an extension box with a 3 A fuse. (c) same as that ofSn119
III. If all the 10 friends use the laptop for 5 h, then (d) half that ofSn119
25. The electrostatic energy of a nucleus of charge Ze is
the cost of the consumed electricity is about
kZ 2e2
� 22.50.
Select the correct option with the true statements. equal to - -, where k is a constant and R is the
R
(a) I only (b) I and II only
e
daughter nuclei of charges Z and equal radii. The
nuclear radius. The nucleus divides into two
(c) I and III only (d) II and III only
20. Frosted glass is widely used for translucent windows. 2
The region, where a transparent adhesive tape is change in electrostatic energy in the process when
stuck over the frosted glass becomes transparent. they are far apart is
The most reasonable explanation for this is 0.375kZ 2e2 0.125kZ 2e2
R R
(a) (b)
(a) diffusion of adhesive glue into glass
(b) chemical reaction at adhesive tape-glass interface kZ2e2 0.5kZ 2 2
R R
e
(c) - - (d)
(c) refractive index of adhesive glue is close to that of glass
(d) adhesive tape is more transparent than glass 26. Two masses M1 and M2 carry positive charges Q1 and
21. Consider two equivalent, triangular hollow prisms A Q2 , respectively. They are dropped to the floor in a
and B made of thin glass plates and arranged with laboratory set up from the same height, where there
negligible spacing as shown in the figure. A beam of is a constant electric field vertically upwards. M1 hits
white light is incident on prism A from the left. Given the floor before M2 • Then,
that, the refractive index of water is inversely related
to temperature, the beam to the right of prism B
(a) Ql > Q2 (b) Ql < Q2
(c) M1 Q1 > M2Q2 (d) M1Q2 > MR1
would not appear white, if
27. Which one of the following schematic graphs best
represents the variation of p V (in Joules) versus T (in
Kelvin) of one mole of an ideal gas? (The dotted line
represents pV = T)
,,
(a) both prisms are filled with hot water (70°C) ,,,,
,
,,
(b) both prisms are filled with cold water (7° C) (a) pV (J) ,, (b) pV (J) ,,
,, ,
(c) both prisms are empty ,, ,,
, ,,
(d) prism A is filled with hot water (70°C) and prism B ,, ,,
,
with cold water (7° C) ,,
T ( K) T ( K)
22. A ball is moving uniformly in a circular path of
radius 1 m with a time period of 1.5 s. If the ball is
suddenly stopped at t = 8.3 s, the magnitude of the
displacement of the ball with respect to its position at
t = 0 s is closest to
,
,,
,,
(b) 33 m
,
(a) 1 m (c) pV (J) (d) pV (J) ,,
(c) 3 m (d) 2 m ,,
, ,,
23. A particle slides from the top of a smooth , ,,
,,
hemispherical surface of radius R which is fixed on a T ( K) T ( K)
horizontal surface. If it separates from the
WWW.JEEBOOKS.INl
28. Mumbai needs 1.4 x 1012 L of water annually. Its 34. IUPAC name of the following compound
effective surface area is 600 km and it receives an 2 0
average rainfall of 2.4 m annually. If 10% of this rain
water is conserved, it will meet approximately
(a) 1% of Mumbai's water needs HOD
(b) 10% of Mumbai's water needs lS
(c) 50% of Mumbai's water needs (a) 1-hydroxycyclohex-4-en-3-one
(d) 100% of Mumbai's water needs (b) 1-hydroxycyclohex-3-en-5-one
elastically with another stationary mass m. After the

29. A mass M moving with a certain speed V collides (c) 3-hydroxycyclohex-5-en-1-one
collision, the masses M and m move with speeds V'

(d) 5-hydroxycyclohex-2-en-1-one
35. In water-gas shift reaction, hydrogen gas is produced
and v, respectively. All motion is in one dimension. from the reaction of steam with
Then,
(a) methane (b) coke
(a) V = V' + v (b) V' = V + v (c) carbon monoxide (d) carbon dioxide
(c) V' = (V + v) (d) v = V + V' 36. Treatment with lime can remove hardness of water
2
caused by
face PQ of an isosceles prism PQR with apex angle
30. Four ray 1, 2, 3 and 4 are incident normally on the
(a) CaC12 (b) CaSO4
LQ = 120 °. The refractive indices of the material of (c) Ca(HCO3 )2 (d) CaCO3
the prism for the above rays 1, 2, 3 and 4 are 1.85, 37. The most polarisable ion among the following is
1 .95, 2.05 and 2.15 respectively and the surrounding (a) F" (b) r (c) Na+ (d) Cr
QR are
medium is air. Then, the rays emerging from the face 38. For a multi-electron atom, the highest energy level
among the following is
(a) 4 only (b) 1 and 2 only (a) n = 5, l = 0, m = 0, s = + 1
(c) 3 and 4 only (d) 1, 2, 3 and 4 2
CHEMISTRY
1
(b) n = 4, l = 2, m = 0, s = + -
2
1
(c) n = 4, l = ], m = 0, s = + -
2
31. The hybridisations of N, C and O shown in the 1
following compound (d) n = 5, l = ], m = 0, s = + -
2
"--N =C=O 39. The oxide, which is neither acidic nor basic is
(a) As2O3 (b) Sb4 O10 (c) N2O (d) Na 2O
respectively, are
40. The element whose salts cannot be detected by
(a) sp2, sp, sp2 (b) sp 2, sp 2, sp 2 flame test is
2
(c) sp , sp, sp (d) sp, sp, sp2
41. The plot of concentration of a reactant vs time for a
(a) Mg (b) Na (c) Cu (d) Sr
32. The following compounds
� � chemical reaction is shown below.
cQ)
are C
(a) geometrical isomers (b) positional isomers 0
(c) optical isomers (d) functional group isomers

33. The major product of the following reaction (.)
C
0
Br 0
I Br 1. Excess ale. KOH
2. NaNH2 0 Time
Ph /'--._/
+ The order of this reaction with respect to the reactant
3. H30
lS lS
H (a) 0 (b) 1 (c) 2

H (d) not possible to determine from this plot
�
(a) Ph H ( b)
Ph 42. During the free expansion of an ideal gas in an
Br isolated chamber,
Br Br (a) internal energy remains constant
H H (b) internal energy decreases
(c) P h � (d) Ph � (c) work done on the system is negative
Br H
(d) temperature increases
WWW.JEEBOOKS.INl
43. The number of moles of water present in a spherical 5 1 . The mode of speciation mediated by geographical
water droplet of radius 1.0 cm is, isolation is referred as
[Given : Density of water in the droplet = 1.0 g cm -3 ] (a) adaptive radiation
(b) allopatric speciation
(a) 1t (b) 21t (c) parapatric speciation
18 27
(d) sympatric speciation
(c) 241t (d) 21t
9 52. Which one of the following metabolic conversion
44. Among the following, the correct statement about requires oxygen?
cathode ray discharge tube is (a) Glucose to pyruvate
(a) the electrical discharge can only be observed at high (b) Glucose to CO 2 and ethanol
pressure and at low voltage. (c) Glucose to lactate
(b) in the absence of external electrical or magnetic field, (d) Glucose to CO 2 and Hz O
cathode rays travel in straight lines. 53. Where are the proximal and distal convoluted
(c) the characteristics of cathode rays depend upon the tubules located within the human body?
material of electrodes. (a) Adrenal cortex
(d) the characteristics of cathode rays depend upon the (b) Adrenal medulla
gas present in the cathode ray tube.
(c) Renal cortex
45. For a spontaneous process, (d) Renal medulla
(a) enthalpy change of the system must be negative 54. In a diploid organism, when the locus X is
(b) entropy change of the system must be positive inactivated, transcription of the locus Y is triggered.
(c) entropy change of the surrounding must be positive Based on this observation, which one of the following
(d) entropy change of the system plus surrounding must statements is CORRECT?
be positive
(a) X is dominant over Y
BIOLOGY
(b) X is epistatic to Y
(c) Y is dominant over X
(d) Y is epistatic to X
46. Which one of the following is a CORRECT statement
about primates' evolution? 55. Which one of the following sequences represents the
CORRECT taxonomical hierarchy?
(a) Chimpanzees and gorillas evolved from macaques
(a) Species, genus, family, order
(b) Humans and chimpanzees evolved from gorillas
(b) Order, genus, family, species
(c) Human, chimpanzees and gorillas evolve from a
common ancestor (c) Species, order, genus, family
(d) Humans and gorillas evolved from chimpanzees (d) Species, genus, order, family
47. The crypts of Lieberkuhn are found in which one of 56. Which one of the following organs is NOT a site for
the following parts of the human digestive tract? the production of white blood cells?
(a) Oesophagus (a) Bone marrow (b) Kidney
(b) Small intestine (c) Liver (d) Spleen
(c) Stomach 57. Which one of the following anatomical structures is
(d) Rectum involved in guttation?
48. Removal of the pancreas impairs the breakdown of (a) Cuticle (b) Hydathodes
(a) lipids and carbohydrates only (c) Lenticels (d) Stomata
(b) lipids and proteins only 58. Which one of the following parts of the eye is affected
(c) lipids, proteins and carbohydrates in cataract?
(d) proteins and carbohydrates only (a) Cornea (b) Conjunctiva
49. Microscopic examination of a blood smear reveals an (c) Retina (d) Lens
abnormal increase in the number of granular cells 59. Which one of the following organisms is a bryophyte?
with multiple nuclear lobes. Which one of the (a) Liverwort (b) Volvox
following cell types has increased in number? (c) Chlamydomonas (d) Fern
(a) Lymphocytes (b) Monocytes
60. During oogenesis in mammals, the second meiotic
(c) Neutrophils (d) Thrombocytes
division occurs
50. Which one of the following genetic phenomena is (a) before fertilisation
represented by the blood group AB? (b) after implantation
(a) Codominance (b) Dominance (c) before ovulation
(c) Overdominance (d) Semidominance (d) after fertilisation
WWW.JEEBOOKS.INl
� PART- I I (2 Marks Questions)
MATHEMATICS 67. In an hour-glass approximately 100 grains of sand

fall per second (starting from rest); and it takes 2 s
61. Let a, b, c, d be distinct real numbers such that a, b for each sand particle to reach the bottom of the
are roots of :x? - 5cx - 6d = 0, and c, d are roots of hour-glass. If the average mass of each sand particle
:c - 5ax - 6b = 0. Then b + d is is 0.2 g, then the average force exerted by the falling
W lW � 1� � 1« sand on the bottom of the hour-glass is close to
00 1 W
(a) 0.4 N (b) 0.8 N
62. Let S = {1, 2, 3, . . . , 100}. Suppose b and c are chosen at (c) 1.2 N (d) 1.6 N
random from the set S. The probability that
4:x? + bx + c has equal roots is 68. A student uses the resistance of a known resistor
(1 Q) to calibrate a voltmeter and an ammeter using
(a) 0.001 (b) 0.004 (c) 0.007 (d) o. o i
63. Let N be the set of positive integers. For all n E N, let
the circuits shown below. The student measures the
ratio of the voltage to current to be 1 x la3 Q in
3
fn = (n + 1)1/3 l/
and circuit (a) and 0.999 Q in circuit (b). From these
measurements, the resistance (in Q) of the voltmeter
-n
A= {n E N : fn + 1 <
l
3(n + 1) 3
'l/ < fn } and ammeter are found to be close to
Then,
(a) A = N 1 =Q 1 =Q
(b) A is a finite set
(c) the complement of A in N is nonempty, but finite
(d) A and its complement in N are both infinite (a) (b)
64. A prime number p is called special if there exist (a) 10 and 10-
2 2
(b) l d3 and 10-3
primes Pi, p2 , Po , p4 such that p = Pi + p2 = p3 - p4 • (c) 10-2 and 102 (d) 10-2 and l d3
The number of special primes is 69. A hot air balloon with a payload rises in the air.
(a) 0 Assume that the balloon is spherical in shape with
(b) 1 diameter of 1 1 . 7 m and the mass of the balloon and
(c) more than one but finite the payload (without the hot air inside) is 2 10 kg.
(d) infinite Temperature and pressure of outside air are 27 °C
65. Let ABC be a triangle in which AB = BC. Let X be a and 1 atm = 105 N/m 2 , respectively. Molar mass of
point on AB such that AX : XB = AB : AX. If dry air is 30 g. The temperature of the hot air inside
AC = AX, then the measure of LABC equals is close to [The gas constant, R = 8.31JK- 1mol-1]
(a) 18° (b) 36° (c) 54° (d) 72° (a) 27 ° C (b) 52 °C
(c) 105 C° (d) 171 °C
PHYSICS 70. A healthy adult of height 1 . 7 m has an average blood
pressure (BP) of 100 mm of Hg. The heart is typically
66. A water-proof laser pointer of length 10 cm placed in at a height of 1 .3 m from the foot. Take, the density
a water tank rotates about a horizontal axis passing of blood to be la3 kg/m3 and note that 100 mm of Hg
through its centre of mass in a vertical plane as is equivalent to 13.3 kPa (kilo pascals). The ratio of
shown in the figure. The time period of rotation is BP in the foot region to that in the head region is
60 s. Assuming the water to be still and no reflections close to
1-- =�-r:��-
from the surface of the tank, the duration for which (a) one (b) two
the light beam escapes the tank in one time period is (c) three (d) four
close to (Take, refractive index of water = 1.33)
CHEMISTRY
4�m 71. PbO2 is obtained from
(a) the reaction of PbO with HCl
(b) thermal decomposition of Pb(NO3 ) 2 at 200° C
(a) 8. 13 s (b) 14.05 s (c) the reaction ofPh_i O4 with HNO3
(d) the reaction of Pb with air at room temperature
(c) 16.67 s (d) 23.86 s
WWW.JEEBOOKS.INl
KVPY Question Paper 201 9 Stream : SA 7
72. For one mole of a van der Waals' gas, the 77. Papaya is a dioecious species with XY sexual
compressibility factor Z = ( ��) at a fixed volume genotype for male and XX for female. What will be
the genotype of the embryos and endosperm nuclei
will certainly decrease, if after double fertilisation?
(a) 50% ovules would have XXX endosperm and YY
[Given : "a" and "b" are standard parameters for embryo, while the other 50% would have XXY
van der Waals' gas] endosperm and XX embryo
(a) "lJ' increases and "d' decreases at constant (b) 100% ovules would have XXX endosperm and XY
temperature embryo
(b) "b" decreases and "a" increases at constant (c) 100% ovules would have XXY endosperm and XX
temperature embryo
(c) temperature increases at constant "a" and "b" values (d) 50% ovules would have XXX endosperm and XX
(d) "b" increases at constant "a" and temperature embryo, while the other 50% would have XXY
73. The correct statements among the following. endosperm and XY embryo
i. E28 (H) > E28 (Li) < E28 (Na) > E28 (K) . 78. Solid and dotted lines represent the activities of
pepsin and salivary amylase enzymes of the digestive
with principal quantum number n is equal to
ii. The maximum number of electrons in the shell
best represents their activity us pH?
v\
tract, respectively. Which one of the following graphs
2n2 •
I\
iii. Extra stability of half-filled subshell is due to z,
,, '' :2:z,
.;i_
smaller exchange energy. 3 '' ,
iv. Only two electrons, irrespective of their spin,
(a)
,,
,/ \'
''
( b)
1i '' ,,,
'' ,,
rr
may exist in the same orbital are. "
(a) i and ii (b) ii and iii 5 10 5 10
pH pH
(c) iii and iv (d) i and iv
X. When 2.00 g of this compound is heated with

74. An organic compound contains 46. 78% of a halogen z,
(c) 3u (d) 0 :� :
_,
:
fuming HN03 in the presence of AgN03 , 2.21 g AgX
<{ <{ I
was formed. The halogen X is C IT

5 10 5 10
[Given : atomic weight of Ag = 108, F = 19, Cl = 35.5, pH pH
Br = 80, I = 12 7]
(a) F (b) Cl (c) Br (d) I 79. If the gene pool of the locus X in the human genome
C 6Hio , when treated with HBr, forms a gem

75. An organic compound X with molecular formula is 4, then what would be the highest possible number
of genotypes in a large population?
dibromide. The compound X upon warming with (a) 6 (b) 8
HgS04 and dil. H�04, produces a ketone, which (c) 10 (d) 16
gives a positive iodoform test. The compound X is 80. Match the plant hormones in Column I with their
primary function in Column II.
(a) /' (b ) �
Column I Column II
(d)
P. Abscisic acid i. Promotes disease
resistance
BIOLOGY
Q. Ethylene ii. Maintains seed dormancy
R. Cytokinin iii. Promotes seed germination
76. A cell weighing 1 mg grows to double its initial mass s. Gibberellin iv. Promotes fruit ripening
before dividing into two daughter cells of equal mass. v. Inhibits leaf senescence
Assuming no death, at the end of 100 divisions what
will be the ratio of the mass of the entire population Choose the correct combination
of these cells to that of the mass of the earth? Assume (a) P-iii, Q-iv, R-i, S-ii
that mass of the earth is 1024 kg and 210 is (b) P-ii, Q-iv, R-v, S-iii
approximately equal to 1000. (c) P-v, Q-iii, R-ii, S-i
w 1�s � 1� (d) P-iv, Q-ii, R-iii, S-v
(c) 1 (d) l(r
WWW.JEEBOOKS.INl
Answers
PART-/
(c) 2 (c) 3 (b) 4 (a) 5 (a) 6 (b) 7 (a) 8 (c) 9 (a) 10 (d)
11 (c) 12 (c) 13 (d) 14 (a) 15 (b) 16 (a) 17 (a) 18 (b) 19 (c) 20 (c)
21 (d) 22 (d) 23 (a) 24 (c) 25 (a) 26 (d) 27 (a) 28 (b) 29 (d) 30 (c)
31 (a) 32 (d) 33 (a) 34 (d) 35 (d) 36 (c) 37 (b) 38 (b,d) 39 (c) 40 (a)
41 (a) 42 (a) 43 (b) 44 (b) 45 (d) 46 (c) 47 (b) 48 (c) 49 (c) 50 (a)
51 (b) 52 (d) 53 (c) 54 (d) 55 (a) 56 (b) 57 (b) 58 (d) 59 (a) 60 (d)
PART-I/
61 (c) 62 (a) 63 (a) 64 (b) 65 (b) 66 (c) 67 (a) 68 (b) 69 (c) 70 (c)
71 (c) 72 (b) 73 (a) 74 (c) 75 (d) 76 (c) 77 (d) 78 (a) 79 (c) 80 (b)
Solutions
1 . (c) For an equilateral triangle ABC ⇒ b2 - � > 0 ⇒
bs - 8
>0 4. (a) The sum of first n ,n � 1 terms of
having side length a. If R and r are radii b b arithmetic progression with first term 2
of the circumcircle and the incircle of (b - 2)(b2 + 2b + 4) and common difference 4, is
triangle ABC respectively, then ⇒ >0
b Sn = !1'. [4 + (n - 1)4] = 2n 2
R = i sec30 = � (�) = �
°
⇒ b E (-oo, 0) U (2, oo) . . . (i) 2
For option (c), So, the average of the first n terms
A 2
b - 3b > - 2
s
Mn = _11,_ = 2n
2 n
⇒ b - 3b + 2 > 0
�:,n
10 10
⇒ (b - 2)(b - 1) > 0 Now, I, Mn = 2
(1° ; 1 1) = 1 10
n=l n=l
b E (-oo, 1) U (2, oo)
mean if b E (-oo, 0) u (2, oo) = 2x
then b2 - 3b > - 2
3. (b) Let the given quadratic polynomial 5. (a) It is given that in triangle ABC,
p(x) = x2 + ax + b has two distinct real LBAC = 90°, AD is the altitude from A on
roots a and �, then to BC.
p(x) = x2 + ax + b = (x - a)(x - �)
and since g(x) = p(:x!' ) = (:x!' - a)(:x!' - �)
and r = � tan 30° = � x ---1:_ = ___!1,___
let a = a� and � = ��
:. "!!:_ = �-'3 = 2, which is independent of a

2 2 ,,/3 2,,/3
a then g(x) = (:x!' - a� )(:x!' - �f )
= (x - a1 )(x - �1 )(x2 + <X1X + af)
r a (X2 + �1X + �i)
2,,/3
·: the discriminants of quadratic
and it is constant. Since, AB = 15 and BC = 25
2. (c) Given quadratic equation
equations
x2 + a1x + af and x2 + �1x + �i are AC = ,JBC2 - AB2 = -J625 - 225
2x2 + bx + � = 0, has two distinct real negative.
b = v"400 = 20
:. g(x) has exactly two distinct real roots
roots, so
D>O
and since g(x) = x6 + ax!' + b is an even Now, since area of MBC = _! (BC)(AD)
2
degree polynomial, so there exists a real
⇒ b2 - 4(2)G) > 0 number 'a' such that g(x) � a for all real x. = _! (AB)(AC)
2
WWW.JEEBOOKS.INl
⇒ � (BC)(AD) = � x 15 x 20 Now, 1 2. (c) Given equations

2 2 P(l) = a + b + c + d = 2 6x + 4y + z = 200,
25 x AD = 300
. . .(i) . . . (i)
⇒ P(2) = Sa + 4b + 2c + d = 4
AD = 12
. . . (ii) and x + y + z = 100 . . . (ii)
⇒ P(3) = 27a + 9b + 3c + d = 6 . . . (iii)
P(4) = 64a + 16b + 4c + d = 8 . . . (iv)
By Eqs. (i) and (ii), we get
5x + 3y = 100
EF = AD = 12
·: AEDF is a rectangle, then
From Eqs. (i) and (ii), we get
7a + 3b + c = 2
For non-negative integer solutions, when
triangle, a, b and c satisfy the following
6. (b) It is given that the sides of . . . (v) x = 2, then y = 30
From Eqs. (ii) and (iii), we get x = 5, then y = 25
c2 = 2ab 19a + 5b + c = 2
relations
. . . (i) . . . (vi) x = 8, then y = 20
From Eqs. (iii) and (iv), we get
37a + 7b + c = 2
and a + c2 = 3b2
2
. . . (ii) x = 1 1, then y = 15
From Eqs. (i) and (ii), we get . . . (vii) x = 14, then y = 10
12a + 2b = 0
A
Now, from Eqs. (v) and (vi), we get x = 1 7, then y = 5
. . . (viii) and x = 20, then y = 0
18a + 2b = 0
and from Eqs. (vi) and (vii), we get In every case z = 100 - (x + y) > 0
. . . (ix)
So, total number of non-negative integral
a = 0 and b = 0,
From Eqs. (viii) and (ix), we get solutions are 7.
c = 2 and d = 0.
1 3. (d) It is given that, N2 = 165
So, P(x) = 2x = 3 x 5 x 11 and N1 = 2!55 + 1
As we know that, if n is odd integer then
a2 + 2ab = 3b2
:. no cubic polynomial is possible.
a + 2ab + b2 = 4b2
xn + yn is divisible by x + y.
⇒ 2 1 0. (d) Since in the group of first 10 two
digit number 10-19, has atleast 1 prime So, N1 = 2!55 + 155 is divisible by 2 + 1 = 3
⇒ (a + b) 2 = (2b)2 = (b + b)2 and N1 = 2!55 + 155
a = b, so c = -.f2a
number similarly in other groups of 10
⇒ = (2!5 )11 + (15 )11 = (32)11 + (1)11
LA = LB = 45°
two digits numbers
20-29, 30-39, 40-49, 50-59, 60-69, 70-79, is divisible by 32 + 1 = 33
7. (a) As N be the least positive integer 80-89 and 90-99 have almost 1 prime :. the HCF of N1 and N2 is 33.
and when a non-zero digit C is written numbers. 1 4. (a) It is given that circumference of
after the last digit of N, the resulting So, the number of almost prime two-digit circle C is l and the perimeter of triangle
number is divisible by C. number is 90.
1 1 . (c) Let a convex quadrilateral ABCD
T is l.
So, lON + C is divisible by C Now, let the radius of circle C is r, so
and K, L, M, N be the mid-point of AB,
BC, CD, DA respectively.
:. lON must be divisible by C.
21tr = l ⇒ r = J_
Now, the least integer (N) which is 21t
divisible by digit 'C i.e. (1 to 9) must be · 1e c 1s
· A1 = 1tr 2 = -
2
z
:. area of circ
L.C.M of {l, 3, 4, 6, 7, 9}. 41t
= L.C.M of {4, 7, 9} Now, as we know that area of triangle
= 252 = N will be maximum for given perimeter if it
and sum of digits of number 'N' is is an equilateral triangle, let the length
of side of equilateral triangle is 'd, then
3a = l ⇒ a = -l
2+ 5+ 2= 9
8. (c) Let the given 11 distinct positive
integers are in increasing order M
C D and area of equilateral triangle is
Xi , Xi , 43 , X4 , Xi; , x6 , Xi , Xs , Xii , Xio , Xi i , so Xi i
is largest of these integers and the Now, as area MKP = area f..BKP = x (let) A2 = ../8 a2
(t_ )
Similarly 4
ti.BLP = ti.CLP = y
median is x6 •
Now, median of first 10 numbers is So, A2 = ../ 3 = __!__
x6 + x6 ti.CPM = ti.DPM = z 4 9 12../3
and ti.DNP = ti.ANP = w
= m (Let).
2
It is given that Area (PKAN) = x + w = 25
2
z
A2 - -z- 2- - -;--
Now, we have to replace largest number Al - 41t - 3../3
area (PLBK) = x + y = 36
>1
Xi i by m and then increasing order will be
Xi , Xi , 43 , X4 , Xi; , m, x6 , Xi , Xs , Xg , Xio and area (PMDN) = z + w = 41 12 8
So area (PLCM) = y + z
+ x6 ../
m < x6 as Xi; < Xi; < x6 Since, as we took an equilateral triangle,
2
take a triangle T such that the ratio
= (x + y) + (z + w) - (x + w) which has maximum area. But we can
= area (PLBK) + area (PMDN) -
So, median decreases.
9. (a) Let the equation of a cubic
area (PKAN)
area (C) is greater than any positive real
polynomial area (T)
P(x) = ai3 + bx2 + ex + d = 36 + 4 1 - 25= 77 - 25= 52
number a.
WWW.JEEBOOKS.INl
1 5. (b) I t i s given that, the number of O (m)

three digit number abc, such that
b+ c
= be . . . (i)
2
the above relation is true if b = c = 0 X1 = 0.3 --------------------
And if neither b nor c is zero, then
- + - = 2, and b, c E {l, 2, 3, 4, 5, 6, 7, 8, 9}
1 1 If bending of light caused by B is less
b C than or more than that of A, then out
'--=-------+-_._-----+ (s) going beam of light is not white.
and a E {l, 2, 3, 4, 5, 6, 7, 8, 9}
Then b = c = 1 1 .6 .9
t1 t2 So, when both prisms are filled with
water at different temperatures, their
So, total number of such three digit From data of graph,
refractive indices are different and the
number are 2 x 9 = 18 Terminal velocity,
dispersion produced by A and B are not
1 6. (a) Formation of rainbow is shown � - Xi_ 0.4 - 0.3
in (d) beam to right of prism B will be
V= = equal and opposite. Hence, with condition
below. t2 - ti. 1.9 - 1.6
O.l 0.33 m/s coloured.
22. (d) Time period of rotation of ball
White light = =
1 9. (c) Power requirement for 1 laptop,

0.3
= 1.5 s
Total
Pi_ = 90W So, in time interval of 7.5 s (= 1.5 x 5) s
1..---+--::r-7 internal
reflection So, power requirement for 10 laptops, ball completes 5 revolutions.
P = lO X Fl_ = 10 x 90 Also, ball covers one-fourth of circular
= 900 W = 0.9kW 1.5
path in time = 0.375 s.
In 5h, electrical energy used by all 4
laptops, So, in remaining 0.8 s (= 8.3- 7.5s) ball is
,ti�'---'---.L.....a------- E = P x t = 0.9 x 5 very near to other end of diameter as
Observer shown in the figure.
= 4.5 kWh
So, processes involved in formation of
Cost of electrical energy used is Position of ball at
rainbow in correct order are: refraction,
total internal reflection, refraction. Cost = E x Unit cost
Hence, the correct order is given in = 4.5 x 5
option (a). = '{ 22.50
1 7. (a) Here, 10 divisions of vernier scall So, statement III is correct.
= 11 main scale divisions For laptop charger, input voltage is
. sea1e division
. . . 11 . 220 V.
S o, 1 vernier = - main
10
I
So, current when all 10 laptops are
scale divisions connected through an extension, = 7 .s?ss
I = "!!_ = oo
Now, we use formula for least count, 9 Position
= 4. lA of ball at
Least count = l main scale division - 1 V 220 t=8.3s
vernier scale division. As, line current exceeds current rating of Clearly, displacement of ball is nearly
⇒ LC = lMSD - lVSD fuse, therefore 3A fuse cannot be used. equals to diameter (= 2 m) of circular path.
23. (a) Condition given in question is
So, statement II is incorrect.
20. (c) Frosted glass has a rough layer
= 1- �� ) MsD
( shown below.
which causes irregular refraction and
= _ --1:_MSD I
10 makes glass translucent. I
L Particle
When a transparent tape which has 'l"' � separates here
= _ --1:_ x lmm
Tr_____ �
10 refractive index close to that of glass is R-h "l'
= -0.l mm pasted over the rough surface of glass,
the tape glue fills the roughness of glass. R :I h
So, magnitude of least count is 0.1 mm. I
This makes glass surface more smooth
Let v = speed of particle when it
I
1 8. (b) Velocity = Slope of distance
and so refraction is more regular. This
- Time graph makes region of tape transparent.
21 . (d) Prism B is inverted relative to
Last portion of given graph is a straight separates from hemisphere.
line which indicates that velocity is As there is no friction, loss of potential
prism A. So, dispersion of light caused by
constant, i.e. terminal velocity is reached. energy appears in form of kinetic energy
prism A and B is in opposite direction.
of particle.
WWW.JEEBOOKS.INl
mg(R- h) = _!_ mv2 26. (d) Time of fall = ✓ 2h 28. (b) Surface area over which rain is
2 llnet received, A = 600 km 2
⇒ v = ,J2g(R - h) = 600 X (Hr )2 m 2
24. (c) Given, nuclear radius is = 6 X 108 m 2
Average rainfall, h = 2.4m
Volume of water received by rain, V
E
Here, atomic mass number of nucleus = A 8

= A x h = 6 x 10 x 2.4 m
3
:. Nuclear density d is given by Water conserved = 10% of volume

Mass number IIIIIIIIIIIIIIIIIIIIII received by rain
Volume Net acceleration of charged masses is = 6 x 108 x ___!Q_ x 2.4m3 = 1.44 x 108 m3
A A qE 100
⇒ d=- - llnet = g -
� 1t.R3 4 - = 1.4 X 10 lo'3 L = 1.4 X 1()1 1 L
8
X
3 - 1t (roA-3 )3
3 As, M1 hits the floor before M2. Percentage of total water consumption
d = - - A- 3 received by rain is
⇒ ⇒ >
(! (! 1.4 X ld- 1 X 100 = l0%
,1
- 1tr0 - A 41trJ
3
3 1 1 1.4 X [ 01 2
29. (d) Collision i s elastic, s o both linear
As r0 = a constant, so nuclear density is a ⇒ ->-
lli (½
constant quantity. momentum and kinetic energy are
:. Nuclear mass density of U238 is same
⇒
conserved.
as that of Sn119 • When reciprocal is taken in equality sign
25. (a) Electrostatic energy of a nucleus
is reversed, then. We have following situation,
QE Q Before � V
of charge Ze is g- l > g- � � ---- m=O
Ml M2 collision � '
R
kZ 2e2
U1 = - - ... (i) Ql E Q�
⇒ - >-
Ml M2 After ��
When this nucleus is divided into two
equal nuclei of radius r, then as density Ql E Q2E collision � '
⇒ -- < --
of nuclear matter is a constant, we have Ml M2 According to figure,
initial density = final density Here, multiplication with - l reverse sign MV = MV' + mv ... (i) (linear momentum
M of inequality. conservation)
M - 2
So, S'i_ < Q2 _!_MV 2 = _!_MV'2 + _!_ mv2 ... (ii)
:!_ n.R3 � 1tr3 Ml M2 2 2 2
3 3
3 or MR1 < M1Q2 (kinetic energy conservation)
R R
⇒ r3 = - or r = -I ... (ii) ⇒ M1Q2 > MR1 From Eqs. (i) and (ii), we get
27. (a) From gas equation,
2
23 M(V - V ') = mv ... (iii)
Now, final electrostatic energy is given by and M(V 2 - V '2 ) = mv2 ... (iv)
(;
p V = nRT
U2 2 x - �u, -
2
Here, n = 1 mole Dividing Eq. (iv) by Eq. (iii), we have
' 2k( z ) e2
kZ 2e2 M(V 2 - V '2 ) = mv2
Substituting the value of R in Eq. (i), we
=
2 So, p V = RT ... (i)
, M(V - V ') mv
l get or V + V ' = v
p V = 8.3 T 30. (c) Total internal, reflection occurs
Clearly, slope of p V versus T line is 8.3, 1
1 kZ2e2 when n � -- .
[from Eq. (ii)] = 2 - which is greater than one. Hence, sin ic
�
23 following graph is correct.
1
⇒ U2 = 2 · U1 pV (J)
23
[from Eq. (i)] = 0.63 U1
So, change in electrostatic energy in this
process is
/J.U = U1 - U2 (·: U1 > U2)
= U1 - 0.63U1= ( 1 - 0.63) U1 = 0.375 U1
kZ 2e2
= 0.375 [From Eq. (i)] T ( K)
R
WWW.JEEBOOKS.INl
35. (d) Water-gas shift reaction is 41t g.

each of ray is 30° over face PR.
I n given situation, angle of incidence of :. Mass = volume x density =
CO+ H2O FeO · Cr203 (Catalyst) l 3
So, i = 30° (Atomic weight of water = 18)
21t
⇒ _ 1_ = _ _ 1_ = 2
In this reaction, hydrogen gas is n = - 41t - = -
sin i sin 30° 3 X 18 27
44. (b) Cathode ray is observed only at
produced from the reaction of steam with
surface PR, n � 2 . As refractive index for

Hence, for total internal reflection at carbon dioxide.
36. (c) Temporary hardness (caused by low pressure and high voltage, which
pass from face PR while rays 3 and 4 pass

3 and 4 is more than 2, only rays 1 and 2, bicarbonates of calcium or magnesium) travel in straight line in the absence of
through face QR (as shown in diagram).

can be removed by using lime, Ca(OH) 2• electrical and magnetic fields.
Characteristics of cathode rays are
3 1 . (a) Hybridisation is determined from
Ca(HCO3 )2 + Ca(OH)2 ----t 2CaCO3
independent of the material of electrode
+ 2H20
37. (b) Among anions with same charge,
or the gas present in the tube.
45. (d) For a spontaneous process in an
the steric number (number of atoms
bonded to the central atom + the number
the one having greatest size has
of lone pairs). Number of hybrid orbitals isolated system, the change in entropy is
maximum polarisability. Thus, rion
must be equal to the steric number. positive, i.e, dS > 0.
having most polarisability.
"-�=C=O:
38. (b, d) Among the orbitals of a
From the Lewis structure. However, if a system is not isolated, the
R entropy change of both the system and
multi-electron atom, the one with surroundings are to be taken into account
greatest value of n + l has the greatest because system and surroundings
(i) Steric number of N-atom = 3
energy. together constitute the isolated system
(2 bonded atoms + 1 lone pair),
:. Hybridisation = sp 2 (3 hybrid Between two orbitals with same value of thus, the total entropy change (dStotal ) is
orbitals). n + l e.g. options (b) and (d), the one with sum of the change in entropy of the
greater value of n has greater energy.
39. (c) N2O is a neutral oxide, which is
(ii) Steric number of C-atom = 2 system (dSsystem ) and the change in
(2 bonded atoms), entropy of the surroundings
:. Hybridisation = sp (2 hybrid neither acidic nor basic. (dSsurroundings ),
orbitals). 40. (a) Of all the s-block elements, Mg i.e., dStotal = dSsystem + d&,urroundings for a
(iii) Steric number of O-atom = 3 and Be salts do not impart colour to spontenceus process, dStotal must be
(1 bonded atom + 2 lone pair) flame. positive, i.e., dStotal is also termed as
41 . (a)
:. Hybridisation = sp 2 (3 hybrid dSuniverse·
orbitals). 46. (c) The correct statement for
32. (d) One isomer is an alkyne and the
For a reaction
primates' evolution is that human,
X ----t Y, chimpanzees and gorillas share a
other one is an alkadiene. Since, they
have two different functional groups, rate = - d[X\ [X] = concentration of X. common ancestor. From fossil records,
they are functional group isomers. dt primatologists came to know that human,
33. (a) If reaction is nth order, chimpanzee and gorilla are evolved from
A
rate oc [Xr a common ancient ancestor about 10
Br
I Br I.Excess alcoholic KOH1 � d[X] is million years ago. Recent studies on
- HBr Ph' &"'111111111 From the graph, the slope gorilla genome confirmed that gorilla
Ph/'-...,/ dt
e + constant. diverged from the common ancestor
.,...,_, ,Br 2.NaNH, Ph- Coc°N/ 3.H,O Ph-CoCH about 6 million years ago.
47. (b) The crypts of Lieberkuhn are
PV "', -HBr :. Rate is constant at any concentration.
- 2NH, or Ph0H
n=0
42. (a) In a free expansion, external
found in small intestine. Crypts are
34. (d) 0
invagination of the epithelium around
pressure (pex ) = 0 the villi and lined largely with younger
1 11 W =- Pex · dV = 0 epithelial cell which are involved in
6(")2 secretion of mucus.
48. (c) Removal of pancreas impairs the
and the system is isolated.
3 Heat does not enter or leave, q = 0.
H� 4
dU = q + W = 0, where U = internal breakdown of lipids, proteins and
Principal functional group is ketone. carbohydrates because pancreas produces
energy.
:. <; is carbonyl carbon atom.
43. (b) Number of moles,
insulin and other important enzyme like
Locants for hydroxyl groups and double trypsin, chymotrypsin, amylase and
bonds are 5 and 2, which are preferred mass (m) -
n=- - - - - - lipase which helps in breakdown of
over 3 and 5, since the lower number at molar mass (M) macromolecules.
first difference (2 compared to 3) is Given, radius = 1.0 cm, 49. (c) Microscopic examination of blood
preferred. 41t cm3 smear reveals an abnormal increase in
:. volume =
Hence, the IUPAC name of given 3 neutrophils. Neutrophils have a
compound is 5-hydroxycyclohex-2-en- Given, density = 1.0 g cm - 3 , multilobed nucleus and granulated
1-one. cytoplasm.
WWW.JEEBOOKS.INl
Their number increases in blood in deals with identification, nomenclature 60. (d) The second meiotic division
response of bacterial infection, acute and classification. Carlous Linnaeus occurs after fertilisation. Oogenesis is the
inflammation and Eclampsia. invented binomial nomenclature and formation of female gametes (egg).
Neutrophils are produced by developed a classification system known Oogenesis begins in female before birth.
hematopoiesis in the bone marrow and as taxonomic hierarchy. The various During early fetal development, germ cell
are active phagocytic cells. units of classification is kingdom, differentiate into oogonia. After several
Lymphocytes are white blood cells phylum, class, order, family, genus and mitotic divisions, oogonia begins meiosis
species. and known as primary oocytes. It
56. (b) Kidneys are not associated with
which occurs in blood, lymph and
lymphoid organs. remains arrested after diplotene of
Monocytes are mononuclear phagocytic the production of white blood cells. prophase-1 of meiosis-I until the female
cells. Kidneys regulate blood volume and becomes sexually mature. After puberty,
primary oocyte completes meiosis-I and
Platelets are known as thrombocytes composition, release erythropoietin and
excrete waste in the urine. produces secondary oocytes and it arrests
50. (a) Blood group AB represents

and helps in blood clotting.
Bone marrow is involved in at metaphase-11 and it completes meiosis
-II only after fertilisation.
6 1 . (c) It is given that the quadratic
hematopoiesis. It is the site of
codominance. In codominance a
B-lymphocytes synthesis and maturation.
heterozygous individual expresses both
alleles simultaneously with blending. No Liver produces monocytes (a type of equation
single allele is dominant over the other. white blood cells). x2 - 5cx - 6d = 0 has roots a and b, then
Expression of both A and B alleles at In spleen, B and T-lymphocytes are a + b = 5c . . . (i)
same time results in AB type blood. present. 50% of spleen cells are . . . (ii)
5 1 . (b) Allopatric speciation is a genetic
and ab = - 6d
B-lymphocytes and 30-40% are and, the quadratic equation
x2 - 5ax - 6b = 0 has roots c and d, then
57. (b) Hydathodes are involved in
divergence permitted by geographical T-lymphocytes.
isolation. It is a speciation that occurs c + d = 5a . . . (iii)
when population of the same species guttation. Hydathodes are specialised
pore located along the leaf margins and
and cd = - 6b . . . (iv)
becomes isolated due to geographic
barriers such as mountain ranges and tip which secrets water droplets. The Now, from Eqs. (i) and (iii), we have
= - 5(a - c)
water bodies. The population is exudation of water droplets from the tip (a + b) - (c + d) = 5c - 5a
⇒ (a - c) + (b - d)
(b - d) = 6(c - a)
reproductively isolated and each of the or margin of the leaves is called
population accumulates different guttation. Hydathodes mediated ⇒ . . . (v)
mutation and become diverge. guttation occurs under high humidity
:. a and c are the roots of equations.
52. (d) Conversion of glucose to CO2 and and in the absence of transpiration.
x2 - 5cx - 6d = 0 and x2 - 5ax - 6b = 0,
H2O requires oxygen. In aerobic Cuticle is an extracellular layer which
covers the epidermis of plants which respectively.
respiration glucose reacts with oxygen
forming ATP, carbon dioxide and water provides protection against dessication a2 - 5ac - 6d = 0
and c - 5ac - 6b = 0
2
⇒ (a - c ) - 6(d - b) = 0
are released as byproducts. and external environmental stress.
2
C 6H12O 6 + 6O 2 -----t 6CO 2 + 6H2O + ATP Lenticels and stomata both regulates 2
53. (c) Proxima and distal convoluted

gaseous exchange between internal plant 6(d - b)
⇒ a+ c= = 36 . . . (vi)
tissues and atmosphere and also regulates a-c
tubules are located in renal cortex.
58. (d) Cataract affect the lens in eye. It

water movement through transpiration.
Convoluted means the tubules one tightly From Eqs. (i) and (iii), we have
coiled. Proximal convoluted tubules are (a + b) + (c + d) = 5(a + c)
acid, Cr, HCO3 , Ca , Mg 2 + and

occurs due to the clouding of lens and
b + d = 4(a + c) = 4(36) [from Eq. (vi)]
associated with the reabsorption of
+ + prevent light and image from reaching to ⇒
filtered water, Na , K . glucose, amino
2+ retina. Cataract makes a person vision ⇒ b + d = 144
4x2 + bx + c = 0
blurry and less colourful. 62. (a) The quadratic equation
59. (a) Liverwort These are
secretion of W, Ntt:, urea whereas distal
convoluted tubules are associated with
+
reabsorption of water, Na , er and Ca 2 + . non-vascular plants and one of the three has equal roots if b - 16c = 0
2
b2 = 24 c
54. (d) When one gene masks or ancient lines of bryophytes (liverworts,
⇒
Volvox It is a spherical multicellular

modifies the expression of another gene hornworts and mosses).
Now,c should be chosen from the set
at distinct locus is known as epistasis.
Gene that masks other or expresses itself green algae and used as a genetic model S = {1, 2, 3, ... , 100}, such that it is a
perfect square number, so
Chlamydomonas It is a genus of
is epistatic gene and gene that is masked of morphogenesis.
is hypostatic gene. Here, X is inactivated C = 1, 4, 9, 16, 25, 36, 49, 64, 81, 100
by Y and triggers its own expression that unicellular green algae found in soil, :. number of ordered pair ( b, c) will be 10.
means Y is epistatic to loci X because it freshwater and oceans. 10
So, required probability =
masks the expression of X. Fern These are vascular plants that
55. (a) The correct taxonomic hierarchy
lO0 x 100
possess true roots, leaves and stem and 1
= -- = 0.001
is species, genus, family, order. are reproduced by spores. Ferns and 1000
Taxonomy is the branch of biology that lycophytes are pteridophytes.
WWW.JEEBOOKS.INl
63. (a) I t i s given that fo r n E N :.XB = x2 - AB 67. (a) Force Rate of change of
AB = AX + XB = x - AB + x2 - AB
=
-1± /1+4 _ ±-/5 - 1

113 113 momentum
fn = (n + 1) -n
2
(n + 1) - n ⇒ x + x - 1= 0
(n + 1?3 + (n + 1?3 n :.r3 + n :.r3 =
⇒ X
1 2 2
(n + 1?3 + (n + 1?3 n :.r3 + n :.r3 X>
-/5 - 1
0, SO X = --
AB2 + BC2 - AC2

2
·: 'd n E N
3n :.r3 < (n + 1?3 + (n + 1?3 n :.r3 + n :.r3 Now, cos0 = - - - - - -
3 2(AB)(BC)
< 3(n + 1?
[·: AB BC]
1 2(AB2 ) - (AX 2 )
⇒ --� � ⇒ cos0 = =
3(n + 1?3 2(AB 2 ) Velocity with which a sand particle
v = u + gt
1� 1- 2 2 2 strikes the bottom of hour-glass,
< -- �3� -- � � - � < - _ 2(AB ) - (x . AB )
(n + 1? + (n + 1?3 n :.r3 + n :.r3 3n :.r3 -
2(A B�)
1 1 ⇒ v 0 + 10 x 2
= = 20 ms- 1
2
< /, < --
= Pr - P; = O - mv
⇒ 2- x
3(n + 1?3 n 3n ll'3 Change in momentum of particle
2 - (�)
2
Similarly, 2
- 0.2 X 10- 3 X 20
=
1
---- < fn + I < ----
1
= - 4 x 10- 3 kg-ms- 1
3(n + 2? 3 3(n + 1?3
II'3 < fn + l ' 'd n E N

2 Momentum imparted to base by the
1
fn + I < 8 - (5 + 1- 2-/5) particle 4 x 10- 3 kg-ms- 1
=
3(n + 1) =
So, set A = N.
8 Total change of momentum imparted per
second by all 100 particles
2-/5 + 2
1 1
64. (b) It is given that for prime 4 x 10- 3 kg-ms- x 100 s-
numbers A, p2 , P3 , p4 the special prime
=
8
= 0.4 kg-ms-1
number =
-
-J5 + 1- = cos36° =
So, force on bottom 0.4 N
So, 0 = LABC = 36 ° 68. (b) When a voltmeter put in series, it
If all A , p2, P3 , p4 are odd, then (p1 + p2 ) 66. (c) When angle of incidence of laser
Case I still reads potential drop and when an
ammeter is connected in parallel, it still
and (p3 - p4 ) are even, which is not on surface of water is less than critical shows current through it.
possible. incidence, it goes out otherwise reflected
Case a
back into the tank.
If one of A and p2 is even, say p2 is 2 and
Case II B
Laser comes out from
p4 must be 2.
So, p = Pi + 2 = p3 - 2
a path of 2 ic rotation
the above equation is satisfied only if A

=
P 5, A 3 and P3 = 7 =
So, the number of special prime p is 1.

65. (b) It is given that in MBC,
AB = BC
A
( n-.! )
=
Let l current through cell, then
A 1 11 potential drop read by voltmeter is
For water, i c = sin- = sin- -- )
( 1.33 =
V 1- Rv (this is reading of voltmeter)
sin- 1 (0.75)
In loop AB,
⇒ ic= Where, Rv is the resistance of voltmeter
X ⇒ ic = 50°
If co angular speed and t time to travel
= = VAB 11 x l l2 x RA and l l1 + 12
= = =
an arc of 2 ic, then using cot 2 i c- =

Where, RA is the resistance of ammeter
We have, t = _
0
a �- - - - - - �c
� 2 ic
AX AB 1
We substitute for 11 from above equation
XB AX X l = l�A + 12 = liRA + 1)
= =
to get
and - - - (say)
⇒ AX = x - AB
2 X � X 1t ⇒
( !� )
l80 = 16.67 s l
⇒ 12 - =
--
and XB = xAX (RA + 1)
(this is reading of ammeter)
WWW.JEEBOOKS.INl
Now given, where Po = density of outside air van der Waals' gas, the actual pressure
Hf
an 2
voltmeter reading IRy and pi = density of inside air. and volume are:
⇒ V (p0 - pi ) = 2 10
= 1x =
ammeter reading
/-
(-- ) P = Po - --
2 V = V0 + nb
,
RA + 1 2 10 3 V
⇒ = i 1tr3
( ·: V
Po - Pi � = )
RT
pV
4 nr·
PM PM
So, Ry (RA + 1) = 1000 ... (i) 3 :.As "d' increases, p decreases, so
Case b
RTO RT; T0
2 10 x 3 1 1
� - - - - = ------ ⇒- - - decreases, when temperature is constant.
pV
3
11.7 T;,
RT
B 4 X 7t X -- ) and, as "lJ' decreases, V decreases, so
A I-- - -- - - -� (
Hf
680 x 8 x 8.31 decreases, when temperature is constant.
4 x 1t x 0- 1.7)3 x x 30 x 10- 3
T;, - T0
Note option (c) : When temperature
increases, p V also increases and
1Q
TOT; therefore Z would not necessarily

1
⇒ = __
1387
decrease.
73. (a) (i) Energy of the 2.surbital of
⇒ T0 T;, = 1387 (T;, - T0 )
Let I = current through cell, then

A
⇒ 300 T;_ = 1387 T;_ - 300 X 1387
ammeter reading in this case is I.

different elements decreases as nuclear
(as, T0 = 27°C = 300 K) charge (equal to atomic number) of atom
300 x 1387 =
So T' = 383 K increases.
'
Also, in loop AB,
1087 (ii) There are n 2 orbitals in a shell with
T;, = 383 - 273 = 110° C principal quantum number n.
:. total number of electrons = 2n 2•
= =
VAB l1 x l l2 x Ry
So, temperature of hot air is near to 105° C.
70. (c)
= I2 (Ry + 1)
=
As, 1 11+ 12 = I�y + 12
(iii) Extra stability of half-filled orbitals
I Head
is due to greater exchange energy.
So, 12 = - - - (iv) For two electrons will be in the same
(Ry + 1) • orbital, their spin quantum numbers
Hence, voltmeter reading is V l�y =
} m
.-----,......_____, 1 .7m must be different.
=
IRy
(this is reading of voltmeter)
74. (c) Mass of AgX = 2.21g
It is not irrespective of their spin.
(Ry + 1)
Heart
Now given, voltmeter reading + ammeter
reading = 0.999 n. Mass of X = 46.78% of 2.00 g
46.78 x 2.00
I 7
=
IRy 1 .3m
100
(Ry + l) J
I
So, 0.999 = l 0.94 g
:. Mass of Ag in AgX must be
= 13.3 - lo'3 x lO x 0.4

⇒ 0.999 = ____&_ Pressure at head level = Pheart - pgh 2.2 1 - 0.94 g
Ry + 1
= 1.27 g
= Hf n
So, Ry = 999Q ... (ii) = 9.3 kPa 1.27,
:. Number of moles of Ag =
Hf
Pressure at foot level = Pheart + pgh 108
Substituting Ry in Eq (i), we get = 13.3 + x 10 x 1.3 which is also equal to number of moles
=
1 = 2 .3 kPa ofX.
RA - 6
'n'
999 . 2 .3 mass
=
So, ratio = - 6 - = 2 .9 or 3 :. Atomic mass of X =
or R 10- 3
= n
69. (c) Hot air balloon will rise in the
9.3
71 . (c) (a) PbO + HCl----t PbC12 + H2O
A
=
0.94 x 108
80
atmosphere when upthrust of buoyant 1.27
(not correct option)
:. The halogen must be bromine (Br).
75. (d)
force is greater than weight of balloon
(b) 2Pb(NO3 ) 2 ----t 2PbO + 4NO 2 + 0 2
and its payload.
(not correct option)
Upthrust = Weight of atmospheric air Br Br
(c) Pb 3 O4 + 4HNO3 ----t 2Pb(NO3 ) 2
displaced by balloon + PbO2 + 2H 2 O (correct option) �+ 2HBr·--➔�
So, upthrust � weight of balloon and its (d) Pb + air (contains 0 2, H20 and COJ
payload room (Hydrobromination, Markownikoffs
⇒ (Volume of air displaced x density of temperature product, which is a gem-dibromide).
atmospheric air x Acceleration due to Protective layer of varying composition,
gravity) � (Volume of air of inside balloon mainly PbCO3 is formed only on the
x density of air inside balloon x surface. (not correct option)
72. (b) If p0 and V0 are used as notation
acceleration due to gravity) + (Weight of
payload of balloon)
⇒ V · Po · g � V · Pi · g + 2 10 X g of ideal pressure and ideal volume of a
WWW.JEEBOOKS.INl
Acid catalysed hydration of alkyne gives 1024 = 1

= -- Graph (c) and (d) represents constant
ketone. In the case of terminal alkyne, 1024 activity of both enzyme. At low pH
the product is a methyl ketone, which So, option (c) is correct activity of pepsin increases and become
77. (d) In papaya, sexual genotype for
gives haloform test. stable as pH is increasing and activity of
0 0 amylase increases at above pH 5 and
� I2 + Na0H
male is XY and for female is XX. In become stable at high pH.
79. (c) Gene pool of locus X = 4
� ONa double fertilisation, the X nuclei fuses
with egg and polar nuclei then resulting
+ CHI3 + other genotype of embryo and endosperm is XX Possible genotype = !:1'.. (n + 1)
products
2
(NaI+H2 0)
and XXX. When Y nuclei fuses with the
egg cell and polar nuclei then resulting n = Total number of gene for 'X' loucs
n=4
1
Yellow product genotype for embryo and endosperm is
(positive haloform test) XY and XXY.
76. (c) Mass of one cell = 1 mg = 10- 6 kg So, 50% XXX and XXY is genotype of = !:1'.. (n + 1)
2
Division in the cell is calculated as 2 n endosperm and 50% XX and XY is
genotype of embryo. =i (4 + 1) = 2(5) = 10
78. (a) Graph (a) represents the activity
So, after 100 divisions, 2
Number of cells = 2n = z-00 So, highest possible genotype in a
of pepsin at low pH and salivary amylase population is 10.
80. (b) The correct combination of plant
Total mass of cells = Total no. of cells x activity at high pH. Enzymes have a
Mass of one cell
= z-00 X D 10- 6 kg
particular pH where they have the proper
conformation to have maximum catalytic hormones with their function is as follows
= z-0 = 10'3 activity. Pepsin have maximum catalytic (P) Abscisic acid-Maintains seed
= (103 )10 X 10- 6 kg activity at a very low pH (2.0) and no dormancy
= 10'3° x lO- 6 kg longer functional once moved to alkaline (Q) Ethylene-Promotes fruit ripening
condition and optimum pH for salivary (R) Cytokinin-Inhibits leaf senescence
= l0+ 24 kg
amylase ranges from 6 to 7 and it is most (S) Gibberellin-Promotes seed
Mass of earth is 1024 kg active at pH 6.8. germination
. = -Total
Rat10 - mass
- - of- cells
- Graph (b) represents minimum activity of
Mass of earth pepsin and salivary amylase.
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions
MATHEMATICS Then
(a) both I and II are true (b) both I and II are false
1. The number of pairs (a, b) of positive real numbers
(c) I is true and II is false (d) I is false and II is true
satisfying a 4 + b4 < 1 and a 2 + b2 > 1 is
5. The number of polynomials p(x) with integer
(a) 0 (b) 1
coefficients such that curve y = p(x) passes through
(c) 2 (d) More than 2
(2, 2) and (4, 5) is
2. The number of real roots of the polynomial equation (a) 0 (b) 1
x4 - x2 + 2x - 1 = 0 is (c) more than 1 but finite (d) infinite
(a) 0 (b) 2 6. The median of all 4-digit numbers that are divisible
(c) 3 by 7 is
3. Suppose the sum of the first m terms of an arithmetic
(d) 4
progression is n and the sum of its first n terms is m,

(a) 5797 (b) 5498.5 (c) 5499.5 (d) 5490
where m n. Then, the sum of the first (m + n) terms

7. A solid hemisphere is attached to the top of a
* cylinder, having the same radius as that of the
of the arithmetic progression is cylinder. If the height of the cylinder were doubled
(a) l - mn (b) mn - 5 (keeping both radii fixed), the volume of the entire
(c) - (m + n) (d) m + n system would have increased by 50%. By what
4. Consider the following two statements percentage would the volume have increased if the
radii of the hemisphere and the cylinder were
I. Any pair of consistent liner equations in two
doubled (keeping the height fixed)?
variables must have a unique solution.
(a) 300% (b) 400%
II. There do not exist two consecutive integers, the (c) 500% (d) 600%
sum of whose squares is 365.
WWW.JEEBOOKS.INl
8. Consider a 11PQR in which the relation PHYSICS

QR2 + PR2 = 5 PQ2 holds. Let G be the point of
intersection of medians PM and QN. Then, LQGM is 16. A block of wood is floating on water at 0° C with
always volume V0 above water. When the temperature of
(a) less than 45° (b) obtuse
water increases from O to 10°C, the change in the
(c) a right angle (d) acute and larger than 45° volume of the block that is above water is best
9. Let a, b, c be the side-lengths of a triangle and l, m, n

described schematically by the graph.
+m+ n
be the lengths of its medians. Put K = l
a+b+c
(a)
Vo � ( ) Vo
Then, as a, b, c vary, K can assume every value in the b

interval � t
(t � )
1 0°c
0°C 0°C
(a)
(c) (d)
(c) (1 , 1) Vo Vo
� �
10. Let x0 , y0 be fixed real numbers such that � + y� > 1.
If x, y are arbitrary real numbers such that
1 0°c 1 0°c
0°C 0°C
x2 + y2 � 1, then the minimum value of
(x - x0 ) 2 + (y - y0 )2 is
17. A very large block of ice of the size of a volleyball
court and of uniform thickness of 8 m is floating on
(a) <.J� + y� - 1)2 + y� - 1
(b) � water. A person standing near its edge wishes to
(d) ( l.xal + l y0 l )2 - 1
(c) ( l.xal + l y0 l - 1)2 fetch a bucketful of water using a rope. The smallest
11. Let PQR be a triangle is which PQ = 3. From the
length of rope required for this is about
vertex R, draw the altitude RS to meet PQ at S.

(a) 3.6 m (b) 1.8 m (c) 0.9 m (d) 0.4 m
Assume that RS = ../3 and PS = QR. Then, PR equals
18. A box filled with water has a small hole on its side
near the bottom. It is dropped from the top of a
(a) -./5 (b) -/6
tower. As it falls, a camera attached on the side of
(c) -/7 (d) ,Js
the box records the shape of the water stream coming
12. A 100 mark examination was administered to a class out of the hole. The resulting video will show
of 50 students. Despite only integer marks being (a) the water coming down forming a parabolic stream
given, the average score of the class was 47.5. Then, (b) the water going up forming a parabolic stream
the maximum number of students who could get (c) the water coming out in a straight line
marks more than the class average is (d) no water coming out
(a) 25 (b) 35
19. An earthen pitcher used in summer cools water in it
(c) 45 (d) 49
essentially by evaporation of water from its porous
13. Let S be the sum of the digits of the number 152 x 518 surface. If a pitcher carries 4 kg of water and the rate
in base 10. Then, of evaporation is 20 g per hour, temperature of water
(a) S < 6 (b) 6 '.,'.; S < 140 in it decreases by 11T in two hours. The value of 11T is
(c) 140 '.,'.; S < 148 (d) S � 148 close to (ratio of latent of evaporation to specific heat
14. Let PQR be an acute-angled triangle in which
of water is 540° C)
PQ < QR. From the vertex Q draw the altitude QQ1 ,
(a) 2. 7° C (b) 4.2 ° C (c) 5.4°C (d) 10.8°C
the angle bisector QQ2 and the median QQ3 , with 20. Two plane mirrors are kept on a horizontal table
Q1 , Q2, Q3 lying on PR Then, making an angle 0 with each other as shown
(a) PQ1 < PQ2 < PQ3 schematically in the figure. The angle 0 is such that
(b) PQ2 < PQ1 < PQ3
any ray of light reflected after striking both the
mirrors returns parallel to its incident path. For this
(c) PQ1 < PQ3 < PQ2
to happen, the value of0 should be
(d)PQ3 < PQ1 < PQ2
15. All the vertices of a rectangle are of the form (a, b)
with a, b integers satisfying the equation
(a - 8)2 - (b - 7) 2 = 5 . Then, the perimeter of the
rectangle is
(a) 20 (b) 22
(c) 24 (d) 26 (a) 30° (b) 45° (c) 60° (d) 90°
WWW.JEEBOOKS.INl
2 1 . A certain liquid has a melting point of -50°C and a 27. Select the correct statement about rainbow.
boiling point of 150° C. A thermometer is designed (a) We can see a rainbow in the western sky in the late
with this liquid and its melting and boiling points are afternoon
designated at 0°L and 100°L. The melting and boiling (b) The double rainbow has red on the inside and violet on
points of water on this scale are the outside
(a) 25°L and 75°L, respectively (c) A rainbow has an arc shape, since the earth is round
(b) 0°L and 100°L, respectively (d) A rainbow on the moon is violet on the inside and red
on the outside
(c) 20°L and 70°L, respectively
(d) 30°L and 80°L, respectively 28. Remote sensing satellites move in an orbit that is at
an average height of about 500 km from the surface
22. One can define an alpha-volt (a-V) to be the energy
acquired by an a-particle when it is accelerated by a of the earth. The camera onboard one such satellite
has a screen of area A on which the images captured
potential of 1 V. For this problem, you may take a
proton to be 2000 times heavier than an electron. by it are formed. If the focal length of the camera lens
Then, is 50 cm, then the terrestrial area that can be
observed from the satellite is close to
(a) 1 a- V = l eV/4000 (b) 1 a-V = 2 eV
(a) 2 x 10 3 A (b) 106 A (c) ld-2 A (d) 4 x ld-2 A
(c) 1 a-V = S000 eV (d) 1 a-V = l eV
29. Letters A, B, C and D are written on a cardboard as
□
23. In a particle accelerator, a current of 500 µA is
shown in the figure below.
carried by a proton beam in which each proton has a
speed of 3 x 107 m/s. The cross-sectional area of the
beam is 1.50 mm2 • The charge density in this beam
(in C/m3 ) is close to
W l� � 1� � 1� 00 1 �
24. Which of the following is not true about the total The cardboard is kept at a suitable distance behind a
lunar eclipse? transparent empty glass of cylindrical shape. If the
(a) A lunar eclipse can occur on a new moon and full moon glass is now filled with water, one sees an inverted
day image of the pattern on the cardboard when looking
(b) The lunar eclipse would occur roughly every month, if through the glass. Ignoring magnification effects, the
the orbits of earth and moon were perfectly coplanar image would appear as
(c) The moon appears red during the eclipse because the
□
blue light is absorbed in earth's atmosphere and red is (b)
transmitted
(d) A lunar eclipse can occur only on a full moon day 0 8
25. Many exoplanets have been discovered by the transit J

c
method, where in one monitors, a dip in the intensity
(c) (d)
of the parent star as the exoplanet moves in front of
it. The exoplanet has a radius R and the parent star 8 0 8 0
V
has radius 100 R. If I0 is the intensity observed on
earth due to the parent star, then as the exoplanet J
c
transits 30. If a ball is thrown at a velocity of 45 m/s in vertical
0.9 I0
(a) the minimum observed intensity of the parent star is upward direction, then what would be the velocity
profile as function of height? (Assume, g = 10 m/s 2)
0.99 I0
(b) the minimum observed intensity of the parent star is
(a) (b)
0.999 I0
(c) the minimum observed intensity of the parent star is 45 L 45
L
v(m/s u v(m/
0.9999 I0
(d) the minimum observed intensity of the parent star is :
�0 Height 1 01 0 Height 1 01
26. A steady current I is set up in a wire whose (m) (m)
cross-sectional area decreases in the direction of the
(c) (d)
flow of the current. Then, as we examine the
narrowing region, 45 L 45
L
(a) the current density decreases in value v(m/s v(m/s
(b) the magnitude of the electric field increases �
�
(c) the current density remains constant � 0 Height 1 01 0 Height 1 01
(d) the average speed of the moving charges remains (m) (m)
constant
WWW.JEEBOOKS.INl
CHEMISTRY 37. The correct statement about the following compounds
� �
31. The number of water molecules in 250 mL of water is
closest to Br Br
[Given, density of water is 1.0 g m L - 1 ; Avogadro's X y
number = 6.023 x 1023]
lS
(a) 83.6 X 1023 (b) 13.9 x 1023
(c) 1.5 X 1023
(d) 33.6 x 1023 (a) Both are chiral
(b) Both are achiral
32. Among the following, the correct statement is (c) X is chiral and Y is achiral
(a) pH decreases when solid ammonium chloride is added (d) X is achiral and Y is chiral
to a dilute aqueous solution of NH.i
(b) pH decreases when solid sodium acetate is added to a 38. The most acidic proton and the strongest nucleophilic
dilute aqueous solution of acetic acid nitrogen in the following compound
(c) pH decreases when solid NaCl is added to a dilute
aqueous solution of NaOH
(d) pH decreases when solid sodium oxalate is added to a
dilute aqueous solution of oxalic acid
33. The solubility of BaSO4 in pure water (in g L -1) is
closest to
[Given; Ksp for BaSO4 is 1.0 x 10-10 at 25°C. Molecular respectively, are
(a) N° - H; Nb (b) Nb - H; N °
weight of BaSO4 is 2 33 g mol -1] (c) N° - H; N ° (d) N c - H; N°
(a) lO x 10-5
39. The chlorine atom of the following compound
(b) lO x 10-3
(c) 2. 3 X 10-5 CIC
(d) 2. 3 x 10-3
Cl� �· d
34. Among the following, the incorrect statement is ,,,
(a) no two electrons in an atom can have the same set of
J a
four quantum numbers lO Cl
(b) the maximum number of electrons in the shell with
principal quantum number, n is equal to n 2 + 2 that reacts most readily with AgNO3 to give a
(c) electrons in an orbital must have opposite spin precipitate is
(d) in the ground state, atomic orbitals are filled in the (a) Cl0 (b) Clb (c) Cle (d) Cld
order of their increasing energies 40. Among the following sets, the most stable ionic
35. A container of volume 2.24 L can with stand a species are
0:)
maximum pressure of 2 atm at 298 K before 8 Ell Ell
Ell
exploding. The maximum amount of nitrogen (in g) and /\
(a) O:) and /\ (b)
e
that can be safely put in this container at this
0:) e
temperature is closest to 8 Ell
(a) 2.8 (b) 5.6

(c) and /\ (d) O:) and /\
(c) 1.4 (d) 4.2
36. The compound shown below
41. The correct order of energy of2s-orbitals in H, Li, Na
and K, is
(a) K < Na < Li < H (b) Na < Li < K < H
(c) Na < K < H < Li (d) H < Na < Li < K
42. The hybridisation of xenon atom in XeF4 is
can be readily prepared by Friedel-Craft's reaction (a) sp3 (b) dsp 2
between (c) sp3 d 2 (d) d 2sp3
(a) benzene and 2-nitrobenzoyl chloride 43. The formal oxidation numbers of Cr and Cl in the
(b) benzyl chloride and nitrobenzene ions Cr/�- and Cl03 , respectively are
(c) nitrobenzene and benzoyl chloride
(d) benzene and 2-nitrobenzyl chloride (a) + 6 and +7 (b) +7 and +5
(c) +6 and +5 (d) +S and +7
WWW.JEEBOOKS.INl
44. A filter paper soaked in salt X turns brown when 53. Which one of the following proteins does not play a
exposed to HN03 vapor. The salt X is role in skeletal muscle contraction?
(a) KCl (b) KBr (c) KI (d) K2S04 (a) Actin (b) Myosin
45. The role of haemoglobin is to (c) Troponin (d) Microtubule
(a) store oxygen in muscles 54. Which one of the following reactions is catalysed by
(b) transport oxygen to different parts of the body high-energy ultraviolet radiation in the stratosphere?
(c) convert CO to CO2 (a) 02 + 0 ---t 03 (b) 02 ---t O + 0
(d) convert CO2 into carbonic acid (c) 03 + 03 ---t 302 (d) O + 0 ----t 02
BIOLOGY
55. Which one of the following statements is true about
trypsinogen?
(a) It is activated by enterokinase
46. Which one of the following molecules is a secondary (b) It is activated by renin
metabolite?
(a) Ethanol (b) Lactate (c) It is activated by pepsin
(c) Penicillin (d) Citric acid (d) It does not need activation
47. Lecithin is a 56. Which one of the following organisms respires
(a) carbohydrate (b) phospholipid through the skin?
(c) nucleoside (d) protein (a) Blue whale (b) Salamander
(c) Platypus (d) Peacock
48. The water potential ('JI p) of pure water at standard
temperature and atmospheric pressure is 57. Which one of the following human cells lacks a
(a) 0 (b) 0.5 (c) 1.0 (d) 2.0 nucleus?
(a) Neutrophil (b) Neuron
49. Action potential in neurons is generated by a rapid
(c) Mature erythrocyte (d) Keratinocyte
influx of
(a) chloride ions (b) potassium ions 58. The first enzyme that the food encounters in human
(c) calcium ions (d) sodium ions digestive system is
(a) pepsin (b) trypsin
50. Erythropoietin is produced by
(a) heart (b) kidney (c) chymotrypsin (d) amylase
(c) bone marrow (d) adrenal gland 59. Glycoproteins are formed in which one of the
51. Tendrils are modifications of following organelles?
(a) stem or leaf (b) stem only (a) Peroxisome (b) Lysosome
(c) leaf only (d) aerial roots only (c) Golgi apparatus (d) Mitochondria
52. Which one of the following combinations of 60. An example of nastic movement (external
biomolecules is present in the ribosomes? stimulus-dependent movement) in plants is
(a) RNA, DNA and protein (a) folding up of the leaves of Mimosa pudica
(b) RNA, lipids and DNA (b) climbing of tendrils
(c) RNA and protein (c) growth of roots from seeds
(d) RNA and DNA (d) growth of pollen tube towards the ovule

MATHEMATICS (b) 12 (c) 15
61. What is the sum of all natural numbers n such that
(a) 9 (d) 18
63. The number of solid cones with integer radius and
the product of the digits of n (in base 10) is equal to integer height each having its volume numerically
n2 - lOn - 36? equal to its total surface area is
(a) 12 (b) 13 (c) 124 (d) 2612 (a) 0 (b) 1 (c) 2 (d) infinite
62. Let m (respectively, n) be the number of 5-digit 64. Let ABCD be a square. An arc of a circle with A as
integers obtained by using the digits 1, 2, 3, 4, 5 with centre and AB as radius is drawn inside the square
repetitions (respectively, without repetitions) such joining the points B and D. Points P on AB, S on
m.
that the sum of any two adjacent digits is odd. Then AD, Q and R on arc BD are taken such that PQRS is
- 1s equa1 to
n
a square.
WWW.JEEBOOKS.INl
Further suppose that PQ and RS are parallel to AC.

area PQRS .
Then, ----- 1s
area ABCD
(a) -1 (b) � (c) -1 (d) �
8 5 4 5
65. Suppose ABCD is a trapezium whose sides and
height are integers and AB is parallel to CD. If the
area ofABCD is 12 and the sides are distinct, then
I AB - CDI
(a) is 2
CHEMISTRY
(b) is 4
(c) is 8
(d) cannot be determined from the data 7 1 . Among the following, the species with identical bond
PHYSICS
order are
(a) CO and ot (b) 02 and CO
(c)ot and B2 (d) CO and N;
66. A coffee maker makes coffee by passing steam
72. The quantity of heat (in J) required to raise the
through a mixture ofcoffee powder, milk and water.
temperature of 1.0 kg of ethanol from 293.45 K to the
If the steam is mixed at the rate of 50 g per minute in boiling point and then change the liquid to vapor at
a mug containing 500 g of mixture, then it takes that temperature is closest to
about t0 seconds to make coffee at 70° C when the [Given, boiling point of ethanol 351.45 K. Specific
initial temperature of the mixture is 25° C. The value heat capacity ofliquid ethanol 2.44 J g-1K -1 . Latent
of t0 is close to (ratio of latent heat of evaporation to heat of vaporisation of ethanol 855 J g-1]
(a) 142 X 102 (b) 9.97 X 102
specific heat of water is 540°C and specific heat of the
mixture can be taken to be the same as that of water) (c) 142 x Hf (d) 9.97 x Hf
(a) 30 (b) 45 (c) 60 (d) 90
73. A solution of 20.2 g of 1,2-dibromopropane in MeOH
67. A person in front of a mountain is beating a drum at upon heating with excess Zn produces 3.58 g of an
the rate of 40 per minute and hears no distinct echo. unsaturated compound X. The yield (%) ofX is closest
If the person moves 90 m closer to the mountain, he to [Atomic weight of Br is 80.]
has to beat the drum at 60 per minute to not hear (a) 18 (b) 85 (c) 89 (d) 30
any distinct echo. The speed of sound is
(a) 320 ms-1 (b) 340 ms-1 (c) 360 ms-1 (d) 380 ms-1 74. The lower stability of ethyl anion compared to methyl
anion and the higher stability of ethyl radical
68. A glass beaker is filled with water up to 5 cm. It is compared to methyl radical, respectively, are due to
kept on top of a 2 cm thick glass slab. When a coin at
(a) +I-effect of the methyl group in ethyl anion
the bottom of the glass slab is viewed at the normal
cr ➔ p-orbital conjugation in ethyl radical
incidence from above the beaker, its apparent depth
from the water surface is d cm. Value of d is close to (b) - I-effect of the methyl group in ethyl anion and
(the refractive indices of water and glass are 1.33 and cr ➔ cr * conjugation in ethyl radical
1.5, respectively) (c) + I effect of the methyl group in both cases
(a) 2.5 cm (b) 5.1 cm (c) 3.7 cm (d) 6.0 cm (d) + I- effect of the methyl group in ethyl anion and
69. A proton of mass m and charge e is projected from a cr ➔ cr * conjugation in ethyl radical
very large distance towards an a-particle with 75. The F-Br-F bond angles in BrF5 and the Cl-P-Cl bond
velocity v. Initially a-particle is at rest, but it is free angles in PC1t;, respectively, are
to move. If gravity is neglected, then the minimum (a) identical in BrF;; but non-identical in PC15
separation along the straight line of their motion will (b) identical in BrF;; and identical in PC],,
be (c) non-identical in BrF;; but identical in PC15
(a) e2t4ne0 mv2 (b) 5e2t4ne0 mv2 (d) non-identical in BrF;; and non-identical in PC15
(c) 2e2t4ne0 m v (d) 4e2/4ne0 mv2
BIOLOGY
2
70. A potential is given by V (x) = k(x + a )2 / 2 for x < 0 and

V(x) = k(x - a)2 / 2 for x > 0. The schematic variation of 76. If the genotypes determining the blood groups of a
oscillation period T for a particle performing periodic couple are rA r° and rA rB then the probability of their
'
motion in this potential as a function of its energy E first child having type Oblood is
lS (a) O (b) 0.25 (c) 0.50 (d) 0. 75
WWW.JEEBOOKS.INl
77. A cross was carried out between two individuals Column I Column II Column III
heterozygous for two pairs of genes was carried out. P. Hypermetropia (i) Near-sightedness a. Convex lens
Assuming segregation and independent assortment,
the number of different genotypes and phenotypes Q. Myopia (ii) Far-sightedness b. Concave
obtained respectively would be lens
(a) 4 and 9 (b) 6 and 3 (a) P-ii-b (b) Q-i-b
(c) 9 and 4 (d) 1 1 and 4 (c) P-i-a (d) Q-i-a
78. If the H+ concentration of an aqueous solution is 80. Which one of the following properties causes the
0.001 M, then the pOH of the solution would be plant tendrils to coil around a bamboo stick?
(a) 0.001 (b) 0.999 (c) 3 (d) 1 1 (a) Tendril has spines
79. Consider the following vision defects listed in (b) The base of the tendril grows faster than the tip
Columns I and II and the corrective measures in (c) Part of the tendril in contact with the bamboo stick
Column III. Choose the correct combination. grows at a slower rate than the part away from it.
(d) The tip of the tendril grows faster than the base
Answers
PART-/
(d) 2 (b) 3 (c) 4 (b) 5 (a) 6 (b) 7 (c) 8 (c) 9 (c) 10 (a)
11 (c) 12 (d) 13 (b) 14 (a) 15 (a) 16 (a) 17 (c) 18 (d) 19 (c) 20 (d)
21 (a) 22 (b) 23 (d) 24 (a) 25 (d) 26 (b) 27 (*) 28 (c) 29 (d) 30 (a)
31 (a) 32 (a) 33 (d) 34 (b) 35 (d) 36 (a) 37 (c) 38 (b) 39 (a) 40 (d)
41 (a) 42 (c) 43 (c) 44 (c) 45 (b) 46 (c) 47 (b) 48 (a) 49 (d) 50 (b)
51 (a) 52 (c) 53 (d) 54 (b) 55 (a) 56 (b) 57 (c) 58 (d) 59 (c) 60 (a)
PART-I/
61 (b) 62 (c) 63 (b) 64 (d) 65 (b) 66 (b) 67 (c) 68 (b) 69 (b) 70 (b)
71 (c) 72 (d) 73 (b) 74 (a) 75 (d) 76 (a) 77 (c) 78 (d) 79 (b) 80 (c)
* No options are correct.
Solutions
1 . (d) We have, 2. (b) Given,
a4 + b4 < 1 and a2 + b2 > 1 x4 - x2 + 2x - 1 = 0 = - (m - n)
The graph of x2 + y2 = l and x4 + y4 = 1 ⇒ x4 - (x - 1)2 = 0 ⇒ 2a + (m + n - l) d = - 2 [m ;c n]
are 2
⇒ (x - x + 1) (x2 + x - 1) = 0 m+ n
y S:,, + n = - - (2a + (m + n - l) d)
⇒ 2
x4+y4=1 or x2 + x - 1 = 0 m+ n
= (- 2) = - (m + n)
2
⇒ x - x + 1 = 0 has no real roots. 2
⇒ x2 + x - 1 = 0 has two real roots 4. (b) (I) Any pair of consistent linear
3. (c) Given, Sm = n and Sn = m equation in two variables must have a
Sm � [2a + (m - l)d] = n
unique solution. This statement is false.
= ... (i) Consistent equation may have unique or
2
Sn = !!'. (2a + (n - l) d) = m ... (ii)
infinite solution.
2 (II) There do not exists two consecutive
Y' integers the sum of whose square is 365.
On subtracting Eq. (ii) from Eq. (i), we get
(m - n) a + (m - n) (m + n - 1) !{_
Clearly from graph. This statement is also false
There are many positive real number 2 132 + 142 = 365.
(a, b) satisfying a4 + b4 < l and a2 + b2 > 1
WWW.JEEBOOKS.INl
5. (a) Let and volume of hemisphere = � rcr3 OG 2 + GM2 = QM2

P(x) = anxn + an _ lxn - 1 + an rn - 2 + ... 3 LQGM = 90°
-
+ �x + a0 :. Volume of solid = rcr 2h + � rcr3 9. (c) Let MBC
3
a0 , � , a2 . • • E l When height of cylinder is doubled, then BC = a
Given, P(2) = 2 and P(4) = 5 volume of solid = 2rcr 2h + � rcr3 AC = b
2 = an 2n + an 1 2n - 1 + an 2 2n - 2 + ... 3 AB = c
- -
V2 = � = a
+ � 2 + a0 . . . (i) 2rcr 2h + � rcr3 A
n l
n
5 = an 4 + an _ l 4 - + an_ 2 4n - 2 + ....
V1 2 rcr 2h + � rcr3
+ 4� + a0 • • • (ii) 3
On subtracting Eq. (i) from Eq. (ii), we get 2h + � r
3 3 h r
h + �r 2
3 = an (4n - 2n ) + an 1 (4n - 1 - 2n - l ) ⇒ ⇒- = -
2 3
-
+ ... + 2� 3 B D C
Clearly, LHS is odd number and RHS is When the radius is doubled, then volume and median of MBC
even number. . = 4rcr 2h + - 16 rcr -
3
of sohd AD = l
:. No polynomials exists.
6. (b) Four digits number which is
3 BE = m
hl
16 CF = n
v 4h + ---;-- r
= 6I
divisible by 7 are 1001, 1008, 1015, .... , ; 4h + 8h
L·:
r
-= = = AD is median,
9996. h + £'r h + h 3 2J AD <
AB + BC
Hence, total number of such numbers 3 2
= 1286 Hence, volume is increased by 500%. b+ C
( � Yh
l<
8. (c) In M'QR 2
observation a+ b a+ c
Given, QR2 + PR2 = 5PQ 2 Similarly, m< - - and n < - -
Median PM and QN intersect of G.
N Yh
+ ( + 1 observation
Median = - � 2- � ----- p
2
l+ m+ n < a+ b+ c
2
l+ m+ n . . . (i)
2 ⇒ <l
a+ b+c
[·: N is even]
th Also in Af3GC, BG + GC > BC
1286 . 2
(- ) observation - (m + n) > a
2 3
th
r r
1286 . Q M R Similarly, � (n + l) > b and � (m + l) > c
+ (-- + 1) observation 2 1 3 3
Median = -� - 2 - � ---- QG = -QN, GM = -PM 4
2 3 3 - (l + m + n) > a + b + c
3
643th + 644th ⇒ QG 2 + GM2 = rn QN + (½ PM l + m + n > 3
2 ⇒ - - - . . . (ii)
a+ b+ c 4
(1001+ (642)7) + (1001) + (643)7)
= = '!_ QN 2 + "I_ pM2 From Eqs. (i) and (ii), we get
2 9 9
l+ m+ n
2 (1001) + 7 (642 + 643) 2PQ + �R _ PR
2 2 2 E ( � , l)
2 = i( ) a+ b+ c 4
+ i( 2PQ + �R
2 (1001) + 7 (1285) 1 0. (a) Let P(x0 , y0 )
2 2 _ QR2
2 ) Given x2 + y2 � 1
= 100 1 + 4497.5= 5498.5
7. (c) Let the height and radius of
Let any arbitrary point 8(x, y).
8PQ 2 + 8QR2 - 4PR2 y
cylinder are h are r, respectively. 1 + 2PQ 2 + 2PR2 - QR2 (0 , 1 )
:. Volume of cylinder = rcr 2h 9 4
X'
(1 , 0) X
h h
Y'
WWW.JEEBOOKS.INl
PQ 2 = (x - .xo)2 + (y - y0 )2 1 4. (a) Given, PQR is an acute angle 1 6. (a) As temperature of water is

PQ 2 = (OP - OQ)2 triangle. increased from 0°C to 10°C, density of
PQ 2 = (OP - OQ)2 PQ < QR water initially increases upto a maximum
PQ 2 = (✓X6 + xg - 1) 2
[·: OQ = l]
at 4°C and then it reduces.
So, buoyant force on block of wood also
:. Mininimum value of PQ 2 is increases till temperature reaches 4°C
<✓X6 + yg - 1)2 and then decreases from 4°C to 10°C.
1 1 . (c) Given, in l'J'QR

Hence, volume of block above water also
increases upto 4° C and then decreases
PQ = 3 p 01 02 03 R from 4°C to 10°C.
Altitude RS = -/3 q :. Variation of V0 versus t as shown below.
⇒ PS = QR LQRP < LQPR Vo
R PQ3 = "I_PR
2
PQ2 : Q2 R = r : p
PQ2 = (- r
) PR
1 7. (c) Fraction of thickness of ice block
r+ P 0°c 4°C 1 0°c
But r< p out of water is
p s Q PQ2 < -PR
1
x = 1 - ( Pice ) = 1 -
0.9 or
x = 0.1
ln 11SQR, QR2 = SR2 + SQ 2 2 Pwater 1
PS2 = (-/3)2 + (QP - PS)2 Comparison between altitude and angle
[·: SQ = PQ - PS] bisector
PS2 = 3 + (3 - PS) 2 LQPQ2 + LPQR + LPQQ2 = LRQQ2
PS2 = 3 + 9 - 6PS + PS2 ⇒ PS = 2 + LQQ2R + LQRQ2
:. LPQQ2 = LRQQ2
In l'J'RS, 0.8 m
[since, QQ2 is angle bisector of LQ]
PR2 = PS2 + RS2 = (2)2 + (-/3)2 = 4 + 3
LQPQ2 + LPQR = LQQ� + LQRQ2
PR = -.fi
:.PQ < QR the LQPQ2 < LQRQ2
1 2. (d) Total number of students = 50
Average marks of student = 47.5
Hence, LQQ? < LQQ� --- - -------
But LQQ? + LQQ� = 180° So, minimum length of rope required =
:. Total marks of students Hence, LQQ? < 90° and LQQ� > 90° thickness of ice x 0.1= 8 x 0.1 = 0.8 m.
= 50 X 47.5 = 2375 ·: Foot from Q to side PR lie inside !'J'QQ2 Hence, nearest option is 0.9 m.
Now, the student get integer marks PQl < PQ2 < PQ3
⇒ 1 8. (d) When box with hole is in free fall,
Hence, the maximum number of students both water and box cover equal distance
1 5. (a) Given, (a - 8)2 - (b - 7) 2 = 5
we will divide total mark by 48. downwards in equal time.
2375 ⇒ (a - 8 + b - 7) (a - 8 - b + 7) = 5
= 49 Hence, no water comes out of hole in free
48 ⇒ (a + b - 15) (a - b - 1) = 5
fall of box.
1 9. (c) Water evaporated in two hours
1 3. (b) Given number, There are four case
a + b - 15 = 5; a - b - 1 = 1 . . . (i)
n = 152 X 518 = m = 2 h x 20 g/h
a + b - 15 = l; a - b - 1 = 5 ... (ii)
n = 32 X 52 X 518 = 40 g = 40 x 10-3 kg
a + b - 15 = - 5; a - b - 1 = - 1 . . . (iii)
n = 9 X 520
a + b - 15 = - l; a - b - 1 = - 5 ... (iv) Heat absorbed by water during
Taking log base 10 both side evaporation is
20
On solving, we get
log10 n = log10 9 + log10 5 Q = Mass evaporated x Latent heat
(i) a = 1 1, b = 9 (ii) a = 1 1, b = 5
= 2log10 3 + 20log10 5 Q = mL . . . (i)
(iii) a = 5, b = 5 (iv) a = 5, b = 9
= 2 X 0.4771 + 20 X (1 - 0.3010) Assuming this heat is taken entirely from
0(1 1 , 5) 4 C(1 1 , 5) water in earthen pot, if 11T is decrease of
= 14 characters value
temperature of pot then,
Hence, the number have 15 digits
Q = Msl1T . . . (ii)
S = Sum of digits of the number
6 6 where, M = mass of water in pot
Now, n has last digit is 5.
and s = specific heat of water.
:. Minimum value of S = 1 + 5 = 6
Equating Eqs. (i) and (ii), we get
Maximum value of S = 9 x 14 + 5
A(5, 5) 4 8(5, 5) mL = Msl1T
= 126 + 5 = 13 1
:. Perimeter = 2(4 + 6) = 20 or l1T = -m -
X L=- 40 x 10-3 x 540 = 5.40C
: . 6 '.,'.; 8 < 140 - -
M s 4
WWW.JEEBOOKS.INl
20. (d) As emergent ray i s parallel to 24. (a) A lunar eclipse occurs only on a 27. (No option is matching)
incident ray, deviation angle is 180°. o full moon day. In late afternoon rainbow is visible in
But o = 360°- 20 So, option (a) is incorrect. east side when light of sun in west side is
25. (d) Intensity of radiation (mainly
where, 0 = angle between inclined reflected and refracted by a layer of water
mirrors. droplets.
visible light) emitted from surface of a
Rainbow is circular because locous of
star is proportional to its area.
reflected rays reaching eye of observer is
So, I oc A or I =
kA a circle. Its roundness is not due to
where, k = constant. roundness of earth.
There is no rainbow on moon due to lack
krc (100 R) k re R x 10000
Now, if 10 = intensity of parent star.
=
2
=
2 of atmosphere.
Then, 10
In case of a primary rainbow, violet
° =
° When exoplanet is in front of star, colour is on inside and red colour is on
So, 360 - 20 180
observed intensity will be minimum. Let outside of arc.
20 = 180° ⇒ 0 = 90°
2 1 . (a) From principle of thermometry,
or
intensity minimum is /min then In case of a secondary rainbow, red colour
- re R2]
'
2
is on inside and violet colour is on outside
=
T -� .�
TLF,P /min k [rc (100 R)
- - _ a constant for every
= of arc.
TuFP - TLFP
thermometric scale. Star radius
1 00 R
Now, for any temperature L on a
thermometer designed with given liquid Exoplanet
and equivalent temperature C on radius R
centigrade scale, we have
R V
Imin krcR2 (10000 - 1)
L - TLFP C - TLFP
-(
( )
l;:,;1:f ) ⇒ =
krcR2 X 9999
TUFP - TLFP TUFP - TLFP Centigrade
scale
scale =
L - (- 50) C - 0-
krcR2 X 9999
lo - krcR2 x 10000
⇒ - - - /min
C
So, -
150 - (- 50) 100 - 0
___,, East
L + 50
⇒ =
10 0.9999 West .------
/min X
26. (b) When current flows through a

150 + 50 100
So, none of the option is correct. Option
⇒ L + 50 = 2C (b) is correct, if only secondary rainbow is
Now at 0°L, centigrade scale reading will conductor of tapered cross-section,
28. (c) Consider the given diagram,

considered.
be current flow through every section
0 + 50 2 C or C
5 remains constant.
= o 25° L = =
Screen
2
I I
° � I A1
and at 100 L, centigrade scale reading
I
= 12
will be
100 + 50 2 C or C
= kA-2
150
=
75° L = =
⇒ 11
2
22. (b) An alpha-volt (a-V ) is the energy
⇒ AA1
A_ =
A2
⇒ <l
acquired by an a-particle (charge 2e j2 Al
units) when accelerated by a potential ⇒ j2 A<
1 a- V = q (dV )
difference of 1 V. Current density increases in the narrow
j = nevd
region.
= 2e x lV = 2 eV Assuming area observed and screen both
23. (d) If Q is charge contained in L
Also,
⇒ nevd < nevd circular, we have
1 2
di
h
d2 d
length of beam of area A, then ⇒ vd < vd =
01 0 2 ⇒ ⇒ 2 "!!_
= =
=
1
Drift velocity increases in the narrow

2
f di f
LxA xp Q
di
. E and d2 diameter of area on earth.
where, = diameter of camera screen
region.
I
where, p = charge density of beam. =
So, p=
Q = Q!t and J= - area observed on earth A0
p Now =
L x A Llt x A v x A ' area of screen A

where, p = resistivity of material.
500 x 10-6
⇒ °Ei < 2 ⇒ < E2
E
°Ei
3 X 107 X 150 X 10-6 p p
5
= __ X 10-5 = 1.1 X 10-5 Cm-3 Electric field magnitude increases in the
3 X 1.5 narrow region.
WWW.JEEBOOKS.INl
⇒
�
=
u�
r
= (5
�i::i:
3
2 r
= (10 x lo'3 x 102)2 = (106 )2 = 1 d-2

29. (d) A cylindrical lens produces erect
Solubility (in mol/L) x Molecular weight
= 233 X 10-5 = 2. 3 X 10-3
34. (b) Consider the following statements.
(I) According to Pauli's exclusion
Here, the marked carbon (*) is chiral as
it has 4 different groups attached to it.
/ 'y
CH 3
j
CH 2
'
CH
2
CH 3
principle, no two electrons in an atom can Br
and laterally inverted image.
□
have the same set of four quantum
So, image appears as shown below. numbers. y
Thus, statement (a) is correct. Here, the marked carbon (*) is achiral
(II) The maximum number of electrons in as it has 2 similar ethyl group attached
the shell with principle quantum number, to it.
38. (b)
n= 2n 2•
Thus, statement (b) is incorrect. o
30. (a) For the ball, we have (III) Electrons in an orbital must have CH3
u = 45 ms-i , g = - 10 ms-2
. spin, . m = + -1 and -
. 1.e. -1. Thus, b/"----._ c /
opposite N N
Now using, v2 - u 2 = 2gh, we have
8
2 2 H H
v2 = (45) 2 - 20h
statement (c) is correct. N
H
v = ,J2025 - 20h
(IV) According to Aufbau principle, in the
⇒ ground state of the atoms, the orbitals are In the given compound most acidic
At v = O' h =
2025 = 101 m filled in order of their increasing energies. proton will be N b - H This is because
20 Thus, statement (d) is correct.
at h = 0, v = 45 ms-i 35. (d) From ideal gas equation
its conjugate base will get resonance
pV = nRT
stabilised and the most nucleophilic
v-h graph must be negative at all points.

As velocity decreases with height, slope of nitrogen will be Ne . This is because the
maximum number of moles in container,
is localised over sp3 -hybrid orbital.
lone pair of electrons present on this N
n = pV =
Hence, correct graph is (a).
3 1 . (a) Given, density of water = 10 g mL-i 39. (a) The reaction between
2 x 2.24
RT 0.082 1 x 298
volume of water = 250 mL. haloalkane and AgNO3 gives
= o.18 moles
:. Mass of water = density x volume carbocation intermediate. So, more
Maximum weight of N 2 in container
= lO x 250= 250 g = 0.183 X 28 = 5.127 g easily it will be formed, more readily it
18 g of water contains At 5.127 g exploding can occur. Thus, it will react to give precipitate.
= 6.023 x 1023 molecules must be less than 5. 127. Thus, the In the given compound
:. 250 g of water contains maximum amount of nitrogen that can be 8
safely put in this container at 298 Cl C(
l _J+
6.023 X 1023 temperature and exert pressure less than
X 250 Cl Cl
b Cl � Cl b
18 2 atm will be closest to 4.2 g.
36. (a)
n AgN03
= 83.65 x 1023 molecules
0
32. (a) Dil.aqueous solution of NHa is
51,c,
8 +
0 Cl 0
NH4 OH .
NH4 OH � NH! + Off
+ 1
c(
On adding solid ammonium chloride Benzene 2· nitrobenzoylchloride
CI CI'
NH4 Cl ---t NH! + er D
The reaction moves backward due to
common ion effect. The concentration of 0
+
Off decreases and hence the pH
decreases. Cl a is easily lost from this compound
33. (d) Given, K,,p = 1 x 10-10 and carbocation formation takes place
s s
readily. This is because this Cla is
BaSO � Ba2+ + SO'.i" This reaction is Friedal-Craft acylation. In
4 closest to electronegative atom 0, which
Let the solubity of Ba 2+ and so;- be S

this reaction, benzene reacts with acyl will attract the electron density towards
halide or acid anhydride in the presence itself and readily leaves C -Cla bond.
Ksp = s2 of Lewis acid like AlC1s to yield Hence, it will most readily react with
acylbenzene.
37. (c)
l x l0-10 = S2 AgNO3 to give precipitate.
40. (d) The specie which follows
{%:
2�CH 3
CH 2 CH
S = 10-5 mol/L
CH ; CH2
Thus, solubility of BaSO 4 in pure water H
Huckel's rule (4n + 2)1t will be most
X
Br stable species.
(in g/L)
WWW.JEEBOOKS.INl
strongest reducing agent. Thus, salt X

Among the given salt, KI is the experiences low oxygen level. The
½ + 2N02 + 2KN03
OJ and resulting rise in red-blood cells increases
is KI. the oxygen carrying capacity of the blood.
(a)
2KI + 4HN03 ----t 5 1 . (a) Tendrils are the modifications of
It has Site-s, doesn't
follow Huckel's rule stem or leaf. The tendril is a thread-like,
+ 2H20
45. (b) The role of haemoglobin is to
twisting, clinging growth on the vines of
the plant that enables it to attach itself to
(b) � another object or another plant for
transport oxygen from lungs or gills to
different parts of the body. There it support. Plants such as grapes, peas and
It has Site-s, doesn't It has 21te-s,
L
52. (c) Ribosomes consist of two
cucumbers have tendrils.
follow Huckel's rule follows Huckel's rule releases the oxygen to permit aerobic
respirisation to provide energy to
power the functions of the organism in biomolecules (i.e. RNA and proteins).
c OJ The small ribosomal subunits which read
the process called metabolism.
46. (c) Penicillin is a secondary
( ) the RNA, and large subunits which join
It has l01te s, follows It has 41te-s, doesn't amino acids to form a polypeptide chain.
Huckel's rule follow Huckel's rule metabolite. Secondary metabolites are Each subunit comprises one or more
organic compounds produced by ribosomal RNA (rRNA) molecules and a
53. (d) Microtubule does not play a role

bacteria, fungi or plants which are not variety of ribosomal proteins (r -protein).
(
directly involved in the normal growth,
� OJ
It has l01te-s, follows It has 21te-s, follows development or reproduction of the in skeletal muscle. Microtubules are
Huckel's rule Huckel's rule organism, e.g., antibiotics like hollow fibrous shafts whose main
As both the species in option (d) follow penicillin, streptomycin, etc. Rest function is to help support and give shape
Huckel's rule. Thus, it is correct option. to the cell. They also serve a
4 1 . (a) As the atomic number increases,

molecules like ethanol, lactate and
transportation function as they are the
citric acid are primary metabolites.
47. (b) Lecithin is a phospholipid that
routes upon which organelles move
the energy of orbital decreases. This is
54. (b) In the stratosphere, ozone is
through the cell.
because the atomic radii decreases (nuclear is important in cell structure and
charge increases) with increase in atomic metabolism. Lecithins are composed of created primarily by ultraviolet
number. The atomic number ofH, Li, Na phosphoric acid, cholines, esters of radiation. When high energy ultraviolet
and K respectively, are 1, 3, 11 and 19. glycerol and two fatty acids; the chain rays strike ordinary oxygen molecules
Thus, the correct order of energy of length, position and degree of (02 ), they split the molecule into two
2s-orbitals is unsaturation of these fatty acids vary single oxygen atoms, known as atomic
K < Na < Li < H.
42. (c) The hybridisation of any compound
and this variation results in different oxygen.
lecithins with different biological 02 ➔ 0 + 0
functions.
X = I_ 48. (a) Pure water at standard

can be calculated as, A freed oxygen then combines with
[Valence electrons another oxygen molecule to form a
2 temperature and atmospheric pressure molecule of ozone (03 ).
+ Number of monoatomic + Anion/cations] has a water potential of zero. As solute
55. (a) Trypsinogen is an inactive
1 is added, its value becomes more
:. For XeF4 (X) = - (8 + 4 - 0) = 6 substance secreted by the pancreas, from
43. (c) In Cr20f,

negative. This causes water potential
:. The hybridisation is sp3 d •
2 which the digestive enzyme trypsin is
2 to decrease. Water potential is the
formed in the duodenum. Trypsinogen is
measure of the potential energy in
converted into its active form trypsin by
'I' (Psi) and is expressed in units of

water. It is denoted by the Greek letter
an enzyme enterokinase. This results in
2(x) + 7(-2) = - 2
Let the oxidation state of Cr be x the subsequent activation of pancreatic
pressure (pressure is a form of energy)
digestive enzymes.
56. (b) Salamanders are a group of
called Mega Pascals (MPa).
49. (d) An action potential is
2x - 14 = - 2
2x = 12
In C103 ,
amphibians typically characterised by a
generated by the rapid influx of
X= + 6 + lizard-like appearance with slender
Na ions followed by a slightly slower
+ bodies, blunt snouts, short limbs and a
efflux of K ions. The action potential
tail. Salamanders breath through their
=-1
Let the oxidation state of Cl be x is the mechanism by which nerve cells
skin and the thin membranes in the
l(x) +3(-2) communicate and conduct information
mouth and throat.
57. (c) Mature human erythrocytes (Red
x- 6= - 1 and muscle cells are induced to
x=+5 contract.
44. (c) As, a filter paper soaked in salt X 50. (b) Erythropoietin (EP0) is a
blood cells) lack a nucleus. The absence of
a nucleus is an adaptation of the red
hormone produced by the kidney that
vapour, then salt X must be a strong
turns brown when exposed to HN03 blood cell for its role. It allows the REC to
promotes the formation of red blood
contain more haemoglobin and therefore
cells by the bone marrow. Chemically,
reducing agent which will reduce HN03 to carry more oxygen molecules. It also
erythropoietin is a protein with an
N02 (brown gas). attached sugar (a glycoprotein). It is allows the cell to have its distinctive
produced by kidney cells when the body biconcave shape which aids diffusion.
WWW.JEEBOOKS.INl
58. (d) The first enzyme that the food 3, 4, 5 without repetitions such that sum 64. (d) Given, ABCD is a square.
encounters in the digestive system is of any two adjacent digits is odd.
amylase. Digestion begins in the mouth Sum of two digits are odd if one is even
with the secretion of saliva and its and other is odd.
digestive enzymes. Saliva contains the Even = 2, 4
digestive enzyme amylase, which works
Odd = 1, 3, 5
on carbohydrate, starch like breads,
potatoes or pasta to help break them Case I Digit is repeated.
down into simple sugars. Two possibilities
59. (c) Glycoproteins are formed in the (a) odd even odd even odd
Golgi apparatus of the cell. = 3 X 2 X 3 X 2 X 3 = 108
Glycoproteins are proteins that contain (b) even odd even odd even
covalently attached sugar residues. LCAP = LMAP = 45°
Glycoproteins are present at the surface = 2 X 3 X 2 X 3 X 2 = 72
of cells where they function as membrane m = 108 + 72 = 180 AM = MP = QN
proteins and play a role in cell to cell Case II Digit is not repeated. PQRS is a square,
interactions. MN = PQ = PS
The possibility of arrangement is
60. (a) An example of nastic movement PS = 2PM = 2AM
odd even odd even odd
in plants is folding up of the leaves of AN = AM + MN = 3AM
= 3 X 2 X 2 X 1 X 1 = 12
Mimosa pudica. Nastic movements in In MBQ,
plants are reversible and repeatable n = 12 AQ 2 = AN2 + QN2
movements in response to a stimulus m = 180 = 15 1 = (3AM)2 + AM2 [·: A Q = 1]
whose direction is determined by the n 12
63. (b) Let height and radius of cone is h
10AM2 = 1
anatomy of the plant. The leaves of the AM2 = 1
Mimosa pudica fold up when touched and and r respectively, h, r E I
returns to full leaf in a few minutes. The AM2 = _!__
Given volume of cone = Surface area of 10
leaves of the Mimosa achieve this rapid cone Area of square PQRS = PS2
folding by a change in turgor pressure.
6 1 . (b) Given, n 2 - 10n - 36 .!. 1tr2h = 1trl + 1tr 2 = 4AM2 = __! = �
3 10 5
n is a natural number. Area square PQRS = �
⇒ I nr 2h = nr .Jh 2 + r 2 + nr 2 Area of square ABCD 5
65. (b) We have,
:. Product of its digits is � 0 3
[r "# OJ
:. n 2 - 10n - 36 � 0
-- - ⇒ __!_ rh = .Jh 2 + r 2 + r
10 ± \1 100 + 144 3 ABCD is a trapezium.
n=
2 AB is parallel to CD.
⇒ rh - 3r = 3 .Jh 2 + r 2
n = 5 ± .Jfil Area of trapezium = 12
⇒ r 2h 2 + 9r 2 - 6hr 2 = 9h 2 + 9r 2 D b
n E (- oo, 5 - .Jfil) U (5 + .Jfil, oo) C
But n is positive integer. ⇒ h 2 (r 2 - 9) = 6hr 2
2
n � 13 6r
⇒ h=-
When n is two digits numbers, then r2 - 9 h
h = 6 (�
maximum product = 9 x 9 = 81
⇒
n 2 - 10n - 36 '.,'.; 81 r2 - 9
)
h = 6 + _____15±_
n 2 - 10n - l 1 7 '.,'.; 0 A b E a B
⇒ __!_ x h (AB + CD) = 12
⇒
n E [5 - v'142, 5 + v'142] r2 - 9
n is taken two digit number. 2
h and r are integer.
·: r - 9 is a factor of 54.
24
h
n E [13,17) = 13, 14, 15, 16 2 ⇒ AB + CD =
:. Product of digits = 3, 4, 5, 6
:. r 2 - 9 = ], 2, 3, 6, 9, 18, 27, 54 Sides and height of trapezium are
r 2 = 10, 11, 12, 15, 18, 27, 36, 63
When put n = 13
integer.
:. h is a factor of 24
132 - lO x 13 - 36 = 169 - 166 = 3
h = 1, 2, 3, 4, 6, 8, 12, 24
n = 13 satisfies r = 6 only possible value.
62. (c) We have, m is 5-digits number h = 6 + _____15±_
36 - 9 AB + CD = 24, 12, 8, 6, 4, 3, 2, 1
using digits 1, 2, 3, 4, 5 with repetition
But AB + CD > h
such that sum of two adjacent digit is odd = 6+ 2= 8
and n is 5-digits number using digits 1, 2, AB + CD = 24, 12, 8, 6
r = 6, h = 8
WWW.JEEBOOKS.INl
In Af3EC, So, we have dU

BEC is a right angled triangle.
If - = 0, when x = ± a.
2x 60 dx
:. h must be 3 and 4 d2u
In case I, . . . (i)
V 40
When h = 3, BE = 4, CE = 5
Now, -- = km> 0
2<x - 9o) 60 dx2
In case II, = . . . (ii)
AB + CD = 8
V 60 So, particle is in unstable equilibrium at
AE + BE + AE = 8
Substituting for x from Eq. (i) in Eq. (ii), X = ± a.
2AE = 8 - BE = 8 - 4
we get Hence, particle is unbounded for - a > x
AE = 2
2.x - 180 = V and x > a.
:. AB = 4 + 2 = 6, CD = 2
⇒ � v - 180 = v In region, - a '.,'.; x '.,'.; a, time period of
2
⇒ v = 360 ms-1 particle reduces from a maximum.
68. (b) Apparent depth d in case of more
:. IAB - CDI = 1 6 - 2j = 4
66. (b) Let m gram of steam is condensed
So, correct graph is (b).
than one medium is 7 1 . (c) The bond order can be calculated
= 2 + ...
+
in the process of heating mixture from as
di d
25°C to 70°C. d . . . (i) 1
µ1µ2 B.0 = - (Nb - N )
Then, 2 a
Heat lost by steam = Heat gained by where, di and d2 are the thickness of
slabs of medium with refractive index µ 1 where, Nb = electrons in bonding orbitals
mixture
and µ 2, respectively. Na = electrons in antibonding orbitals.
⇒ Heat of condensation of steam + Heat
given by water formed = Heat gained by Here, di = 5 cm, µ 1 = 133 (a) CO and 0�
mixture d2 = 2 cm, µ 2 = 15 The electronic configuration of CO (14) is
⇒ m - L + ms,,/1T = M- s,,,t,,.T Substituting these values in Eq. (i), erls2 er* ls2 er2s2 er* 2s2 er* 2p; 1t 2p; 1t2p2
y
⇒ mL + mq,, (100 - 70) we get

Apparent depth, d = � + _!
B.O = � (10 - 4) = § = 3
= 500 X q,, X (70 - 25) 2 2
500 X q,, X 45 133 15 The electronic configuration of 0� (18) is
⇒m= = 5.088cm = 5.1cm
69. (b) As a-particle is free to move,
L + 30q,, erls2 er* ls2 er2s2 er* 2s2er2p; 1t2p;
500 x 45 1t2p 2 1t * 2p; 1t* 2p 2
⇒m= initial kinetic energy of system will be
y y
(b) 02 and CO
B.O = � (10 - 8) = 1
(� + 30)
The electronic configuration of 02 (17) is

k; = � µv2 2
2
500 X 45 = g
⇒ m= 40 where, µ = reduced mass of system
(540 + 30) m - 4m
erls2 er* ls2 er2s2 er* 2s2 er2p; 1t2p;
Now, in 1 min, 50 g of steam is m + 4m
condensed. 1t2p; n* 2p; n* 2p�
Now, by energy conservation, we have 1 3
:. 40 g of steam will be condensed in time B.O = - (10 - 7) = - = 1.5
Initial kinetic energy = Potential energy 2 2
to ,
at minimum separation r B.O of CO is 3
to - _ - 40 x 60
- S_
- - 48 S l m . 4m 2 1 2e2 [as calculated in option (a)]
50 ) v =
Nearest answer is 45 s.
2 ( m + 4m 4ne0 · -----;:- (c) B.O of 0� is 1
67. (c) As drummer does not hear any 5e2 [as calculated in option (a)]
⇒ r = ----2 The electronic configuration of B2 (10) is
echo this means time between two 41te0 mv
70. (b) Given, potential function for the
successive wavefronts is equal to time in erls2 er* ls2 er2s2 er* 2s2 1t2p! 1t2p�
which a wavefront reaches back to 1 2
oscillating particle is B.O = - [6 - 4] = - = 1
drummer. 2 2
k(x + a)2 , x < 0
IE--- - - x- - - ----- (d) B.O of CO is 3
V (x) = j 2
a)2
k(x- ----' [as calculated in option (a)]
- - , X> 0 Electronic configuration of � (13) is
2
So, potential energy of the particle (mass erls2 er* ls2 er2s2 er* 2s2 1t2p; 1t2p; er2p;
1
m) is B.O = - [9 - 4] = -5 = 2 .5
km (x + a>2 2 2
, x< 0
2 Thus, option (c) is correct.
72. (d) Given, mass of ethanol = 1 kg
Distance covered by sound = 2x U(x) = j
km(x - a)2
If v = speed of sound, then , x< 0
2
2x · = 1000 g
- = t1me .
mterva 1 b etween two successive dU km(x + a), x < 0
V
={ Latent heat of vaporisation of ethanol
dx km (x - a), x > 0
wavefronts. = 855 Jg-1
WWW.JEEBOOKS.INl
Specific heat capacity of ethanol The geometry of PC15 is triangular Yr YYRr YYrr YyRr Yyrr
= 2.44J I gk-1 pyramidal. yellow yellow yellow yellow
Heat, q = mct.T + heat of vaporisation Cl round wrinkled round wrinkled
= 1000 X 2 .44 (35 1.45 - 293.45) 1 c1
,...,... yR YyRR YyRr yyRR yyRr
CI - P '--
+ 855 x lOOOJ 1 Cl yellow yellow green green
= 9.97 x 10 5 J Cl round round round round
YyRr Yyrr yyRr yyrr
73. (b) The axial bonds suffer more repulsions yr
Br yellow yellow green wrinkled
��
B than equitorial bonds, so they are larger
� round wrinkled round green
Zn
in bond length.
1 , 2-dibromopropane Prop • 1· ene
76. (a) The genotype of child having
The genotypic ratio is 1 : 2 : 1 : 2 : 4 : 2 : 1 :
(X)
2:1
blood group-O with parents having IA I°
Moles of 1, 2-dibromo propane The phenotypic ratio is 9 : 3 : 3 : 1
and IA IB blood groups can be represented
20.2 as :. The number of different genotypes and
= = 0.1 mole
202 phenotypes obtained would be 9 and 4,
Parents IA o A respectively.
3.58
78. (d) The Ir ion concentration of an
Moles of prop-1-ene = �
42
= 0.085 mole aqueous solution is 0.001 M or 1 x 10-3 M
Genotype 1A 1A 1A 1 B 1A 10 1 B 10
0.035 Blood Blood B Blood Blood Since we know that pH = - log[Ir ]
% yield = x 100 = 85%. Phenotype group -A group -A group -A group -B Using this equation, by plugging in the
0.1
74. ((!) The lower stability of ethyl anion
values
Offsprings
(Clla CH2) compared to methyl anion pH = - log 10-3 = - (- 3) log 10 = 3
From the above cross, it is shown that pH = 3
(CH;) is because of + I-effect of methyl
none of the offsprings will be of blood
group of ethyl anion. The higher stability We know that
group-O.
of ethyl radical compared to methyl pOH = 14 - pH = 14 - 3 = 1 1
:. The probability of their first child
radical is due to cr - p-orbital conjugation having type-O blood is zero. pOH = 1 1
which is known as hyper conjugation in
77. (c) In the given question, both 79. (b) Hypermetropia is far
ethyl radical. parents are heterozygous for two pairs of sightedness. A vision condition in which
genes. This means the cross is a dihybrid nearby objects are blurry. It is corrected
cross. by using convex lens.
Lets assume a dihybrid cross Myopia is near sightedness. A condition
in which close objects appear clearly but
Hyper conjugation Pure breeding - Yellow round , Wrinkled green far ones do not. It is corrected using
in ethyl radical traits seeds seeds
75. (d) The geometry ofBrF;; is square
concave lens.
80. (c) The tendrils are sensitive to
(YYRR) (yyrr)
pyramidal. Heterozygous - Yellow round seeds touch. When they come in contact with
trait (YyRr)
F any support, the part of the tendril in
1Gametes contact with the object does not grow
F ¢J F
rapidly as the part of the tendril away
Br @) @ @) ® from the object. This causes the tendril to
circle around the object and thus cling to
F F it. This process is known as positive
thigmotropism. Thigmotropism is the
Here, the lone pair occupies the axial
position and hence axial bonds will suffer
)( YR Yr yR yr directional response of a plant organ to
touch or physical contact with a solid
YYRR YYRr YyRR YyRr object. This differential response is
more repulsion than axial bonds. YR
yellow yellow yellow yellow generally caused by the induction of some
Thus, the axial Br-F bond length will be pattern differential growth.
round round round round
different than equitorial Br-F.
WWW.JEEBOOKS.INl
KVPY
Stream : SA (Nov 19)
MM : 1 00
Instructions
MATHEMATICS on side BC such that MP is parallel to AB. If the area
18
T is a scalene triangle. The number of points A in the
1 . Suppose BC is a given line segment in the plane and of the quadrilateral BNMP is equal to � of the area
of L1ABC, then the ratio AM I MC equals
same order) is similar to triangle T is
plane such that the triangle with vertices A, B, C (in (a) 5 (b) 6
18 15
(c) (d)
2. The number of positive integers n in the set

(a) 4 (b) 6 (c) 12 (d) 24 2
5. Let n ;::>: 4 be a positive integer and let � , 12 , • • • , ln be
5
! has a terminating decimal the lengths of the sides of arbitrary n sided

n
{2, 3, . . . , 200} such that
non-degenerate polygon P. Suppose
=n
expansion is
ii_ + 12 + . . . + 1n - 1 l,,,_
3. If a, b, c are real numbers such that a + b + c = 0 and
(a) 16 (b) 18 (c) 40 (d) 100 +
1 ln �
2 �
a 2 + b2 + c2 = 1, then (3a + 5b - 8c)2 + ( - Sa + 3b + 5c)2
I. The lengths of the sides of P are equal.
Consider the following statements:
II. The angles of P are equal.

+ (5a - 8b + 3c)2 is equal to
(a) 49 (b) 98 III. P is a regular polygon if it is cyclic.
� lfi 00 2W Then,
4. Let ABC be a triangle and M be a point on side AC (a) I is true and I implies II (b) II is true
closer to vertex C than A. Let N be a point on side AB (c) III is false (d) I and III are true
such that MN is parallel to BC and let P be a point
WWW.JEEBOOKS.INl
14. The least value of a natural number n such that

I. n2 + 3 is never divisible by 17. n!
6. Consider the following statements: For any integer n,
II. n2 + 4 is never divisible by 17.

n-1 n-1 n n
( )+( ) < ( ), where ( ) = , is
5 6 7 r (n - r) ! r !
Then, (a) 12 (b) 13
(a) both I and II are true (b) both I and II are false (c) 14 (d) 15
7. Let S be the set of all ordered pairs (x, y) of positive

(c) I is false and II is true (d) I is true and II is false
:ti/o and the average marks of girls is y% with x ,t. y. If
15. In a Mathematics test, the average marks of boys is
integers, with HCF (x, y) = 16 and LCM (x, y) = 48000. the average marks of all students is z%, the ratio of
The number of elements in S is the number of girls to the total number of students is
8. Consider the set A of natural numbers n whose units

Z- X
(a) 4 (b) 8 (c) 16 (d) 32 (a) (b) z - y
y-x y-x
digit is non-zero, such that if this units digit is z+ x
(c) z + y (d)
erased, then the resulting number divides n. If K is y-x y-x
the number of elements in the set A, then
PHYSICS
(a) K is infinite (b) K is infinite but K > 100
(c) 25 '.,'.; K '.,'.; 10 (d) K < 25
9. There are exactly twelve Sundays in the period from 16. Particles used in the Rutherford's scattering
January 1 to March 31 in a certain year. Then, the experiment to deduce the structure of atoms
day corresponding to February 15 in that year is (a) had atomic number 2 and were fully ionised
(a) Tuesday (b) Wednesday (b) had atomic number 2 and were neutral
(c) Thursday (c) had atomic number 4 and were fully ionised
(d) not possible to determine from the given data (d) had atomic number 4 and were neutral
10. Consider a three-digit number with the following 17. The number of completely filled shells for the
properties: element 1 6S32 is
I. If its digits in units place and tens place are
interchanged, the number increases by 36; (a) 1 (b) 2
II. If its digits in units place and hundreds place (c) 3 (d) 4
are interchanged, the number decreases by 198. 18. In an experiment on simple pendulum to determine
Now, suppose that the digits in tens place and the acceleration due to gravity, a student measures
hundreds place are interchanged. Then, the number the length of the thread as 63.2 cm and diameter of
(a) increases by 180 (b) decreases by 270 the pendulum bob as 2.256 cm. The student should
(c) increases by 360 (d) decreases by 540 take the length of the pendulum to be
11. Consider four triangles having sides (5, 12, 9), (5, 12, (a) 64.328 cm (b) 64.3 cm
1 1), (5, 12, 13) and (5, 12, 15). Among these, the (c) 65.456 cm (d) 65.5 cm
triangle having maximum area has sides. 19. A uniform metallic wire of length L is mounted in
(a) (5, 12, 9) (b) (5, 12, 1 1) two configurations. In configuration 1 (triangle), it is
(c) (5, 12, 13) (d) (5, 12, 15) an equilateral triangle and a voltage V is applied to
12. In a classroom, one-fifth of the boys leave the class corners A and B. In configuration 2 (circle), it is bent
at diametrically opposite points P and Q. The ratio of

and the ratio of the remaining boys to girls is 2 : 3. in the form of a circle and the potential V is applied
If further 44 girls leave the class, then class the ratio
of boys to girls is 5 : 2. How many more boys should the power dissipated in configuration 1 to
leave the class so that the number of boys equals that configuration 2 is
of girls?
(a) 16 (b) 24 (c) 30 (d) 36
13. Let X, Y, Z be respectively the areas of a regular
pentagon, regular hexagon and regular heptagon
(a) 2/3 (b) 9/8 (c) 5/4 (d) 7/8
which are inscribed in a circle of radius 1. Then,
20. Six objects are placed at the vertices of a regular
(a) !!__ < � < � and X < Y < Z
5 6 7 hexagon. The geometric centre of the hexagon is at the
origin with objects 1 and 4 on the X-axis (see figure).
The mass of the kth object is mk = ki M I cos0k I , where
(b) !!__ < � < � and X > Y > Z
5 6 7
(c) !!__ > � > � and X > Y > Z i is an integer, M is a constant with dimension of
5 6 7 mass and 0k is the angular position of the k th vertex
=
(d) !!__ > K_ > � and X < Y < Z measured from the positive X-axis in the
�
ww-w
� .J�
E�E�
B�O�
O�K�
S�.l�
5 6 7 counter-clockwise sense.
Nl
24. Two students P and Q perform an experiment to

vanishes, the value of i is verify Ohm's law for a conductor with resistance R.
I f the net gravitational force o n a body at the centroid
3 2 They use a current source and a voltmeter with least

counts of 0.1 mA and 0.1 mV, respectively. The plots
,(5> , current I for both are shown below.

of the variation of voltage drop V across R with
12
10 y
I
5 6 8 I
>T �
(a) 0 (b) 1 (c) 2 (d) 3 6
I
21 . A mirror is placed at an angle of 30° with respect to I
Y-axis (see figure). A light ray travelling in the 0 I
negative y-direction strikes the mirror. The direction E -2 /

/
':;' -4
I
of the reflected ray is given by the vector -6 I

-8
-1 0 I
-1 2 I
-6 -4 -2 0 2 4 6
J(mA) �
X 12 ,.
10
8
>T �
6
i - "'3j
/
(a) i (b)
0
"'3i - j
22. A total charge q is divided as Qi and q2 which are kept
(c) (d) i - 2 j
E -2
�
/
':;' -4
w
/
-6
a. The magnitude of the electric field E at the third

at two of the vertices of an equilateral triangle of side -8
-1 0
as a function of x = Qi I q. Choose the correct figure.

-1 2
vertex of the triangle is to be depicted schematically -6 -4 - 2 0 2 4 6
J(mA) �
The statement which is most likely to be correct?
(a) ( (a) P has only random error(s)
E )E (b) Q has only systematic error(s)
b (c) Q has both random and systematic errors
(d) P has both random and systematic errors
0.0 0.5 1 .0 0.0 0.5 1 .0
X X 25. A cylindrical vessel of base radius R and height H
has a narrow neck of height h and radius r at one end
\J
(c) (d)
(see figure). The vessel is filled with water (density p w )
(\
E
and its neck is filled with immiscible oil (density p0).
E
Then, the pressure at
2r
�
0.0 0.5 1 .0 0.0 0.5 1 .0
X X h
23. The refractive index of water in a biology laboratory

tank varies as 1.33 + 0.002 / ).,-2, where A is the
wavelength of light. Small pieces of organic matter
of different colours are seen at the bottom of the tank
using a travelling microscope. Then, the image of the
organic matter appears 2R
(a) deeper for the violet pieces than the green ones
(b) shallower for the blue pieces than the orange ones
(c) at the same depth for both the blue and orange pieces
(c) M is gHpw
(d) deeper for the green pieces than the red ones
WWW.JEEBOOKS.INl
26. Two cars 81 and 82 are moving in coplanar concentric Ignoring magnification effects, consider the following
circular tracks in the opposite sense with the periods statements.
of revolution 3 min and 24 min, respectively. At time (I) First image has been viewed from the planar
t = 0, the cars are farthest apart. Then, the two cars side of a piano-concave lens and second image
will be from the planar side of a plano-convex lens.
(a) closest to each other at t = 12 min and farthest at (II) First image has been viewed from the concave
t = 18 min side of a piano-concave lens and second image
(b) closest to each other at t = 3 min and farthest at from the convex side of a plano-convex lens.
t = 24 min
(III) First image has been viewed from the concave
(c) closest to each other at t = 6 min and farthest at
t = 12 min
side of a piano-concave lens and second image
(d) closest to each other at t = 12 min and farthest at from the planar side of a plano-convex lens.
t = 24 min (IV) First image has been viewed from the planar
27. In the circuit shown below, a student performing from the convex side of a plano-convex lens.
Ohm's law experiment accidently puts the voltmeter
and the ammeter as shown in the circuit below. The Which of the above statements are correct?
reading in the voltmeter will be close to (a) Only statement III is correct
6V (b) Only statement II is correct
2kQ
(c) Only statements III and IV are correct
(d) All statements are correct
CHEMISTRY
3 1 . The IUPAC name for the following compound is
(a) O V (b) 4.8 V (d) 1.2 V
28. The Bhagirathi and the Alaknanda merge at
Deoprayag to form the Ganga with their speeds in (a) 4,6-dimethylheptane (b) 1,3,5-trimethylhexane
the ratio 1 : 1: 5. The cross-sectional areas of the (c) 2,4-dimethylheptane (d) 2,4,6-trimethylhexane
Bhagirathi, the Alaknanda and the Ganga are in the
ratio 1 : 2 : 3. Assuming streamline flow, the ratio of 32. The stability of carbocations
the speed of Ganga to that of the Alaknanda is E!) E!) E!)
(a) 7 : 9 (b) 4 : 3 (c) S : 9 (d) 5 : 3 (CH3bC(OCH3) CH3CH2CH2CH2 CH3CHCH2CH3
11 Ill IV
29. A long cylindrical pipe of radius 20 cm is closed at its
upper end and has an airtight piston of negligible follows the order
mass as shown. When a 50 kg mass is attached to (a) III < IV < II < I (b) III < IV < I < II
the other end of piston, it moves down by a distance (c) IV < III < II < I (d) IV < III < I < II
an ideal gas, M ! l (see figure) is close to (g = 10 m/ s2 ,

t-,,1 before coming to equilibrium. Assuming air to be 33. The acidity of compounds I-IV in water
I. ethanol II. acetic acid
atmospheric pressure is 1()5 Pa), III. phenol IV. acetonitrile
follows the order
(a) IV < I < III < II (b) I < II < III < IV
(c) IV < I < II < III (d) IV < III < I < II
34. In the following reaction,
0
� NH,
(a) o.oi (b) 0.02 (c) 0.04 (d) 0.09
30. The word KVPY is written on a board and viewed
through different lenses such that board is at a the major product is
distance beyond the focal length of the lens. Br
�
(a)
v
First image Second image
WWW.JEEBOOKS.INl
Y
CONH 2 43. The oxidation states of P atom in POC1 3 , H2PO3 and
(d) H4 P2O 6 , respectively are
/✓
(a) +5, +4, +4 (b) +5, +5, +4
(c) +4, +4, +5 (d) +3, +4, +5
Br
neutralised by y mL of lM NaOH. The same volume

44. A solution (5 mL) of an acid X is completely
35. The reddish brown precipitate formed in the
of 0.6 M of H2 SO4 completely. The normality (N) of

Fehling's test for aldehydes (RCHO) is due to the (y mL) of lM NaOH is required to neutralise 10 mL
formation of
(a) Cu (b) Cu 20 the acid X is
(c) CuO (d) (RCOOh Cu (a) 1.2 (b) 2.4 (c) 4.8 (d) 0.6
36. The reducing ability of the metals K, Au, Zn and Pb 45. 1.25 g of a metal (M) reacts with oxygen completely
follows the order to produce 1.68 g of metal oxide. The empirical
(a) K > Pb > Au > Zn (b) Pb > K > Zn > Au formula of the metal oxide is
(c) Zn > Au > K > Pb (d) K > Zn > Pb > Au [molar mass of M and O are 69.7 g mol-1 and 16.0 g mol-1 ,
respectively]
37. White phosphorus catches fire in air to produce dense
(a) M20 (b) M203 (c) M02 (d) M3 04
white fumes. This is due to the formation of
BIOLOGY
(a) P4010 (b) PH 3
(c) H 3 P03 (d) H 3 P02
in the shell with the principal quantum number n = 4

38. The maximum number of electrons that can be filled 46. According to Watson-Crick model, hydrogen bonding
in a double-stranded DNA occurs between
lS
(a) adenine and guanine (b) adenine and thymine
39. At a constant pressure p, the plot of volume (V) as a

(a) 64 (b) 26 (c) 18 (d) 32 (c) cytosine and adenine (d) guanine and thymine
function of temperature (T) for 2 moles of an ideal gas

47. Which one of the following statements about mitosis
is correct?
gives a straight line with a slope 0.328 LK-1 . The
value of p (in atm) is closest to
(a) One nucleus gives rise to 4 nuclei
(b) Homologous chromosomes synapse during anaphase
[Gas constant, R = 0.0821 L atm mor1 K-1 ] (c) The centromeres separate at the onset of anaphase
(a) 0.25 (b) 0.5 (d) Non-sister chromatids recombine
(c) 1.0 (d) 2.0 48. Gaseous exchange of oxygen and carbon dioxide
40. Which of the following transformations can be carried between alveolar air and capillaries takes place by
out by using HI as a reducing agent, under acidic (a) active transport
[Given : Iis) ➔ 2r; E = 0.54 V]

conditions? (b) diffusion
0
(c) carrier-mediated transport
(i) Cu+ ➔ Cu(s); E = 0.52 V
0 (d) imbibition
(ii) Cr3 + ➔ Cr2+ ; E = - 0.41 V
0
49. Of the periods listed below, which one is the earliest
(iii) Fe3+ ➔ Fe 2+ ; E = 0.77 V
0 period when ostracoderms, the jawless and finless
(iv) Fe 2+ ➔ Fe(s); E = - 0.44 V
0 fishes, appeared?
(a) Devonian period (b) Cambrian period
(a) (i) and (iii) (b) (ii) and (iv) (c) Carboniferous period (d) Silurian period
(c) Only (iii) (d) Only (ii)
50. Scurvy is caused by the deficiency of
41. C 60 emerging from a source at a speed (v) has a
de Broglie wavelength of 11.0 A. The value of v
(a) nicotinic acid (b) ascorbic acid
(c) pantothenic acid (d) retinoic acid
(in ms-1 ) is closest to 51. Optical activity of DNA is due to its
34 (a) bases (b) sugars
[Planck's constant h = 6.626 x 10- Js]
(c) phosphates (d) hydrogen bonds
(a) 0.5 (b) 2.5 (c) 5.0 (d) 30
52. The monarch butterfly avoids predators such as
42. The lattice energies of NaCl, NaF, KCl and RbCl birds by
follow the order (a) changing colour frequently
(a) KCI < RbCl < NaCl < NaF (b) flying away from the predator swiftly
(b) NaF < NaCl < KCI < RbCl (c) producing a chemical obnoxious to the predator
(c) RbCl < KCI < NaCl < NaF (d) producing ultrasonic waves
(d) NaCl < RbCl < NaF < KCI
WWW.JEEBOOKS.INl
53. Filariasis is caused by 58. Match the diseases given in Column I with the
(a) Entamoeba histolytica (b) Plasmodium falciparum principal causal organisms in Column II and choose
(c) Trypanosoma brucei (d) Wuchereria bancrofti the correct combination.
54. Which one of the following conversions does not Column I Column II
happen under anaerobic conditions? (P) AIDS (i) HBV
(a) Glucose to ethanol by Saccharomyces (Q) Syphilis (ii) Neisseria sp.
(b) Lactose to lactic acid by Lactobacillus (R) Viral hepatitis (iii) Treponema sp.
(c) Glucose to CO2 and Hp by Saccharomyces (S) Gonorrhoea (iv) HIV
(d) Cellulose to glucose by Cellulomonas (a) P-iv, Q-iii, R-i, S-ii (b) P-iv, Q-ii, R-i, S-iii
55. An amount of 18 g glucose corresponds to (c) P-i, Q-ii, R-iv, S-iii (d) P-i, Q-iv, R-ii, S-iii
(a) 1.8 mole (b) 1 mole (c) 0. 18 mole (d) 0. 1 mole 59. Chromosomes are classified based on the position of
56. The number of electrons required to reduce one centromere. A chromosome having a terminal
molecule of oxygen to water during mitochondrial centromere is called
oxidation is (a) metacentric (b) telocentric
(a) 4 (b) 3 (c) 2 (d) 1 (c) sub-metacentric (d) acrocentric
57. Which one of the following molecules is derived from 60. Which one of the following options lists the primary
pantothenic acid? energy source(s) for all forms of life on the earth?
(a) Thiamine pyrophosphate (a) Light, inorganic substances
(b) Nicotinamide adenine dinucleotide phosphate (b) Inorganic substances, organic substances
(c) Flavin adenine dinucleotide phosphate (c) Light, organic substances
(d) AcetylCo-A (d) N2 , CO2
::> PART- I I (2 Marks Questions)
MATHEMATICS 64. Let C1 , C2 be two circles touching each other

61. Let ABCD be a trapezium with parallel sides AB and externally at the point A and let AB be the diameter
CD such that the circle S with AB as its diameter of circle C1 . Draw a secant BAa to circle C2 ,
touches CD. Further, the circle S passes through the intersecting circle C1 at a point A1 (;c A), and circle C2
mid-points of the diagonals AC and BD of the at points A2 and Aa . If BA1 = 2, BA2 = 3 and BAa = 4,
then the radii of circles C1 and C2 are respectively
trapezium. The smallest angle of the trapezium is
(a) ..'.: (b) ..'.: (a) -J30 , 3-fw (b) -J5 , 7-Jf,
3 4 5 10 2 10
(c) ..'.: (d) ..'.: (c) -J6 ' -J6 (d) ,.ffo 1 7-Jfo
5 6 2 2 3 ' 30
62. Let S be the set of all points (� , 1) on the circle with 65. Let a, b, c, d be real numbers between - 5 and 5 such
I a I = ✓4 - �, l b I = -J4 + .J5 - b , l e i = ,_/4 - .J5 + c,

that
prime integers, c and d are relatively prime integers

radius 1 centred at (0, 0) where a and b are relatively
(that is HCF (a, b) = HCF (c, d) = 1), and the integers l d l = -J4 + .J5 + d
b and d are even. Then, the set S Then, the product abed is
(a) is empty (a) 1 1 (b) - 1 1
(b) has four elements (c) 121 (d) - 121
PHYSICS
(c) has eight elements
(d) is infinite
66. Persons A and B are standing on the opposite sides of

63. Suppose we have two circles of radius 2 each in the
plane such that the distance between their centers is
2.,/3 . The area of the region common to both circles a 3.5 m wide water stream which they wish to cross.
lies between Each one of them has a rigid wooden plank whose
(a) 0.5 and 0.6 (b) 0.65 and 0.7 mass can be neglected. However, each plank is only
(c) 0. 7 and 0. 75 (d) 0.8 and 0.9 slightly longer than 3 m. So, they decide to arrange
them together as shown in the figure schematically.
WWW.JEEBOOKS.INl
With B (mass 1 7 kg) standing, the maximum mass of given charge Q, so that balls move away from each
A, who can walk over the plank is close to other with each thread making an angle of 45° from
A 3m the vertical. The value of Q is close to
(-�- = 9 x 109 in SI unirs)
1
41t£0
(a) l µC (b) l5 µC (c) 2 µC (d) 2.5 µC
3.5 m 70. Two parallel discs are connected by a rigid rod of
(a) 1 7 kg (b) 65 kg (c) 80 kg (d) 105 kg length L = 0.5 m centrally. Each disc has a slit
67. Two different liquids of same mass are kept in two oppositely placed as shown in the figure. A beam of
at different velocities u, while the system is rotated at

identical vessels, which are placed in a freezer that neutral atoms are incident on one of the discs axially
extracts heat from them at the same rate causing
angular speed of 600 rev/second, so that atoms only
figure below shows that temperature T versus time t
each liquid to transform into a solid. The schematic
with a specific velocity emerge at the other end.
plot for the two materials. We denote the specific Calculate the two largest speeds (in metre/second) of
heat of materials in the liquid (solid) states to be CL l the atoms that will emerge at the other end.
(C81) and CL2 (C82 ), respectively.
T
2 (a) 7 5, 25 (b) 100, 50 (c) 300, 100 (d) 600, 200
Choose the correct option given below. CHEMISTRY

7 1 . Among the following compounds, E/Z isomerism is
(a) CLI < CL2 and C81 < C82 (b) CLI > CL2 and C81 < C82
(c) CLI > CL2 and C81 > C82 (d) CLI < CL2 and C81 > C82
possible for
68. A ray of light originates from inside a glass slab and (a) 2-methylbut-2-ene (b) 2-methylbut-1-ene
is incident on its inner surface at an angle 0 as shown (c) 3-methylpent-1-ene (d) 3-methylpent-2-ene
below.
72. In the reaction,
Glass slab 1 . NaNH2, t. CH3
H 3c- c==c - H 2. x H3C �
3. y
x and y, respectively are

-2 (a) x = CHpH; y = Pd I BaS04 , quinoline, H 2
(b) x = CH 3 I; y = Pd / BaS04 , quinoline, H 2
(c) x = CH 3 I; y = Na in liq. NH 3
\
(d) x = CH 30H; y = Na in liq. NH3
Screen
73. Among the following molecules, the one with the
largest bond angle at the central atom is
In this experiment, the location x of the spot where
(a) CIF 3 (b) POC13 (c) BC13 (d) S03
the ray hits the screen is recorded. Which of the
following correctly shows the plot of variation of x 74. A compound has the following composition by weight
□
with the angle 0 ? : Na = 18.60%, S = 25.80%, H = 4.02% and O = 51.58%.
Assuming that all the hydrogen atoms in the
o � o � o rs] o µ7
compound are part of water of crystallisation, the
X X X X correct molecular formula of the compound is
LJ w LJJ (a) Na2 Sp3 · 3H20 (b) Na2 S04 • 5Hp
(c) Na2 S04 - lOHp (d) Na2 Sp3 · 5Hp
0� 0� 0� 0� °
75. X g of ice at 0 C is added to 340 g of water at 20°C.
A. B. C. D. The final temperature of the resultant mixture is
(a) A (b) B (c) C (d) D 5° C. The value of X (in g) is closest to
69. Four identical pendulums are made by attaching a [Heat of fusion of ice = 333 Jig; specific heat of water
small ball of mass 100 g on a 20 cm long thread and = 4.184 J/g.K]
suspended from the same point. Now, each ball is (a) 80.4 (b) 52.8 (c) 120.6 (d) 60.3
WWW.JEEBOOKS.INl
BIOLOGY 77. A 25,000 Da protein contains a single binding site for

a molecule (ligand), whose molecular weight is 2,500
76. Considering ABOblood grouping system in humans, Da. Assuming high affinity and physiologically
during blood transfusion some combinations of blood irreversible binding, the amount of the ligand
groups are compatible (.I), whereas the others are required to occupy all the binding sites in 10 mg
incompatible (X). Which one of the following options protein will be
is correct? (a) 0. 1 mg (b) 1 mg
(c) 10 mg (d) 100 mg
Recipient
0 A B AB 78. In an in vitro translation experiment, poly (UC) RNA
0 template produced poly (Ser-Leu), while poly (AG)
0
X X X ✓
X
RNA template produced poly (Arg-Glu) polypeptide.
A ✓ ✓ X
(a) C
0 Which one of the following options represents correct
0 B ✓ ✓ X X
✓ ✓
interpretations of the codons assignments for Ser,
Leu, Arg and Glu?
AB ✓ ✓
(a) Ser-UCU, Leu-CUC, Arg-AGA, Glu-GAG

(b) Ser-CUC, Leu-GAG, Arg-UCU, Glu-AGA
Rec ipient
0 A B AB (c) Ser-AGA, Leu-UCU, Arg-GAG, Glu-CUC
0 (d) Ser-GAG, Leu-AGA, Arg-CUC, Glu-UCU
0
X X X X
A ✓ X ✓ X
( b) C
0
X
79. A single bacterium is actively growing in a medium
0 B X
that supports its growth to a number of 100 million.
✓ ✓
AB ✓ ✓ X
Assuming the division time of the bacterium as
✓
3 hours and the lifespan of non-dividing bacteria as

Recipient
5 hours, which one of the following represents the
0 A B AB maximum number of bacteria that would be present
0
0
✓ X X X at the end of 15 hours?
(c) C
A ✓ ✓ X X (a) 10 (b) 64 (c) 24 (d) 32
0
X
0 X
80. A couple has two sons and two daughters. Only one
B ✓ ✓
son is colourblind and the rest of the siblings are

AB ✓ ✓ ✓ ✓
normal. Assuming colourblindness is sex-linked,
Recipient which one of the following would be the phenotype of
0 A B AB the parents?
0 ✓ ✓ ✓ ✓ (a) Mother would be colourblind, father would be normal
0 A X ✓ X ✓ (b) Father would be colourblind, mother would be normal
(d) X (c) Both the parents would be normal
C
0 B X ✓ ✓
0
AB X X X ✓ (d) Both the parents would be colourblind
Answers
PART-/
(c) 2 (b) 3 (c) 4 (a) 5 (d) 6 (d) 7 (b) 8 (d) 9 (c) 10 (d)
11 (c) 12 (b) 13 (d) 14 (c) 15 (a) 16 (a) 17 (b) 18 (b) 19 (b) 20 (a)
21 (c) 22 (c) 23 (b) 24 (d) 25 (a) 26 (d) 27 (c) 28 (c) 29 (c) 30 (d)
31 (c) 32 (b) 33 (a) 34 (c) 35 (b) 36 (d) 37 (a) 38 (d) 39 (b) 40 (c)
41 (*) 42 (c) 43 (a) 44 (b) 45 (b) 46 (b) 47 (c) 48 (b) 49 (b) 50 (b)
51 (b) 52 (c) 53 (d) 54 (c) 55 (d) 56 (a) 57 (d) 58 (a) 59 (b) 60 (a)
PART-I/
61 (d) 62 (a) 63 (c) 64 (a) 65 (a) 66 (c) 67 (b) 68 (a) 69 (b) 70 (d)
71 (d) 72 (c) 73 (a) 74 (d) 75 (d) 76 (d) 77 (b) 78 (a) 79 (d) 80 (c)
* No option is correct.
M/WW.JEEBOOKS.IN]
Solutions
1 . (c) Let triangle T is PQR and other dABC - MPC We know,
L L
triangle is ABC. Area of MBC AC2 Product of two number = HCF x LCM
. . . (ii)
Area of dMPC MC2 xy = 16 X 48000
From Eqs. (i) and (ii), we get xy = 16 X 16 X (31 X z3 X 53 )
6
Area of MNM AM2 As HCF of (x, y) = 16
-
Area of dMPC MC2 z3 can be selected in 1 ways and 31 and 53
Area of MNM + Area of dMPC can be selected in (1 + 1) (3 + 1) = 8 ways
Q R B C Area of dMPC :. Number of ordered pairs = 8
8. (d) Let two digits number
p AM2 + MC2
B C
MC2
RV
ab = 10a + b, b ,t, 0
Now, Area of MNM + Area of dMPC
= Area of dABC - Area of BNMP if b is erased.
Q 13 (Area of MBC) _ AM2 + MC2 Then, the resulting number is a.
- :. ab is divisible by a if ab is multiple of c.
18 (Area of dMPC) MC2
:. Such number are 11, 12, 13, 14, 15, 16,
A can taken position if MBC - l'J'QR. . . .) , -
From Eq. (111 (AC2) = -AM2- + MC2
13 -- 17, 18, 19, 22, 24, 26, 28, 33, 36, 39, 44,
( -
We can arrange A, B, C in 3! ways 18 MC2 ) MC2 48, 55, 66, 77, 88, 99.
= 6 ways
⇒ 13 (AM + MC)2 = 18 (AM2 + MC2) :. Total number are 23.
Total position of A can take = 3! x 2 = 12 AM = 5
⇒ Hence, K < 25
9. (c) There are 90 days from 1 January
ways
2. (b) We have, n E {2, 3, 4, 5, 6, . . . , 200}
MC
5. (d) We have, � ' "2, � ..., Zn be the to 31 March (Non-leap year)
__! has terminating decimal of n = 2a x ff lengths of the side of arbitrary n sided If year 13 leap year, then total number of
n non-degenerate polygon P and days = 91 (13 weeks)
:. n = 2, 4, 5, 8, 10, 16, 20, 25, 32, 40, 50, _li__ + 1 + 1 + ... + Zn - 1 + Zn = n, n '?. 4 But we have 12 Sunday
64, 80, 100, 125, 128, 160, 200 "2 � Z4 Zn �
:. 12 weeks
:. Total number of n = 18
3. (c) We have,
Using AM '?. GM, we get
rn
:. 1st Jan will be Monday as there will be
� + "2 + � + ... + Zn 90 days January 1 to 31 March.
a + b + c = 0 and a2 + b2 + c2 = 1 I : T. '?. (t; X r x ... X z:
T; :. 15th February will be Thursday.
1 0. (d) Let three digits number be
Now (3a + 5b - &) 2 + (- 8a + 3b + 5c)2
2
+ (5a - Sb + 3c)
= 9a2 + 25b2 + 64c2 - 48ac + 30ab _li__ + 1 + ... + Zn
'?. n lO0x + lOy + z.
- 80bc + 64a 2 + 9b2 + 25c2 - 80ac "2 � � According to problem,
- 48ab + 30bc + 25a2 + 64b2 + 9c2 n '?. n ⇒n = n lO0x + lOy + z = lO0x + lOz + y - 36
+ 30ac - Sab - 48bc So, AM = GM ⇒ 9y - 9z + 36 = 0
= 98(a 2 + b2 + c2) - 98 (ab + be + ca) � = "2 = � . . . = Zn ⇒ y - z + 4= 0 . . . (i)
= 98 (a2 + b2 + c2) :. The length of sides of P are equal and ⇒ lO0x + lOy + z = lO0z + lOy + x + 198
P is regular polygon of it is cyclic. ⇒ x-z-2=0 . . . (ii)
6. (d) Let n 2 + 3 is divisible by 1 7
+ b + c)2 - (a2 + b2 + c2)
- 98( (a ) Now, (lO0x + lOy + z) - (lO0y + lOx + z)
2
= 90(x - y)
n 2 + 3 = 17K [K E N]
= 98(1) - 9{ 0; 1) = 98 + 49 = 147 = 90(6) [·: from Eqs. (i) and (ii)]
⇒ n 2 = 17K - 3
= 540
4. (a) d ABC - MNM ⇒ n 2 = 3 (17m - 1) [·: K = 3 m] :. So, on interchanging for digit at tens
A 3 (1 7 m - 1) is a perfect square is not place and hundred place, the value of
possible. number is decreased by 540.
:. n 2 + 3 is never divisible by 17. 1 1 . (c) We have,
n 2 + 4 put n = 9 Four triangle having sides are
(9) 2 + 4 = 81 + 4 = 85 is divisible by 17. (5, 12, 9), (5, 12, 1 1), (5, 12, 13), (5, 12, 15)
:. I is true and II is false. A right triangle has maximum area.
P C 7. (b) We have, :. Among these the triangle whose sides
B
:. It has maximum area.

Area of MBC AC2 HCF (x, y) = 16 (5, 12, 13) form a right angled triangle.
. . . (i)
Area of MNM AM2 LCM (x, y) = 48000
WWW.JEEBOOKS.INl
1 2. (b) Let the number of boys and girls Now, given ⇒ RAB
2 L
- X- xx
=
in classroom is x and y, respectively. -Bx +- Gy- = z 3 3
Given, -x - x /- 5 = -2 ⇒-
4x 2
=- B+G Power dissipated is
y 3 5y 3 2
9V 2
X 5 ⇒ B(x - z) = G (z - y) = !!_ = z - Y Pi = - V - = - - ... (i)
⇒ . . . (i) G x-z RAB 2Lx
y G 1 1 x-z
Now, = = In case II,
- x - x /- 5 = -5 ⇒ - 4x
- - 5 B + G !}__ + 1 z-y
Also, +1 x-y
y - 44 2 5 (y - 44) 2 G x-z
⇒ 8x = 25y - 1 100 . . . (ii) G z-x
⇒
From Eqs. (i) and (ii), we get B+G y-x
X = 50, y = 60 1 6. (a) Particles used in Rutherford's
Let z number of boy leaves so number of scattering experiment (Geiger-Marsden V
boys and number of girls are equal. experiment) are a-particles derived from 1trx x 1trx 1t 2r 2x2
50 - 10 - z = 60 - 44 a tube of radium emanation (or radon). RPQ = (1trx l l 1trx) = - - -= - -
1trx + 1trx 21trx
z = 40 - 16 = 24 a-particles are helium nuclei :He, they
1 3. (d) We have,
1 1 L Lx
are fully ionised and have atomic = - 1trx = - 1t x - x = -
X, Y, Z be respectively the area of a
2 2 21t 4
number 2.
1 7. (b) Atomic number of 16 s'32 is 16.
So, power dissipated is
= V = 4V
P2 - - - -
regular pentagon, regular hexagon and 2 2
regular heptagon which are inscribed in Its electronic configuration using 2n 2 rule
RPQ Lx
radius of unit circle. IS
1s2 , 2s2p 6 , 3s2p 4
16 S = '-----,-------- Ratio of power dissipated in two cases is
�
f'i _ 9V 2 l 2Lx _ 9
4V 2 I Lx 8
[Ne] Unfilled
- -
So, number of fully filled orbits or shells P2
is 2. 20. (a) For a mass m at centroid of
1 8. (b) Length of pendulum = Length of hexagon (at origin), net force is zero
thread + Radius of bob when 'I.F,, = 0 and 'I.F;, = 0.
2
= 63.2 + · 256 = 63.2 + 1128
2 3
X = 5 x I x 1 x sin 21t = 64.328 cm
2 5 mk = llM-
But now the student must apply rule for
X = � sin 21t 1 cos 0k l
taking significant digits in a
2 5 measurement. 4
Similarly, In addition or subtraction,
21t and Z = 2 sin 21t
Y = � sin Number of digits after decimal in result
6 2 2 7 5 6
X 1 . 21t Y 1 . 21t Z 1 . 21t = Least number of digits after decimal in
5 2 5 ' 6 2 3 ' 7 2 sm 7
= s m = s m = quantities added Now, 'I.F,, = sum of all x-components of
So, length of pendulum = 64.3 cm. forces on m due to masses at vertices of
1 9. (b) Let a = side length of equilateral
. -
Sln 21t > Sln
. -21t > Sln
. -21t
hexagon.
:. !!__ > � > � and X < Y < Z
5 6 7
Gm
5 6 7
triangle, r = radius of circle and x = =-
,.-
., ('I. (k'M I cos 0k I · cos 0k ))
1 4. (c) Given, L L
resistance per unit length of wire used.
· ·
= -GmM - .,- (l' I cos0° l · cos 0° + 2' I cos 60° I
Then, L = 3a = 21tr or a = - and r = - r·
n - 1 ½ + n - 1c < nc; 3 21t · cos 60°+ 3 ; I cos 120° I · cos 120°
6
n c6 < nc; Now, in case I, + 4 i I cos 1so0 I · cos 1so0
+ ncr =
[·: ncr - 1 n+ lC l
r + 5 i I cos 240° I · cos 240°
- < - -
n! n!
⇒ - - v� + 6 ; I cos 300° I · cos 300° )
(n - 6) ! 6! (n - 7)! 7! 2 ; 3i 5 i 6;
_ GMm
- - ,. 2 - · ( 1; + - - - - 4 ; - - + - )
⇒ n - 6> 7 4 4 4 4
Equivalent resistance across AB is
⇒ n > 13 As 'I.F,, = 0, for net force on m to be zero.
:. Least value of x = 14
1 5. (a) Let the number of boy = B
ax x 2ax we have
RAB = (ax II 2ax) = - -
ax + 2ax 2i 3i 5i 6i
2a2x2 2
1i + - - - - 4i - - + - = 0
and number of girls = G 4 4 4 4
=- - = - ax
Sum of marks obtained by boys = Bx 3ax 3 Above equation is satisfied with i = 0.
:. Sum of marks obtained by girls = Gy
WWW.JEEBOOKS.INl
21. (c) Following laws of reflection, Now, µ orange < µ blue 27. (c) The resistance of voltmeter is
reflected ray makes an angle of 30° with ⇒ (Apparent depth)blue very high and resistance of ammeter is
mirror as shown below. < (Apparent depth)orange very low. When ammeter is put in
parallel to 8 kQ resistor, nearly whole of
24. (d) For P errors are both positive and
A Incident negative. current goes through the ammeter.
ray Hence, circuit is equivalent to following.
For Q errors are only positive.
So, P has both random and systematic
N
25. (a) Pressure is same at all the points

errors.
resistance
of base.
i.e. Pressure at M = Pressure at N '-------< V I------'
Reflected Also, pressure applied anywhere to the High resistance
ray fluid is equally transmitted in all
B So, maximum potential drop occurs in the
A A
directions.
voltmeter (high resistance). Hence,
column of height h + pressure due to
So, if a vector xi + yj is along the So, pressure at base = pressure due to oil
l. or !__ = - ---1:___
reading of voltmeter is nearly 6 V.
water column of height H. 28. (c) As water is not stored anywhere.
reflected ray, then
tan (-30° ) =
X X -/3 ⇒ Po gh + Pw gH ⇒ g (po· h + Pw H) So, volume flow rate of Ganga = volume
22. (c) When q1 and q2 are the magnitudes

This is correct with option (c). 26. (d) T= 24 min flow rate of Bhagirathi + volume flow
---=------->S2 rate of Alaknanda
of charges at two vertices of an equilateral
triangle of side a, magnitude of electric
field at third vertex is
T=3 min
Positions of cars at t = Os
Ag vg = Ai, q, + Aa va
:. By equation of continuity, we have
At t = 12 min, car Si
has completed three ⇒ ... (i)
rounds and it is at its position. It is given that area of flow of Ganga,
At t = 12 min, car S2 completed half round Alaknanda and Bhagirathi are in ratio,
and it is at diametrically opposite point Ag : Aa : Ai, = 3 : 2 : 1
as shown below.
= 3x, Aa = 2x, Ai, = x
or Ag
Also, ratio of speeds of Bhagirathi and
Q Vi, .' V = 1 .· �
Alaknanda is
q, = y, Va
2
3
or =
y
2
Substituting these values in Eq. (i), we
= 1 2 min
S2
get
Positions of cars at t 3
3x- v = x • y + 2x• - y = 4xy
So, cars are closest at t = 12 min. g
= -4 y
2
At t = 24 min, cars Si
and S2 are both at So, V
So, field is minimum when CJi = �- g 3
2 their initial positions and so are farthest,
q
as shown below. :. Ratio of speed of Ganga to that of
This condition is satisfied in graph (c).
23. (b) As, refractive index,
Alaknanda is
4
0.002 Vg _
y
3
_ 8
µ- - -
9
2y
- 133 + -
Q
,.2 Va 3
29. (c) Initially pressure inside the

So, µ is more for small wavelengths.
i.e. µ orange < µ green < µ blue
cylinder is atmospheric pressure p0 •
real depth
As, µ = ------ When mass m is attached to piston and it
apparent depth
comes down by a distance M, let pressure
1 is p.
⇒ Apparent depth oc Hence, cars are farthest from each other
at t = 24 min.
WWW.JEEBOOKS.INl
34. (c)
⇒ p0 (A) (l) = pA(l + t.l)
o
= pV
Then, in equilibrium, So, a plano-concave lens acts like a
p0V0 diverging lens weather object is viewed ©Y NH,
from plane side or curved side. @7' N H, �
i
p
Hence, image appears erect in both cases.
l Po
l :. First image appears same when viewed
from plane or curved side of a
Benzamide
This reaction is known as Hofmann
Aniline
bromamide reaction. It is used for

plano-concave lens.
preparing amine containing one carbon
Initially Similarly, a plano-convex lens is a
less than the starting amide. In this
m converging lens from both side view.
reaction, migration of an alkyl or aryl
Finally So, second image appears always group takes place from carbonyl carbon of
inverted in both cases.
31 . (c) The IUPAC name for the
the amide to N-atom.
35. (b) Fehling's reagent is a mixture of
So, final pressure will be
P_-
p0 A I
= ___EL
following compound is aqueous copper sulphate and alkaline
A(l + t.l) (l + t.l)
sodium potassium tartarate. When an
In equilibrium, weight of mass m is
5
aldehyde is heated with Fehling's reagent
balanced by force of suction due to 7 3 1
reduced pressure p.
a reddish brown precipitate is obtained
(p0 - p) A = mg
2, 4-dimethylheptane
32. (b) As the size of alkyl group goes on

and the aldehydes are oxidised to
increasing, the + I effect exerted by it

corresponding carboxylate anion. This
1 p0A _ l
⇒ ( Po - - p11 - ) A - mg ⇒ -- --+ l reddish brown precipitate is due to the
l+ M mg M becomes strong and, thus the carbocation formation of copper oxide.
=
will be more stable. So, among 1°, 2° and
l(f X 1t X (20 X 10-2 ) 2 _}___
⇒ +l 3 ° carbocation, 3 ° will be most stable. RCHO + 2Cu2+ +50H-� Rcoo
50 x 10 M (Fehling's solutions)
22 x 8 Although (CH 3 )2 C (OCH 3 ) will be highly + Cu2O,l, +3H2O
⇒ - l = J__
7 M Red brown
M = 0.04
stable among the given carbocations due
= 169 36. (d) The reducing ability of metals
(ppt).
J__ to resonance stabilisation.
⇒ or
M 7 l
30. (d) For a plano-concave lens, when
+ [:•• can be determined by electrochemical
(CH3) 2-C - Q - CH3 -
series. In this series, various elements
curvature of surface 1 is Hi_ = oo and

view is from concave side. Radius of + are arranged according to their
(CH3l 2- C= Q - CH3
radius of curvature of surface 2 is R2 = R.
decreasing values of standard reduction
Thus, the correct order of stability of potentials. The reducing ability of the
carbocations will be
The increasing order of E0 values of given

metal increases as you go up the series.
+ +
CH3CH2CH2CH2 < CH3CHCH2CH3 <
Object Image
A
' metals are,
' (1 0) (20)
Ill IV K < Zn < Pb < Au.
+ Thus, the correct order of reducing ability
(CH3l 3C < (CH3l 2C(OCH3)
of metals K, Au, Zn and Pb follows the
(3 )
0
So, focal length of lens using order
f
I
1
= (µ - 1) ( 1
-
1
) Lµ = 2 for glassJ
r 3 1 33. (a) The acidity of compounds in K > Zn > Pb > Au.
Hi_ R2 water depends upon the ease with which 37. (a) White phosphorus is highly
+ reactive and catches fire when exposed to
we have, when viewed from curved side, it can lose H ions. Acetic acid is the
/= �
air and produces white dense fumes of
phosphorus oxide, P4 010 •
strongest acid as the negative charge on
(µ - 1) carboxylate ion (conjugate base) is
= - R, R2 = oo.
P4 + 50 2 ➔ P4 010
38. (d) The maximum number of
and delocalised over two oxygen atoms.
Hi_
Hence, W ion can be easily lost. The next
with principle quantum number, n = 2n

strongest acidic compound phenol. This is electrons that can be filled in the shell
2
n=4
because the phenoxide ion is resonance
Maximum number of electrons = 2(4) 2 = 32

stabilised. This easily allows the H to For
Object Image
39. (b) According to ideal gas equation
leave as W ion. Among acetonitrile and
p = nRT ⇒ - V =- = slope
ethanol, ethanol is more acidic, this is
because in ethanol the H-atom is directly nR
T P
When viewed from plane side, V
= (µ - l) (-i ) Given, slope = 0.328, n = 2
attached to more electronegative atom, 0.
p= =
7 Thus, the correct order of acidity of
/=�
compound I -IV in water will be nR 2 x 0.082 1
0.500 atm
⇒ IV < I < III < IL slope 0.328
(µ - 1)
WWW.JEEBOOKS.INl
40. (c) The more positive E0 value of Number of equivalents of H 2 SO4 diffuse between the air in the alveoli and
metal, feasible transformation can be = 0.6 X 10 X 2 = 12 the blood in the capillaries. Diffusion is
carried out by using HI as reducing agent (Number of equivalents) NaOH the movement of gas from an area of high
under acidic conditions. concentration to an area of low
= (Number of equivalents) H 2 so
49. (b) The class Ostracodermi is

concentration.
As E0 = 0.77 V (Fe3 + ➔ Fe2+ ) is more
4
= y = 12 mL
positive than, E0 = 0.54 (12 (s) ➔ 2r) thus Also, number of equivalents of acid
can be used for carrying out represented by the fossil vertebrates of
= Number of equivalents of NaOH
transformation as it is the strongest late Cambrian period. The earliest known
N x 5 = l x 12 x 1 [N = M x basicity] vertebrates to appear in fossil record
oxidising agent among the other given
options. N = 12 = 2.4 were jawless primitive fish-like animals
4 1 . (*) According to de-Broglie
45. (b) M + 02 ➔ M02
collectively called ostracoderms. These
animals resembled the present day
h
wavelength
/\, = -
1.25 cyclostomes (lampreys and hagfishes) in
Percentage of M = x 100 = 74.4%
many respects.
50. (b) Scurvy is caused by the deficiency
mv 168
Mass of C 60 = 12 x 60 = 720 g Percentage of oxygen in oxide

of vitamin-C (Ascorbic acid) in the body.
0 = 100 - 74.4% = 25.6%
Given, 11, = 110A = 11 x 10-10 m It can lead to anaemia, debility,
h = 6.626 x 10-34 Js
To calculate empirical formula exhaustion, spontaneous bleeding, pain
At mass Moles Simplest Simplest in the limbs and especially the legs,
34 2 1 Eleme % of
- h -
= 6.626 x 10- kg m s- of of molar whole
swelling in some parts of the body and
v-
-nt element
2
6.626 x 10-34 kgm s-1
element element ratio no.
sometimes ulceration of the gums and
- 744
720 x 10-3 kg x 11 x 10-10 m 106 loss of teeth.
5 1 . (b) DNA polymer is made up of
mA M 74.4 69.7 = 1 l x 2= 2
69.7
106
�
= 0.8 X 10- lS rn/s = 106
25.6 16 nitrogenous base, a sugar and one or
No option is correct in the given forma� - 1.50x 2
as the value of wavelength is given in A 0 25.6 16 16 106 more phosphate. Optical activity results
=3
= 16 = 150 due to the molecular asymmetry. The
which gives the large difference in
nucleic acid bases have a plane of
answer.
42. (c) Lattice energy is the energy
:. Empirical formula of metal oxide is symmetry. Hence, they do not induce
M2O3 .
46. (b) In 1953, JD Watson and FHC
optical activity. Sugars are asymmetric
required to completely separate one mole and cause optical activity of DNA.
52. (c) The monarch butterfly avoids
of a solid ionic compound into gaseous Crick proposed a 3-D model of
constituent. Lattice energy increases physiological DNA. They proposed that predators such as birds by producing a
with decrease in the size of ions. DNA is a double-stranded helical chemical obnoxious to the predator.
This is because as the size of ion is less, molecule. It consists of two Monarchs lay their eggs on milkweed
intermolecular distance will be less and sugar-phosphate backbones on the (swan plants), a member of the genus
so forces of attraction is greater. outside, held together by hydrogen bonds Asclepias. As the caterpillars eat the
Thus, the correct increasing order of between pairs of nitrogenous bases on the milkweed leaves, they ingest chemicals
lattice energies is, inside. The bases adenine (A) always called cardiac glycosides. Birds or other
pairs with thymine (T) by two hydrogen animals that eat the caterpillars (or
RbCl < KCl < NaCl < NaF.
43. (a) Let the oxidation state of P-atom
bonds and guanine always pairs with milkweed itself) become sick and vomit.
cytosine (C) by three hydrogen bonds. The caterpillars sequester (hold onto) this
in POC13 , H2PO3 and H4 P2O 6 be x. This complimentarity is known as the toxin as they pupate and the toxins are
(i) POC1 3 base pairing rule.
47. (c) In anaphase, sister chromatids
transferred to the adult butterflies. Birds
X + 1 (-2) + 3(-1) = 0 or other creatures that eat the monarchs
x-2- 3= 0 separate from centromeres so, number of become sick, so they learn to leave both
53. (d) Filariasis is caused by

x= + 5 chromosome becomes double. Other the butterflies and larvae alone.
(ii) H 2 PO3 statements about mitosis can be
2(1) + x + 3(-2) = 0 corrected as Mitosis is a single nuclear Wuchereria bancrofti. It lives in
2+ x- 6= 0 division that results in two nuclei. lymphatic vessels and causes swelling of
lower limbs and scrotum. Entamoeba
x=+ 4 Synapsis takes place during prophase-I of
histolytica causes amoebiasis.
(iii) H 4Pp6 meiosis not during mitosis. Non-sister
Plasmodium falciparum causes malaria.
4(1) + 2x + 6(-2) = 0 chromatids recombine during prophase-I
Trypanosoma brucei causes African
of meiosis. During mitosis, each sister
54. (c) Conversion of glucose to CO2 and
4 + 2x - 12 = 0 sleeping sickness.
2x = 8 chromatid separates and moves to
x=+ 4 opposite pole of the cell at anaphase.
48. (b) Gaseous exchange occurs at the
H 2O by Saccharomyces is a reaction which
44. (b) Number of equivalents takes place in aerobic conditions, i.e. in
= M x V x acidity/basicity
alveoli in the lungs and takes place by the presence of oxygen.
diffusion. The alveoli are surrounded by C6 H12 O 6 + 602 ➔ 6CO2 + 6H2O
Number of equivalents of NaOH
capillaries so, oxygen and carbon dioxide
= lx y x l= y
WWW.JEEBOOKS.INl
55. (d) A mole is the quantity of a contain specific combinations of inorganic But 4 (k 2 + m2 + k + m) + 2 is not
substance whose weight in grams is equal elements including carbon, hydrogen, multiple of 4.
to the molecular weight of the substance. nitrogen and oxygen that combine to form :. Not possible.
proteins and nucleic acids.
61 . (d) Given,
1 mole is equal to 1 moles Glucose, or :. S is empty set.
180.15588 grams.
ABCD is a trapezium where AB is
63. (c) Given,
:. 18 g of glucose = x mole x 180 g
parallel to CD. A circle S with AB as
Two circle each of radius is 2
diametre touch CD and also circle passes

x mole = � = 0.1mole and difference between their centre is 2'/3
through the mid-points of diagonal AC AB 2'/3 ⇒ AC --1:AB
180
:. An amount of 18 g glucose corresponds = =
AC --/3
2
AR = RC
to 0.1 mole. and BD.
56. (a) Four electrons are required to
=
reduce one molecule of oxygen to water LARB = 90°

during mitochondrial oxidation. :.MBCis isosceles
02 + 4e- + 4W ➔ 2H20 AB = BC . . . (i)
This process mentioned above takes place
during oxidative phosphorylation. It is
the metabolic pathway in which cells use
enzymes to oxidise nutrients, thereby
AC -J3
releasing energy which is used to produce
ATP.
57. (d) Vitamin-B5 is pantothenic acid or AP
In MPC, cos0 = - = -
2
Similarly, in MED
D M P
0 = 30°
BQ = QD
pantothenate, that is required in the
synthesis of acetyl Co-A. In all living Area of common region
organisms, Co-A is synthesised in a five LAQB = 90° = 2 (Area of sector - Area of MPQ)
step process that requires four molecules
AB = AD
of ATP, pantothenate and cysteine.
:. MBD is isosceles. = 2 (� X 1t(2)
2
- --1: X (2) 2 X sin 60° )
58. (a) HIV is the causative organism for

. . . (ii) 360 2
AIDS.
Syphilis is a bacterial infection caused by
From Eqs. (i) and (ii),
AB = BC = AD
:. Trapezium is isosceles.
= 2 ( 4: -
4:3 )
Treponema sp. It spreads by sexual
. LADM = -AM OP OP
= 2 ( � (3.14) - (173) )
In MDM,
contact that starts as a painless sore.
AD AD 20P
Viral hepatitis caused by HBV is an sm - =-=- - = 2 (209 - 173) = 2 (0.36) = 0.72
[·: OP = iAB]
infection that causes liver inflammation :. Area of region lie between 0.7 and 0.75.
64. (a) Given,
and damage organs.
AB is diameter of circle C1 .
sin (LADM) = I_
Gonorrhoea is caused by Neisseria sp. It
is sexually transmitted bacterial infection ⇒
2
LADM = 30° = �
that if let untreated may cause infertility.
59. (b) Telocentric chromosome is a ⇒
62. (a) Let the equation of circle is

6
chromosome like a straight rod with the
centromere in terminal position.
Metacentric chromosome is a X-shaped x2 + y2 = ], ( Ti , �) lie on circle.
chromosome, with the centromere in the
middle so that the two arms of the
BAI = 2
chromosomes are almost equal.
BA2 = 3
Acrocentric chromosome is a chromosome
BAs = 4
in which the centromere is located quite ⇒
c and d are relatively prime.

near one end of the chromosome.
circle C2 = r2
Sub-metacentric chromosome is a
Let radius of circle Ci = r1 and radius of
d
chromosome whose centromere is located _. _ _£ is rational.
BA = 2r1 and AC = 2r2

60. (a) Living organisms require energy
near the middle.
b2 - a 2 = ')...,2 [·: b is even; :. a is odd]
BM = -1 BAI = 1
So,
to grow, reproduce and respond to the b is even, a is odd. ⇒
:. ')...,2 is odd ⇒ b = ')...,2 + a
2
BN = BA2 + -AA
2 2
environment. Energy sources include
1
b = (2k + 1) + (2m + 1)2 2
b 4k 4k + 4m +
primarily light and inorganic compounds. 2 ⇒
⇒
2
2
The most common source of energy on the
⇒ 2 2
b2 = 4 (k2 + m2 + k + m) + 2
= + 1 + 4m + 1 1 7
earth is photosynthesis, which transforms =3+ -=-
⇒ 2 2
sunlight into food. Life forms usually
:. b is even; :. b2 is multiple of 4.
WWW.JEEBOOKS.INl
In !illMP and t.BNQ, 67. (b) Let Q = rate of heat removal.

!illMP - !illNQ Then, Q · t = meT
BM
- - �
BP
BN BQ ⇒ T = !l_ · t
me
Comparing this with y = mx,
__l r
⇒ = _ _ 1_
7 / 2 2r1 + r2
Slope of T-t line oc 1
tan 45° = F,
⇒ 2r2 = 3r1 . . . (i) Specific heat
mg
Now, BA2 x B,¾ = BA x BC
Slope of graph
mg = F,
⇒ 3 x 4 = 2r1 (2r1 + 2r2)
l
T 1 in solid state
⇒
2k
r/ + r1 r2 = 3
⇒ 12 = 4 (r/ + r1 r2)
mg = -. ,
Slope of graph
x·
⇒ . . . (ii) 2 in liquid ⇒
l
state is more
mgx2 = 2k
r,1 = @ = -Jw and r2 = -fw

⇒
3 l
V5 5 10
where, x = l sin 0 = -_
-J2
65. (a) Given, So, substituting values, we get
From graph,
l a l = -../ 4 - ,J5=a, 20 0-2
= 2 x 9 x 109 x l
⇒ 100 X 10-3 X 10 X ( :,�
l b l = ,,/ 4 + ,,/ 5 - b and r
l ei = ,/ 4- ,J C> + e 68. (a) As 0 increases, angle of incidence

2
(i = 90 - 0) decreases. Initially upto i = ic 2 10-
l d l = ,_/ 4 + ,, 5 + d ⇒ =
angle of critical incidence, reflection q 9 x 109
On squaring, we get takes place and x is positive. Also, x ⇒ l > 10-12
a2 = 4 - ,J5 - a increases till 0 is such that i = ic , after (slightly higher than 10-12)
q > 10-6 C
= a2 - 4 = - ,J5 - a that refraction takes place and x becomes ⇒
Again squaring, we get negative. So, nearest answer is 1.5 µC.
70. (d) Time at which discs gaps are
a4 - 8a2 + 16 = 5 - a
4
⇒ a - 8a2 + a + 1 1 = 0 alined,
t = - , -, - , ...
Similarly, squaring other given equation 1t 31t 51t
and solving we can say that (0 (0 (0
X
So, speeds of atoms that emerges on other
0
a, b, - e, - d are roots of equation 0
When 8 is less side are
x4 - 8x2 + X + 1 1 = 0 and TIR occur 0.5 -
69. (b) Electrostatic force on any of the
:. The product of roots
Vi. = - - = 600 ms-1
� X 21t
1.e. abed = 1 1 600
66. (c) When planks are arranged as
ball is (let x = separation between two
0.5
adjacent balls). and v2 = = 200 ms-1
given in question, we have following � X 21t
kq2 600
7 1 . (d) If alkenes have two different
situation.
Pivot x2
m 1 7 kg substituents (x,y) at each end of the
A B C = C, then only they can show
EIZ isomerism.
(a) 2-methylbut-2-ene
kq2
x2 x@ @x
q
(,,/2x)2 x2 · cos 45
Fe = _!!i.._ + 2k ° '-c=c(
l
�- - 3.5 m - ---->
-
y@ ®y
= k 2 + -J2 k2q
Let m = maximum mass of A.
As x = y, this alkene will not show
2x x
l l
Then, for safe crossing,
mg X 0.5 = 17 X g X 2.5
= ( I + ,,/2 ) k 2 = 2k2
EIZ isomerism.
m=
(b) 2-methylbut-1-ene
1 7 x 2.5 2 x x
⇒ = 85 kg
"
0.5 x (8) �x
So, a man of mass upto 80 kg can pass
As each ball is at an angle of 45° from '-c-c/�
/ -
over planks. each other, so in equilibrium, we have y (8) @Y
WWW.JEEBOOKS.INl
76. (d) Blood group-O individuals are called universal donor as

:. It will not show E/Z isomerism.
Here also x = y
they can give blood to person with blood group-A, B, AB and 0.
(c) 3-methylpent-1-ene Blood group-AB individuals can only give blood to persons with
x (8) (8)x blood group-AB but can receive blood from all other blood
)c=c <:----� groups.
y (8) 1CH2( CH 3) CH2CH 3I Y Therefore, the correct table for the blood transfusion
This compound will not show E/Z isomerism. compatibility for ABO blood group system in human is
(d) 3 -methylpent-2-ene Rec ipient

x (8) )CH2CH 3Ix 0 A B AB
........_
0
/ C = C .....,__ 0 ✓ ✓ ✓ ✓
y@ @;)Y A X ✓ X ✓
As x "# y, thus this alkene will show El Z is isomerism. (d) X X ✓
72. (c)
0 B ✓
AB X X X ✓
77. (b) Assuming x as the amount of ligand to occupy all the

�
CH 3 - C == C - H Ol N"a NH2 CH 3 C ==CCJ NaD
\,
CH 3 1 (ii) C!1-3 -� (x) binding sites in 10 mg protein.
iii) N i q. NHs x mg Ligand molecular weight
H6=CH <( � CH 3C== CCH 3 + N al =
Protein in grams Protein molecular weight
2500
CH 3 X=- - X 10 = 1mg
(Trans form) 25000
Thus, in the given reaction, 78. (a) Serine is coded by UCU, UCC, UCA, UCG, AGU, AGC
x = Clf:i l and y = Na / liq. NH3 • Leucine is coded by CUU, CUC, CUA, CUG, UUA, UUG
73. (a) The bond angle depends upon the electronegativity of Arginine is coded by AGA, AGG, CGU, CGC, CGA, CGG
the central atom. More is the electronegativity of the central, Glutamic acid is coded by GAA, GAG
larger is the bond angle. Thus, among the given central atom Cl Therefore, option (a) is the correct interpretation of the assigned
has the highest electronegativity. Therefore, ClF;i has the amino acids.
largest bond angle at the central atom.
74. (d)
Ser-UCU, Leu-CUC, Arg-AGA, Glu-GAG
79. (d) The number of bacteria after 15 hours will be 32. This
At mass Simplest Simplest happens as each bacterium doubles up after every 3 hours, i.e. it
% of Moles of 15
Elements of molar whole will double = 5 times in 15 hours.
element element
element ratio no.
18.6 0.8 Therefore, the sequence in which the growth of bacteria taking
Na 18.6 23 = 0.8 =l lx 2= 2
23 0.8 place will be
25.8 0.8
s 25.8 32 = 0.8 =l lx 2= 2 1 � 2 �4� 8 � 16 �32
32 0.8 80. (c) Colourblindness is a X-linked recessive disease, i.e. an
-
5158 - heterozygous mother does not show the disease and is a carrier.
3.22
0 51.58 16 16 = 4 4X 2= 8 But a father cannot be a carrier of the disease as it has single
0.8
= 3.22 X-chromosome.
4.02- 4.02 In the given question, the son is colourblind which means it had
- = 5 5 X 2 = 10
H 4.02 1 1 0.8 inherited Xe from the mother. But another son is normal. This
= 4.02 shows that the mother is heterozygous for the disease.
Thus, the empirical formula of compound is Na 2 S2 H1008 • The expected cross for the question will be
As it is given the all the hydrogen atoms in the compound are xcx X 'X'(
part of water of crystallisation, therefore molecular formula will Normal Normal
be Na 2 S2O3 · 5Hp. father
75. (d) Given, latent heat of fusion of ice = 333 J/g
First X g of ice at 0° C melts and then its temperature increases

Specific heat of water = 4.184J/g K
by gaining heat from 340 g of water at 20° C. xcx xcy xx

:. Energy gained by X g of ice = energy lost by 340 g of water
'X'(
Normal Colourblind Normal Normal
[E = mc dT]
carrier son daughter son
X (333) + X X 4.184 (278 - 273) = 340 X 4.184 (293 - 278)

daughter
This shows that both the parents would be normal if they
X = 60.29 = 60.3 g
333X + 20.92X = 2 1338.4 ⇒ 353.92X = 2 1338.4 have one colourblind son and one normal son.
WWW.JEEBOOKS.INl
KVPY
Stream : SA (Nov 05)
MM : 1 00
Instructions
MATHEMATICS (b) S is the empty set

(c) S has exactly one element
1. A quadrilateral has distinct integer side lengths. If (d) S is a finite set and has at least two elements.
the second-largest side has length 10, then the
maximum possible length of the largest side is 5. Let A1 � A:i ... A9 be a nine-sided regular polygon
(a) 25 (b) 26 (c) 27 (d) 28 with side length 2 units. The difference between the
200 ! lengths of the diagonals A1 A; and A2A4 equals
2. The largest power of 2 that divides is (a) 2 + .JI2 (b) .JI2 - 2
100 !
6. Let a1 , a2 , • • • , a n be n non-zero real numbers, of
(c) 6 (d) 2
(a) 98 (b) 99 (c) 100 (d) 101
3. Let a1 , a2 , a3 , a4 be real numbers such that which p are positive and remaining are negative. The
a1 + a2 + a3 + a4 = 0 and af + a: + a; + a! = 1. Then, number of ordered pairs (j, k), j < k, for which a .ak is
positive, is 55. Similarly, the number of orderec1 pairs
the smallest possible value of the expression (j, k), j < k, for which apk is negative, is 50. Then, the
value of p2 + (n - p) 2 is
(a1 - a2 ) 2 + (a2 - a3 )2 + (a3 - a4 ) + (a4 - a1 )2 lies in
the interval
(a) 629 (b) 325 (c) 125 (d) 22 1
4. Let S be the set of all ordered pairs (x, y) of positive

(a) (0, 1.5) (b) (1.5, 2.5) (c) (2.5, 3) (d) (3, 3.5)
7. If a, b, c, d are four distinct numbers chosen from the
integers satisfying the condition x2 - I = 1 2 345 6 78. set {1, 2, 3, ... ,9}, then the minimum value of'!_ + !!. is
b d
Then, 13 25
(a) � (b) � (c) (d)
(a) S is an infinite set 8 3 36 72
WWW.JEEBOOKS.INl
8. If 72x - 43Y = 6xy , where x and y are non-zero rational

PHYSICS
numbers, then x + y equals
10 10 16. Consider the following statements (X and Y stand for
(b) (c) - 3 (d) -
two different elements):
(a) 3
3 3
9. Let AB be a line segment oflength 2. Construct a J! Jg
(I) X and Y are isotopes.
semicircle S with AB as diameter. Let C be the (II) :�x and :g Y are isotopes.
mid-point of the arc AB. Construct another semicircle
T external to the L1ABC with chord AC as diameter. (III) 114X and 1r Y have the same number of
The area of the region inside the semi-circle T but neutrons.
outside S is (IV) 92 X and 94 Yare isobars
235 235
Which of the above statements are correct?

(a) � (b) .!. (c) _1t_ (d) -1:_
2 2 J2 J2
10. Let r (x) be the remainder when the polynomial (a) Only statements II and IV are correct
+ _x125 + lf + 1 is divided by l' - x. Then,

_x1 35 _ _x1 15 (b) Only statements I, II and IV are correct
(a) r(x) is the zero polynomial

(c) Only statements II, III and IV are correct
(b) r(x) is a non-zero constant
17. A student performs an experiment to determine the
acceleration due to gravity g. The student throws a
(c) degree of r(x) is one (d) degree of r(x) is two
11. It is given that the number 43361 can be written as a steel ball up with initial velocity u and measures the
product of two distinct prime number Pi , p2 • Further, height h travelled by it at different times t. The
assume that there are 42900 numbers which are less graph the student should plot on a graph paper to
than 43361 and are coprime to it. Then, Pi + p2 is readily obtain the value of g is
(a) 462 (b) 464 (c) 400 (d) 402 (a) h versus t (b) h versus t 2
12. Let ABC be a triangle with LC = 90 . Draw CD ° (c) h versus ✓t (d) h I t versus t
perpendicular to AB. Choose points M and N on sides 18. A person goes from point P to point Q covering 1 / 3 of
AC and BC respectively such that DM is parallel to the distance with speed 10 km/h, the next 1/3 of the
BC and DN is parallel to AC. IfDM = 5, DN = 4, then distance at 20 km/h and the last 1/3 of the distance at
AC and BC are respectively equal to 60 km/h. The average speed of the person is
41 41 39 39 38 38 37 37
(a) (b) , (c) , (d) , (a) 30 km/h (b) 24 km/h (c) 18 km/h (d) 12 km/h
4' 5 4 5 4 5 4 5
19. A person looks at the image of two parallel finite
length lines PQ and RS in a convex mirror (see
13. Let A, G and H be the arithmetic mean, geometric
mean and harmonic mean, respectively of two figure).
distinct positive real numbers. Ifa is the smallest of
)_
: :
the two roots of the equation A(G - H)x2 + G(H - A) x
+ H (A - G) = 0 then,
(a) - 2 < a < - 1 (b) 0 < a < l
(c) - 1< a < 0 (d) l < a < 2
14. In the figure, ABCD is a unit square. A circle is Which of the following represents schematically the
drawn with centre O on the extended line CD and image correctly?
Note Letters P, Q, R and S are used only to denote
passing through A. If the diagonal AC is tangent to
the circle, then the area of the shaded region is
the endpoints of the lines.
Q) )'
1:---- q__-p
�S s--R
-,.,.. -
X (A) (B)
:) :)
B C Q p
s
9 - 1t 8 - 1t 7 - 1t 6 - 1t
(a) (b) (c) (d)
6 6 4 4
R
15. The sum of all non-integer roots of the equation
I - 6x4 + 11:l' - 5x2 - 3x + 2 = 0 is (C) (D)
(a) 6 (b) -11 (c) - 5 (d) 3 (a) A (b) B (c) C (d) D
M/WW.JEEBOOKS.IN]
20. In Guericke's experiment to show the effect of 25. The word KVPY is written on a board and viewed
atmospheric pressure, two copper hemispheres were through different lenses such that board is at a
tightly fitted to each other to form a hollow sphere distance beyond the focal length of the lens.
and the air from the sphere was pumped out to create
vacuum inside. If the radius of each hemisphere is R
and the atmospheric pressure is p, then the
minimum force required (when the two hemispheres
are pulled apart by the same force) to separate the First image Second image
hemispheres is Ignoring magnification effects, consider the following
(a) 2prcR
2
(b) 4prcR
2
(c) prcR
2
statements:
(I) First image has been viewed from the planar
21. Positive point charges are placed at the vertices of a side of a plano-convex lens and second image
star shape as shown in the figure. Direction of the from the convex side of a plano-convex lens.
electrostatic force on a negative point charge at the
centre O of the star is (II) First image has been viewed from the concave
from the convex side of a plano-convex lens.
(III) First image has been viewed from the concave
from the planar side of a plano-convex lens.
(IV) First image has been viewed from the planar
from the convex side of a plano-convex lens.
q
(a) towards right (b) vertically up
Which ofthe above statements are correct?
(c) towards left (d) vertically down (a) All statements are correct
(b) Only statement III is correct
22. A total solar eclipse is observed from the earth. At (c) Only statement IV is correct
the same time an observer on the moon view's the
earth. She is most likely to see (E denotes the earth)
(d) Only statements II, III and IV are correct
26. A ball is dropped vertically from height h and is
E E
bouncing elastically on the floor (see figure). Which of
the following plots best depicts the acceleration of the
A . B o ball as a function of time.
( ) ( )
E E
(D)
(C) 0 ( b)
( a)
(a) A (b) B (c) C (d) D
23. Ice in a freezer is at -7°C. 100 g of this ice is mixed
with 200 g of water at 15° C. Take the freezing
temperature of water to be 0°C, the specific heat of
ice equal to 2.2 Jig °C, specific heat of water equal to
4.2 Jlg° C and the latent heat of ice equal to 335 Jig.
Assuming no loss of heat to the environment, the (c) (d)
C
mass of ice in the final mixture is closest to
!a5 1--:-i__,___, _ �
0
��
!
(a) 88 g (b) 67 g (c) 54 g (d) 45 g
24. A point source of light is placed at 2/ from a .;i
converging lens of focal length f. A flat mirror is
placed on the other side of the lens at a distance d
such that rays reflected from the mirror are parallel 27. A student studying the similarities and differences
after passing through the lens again. If f = 30 cm, between a camera and the human eye makes the
then d is equal to following observations:
(a) 15 cm (b) 30 cm (c) 45 cm (d) 75 cm I. Both the eye and the camera have convex lenses.
WWW.JEEBOOKS.INl
II. In order to focus, the eye lens expands or 32. The stability of carbanions
contracts while the camera lens moves forward
CH3CHCH2CH3
(J
or backward.
II
III. The camera lens produces upside down real
(CHs) 3C CH3C(Ph)CH2CH3
(J
images while the eye lens produces only

upright real images. III IV
follows the order
N. A screen in camera is equivalent to the retina
in the eyes. (a) III < IV < I < II (b) I < II < IV < III
(c) III < II < I < IV (d) IV < III < II < I
V. A camera adjusts the amount of light entering
in it by adjusting the aperture of the lens. In 33. In the following reaction
the eye, the cornea controls the amount of light.
Which of the above statements are correct? � OH
V
NaOH
(a) Statements I, II and IV are correct
(b) Statements I, III and V are correct
the major product is
(c) Statements I, II, IV and V are correct
28. A particle starts moving along a line from zero initial 0
velocity and comes to rest after moving distance d.
During its motion, it had a constant acceleration f (
a) V U
over 2/3 of the distance and covered the rest of the
distance with constant retardation. The time taken to
cover the distance is
(a) -J2d / 3/ (b) 2,JdT31 (c) -J3d // (d) -J3d / 2/
29. If the image formed by a thin convex lens of power P
has magnification m, then image distance v is 34. In the reaction of 1-bromo-3-chlorocyclobutane with
(a) v = l - m (b) v = l + m (c) v = .!!!'. (d) v = 1 + 2m two equivalents of sodium in ether, the major product
p p p p
to--ol
lS
30. A long cylindrical pipe of radius 20 cm is closed at its
upper end and has an airtight piston of negligible (a) Br --0----0- CI (b)
mass as shown. When a 50 kg mass is attached to
the other end of the piston, it moves down. If the air
in the enclosure is cooled from temperature T to (c) c1 --0--0- c1
T - t,,.T, the piston moves back to its original position.
(d) �
Then t,,.T I T is close to (Assuming air to be an ideal 35. The order of basicity of
gas, g = 10 m/ s2 , atmospheric pressure is 105 Pa) N H,
02 N O
I
CJ N
0 N
H
(a) 0,01 (b) 0.02 (c) 0.04 (d) 0.09 Ill IV
CHEMISTRY
in water is
(a) IV < III < I < II (b) II < I < IV < III
(c) IV < I < III < II (d) II < III < I < IV
31. The structure of 3-methylpent-2-ene is
36. The first ionisation energy of Na, B, N and Oatoms
follows the order
(a) )=\ (b) � (a) B < Na < 0 < N (b) Na < B < 0 < N
(c) Na < 0 < B < N (d) 0 < Na < N < B
37. Among P2 05 , As2 03 , Sb203 and Bi2 03 , the most acidic
(c) � (d) oxide is
h (a) Pp5 (b) Asp3 (c) Sbp3 (d) Bip3
WWW.JEEBOOKS.INl
38. Among K, Mg, Au and Cu, the one which is extracted 50. Which one of the following statements is correct
by heating its ore in air is about the tobacco mosaic virus?
(a) K (b) Mg (c) Au (d) Cu (a) It affects all monocotyledonous plants
39. The metal ion with total number of electrons same as (b) It affects photosynthetic tissue of the infected plant
(c) It does not infect other species belonging to the
s2- is
+ 2+ Solanaceae
(a) Na (b) Ca (c) Mg2 + (d) Sr 2+
(d) It infects gymnosperms
40. X g of Ca [atomic mass = 40] dissolves completely in
51. Which one of the following statements is correct
concentrated HCl solution to produce 5.04 L of H2 gas
about placenta?
at STP. The value of X is closest to
(a) Placenta is permeable to all bacteria
(a) 4.5 (b) 8.1 (c) 9.0 (d) 16.2
(b) Oxygen and carbon dioxide cannot diffuse through the
41. A 20 g object is moving with velocity 100 ms-1 . The placenta
de Broglie wavelength (in m) of the object is
[Planck's constant h = 6.626 x 10-34 Js]
(c) Waste products diffuse out of placenta into maternal
blood
(a) 3.3 13 X 10-34 (b) 6.626 X 10-34 (d) Placenta does not secrete chorionic gonadotropins
3
(c) 3.3 13 x 10- 1 (d) 6.626 x 10-31 52. The respiratory quotient of the reaction given below is
42. In a closed vessel at STP, 50 L of CH4 is ignited with 2(C 51 H 98O6 ) + 14502 ➔ 102C02 + 90Hp + Energy
750 L of air (containing 20% 02 ). The number of (a) 0.703 (b) 0.725 (c) 0.960 (d) l.422
moles of 02 remaining in the vessel on cooling to 53. Which one of the following statements is incorrect
room temperature is closest to about nucleosomes?
(a) 5.8 (b) 2.2 (c) 4.5 (d) 6. 7
(a) They contain DNA
43. CO2 is passed through lime water. Initially the (b) They contain histones
solution turns milky and then becomes clear upon (c) They are membrane-bound organelle
continued bubbling of CO2 • The clear solution is due (d) They are a part of chromosomes
to the formation of
54. The immediate precursor of thyroxine is
(a) CaCO3 (b) CaO
(a) tyrosine (b) tryptophan
(c) Ca(OH)i (d) Ca(HCO3 )2
(c) pyridoxine (d) thymidine
44. The maximum number of electrons that can be filled
55. The maximum number of oxygen molecules that can
n = 3 is
in the shell with the principal quantum number
bind to one molecule of haemoglobin is
(a) 18 (b) 9 (c) 8 (d) 2 W8 �6 �4 00 2
45. The atomic radii of Li, F, Na and Si follow the order 56. Which one of the following biomolecules is
(a) Si> Li>Na> F (b) Li> F>Si> Na
synthesised in smooth endoplasmic reticulum?
(c) Na> Si>F> Li (a) Proteins (b) Lipids
(d) Na> Li> Si> F
(c) Carbohydrates (d) Nucleotides
BIOLOGY
57. The products of light reaction during photosynthesis
include
+
46. The major excretory product of birds is (a) ATP and NADPH (b) 02 and NADP
+
(a) urea (b) uric acid (c) 02 and H2O (d) NADP and Hp
(c) nitrates (d) ammonia 58. Hypothalamus directly controls the production of
47. Codon degeneracy means that which of the following hormones?
(a) several amino acids are coded by more than one codon (a) Glucocorticoid and insulin
(b) one codon can code for many amino acids (b) Insulin and glucagon
(c) one amino acid can be coded by only one codon (c) Atrial natriuretic factor and gastrin
(d) the codons are triplet nucleotide sequences (d) Glucocorticoids and androgens
48. In cell cycle, during interphase 59. Which one of the following drug is not obtained from
(a) two daughter cells are produced fungal or plant sources?
(b) the nucleus is divided into two daughter nuclei (a) Penicillin (b) Reserpine
(c) the chromosome condenses (c) Acetaminophen (d) Quinine
(d) the DNA is replicated 60. Jean Baptiste Lamarck explained evolution based on
49. Transfer of genetic material between population is (a) natural selection
best defined as (b) survival of the fittest
(a) gene flow (b) genetic drift (c) mutations
(c) genetic shift (d) speciation (d) inheritance of acquired characteristics
WWW.JEEBOOKS.INl

MATHEMATICS Choose the correct option.
(a) CLI > CL2 and U1 < U2 (b) CLI > CL2 and U1 > U2
6 1 . Let S be the circle in XY-plane which touches the
(c) CLI < CL2 and U1 > U2 (d) CLI < CL2 and U1 < U2
X-axis at point A, the Y-axis at point B and the unit
:c
circle + y2 = 1 at point C externally. If O denotes 67. A long horizontal mirror is next to a vertical screen
the origin, then the angle OCA equals (seen figure).
5 3 3
(a) 1t (b) � (c) 1t (d) 1t
8 2 4 4
62. In an isosceles trapezium, the length of one of the
C
a.,
parallel sides, and the lengths of the non-parallel
sides are all equal to 30. In order to maximise the
area of the trapezium, the smallest angle should be
(a) � (b) � (c) � (d) � I(----- d�
6 4 3 2 Parallel light rays are falling on the mirror at an
63. Let A1 , A2 , As be regions in the XY-plane defined by angle a from the vertical. If a vertical object of height
A1 = {(x, y) : x2 + 2y2 � 1} h is kept on the mirror at a distance (d > h ) tan a. The
length of the shadow of the object on the screen
A2 = {(x, y) : l x'3 1 + 2-v'2 l yl3 � 1} would be
As = {(x, y) : max ( I x i , -v'2 I y l ) � 1} (a) !!_
2
(b) h tan a
Then, (c) 2h (d) 4h
(a) A1 ::i A2 ::i � (b) � ::J Al ::J A2
(c) A2 ::i � ::i A1 (d) � ::i A2 ::i A1
68. A spherical marble of radius 1 cm is stuck in a
circular hole of radius slightly smaller than its own
64. Let ABCD be a square and E be a point outside radius (for calculation purpose, both can be taken
ABCD such that E, A, C are collinear in that order. same) at the bottom of a bucket of height 40 cm and
Suppose EB = ED = -J130 and the areas to L1EAB and filled with water up to 10 cm.
lJ
square ABCD are equal. Then, the area of square
ABCD is
(a) 8 (b) 10 (c) .JI2o (d) .JI25
65. Consider the set A = {1, 2, 3, ... , 30}. The number of
ways in which one can choose three distinct number
from A so that the product of the chosen numbers is
divisible by 9 is If the mass of the marble is 20 g, then the net force
(a) 1590 (b) 1505 (c) 1 1 10 (d) 1025
on the marble due to water is close to
(a) 0.02 N upwards (b) 0.02 N downwards
PHYSICS
(c) 0.04 N upwards (d) 0.04 N downwards
69. In the circuit shown below (on the left) the resistance
66. Two different liquids of same mass are kept in two and the emf source are both variable.
identical vessels, which are placed in a freezer that
extracts heat from them at the same rate causing
each liquid to transform into a solid. The schematic
figure below shows the temperature T versus time t
plot for the two materials. We denote the specific
heat in the liquid states to be CL l and CL for
2
materials 1 and 2, respectively and latent heats of
fusion U1 and U2 , respectively. V
T 2V0 - - - - - - - H
1 G
I
I
2
I0 210 I
WWW.JEEBOOKS.INl
The graph of seven readings of the voltmeter and the

ammeter (V and J, respectively) for different settings
of resistance and the emf, taken at equal intervals of
time M, are shown below (on the right) by the dots
connected by the curve EFGH. Consider the internal
resistance ofthe battery to be negligible and the
voltmeter an ammeter to be ideal devices. (Take,
Vo
Ro -=- ).
Io
Then, the plot of the resistance as a function of time
corresponding to the curve EFGH is given by
H-.C
Y= ., r Ph
(a) R (b) R CH3
�
2R0 ----------- H
Y = H3C Ph
E F
Ro
73. KMn04 reacts with H202 in an acidic medium. The
I
G
Ro/2 - - - � - - - 1
0 number of moles of oxygen produced per mole of
4/J.t 6/J.t t o 2/J.t 4/J.t 6/J.t t
KMn04 is
(a) 2.5 (b) 5 (c) 1.25 (d) 2
(c) R (d) R
2R0 - - - - - - - - - - - H 74. The photoelectric behaviour ofK, Li, Mg and Ag
metals is shown in the plot below. !flight of
I
I
wavelength 400 nm is incident on each of these
E F I
RO ,.........�� I E
Ro �
I
Ro /2 - - - � - - -
I
I
Ro/2 - - - � - - - 1G metals, which of them will emit photoelectrons?
I
O 0 [Planck's constant h = 6.626 x 10-34 Js; velocity of
O 2/J.t 4/J.t 6/J.t t o 2/J.t 4/J.t 6/J.t t
light c = 3 x 108 m s-1; 1 eV = 1.6 x 10-19 J]
70. Stokes' law states that the viscous drag force F
experienced by a sphere of radius a, moving with a
speed v through a fluid with coefficient of viscosity 11,
(a) K (b) K and Li
(c) K, Li and Mg (d) K, Li, Mg and Ag
is given by F = 61t11av. Ifthis fluid is flowing through 75. A piece of metal weighing 100 g is heated to 80°C and
a cylindrical pipe of radius r, length l and pressure
difference ofp across its two ends, then the volume of
dropped into 1 kg of cold water in an insulated
water V which flows through the pipe in time t can be

container at 15° C. If the final temperature of the
water in the container is 15.69°C, the specific heat of
written as f 1f
= k( r 11b rc, where k is a dimensionless
the metal in J/g.° C is
(a) 0.38 (b) 0.24
constant. Correct values of a, b and c are (c) 0.45 (d) 0.13
BIOLOGY
(a) a = ], b = - ], c = 4 (b) a = - 1, b = 1, c = 4
(c) a = 2, b = - 1, c = 3 (d) a = 1, b = - 2, c = - 4
CHEMISTRY
76. The nucleus of a diploid organism contains 3 ng of
DNA in G1 -phase. Which one of the following
71 . The reaction of an alkene X with bromine produces a statements describes the state of the cell at the end of
compound Y, which has 22.22% C, 3. 71 % H and S-phase?
74.07% Br. The ozonolysis of alkene X gives only one
o
product. The alkene X is,
[Given, atomic mass of C = 12; H = 1; Br = 80] >, 0
OJ �
c
(a) ethylene (b) 1-butene a5 0

c .-9!
Q) Q)
(c) 2-butene (d) 3 -hexene (.) .8
:.=: o
72. In the following reaction, Q)
-� Cl.
.r::
Hg 2 + di!. NaOH
H3 C - C - C - H � X --- Y
H p+ PhCHO
2 4 5
X and Y, respectively, are
3
Incident photon energy (eV)
WWW.JEEBOOKS.INl
(a) The nucleus divides into two and each nucleus 78. The concentration ofOI-r ions in a solution with the
contains 3 ng of DNA H+ ions concentration of 1.3 x 10-4 M is
(b) The nucleus does not divide and it contains 3 ng of
DNA (a) 7.7 X 10-4 M (b) 1.3 X 10-4 M
(c) The nucleus divides into two and each nucleus (c) 2.6 x 10-s M (d) 7.7 x 10-11 M
contains 1.5 ng of DNA 79. Given that tidal volume is 600 mL, inspiratory
(d) The nucleus does not divide and it contains 6 ng of reserve volume is 2500 mL and expiratory reserve
DNA volume is 800 mL, what is the value of vital capacity
77. Three cellular processes are listed below. Choose the of lung?
correct combination of processes that involve proton (a) 3900 mL (b) 3300 mL
gradient across the membrane. (c) 3 100 mL (d) 1400 mL
I. Photosynthesis II. Aerobic respiration 80. Which of the following organisms produces sperm
III. Anaerobic respiration without involving meiosis?
(a) II and III (b) I and II (a) Sandfly and fruitfly (b) Housefly and grasshopper
(c) I, II and III (d) I and III (c) Honeybee and ant (d) Zebra fish and frog
Answers
PART-/
(b) 2 (c) 3 (b) 4 (b) 5 (d) 6 (c) 7 (d) 8 (d) 9 (b) 10 (c)
11 (a) 12 (a) 13 (b) 14 (d) 15 (d) 16 (c) 17 (d) 18 (c) 19 (b) 20 (c)
21 (a) 22 (c) 23 (b) 24 (c) 25 (d) 26 (b) 27 (c) 28 (c) 29 (a) 30 (c)
31 (a) 32 (c) 33 (d) 34 (d) 35 (c) 36 (b) 37 (a) 38 (d) 39 (b) 40 (c)
41 (a) 42 (b) 43 (d) 44 (a) 45 (d) 46 (b) 47 (a) 48 (d) 49 (a) 50 (b)
51 (c) 52 (a) 53 (c) 54 (a) 55 (c) 56 (b) 57 (a) 58 (d) 59 (c) 60 (d)
PART-I/
61 (a) 62 (c) 63 (d) 64 (b) 65 (a) 66 (c) 67 (c) 68 (*) 69 (d) 70 (a)
71 (c) 72 (b) 73 (a) 74 (b) 75 (c) 76 (d) 77 (b) 78 (d) 79 (a) 80 (c)
WWW.JEEBOOKS.INl
Solutions
1 . (b) We have, side of quadrilateral has :. LA10� = -2 1t 81t ⇒ LAPA
X 4= -
41t
4 = -
:. ai and ak are both positive or negative.
distinct integer second largest size has 9 9 9 PC2 + n -Pc2 = 55
length 10. OA1 = OA2 = r and apk is negative j< k
Let a = 8, b = 9, c = 10, (All are distinct) In M1 0A2, apk = 50
We know, in quadrilateral Sum of three any one of ai and ak are positive:
p½ x n -Pcl = 50 ⇒ P(n - P) = 50
sides is greater than fourth side
:. a + b + c > d ⇒ 8 + 9 + 10 > d ⇒ d < 2 7
⇒ P C2 + n -Pc2 = 55
⇒ P(P - 1) + (n - P) (n - P - 1) = 1 10
:. Maximum length of 4th side is 2 6.
2. (c) Exponent of 2 in 200!.
2 00 1 2 001 1 2001 + [ 2001 + 1 2001 ⇒ P2 - P + (n - P)2 - (n - P) = 1 10
=1 + [ +
⇒ P2 + (n - P)2 - n = 1 10
⇒ {P + (n - P)}2 - 2P(n - P) - n = 1 10
L2J 7J LYJ 7J L7J
1 2007 + 1 2007 + 1 2007
⇒ n 2 - 100 - n - 1 10 = 0 [·: P(n - P) = 50]
+
L7J L7J L7J
= 100 + 50 + 2 5 + 1 2 + 6 + 3 + 1 = 197 n 2 - n - 2 10 = 0
Exponent of 2 in 100! ⇒ (n - 15) (n + 14) = 0
= 1 1001 + 1 1001 + 1 1001 + 1 1001 + 1 1001 n = 15, n ;t - 14
L2J L7J LYJ L7J L7J P(15 - p) = 50
+
1 1001 + 1 1001 A1 ⇒ p 2 - 15p + 50 = 0
L7J L7J 21t _ OA; + OAff - A1Aff
COS- - - � - �� (P - 10) (P - 5) = 0, p = 5 or 10
= 50 + 2 5 + 1 2 + 6 + 3 + 1 = 97 9 20APA2
:. P 2 + (n - P)2 = 52 + 102
:. Exponent of 2 . 21t 2r 2
-4 = 2 5 + 100 = 1 2 5
7. (d) We have,
97 COS- = - -
2 00!
= z-97 = 2100 9
= r2 -
In 2r 2
100! 2 21t
r 2 cos 2 a, b, c, d are four distinct number from
:. The largest power of 2 is 100. 9
3. (b) Given, £li + (½ + a.a + a4 = 0
the set {l, 2 , 3, ... , 9}.
r2 = 2 2
_ _ __ The minimum value of � + � is possible
2 rc 2
and 1 - cos 2 sin � b d
a; + aff + af + a! = 1 9 9
It is possible only when a = 2, b = 9, c = ], d = 8
1 1 r=- 2 1 16 + 9 2 5
when, £li = a2 = - and a.a = a4 = - - . 1t
Sln -
-+ -=- -=-
2 2 9 8 72 72
(2'3 · 32? · (24 · 3)Y = 2xy · 3xy

8. (d) Given, 72x · 4if' = 6xy
2
9
:. (Gi - a2>2 + (a2 - aa >2 + (a.a - a4 ) 8 r2 + r2 - A
1 L1i , cos- - ---2 1�Ai
1t
+ (a4 - 0i )2 • •1Q•-'f
In LUJ. �
9 2r
- ) z3 x + 4y . 32x + y = �Y . 3xy
+ ) (- i + i ) ( - ir ⇒
G i \G i \ \ -i Equating the exponent of 2 and 3, we get
0+ 1+ 0+ 1= 2 Similarly, MpA4 , 3x + 4y = xy and 2x + y = xy
The value lies between (1.5, 2 .5).
4. (b) x and y are positive integer
21t
A�4 = 2r sin On solving these equation, we get
9 -15 5
x = - and y = -
x2 - y2 = 1 2345678 :. A1� - A�4 = 2r ( sin 4 - sin 2 ) 3 3
; ;
x+ y=- + - = -
RHS 12 345678 is and even number and - 1 5 5 - 10
last digit is 8. = 2r, (2 sin � cosi ) 3 3 3
:. The last digit of x be 3, 7 9. (b) Given,
and the last digit of y be 1, 9. 2 1 AB is diameter of circle S and C is the
:. x and y must be odd and square of =-x 2 sin � x � [·.- r = - ] mid-point of arc length of AB.
sin � 9 2 sin �
difference is multiple of 8 but RHS is not 9 9
multiple of 8. C
=2
6. (c) Let p are positive number from
:. S is the empty set.
5. (d) Given, A1 , A2 , As , ... , A9 are nine
3
Gi , a2 , a.a , . . . , an
side regular polygon of each side 2 units.
Given aj , ak is positive j< k and apk = 55
:. n - p are negative number.
A1A2 = AA = As A4 = ..... = A8A9 = 2
21t
LAPA2 = - apk is positive.
9 A 0 B
WWW.JEEBOOKS.INl
AC is diameter of circle T. In WNC and WMA, 1 5. (d) Given,

AB = 2 WNC - WMA :x!' - 6x4 + 1 1:x:3 - 5x2 - 3x + 2 = 0
OA = OB = OC = 1 ⇒
DN NC (x - 1) (x - 2) (:x:3 - 3x2 + 1) = 0
Area of shaded region DM MA The sum of non-integer roots are sum of
= Area of semi-circle T + Area of ⇒ i = � ⇒ MA = 25 roots of equation
dOAC- Area of quadrant of circle S 5 MA 4 x3 - 3x2 + 1 = 0 i.e. 3.
J2
( )
2
1t - + 1 x l x l - - 1t x (l)2
25 41
:. AC = MC + AM = 4 + - = -
4 4 1 6. (c) For a nucleus, 1X
Mass number, A = N + Z
=-
1 3. (b) We have, A, G, H be arithmetic,
-
2 2 2 4
1t 1 1t 1 geometric and harmonic mean respectively
= - + - -- = - where, N = number of neutrons
4 2 4 2 of two distinct positive real numbers. and Z = number of protons.
10. (c) Let p(x) = x135 + x125 - x115 + :x!' + 1, A(G - H)x2 + G (H - A)x + H (A - G) = 0
In l�X and l�Y, number of protons are

In ��X and �t Y, number of protons are
q(x) = x3 - x and p(x) = q(x)k + r(x) Let a and � be roots of the given equation different. So, these are not isotopes.
x135 + x125 _ _x1 15 + :x!' + 1 a<�
= (:x:3 - x)k + ax2 + bx + c :. a + � =
-G (H - A) H(A - G)
⇒ a� = equal. So, these are isotopes.
[·: r(x) = ax2 + bx + c] A (G - H) A (G - H)
Put x = 0, � = lis satisfied the equation,
11
In 4 X and 1rY,
number of neutrons are
c=l i.e. AG - AH + GA - GA + HA - HG = 0 174 - 85 = 89 and 1 77 - 88 = 89.
Put x = ], 3 = a + b + c ⇒ 3 = a + b + 1 So, both have same number of neutrons.
:. One of root is 1
⇒ a+ b= 2 . . . (i) In ��5 X and �l5 Y, both have same mass
Put x = - ], - 1 = a - b + c ⇒ - 1 = a - b + 1 a = -H(A -- G)-
A(G - H) number, so these are isobars.
a- b=-2
1 7. (d) For thrown ball,
⇒ . . . (ii)
From Eqs. (i) and (ii), we get a=- AH - GH
⇒ - - 1 h 1
a = 0, b = 2 AG -AH h = ut - - gt 2 ⇒ - = u - - gt
2
G - GH 2 t 2
r(x) = 2x + 1 a=- - [·: AH = G 2]
Degree of r(x) = 1 AG -AH ⇒ !!. = -g . t + u
1 1 . (a) The distinct prime factor of G (G - H) Q t 2
a= ⇒ a= [·: A > G] Comparing with y = mx + c, graph of
4336 1 = 131 x 331 A(G - H) A
h · a straig· ht 1m -g
· e WI"th s1ope -
where A = 131and p2 = 331 a< l - versus t 1s .
Hence, 0< a < 1 t 2
1 4. (d) Given, ABCD is a square
A + p2 = 131+ 33 1 = 462
1 2. (a) Given, ABC is right angled
h
t
AB = CD = AD = BC = 1
triangle AC is tangent of circle (0, u) Slope
LC = 90° LOAC = 90° =tan0 =-2g
CD is perpendicular on AB, DN and DM LCAD = 45°
are parallel to AC and BC, respectively. LOAD = 45°
DN = 4 and DM = 5 OA = J2 From above graph, value of acceleration
B 0 due to gravity can be obtained by
0 45 ° multiplying its slope with 2.
b 1 8. (c) Let total distance is 3x km.
y
A B
IE---- X - -41(.- X ___.,__ _ X ------ll
p Q
For first part, time taken is t1 = � h
10
a
For second part, time taken is t2 = � h
20
90-0
A X For third part, time taken is t3 = � h
60
In WMC and WNB, Average speed for PQ distance
WMC - WNB :.Area of shaded region Total distance 3x
DM MC = Area of square + Area of Total time �+ �+�
DN NB MOD - Area of sector 10 20 60
⇒ � = _±_ ⇒ NB = 16
4 NB 5
= 1 + _! X 1 - � X
2 60
(J2)
2 · 1t =
3x
(6x \� + X) = 18 km/h
3
16 41 1 1t 3 1t 6 - 1t
BC = CN + NB = 5 + - = - - 1+ _ _ _ _
5 5 2 4 2 4 4
WWW.JEEBOOKS.INl
42
0
KVPY Question Paper 2017 Stream : SA
1 9. (b) For points P and Q ray diagram Hence, shadow of moon covers only a So, correct graph of acceleration and time
will be as shown below. small part of earth as shown in the figure will be as shown below.
given below. a
Earth
Shadow
of moon
23. (b) Let m gram of ice melt and water

- 9 .8 ms-2 t--- - - - - - -�
27. (c) Image produced on retina are real
Clearly image will be
reaches 0°C.
Q and inverted. We are able to perceive
p Then,
them as erect because of processing of our
⇒ miceLice + mice qce� '½ce = m,,,c,,,� Tw

Heat lost by ice = Heat gained by water
brain.
Only statement III is incorrect all other
⇒ m(335) + m(2.2) (0 - (-7)) are correct.
R s = 200 (42) (15 - 0) 28. (c)
20. (c) In Guericke's experiment,

⇒ m (335 + 15.4) = 12600
= 36g
Acceleration = f Retardation =a
12600
Jn �
⇒ m=
t= O
So, ice left in mixture is 100 - 36 = 64 g.
350.4 V1 d
A t--- - - - - --+- - - ---< V2 =0
3
u =O B C
F -� 2
Hence, nearest option is 67 g. d
24. (c) Let S is the source placed at

�
A =rcR2 Velocity of particle at the end of '!,_
If pressure difference between outside distance 2/(= 60 cm). 3
and inside is p, then � 2! � distance is Vi_.
F = p or F = pA = prcR2 I Now, by equation of motion,
s
- I
A I 2 2
2 1 . (a) Net resultant force is due to

⇒ v - u = 2as, we have
⇒ vf_ - 0 = 2/ x 'j,_ d
2
unbalanced forces of 3 q and 2 q charges. 3

2q
2f - - --->< ⇒ vf_ = � fd ⇒ Vi. = �
-J3 . .JT<l
I<-- - -
3
Image of S is formed at S' (OS' = 60 cm). As, final velocity is zero, so for next part
= 2as
As light rays after reflection from mirror of journey is
are parallel after passing through lens, 2 2
0 - v; = 2a ( ½d)
v -u
this is possible when they cross through
focus as shown in figure. Gives,
-- fd = - ad
For plane mirror, MS" = MS' 4 2
q So, OM = d = OS" + S"M ⇒
3 3
After cancellation of equal forces, we 30
= f + L = 30 + = 45 cm or deacceleration, a = - 2/
have following configuration: 2 2
25. (d) A plano-concave lens is a
q Now, using v = u + at, for first part of
Unbalanced journey,
diverging lens and a plano-convex lens is
a converging lens.
Image formed by a plano-concave lens is
---- -lf--- ➔ Resultant is more always erect and virtual.
near to large force
Image formed by a plano-convex lens is
-- - ---'r- - ++- - --- 2q real and inverted when object is placed at
For second part of journey,
Unbalanced a distance larger than focal length of lens.
V= U + at
large force Plano-convex lens is a converging lens.
Hence, net force is towards right. Hence, image formed by a plano-convex ⇒
22. (c) Size of moon is very small lens is inverted. ⇒
26. (b) Acceleration of ball at all

compared to that of earth also, moon is So, all statements are correct.
much nearer to earth in comparison to ⇒
sun. 2
instances is - 9.S ms- •
WWW.JEEBOOKS.INl
So, total time is 32. (c) Among the given carbanions

t = ti + t2 compound IV has maximum stability as ---V---
CI_____A_ Br �
Ether
�i+ �i
it is resonance stabilised, i.e. 1 -bromo-3-chlorocyclobutane
=
Qv
CH , C H,C H , � + c1-0-0-c1
= =
C
J3 i f!
Major
Minor
bicyclo [1 .1 .OJ
29. (a) Magnification is given by

o :
This reaction is an example of
/ -- v
m= -=- V Wurtz' reaction.
u f 35. (c) Among the given compounds IV
⇒ /m = f - V will have the least basicity as the lone
pair on nitrogen takes part in resonance
⇒ v = /(1 - m)
v=- -
and will not be available for donation.
1- m
⇒ Compound I will have more basicity than
30. (c) Initial pressure in cylinder is

IV, because of the availability oflone pair
than II and III because of the - I effect of

ofNH2 group. But its basicity will be less
atmospheric pressure p0 •
When mass m is attached to piston, then N02 which decreases the basicity of aniline.
pressure = p0
- mg Now between compounds II and III, II
A. will be most basic. This is because it is an
As, temperature remains constant during Among the other given carbanions, aliphatic amine and also in III, the
expansion stability order of carbanion decreases as nitrogen is present within the ring, so its
electron will not be as much available as
+ I effect of methyl groups. There is an
⇒ P;V; = Pr Vr we move from 1 ° to 3° anion because of
⇒ Pov; = (Po - 7} Vr
increased intensity of negative charge on
in IL
Thus, the order of basicity will be,
IV < I < III < IL
36. (b) As Na is an alkali metal it has
Vr _ central carbon of 3° carbanion which
7)
⇒ - Po
further makes it unstable. Thus, the
V; (Po - least ionisation energy due to its large
correct increasing order is
e e size. Rest of the three elements B, N and
v; = 1 - mg ⇒ mg = 1 - v; (CH3bC < CH3CHCH2CH 3 0 are non-metal and lie in same period.
Vr PoA PoA Vr 3' 2' So, as we move from left to right in a
Ill II
mg V1 - V; dV period the ionisation energy increases
⇒ = =
cr
due to increased nuclear charge. But,
PoA Vr Vr
N has half-filled configuration which is
Now, when temperature is reduced by 1'
stable, thus it will have maximum
33. (d)
I IV
dT, the volume of gas again contracts to ionisation energy. Thus, the correct order
its original volume. is, Na < B < 0 < N.
OH
T
⇒ V = constant 37. (a) P2O5 , As2O3 are acidic oxides,
""
v
Sb2O3 is an amphoteric while Bi2O3 is
d V dT .-0 basic oxide but P2O5 is most acidic among
or - --
T Diazonium Phenol them all. This is because down the group,
dT dV mg salt
cr
⇒ metallic character increases and metal
- - - - -
T
-
�OH oxides are more basic, thus the basicity of
V1 P<0-
metallic oxides also increases.
38. (d) Metal with low reactivity can be
⇒
N
50 x 10 N extracted by heating ore in air. This
.-0 � � process of extraction is known as
10 5 X 3.14 X (0.2)2 p-hydroxy azobenzene
(azodye)
roasting. Among the given metals, Cu has
5 102 least reactivity, so it can be directly
=- - X -�5 -� 2 This reaction is known as coupling
3.14 X 4 10 X 10- extracted by heating its ore in air.
reaction. In this reaction electrophilic
= 0.4 X 10-l = 0.04 2Cu 2S + 302 ➔ 2Cu 2O + 2SO2 t
3 1 . (a) The structure of 39. (b) Total number of electrons in
aromatic substitution takes place where
aryl diazonium cation is the electrophile -
3-methylpent-2-ene is and the activated arene is a nucleophile. s2 = 16 + 2 = 1s
5 4 34. (d) In the reaction of Total number of electrons present in the
=h
CH3-CH2 � elements given in options are as follows
2 1-bromo-3-chlorocyclobutane with two
__ /C = CH "" (i) Na+
1 equivalents of sodium in ether gives
(CH3'1 CH 3 bicyclo [1. 1.0] as a major product. Total number of electrons in
... __ .,.,,
Na+ = 1 1 - 1 = 10
WWW.JEEBOOKS.INl
50. (b) Tobacco Mosaic Virus (TMV)

2+
(ii) Ca For n=3
Total number of electrons in :. Maximum number of electrons in shell affects photosynthetic tissue of the
Ca + = 20- 2 = 18
2
with (n = 3) = 2(3)2 = 18.
45. (d) Among the given elements Li and
infected plant. Other statements can be
2+
(iii) Mg corrected as TMV affects all
Total number of electrons in Na belong to group 1, i.e. they are alkali dicotyledonous plants, of which most
Mg 2+ = 12 - 2 = 10 metals. So, they will have maximum important are tobacco and tomato. But it
(iv) Sr +
2 atomic radii. Between Li and Na, Na will does not affect any monocotyledonous
have the largest atomic radii. This is plant. TMV is a ssRNA virus, it infects a
Total number of electrons in
because as we move down the group wide range of plants, especially tobacco
Sr + = 3 8 - 2 = 36
2
2- atomic radii increases. and other members of the family

Thus, S and Ca + have same
2
Si belongs to group 14 and F belongs to Solanaceae. TMV does not infect
40. (c) Ca + 2HC1 ➔ CaC12 + H 2

number of electrons.
group 17. So, as we move from left to gymnosperms.
right in period the atomic radii decreases. 5 1 . (c) Placenta allows the foetus to
At STP 22.4 L of H 2 = l mole of H 2 Thus, Si will have large atomic radii than transfer waste products to the mother's
1 F but less than Li.
:. 5.04 of H2 = - x 5.04= 0.225 mole blood. Other statements can be corrected
X
22.4 So, the correct order of atomic radii of as Placenta gives protection against most
Number of moles of Ca = given elements is, Na>Li> Si>F. bacteria and does not allow infections to
40 46. (b) The major excretory product of enter the foetus.
X
1 mole of Ca reacts to produce 1 mole ofH 2 • birds is uric acid. Nitrogenous wastes in Placenta allows gaseous exchange via the
- moles of Ca reacts to produce 0.225 the body of animals tend to form toxic mother's blood supply, i.e. it allows
40 ammonia, which must be excreted.
diffusion ofO2 and CO2 • Placenta
X
moles of H2 gas. Mammals such as humans excrete urea,
produces hormones like human Chorionic
- = 0.225 while birds, reptiles and some terrestrial
Gonadotropin (hCG), progesterone,
X = 9.000
40 invertebrates produce uric acid as waste
oestrogen and human Placental Lactogen
4 1 . (a) Given, mass of an object = 20 g

excretory product.
(hPL).
52. (a) Respiratory Quotient (RQ)
47. (a) There are 64 codons present in
Velocity of an object = 100 ms-1 each living organism, out of which, 61
measures the ratio of the volume of
According de Broglie codons represent or code for amino acids
carbon dioxide (Ve) produced by an
and rest three are stop codons. Thus,
!!___ 6.626 X 10-3 l organism to the volume of oxygen
')..,, = = there are more codon combinations than
mv 2 0 x 10-3 x 100 consumed (V0 ). The RQ for the given
there are amino acids. The genetic code is
= 3.3 13 X 10-34 m equation is
described as degenerate because more CO2 produced 102
42. (b) CH4 + 202 ➔ CO2 + 2H2O than one codon sequence can code for the RQ = = = O.703
02 consumed 145
same amino acid.
48. (d) In cell cycle, during interphase,
of 02 in 750 L of air (containing 20%
RQ = 0.703
53. (c) Nucleosome is a structural unit of
of O2)
= � X 750 = 150 L the DNA is replicated. Interphase begins
100 with 01 -phase. During this phase, the cell a eukaryotic chromosome, consisting of a
Some of CH4 is ignited with 100 mL of 02• length of DNA coiled around a core
makes a variety of proteins that are
histone. Thus, nucleosome is not a
:. Remaining volume of 02 in vessel = 50 L needed for DNA replication. 01 -phase is
membrane bound organelle of a cell.
54. (a) Tyrosine is the immediate
22.4 L contains 1 mole of 0 2 followed by synthetic or S-phase. This
43. (d) CO2 is passed through lime water

:. 50 L contains = 1/22.4 x 50 = 22 mole. phase is responsible for the synthesis or
precursor of the thyroxine hormone.
replication of DNA. The aim of this
Thyroxine is produced in the thyroid
which initially turns the solution milky process is to produce double the amount
gland from tyrosine and iodine.
because of formation of calcium of DNA, providing the basis for the Thyrotropin Releasing Hormone (TRH) is
carbonate. On continuous bubbling of CO2 chromosome sets of the daughter cells. produced by the hypothalamus which
the solution becomes clear due to the
49. (a) Gene flow is the transfer of induces the release of thyroxine.
55. (c) The haemoglobin molecule has
formation of calcium bicarbonate.
genetic variation from one population to
Ca(OH)i + CO2 ➔ CaCO3 .j, + Hp
Lime water (Milky) another. Genetic drift is a change in the four binding sites for oxygen molecules.
frequency of an allele within a population Thus, each Hb tetramer can bind four
CaCO3 + CO2 + H 2 O ➔ Ca(HCO3 )i ( aq)
Excess Calcium bicarbonate over time. Speciation is the formation of oxygen molecules. Haemoglobin is the
(Soluble in water) new and distinct species in the course of oxygen transporting protein of red blood
44. (a) Maximum number of electrons evolution. Genetic shift is a major change cells and is a globular protein with
that can be accommodated in the shell. within a population which changes the quaternary structure. Haemoglobin
Principal quantum with number, population altogether. consists of four polypeptide subunits,
2a chains and 2� chains.
n = 2n 2
WWW.JEEBOOKS.INl
56. (b) The smooth endoplasmic during his life in order to adapt to its 30 1t 0 1t
⇒ - = - Or - = -
reticulum functions in lipid synthesis and environment, those changes are passed 2 2 2 2
metabolism, the production of steroid on to its offsprings. ⇒ 0 = � or e = 1t
hormones and detoxification. Smooth 61 . (a) OC = l radius of circle x2 + y2 = 1 3
Endoplasmic Reticulum (SER) is a OA = AP For maximum 0 = �
meshwork of five disc-like tubular 3
63. (d) Given, A1 = {(x, y) : x2 + 2y2 '.,'.; l}
LAOP = LOPA = 45°
membrane vesicles, part of a continuous
membrane organelle within the
A2 = {(x, y) : l xl3 + Wl yl3 '.,'.; l}
cytoplasm of eukaryotic cells.
57. (a) The light dependent reaction of
� = {(x, y) : max ( I x i , -v'21 Y� l)} '.,'.;
photosynthesis uses light energy to make Graph of A1 , A2 and � are
two molecules needed for the next stage
of photosynthesis. These include the
energy storage molecule ATP and the
X=-1
y= 1
../2
0
( · ii
reduced electron carrier NADPH. The J_
x2 +2/=1
light reaction takes place in the thylakoid x= 1
membranes of chloroplasts.
58. (d) Hypothalamus directly controls
AP = PC radius of circle
In l'J'CA, ( 1 , 0)
the production of glucocorticoids and
:. LPCA + LPAC + LCPA = 180°
androgens. These hormones are secreted
in response to ACTH (Adrenocorticotropic
⇒ 2LPCA + 45° = 180°
0
y = -_1__
../2 _1_)
( 0' _../2
Hormone), which is secreted from the ⇒ LPCA = 135
2
anterior pituitary gland. The ACTH is Clearly from graph A1 c A2 c �
⇒ LOCA = 180° - LPCA
released in response to corticotropin 0 64. (b) Given, area of ti..EAB = area of
135 31t
releasing hormone from the ⇒ LOCA = 180° - = 1t -
EB = ED = -JITi,o
2 8 square ABCD
hypothalamus. The pathway can be
51t
explained as ⇒ LOCA =
8
62. (c) Given ABCD is trapezium
Let side of square = x
AD = BC = CD = 30
Hypothalamus ACTH-releasing hormone BM = � = AM
.J2
Let the smallest angle be 0. D C
Pituitary I ACTH
D C
Z_J��
1
gland
/�
Adrenal gland
A M N B
Gluc oc ortic oids Androgens LDAB = 0 B
59. (c) Acetaminophen, also known as

In MMD,
AM
paracetamol is not produced by plant or cos0 = ⇒ AM = 30cos0
30
fungi, it is artificially formed. The DM
sin0 = = DM = 30sin0 E
starting material for the manufacturing
30 Area of MEB = Area of ti..BEM - area of
of paracetamol is phenol which is
Area of trapezium = � (AB + CD) DM (MMB)
nitrated to give a mixture of the ortho
2
and para-nitrotoluene. = � EM x BM - �AM x BM
⇒ A = � (60 + 60cos0) 30sin0 2 2
Other drugs are obtained as, penicillin is
2
an antibiotic obtained from ascomycetous = � BM (EM - AM)
fungi Penicillium notatum. Reserpine is ⇒ A = 900 (sin0 + sin0 cos0) 2
an alkaloid derived from the roots of ⇒
d0
dA
= 900 (cos0 - sin 20 + cos20) ✓
= � � ( 130 - � - � )
�-� [✓
Rauwolfia serpentina plant. Quinine
-�)
comes from the bark of the Cinchona . . . dA
For maximum or m1n1mum, put - = O
d0 x
tree. = x2
60. (d) Lamarck is best known for his
2
130 - :
cos0 - sin 0 + cos20 = 0
f�
-uV - = 2','2x + .J2
theory of Inheritance of Acquired ⇒ cos0 + cos20 = 0
Characteristics', first presented in 1801. 38 ⇒
It states that if an organism changes
⇒ 2cos cos_(}_ = 0
2 2 2
WWW.JEEBOOKS.INl
⇒ 130 - : =
x
(�r From similar triangles f..BGF and ti.DEF,
DE FE
From E to F,
Vo IoRo
s lope = R0
=
BG GF
we have - - -
1' Vo
2 2 ⇒
x 25 x
:. At F, resistance = R0 =
⇒ 130 - =
Io
2 2 d x
2 2 =( : )
From F to G,
⇒ 13x = 13O ⇒ x = 10
= h' + h V = V0 = constant
:. Area of square = 10
65. (a) Given, A
<_!,_
X h
=
⇒ . . . (i)
{l, 2, 3, . . . , 30}
Now, from similar triangles MEG and
But current increases, so resistance must
Case I All three number are multiple of 3
Ro V
decreases.
At G, resistance = = o.
c
then product of three number are
CE BG
MCE, we have
divisible by 9.
AG
2 2Io
From G to H, current is constant but
10 3 = 120 - - -
AE
MEG = ti.FBG
Case II Two number are multiple of 3
and other are not multiple of 9. voltage increases, so resistance
AG GF = x 2 Vo Vo
10 C X 20 ½ = 900 decreases.
Case III One are multiple of 9 and other At H, resistance = = R0

I.e. and =
H + h' h
2
Io
=
d+ x
⇒ - - - - 210
two are not multiple of 3. X
d H + h' - h
3 C7i X 2°C = 570 So, correct option is (d).
2
:. Total number of ways = 120 + 900 + 570

= 1590
⇒
X h
. . . (ii) 70. (a) From � = k ( r rt r c, 1
Equating Eqs. (i) and (ii), we get we have
h' + h H + h' - h
= = [ ML-�r
66. (c) We have, heat extracted from a
h h
2
U = Qt = mL ⇒ L ex. U
liquid during solidification, [L3r ]
l r [ML-l rl t [L]°
2h = H
Hence, height of shadow on wall is 2h.
Also, heat extracted from liquid during ⇒
a + b = 0 ⇒ - 2a - b + c = 3
Equating powers of M, L and T, we get
H = Qt = mcti.T
cooling,
68. (No option is matching)
-2a - b = - 1
Solving, we get a = 1, b = - l and c = 4
Temperature of liquid, Net force on marble due to water is
!l__ · t + T;
T 7 1 . (c) Skeletal diagram for the given
me
=
Slope of T versus t line is inversely

information can be shown as:
9 cm
X + Br2 - y
1
proportional to specific heat c.
Now, from given graph, we get 1 cm Ofln, H 2 0
T One product
G)
Fnet = (Force of water column of height -
Emperical formula for Y can be
⇒ CL1 < C12 = 1tr 2 Pwgh - Volume of marble
Slope of 2 is more 9 cm) - (Buoyant force on marble)
calculated as,
under water x Pw x g Elem- % of At
= 1tr pw gh -
Moles Simplest Simplest
� 1tr pw g
ents elem mass of molar whole
2 3
ent element ratio no.
3
= 1tr2pw g (h - � r)
C 22.22% 12 22.22/12 1.85/0.92 2 X 2
we get, U1 > U2 and CLl < CL2

= 1.85 = 2.01
67. (c) From geometry of figure, shadow = 3.14 x (l x 10-2)2 x lO00 x 10

H 3.71% 1 3.71/1 3.71/0.92 4x 2
length is CD (= H).
= 3.71 = 4.03
( 9 - �) X 10-2 Br 74.07% 80 74.07/80 0.92/0.92 1 X 2
�
= 0.92 =1
C 2
<::-
= 26 x 10- = 0.26N (downwards)
oe, � 69. (d) In given V-I graph,
:. The emperical formula of Y is C4 H8 Br2.
d o
a
According to retero synthesis.
,� e,'?l-�� H V
CH3 - CH = CH - CH3 + Br2
2V0 - - - - - - - - - H
'Q �($ � (X)
2-butene
CH3 - CH- CH-CH3
T
h' F
(sr sI y
Vo iG
I
I
IE----- x � d- x ➔
A G F E I
E I (Y)
--- - - d - - --
- I 2, 3-dibromobutane
Io 210
WWW.JEEBOOKS.INl
Also, :. (Number of eq.) KMn04 cell with 3 ng of DNA in 0 1 -phase will

= (Number of eq.) H o now have 6 ng of DNA 0 2 -phase comes
CH3 - CH = C H - CH3 + 03 2 2
1 lx 5 = x x 2 after S-phase. It is second growth phase
(X)
X = � = 2.5
... .. but here the DNA content will remain
0 .
). 'Z 6 ng.
77. (b) In photosynthesis,
74. (b) Given, wavelength ').,, = 400 nm
CH3 - - CH3
r\ ( r
photophosphorylation and in aerobic
o
0 o = 400 x 10-9 m
Energy of photon E =
he
respiration, oxidative phosphorylation
occurs that requires proton gradient. The
� I Zn/H20
').,,
6.626 x 10- Js x 3 x 108 m / s
34
sunlight-driven production of ATP from
ADP and inorganic phosphate is called
- H __J
E=
2CH3C 400 x 1 0 -11 m photophosphorylation. It occurs in the
Acetaldehyde chloroplast. Oxidative phosphorylation is
E = 497 X 10-19 J
72. (b)
the process in which ATP is formed by
_ l_ e_
V__
= 497 x 10-19 x the transfer of electrons from NADH or
_
1.6 x 10-19 J
0 FADH 2 to 02 by a series of electron
Hg 2 + II E = 3.l eV carriers. It occurs inside the
CH3 - C = C -H o H3C C - H3C mitochondria.
78. (d) [H+ ] [Of ] = 10- 14
H3 + M If the energy of incident light � work
f
PhCHO dil. NaOH function of light. Then photoelectrons will
(aldol
-4
condensation) be ejected. 1.3 X 10 X [OH-] = 10-1 4
;j
0 Thus, K and Li will emit photoelectrons [OH-] = � X 10+4 X 10-14
II as their threshold energy (obtained from 1.3
CH3 - C - CH CH- Ph graph) is less than 3.1 eV.
75. (c) Given,
(Yl = � X 10-10 = 0. 769 X 10-lO
(a, �-unsaturated ketone) 1.3
In first step one molecule of water adds to = 0.77 X 10-10 = 7.7 X 10-11 M
79. (a) Vital capacity = Inspiratory
weight of metal = 100 g
alkyne on warming with mercuric ° °
sulphate and dilute sulphuric acid to T2 = 15.69 C, Tl = 80 C
° reserve volume + Tidal volume +
form carbonyl compound, i.e. acetone. In Specific heat of water = 4184J/g C
Expiratory reserve volume
second step 2 molecules of acetone Heat gained by 100 g of metal = Heat lost
condense in presence of dil. NaOH to = 2500 mL + 800 mL + 600 mL = 3900 mL
We know, Q = me t.T
by 1000 g of water.
form a, �-unsaturated ketone. This Vital capacity is the volume of air
.'. 100 X X X (80 - 15.69)

breathed out after the deepest inhalation.
80. (c) All haploid sexually reproducing
reaction is known as aldol condensation.
73. (a) For the reaction,
-4
= lO00 x 4184 (15.69 - 15)
+7 +
organisms would produce sperms/male
2MnO4 + 5H2 0 2 + 6H ---t = lOOx (64.3 1) = 2886.96 gametes without the process of meiosis,
2 2886.96 e.g. Honeybee (Apis) and Ant (Formica).
2Mn 2+ + 8H2 -O + 50 2 X= = 0.448 = 0.45 J/g.° C
643 1 Haploid parents produce gametes by
76. (d) In the 01 -phase of cell cycle, the
Let the number of moles of oxygen mitotic division. This happens because
produced per mole KMnO4 be x. meiosis is reductional division in which
cell grows in size, i.e. the cell synthesises
Number of equivalent = Number of moles the daughter cells contain half the
various enzymes and nutrients that are
x change in oxidation state number of chromosomes as the parent
needed later on for DNA replication. The
cell. Therefore, haploid organisms do not
Number of equivalent of Hp2 = x x 2

Number of equivalent ofKMnO4 = 1 x 5 next phase of cell cycle is S-phase during
show meiosis to further disturb their
which the DNA amount doubles up, i.e. a
ploidy.
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions
MATHEMATICS 5. Let a1 , a2 , . . . , a100 be non-zero real numbers such that

1. Suppose the quadratic polynomial P(x) = a:c + bx + c a1 + a2 + ... + a100 = 0
Then,
has positive coefficients a, b, c in arithmetic
(a) ��01 ai2°i > 0 and ��01 ai2-a; < 0
progression in that order. If P(x) = 0 has integer roots
a and�- Then, a + � + a� is equal to (b) ��01 Gt 2°i � 0 and ��01 Gt 2-a; � 0
(a) 3 (b) 5 (c) 7 (d) 14 (c) ��01 £1i 2a; '.,'.; 0 and ��01 Gt 2-ai '.,'.; 0
2. The number of digits in the decimal expansion of (d) The sign of��01 ai2a; or ��01 ai2-a;
H?516 is
depends on the
choice of Gt ' s
(a) 16 (b) 17 (c) 18 (d) 19 6. Let ABCD be a trapezium, in which AB is parallel to
3. Let t be real number such that t = at + b for some CD, AB = 11, BC =4, CD = 6 and DA = 3. The distance
positive integers a and b. Then, for any choice of
2
between AB and CD is
positive integers a and b, t3 is never equal to (a) 2 (b) 2.4 (c) 2.8
(d) Not determinable with the data
4. Consider the equation (1 + a + b )2 = 3(1 + a2 + b2l ,

(a) 4t + 3 (b) St + 5 (c) lOt + 3 (d) 6t + 5
7. The points A, B, C, D, E are marked on the
where a, b are real numbers. Then, circumference of a circle in clockwise direction such
that LABC = 130° and LCDE = 110°. The measure of
(a) there is no solution pair (a,b)
LACE in degree is
(b) there are infinitely many solution pairs (a,b)
(a) 50° (b) 60°
(c) there are exactly two solution pairs (a,b)
(d) there is exactly one solution pair (a,b)
(c) 70° (d) 80°
WWW.JEEBOOKS.INl
8. Three circles of radii 1, 2 and 3 units respectively

touch each other externally in the plane. The
PHYSICS
circumradius of the triangle formed by joining the 16. A person walks 25.0° north of east for 3. 18 km. How
centers of the circles is far would she have to walk due north and then due
(a) 1.5 (b) 2 (c) 2.5 (d) 3 east to arrive at the same location?
9. Let P be a point inside a L1ABC with LABC = 90°. Let (a) Towards north 2.88 km and towards east 1.34 km
Pi and P2 be the images ofP under reflection in AB (b) Towards north 2. 1 1 km and towards east 2. 1 1 km
and BC respectively. The distance between the (c) Towards north 1.25 km and towards east 1.93 km
circumcenters of L1ABC and .PiPP2 is (d) Towards north 1.34 km and towards east 2.88 km
AP + BP + CP 17. The length and width of a rectangular room are
(a) AB (b) measured to be 3.95 ± 0.05 m and 3.05 ± 0.05 m,
2 3
AB + BC + AC
(c) AC
respectively. The area of the floor is
(d) (a) 1205 ± 0.01 m2 (b) 1205 ± 0.005 m2
(c) 1205 ± 0.34 m2 (d) 1205 ± 0.40 m2
2 2
10. Let a and b be two positive real numbers such that
a + 2b � 1. Let A1 and A2 be respectively the areas of 18. A car goes around uniform circular track of radius R at
circles with radii ab3 and b2 • Then, the maximum a uniform speed v once in every T seconds. The
Ai magnitude of the centripetal acceleration is ac. If the
possible value of is car now goes uniformly around a larger circular track
of radius 2R and experiences a centripetal acceleration
A
2
(a) -1 (b) J_ of magnitude 8ac - Then, its time period is
16 64 (a) 'XI' (b) 3T (c) T /2 (d) 3/'XJ'
(c) 1 (d) J_
1 6'12 32 19. The primary and the secondary coils of a transformer
contain 10 and 100 turns, respectively. The primary
11. There are two candles of same length and same size. coil is connected to a battery that supplies a constant
Both of them burn at uniform rate. The first one voltage of 1.5 V. The voltage across the secondary coil
burns in 5 hr and the second one burns in 3 h. Both lS
the candles are lit together. After how many minutes (a) 1.5 V (b) 0.15 V (c) 0.0 V (d) 15 V
the length of the first candle is 3 times that of the
20. Water falls down a 500.0 m shaft to reach a turbine
other?
which generates electricity. How much water must
(a) 90 (b) 120 (c) 135 (d) 150 fall per second in order to generate 1.00 x 109 W of
12. Consider a cuboid all of whose edges are integers and power ? (Assume 50% efficiency of conversion and
whose base is a square. Suppose the sum of all its g = 10 ms-2)
edges is numerically equal to the sum of the areas of (a) 250 m3 (b) 400 m3
all its six faces. Then, the sum of all its edges is (c) 500 m 3
(d) 200 m3
(a) 12 (b) 18 (c) 24 (d) 36 21. The diagram below shows two circular loops of wire
13. Let A1 , A2 , . . . . . , Am be non-empty subsets of (A and B) centred on and perpendicular to the X-axis
{ 1, 2, 3, . . . , 100} satisfying the following conditions: and oriented with their planes parallel to each other.
The Y-axis passes vertically through loop A (dashed
1. The numbers I A1 1 , I A2 1 , . . . , I Am i are distinct. line). There is a current JB in loop B as shown in the
2. A1 , A2 , . . . , Am are pairwise disjoint. diagram. Possible actions which we might perform on
(Here I Al donotes the number ofelements in the set A) loop A are
Then, the maximum possible value ofm is
y
(a) 13 (b) 14 (c) 15 (d) 16

14. The number of all 2-digit numbers n, such that n is
equal to the sum of the square of digit in its tens - X- - - ---------------x
place and the cube of the digit in units place is
wo �2 00 4
15. Let f be a function defined on the set of all positive
�1
integers such that f(xy) = f(x) + f(y) for all positive

B
integers x, y. If f(12) = 24 and f(8) = 15. The value of

/(48) is (I) move A to the right along X-axis closer to B
(a) 31 (b) 32 (c) 33 (d) 34 (II) move A to the left along X-axis away from B
WWW.JEEBOOKS.INl
(III) as viewed from above, rotate A clockwise about nucleus. The lead nucleus has A =206. The
Y-axis electrostatic force between two protons in this
(IV) as viewed from above, rotate A anti-clockwise nucleus is approximately
about Y-axis (a) 102 N (b) 107 N (c) ld-2 N (d) 1017 N
Which of the actions will induce a current in A only 26. A hollow lens is made of thin glass and in the shape
in the direction shown? of a double concave lens. It can be filled with air,
(a) Only (1) (b) Only (11) water of refractive index 1.33 or CS2 of refractive
(c) Only (1) and (IV) (d) Only (II) and (III) index 1.6. It will act as a diverging lens, if it is
(a) filled with air and immersed in water
22. A rigid ball rolls without slipping on a surface shown
below: (b) filled with water and immersed in CS2
(c) filled with air and immersed in CS2
(d) filled with CS2 and immersed in water
27. A stone thrown down with a speed u takes a time 4
to reach the ground, while another stone thrown
Which one of the following is the most likely upwards from the same point with the same speed
representation of the distance travelled by the ball takes time t2 • The maximum height the second stone
versus time graph? reaches from the ground is
w - ��
1
2
� gffi� + �2
1 (c) g/ 8(t1 - t2)2

(a)T�l;;,�c)o;lL :IL 28. An electric field due to a positively charged long
TI� TI� TI� TI�
straight wire at a distance r from it is proportional to
23. In an experiment, set up A consists of two parallel r- 1 in magnitude. Two electrons are orbiting such a
shown in the figure. A second set up B is identical to
wires which carry currents in opposite directions as long straight wire in circular orbits of radii 1 A and
t t rnt
2A . The ratio of their respective time periods is
set up A, except that there is a metal plate between (a) l : 1 (b) l : 2 (c) 2 : 1 (d) 4 : 1
the wires.
29. Two particles of identical mass are moving in circular
K is a constant. If the radii of their orbits are r1 . r2

orbits under a potential given by V(r) = Kr-n , where
and their speeds are Vi_ • v2 , respectively. Then,

(a) uf_rt = u:r2n (b) u[_r1-n = u:r2-n
(c) l{r1 = u:r2 (d) uf_r/-n = u:r22 - n
Let FA and FB be the magnitude of the force between
Set up A Set up B
30. Mercury is often used in clinical thermometers.
the two wires in setup A and setup B, respectively. Which one of the following properties of mercury is
(a) FA > Fe "# 0 (b) FA < Fe not a reason for this ?
(c) FA = Fe "# 0 (d) FA > Fe = 0 (a) The coefficient of the thermal expansion is large
(b) It is shiny
24. In the circuit, wire 1 is of negligible resistance. Then, (c) It is a liquid at room temperature
(d) It has high density
Wire 1 CHEMISTRY
31. One mole of one of the sodium salts listed below,
having carbon content close to 14.3% produces 1 mole
(a) current will flow through wire 1, if£i "# £2 of carbon dioxide upon heating (atomic mass of
(b) current will flow through wire 1, if� "# � Na = 23, H = 1, C = 12, 0 = 16). The salt is
Hi_ R2 (a) CiH5COONa (b) NaHCO3
(c) current will flow through wire 1, if f1 + f2 "'- f1 -e� (c) HCOONa (d) CH3COONa
(Hi_ + R2) (Hi_ - R2) 32. Among formic acid, acetic acid, propanoic acid and
(d) no current will flow through wire 1 phenol, the strongest acid in water is
25. The radius of a nucleus is given by r0 Al/3 , where (a) formic acid (b) acetic acid
r0 = 1.3 x 10-15 m and A is the mass number of the (c) propanoic acid (d) phenol
WWW.JEEBOOKS.INl
33. According to Graham's law, the rate of diffusion of 44. The electronic configuration, which obeys Hund's rule
CO, 02 , N2 and CO2 follows the order for the ground state of carbon atom is
(a) CO = N2 > 02 > CO2
(b) CO = N2 > CO2 > 02
(c) 02 > CO = N2 > CO2 ( a) Energy
+ + -2p
-#- 2s ( b) Energy
(d) CO2 > 02 > CO = N2
34. The major product formed when 2-butene is reacted -#- 1s -#- 1s
with 03 followed by treatment with Zn/H20 is
*if- -2p
(a) CH.i COOH (b) CH.i CHO
(c) CH.i CH2OH (d) CH2 = CH2
+ + +2p
35. The IUPAC name for the following compound is
cu -CH2- CH2- CH2- C- CH2- CH2-Cl-l
(c) Energy
2s (d) Energy
-+ 2s
II
i--a i--a -#- 1 s -#- 1s
CH2
(a) 2-propylhex-1-ene (b) 2-butylpent-1-ene 45. The graph that depicts Einstein's photoelectric effect
(c) 2-propyl-2-butylethene (d) Propyl-1-butylethene for a monochromatic source of frequency above the
threshold frequency is
36. The major products obtained in the reaction of oxalic
acid with cone. H2S04 upon heating are u u
·c ·c
(a) CO, CO2 , Hp (b) CO, SO2 , Hp t,
(1) -
C t,
(1) -
C
(c) H2S, CO, Hp (d) HCOOH, H2S, CO (a) � � (b ) <ii
0
�
�
37. Li OH reacts with CO2 to form Li2C03 (atomic mass of
- :J - :J
0 u 0 u
.c .c
CL CL
Li = 7). The amount of CO2 (in g) consumed by 1 g of
LiOH is closest to Intensity of Intensity of
(a) 0.916 (b) 1.832 radiation rad iation
(c) 0.544 (d) 1.088
u
·c
u
·c
38. The oxidation number of sulphur is - 4 in t,
(1) -
C t,
(1) -
C
(a) H2S (b) CS2 - (1)
(c) � � (d) <ii �
0 �
(c) Na2SO4 (d) Na2SO3 o u
-
0
:J
u
.c .c
CL CL
39. Al2 03 reacts with
(a) only water (b) only acids Intensity of Intensity of
(c) only alkalis (d) both acids and alkalis radiation rad iation
BIOLOGY
40. The major product formed in the oxidation of
acetylene by alk. KMn04 is
(a) ethanol (b) acetic acid
6.6 x 109 bp?
(c) formic acid (d) oxalic acid 46. What is the length of human DNA containing
41. In a closed vessel, an ideal gas at 1 atm is heated
from 27° C to 327°C. The final pressure of the gas will (a) 22 nm (b) 0.22 mm
approximately be (c) 2.2 m (d) 22 m
(a) 3 atm (b) 0.5 atm 47. The Diphtheria, Pertussis, Tetanus (DPT) vaccine
(c) 2 atm (d) 12 atm consists of
42. Among the elements Li, N, C and Be, one with the (a) live attenuated strains of diphtheria, pertussis,
Tetanus
largest atomic radius is
(b) toxoid of diphtheria, tetanus and heat-killed whole
(a) Li (b) N cells of Pertussis
(c) C (d) Be (c) whole cell lysate of diphtheria, pertussis, tetanus
(i) CdC12 + 2KOH -----+ Cd(OH\ + 2KC1

43. A redox reaction among the following is (d) heat-killed strains of diphtheria, pertussis, tetanus
(ii) BaC12 + K2S04 -----+ BaSO4 + 2KC1

48. Which of the following is not an enzyme?
(a) Lipase (b) Amylase
(iii) CaCO3 -----+ CaO + CO2 (c) Trypsin (d) Bilirubin
(iv) 2Ca + 02 ---t 2Ca0 49. The pH of the avian blood is maintained by
(a) (i) (b) (ii) (c) (iii) (d) (iv) (a) Hco;- (b) H�O4 (c) Clfs COO- (d) c1-
WWW.JEEBOOKS.INl
50. Podocyte layer that provides outer lining to the 56. Which one of the following animals is a connecting
surface of glomerular capillaries are found in link between reptiles and mammals?
(a) Bowman's capsule (b) loop of Henle (a) Platypus (b) Bat
(c) renal artery (d) ureter (c) Armadillo (d) Frog
51. If a dsDNA has 20% adenine, what would be its 57. What is the number of chromosomes in an individual
cytosine content? with Turner's syndrome?
(a) 20% (b) 30% (a) 44 (b) 45
(c) 40% (d) 80% (c) 46 (d) 47
52. Which one of the following is incapable of curing 58. 'Chipko Movement' in the year 197 4 in Garhwal
pellagra? Himalayas involved
(a) Niacine (b) Nicotine (a) protecting tigers
(c) Nicotinamide (d) Tryptophan (b) preventing soil erosion by planting trees
53. In Escherichia coli, how many codons code for the (c) preventing pollution by closing down industries
standard amino acids? (d) hugging trees to prevent the contractors from felling
(a) 64 (b) 60 them
(c) 61 (d) 20 59. Which of the following amino acids is not involved in
54. Bombyx mori (silkworm) belongs to the order gluconeogenesis?
(a) Lepidoptera (b) Diptera (a) Alanine (b) Lysine
(c) Hymenoptera (d) Coleoptera (c) Glutamate (d) Arginine
55. The source of mammalian hormone 'relaxin' is 60. Which of the following entities causes syphilis?
(a) ovary (b) stomach (a) Treponema pallidum (b) Neisseria gonorrhoeae
(c) intestine (d) pancreas (c) HIV (d) Hepatitis-B
MATHEMATICS 64. Let 81 be the sum of areas of the squares whose sides
61. Suppose a is a positive real number such that
a5 - a3 + a = 2 . Then,
are parallel to coordinate axes. Let 82 be the sum of
areas of the slanted squares as shown in the figure.
(b) 2 < a6 < 3
8
(a) a6 < 2 Then, 1 is equal to
I
(c) 3 < a < 4
6
(d) 4 '.,'.; a6 82
62. Consider the quadratic equation n:x? + 7✓nx + n = 0,

where n is a positive integer. Which of the following
I. For any n, the roots are distinct.

statements are necessarily correct?
II. There are infinitely many values of n for which

both roots are real.
III. The product of the roots is necessarily an
integer.
(a) III only (b) I and III
(c) II and III (d) I, II and III
(a) 2 (b) -J2 (c) 1 (d) ---1:_
63. Consider a semicircle of radius 1 unit constructed on -J2
the diameter AB and let O be its centre. Let C be a 65. If a 3-digit number is randomly chosen. What is the
point on AO such thatAC : CO = 2 : 1. Draw CD probability that either the number itself or some
perpendicular to AO with D on the semi-circle. Draw permutation of the number (which is a 3-digit
OE perpendicular to AD with E on AD. Let OE and number) is divisible by 4 and 5?
CD intersect at H. Then, DH equals
-J5 -1 (a) _I_ (b) � (c) � (d) _!
(a) 1 (b) 1 (c) 1 (d) 45 180 60 4
-J5 -J3 -J2 2
WWW.JEEBOOKS.INl
PHYSICS 70. A V-shaped rigid body has two identical uniform

arms. What must be the angle between the two arms,
the variation with x of the moment of inertia I of a

66. Which one of the following four graphs best depict so that when the body is hung from one end the other
arm is horizontal?
its base at a distance x from it?

1
uniform triangular lamina about an axis parallel to (a) cos-1 (1/3) (b) cos- (1/2)
(c) cos-1 (1/4) (d) cos-1 (1/6)
CHEMISTRY
7 1 . In the following reaction, X, Y and Z are
0
CH3 CH3
+ x -4 6 L &No,
(a) (b )
(b) X = CH3COCI; Y = Anhydrous AIC1 3 ; Z = HNO3 + H2 SO4

(a) X = CH3Cl; Y = Anhydrous AIC1 3 ; Z = HNO3 + H2SO4
X X
'U
(d) X = CH3Cl; Y = Dil. H2SO4; Z = HNO3
h h
(c) X = CH3Cl; Y = Cone. H2SO4; Z = HNO3 + H2SO4
(c) 72. 2,3-dibromobutane can be converted to 2-butyne in a

(
two steps reaction using
� • (a) (i) HCl and (ii) NaH
X
h
X (b) (i) ale.KOH and (ii) NaNH2
h
(c) (i) Na and (ii) NaOH
73. Given, N0(g) + 0 3 (g) ----+ NO2 (g) + 0 2 (g);

67. A rectangular block is composed of three different (d) (i) Br2 and (ii) NaH
glass prisms (with refractive indices µ1 , µ2 and µ3 )
1',.H = - 198.9 kJ/mol
as shown in the figure below. A ray of light incident
03 (g) ----+ 3 I 2 0ig); 1',.H = - 142.3 kJ/mol

normal to the left face emerges normal to the right
face. Then, the refractive indices are related by
02 (g) ----+ 20 (g); 1',.H = + 495.0 kJ/mol
The enthalpy change (1',.H)for the following reaction is
45° 45° N0(g) + 0(g) ----+ NO2 (g)
(a) -3041kJ/mol
(a) µ f + µ � = 2µ: (b) µ f + µ � = µ: (b) +304. 1 kJ/mol
(c) µ f + µ : = 2µ � (d) µ � + µ: = 2 µ f (c) -403.lkJ/mol
(d) +403. 1 kJ/mol
68. A uniform metal plate shaped like a triangle ABC
74. A 1.85 g sample of an arsenic containing pesticide
has a mass of 540 g. The length of the sides AB, BC
and CA are 3 cm, 5 cm and 4 cm, respectively. The was chemically converted to As o!- (atomic mass of
plate is pivoted freely about the point A. What mass As = 74.9) and titrated with Pb2+ to form Pb3 (AsO4 )i.
must be added to a vertex, so that the plate can hang If 20 mL of 0.1 M Pb2+ is required to reach the
with the long edge horizontal? equivalence point, the mass percentage of arsenic in
W l� g � C � 5� g � C the pesticide sample is closest to
� l� g � B 00 5 � g � B (a) 8. 1 (b) 2.3
69. A 20 g bullet whose specific heat is 5000 J kg°C and (c) 5.4 (d) 3.6
moving at 2000 m/s plunges into a 1.0 kg block of 75. When treated with cone. HCL MnO2 yields a gas (X)
wax whose specific heat is 3000 J kg°C. Both bullet which further reacts with Ca(OH)2 to generate a
and wax are at 25° C and assume that (i) the bullet
white solid (Y). The solid Y reacts with dil. HCl to
comes to rest in the wax and (ii) all its kinetic energy
produce the same gas X. The solid Y is
goes into heating the wax. Thermal temperature of
the wax (in °C) is close to (a) CaO (b) CaCl 2
(a) 28. 1 (b) 31.5 (c) 37.9 (d) 42. 1 (c) Ca(OCl)Cl (d) CaCO3
WWW.JEEBOOKS.INl
BIOLOGY
\_
a., a.,
/
ti! ti!
76. The atmospheric pressure is 760 mm Hg at the sea C C
p
uCll
0 Q. 0
level. Which of the following ranges is nearest to the ·-sCll
partial pressure of CO2 in mm Hg? a.,
a:
a.,
a:
(a) 0.30-0.31 (b) 0.60-0.61
(c) 3.0-3. 1 (d) 6.0-6.1 Temperature Temperature
I
77. A breeder crossed a pure bred tall plant having white
flowers to a pure bred short plant having blue a., a.,
(\
ti! ti!
flowers. He obtained 202 F1 progeny and found that C
they are all tall having white flowers. Upon selfing

R. S.
uCll
0 0
·-sCll
these F1 plants, he obtained a progeny of 2160 plants. a.,
a:
a.,
a:
Approximately, how many of these are likely to be
short and having blue flowers? Temperature Temperature
(a) 1215 (b) 405 (a) P and P (b) P and S
(c) 540 (d) 135 (c) P and R (d) R and R
78. Match the different types of heart given in Column I
80. Match the enzymes in Column I with the reactions in
with organisms given in Column II. Choose the
Column II. Select the correct combination.
correct combination.
Column I Column II Column I Column II
P. Neurogenic heart i. Human P. Hydrolase i. Inter-conversion of optical isomers
Q. Bronchial heart ii. King crab Q. Lyase ii. Oxidation and reduction of two
R. Pulmonary heart iii. Shark substrates
(a) P-ii, Q-iii, R-i R. Isomerase iii. Joining of two compounds

(b) P-iii, Q-ii, R-i S. Ligase iv. Removal of a chemical group from a
(c) P-i, Q-iii, R-ii substance
(d) P-ii, Q-i, R-iii v. Transfer of a chemical group from one
substrate to another
79. Given below are the four schematics that describe the
dependence of the rate of an enzymatic reaction on (a) P-iv, Q-ii, R-iii, S-i (b) P-v, Q-iv, R-i, S-iii
temperature. Which of the following combinations is (c) P-iv, Q-i, R-iii, S-v (d) P-i, Q-iv, R-v, S-ii
true for thermophilic and psychrophilic organisms?
PART-/
Answers
(c) 2 (c) 3 (b) 4 (d) 5 (a) 6 (b) 7 (b) 8 (c) 9 (c) 10 (b)
11 (d) 12 (c) 13 (a) 14 (c) 15 (d) 16 (d) 17 (c) 18 (c) 19 (c) 20 (b)
21 (a) 22 (d) 23 (c) 24 (d) 25 (a) 26 (d) 27 (b) 28 (b) 29 (a) 30 (d)
31 (b) 32 (a) 33 (a) 34 (b) 35 (a) 36 (a) 37 (a) 38 (*) 39 (d) 40 (d)
41 (c) 42 (a) 43 (d) 44 (a) 45 (c) 46 (c) 47 (b) 48 (d) 49 (a) 50 (a)
51 (b) 52 (b) 53 (c) 54 (a) 55 (a) 56 (a) 57 (b) 58 (d) 59 (b) 60 (a)
PART-I/
61 (c) 62 (b) 63 (c) 64 (a) 65 (b) 66 (a) 67 (c) 68 (c) 69 (c) 70 (a)
71 73 74 75 76 78 79 80
(a) 72 (b) (a) (c) (c) (a) 77 (d) (a) (d) (b)
WWW.JEEBOOKS.INl
Solutions
1 . (c) We have, p(x) = ax2 + bx + c, where (iii) lOt + 3 . . . (i)
a , b, c are in AP and a , b, c are positive
2
a+ b = 10, ab = 3
real. a = 3, b = 1 it is possible Also, area of
a, � are root of p(x) = 0, where a and � are (iv) 6t + 5 Af3CE = _! x BE x h
integers. 2 2
a + b = 6, ab = 5
p(x) = ax2 + bx + c = 0 a = 1, b = 5 it is also possible = .! x 5 x h . . . (ii)
-b 2
a + � = - , a� = -C Hence, option (b) is correct.
4. (d) Given,
a a From Eqs. (i) and (ii),
a, � are integer. .! x 3 x 4 = .! x 5 x h
(1 + a + b)2 = 3 (1 + a2 + b2) 2 2
h = 2.4
-b
a+�= = - A, A E I 1 + a + b2 + 2a + 2b + 2ab
2
a
7. (b) Given,
⇒
⇒ b = aA = 3 + 3a2 + 3b2
a, b, c are in AP. ⇒ 2a2 + 2b2 - 2a - 2b - 2ab + 2 = 0 LABC = 130°
b=
a+ c
⇒
a+ c
= aA ⇒ (a2 - 2a + 1) + (b2 - 2b + 1) LCDE = 1 10°
2 2 ABCE is a cyclic quadrilateral.
+ (a2 + b2 - 2ab) = 0
⇒ c = a (2A - 1)
(a - 1)2 + (b - 1)2 + (a - b)2 = 0 A
ax2 + aAX + a(2A - 1) = 0 ⇒
⇒ x2 + AX + (2A - 1) = 0 [·: a "# 0] a - 1 = 0, b - 1 = 0, a - b = 0

2 a = ], b = ], a = b
D = A- - 4 (2A - 1) is a perfect square for ⇒
integral roots. a = b= l B
2
A- - SA + 4 = k
2 Exactly one pair.
⇒ (A - 4) - 12 = k 2
2
5. (a) We have, � , a2 , £i.3 , ··· , a100 be
⇒ (A - 4 - k) (A - 4 + k) = 2 x 6 non-zero real number and
⇒ ,_, - 4 - k = 2 and ,_, - 4 + k = 6 � + a2 + aa + ... + �00 = 0
Gt . 2 ; > Gt and Gt . 2- ; < Gt
a a
·: A = 8 and k = 2 D
- b + -C 100 . 100 100 100
a + � + a� -- - :. L, � · 2 "'
> L, Gi and L, � · 2- ; < L, Gia LABC + LAEC = 180°
a a
i=l i=l i=l i=l ⇒ LAEC = 50°
- aA + a (2A - 1) 100 100
= ACDE is also cyclic quadrilateral.
a ⇒ L, � · 2 i > 0 and L, � · 2-
° a
;<0
a (A - 1) i=l i=l LCDE + LEAC = 180°
Hence, option (a) is correct. LEAC = 70°
6. (b) ABCD is a trapezium.
a ⇒
= A - 1= 8- 1= 7 In MEC,
2. (c) We have, AB is parallel to CD. LEAC + LAEC + LACE = 180°
Hf · 516 = 16· 164 · 516 AB = 1 1, BC = 4, CD = 6 and DA = 3 70° + 50° + LACE = 180°
Construct CE is parallel to DA.
⇒
= 16 X �6 · 516 LACE = 60°

8. (c) Given, radii of circle are 1, 2 and 3.
⇒
= 16 X (10)16 D 6
:. Total number of digits in Hf • 516 = 18
3. (b) Given,
t 2 = at + b, where a, b are positive 3 3
integers. t3 = at 2 + bt
⇒ t3 = a (at + b) + bt
8
t3 = a2t + bt + ab A 6 E +--- 5 -
-------- 1 1 -------
⇒
⇒ t3 = (a2 + b)t + ab
(i) 4t + 3 CE = 3
2
a + b = 4, ab = 3
BC = 4 :. Side of t.ABC are
a = ], b = 3 it is possible BE = 5 AB = 5
(ii) St + 5 :. LBCE is a right angled triangle. BC = 3
2 :.Area of Af3CE = _! EC x BC
a + b = 8, ab = 5 AC = 4
2
It is not possible
WWW.JEEBOOKS.INl
where AB is hypotenuse of triangle.

:. MBC is formed a right angled triangle 1 1 . (d) We have, length and size of two A1 n A2 nA:i ... n A,,, = 
candles are same. Let L be the length of :. A1 n A2 u As ... u A,,, = {l, 2, 3, ... , 100}
We know circumradius of a right angled candles. Let IA1 1 = 1IA21 = 2 .... IA,,,I = M
triangle is the half of the hypotenuse. Given, first candle burns in 5 h and Ai , A2 , As ... , A,,, are disjoint set.
:. Circumradius = � x AB second candle burns in 3 h.
:. IA1 1 + IA21 ... + IA,,,I= 100
2 L
In one hours length of candles are - and 1 + 2 + 3 .... + m = lO0
= � X 5 = 25 L m (m + 1) = 100
2 . 1y.
9. (c) ABC is a right angled triangle,
-, respective
3 2
LABC = 90° Let after time t h the length of candles m2 + m - 200 = 0
Circumcentre of t.ABC is mid-point of AC are Li_ and L2. ✓
-b ± b - 4ac -1± ✓1+ 4· 1· 200
2
Li_ = L - - t and L2 = L - - t
i.e. M.
L L 2a 2- 1
5 3 -1± ✓1+ 800 -1+ ✓80 1
According to the problem, 2 2
27.30
Li_ = 3L2 = -1+ 28.30 = = 16.65
L - � t = 3 ( L - ½ t)
2 2
1 + 28.30 = 29.30 = 1465
m=
⇒ 1 - � t = 3 - t ⇒ {1 - � ) = 3 - 1
2 2
:. m < 14
4t :. Maximum possible of m is 13.
⇒ = 2 ⇒t = �h
5 2 (14th set will have same size as that of
C previous size)
1 4. (c) Let two-digits number be
⇒ t = � x 60 = 150 min
n = 10a + b
2
n = a2 + b3
1 2. (c) Given, a cuboid has all edges are
Circumcentre of t.R,_PP2 is mid-point of integers and base is square. Given,
Let the length, breadth and height of 10a + b = a 2 + b3
Pi_ P2.
AB is perpendicular bisector of PR,_ and cuboid is x, x, y. a 2 - 10a + b3 - b = 0
BC is perpendicular bisector of PP2•
⇒
⇒ a (a - 10) + b (b + 1) (b - 1) = 0
Perpendicular bisector of PR,_ and PP2
intersect at B.
⇒ b (b + 1) (b - 1) = a (10 - a)
:. B is circumcentre of t,.R,_PP2•
b "# lif b = l then a = lO not possible
if b = 2, a (10 - a) = 6, no value of a
AC
:. Distance between b = 3, a (10 - a) = 24, a = 4, 6
BM = AM = MC = -- X
y Numbers are 43 and 63.
2 If b = 4, a(lO - a) = 60 no value of a
If b = 5, a (10 - a) = 120 not possible
X
1 0. (b) Given, a + 2b '.,'.; 1 a, b are positive
Sum of all edges of cuboid = 4x + 4x + 4y
real number. :. Numbers are 43 and 63.
1 5. (d) Given, /(xy) = / (x) + / (y)
Sum of area of all faces = 2x2 + 2xy + 2xy
Radius of circle cl = ab3
Given,
Radius of circle C2 = b2 /(12) = 24⇒/(8) = 15
Sum of all edges of cuboid = Sum of area
:. Area of circle cl = Al = rca2b6 / (8) = /(2· 2 - 2) = / (2) + / (2) + / (2)
of all faces
and area of circle C2 = A2 = rcb4 ⇒ 15 = 3/(2) ⇒/(2) = 5
4x + 4x + 4y = 2 (x2 + xy + xy)
A1 rca2b6
Now, = = a 2b2 ⇒ 4(2x + y) = 2 (x2 + 2xy) :. f (48) = / (12- 2- 2) = / (12) + / (2) + /(2)
A2 nh4 = 24 + 5 + 5 = 34
1 6. (d) Displacement of person is
2
⇒ x + 2xy - 4x - 2y = 0
a + 2b '.,'.; 1 ⇒ x2 + 2x(y - 2) - 2y = 0
a + 2b
⇒ '?. -J2a6 - - - -
- 2 (y - 2) ± \,I 4(y - 2)2 + 4(2y) N
2 ⇒ x = - __:.:___ __,_ __ _ _ _ _ _
[·: AM '?. GM] 2 -------- B
⇒ l'?. (a + 2b) 2 '?. &lb ⇒ X= y - 2± -Jy2 - 2y + 4 �� :
"''o '
⇒ 8ab '.,'.; 1
a2b2 '.,'.; 2
':)· 1'
x is integer, when y = 2
⇒ -----+-'-'2::..::5�
0 --'--- E
64 y = 2, x = 2 w 0 A
A1 < J:.
A2 1 3. (a) We have, A1 , A2 , Aa .... , A,,, are
Hence, sum of edges = 8x + 4y = 16+ 8 = 24
-
64
s
A non-empty subsets of {l, 2, 3, . . . , 100}
:. Maximium value of i = J:.
A2 64 IA1 I , IA21 ,••• , IA,,,I are distincts.
WWW.JEEBOOKS.INl
From above figure, distance travelled 21 . (a) Current in loop is shown 25. (a) Taking protons a t dimetrically
along north direction is anti-clockwise. opposite points of nucleus,
AB= OB sin 25° = 3.18 x sin 25° = 1.34km
Distance travelled along east direction is
OA = 3.18 x cos 25° = 2.88km
1 7. (c) Area, A = l x b
= 3.95 X 3.05 = 12.05 m 2
Now, A= lx b
dA dl db
⇒ -= -+ - Hence to induce a anti-clockwise current
A l b in A, flux going into A must be increased
l b Lead
anti-clockwise current in A. This is in
⇒ M = (� + � ) x A and by bringing A closer to B, we get a
nucleus
ke2 k · e2
0.05 0.05 accordance with Lenz's law. Force of electrostatic repulsion,
22. (d) As ball moves from point A to F = k (e)2(e) =

=( + ) X 12.05
3.95 3.05
= 0.34 point D, r oA
(r
3 2
11 ) rg . A 2/3
2
So, area of floor is A = 12.05 ± 0.34 m • Substituting values in above equation, we
1 8. (c) When car goes around track of
radius R, then
get
A
9 X 109 X (16 X 10- 19 )
2
F = ---
D
� �� - ��
15 2 Z'3
Time period, T=
2rcR C (13 X 10- ) (206)
V
= 0.039 X 102 N
region BC. Then, from C to D, it moves
Velocity of ball increases rapidly in
26. (d) When medium outside a lens is
2
R
Centripetal acceleration, ac = !!._
parabolic in region BC and slope of AB is

with a constant velocity. So, graph is denser than medium of lens, then a
less than slope of CD, as shown below.

When car goes around circular track of concave lens will acts like a convex lens
radius 2R, then and vice-versa.
D
Centripetal acceleration, X Now, when hollow lens is filled with
2 2
, v' 8v , CS2 (rt = 16) and immersed in water
a = - = - ⇒ v = 4v (rt = 133), its nature remains diverging as
C 2R R C
� straight line
refractive index of medium of lens is
So, time period of car is
+-- Parabolic curve more than refractive index of
2rcR' 2rc (2R) B
T' = = surrounding medium.
v' 4v A
27. (b) For first stone,
- - - - - - - - - - - t=O
1 2rcR T Strai ht line
=- X- -=-
u
2 V 2
1 9. (c) As primary voltage is constant,
Note Velocity change is not very abrupt.
h
there is no change of magnetic flux of 23. (c) Metal plate between wires may
secondary coil. modify field pattern within the metal
volume but number of field lines is not
So, there is no induction and hence
changed.
voltage across secondary is zero.
20. (b) Power output, P = 50% of
So, force between wires is same in both
cases and is non-zero.
potential energy of water
i.e.
24. (d)
� x ( mgh )
Received by generator per second
or ... (i)
=
100 t For second stone,
= 0.5 X (: ) p X g X h ... (i)
Here, P = l x 109 W,
g = 10 ms-2, p = 1000 kgm-3
and h = 500 m.
Current leaving the cell must be equal to h
Substituting these values in Eq. (i),
current going into the cell.
we get
loop must be zero for any value of E or R.

So, current going from first loop to second
Volume flow rate of water = � ... (ii)
t
Hence, there is no current through the
l x 109 Adding Eqs. (i) and (ii), we get
wire connecting loops.
0.5 X 1000 X 10 X 500 1 2 2
0 = u(t1 + t2 ) - - g(t1 - t2 )
WWW.JEEBOOKS.INl
⇒ 30. (d) Fluid used in a thermometer

must be easily visible, expands uniformly
Maximum height attained by second and significantly and it must be a liquid
stone is
at room temperature.
H= h+ - u2
So, density of mercury is not a feature
2g
H = uti_ + - gt12 + -
for selecting mercury in clinical
1 u2
31 . (b) NaHC03 which is a sodium salt
⇒
=o=-
thermometers.
6
2 2g
Substituting for u and rearranging, only produces carbon dioxide on heating
we get
H = _ff_ (ti_ + t2) 2
while the other salts produce ions on
+--t
heating. Also, its carbon content which is
28. (b) Electron revolve around wire due

8 close to 14.3%.
2NaHC03 ------t Na 2C03 + H20 + CO 2 Thus, the order of acidic strength of given
As field E oc r-1 ⇒ E = kr-1

to its electrostatic force of attraction.
'6'
compounds is
= 23 + 1+ 12 + 16x 3 = 84
Molecular mass of NaHC03
OH
+ % of C =
12
x 100 = 14.28%
84
32. (a) Key Idea
HCOH >CH,COOH > CH,CH,COOH >
�
11 Acetic Propanoic
O acid acid Phenol
• The substituents attached to benzoic Formic
+ acid having + I effects tends to acid
decrease its acidity. Hence, formic acid is a strongest acid.

+ • Carboxylic acids are more acidic than 33. (a) According to Graham's law, rate
phenol as they are more resonance
of diffusion is inversely proportional to
stabilised.
the square root of molar mass, i.e.
F = eE = ker-1 r oc
So, force on electron is
Among the three carboxylic acids given in 1
the options, the + I effect of CH.i group
-.J A1
----;:=
This force is necessary centripetal force. intensifies the negative charge on the
carboxylate ion thereby making acetate Thus, rate of diffusion decrease with
So,
2 ion less stable than formate ion. As a increase in molecular weight. Therefore,
mv ke the order of rate of diffusion will be
result, the release of W ion from acetic
r r
v=
acid will become more difficult as CO = N2 > 02 > CO2
fl
⇒ compared to formic acid. Hence, formic (28 g) (28 g) (32 g) (44 g)
acid is a stronger acid than acetic acid. 34. (b) The major product, formed when
As velocity of electron is independent of 2-butene is reacted with 03 followed by
radius of paths, [CH3 +-C?
0
. . }8 ? o}e
H -C . . . treatment with Zn / H20 is acetaldehyde.
⇒ --.::o --.::o This reaction is known as reductive
Acetate ion Formate ion
Now, ratio of time periods of rotation are ozonolysis.
2 1 Further since +I effect of alkyl groups
CH3CH= CH - CH3 + 03
l
-(
T1 - ( : ) _ r1 - 1.A 1
\oj_
increases in the order CH.i -< CH.i CH2- 2 butene
- - -
- the relative acid strength will decrease in
T2 2 2 � 2A. 2 the same order, i.e.,
:: ) CH3CH ': ! CH -CH3
29. (a) Given,

H C OH > CH.i COOH > CH.i CH2COOH
::
l
\ /
0
II o _;__;__ o
Potential, V = Kr- n
Now between carboxylic acids and

Ozonide
E = - dV = - _!!__ (Kr- )
So, magnitude of field, phenol, carboxylic acids are stronger Zn/H20
n acids than phenol because carboxylate
dr dr ion is more resonance stabilised. This is 2CH3 - C - H
nK
⇒ =E
n
+l
because the negative charge on the II
r carboxylate ion is delocalised over two 0
Hence, force, F = mE = -mnK1 -
Acetaldehyde
electronegative oxygen atoms.
n
r + 35. (a) The IUPAC name of the following
As particles are rotating in circular path, is
F = mv = mnKI
2 6 5 4 3 2
CH.i CH2 CH2 CH2 C CH2 CH2CH.i
n
r +
= nK = constant
r Carboxylate ion (More resonance II
2 n 1CH2
vf_rt = v�r2n
stabilised)
⇒ v r
2 propylhex-1-ene
So,
WWW.JEEBOOKS.INl
36. (a) The major products obtained in 41 . (c) According to ideal gas equation, 45. (c) According to photoelectric effect,
the reaction of oxalic acid with pV = nRT
nRT
the number of electrons ejected is
p=
cone. H2SO4 upon heating are carbon proportional to the intensity of radiation.
monoxide, carbon dioxide and water. � Thus on increasing the intensity of
COOR radiation, the value of photoelectric
I � CO + CO2 + H2O At constant volume and number of moles
p oc T
current also increases, i.e. photoelectric
COOR H2"30, current oc intensity of radiation. Hence,
Oxalic acid A = Tl its graph would be linear.
37. (a) 2LiOH + CO2 ----t Li2CO3 + H2O P2 T2
()
·c::
Number of moles of LiOH = J:_ moles T1 = 21°c = 21 + 213 = 300K t5 -
- ()Q)��
Q)
- C
24 T2 = 327°C Q)
0
2 moles of LiOH reacts with 1 mole of = 327 + 273 = 600K 0 ::::,
CO2 to form 1 mole of Li2CO3 and H2O. 1 300

1 - p2 600
:. Number of moles of CO2 = -
24 x 2 Intensity of
⇒ p2 = 2 atm radiation
= � moles 46. (c) The distance between
48 42. (a) As the given elements Li, N, C
and Be belong to same period i.e. 2nd 2 nucleotides/nitrogen bases is
1 mole of CO2 = 44 g
1 1 period, so on moving from left to right in 0.34 x 10-9 m or 3.4 A.
- moles of CO2 = - x 44 = 0.916 g a period the atomic radius decreases Therefore the length of human DNA
48 48
because the effective nuclear charge containing 6.6 x 109 bp would be
38. (*) The oxidation number of S in increases. Thus, Li has the largest atomic = 0.34 x 10-9 m x 6.6 x 109 bp
given compounds are as follows radius among them all. = 2244 m or 2.2 m
(i) H2S 43. (d) A redox reaction is one in which 47. (b) DPT is a class of combination
Let the oxidation state of S be x the oxidation and reduction reactions vaccines against three infectious diseases
.'. 2 + X = 0 occur simultaneously. in humans, i.e. diphtheria, pertussis
x=-2 (i) CdC12 + 2KOH ----t Cd(OH)2 + 2KC1 (whooping cough) and tetanus. The
(ii) CS2 This is an example of double vaccine components include diphtheria
displacement reaction. and tetanus toxoids and killed whole cells
4 + 2x = 0 ⇒ x = - 2
of the bacterium that causes pertussis.
(iii) Na 2SO4 (ii) BaC12 + K2SO4 ----t BaSO4 + 2KC1
This is a double displacement reaction. 48. (d) Bilirubin is an orange yellow
2(+1) + X+ 4(-2) = 0 pigment formed in the liver by the
Reduction
2+ x - 8= 0 breakdown of haemoglobin and excreted
x=+ 6 (iii) CaCO3 ----t CaO + CO2 in bile. It is not an enzyme. Other options
Reduction like lipase, amylase and trypsin are lipid
(iv) Na2SO3
0 0 +2 - 2 digesting, starch digesting and
2(+1) + X+ 3(-2) = 0 (iv) 2Ca + 02 ----t 2CaO endopeptidase enzymes.
49. (a) The pH of the avian blood is
2+ x - 6= 0
Oxidation
x=+ 4
maintained by bicarbonate (HCO3 ) ions.
No, option is correct. As both oxidation and reduction reaction
A variety of buffering systems exist in the
occurs simultaneously, so it is a redox
39. (d) A1p3 is an amphoteric oxide body of birds that helps to maintain the
reaction.
(those oxides which show both the pH between 7.35 and 7.45. Since the
44. (a) According to Hund's rule, 'pairing bicarbonate (HC03 ) ion is a base, it helps
properties of acids and bases), so it can
of electrons in the orbitals belonging to neutralise the acid in the blood and
react both with acids and alkalis, e.g.
same subshell does not take place until increases the pH above 7.
50. (a) Podocytes are cells of squamous
Al2O3 + HCl ----t AlC13 + H2O each orbital belonging to that subshell
Al2O3 + NaOH + H2O ----t Na[Al(OH) 4 ] has got one electron each, i.e. it is singly
epithelium of Bowman capsule of
40. (d) The major product formed in the occupied.
nephron. The Bowman's capsule filters
oxidation of acetylene by alk. KMnO4 is The electronic configuration, which obeys the blood, retaining large molecules such
oxalic acid. Hund's rule for ground state of carbon is as proteins while smaller molecules such
1s2 2s22p2. as water, salts and sugars are filtered as
CH Alk. KMn04 ICH = O 2[01
Ill +2[0J ] the first step in the formation of urine.
+ + -2p
Alk. KMn04
CH l6H = O 5 1 . (b) If dsDNA has 20% adenine, then
Acetylene Glyoxal according to the Chargaffs rule, it would
COOH
I -f- 2s have 20% thymine. The remaining 60%
COOH represents both G + C. Since guanine and
Oxalic acid
-f- 1 s cytosine are always present in equal
(Major product) numbers, the percentage of cytosine
molecule is 30%.
WWW.JEEBOOKS.INl
52. (b) Pellagra cannot be cured by 60. (a) Causative agent of syphilis is In t.OCD,
nicotine. Instead, pellagra can be cured
by giving niacine, nicotinamide and
Treponema pallidum. Syphilis is a
bacterial infection usually spreads by
CD = .joD 2 - oc2 = 1 - _1_ = 2-1
9 3
2
✓
tryptophan. Pellagra is a disease caused sexual contact that starts as a painless In MCD,
by a lack of the vitamin niacin (vitamin sore.
B3 ) which includes both nicotinic acid and Neisseria gonorrhoeae causes gonorrhoea. AD = .jCD 2 + AC2 = ✓�9 + �9
nicotinamide and its precursors, i.e. the HIV causes AIDS. Hepatitis-B virus
amino acid tryptophan. The main _ 2./3 _ 2
causes hepatitis, i.e. a liver infection.
- 3 - .J3
61 . (c) Given, a5 - a3 + a = 2
symptoms of pellagra are dermatitis,
dementia and diarrhoea. In t.DEH - t.OEA
53. (c) In all living organisms, there are ⇒ a5 - a3 + a - 2 = 0 DE DH 11./3 DH
Let / (a) a5 - a3 + a- 2
= - = - ⇒ --- = -
64 codons and out of which 3 codons are OE OA -/2 1./3 1
stop or termination codons, i.e. UAA, /' (a) = 5a4 - 3a2 + 1
UAG and UGA which do not code for any f'(a) > 0, 'd a E R
amino acids. Therefore, 61 codons code :. a5 - a3 + a - 2 = 0 has only one roots. ⇒ DH = ---1:___
for the standard 20 amino acids. for a6 = 3 ⇒ a = (3)116 = 12 [by calculation] -12
54. (a) The order of silkworm (Bombyx / (4116 ) > 0 and at a6 = 4, a = (4)116
mori) is Lepidoptera. It is the order of So one root lies in (3, 4). 64. (a) Here,
insects that includes butterflies and :. 3 < a < 4
6
moths. About 1,80,000 species of the
62. (b) Given, nx2 + 7✓n x + n = 0
Lepidoptera are described till now.
D = 49n - 4n 2 = n (49 - 4n)
D '# 0 ; :. 'd n E
55. (a) Relaxin hormone is produced by
the ovary and the placenta with r
important effects in the female :. Roots are distinct.
reproductive system and during For roots are real D � 0
pregnancy. In preparation for childbirth, 49
it relaxes the ligaments in the pelvis and :. n (49 - 4n) � 0 ⇒ n �
4
softens and widens the cervix. ,.___ _ a- - -
So, n E {l, 2, 3, 4, ... , 12} ➔
56. (a) Platypus is a connecting link
Product of roots is !1'..

So, x have finite value. 2
a + ( � )\ ( � )\ .. .
between reptiles and mammals. They Si =
have few mammalian characters such as = 1

hair, mammary glands, diaphragm n
:. Products of root is necessarily integer. 82 = +( + .. .
whereas it lays eggs with yolk and egg c; r �r
o ____
shell similar to reptiles. Hence, option (b) is correct.
63. (c) Given,
2 a2 a2 a2 4a2
57. (b) The people with Turner's Si = a + - + - + ... = - - = -
4 16 1 - _1_ 3
syndrome have 44 + XO chromosomes, 4
so there are a total of 45 chromosomes
only in each cell. Such persons are sterile a2
a2 + -
a2 + - a2 1 2 4a2
S2 = - + ... = - - = -
females who have rudimentary ovaries, 2 8 32 1 - _l_ 6
undeveloped breasts, small uterus, short 4
stature and abnormal intelligence. 4a2
58. (d) 'Chipko Movement' was headed Si = 3 =2
A 2 C 1 0 B S2 4a2 / 6
by social activist Sunder Lal Bahuguna
65. (b)The 3-digit number which is
3 3
in Uttarakhand to save trees from felling.
0 is centre of circle.
The movement got its name due to AB is diameter of circle.
divisible by 4 and 5 both.
people's action of hugging trees in order
i.e. last digits are 00, 20, 40, 60, 80
to prevent them from cutting down by OA = OB = _l_AB = 1
C is a point on AO such that
state forest contractors. 2 Now ending with 00 are (100, 200, 300 . . .
900) = 9
If digit repeat other than 0' then they are
59. (b) Lysine is not involved in AC = 2 ⇒AC = 20C
gluconeogenesis. Gluconeogenesis is the - -
biosynthesis of new glucose from certain oc 1 (220, 440, 660, 880) but 220 number can
non-carbohydrate carbon substrates like CD is perpendicular to AO. be permuted according to condition as
amino acids, etc. Out of the 20 amino :. OD = OA radius of circle (220, 202).
acids, 18 are glucogenic (i.e. can be OE is perpendicular on AD. Similarly, for 440 as (440, 404), 660 and
880, so there are 8 favourable cases.
If the number have no digit repeated like
converted to glucose upon :. AOD is isosceles triangle.
gluconeogenesis) while the remaining two :. E is mid-point of AD.
2
amino acids, i.e. lysine and leucine are OA = 1, OC = 1 AC = OD = 1 120, 120 can be permuted in 4 ways.
purely ketogenic (i.e. can be degraded 3, 3, So, such number are 8 x 4 x 4 = 128
into acetyl-Co-A).
WWW.JEEBOOKS.INl
centroid G to prevent tilting of lamina, let

Total favourable cases = 9 + 8 + 128 = 145 Weight of lamina acts through its Substituting values in above equation,
a mass mi is added at vertex B. From A,

. =-
. d probab1.11ty 145 29 we get
Reqmre =-
perpendicular AE is dropped on BC. AD
900 180 20 X 10-3 X (2000)2
66. (a) By parallel axes theorem,
t.T =
is medium and G is centroid of MBC.
2(20 X 10-3 X 5000 + 1 X 3000)
Now, consider MBC and !'-.EBA.
moment of inertia of triangular lamina 400
about a parallel axes, which passes below ⇒ t.T = 3l = 12. 9 ⇒ Tr - 'I'; = 12.9
its centre of mass is A
or Tr = 25 + 12.9 = 3 7.9° C
70. (a) Let length of each of rod is l and
4
3
angle between them is 0.
' '} xl l S
(_0__x\ ilr�➔ 3
)
l = lcM + M ( 1 - xr C 5/2 D E x B
When axis of rotation of lamina, passes MBC - f..EBA
AB BC ⇒ EB = x = -AB2 - ⇒ EB = x = -9
above its centre of mass and its moment
EB AB BC
of inertia is -=-
l = lcM + M(x - ir
5
So, DE = BD - EB
Clearly, I versus x is a parabolic graph. = -5 - -9 = -25 - 18 7

- = - cm
Also, I first reduces axis of rotation comes
2 5 10 10
Now, consider MDE, G is centroid of
MBC.
closer to centre of mass and then it again
AG 2
- = - or AG = - AD
increases.
So, correct variation of I with x is
2
GD 1
So, p
3 Ro d 1
Also, GH is parallel to DE.
AG GH
A
=
' AD DE
0
So
-;-2 AD x DE
8 Ro d 2
AG x DE 3
⇒ GH = - - = �_ _ _
_
C: O
X = h/3 AD AD
- -+ - ---' - - �---4x
mg mg
67. (c) Ray diagram of ray through the 2 7 14 7
= - X - = - = - cm Let the lower rod is horizontal and upper
3 10 30 15 rod makes 0 angle with horizontal.
For BC to remain horizontal, torque of
composition of prisms will be
downwards from their centres A and B as

Weights of rods acts vertically
mig about A must be balanced by torque
of mg about A. shown in above figure.
mg x GH = mi g x BE
acting through point A from point D is
⇒ Now, perpendicular distance of weight
7 9
CD = l cos 0 - }_ cos 0
⇒ 540 X - = mi X -
15 5
B 2
By Snell's law on surface AB and AC, we
C 540 X 7 X 5
CD = -l cos 0
⇒ mi = = 140 g
15 X 9
have µ 1 sin 45° = µ 2 sin 0 ... (i) 2
B, so that BC remains horizontal.
So, mass of 140 g must be added to vertex
acting through B from point D is
and µ3 sin 45 = µ 2 cos 0
° ... (ii) and perpendicular distance of weight
69. (c) As kinetic energy of bullet is used
BD = }_ - l cos 0 = l (1 - 2 cos 0)
As a - 0 = 45 , from figure
°
Squaring and adding Eqs (i) and (ii), up in heating and melting the wax. 2 2
µ 12 + µ32 = � By energy conservation, we have
we get µ At equilibrium torque of these two
2 2
68. (c) Given situation is
1
2 lnt,vt;2 = Tnu,c;,, (t.Tw ) + 111t, q, (t.'11, ) weights about D must balance each other,
.
1.e. l e l
mg x - cos = mg x - (1 - 2 cos 0)
As both bullet and wax initially are at 2 2
same temperature ('I'; = 25° C).
⇒ � cos 0 = .!
So, t.Tw = t.'z;, = t.T (say) 2 2
1
Then, - 111t,q;2 = (1nu,c;,, + 111t, q, ) t.T ⇒ cos 0 = .!
2
530 B
3
C D
or or 0 = cos-1 (1)
WWW.JEEBOOKS.INl
6:
7 1 . (a) For the given reaction, 74. (c) 3Pb2+ + 2AsO4 -----t Pba (AsO4 )2 77. (d)
3 2+
TTWW x ttww
Tall plant Short plant
0
3 moles of Pb reacts with 2 moles AsO4
(with white) ( with blue )
:. 1 mole of Pb will react with flowers flowers
+ C H CI
3 -
Anhyd. AICl3 M
F
-rie
- d-
el-
-C
� ra-
ft'-
s-
2
= - moles of AsO 4 L
,,,
_,,.,, 3 TtWw
(X) reaction
(Tall plant with white flower) (202 plants)
L
Benzene Toluene Normality = Molarity x Volume
Selfing
"'°'""°•'"' NPb 2 + = 0.1 X 3
V
� = 2 X 10- Obtained 21 60 plants total
� NO, 1000
According to dihybrid phenotypic ratio
Nitration N,� = � X 2 X 10-3 = 0.00133 9 : 3 : 3 : 1,
�4 3
2- nitro toluene TW - 9
NAs = N 3_ = 0.00133
Ag;) 4
Tw - 3
When benzene reacts with CHaCl in
WAs = NAs x MassAs tW - 3
presence of anhyd.A1Cl3 , then toluene is
formed. This reaction is known as = 0.00133 X 749 tw - 1
Friedel-Craft's reaction. The formed = 0.0996 The total number of short and blue
toluene then undergoes nitration to give 0 · 0996 flowered plants is
% of As = x 100
2-nitrotoluene. 1080
72. (b) For the conversion of
1.85 _!_ X 2 130 = = 135
78. (a) P-ii, Q-iii, R-i

= 5.38 16 8
2,3 -dibromobutane to 2-butyne following = 5.4%
steps can be used
75. (c) When treated with conc.HCl, - A neurogenic heart requires
Step 1 MnO2 yields a chlorine gas (X), which nervous input to contract. It is seen
in crustaceans like king crab.
further reacts with Ca(OH) 2 to generate
Ale.KOH calcium oxychloride CaOC1 2(Y), which is - Bronchial hearts are myogenic
-HBr accessory pumps found in coleoid
2, 3-dibromobutane a white solid that then reacts with dil.
Br cephalopods like shark that
HCl to produce again chlorine gas (X).
I The equations can be written as
supplement the action of the main,
CH
3 - C H = C - C H3 systemic heart.
2-bromo but-2-ene MnO 2 + HCl (cone.) -----t Cl2 (g) - Pulmonary heart is found in humans
In this step, dehydrohalogenation occurs X
where the portion of the circulatory
where 2,3-dibromobutane gets converted Ca(OH) 2 + Cl2 -----t CaOCl2
y system carries deoxygenated blood
into 2-bromobut-2-ene. away from the right ventricle of the
CaOCl2 + dil. HCl -----t Cl2 + CaC12 + H2O
Step 2 (X) heart to the lungs and returns
oxygenated blood to the left atrium
76. (a) pCO2 = 0.30 - 0.3 1mm Hg in air.
Br Thus, solid Y is Ca(OCl)Cl.
I and ventricle of the heart.
79. (d) Both thermophiles and
-NaBr
CH3- CH = C - CH3 + NaNH2 �
Air contains 0.04% of carbon dioxide. psychrophiles will show same enzymatic
CH
3 - C= C - CH3 This means that in every 100 molecules reaction graph. Mostly proteinaceous
In this step, also dehydrohalogenation of air, 0.04 will be CO2 molecules. enzymes are labile to temperature.
occurs where alkenyl halide on treatment The number of moles of carbon dioxide in Thermophiles live at very high
73. (a) Given,

with soda amide gives 2-butyne. 100 molecules of air will be temperature while psychrophiles live in
nCO 2 = 0.04 molecules x NA = 0.04 x NA the range of-20° C to +10° C. In either
NO(g) + 0:J (g) -----t NOig) + O (g); 2 The total number of moles in the sample case, rising temperature will first raise
/J.H1 = - 198.9 kJ/mol of air will be the rate of reaction but if temperature is
still raised continuously, enzymes get
3
03 -----t - O2 (g) /J.H2
n10w = 100 molecules x NA = lO0NA
80. (b) P-v, Q-iv, R-i, S-iii

denatured, hence reaction rate decreases.
2 This means that mole fraction of carbon
= - 142.3 kJ/mol dioxide in the mixture will be
- Hydrolases catalyse transfer of a
02 -----t 202 (g) /J.H3 = + 495.0 kJ/mol xco 2=
0.04N
,1, = 0.0004
chemical group from one substrate
For the reaction, lO0NA
to another.
NO(g) + O(g) -----t NOig) Carbon dioxide's partial pressure in air
- Lyase catalyses removal of chemical
1 will thus be
/J.H = /J.Hl - /J.H2 - - /J.H3 groups from a substrate.
2 pCO 2 = 0.0004 x 760 mm Hg - Isomerase catalyses interconversion
1 = 0.304mm Hg of optical, geometric or positional
= - 198.9 - (-142.3) - - X 495
2 :. We can say it ranges between isomers.
= - 3041kJ/mol 0.30-0.31 mm Hg. - Ligase catalyses linking together of
two compounds.
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions
2. This question paper contains two parts; Part I and Part I I . There are four sections; Mathematics, Physics, Chemistry
MATHEMATICS 4. In the figure given below, a rectangle of perimeter

76 units is divided into 7 congruent rectangles.
1 . Two distinct polynomials f(x) and g(x) are defined as
follows:
f(x) = :C + ax + 2; g(x) = x2 + 2x + a.
If the equations f(x) = 0 and g(x) = 0 have a common
f(x) + g(x) = 0 is
root, then the sum of the roots of the equation
(a) - �
2
(b) O (c) �
2
(d) l
I I
What is the perimeter of each of the smaller
rectangles?
2. If n is the smallest natural number such that
5. The largest non-negative integer k such that 24k
(a) 38 (b) 32 (c) 28 (d) 19
n + 2n + 3n + . . . + 99n is a perfect square, then the
number of digits of n2 is
divides 13! is
3. Let x, y, z be positive reals. Which of the following
(a) 1 (b) 2 (c) 3 (d) more than 3
W2 �3 �4 00 5
I. x3 + y3 + z3 = 3xyz II. x3 + y 2z + yz 2 = 3xyz

6. In a L1ABC, points X and Y are on AB and AC,
implies x = y = z ?
the two following equalities always hold? (Here [PQR]
III. x3 + y 2z + z 2x = 3xyz N. (x + y + z)3 = 27 xyz
respectively, such that XY is parallel to BC. Which of
denotes the area of L1PQR).

(a) I, IV only (b) I, II and IV only I. [BCX] = [BCY]
(c) I, II and III only (d) All of them II. [ACX] · [AB Y] = [AXY] · [ABC]
WWW.JEEBOOKS.INl
(a) Neither I nor II (b) Only I 15. How many ways are there to arrange the letters of
(c) Only II (d) Both I and II the word EDUCATION so that all the following
7. Let P be an interior point of a L1ABC. Let Q and R be three conditions hold?
the reflections of P in AB and AC, respectively. If - the vowels occur in the same order (EUAIO),
Q, A, R are collinear, then LA equals - the consonants occur in the same order (DCTN),
(a) 30° (b) 60° (c) 90° (d) 120° - no two consonants are next to each other.
8. Let ABCD be a square of side length 1, and r a circle (a) 15 (b) 24 (c) 72 (d) 120
passing through B and C, and touching AD. The
radius ofr is
1
PHYSICS
(a) -3 (b) -1 (c) - (d) _!"!
8 2 J2 8 16. In an experiment, mass of an object is measured by
9. Let ABCD be a square of side length 1. Let P, Q, R, S applying a known force on it, and then measuring its
acceleration. If in the experiment, the measured
be points in the interiors of the sides AD, BC, AB, CD
respectively, such that PQ and RS intersect at right
values of applied force and the measured acceleration
are F = 10.0 ± 02 N and a = 1.00 ± 0.01 m/s 2 ,
angles. If PQ = , then RS equals
3../3
respectively. Then, the mass of the object is
4
(a) 10.0 kg (b) 10.0± 0.1 kg
(a) _!_ (b) 3J3 (c) 10.0± 0.3 kg (d) 10.0± 0.4 kg
-J3 4
17. A hollow tilted cylindrical vessel of negligible mass
(c) J2 + 1 (d) 4- W rests on a horizontal plane as shown. The diameter of
the base is a and the side of the cylinder makes an
2
10. In the figure given below, if the areas of the two angle 0 with the horizontal.Water is then slowly
regions are equal then which of the following is true? poured into the cylinder. The cylinder topples over
when the water reaches a certain height h, given by
2y
y y
X X
h
(a) X = y (b) x = 2y
(c) 2x = y (d) x = 3y �- 0
-� -- - - - - - - - - - - - - - - -
11. A man standing on a railway platform noticed that a
train took 2 1 s to cross the platform (this means the (a) h = 2atan0 (b) h = atan 2 0
time elapsed from the moment the engine enters the
platform till the last compartment leaves the (c) h = atan0 (d) h = � tan0
2
platform) which is 88 m long, and that it took 9 s to
pass him. Assuming that the train was moving with 18. An object at rest at the origin begins to move in the
uniform speed, what is the length of the train in + x-direction with a uniform acceleration of 1 m/s 2 for
meters? 4 s and then it continues moving with a uniform
(a) 55 (b) 60 velocity of 4 m/s in the same direction.The x -t graph
(c) 66 (d) 72 for object's motion will be
12. The least positive integer n for which
Vn + 1 - Vn < _l__ is
X
12
6 � 7 �s 00 9
(a)
W
( b)
13. Let n > 1 be an integer. Which of the following sets of

numbers necessarily contains a multiple of 3? 4s 4s
(a) n19 - 1, n19 + 1 (b) n19 , n38 - 1
(c) n , n + 1
ss ss
(d) nss , n19 - 1
14. The number of distinct primes dividing 12 ! + 13 ! + 14 ! (c) (d)
lS
(a) 5 (b) 6 (c) 7 (d) 8
WWW.JEEBOOKS.INl
1 9. If the axis of rotation of the earth were extended into 26. A light bulb of resistance R = 16 Q is attached in
space, then it would pass close to series with an infinite resistor network with identical
(a) the moon resistances ras shown below. A 10 V battery drives
(b) the sun current in the circuit. What should be the value of r
(c) the pole star such that the bulb dissipates about 1 W of power.
(d) the centre of mass of all the planets in the solar system
r r r
R
20. Methane is a greenhouse gas because
(a) it absorbs longer wavelengths of the electromagnetic
�
spectrum while transmitting shorter wavelengths
(b) it absorbs shorter wavelengths of the electromagnetic ----------
spectrum while transmitting longer wavelengths
(c) it absorbs all wavelengths of the electromagnetic (a) 14.8 Q (b) 29.6 Q (c) 7.4 Q (d) 3.7 Q
spectrum 27. A ball is launched from the top of Mt. Everest which
(d) it transmits all wavelengths of the electromagnetic is at elevation of 9000 m. The ball moves in circular
the earth's surface is g. The magnitude of the ball's

spectrum orbit around earth. Acceleration due to gravity near
21 . A parachutist with total weight 75 kg drops vertically
onto a sandy ground with a speed of 2 ms -1 and acceleration while in orbit is
comes to halt over a distance of 0.25 m. The average (a) close to g I 2 (b) zero
force from the ground on her is close to (c) much greater than g (d) nearly equal to g
U denote the potential energy and K denote the

(a) 600 N (b) 1200 N 28. A planet is orbiting the sun in an elliptical orbit. Let
(c) 1350 N (d) 1950 N
22. The !3-particles of a radioactive metal originate from kinetic energy of the planet at an arbitrary point on
(a) the free electrons in the metal the orbit. Choose the correct statement.
(b) the orbiting electrons of the metal atoms (a) K I UI always
(d) the nucleus of the metal atoms (c) K = I UI always
(d) K = I UI for two positions of the planet in the orbit
23. An optical device is constructed by fixing three
identical convex lenses of focal lengths 10 cm each 29. One mole of ideal gas undergoes a linear process as
inside a hollow tube at equal spacing of 30 cm each. shown in the figure below. Its temperature expressed
One end of the device is placed 10 cm away from a as a function of volume V is
point source. How much does the image shift when
the device is moved away from the source by another
10 cm?
(a) 0 (b) 5 cm (c) 15 cm (d) 45 cm
24. An isosceles glass prism with base angles 40° is
clamped over a tray of water in a position such that (0, 0) V0
the base is just dipped in water. A ray of light
incident normally on the inclined face suffers total
internal reflection at the base. If the refractive index
of water is 1 .33, then the condition imposed on the
refractive index µ of the glass is
(a) µ < 207 (b) µ > 207
(c) µ < l74 (d) µ > l74 30. The international space station is maintained in a
nearly circular orbit with a mean altitude of 330 km
25. A point source of light is moving at a rate of 2 cms - 1 and a maximum of 410 km. An astronaut is floating
towards a thin convex lens of focal length 10 cm in the space station's cabin. The acceleration of
along its optical axis. When the source is 15 cm away astronaut as measured from the earth is
from the lens, the image is moving at
(a) zero
(a) 4 cms-1 towards the lens (b) nearly zero and directed towards the earth
(b) 8 cms-1 towards the lens (c) nearly g and directed along the line of travel of the
(c) 4 cms-1 away from the lens station
(d) 8 cms-1 away from the lens (d) nearly g and directed towards the earth
WWW.JEEBOOKS.INl
CHEMISTRY 42. Among Mg, Cu, Fe, Zn the metal that does not
produce hydrogen gas in reaction with hydrochloric
31 . The percentage of nitrogen by mass in ammonium acid is
sulphate is closest to (atomic masses of H = 1, N = 14, (a) Cu (b) Zn
0 = 16, S = 32) (c) Mg (d) Fe
(a) 21% (b) 24% 43. The maximum number of isomeric ethers with the
(c) 36% (d) 16% molecular formula C4H10 0 is
32. Mendeleev's periodic law states that the properties of W2 �3 �4 �5
elements are a periodic function of their 44. The number of electrons required to reduce chromium
(a) reactivity of elements (b) atomic size completely in Cr20�- to Cr3+ in acidic medium, is
(c) atomic mass (d) electronic configuration
(a) 5 (b) 3 (c) 6 (d) 2
33. Maximum number of electrons that can be
45. At constant pressure, the volume of a fixed mass of a
accommodated in the subshell with azimuthal
gas varies as a function on temperature as shown in
quantum number l = 4, is
the graph
(a) 10 (b) 8 (c) 16 (d) 18
34. The correct order of acidity of the following
compounds is 500
400
§ 300
COOH 200
1 2 3
(a) 1 > 2 > 3 (b) 1 > 3 > 2 (c) 3 > 1 > 2 (d) 3 > 2 > 1 1 00
0 1 00 200 300
35. Reaction of 2-butene with acidic KMn04 gives TJ C°
(a) CH3CHO (b) HCOOH The volume of the gas at 300°C is larger than that at
(c) CH3CH2OH (d) CH3COOH 0° C by a factor of
36. The gas released when baking soda is mixed with W3 �4 �1 �2
BIOLOGY
vinegar is
(a) CO (b) CO2
37. The element which readily forms an ionic bond has
the electronic configuration 46. Excess salt inhibits bacterial growth in pickles by
(a) 1s22s22p3 (b) 1s22s22p1 (a) endosmosis (b) exosmosis
2 2
(c) 1s 2s 2p 2 (d) 1s2 2s2 2p 6 3s1 (c) oxidation (d) denaturation
38. The major products of the following reaction, 47. Restriction endonucleases are enzymes that are used
by biotechnologists to
ZnS(s) + O2 (g) Heat . . . . . . . . . are (a) cut DNA at specific base sequences
(a) ZnO and SO2 (b) ZnSO4 and SO3 (b) join fragments of DNA
(c) ZnSO4 and SO2 (d) Zn and SO2 (c) digest DNA from the 3' end
39. If Avogadro's number is A0, the number of sulphur (d) digest DNA from the 5' end
atoms present in 200 mL of lN H2S04 is 48. Enzyme X extracted from the digestive system
hydrolyses peptide bonds. Which of the following is
(a) Ao (b) Ao (c) Ao (d) A° probable candidate to be enzyme X?
5 2 10
(a) Amylase (b) Lipase
40. The functional group present in a molecule having (c) Trypsin (d) Maltase
the formula Ci2 0 9 is
(a) carboxylic acid (b) anhydride 49. A person with blood group AB has
(c) aldehyde (d) alcohol (a) antigen A and B on RBCs and both anti-A and anti-B
antibodies in plasma
41. A sweet smelling compound formed by reacting acetic (b) antigen A and B on RBCs, but neither anti-A nor
acid with ethanol in the presence of hydrochloric acid anti-B antibodies in plasma
lS (c) no antigen on RBCs but both anti-A and anti-B
(a) CH.i COO Ci\ (b) Ci\ COOH antibodies are present in plasma
(c) CiH5COOCH3 (d) CHpH (d) antigen A on RBCs and anti-B antibodies in plasma
WWW.JEEBOOKS.INl
50. Glycolysis is the breakdown of glucose to pyruvic 56. Widal test is prescribed to diagnose
acid. How many molecules of pyruvic acid are formed (a) typhoid (b) pneumonia
from one molecule of glucose? (c) malaria (d) filaria
Wl �2 �3 00 4 57. Which among grass, goat, tiger and vulture in a food
51. The process of the transfer of electrons from glucose chain, will have the maximum concentration of
to molecular oxygen in bacteria and mitochondria is harmful chemicals in its body due to contamination
known as of pesticides in the soil?
(a) TCA cycle (b) oxidative phosphorylation (a) Grass since it grows in the contaminated soil
(c) fermentation (d) glycolysis (b) Goat since it eats the grass
52. Which one of the following cell types is a part of (c) Tiger since it feeds on the goat which feeds on the grass
innate immunity? (d) Vulture since it eats the tiger, which in turn eats the
(a) Skin epithelial cells (b) B-cells goat, which eats the grass
(c) T-lymphocytes (d) Liver cells 58. Considering the average molecular mass of a base to
53. Deficiency of which one of the following vitamins can be 500 Da, what is the molecular mass of a
cause impaired blood clotting? double-stranded DNA of 10 base pairs?
(a) Vitamin-B (b) Vitamin-C (a) 500 Da (b) 5 kDa (c) 10 kDa (d) 1 kDa
(c) Vitamin-D (d) Vitamin-K 59. Which of the following pairs are both
54. Which one of the following is detrimental to soil polysaccharides?
fertility? (a) Cellulose and glycogen
(a) Saprophytic bacteria (b) Nitrosomonas (b) Starch and glucose
(c) Nitrobacter (d) Pseudomonas (c) Cellulose and fructose
(d) Ribose and sucrose
55. In which one of the following phyla is the body
segmented? 60. Which one of the following is a modified leaf?
(a) Porifera (b) Platyhelminthes (a) Sweet potato (b) Ginger
(c) Annelida (d) Echinodermata (c) Onion (d) Carrot
MATHEMATICS 64. Given are three cylindrical buckets X, Y, Z whose

61. A triangular corner is cut from a rectangular piece of circular bases are of radii 1, 2, 3 units, respectively.
Initially water is filled in these buckets upto the
same height. Some water is then transferred from Z
paper and the resulting pentagon has sides 5, 6, 8, 9,
12 in some order. The ratio of the area of the
pentagon to the area of the rectangle is to X so that they both have the same volume of
11 13 water. Some water is then transferred between X and
(a) (b) (c) 1 5 (d) 17
18 18 18 18 Y so that they both have the same volume of water. If
62. For a real number x, let [x] denote the largest integer hy , hz denote the heights ofwater at this stage in
less than or equal to x, and let {x} = x - [x]. The the buckets Y, Z, respectively, then the ratio hy
number of solutions x to the equation [x] {x} = 5 with hz
0 � x � 2015 is equals
(a) 0 (b) 3 (c) 2008 (d) 2009 (a) -4 (b) 1 (c) -9 (d) 81
63. Let ABCD be a trapezium with AD parallel to BC. 9 4 40
Assume there is a point M in the interior of the 65. The average incomes of the people in two villages are
segment BC such that AB = AM and DC = DM. Then, P and Q, respectively. Assume that P ,t. Q. A person
the ratio of the area of the trapezium to the area of moves from the first village to the second village. The
1',.AMD is new average incomes are P and (l, respectively.
(a) 2 Which of the following is not possible?
(b) 3 (a) P' > P and Q' > Q (b) P' > P and Q' < Q
(c) 4 (c) P' = P and Q' = Q (d) P' < P and Q' < Q
(d) not determinable from the data
WWW.JEEBOOKS.INl
PHYSICS 70. Stokes' law states that the viscous drag force F
speed v through a fluid with coefficient of viscosity 11,

experienced by a sphere of radius a, moving with a
66. A girl sees through a circular glass slab (refractive
index 1.5) of thickness 20 mm and diameter 60 cm to is given by F = 61t11av.
the bottom of a swimming pool. Refractive index of If this fluid is flowing through a cylindrical pipe of
water is 1.33. The bottom surface of the slab is in radius r, length l and a pressure difference of p across
contact with the water surface. its two ends, then the volume of water V which flows
through the pipe in time t can be written as
I I
f b c
� = k ( )\ r
where, k is a dimensionless constant. Correct value of

a, b and c are
------------------------------------- (a) a = 1, b = - ], c = 4
The depth of swimming pool is 6 m . The area of (b) a = - 1, b = 1, c = 4
bottom of swimming pool that can be seen through (c) a = 2, b = - ], c = 3
the slab is approximately (d) a = 1, b = - 2, c = - 4
(a) 100 m2 (b) 160 m2 (c) 190 m2 (d) 220 m2
67. 1 kg of ice at - 20 °C is mixed with 2 kg of water at CHEMISTRY
90° C. Assuming that there is no loss of energy to the 7 1 . When 262 g of xenon (atomic mass = 131) reacted
environment, what will be the final temperature of completely with 152 g of fluorine (atomic mass = 19),
the mixture? (Assume, latent heat of ice = 334.4 kJ/kg, a mixture of XeF2 and XeF6 was produced. The molar
specific heat of water and ice are 4.18 kJ kg-1K-1 and ratio XeF2 : XeF6 is
2.09 kJ kg-1 -K-1 , respectively.) (a) 1 : 2 (b) 1 : 4
(a) 30°C (b) 0° C (c) 80°C (d) 45° C (c) 1 : 1 (d) 1 : 3
68. A rigid body in the shape of a V has two equal arms 72. Reaction of ethanol with cone. sulphuric acid at
made of uniform rods. What must the angle between 1 70° C produces a gas which is then treated with
the two rods be so that when the body is suspended bromine in carbon tetrachloride. The major product
G) G)
from one end, the other arm is horizontal? obtained in this reaction is
(a) cos-1 (b) cos-1 (a) 1,2-dibromoethane
(c) cos-1 G) i)
(d) cos- 1 (
(b) ethylene glycol
(c) bromoethane
(d) ethyl sulphate
69. A point object is placed 20 cm left of a convex lens of 73. When 22.4 L of C4H8 at STP is burnt completely,
focal length f = 5 cm (see in the below figure). The
89.6 L of CO2 gas at STP and 72 g of water are
lens is made to oscillate with small amplitude A
produced. The volume of the oxygen gas at STP
along the horizontal axis. The image of the object will
consumed in the reaction is closest to
also oscillate along the axis with
(a) 89.6 L (b) 1 12 L
(c) 134.4 L (d) 22.4 L
74. The amount of Ag (atomic mass = 108) deposited at
the cathode when a current of 0.5 amp is passed
through a solution of AgN03 for 1 h is closest to
(a) 2 g (b) 5 g
(c) 108 g (d) 11 g
75. The major product of the reaction is
6
0-
�
H +/H20
Product
(a) amplitude A I 9 , out of phase with the oscillations of
the lens (J " (yOH 0-
(b) amplitude A I 3, out of phase with the oscillations of the
lens
HO
(c) amplitude A I 3, in phase with the oscillations of the II Ill IV
lens
(d) amplitude A I 9, in phase with the oscillations of the (a) I (b) II (c) III (d) IV
lens
WWW.JEEBOOKS.INl
BIOLOGY
C C
76. Genomic DNA is digested with Alu I, a restriction 0 0
(c) � (d) �
enzyme which is a four base-pair cutter. What is the =i =i
0. 0.
frequency with which it will cut the DNA assuming a ti: ti:
random distribution of bases in the genome?
(a) 1/4 (b) 1/24 (c) 1/256 (d) 1/1296 Time Time
77. If rice is cooked in a pressure cooker on the Siachen
glacier at sea beach and on Deccan plain, which of 79. What is the advantage of storing glucose as glycogen
the following is correct about the time taken for in animals instead of a monomeric glucose?
cooking rice? (a) Energy obtained from glycogen is more than that from
(a) Gets cooked faster on the Siachen glacier the corresponding glucose monomers
(b) Gets cooked faster at sea beach (b) Glucose present as monomers within the cell exerts
(c) Gets cooked faster on Deccan plain more osmotic pressure than a single glycogen
(d) Gets cooked at the same time at all the three places molecule, resulting in loss of water from the cells
(c) Glucose present as monomers within the cell exerts
78. A few rabbits are introduced in an uninhabited
more osmotic pressure than a single glycogen
island with plenty of food. If these rabbits breed in
molecule, resulting in excess water within the cells
the absence of any disease, natural calamity and
(d) Glycogen gives more rigidity to the cells
predation, which one of the following graphs best
represents their population growth? 80. A line is drawn from the exterior of an animal cell to
the centre of the nucleus, crossing through one
mitochondrion. What is the minimum number of
C
0
C
0 membrane bilayers that the line will cross?
(a) � ( b) � (a) 4
0. 0. (b) 3
ti: ti: (c) 8
(d) 6
Time
Answers
PART-/
(c) 2 (c) 3 (b) 4 (c) 5 (b) 6 (d) 7 (c) 8 (d) 9 (b) 10 (b)
11 (c) 12 (c) 13 (b) 14 (a) 15 (a) 16 (c) 17 (c) 18 (b) 19 (c) 20 (a)
21 (c) 22 (d) 23 (a) 24 (b) 25 (d) 26 (a) 27 (d) 28 (a) 29 (c) 30 (d)
31 (a) 32 (c) 33 (d) 34 (c) 35 (d) 36 (b) 37 (d) 38 (a) 39 (c) 40 (b)
41 (a) 42 (a) 43 (b) 44 (c) 45 (d) 46 (b) 47 (a) 48 (c) 49 (b) 50 (b)
51 (b) 52 (a) 53 (d) 54 (d) 55 (c) 56 (a) 57 (d) 58 (c) 59 (a) 60 (c)
PART-I/
61 (d) 62 (d) 63 (b) 64 (d) 65 (c) 66 (b) 67 (a) 68 (a) 69 (a) 70 (a)
71 (c) 72 (a) 73 (c) 74 (a) 75 (a) 76 (c) 77 (b) 78 (a) 79 (c) 80 (a)
WWW.JEEBOOKS.INl
Solutions
1 . (c) We have, IV. (x + y + z)3 = 27xyz :. (Area of MCX) (Area of MEY)
2
2
f(x) = x + ax + 2 and g(x) = x + 2x + a x=y=z = _! (AX) (AC) sinA x _! (AY)(AB)sinA
Then, (3x)3 = 27i3
g(x) = 0.
Let a be the common root of/ (x) = 0 and 2 2
4. (c) Given,
Hence option (iv) is also true. = _! (AX)(AY) sinA x _! (AB)(AC) sinA
2
a + aa + 2 = 0 2 2
2 = (Area of MXY) (Area of MB C)
and a + 2a + a = 0 Perimeter of rectangle is 76 units.
2
-a 1 Hence, I and II both are true.
7. (c) ABC is a triangle. P be interior
a X X X X
2
= =
a -4 a-2 2- a
2 point of a t.ABC, Q and R be the
a a y y y y y
2 - reflections of P in AB and AC
a -4 2-a
respectively.
a2 - 4 (a + 2) (a - 2) y y y
⇒a = = = _ (a + 2) X X X X R
2-a - (a - 2)
a l y y y
and __ = __ ⇒a = l
2-a 2-a
- (a + 2) = 1
Let x and y are sides of each rectangles.
:. Perimetre of rectangle = 6x + 5y = 76
a + 2 = - l⇒ a = - 3 . . . (i)
f (x) + g(x) = 0 p
:. x - 3x + 2 + x + 2x - 3 = 0
Now and 4x = 3y . . . (ii)
2 2
On solving Eqs. (i) and (ii), we get
2
[·:
2x - x - 1= 0 x = 6, y = 8
- B C
Sum of roots = i a + � = }] :. Perimeter of each rectangle
QAR are collinear
2. (c) We have,
= 2 (x + y) = 2 (6 + 8) = 28 units
5. (b) 13! = 2 X 3
LQAR = 180°
Q is reflection of P on AB
X 4X 5X 6X 7
n + 2n + 3n + ... + 99n is a perfect square
= z-
X 8 X 9 X 10 X 11 X 12 X 13
n x 99 x 100 LQAB = LPAB
n (l + 2 + ... + 99), :f X 52 X 7 X 11 X 13
= (:i
O
X
2 R is reflection of P on AC
24k x 3l
n X 11 X 9 X 2 X 25 LRAC = LPAC
When 13 ! is divide by 24k
2 2
= (3) x (5) x 2 x 11 x n is a perfect square 2
LQAR = 180°
z-O X :f X 5 X 7 X 11 X 13
:. n must be 22. zl k _ ;/ :. 2 (LPAB + LPAC) = 180°
= 210 - 3 k · :f - k · 52 X 7 X 11 X 13
2 2
n = (22) = 484 LPAB + LPAC = 90°
2 LBAC = 90°
8. (d) ABCD is a square
Number of digit of n is 3. ⇒
3. (b) We have,
10 - 3k = integer
AB = BC = CD = AD = 1unit
Then, maximum value of k = 3
6. (d) ABC is a triangle points X and Y
i3 = 3xyz
x = y = z, x, y, z positive reals.
I. i3 + y3 +
on AB and AC respectively.
i3 - 3xyz = (x + y + z)
We know,
XY is parallel to BC.
i3 + y3 + 1
2 2
(x + y2 + z - xy - yz - zx)
A 2
= ..! (x + y + 2 N 1---- - r ---,-+- - ----j M

z) [(x - y) O 1 -r
2
2 2
+ (y - z) + (z - x) ]
When x = y = z
Then, (x - y) 2 + (y - z) 2 + (z - x) 2 = 0
- a
A L-----"'sc"-- - - ----*'
= 3xyz B C A circle r passing through B and C and
= 3xyz
i3 + y3 + z3
IL 2
i3 + y z + yz 2 I. Area of BCX : Area of BCY touching AD.
Put x = y = z It is true because same base between BC is chord of circle.
same parallels. :. OM bisects the chord AB
Then, LHS = RHS
III. Put x = z = l and y = 2 IL Area of MCX = _! (AX)(AC) sin A CM = MB = _!BC = �
2 2 2
Then, it is also true.
Area of MBY = � (AY) (AB) sinA ⇒ OM = MN - ON = 1- r
So, we cannot say only for x = y = z for true 2
WWW.JEEBOOKS.INl
rnr
In /J.OMC, OC2 = OM2 + CM2 Area of fig. (ii) 1 4. (a) We have, 1 2! + 1 3! + 1 4!
2 2 Area of ABCG + Area of DEFG 1 2!(1 + 1 3 + 1 3 X 1 4)
⇒ r = (1 - r) +
= 2xy + (2x - y) y 1 2! (1 + 1 3 (1 + 1 4))
r2 = 1 - 2r + r2 + - ⇒ r = - = 2xy + 2xy _ y2 = 4xy _ y2

⇒ 1 5 1 2! X 1 96
4 8 7xy = 4xy - y2 ⇒ y2 = _l_Xy ⇒ 2y = X
9. (b) ABCD is square
The number of distinct prime of 1 2! x 1 96
2 2
AB = BC = CD = AD = 1
is 2, 3, 5, 7, 1 1 .
1 1 . (c) Let the length of trains be
PQ is perpendicular to RS
1 5. (a) Given, EDUCATION
x meter.
Vowel occurs in same order
0(0, 1 ) S(5, 1 ) C(1 , 1 ) Time taken by train h cross person = 9 s
_E_U_A_I_O_
:. Speed of trains = � mis There are 6 place for letter DCTN
9
Time taken by train to cross platform = 2 1 s :. Total number of arrangement is
P (0, p) 6 C = 15.
1 6. (c) As, force F = ma
X - X +- 88 4
-
9 21
/J.F !J.m !J.a !J.m /J.F !J.a
(\�2)-(±
[·: length of plateform = 88 m] ⇒- = - + - ⇒- = - - -
⇒ 2 1x = 9x + 9 x 88 F m a m F a
A(0, 0) R(r, 0) 8(1 , 0)
·: Slope of PQ x Slope of RS = - 1
/J. 01
⇒ 1 2.x = 9 x 88 ⇒ := � )
q- p x l- 0 = - 1 9 X 88
s- r
⇒ X= = 66 m /J.m 0.2 0.0 1
m max 10
1- 0 12 So, ( ) = + = 0.03
1
1 2. (c) We have,
(3:3r
⇒ q- p = r - s . . . (i)
(PQ)2 = (1 - 0) 2 + (q - p) 2
Maximum error in mass occurs when
⇒ Vn + 1 - Vn < __1__ error in force and acceleration are of
12
1 different signs.
⇒ = 1 + (q - p)2 Vn + l < Vn + - So, !J.m = 0.03 x m = 0.03 x 10 ⇒ /J.m = 0.3 kg
Hence, mass of object is m = 10 ± 0.3 kg.
12
(q - p)2 _
27 _ l _ 1 1 Cubing both sides, we get
⇒ - -
16 16 1 7. (c) Cylinder will topple when centre
n + 1 < n + 3(n?3 x __1__ + 31/n x --
1 1
[·: q - p = r - s]
+ -- of mass of filled cylinder lies outside the
2 11 12 1 44 1 728
⇒ (r - s) = right edge of base. As centre of mass of
16 3nl/3 1
RS = .J<1 - 0) 2 + (r - s)2
( n + __1__ ) + __
l/3
⇒ l< filled cylinder lies at its mid-point.
⇒ 12 12 1 728
Cylinder
RS = ✓ + 161
l/3
n 1/3 1 1
⇒ n + )> 1-
⇒ 1
1 4( 12 1 728
RS = {27 = 3,/3
1/3 1/3 1 1 727
⇒ n (n + -) > - -
�16 4 12 432
1 0. (b) Given,
1n0
Put n = 8 only possible least positive
integers. B
1 3. (b) Let n = 3q + r
Area of both figures are equal A
1(------ a/2 �
O '.,'.; r < 3
sine = BC ⇒ AC = ____!!_
Now, from above diagram, we have
n = 3q, 3q + 1, 3q + 2 AC sine
If n is multiple of 3
i.e. n = 3q So, cose = [ h � ] or h = a tane
X X - sm e
(i ) Then, n19 is also multiple of 3.
2
1 8. (b) Initially, the velocity is
When n = 3q + l and 3q + 2
n3s = (3q + l)3s
Area of fig. (i) = 2xy + Lx (3y)
2
increasing, so the (x - t) graph must be
3xy xy = (3q + 1)36 (3q + 1)2
7
= 2xy + - = - with increasing slope or parabolic.
For first 4-s, x = ut + - at 2
2 2 = (36k + 1) (9q2 + 6q + 1) 1
x = t 2 !2 (parabola).
[·: (x + it = nk + 1] 2
= 36k (9q2 + 6q + 1) + 9q2 + 6q + 1 ⇒
= 3k + 31c + l After 4 s, particle is moving with a
2y
:. n38 - 1 = 3k + 31c + 1 - 1 = 3m constant velocity, so its graph is a
straight line of constant slope after 4 s.
:. n38 - l is multiple of 3
:. x = vt = (4 + at)t = 4t (straight line)
After 4 s, velocity is constant.
2x Similarly, when n = 3q + 2
(ii) n38 - l is also multiple of 3. Hence, best suited option is (b).
WWW.JEEBOOKS.INl
1 9. (c) Axis of rotation of earth as shown 23. (a) Initially given situation is Adding or removing one of repeating
below. 30 cm 30 cm 20 cm member does not alters the resistance of
Ren ·
j- Polaris an infinite network. Let RAB = x, then
I <\( At
1 '-0
/ (The north star) RAB =
i------t \ Axis of rotation rx

⇒ x=r+- -
' I / r+ X
,1 /
⇒ x2 - rx - x = 0
Earth's orbit } 20 20
�---- - - - /I : cm cm From sridharacharya formula, we have
/ I
When device is moved away from source -b± ✓ b2 - 4ac
r
..i � Perpendicular to X= - -----
I plane of orbit 0, then situation is as shown below. 2a
The southern 2 2
cross (- r) ± -..Jr + 4r
⇒ x=-- - -�- -
Axis of rotation of earth passes close to 2
r (1 + -/5)
20. (a) Heat through sun reaches earth
polaris, the polar star. -
⇒ X=- - -
2
resistance R is 1 W,
in form of infrared radiations of higher �f� Now, power consumed by bulb of
frequency range approx 1<>14 Hz. This
i 2R = 1⇒ i 2 = __!_ ⇒ i =
So, distance between object and image in
heat is absorbed by solids on earth's
surface and they re-radiate this heat in
both cases is 90 cm. Hence, there is no IA
16 4
shift in image's position.
24. (b) Base angles of prism is given 40°.
V - i. = - V-
form of infrared radiations of lower Now, current in circuit is
frequency range approx 1<>1° Hz. These
So, angle of prism A = 180° - 80° = 100°.
R + Ren
.
radiations are absorbed by greenhouse i = - ⇒ -
gases like methane and does not escapes �otal

1 10
into space causing warming of earth's ⇒
atmosphere. 4 16 + !___ (1+ -/5)
2
2 1 . (c) As parachutist lands on earth's
surface, there are two forces acting on her. ⇒ l6 + !... (1+ -f5) = 40 ⇒ r = 148 Q
2
rR
esistance 27. (d) Let orbital radius of ball is r then
°
orbital velocity of ball is
For TIR, i > ec ⇒ sin 40 > sin0 c
⇒ sin 40° > µ w ⇒ µ g > � = 2.07 v= ✓G�
�ravitation µg sin40°
Here, r=R+ h
25. (d) From mirror formula, we have
Now, before writing Newton's second law or µ g > 2.07
r = 6400 km
equation, we calculate acceleration of ⇒ r = 6400 km + 9 km
v2 - u 2 = 2as r = R (radius of earth)

parachutist using 1 1 1 or
. . . (i)
2
V u f ⇒
0 - (- 2) = 2 (a) (- 0.25) Now, acceleration of ball in orbit is
- 2- = --
= GM
Here, / = + 10 cm, u = - 15 cm
2
So, retardation of parachutist is 10 x - 15 v GM or a = g
a = 8 ms-2 (directed upwards) ⇒ v= = 30 cm a= - 2
-15 + 10 r r R
� - F'g = ma ⇒ � - mg= ma
Now, using Fnet = ma, we have
Now differentiating Eq. (i) with respect to So, acceleration of ball is nearly equal
time, we get to g.
=
!: ) 28. (a) For a satellite or planet, if total
or � = m(g + a) ⇒ � = 75(10 + 8) = 135 0 N
So, resistive force of ground on
parachutist is 1350 N.
:� :: ( energy is E, then
22. (d) �- -particles are emitted from

2
dv (+ 30) X (+ 2 ems- 1 ) kinetic energy, K = - E
- = ---
dt (- 15)2 and potential energy, U = 2E
=+
following nuclear reaction:
dv 1 where, E is negative.
1 n ---t � P + � e + v
1 ⇒
dt
S cm s-
So, I Ul > K.
A neutron in nucleus is converted into a
So, image is moving away from lens. 29. (c) Process given is
26. (a)
proton with emission of a �--particle and
nr
an antineutrino. This converts emitting
Po
p
nucleus into another nucleus of higher
proton number.
ix ---t ; 1Y + �1 e + v
+
This decay is characteristics of nuclii for
-+---+---➔ v
which,
N 1
z< D B
WWW.JEEBOOKS.INl
9
To find process equation, we use two M = 0.5 mol/L

point form of equation of straight line,
=
:. No. of moles ofH2SO4 = No. of moles of S
y _ Yi Y2 - Y1 (x _ ) 0.5 x 200
Xi base ofthe oompound 3 =d atom = = 0.1 mol
X2 - Xi 1000
Here, (x, y,) = (0, p0 ) and (,½, Y2 ) = (V0 , 0) [No. of moles = Volume x Molarity]
Process equation is coo- 1 mol of S = A0 atoms
p = Po - Po . V
1 A
40. (b) The structure of C1p9 is as

hence increases the acidity. Thus, the :. 0.1 mole of S = A0 x - = _Q_ atoms.
RT
V
o correct order of acidity of the given 10 10
As, p=- compounds are
⇒ RT =
V
Q > y > ¢'

Po - o . V
follows
P
V :o
⇒
V0
: II
T = Po ( 1 - __!"_ )
O
V
I I � c�o � Anhydride
R le�, I :
group
30. (d) At height h, acceleration due to

V0
COOH COOH COOH
/ � C= O ,
3 2 0 �----J
. 1s. g = GM
gravity h 2
35. (d) Acidic potassium permanganate
(R + h) "" C ,-0- C= O
For h < < R,

oxides alkenes to ketones or acids
depending upon the nature of the alkene.
II
0
/c-d
//
GM Thus, reaction of 2-butene with acidic 0
gh =
- =g
molecule having C1p9 is an anhydride

2 KMn04 gives acetic acid. Mellitic anhydride
R
KMn04/H + Thus, the functional group present in a
Direction is towards centre of earth.
3 1 . (a) Total mass of ammonium
� Strong
2 CH3COOH
2 butene oxidising Acetic acid
group.
36. (b) When baking soda is mixed with 4 1 . (a) When acetic acid reacts with
agent
sulphate (NH 4 )2 SO4
= 2 X 18 + 32 + 16 X 4
vinegar aqueous solution of sodium ethanol in the presence of hydrochloric
= 36 + 96 = 132
acetate is formed with the evolution of acid then ethyl acetate (ester) is formed
Mass of nitrogen in (NH4 )2 SO4 = 28 carbon dioxide gas which is a sweet smelling compound.
% of N by mass in (NH4 ) 2 SO 4 = � x 100 CH3COOH + C2H5OH- CH3COOC2H5
= 21.2%
132
Vinegar Baking soda Sodium Acetic acid Ethanol Ethyl acetate
32. (c) According to Mendeleev's periodic

acetate (sweet smelling
compound)
+ H2O (◊ +CO2 (g) + H20
42. (a) The metals that are present
Carbon dioxide gas
law, the physical and chemical properties
of the elements are a periodic function of 37. (d) Alkali metals have the highest below hydrogen in reactivity series will
their atomic mass. tendency to form ionic bond as they have not produce hydrogen gas in reaction
33. (d) Maximum number of electrons low ionisation energy. The general with hydrochloric acid. Among the given
= 2(2l +
that can be accommodated in a subshell electronic configuration of alkali metal is metals, Cu is present below H in
1) ns1. Among the given electronic reactivity series, i.e. it is less reactive
configuration, 1s2 2s2 2p 6 3s1 corresponds to
When l = 4 than H, will not produce H 2 gas in
the configuration of Na, which is an alkali reaction with H Cl acid.
43. (b) Isomers of compound with
Maximum number of electrons metal and hence forms ionic bond readily.
38. (a)
= 2(2 X 4 + 1) = 18
34. (c) Electron donating substituents
molecular formula C4 H10 O are as follows
2ZnS (s) + 3O 2 (g) � 2ZnO + 2SO 2 CH.i CH2CH2CH2OH
tends to decrease the acidic strength
while electron withdrawing substituents This process is known as roasting where CH.i CH(OH)CH2CH.i
tends to increase the acidic strength of the sulphide ore is heated in a regular CH.i - 0 - CH2CH2CH.i
substituted benzoic acids relative to supply of air to give its oxide form at a
benzoic acid. OCH 3 exerts +M effect
CH.i CH2OCH2CH.i
¢
temperature below the melting point of
the metal. CH.i - O - CH - CH.i
39. (c) Given,

which destabilises the conjugate base
I
OCH3 CH.i
Avogadro's number = A
Normality of H2SO4 = 1 N Thus, there are 3 isomeric ethers with
molecular formula C4 H10 O.
44. (c) C r2Of + 14H+ ➔ 2Cr°3 + + 7H2O
of the componnd 2 and h=re +6
Volume of H2 SO4 = 200 mL
Normality = Basicity x Molarity
As in the above reaction, there are net
coo- For H 2 SO4 , basicity = 2 twelve positive charges on the left side
decreases the acidity, whereas NO2 exerts 1= 2 x M and only six positive charges on right
-M effect and stabilises the conjugate side.
WWW.JEEBOOKS.INl
Therefore, 6 electrons are required to pyruvate (pyruvic acid) molecules, a total chemicals in its body. Since vulture
reduce chromium completely in of four ATP molecules and two molecules occupies the top level as it eats the tiger,
Cr20� to Cr3 + in acidic medium of NADH. which eats the goat, which eats the grass
51 . (b) Oxidative phosphorylation is the
Cr20� (aq) + 14W (aq) + 6e- � in the food chain, it will have the
maximum concentration of harmful
2Cr3 + (aq) + 7H20 process in which ATP is formed as a
45. (d) 58. (c) Molecular mass of a base = 500
chemicals in its body.
result of the transfer of electrons from
NADH or FADH2 (produced during
500
glycolysis from glucose) to molecular Da
oxygen ( 02 ) by a series of electron Number of base in a dsDNA = 10 BP or
400 carriers. It takes place in the 20 bases
mitochondria in eukaryotes and in Thus, molecular mass of a dsDNA with
cytoplasm in prokaryotes.
52. (a) Innate immunity refers to
20 bases = 20 x 500 = 10 kDa
200 59. (a) A carbohydrate (e.g. starch,
1 00 +-- - � - � - � -
0 100 200 300
non-specific defence mechanisms that cellulose or glycogen) is a molecule
come into play immediately or within consisting of a number of sugar molecules
T/°C hours of an antigen's appearance in the bonded together by glycosidic linkages
Volume of gas at 0° C body. These mechanisms include physical and on hydrolysis give its constituent
3 barriers such as skin epithelial cells, monosaccharides or oligosaccharides.
V1 = 250 cm Cellulose is a polymer of�, D-glucose and
°
chemicals in the blood and immune
Volume of gas at 300 C system cells that attack foreign cells in glycogen ofa, D-glucose. Glucose, fructose
3
V2 = 500 cm and ribose are monosaccharides.
60. (c) Onion is a bulb, i.e. it is a
the body.
V2 = 500 = 2
53. (d) Vitamin-K is a cofactor for the
V1 250 enzyme responsible for chemical modified leaf. A bulb is an underground
Thus, the volume of the gas at 300°C is reactions that maintains blood clotting pyriform-spherical structure that
possesses a reduced convex or slightly
larger than that at 0° C by a factor of 2. factors : prothrombin; factor VII, IX, X;
46. (b) Excess salt inhibits growth in
conical disc-shaped stem and several
and proteins. Thus vitamin-K plays a key
fleshy scales enclosing a terminal bud.
pickles by exosmosis. Salt kills and role in helping the blood clot thereby
In Onion, the fleshy scales represent leaf
inhibits the growth of microorganisms by preventing excessive bleeding. bases in the outer part and scale leaves
drawing water out of the cells of both the 54. (d) Pseudomonas is denitrifying in the central region.
microbe and the food through osmosis (or bacteria. Denitrifying bacteria are 6 1 . (d) We have,
more specifically exosmosis). Due to microorganisms whose action results in A rectangular corner is cut form a
hypertonic solution outside the bacterial the conversion of nitrates in soil to free rectangular piece of paper.
cell, bacteria will die by plasmolysis.
47. (a) Restriction endonuclease is an
atmospheric nitrogen, thus depleting soil
fertility and reducing agricultural D 4 Q 8 C
enzyme that cuts dsDNA into fragments productivity.
55. (c) Annelida shows metameric
3
at or near specific recognition sites 5
p 9
(palindromic sequence) within the segmentation. It is the repetition of
molecule known as restriction sites. 6
organs and tissues at intervals along the
These enzymes are found in bacteria and body of an animal, thus dividing the body A 12 B
archaea and provide a defence into a linear series of similar parts or Area of rectangle
48. (c) In duodenum, trypsin enzyme

mechanism against invading viruses. segments (metameres).
56. (a) The widal test is one method
= 12 x 9 = 108 sq units
Area of pentagon
catalyses the hydrolysis of peptide bonds, used to diagnose enteric fever also known = Area of rectangle - Area of triangle
Salmonella typhi bacteria. Widal test was

breaking down proteins into smaller as typhoid fever. Typhoid is caused by
peptides. Amylase hydrolyses starch into = 108 - 6 = 102
102 17
maltose inside the mouth. Lipase breaks based on demonstrating the presence of :. Ratio = =
62. (d) We have,

down dietary fats into fatty acids and agglutinin (antibody) in the serum of an 108 18
glycerol. Maltase hydrolyses maltose into infected patient, against the 'H' (flagellar)
typhi.
simple sugar glucose. and 'O' (somatic) antigens of Salmonella
49. (b) Person with blood group AB have
[x] {x} = 5
⇒
X E [0, 2015]
both A and B antigen in the membrane of 57. (d) The increase in concentration of
{x} = �
his red blood cell but lacks both harmful chemical substance like [x]
antibodies (a, b) in his plasma. Due to pesticides in the body of living organisms
at each trophic level of a food chain is {X} E [0, 1)
this reason, blood group AB is called
[x]
universal recipient. called biological magnification. The �<1
50. (b) Glycolysis starts with one

organism which occurs at the highest
trophic level in the food chain will have [x] > 5
molecule of glucose and ends with two the maximum concentration of harmful
:. Total number of solution is 2009.
WWW.JEEBOOKS.INl
63. (b) Given, 65. (c) Let the number of people in two ⇒ m,,,s,,,t,,r = Tntq (O - (- 20 C)) °
ABCD is a trapezium. villages are x and y respectively.

Given, average income of x people = P
+ 111tL + 111t8w (r - 0)
AD is parallel to BC
r
⇒ 2 X 418 X (90 - r ) = 1 X 2.09 X 20
and average income of y people = Q
M is point on BC
r
+ 1 X 3344 + 1 X 418 X
such that AB = AM and DC = DM
are Px and QY respectively.
r=
:. Total income of people in two villages ⇒ 7524 - 376.2 = 3 x 418 x
A N D ⇒ 30°e
One person moves from first village to
So, final temperature of mixture is 30°e.
68. (a) Let length of each of rod is l and
second village.
p
Then, number of people in first village
= x - 1 and second village = y + 1
8 /NZl� c angle between them is 0.
M Q
In MMD, Average income = P' and Q '
Area of MMD = Area of MMN :. Total income = P' (x - 1) and Q ' (y + 1)
+ Area ofuDMN
Area of MMN = Area of MMP :. Px + Qy = P' (x - 1) + Q ' (y + 1)
Total income in both cases are same
⇒ Px - P' (x - 1) = Q' (y + 1) - Qy
Area of /'JJMN = Area of /'JJQM ⇒ x(P - P') + P' = y(Q' - Q) + Q '
= Area of MBP
= Area of /'JJQC :. P' "# P and Q ' "# Q
66. (b) Girl can observe only those light

Hence, option (c) is correct.
= Area of MBM + Area of MMD
:. Area of trapezium ABCD
p
+ Area of to.MDC rays which are refracted and leaves the
= 3 [Area of MPM + Area of /'JJMN)
glass slab at angle of 90° or less as shown
= 3Area of MMD
below.
Area of trapezium ABCD

Ro d 2
B
Area of MMD
3 [Area of MDM] � (g)
= = =3:1 mg mg
Area of MDM 1 : @
64. (d) Let hx , hy and hz are height of

Pool r I h=6m Let the lower rod is horizontal and upper
bottom I
cylindrical bucket of X, Y and Z

I rod makes 0 angle with horizontal.
I I
respectively and rx , ry and rz are radii of downwards from their centres A and B as
Weights of rods acts vertically
X
� ----¼-- 0.6 ------- X �
bases of cylindrical bucket X, Y and Z

Now, from Snell's law in layer 1 and 3, shown in the above figure.
we have
acting through A from point D is
Vx = nr; x hx
respectively. Now, perpendicular distance of weight
n1 sin i = n2 sin r
Vy = 1tr/ x hy
⇒ 1 x sin 90° = � x sin r CD = lcos0 - }_ cos0
Vz = nrl x hz
3
Sln r = -
2
[·: rx = 1] CD
Vx = nhx
. 3
I cos0
[·: ry = 2]
=
Vy = 41thy
2
Vz = 91thz [·: rz = 3]
Now, from Pythagoras theorem, we have and perpendicular distance of weight
·,./ 7
3
At initial stage hx = hy = hz = h
⇒ tan r = _ acting through B from point D is
BD = }_ - lcos0 = !_ (1- 2cos0)
Vx = 1th, Vy = 41th, Vz = 91th
So, from figure, we have
2 2
At second stage some water transfer Z to
tan r = �
X, then volume are equal
At equilibrium torque of these two
weights about D must balance each other.
Vx = Vz = 51th [·: Vx + Vy = 101th] x = h tan r =
6x3
.,, ,
⇒ � = 6.8 m
1.e. mg x }_ cos0 = mg x }_ (1- 2cos0)
At third stage some water is transferred 2 2
between x and y.
Hence, area of pool visible through glass
. A - - 1td- - - 1t X
91th
2
(2x + 0.6)2 - 160 2
Vx = Vy = - [·: Vx + Vy = 91th]
⇒ � cos0 = � ⇒ cos0 = �
G)
s1ab 1s - - - - - - m 2 2 3
4 4
67. (a) Let final temperature of mixture
is r 0e. Then,
2 1
Volume of water at third stage or 0 = cos-
Vy = 41thy = � 1th 69. (a) From lens equation, we have

Heat lost by 2 kg water at 90° e to cool
and Vz = 91thz = 51th
2
down at T'e = Heat gained by 1 kg ice at 1 1 1
� 1th
Vy = 41thy = L_ = 81
- 20°e to reach at 0° e + Heat gained by U U f
Vz 91thz 51th 10
1 kg ice at 0° e to change its state from ice Now, differentiating above equation with
hy 81 du = � du ) or du = 2 du
to water + Water 1 kg formed at 0° e is
=
respect to time, we get
hz 40 (
dt u 2 dt dt dt
⇒ now absorbs heat to reach temperature of
r 0e m ( )
WWW.JEEBOOKS.INl
152 So, it is evident that wherever there will

As, � = magnification (m) No. of initial moles of F2 = = 4 mol
u 38 be the above sequence in the DNA
⇒ dv = m2 - du . . . (i) 2 moles of Xe react completely with fragment, Alu I will make blunt cuts over
i.e. if object oscillates with an amplitude 4 moles of F2 to give 1 mol of XeF2 and there.
amplitude du given by i.
du, then image also oscillates with 1 mol of XeF6 • Now according to question, if there is
Thus, the molar ratio of XeF2 : XeF6 is random distribution of bases in the
72. (a) When ethanol reacts with cone.

Also, magnification, 1 : 1. genome, the probability of occurrence of
m=
�
=(
1: u )
... (ii) sulphuric acid at 170° C produces ethene
the above cut sides will be
- - - -
1 1
- = -- [since Alu I is a 4 base
gas which is then treated with bromine in 4 x 4 x 4 x 4 256
Now, in given question, carbon tetrachloride to give pair cutter]
u = - 20 cm, f = 5 cm 1,2-dibromoethane as a major product. l
So, the frequency will be __ _
m = -1- = -- ⇒ m=- I
5 Cone. H2S04
So,
77. (b) The cooking of rice in open
CH3CH20H 1 70oc CH2 = CH2 256
f + u 5 - 20 3 Ethanol (Dehydration Ethene
of alcohol)
From Eq. (i), we have 1 vessels is favoured at low temperatures
dv = (- ir
Br2 1 �� ition
and higher altitudes due to the
X du reaction)
CH2--CH2 atmospheric pressure. When the rice is
cooked in the pressure cooker, then the
or du = I x A [given, du = A] I I
9 Br Br rice will be cooked faster at the sea beach
1 , 2 dibromoethane because the temperature is higher and
As object is placed between oo and 2/ (major)
pressure is lower at sea level than higher
distance, so on moving object near to
altitude. This will allow the water to boil
lens, its image moves away from lens.
At STP 22 .4 L 89.6L faster inside the pressure cooker and the
So, oscillations of object and image are
78. (a) In the absence of disease, natural

+ 4H2O(g) rice will be cooked faster.
out of phase.
70. (a) By Stokes' law,
72 L
F = 6 1t rt av
72
No. of moles of water at STP = = 4 mol calamities and predation growth of rabbit
rt = - F-
18 is exponential. When resources are
61tav
We have, 1 mole of C4H8 burns completely with 6 unlimited, populations exhibit
Dimensions of viscosity index rt are

moles of 02 to give 4 moles of CO2 and 4 exponential growth, resulting in a
moles of H2O.
79. (c) Glucose is a monosaccharide and
J-shaped curve (i.e. option a).
[rtl = Il M T-1 [ML-1 r1 J

--J =
L 27 At STP 1 mole of 02 contains = 22.4 L
⇒
L - Lr 6 moles of O2 contain = 224 x 6= 134.4 L an osmotically active molecule which
Now, given relation of volume flow rate is 74. (a) Given, current, I = 0.5 A increases osmotic pressure in cell. So,
f = k ( 1 f rt - r
water enters in cell while glycogen is
b c Time, t = 1hr = 3600 s osmotically inert molecule does not
According to Faraday's Ilnd law of change the osmotic pressure. This is the
Atomic mass x I x t
Substituting dimensions of physical electrolysis, reason why glucose is not stored in the
quantities and equating dimensions on W cell instead glycogen is stored in the
both sides of equation, we have animal body.
80. (a) There will be four membrane
96500
[r:l l
t.
--
= [ML-1'-2]° . [ML-1 r 1 [LJ" = � X 0.5 X 36000= 2 g
75. (a)
[T] 96500 bilayers that the line will cross
⇒ [MOL3T-1 ] = [Ma + b L- 2a - b + cT- 2a - b ] 1 = Cell membrane
a+ b= 0
Equating dimensions, we have 2 = Mitochondrion
- 2a - b + c = 3
. . . (i) 1 = Nucleus
- 2a - b = - 1
. . . (ii)
. . . (iii)
c= 4
From Eqs. (ii) and (iii), we have
From Eqs. (i) and (iii), we have

The addition of water to alkenes in the
b= - 1 presence of an acid form alcohols which
Substituting b in Eq. (i), we have occurs through electrophilic addition
a=l mechanism and follows Markownikoff
So, a = 1, b = - 1 and c = 4
rule.
7 1 . (c) 2Xe + 4F2 � XeF2 + XeF6

Hence, option (a) is correct.
76. (c) Alu I has the cut site 5' AGCT3'
262
No. of initial moles of Xe = = 2 mol 3' TCGA5' Cell membrane
13 1
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions

MATHEMATICS coefficient of the highest degree term of k(x) is 1,
then sum of the roots of (x - 1) + k(x) is
1. Let rbe a root of the equation :x? + 2x + 6 = 0. The
6. In a quadrilateral ABCD, which is not a trapezium, it
W4 �5 �6 00 7
value of (r+ 2) (r+ 3) (r+ 4) (r+ 5) is equal to
is known that LDAB = LABC = 60°. Moreover,
(a) 51 (b) - 51 (c) - 126 (d) 126
2. Let R be the set of all real numbers and let f be a LCAB = LCBD. Then,
function from R to R such that (a) AB = BC + CD (b) AB = AD + CD
f(x) + (x + ½) /(1 - x) = 1, for all X E R. Then (c) AB = BC + AD (d) AB = AC + AD
7. A semi-circle of diameter 1 unit sits at the top of a
2/(0) + 3/(1) is equal to semi-circle of diameter 2 units.
(a) 2 (b) 0 (c) - 2 (d) - 4
3. The sum of all positive integers n for which
13 + 23 + ... + (2n)3 . . .
1s a1so an integers 1s
12 + 2 2 + . . . + n2
(a) 8 (b) 9 (c) 15
4. Let x and y be two 2-digit numbers such that y is
(d) Infinite
obtained by reversing the digits of x. Suppose they

also satisfy :x? - y2 = m2 for some positive integer m.
2 units
The value of x + y + m is
The shaded region inside the smaller semi-circle but
outside the larger semi-circle is called a lune. The
(a) 88 (b) 1 12 (c) 144 (d) 154
5. Let p(x) = x2 - 5x + a and q(x) = :x? - 3x + b, where a
area of the lune is
and b are positive integers. Suppose HCF

(p(x), q(x)) = x - 1 and k(x) = 1 cm (p(x), q(x)) If the
WWW.JEEBOOKS.INl
8. The angle bisectors BD and CE of a L1ABC are 13. The number of 6-digit numbers of the form ababab
divided by the incentre I in the ratios 3 : 2 and 2 : 1 (in base 10) each of which is a product of exactly 6
respectively. Then, the ratio in which I divides the distinct primes is
angle bisector through A is (a) 8 (b) 10 (c) 13 (d) 15
(a) 3 : 1 (b) 11 : 4 14. The houses on one side of a road are numbered using
(c) 6 : 5 (d) 7 : 4
consecutive even numbers. The sum of the numbers
9. Suppose S1 and S2 are two unequal circles, AB and of all the houses in that row is 1 70. If there are at
CD are the direct common tangents to these circles. A least 6 houses in that row and a is the number of the
transverse common tangent PQ cuts AB in R and CD sixth house, then
in S. If AB = 10, then RS is (a) 2 '.,'.; a '.,'.; 6 (b) S '.,'.; a '.,'.; 12
A (c) 14'.,'.; a'.,'.; 20 (d) 22'.,'.; a '.,'.; 30
15. Suppose a2, a3 , a4 , a5 , a6 , a7 are integers such that
5 a2 a3 a 4 a5 a6 a7
-=- +-+-+-+-+-
7 2 ! 3 ! 4! 5 ! 6! 7 !'
where O � aj < j for j = 2, 3, 4, 5, 6, 7. The sum of
a2 + a3 + a4 + a5 + a6 + a7 is
(a) 8 (b) 9 (c) 10 (d) 11
(a) 8 (b) 9 (c) 10 (d) 11 PHYSICS

10. On the circle with center 0, points A and B are such
16. In the following displacement x versus time t graph,
that OA = AB. A point C is located on the tangent at
at which among the points P, Q and R is the object's
B to the circle such that A and C are on the opposite speed increasing?
sides of the line OB and AB = BC. The line segment
AC intersects the circle again at F. Then, the ratio
X
LBOF : LBOC is equal to p

Q
0 (a) R only (b) P only

(c) Q and R only (d) P, Q and R
17. A box when hung from a spring balance shows a
reading of 50 kg. If the same box is hung from the
C same spring balance inside an evacuated chamber,
the reading on the scale will be
(a) 1 : 2 (b) 2 : 3 (c) 3 : 4 (d) 4 : 5
(a) 50 kg because the mass of the box remains unchanged.
11. In a cinema hall, the charge per person is '{ 200. On (b) 50 kg because the effect of the absence of the
the first day, only 60% of the seats were filled. The atmosphere will be identical on the box and the spring
owner decided to reduce the price by 20% and there balance
was an increase of 50% in the number of spectators (c) less than 50 kg because the weight of the column of air
on the next day. The percentage increase in the on the box will be absent
revenue on the second day was (d) more than 50 kg because the atmospheric buoyancy
force will be absent
(a) 50 (b) 40 (c) 30 (d) 20
18. Two positively charged spheres of masses mi and m2
12. The population of cattle in a farm increases so that
are suspended from a common point at the ceiling by
the difference between the population in year n + 2
identical insulating massless strings of length l.
and that in year n is proportional to the population in
Charges on the two spheres are Qi and q2 ,
year n + 1. If the populations in years 2010, 2011 and respectively. At equilibrium, both strings make the
2013 were 39, 60 and 123, respectively,then the same angle 0 with the vertical. Then
(a) CJi 7ni_ = q2"½ (b) 7ni_ = "½
population in 2012 was
(a) 81 (b) 84 (c) 87 (d) 90 (c) 7ni_ = "½ sine (d) q21ni_ = CJi m2
WWW.JEEBOOKS.INl
19. A box when dropped from a certain height reaches 26. A bar magnet falls with its north pole pointing down
the ground with a speed v. When it slides from rest through the axis of a copper ring. When viewed from
from the same height down a rough inclined plane above, the current in the ring will be
inclined at an angle 45° to the horizontal, it reaches
the ground with a speed v I 3. The coefficient of
(a) clockwise, while the magnet is above the plane of the
ring and counter clockwise, while below the plane of
sliding friction between the box and the plane is the ring
(Take, acceleration due to gravity is 10 ms-2 ) (b) counter clockwise throughout
w �9 �! � �3 oo !3 (c) counter clockwise, while the magnet is above the plane

of the ring and clockwise, while below the plane of the
9
ring
20. A thin paper cup filled with water does not catch fire (d) clockwise throughout
when placed over a flame. This is because
(a) the water cuts off oxygen supply to the paper cup 27. Two identical bar magnets are held perpendicular to
(b) water is an excellent conductor of heat each other with a certain separation, as shown below.
(c) the paper cup does not become appreciably hotter than The area around the magnets is divided into four
the water it contains zones.
(d) paper is a poor conductor of heat
21. Ice is used in a cooler in order to cool its contents.
Which of the following will speed up the cooling
process?
(a) Wrap the ice in a metal foil
(b) Drain the water from the cooler periodically
IV
(c) Put the ice as a single block
(d) Crush the ice
22. The angle of a prism is 60°. When light is incident at Given that there is a neutral point it is located in
an angle of 60° on the prism, the angle of emergence (a) zone I (b) zone II (c) zone III (d) zone IV
is 40°. The angle of incidence i for which the light ray
will deviate the least is such that 28. A large number of random snap shots using a camera
° ° ° are taken of a particle in a simple harmonic motion
between x = - x0 and x = + x0 with origin x = 0 as the
(a) i < 40 (b) 40 60°
mean position. A histogram of the total number of
23. A concave lens made of material of refractive index times the particle is recorded about a given position
1.6 is immersed in a medium of refractive index 2.0. (Event no.) would most closely resemble.
The two surfaces ofthe concave lens have the same
radius of curvature 0.2 m. The lens will behave as a
(a) divergent lens of focal length 0.4 m ( a) g
c c
iii iii
(b) divergent lens of focal length 0.5 m Q) Q)
(c) convergent lens of focal length 0.4 m

(d) convergent lens of focal length 0.5 m
X
24. A charged particle initially at rest at 0 Xo
O,when released follows a trajectory as
shown alongside. Such a trajectory is g
possible in the presence of (c)
c c
iii iii
(a) electric field of constant magnitude and varying Q) Q)
direction
(b) magnetic field of constant magnitude and varying
X X
I I
direction 0 Xo 0 Xo
(c) electric field of constant magnitude and constant
29. In 1911, the physicist Ernest Rutherford discovered
that atoms have a tiny, dense nucleus by shooting
direction
positively charged particles at a very thin gold foil. A

(d) electric and magnetic fields of constant magnitudes and
key physical property which led Rutherford to use

constant directions which are parallel to each other
25. Two equal charges of magnitude Q each are placed at gold was that it was
a distance d apart. Their electrostatic energy is E. A
third charge - Q 12 is brought midway between these
(a) electrically conducting (b) highly malleable
(c) shiny (d) non-reactive
two charges. The electrostatic energy of the system is
30. Consider the following statements:
now
I. All isotopes of an element have the same number of
(a) - 2E (b) - E (c) 0 (d) E
neutrons.
WWW.JEEBOOKS.INl
II. Only one isotope of an element can be stable and 39. At room temperature, the average speed of helium is
non-radioactive. higher than that of oxygen by a factor of
III. All elements have isotopes. (a) 2/2 (b) 61-/2 (c) 8 (d) 6
IV. All isotopes of carbon can form chemical compounds
with oxygen-16. 40. Ammonia is not produced in the reaction of
Choose the correct option regarding an isotope. (a) NHp with KOH (b) AlN with H2O
(c) NH4Cl with NaN02 (d) NH4Cl with Ca(OH)i
(a) Statements III and IV are correct
(b) Statements II, III and IV are correct 41. The number of isomers which are ethers and having
(c) Statements I, II and III are correct the molecular formula C 4 H100, is
(d) Statements I, III and IV are correct W2 �3 �4 00 5
42. The major product of the reaction of 2-butene with
CHEMISTRY alkaline KMn04 solution is
31. The isoelectronic pair is

0
(a) � (b) �
(a) CO, N2 (b) 02 , NO (c) C2 , HF (d) F2 , HCl OH
32. The numbers of lone pairs and bond pairs in
hydrazine are, respectively (c) (d ) +
(a) 2 and 4 (b) 2 and 6 (c) 2 and 5 (d) 1 and 5 A OH
33. The volume of oxygen at STP required to burn 2.4 g OH
of carbon completely is 43. Among the compounds I-IV, the compound having
(a) 1.12 L (b) 8.96 L (c) 2.24 L (d) 4.48 L the lowest boiling point is
34. The species that exhibits the highest R1 value in a HO
thin layer chromatogram using a non-polar solvent /"---.../'--..
OH
�
OH
on a silica gel plate is II
� OH
OH
(a) ( b)
o
Ill IV
(a) I (b) II
c N (c) III (d) IV
44. Of the following reactions
(c) Q
(El/
(d) Q
(i) A � B, 110 ° = 250 kJ mo1-1
N
(ii) D � E, 110 ° = - lO0 kJ mol-1
(iii) F � 0, 110 ° = - 150 kJ mo1-1
OH
35. The number ofC-C sigma bonds in the compound (iv) M � N, 110 ° = 1 50 kJ mor1
0
The reaction with the largest equilibrium constant is
(a) (i) (b) (ii) (c) (iii) (d) (iv)
IS
45. The first ionisation enthalpies for three elements are
1314, 1680 and 2080 kJ mor1, respectively. The
(a) 16 (b) 17 (c) 18 (d) 11 correct sequence of the elements is
36. If the radius of the hydrogen atom is 53 pm, the (a) 0, F and Ne (b) F, 0 and Ne
radius of the He+ ion is closest to (c) Ne, F and O (d) F, Ne and 0
BIOLOGY
(a) 108 pm (b) 81 pm
(c) 27 pm (d) 13 pm
37. The diamagnetic species is 46. Individuals of one kind occupying a particular
(a) NO (b) NO2 (c) 02 geographic area at a given time are called
38. The pH of0.1 M aqueous solutions of NaCl, (a) community (b) population
CH3COONa and NH4Cl will follow the order (c) species (d) biome
(a) NaCl < CH.i COONa < NH4 Cl 47. What fraction of the assimilated energy is used in
(b) NH4 Cl < NaCl < CH.i COONa respiration by the herbivores?
(c) NH4 Cl < CH.i COONa < NaCl (a) - 10 per cent (b) - 60 per cent
(d) NaCl < NH4 Cl < CH.i COONa (c) - 30 per cent (d) - 80 per cent
WWW.JEEBOOKS.INl
48. Athletes are often trained at high altitude because 55. The auditory nerve gets its input from which o f the
(a) training at high altitude increases muscle mass following?
(b) training at high altitude increases the number of red (a) The sense cells of the cochlea
blood cells (b) Vibration of the last ossicle
(c) there is less chance of an injury at high altitude (c) Eustachian tube
(d) athletes sweat less at high altitude (d) Vibration of the tympanic membrane
49. In human brain, two cerebral hemispheres are 56. Which of the following organelles contain circular
connected by a bundle of fibres which is known as DNA?
(a) medulla oblongata (b) cerebrum (a) Peroxisomes and mitochondria
(c) cerebellum (d) corpus callosum (b) Mitochondria and Golgi complex
(c) Chloroplasts and lysosomes
50. Which one of the following hormones is produced by
(d) Mitochondria and chloroplast
the pancreas?
(a) Prolactin (b) Glucagon 57. A reflex action does not involve
(c) Luteinising hormone (d) Epinephrine (a) neurons (b) brain
5 1 . The stalk of a plant leaf is derived from which one of (c) spinal cord (d) muscle fibre
the following types of plant tissue? 58. Which one of the following options is true in
(a) Sclerenchyma (b) Parenchyma photosynthesis?
(c) Chlorenchyma (d) Collenchyma (a) CO2 is oxidised and Hp is reduced
52. Which of the following muscle types cannot be used (b) H2O is oxidised and CO2 is reduced
voluntarily? (c) Both CO2 and Hp are reduced
(d) Both CO2 and H2O are oxidised
(a) Both striated and smooth
(b) Both cardiac and striated 59. Human mature Red Blood Cells (RBCs) do not contain
(c) Both smooth and cardiac (a) iron (b) cytoplasm
(d) Cardiac, striated and smooth (c) mitochondria (d) haemoglobin
53. The pulmonary artery carries 60. A person was saved from poisonous snake bite by
(a) deoxygenated blood to the lungs anti-venom injection.
(b) oxygenated blood to the brain Which of the following immunities explains this form
(c) oxygenated blood to the lungs of protection?
(d) deoxygenated blood to the kidney (a) Naturally acquired active immunity
54. Both gout and kidney stone formation is caused by (b) Artificially acquired active immunity
(a) calcium oxalate (b) uric acid (c) Naturally acquired passive immunity
(c) creatinine (d) potassium chloride (d) Artificially acquired passive immunity

MATHEMATICS
64. In a L1ABC with LA = 90 , P is a point on BC such
(a) 0 (b) 1007 (c) 2013 (d) 2014
that PA : PB = 3 : 4. If AB = ..f7 and AC = ../5, then

°
6 1 . Let a, b, c be non-zero real numbers such that
BP : PC is
a + b + c = O, let q = a 2 + b2 + c2 and r = a 4 + b4 + c4 .
Then,
(a) 2 : 1 (b) 4 : 3 (c) 4 : 5 (d) S : 7
(a) q2 < 2r always
(b) q2 = 2r always 65. The number of all 3-digit numbers abc (in base 10) for
(c) q2 > 2r always which (a x b x c) + (a x b) +
(d) q2 - 2r can take both positive and negative values (b x c) + (c x a) + a + b + c = 29 is
1947 (a) 6 (b) 10 (c) 14 (d) 18
I, l
� is equal to
PHYSICS
62. The value of
n = 0 2
n
+ \1 2
1 94 7
(a) � (b) � (c) 1947

,/ :if
945
,i :if947 .,/ :if
94 7
66. A uniform square wooden sheet of side a has its
centre of mass located at point O as shown in the
63. The number of integers a in the interval [1, 2014] for
figure below on the left. A square portion of side b of
which the system of equations x + y = a,
this sheet is cut out to produce an L-shaped sheet as
__!__ + y__i__
x- 1 -1
= 4 has finitely many solutions is shown in the figure on the right.
WWW.JEEBOOKS.INl
a b If the refractive index of the material of the prism is

µ, then
(a) µ > .J5 (b) .J 3 < µ < .J5
(c) -v'2 < µ < .J3 (d) µ < -v'2
70. Consider the circuit shown below where all resistors
are 1 kQ.
p
point P (in the above diagram), when

The centre of mass of the L-shaped sheet lies at the
If a current of magnitude 1 mA flows through the
(a) a l b = (./5 - 1) 1 2 (b) a l b = (./5 + 1) 1 2
measured between points P and Q?
resistor marked X, what is the potential difference
(c) a l b = (./3 - 1) 1 2 (d) a l b = (./3 + 1) 1 2
(a) 21 V (b) 68 V
67. A machine is blowing spherical soap bubbles of (c) 55 V (d) 34 V
CHEMISTRY
different radii filled with helium gas.It is found that,
if the bubbles have a radius smaller than 1 cm, then
they sink to the floor in still air. Larger bubbles float
in the air. Assume that the thickness of the soap film 7 1 . 10 moles of a mixture of hydrogen and oxygen gases
in all bubbles is uniform and equal. Assume that the at a pressure of 1 atm at constant volume and
density of soap solution is same as that of water temperature, react to form 3.6 g of liquid water. The
(= 1000 kg m -3 ) . The density of helium inside the pressure of the resulting mixture will be closest to
bubbles and air are 0.18 kg m-3 and 1.23 kg m-3 , (a) 1.07 atm (b) 0.97 atm
the bubbles is (Note 1 µm = 10-6 m)

respectively. Then, the thickness of the soap film of (c) 1.02 atm (d) 0.92 atm
72. The ammonia evolved from 2 g of a compound in
(a) 0.50 µm (b) 1.50 µ m Kjeldahl's estimation of nitrogen neutralises
(c) 7.00 µm (d) 3.50 µm 10 mL of 2 M H2 S04 solution. The weight percentage
of nitrogen in the compound is
68. An aluminium piece of mass 50 g initially at 300°C is (a) 28 (b) 14
dipped quickly and taken out of 1 kg of water, (c) 56 (d) 7
initially at 30° C. If the temperature of the
aluminium piece immediately after being taken out 73. Complete reaction of 2.0 g of calcium (at. wt. = 40) with
reaction of the same quantity of another metal M with

of the water is found to be 160°C, what is the excess HCl produces 1.125 L ofH2 gas. Complete
temperature of the water? Then, specific heat
capacities of aluminium and water are 900 Jkg-1K -1 excess HCl produces 1.85 L ofH2 gas under identical
and 4200 Jkg-1 K - 1, respectively. conditions. The equivalent weight of M is closest to
(a) 23 (b) 9
69. A ray of light incident parallel to the base PQ of an

(a) 165°C (b) 45 °C (c) 31.5°C (d) 28.5°C
(c) 7 (d) 12
isosceles right-angled triangular prism PQR suffers

74. A compound X formed after heating coke with lime
reacts with water to give Y which on passing over
PQ and QRbefore emerging reversed in direction as
0
two successive total internal reflections at the faces
red-hot iron at 873 K produces Z. The compound Z is
shown below.
( a) (b) �
0
R
(c) \_// (d)
75. In the following reaction sequence,

Br
B� 1 . Ale. KOH 3. HgSO/dil, H2so., Heat
X y
2. NaNH2 4. Cone. HNOJH2S04
Ph
WWW.JEEBOOKS.INl
xl;li �
X and Y respectively are, 77. A woman heterozygous for colourblindness marries a
colourblind man. What would be the ratios of carrier
daughters, colourblind daughters, normal sons and
colourblind sons in the F1 -generation?
(a) Ph-C=C-H and (a) 1 : 2 : 2 : 1
(5:"'
N02 (b) 2 : 1 : 1 : 2
(c) 1 : 1 : 1 : 1
(d) 1 : 1 : 2 : 2
(b) NH 78. Two semipermeable bags containing 2% sucrose are

L , aod placed in two beakers, 'P' containing water and 'Q'
Ph
N02 containing 10% sucrose. Which one of the following
H2 N outcomes is true?
0 (a) Bag in 'P' becomes flaccid due to exosmosis
(b) Bag in 'P' becomes turgid due to endosmosis
(c) 9
and (c) Bag in 'Q' becomes turgid due to endosmosis
/2 (d) Concentration of sucrose remains unchanged in both
9
N02 79. Children suffering from phenylketonuria are given
food low in phenylalanine and supplemented with
OH tyrosine. This is because they
(d) I
/'--._/
NH2
and
(a) are unable to utilise phenylalanine
(b) do not require phenylalanine
Ph (c) have increased tyrosine anabolism
(d) have increased tyrosine catabolism
80. Two bottles were half-filled with water from Ganga
BIOLOGY
('P') and Kaveri ('Q') and kept under identical airtight
conditions for 5 days. The oxygen was determined to
be 2% in bottle ('P') and 10% in bottle ('Q'). What
76. In which of the following cellular compartments do could be the cause of this difference?
respiratory reactions occur? (a) Ganga is more polluted than Kaveri
(a) Cytoplasm and endoplasmic reticulum (b) Both the rivers are equally polluted
(b) Mitochondria and Golgi complex (c) Kaveri is more polluted than Ganga
(c) Mitochondria and cytoplasm (d) Kaveri has more minerals than Ganga
(d) Only mitochondria
Answers
PART-/
(c) 2 (c) 3 (a) 4 (d) 5 (d) 6 (c) 7 (b) 8 (b) 9 (c) 10 (b)
11 (d) 12 (b) 13 (c) 14 (c) 15 (b) 16 (a) 17 (d) 18 (b) 19 (a) 20 (c)
21 (d) 22 (b) 23 (d) 24 (a) 25 (b) 26 (c) 27 (a) 28 (c) 29 (b) 30 (a)
31 (a,d) 32 (c) 33 (d) 34 (a) 35 (b) 36 (c) 37 (d) 38 (b) 39 (a) 40 (c)
41 (b) 42 (d) 43 (c) 44 (c) 45 (a) 46 (b) 47 (c) 48 (b) 49 (d) 50 (b)
51 (d) 52 (c) 53 (a) 54 (b) 55 (a) 56 (d) 57 (b) 58 (b) 59 (c) 60 (d)
PART-I/
61 (b) 62 (a) 63 (d) 64 (a) 65 (d) 66 (b) 67 (d) 68 (c) 69 (a) 70 (d)
71 (b) 72 (a) 73 (d) 74 (a) 75 (a) 76 (c) 77 (c) 78 (b) 79 (a) 80 (a)
WWW.JEEBOOKS.INl
Solutions
1 . (c) We have, r be root of the equation 4. (d) We have, MEB is an equilateral.
AB = BE = AE
E
x2 + 2x + 6 = 0 x and y be two-digit numbers.
r 2 + 2r + 6 = 0 Let x = 10a + b, where b is units place and
r = - (2r + 6)
2 a is ten's place.
Now, (r + 2) (r+ 3) (r + 4) (r + 5) y = lOb + a
= (r 2 + 5r + 6) (r2 + 9r + 20) x2 _ Y2 = m2
= (- 2r - 6 + 5r + 6) (- 2r - 6 + 9r + 20) (10a + b) - (10b + a)2 = m2
2
⇒ (10a + b + 10b + a)
= (3r) (7r + 14) = 2 1 (r 2 + 2r)
- - - �a
[·: r 2 + 2r = - 6j
A�
In M3DE and MBC,
(10a + b - lOb - a) = m2
l l(a + b) · 9 (a - b) = m2
= 21 x (- 6)
LBED = LABC
⇒
LDBE = LCAB given,

= - 126 ⇒ 99(a2 - b2) = m2
2. (c) Given, 3 x 1 1 (a2 - b2) = m2
[·: LDBE = LDBC]
2 ⇒
⇒
Now, 3 x l l(a 2 - b2) is a perfect square. M3ED - MBC
2
BE - BD - ED BE - ED
- - - ⇒- -
⇒/(x) + ( x + i ) t (l - x) = l . . . (i)
·: a2 - b2 = 1 1 ⇒ (a + b)(a - b) = 1 1 x 1
a + b = 1 1 and a - b = 1 1 AB AC BC AB BC
AB AE - AD
Put x = 1 - x, we get
/(1 - x) + ( 1 - x + i) r (1 - (1- x) = 1 On solving, we get a = 6, b = 5 ⇒
AB BC
AE - AD = BC ⇒ AB = AD + BC
·: Number x = 60 + 5 = 65
⇒
7. (b) Area of lune = Area of semi-circle
⇒ /(1 - x) + r n - x) /(x) = l . . . (ii) y = 56
ACBD - Area of segment AEBA

2
and m = (65) 2 - (56)2 = (65 + 56) (65 - 56)
Eq. (ii) multiply by (x + i } we get ⇒ m2 = 12 1 x 9 ⇒ m = 33
C
i)
X + y + m = 65 + 56 + 33 = 154
r n - x) (x + i) t<x) + (x + 5. (d) We have,
p(x) = x2 - 5x + a and q(x) = x2 - 3x + b
/(1 - X) = X + -1 . . . (iii) Given, (x - 1) is HCF of p(x) and q(x).
2
·: p(l) = 0 and q(l) = 0
·: p(l) = 0 = 1 - 5 + a and q(l) = 0
On subtracting Eq. (iii) from Eq. (i), we get
/ (x) 1 - (� + x - x2 )] = 1 - x - i = 1- 3 + b 60°
[
⇒ a = 4 and b = 2
-1 - x ·: p(x) = x2 - 5x + 4 and q(x) = x2 - 3x + 2 0
⇒/(x) = 2 ⇒/(0) = 2 and /(1) = - 2 -2- - - -
-
x2 - x + -
1 ⇒ p(x) = (x - 1) (x - 4)
� � 60
2
2
0../3 (1)2
-
= 1t( ) [ X 1t X (1) - ]
4 and q(x) = (x - 1) (x - 2) 2 2 360 4
[i - :3] i - � :3 :3 -
·: 2/(0) + 3/(1) - 2(2) + 3 (- 2) = 4 - 6 = - 2 LCM of p(x) and q(x) = k(x)
1t
3 . (a) G1ven,
p (x) . q(x) = - = + =
i3 + :i3 + W + ... + (2n)3
12 + 22 + 32 + ... + n 2
. k(x) = � 24
8. (b) Given,
HCF ofp(x)and q(x)
(2n )2 (2n + 1)2 r·: Ln 3

2
= n (n + 1)
2 k(x) =
(x - 1) (x - 4)- (x - 1) (x - 2)
x-1 In MBC
_
- 4 4 A
n (n + 1 (2n + 1) j k(x) = (x - 1) (x - 2) (x - 4)
� Ln 2 = n (n + 1�(2n + 1) Now, x - 1 + k(x)
= x - 1 + (x - 1) (x - 2) (x - 4)
4n 2 (2n + 1)2
6n (2n + 1) = (x - 1) (1 + x2 - 6x + 8)
4 _
-
n (n + 1)(2n + 1) = (x - 1) (x - 3) (x - 3)
n+1
6 ·: Roots of x - 1 + k(x) are 1, 3, 3.
2
12n + 6n 6_ Sum of roots are 1 + 3 + 3 = 7
6. (c) ABCD is a quadrilateral
= = (l2n _ 6) + _
n+l n+ l
·: -- is an integer if n + 1 is factor of 6.
6 LDAB = LABC = 60°
LCAB = LCBD The angle bisector BD and CE are divided
B F C
n+l and
·: n + 1 = 1, 2, 3, 6 ⇒ n = 1, 2, 5 Construction, AD and BC produced to by incentre I in the ratio 3 : 2 and 2 : 1
Sum of n = 1 + 2 + 5 = 8 meet at such that respectively.
WWW.JEEBOOKS.INl
BI 3 1 0. (b) Given, 1 2. (b) Given,

ID 2 OA = OB = OF radii of circle
CI 2
Population in year 2010, 201 1 and 2013
BC is tangent on circle at B
IC 1
and were 39, 60 and 123 respectively.
AI b + c BI = a + c
A According to problems,
' IF a ' ID b '

We know = The population of cattle in farm increases
CI a + b n + 2 and that in year n is proportional to

such that difference between in year
IE the year n + 1
BI a + c
C
- = - ⇒ 2(a + c) = 3b . . . (i)
3 (n + 2) - (n) = k (n + 1)
ID - b
-=
CI a + b 2
2 ·: Let population in year 2012 = x
and - = - - = - ⇒ a + b = 2c
IE c
. . . (ii) Year Population
1 2010 39
On solving Eqs. (i) and (ii), we get C 2011 60
b = �a and c = � a
�--
AB = BC
2012 X
OA = AB
2 4 2013 123
-a+ -a
AI = b + c = 2 In MOB,
3 5
4 = !_2 - x - 39
=k . . . (i)
IF a a 4 AO = OB = AB
60
LABO = 60° and 123 - 60 . . . (ii)
Hence, ratio = 1 1 : 4 =k
9. (c) Given, [·: ABC is an equilateral triangle]
AB and CD are direct common tangents
on circle PQ is transverse common

In MBC,
AB = BC
-
x -- 39 - 123 - 60
tangent PQ cuts AB in R and CD in S.

X
LBAC = LBCA
60
⇒ x2 - 39x - 3780 = 0
⇒ LBAC + LBCA + LABC = 180° ⇒
2LBAC = 180° - 90° - 60°
(x - 84) (x + 40) = 0
⇒ X = 84
⇒ LBAC = 15° 1 3. (c) We have,
In /J.OBC, OB = OC 6-digits number are ababab .
LBOC = LBCO = 45° ·: ababab = Hf a + 104 b + lo'3 a + 102 b
⇒ LBOF = 2LBAF + 10a + b
[·: angle subtend on centre of circle is = (Hf + lo'3 + lO)a + (10 + 102 + 1) b
4
twice the angle subtend an arc of circle] = (104 + 102 + 1) (10a + b)

LBOF = 30°
LBOF- - -
= (10000 + 100 + 1) (10a + b)
AB = lO 30° - -2
LBOC 45° 3
= (10101) (10a + b)
RP = RA = 3 x 7 x 13 x 37 (10a + b)
-
[·: tangents from external point 1 1 . (d) Let total seats = x Since, 6-digit number are product of
on a circle are equal] Ticket price of each seat = '{ 200 exactly 6 primes.
Similarly ·: 10a + b is product of 2 primes,
RQ = RB
On first day 60% of seats over filled
10a + b is lie between 10 to 99.
SP = SC
·: Total revenue = � x x 200 = 120x
100 10a + b = 10 = 2 x 5
RS = SP + PQ + RQ On second day 22 = 2 X 1 1
RS = SP + RP Ticket price = 200 - 20% of 200 = 160 34= 2 X 17
RS = SP + RA Total seat filled on 2nd day 38= 2 X 19
RS = SP + AB - RB . . . (i) = -X + - X - = -
60 50 60x 90x 46 = 2 X 23
Also, SQ = SD 100 100 100 100 55 = 5 X 1 1
RS - QR = CD - CS Total revenue on 2nd day 58 = 2 X 29
RS = QR + CD - CS = 9ox x 160= 144x 62 = 2 X 31
RS = RB + AB - SP . . . (ii)
100 74 = 2 x 37
Percentage increase in revenue on 2nd 82 = 2 X 41
SP = RB
day
85 = 5 X 17
RS = SP + AB - RB
144x - 120x X lO0
=( ) 94 = 2 X 47
RS = AB = 10
120x
95 = 5 X 19
=� X 100 = 20% ·: 13, 6-digits number.
120
WWW.JEEBOOKS.INl
1 4. (c) Let the number of houses be 1 6. (a) In given displacement-time

h, its speed when it reaches the ground is
1 9. (a) When box is dropped from height
X, X +2, X + 4, X + 6, X + 8, X + 10, ... graph, velocity at a particular point is
6th number of house is a. given by the slope of tangent to curve v = .J2gh
drawn at that point.
x + lO = a ⇒ x = a - 10 When block slides down the inclined
x > 10
Speed is the magnitude of velocity, so
magnitude of slope gives speed. plane 0 = 45°,
Now, Sn = ?!'.. (2x + (n - 1)2) X
2
Sn = n(x + n - 1)
⇒ 170 = n (a - 10 + n - 1)
2
⇒ n + (a - l l)n - 170 = 0
- - - -
R
(a - 1 1) ± v1 (a - 1 1)2 + 680
⇒ n=
2 As angle of tangent at R(03 ) is maximum,
maximum at R. Hence, speed is

(1 1 - a) ± ,/ (a - 1 1)2 + 680 so slope' s magnitude I ml = I tan 03 I is Net downward acceleration of block is
increasing at point R.
⇒ n= mg sin0 - /
2 a = ----
m
n�6
1 7. (d) In an evacuated chamber, where, f = friction force.
(1 1 - a) ± \l (a - 1 1)2 + 680 buoyant force of air is absent, so reading
�6 mg sin0 - µmgcos0
2 of spring balance is more than 50 kg. ⇒ a=
1 8. (b) In given situation, forces on each
m
800 '.,'.;
⇒ a '.,'.; 33.33 = g (sine - µ cos0)
24 of charged sphere are
12 '.,'.; a '.,'.; 32 = __f_ (1 - µ)
(i) gravitational pull (mg) .J2
a = 12, 14, 16, 18, . . .
When, a = 1 8, n = 10, then Sn = 170
(ii) electrostatic repulsion ( k; q2 )
2 [·: sin0 = cos0 = 1• when 0 = 45°]
a = 18 (iii) tension of string (T)
1 5. (b) We have,
Velocity of block when it reaches bottom
as shown below. of inclined plane is
a2 , (¾ , a4 , £1:; , a6 , � are integers.
v' = ..f2as
� = � + G:i + a4 + £1:; + a6 + � where, s slope length of inclined plane.
=
7 2! 3! 4! 5! 6! 7!
and O '.,'.; aj < j ⇒ v' = .J2ah / sin0
� = 2520a 2 + 840a 3 +210a 4 +42a5 + 7a 6 + a1 1
7 7!
=
(2 � (1 - µ ) x -2 )
⇒ 3600 = 2520� + 840(1:J + 210a4 = .J2gh (1 - µ )
If we resolve tension in horizontal and
+ 42£1:; + 7a6 + � vertical directions, we have following = � (given)
O '.,'.; aj < j situation in equilibrium. 3
a2 = 1 T cos e So, .J2gh (1 - µ ) = � .J2gh
(¾ E {}, 2}
If G:i = 2, then 2520 + (840) x 2 > 3600
3
1
⇒ 1- µ = -
·: l¾ must be 1 9
T sin e 1 8
a4 E {}, 2, 3} ⇒ µ l- - = -
If a4
=
9 9
20. (c) Thermal resistance of thin layer
=2, then 2520 + 840 + 210(2) > 3600
·: a4 must be 1 mg
k of paper is quite less, so heat reaches
3600 = 2520 + 840 + 210 + 42£1:; So, T sin 0 = <Ji2q2 and T cos0 = mg across the paper and water absorbs that
+ 7a6 + � r
k heat. Temperature of paper does not rises
⇒ 30 = 42£1:; + 7a6 + � ⇒ tan0 = 2<Ji q2 beyond 100°C and upto its burning
r - mg
If
£1:; E {l, 2, 3, 4}
temperature.
£1:; = 1 As angle 0 is same for both spheres, we
:. Paper cup does not catches fire.
2 1 . (d) When ice is crushed, total surface
30 < 42 + 7a6 + � have
£1:; = 0 tan01 = tan02
Put £1:; = O, then 30 = 7a6 + � k<Ji q2 - k<Ji q2 area of ice that comes in contact with
or surrounding air increases. As a result
·: a6 = 4 and � = 2 r 27ni g r 2m2g crushing the ice speed up the cooling
·: a2 + l¾ + a4 + £1:; + a6 + � process.
= 1+ 1+ 1+ O + 4 + 2= 9
⇒ "'1 = m2
WWW.JEEBOOKS.INl
22. (b) Graph of deviation o versus angle kQ 2 kQ 2 ! 2 kQ 2 1 2 As gold is very malleable, it is possible to
=
of incidence i is as shown below (for an d d /2 d/2 produce a foil which is only few atoms
equilateral glass, µ = � prism). kQ 2 thick.
2 =- =-E
d 30. (a) Isotopes have same number of
0 [from Eq. (i)] protons. All isotopes of few elements are
26. (c) Direction of current in ring is
stable and non-radioactive. Also, all
isotopes of few elements are unstable and
given by Lenz's law,
radioactive. All elements have isotopes.
"" ::::�
------------- '
�-- ' All isotopes of carbon can form
Bm = 38° ------:----- : compounds with oxygen.
''' '' ''i
''
°
''
'
° °
''
'
°
'=" ·- �! """" "' So, only statements III and IV are correct.
40 45 50 60 anti:clockwise in
nng when �r=- : �
:
appears
on this face
31 . (a, d) Isoelectronic species are those
Clearly, angle of incidence for least viewed from � � of ring species, which have same number of
deviation lies between 40° < i < 50°.
above
electrons. The total number of electrons
23. (d) In air, focal length / of concave
''
'' in each pair given in the options are as
''
r'
follows
S
lens is given by When viewed
from above
(a) CO, N2
J:_ = ___!_ - ___!_
(µ - 1) ( )
Current flows
. rrent appears No. of electrons in CO = 6 + 8 = 14
f.ir Hi_ R2 ant1-clockw1se ,n clockwise
ring when No. of electrons in N 2 = 7 + 7 = 14
R2 = +
Here, nga = 16, Hi_ = - 0.2 m viewed from �
bottom North pole
(b) 02 , NO
,
!arr (c) Ci, HF

and 0.2 m : appears No. of electrons in 02 = 8 + 8 = 16
on this face
_ -2 - 0.6 x 2 No. of electrons in NO =7+ 8 = 15
J:_ = (16 1) )= of ring
( 0.2 0.2
1 No. of electrons in C2 = 6 + 6 = 12
f,.
27. (a) Neutral point appears in region
⇒ air = - - m
6 No. of electrons in HF = 1 + 9 = 10
When this lens is dipped in a medium of in which fields of magnets are in opposite (d) F2 , HCl
refractive index nea = 2.0, then directions. No. of electrons in F2 = 9 + 9 = 18
/iiquid - nga - 1 - nga - 1
fafr
- - No. of electrons in HCl = 1 + 17 = 18
nge - 1 nga
- 1) Thus, CO and N 2 , F2 and HCl are
(
nea isoelectronic pairs.
fa 0.8 - 1
⇒ ⇒ le = � 32. (c) The molecular formula of
hydrazine is NH 2NH 2 •
0.6 From the structure, it is clear that it has

⇒ f. = � x = � m = 0.5 m 2 lone pairs and 5 bond pairs (4 N - H
e 6 0.2 2
and 1 N-N).
33. (d) C (s) + O2 (g) ----t COig)
Hence, lens acts like a convergent lens
of 0.5 m.
24. (a) As particle is initially at rest, so 1 mole of carbon reacts completely with
to move the charged particle an electric 1 mole of oxygen to produce 1 mole of CO2 •
field is required. 12 g of C reacts = l mole ofO2
As path of particle is a curve, so direction 2.4 g of C reacts with = J:.. x 2. 4
of electric field must be changing with From above figure, we can conclude that 12
distance. = 0.2 mole of 02
25. (b) Electrostatic energy of two equal
magnetic fields cancel each other in
region I only.
28. (c) In a simple harmonic motion,
At STP 1 mole ofO2 contains = 22.4L
charges of magnitude Q placed d distance :. 0.2 mole of 02 contains = 22. 4 x 0.2
apart is oscillating particle passes extreme = 4.48 L
positions two times, while it crosses 34. (a) The most often used stationary
. . . (i)
mean position once in each half of phase gel and alumina are polar material.
r12
oscillation. Consequently, the least polar compound
Now, when a third charge - � }s placed So, graph (c) most closely resembles this will have the highest R1 value, as they
(
situation. will be least bounded to the stationary
29. (b) In Geiger-Marsden experiment,
at mid-point of these charges, phase and moves quickly up the TLC
then electrostatic energy of system is plate.
objective is to target a-particles towards
E' = k<Ji q2 + kq2(JJ + k<Ji Ck, an atom. This is possible only when Among the given compound, compound (a)
target is a very thin metal foil. is le� st polar, so its R1 value will be
maximum.
WWW.JEEBOOKS.INl
35. (b) 0 constant. Thus, the reaction with largest

14
1 3�
equilibrium constant will be
16 17
15
F � G, /J.G 0 = - 150 kJ mol-1
45. (a) As 0, F and Ne belong to same
period, i.e. 2nd period, the ionisation
Thus, the number of C - C sigma bonds energies increases on moving from left to
in the above given compound are 17.
36. (c) According to Bohr's radius of an
right. This increase in ionisation energy
Thus, the average speed of helium is is due to decrease in the atomic radii
atom across a period. Thus, the first ionisation
52. 9n 2 higher than of oxygen by a factor of 2-/2.
40. (c) The products formed in each
=- enthalpies for 0, Fe and Ne are 1314,
rn - - pm
z 1680 and 2080, respectively. So, the
where, n = charge on atom reaction given in the options are as correct sequence of the element is 0, F
Z = atomic number follows and Ne.
rHe+ =
529 x 12
= 26.45 = 27 pm (i) NH4 Cl + KOH -----t KCl + NH 3 + Hp 46. (b) Population is a group of
2 (ii) AlN + 3H2O -----t Al(OH)3 + NH 3 individuals belonging to same species
Thus, the radius of He+ ion is closest to occupying a particular geographic area in
27 pm. (iii) NH4 Cl + NaNO2 -----t NaCl + N2 + 2Hp
37. (d) Diamagnetic species are those
a given time. A community is a group of
(iv)NH4Cl + Ca(OH)2 -----t CaC1 2 + NH3 + Hp people living in the same place or having
species which have paired electrons in Thus, ammonia is not produced in a particular characteristic in common.
their molecular orbitals. reaction given in option (c). Biome is a large naturally occurring
The electronic configurations of molecules 41 . (b) Isomers of compound of molecular community of flora and fauna occupying a
given in the options are as follows formula C4H100 are as follows major habitat. Species is a group of living
(i) NO CH3CH(OH)CH2CH3 organisms consisting of similar
Total number of electrons = 7 + 8 = 15 individuals capable of interbreeding.
47. (c) The energy assimilated by the
The electronic configuration of NO will be CH3CH2CH2CHpH
cr1s2 , cr * 1s2 , cr2s2 , cr * 2s2 , cr2p; , n2p; CH3 - 0- CH2 - CH2CH3 herbivores is used in respiration and a
= nzp;, 1t * 2p! CH3 - CHpCH2CH3 fraction of unassimilated energy is
CH3 transferred to decomposers (e.g. faecal
(ii) N02
CH3 - 0- CH - CH.i matter). With increasing trophic levels,
Total number of electrons = 7 + 8 + 8 = 23 the respiration cost also increases
The electronic configuration ofNO2 will Thus, there are 3 isomers which are sharply. On an average, producers
be [18 Ar] cr * 2p;, cr3s2 , cr * 3s1 ethers having the molecular formula consume about 20% of their gross
(iii) 02 C4H10 0. productivity in respiration. The
Total number of electrons in 02 = 16 42. (d) The major product of the reaction herbivores consume about 30% of
Electronic configuration of 02 will be of 2-butene (alkene) with alk. KMnO4 assimilated energy in respiration. In
cr1s2 cr * 1s2 cr2s2 cr * 2s2 cr2p; solution is a vicinal glycol, i.e. butane-2,3 carnivores, the proportion of assimilated
1t2p; 1t2p; 1t * 2p! 1t * 2p; diol. energy consumed in respiration rises to
about 60%.
48. (b) Athletes are often trained at high
(iv) CO2 OH
2� 4 Alk. KMn04
T
Total number of electrons in ,,.. 2 ,,l_ 0 .,,...4
CO2 = 6 + 8 + 8 = 22 1� (Syn addition) v altitude because the air is 'thinner' at
The electronic configuration of CO2 will be 2-butene
OH high altitudes, means there are fewer
[18 Ar] cr * 2p; cr3s
2 oxygen molecules per volume of air.
43. (c) The boiling point of a compound
Butane-2, 3-diol
Thus, CO2 is a diamagnetic species. Every breath taken at high altitude

38. (b) NaCl (NaOH + HCl) is a neutral depends upon the extent of H-bond delivers less of what working muscles
present in it. As compound I, II and IV require. To compensate for the decrease
salt, NH4 Cl (HCl + NH4 OH) is an acidic
salt while CH.i COONa are alcohols, so they can easily form in oxygen there occurs more production of
(Cil.i COOR + NaOH) is a basic salt. H-bonds while compound III is an ether red blood cells to aid in oxygen delivery to
and cannot form H-bonds. Thus the muscles.
49. (d) Corpus callosum is nervous band
The value of pH of acidic salt is less than
7, while for neutral salt pH value is equal compound III, i.e. /"--...o/"--... has
lowest boiling point.
44. (c) The relation between Gibbs free
to 7 and for basic salt pH value is greater which attaches both cerebral
than 7. Thus, the increasing order of pH hemispheres of mammals. It is a thick
0. 1 M aqueous solutions of NaCl, energy and equilibrium constant can be band of nerve fibres that divides the
CH.i COONa and NH4 Cl will be given as cerebral cortex lobes into left and right
NH4 Cl < NaCl < CH.i COONa. /J.G 0 = - 2.303RT log K0q hemispheres. It connects the left and
39. (a) At room temperature log Keq = - /J.G 0 I 2.303RT right sides of the brain allowing for
Vavg = ✓ S:: The reaction having most negative value

of /J.G 0 will have the largest equilibrium
communication between both
hemispheres.
WWW.JEEBOOKS.INl
50. (b) Glucagon is secreted from alpha Its pathway is as discussed below 62. (a) We have,
cells of pancreas. Prolactin is secreted by Receptor ------t Sensory neuron ------t 1947
1
the anterior pituitary. Luteinising (Skin)
Integration centre
l
n
hormone is secreted by the gonadotropic (Spinal cord) n�O 2 + ,/�
cells in the anterior pituitary. Let

Epinephrine (or adrenaline) is secreted
by the medulla of the adrenal gland. Effector � Motor neuron
5 1 . (d) The stalk of plant leaf (petiole) is
1 1
58. (b) In photosynthesis,
(muscle)
/(0) + /(1947) = - - -- +
1 94 '7 1 9�7
- -
derived from collenchyma. Collenchyma 1+ 2 2 z-
947
+2 2
cells are elongated cells with irregular Light reaction ➔ Photolysis of water (Hp
is oxidised) 1 1
thick cell walls that provide structural
support, particularly in growing shoots 2Hp ➔ 02 + 4 [HJ requires light reaction
and leaves. Their thick cell walls are
l
Dark reaction ➔ CO2 is reduced for sugar
composed of the compounds cellulose and formation 1947
pectin.
52. (c) Both smooth muscle (unstriated
4 [HJ + CO2 ➔ (CHp) + Hp (Reduction) 2 2 +1 1
59. (c) A mature REC lacks nucleus,
1947 1947 I !147
muscle) and cardiac muscle are 2 2 [2 2 +1 2 2
mitochondria and endoplasmic reticulum.
functionally involuntary. Muscles that
In humans, mature RBCs are flexible and
are under our conscious control are called
oval biconcave disks. They lack a cell Similarly, / (1) + / (1946) = �
voluntary muscles, while muscles that
I,! (x) = f(0) + / (1) + / (2) + / (3) +

nucleus and most organelles, in order to 1,1 ,
are not under our conscious control are 2 2
accommodate maximum space for
called involuntary muscles. Striated 1947
haemoglobin.
60. (d) Antivenom injection provides
muscles are voluntary muscles.
53. (a) Pulmonary artery arises from left
n=O
artificial acquired passive immunity. . ... + /(1947)
ventricle and carries deoxygenated blood
Passive immunity is the transfer of active
to the lungs. = (/(0) + /(1947) + (/(1) + /(1946)) + ...
humoral immunity of readymade
The pulmonary artery begins in the heart antibodies. It can occur naturally, when ... + (/(973) + /(974))
at the base of the right ventricle. 1
54. (b) Gout is caused by the deposition
maternal antibodies are transferred to = 974 x --
19.17
1
foetus through placenta and it can be
2 2
;!� - )487
of uric acid in joints. Composition of induced artificially when high level of
kidney stone is calcium oxalate, calcium antibodies specific to a pathogen or toxin l f (n) =
2x
phosphate, uric acid, xanthine and indigo are transferred to non-immune persons n= O
-
2 1 u45
calculi. Researches have shown that through blood products that contain 2 x2 2
kidney stones are a complication of gout antibodies, such as antivenom injections 63. (d) Given,
because extra uric acid can collect in the are given. x + y = a ⇒ aE [1,2014J
urinary tract and crystallise into stones.
55. (a) Cochlea is the main hearing
61 . (b) Given, a + b + e = 0 ⇒ a, b, e E R 2 2
and - x - + --
v
· =4
⇒ a 2 + b 2 + e2 = q x-1 y-1
organ. It is composed of sensory cells
called hair cells, which convert vibrations ⇒ a4 + b4 + e4 = r
x2 2
into neural messages. These messages ⇒ (a 2 + b2 + e2) 2 = a 4 + b4 + e4 - - + - Y- = 4

x-1 y-1
are then passed to the auditory nerve and + 2 (a2b2 + b2e2 + e2a 2)
carried up to the brain. ⇒ x y - x2 + xy2 - y2 = 4(x - l)(y - 1)
2
56. (d) Mitochondria and chloroplast
⇒ (a 2 + b2 + e2) 2 = a 4 + b4 + e4 + 2
[(ab + be + ea) 2 - 2abe(a + b + e)J ⇒ x2y + xy2 = 4(xy - (x + y) + 1) + x2 + y2
contain circular DNA. Even though both
⇒ q2 = r + 2[(ab + be + ea)2 - 2(abe)(0)J ⇒ xy (x + y) = 4(xy - a + 1)
organelles are found in eukaryotic cell,
both mitochondria and chloroplast have ⇒ q2 = r + 2 [ab + be + eaJ2 + (x + y)2 - 2xy
characteristics often found in prokaryotic ⇒ l=r+2 ⇒ xy(a) = 4xy - 4a + 4 + a2 - 2xy
cells. These prokaryotic cell's (a + b + e)2 - (a2 + b2 + e2)
2
[ ] ⇒ xya - 2xy = a2 - 4a + 4
characteristics include enclosed double
qr
2
membrane, circular DNA and bacteria ⇒ xy (a - 2) = (a - 2)2
like ribosomes. 0
⇒ q2 = r + 2 ( ;
57. (b) Reflex actions do not involve the
⇒ (a - 2)2 - xy (a - 2) = 0
2q 2 ⇒ (a - 2) (a - 2 - xy) = 0
brain in the decision making process. ⇒ l=r+-
Reflex action is a rapid, spontaneous and 4 ⇒ a = 2 or xy = a - 2
involuntary activity that is produced in or x (a - x) = a - 2 [·: y = a - xJ
response to a stimulus. It is controlled by
⇒ t - Il = r
2
⇒ x2 - ax + a - 2 = 0
spinal cord. ⇒ l = 2r
WWW.JEEBOOKS.INl
R ⇒ � x �� + ij + b � + ij + a � + ij
eir - (�) - l O
= 30
Since, X E Rearranging, we get
D '?. O
⇒ (c + 1) (a x b + b + a + 1) = 30
a2 - 4 (a - 2) '?. 0
+ (c + 1)
⇒ =
⇒ (c + 1) (b(a + 1) + l(a + 1)) = 30

a2 - 4a + 8 '?. 0, 'd a E R (a + l)) (b + 1) (c + 1) = 30 ⇒
(1,_
=
1± \,�
1+ 4
b
⇒
2
a E [1, 2014] l '.,'.; a '.,'.; 9, 0'.,'.; b, c '.,'.; 9
64. (a) Given,
a .J5 + 1
⇒
ABC is right angled triangle.
b
·: Total number of solution = 18
66. (b) Centre of mass of square wooden Note Choice of a different origin gives a
2
B plate with respect to chosen axis is at

different value of!:!:..
centre of plate. b
Q
67. (d) For a soap bubble floating in air,
X ..-- � - � - +-_
a
Gravitational force = Buoyant force
⇒ g (mass of helium + mass of soap film)
-,ff
a/2 = Weight of air displaced by bubble . . . (i)
-./5
2 , Y1
C A y
LA = 90
.xi 2
° Coordinates of centre of mass are
AC = .J5 =
a =
a
AB = ,.ft Mass of square plate, "Ii = ka

2
PA 3
Let r = inner radius of soap bubble and
where, k = mass per unit area. t = thickness of film.
PB 4 Coordinates of centre of mass of removed Then, from Eq. (i), we have
- 1tr3 X Ptte + 41tr 2 X t X Psoap
BC2 = AB2 + AC2 = 5 + 7 = 12
In MBC portion and its mass with respect to axes 4
⇒
chosen are
BC = M = 213
3
= 4 nr3 x Parr 3
In MBP,
2 2 2
b/2
cosB = AB
- - + - PB- -- AP-
Substituting values in above equation, we
2AB - PB b/2 get
-.ft _ 7 + 16x2 - 9x2 ⇒� X 1t X (10-2 )3 X 0.18 + 41t X (10-2)2

⇒ 3
213 - 2 - ,./7 X 4x
x t x lO00
[·: cosB = �� = �] b b = � X 1t X
y
(10- )3 2
X 1 23
X2 = - , Y2 = -
2
2 2 3
= kb2 i 1t (10-6 ) (108)

2 Rearranging, we get
� = 7 + 7x2 ⇒ 28x = 7../3 (x + 1) and mass of removed portion,
"½
⇒
.J3 x2 - 4x + .J3 = 0
⇒ 41t (10- ) · t · 1000 =
,, 3 2
✓3x2 - 3x - x + .J3 = 0
⇒ 3
Now, centre of mass of remaining
⇒ (10 5 ) t = 0.35
=0
⇒ L-shaped portion is given at point
⇒ ✓
( 3x - 1) (x - ../3) P whose coordinates are (b, b) with or t = 3.5 x 10-6 m
= .J3, �, X "# .J3 = 3.50 µ m
68. (c) As heat lost by aluminium piece =
X
respect to chosen axes.
PB = 4 l ../3
= {ms(Tr
heat gained by water
PC = BC - BP = 213 - _±_ = � {ms (T; - Tr )} aluminium - T; )}water
BP 4/ .J3
.J3 .J3 Substituting given values, we get
PC 2 1 ../3
= = 2:1 ⇒ 50 X 10-3 X 900 X (300 - 160)
65. (d) abcis three-digits number

= 1 X 4200 X (T - 30)
abc = 100a + 10b + c

y ⇒ 6300 = 4200 (T - 30)
100 '.,'.; abc < 999, a E {l, 2, 3, ..., 9} b,cE {0,

- mr2
Now , using XCM = "liXi , we have ⇒ T = 30 + 1.5
"Ii m2
-
ka2 (!:!:.) - kb2(lJ_)

or T = 3 1.5°C
Now, (a x b x c) + (a x b) + (b x c)
1, 2, 3, ..., 9}
a3 _ b3
b= ⇒ b = ____
So, temperature of water after taking out
+ (c x a) + a + b + c = 29
ka2 - kb2 2 2(a - b2)
2 2
aluminium piece is 31.5 °C.
WWW.JEEBOOKS.INl
69. (a) From the geometry of given figure, . . 5

i4 = is ( 3 ) :. Resulting moles of gases in mixture
= X - 0.2 + 10 - X - 0.1 = 9.7
. . . 5. . 8. At constant temperature and volume,
So, current, i5 = i4 + is = - is + is = - i3
3 3 A = P2
= � (3i1 ) = 8 i1 n1 n2
3
⇒ _!_ = P2
Similarly, across section bb, 10 9.7
⇒ p2 = 0.97 atm
We have, for total internal reflections
72. (a) 2NH3 + H2S04 ----t (NH4 )i S04
45° + r > ec . . . (i) 1:] tR Eq. of H2S04 = 2 x 2 x lOx 10-3
and 45° - r > ec . . . (ii)
b c [basicity of H2SO4 = 2]
or 90° > 20c ⇒ sin 45° > sin0c
1 1 ⇒ Eq. of H2S04 = Eq. ofNH3 = No. of moles of
⇒ - > - or µ > -J2 . . . (iii)
-J2 µ ammonia = 4 x 10-2
From Eq. (ii), we have So, current,
. = 13 . . 21 . 21 . 1 mole of Nifs = 1 7 g
45 - ec > r - i + i5 = - i5 = - (8i'l ) = 2 l il :. 4 x 10-2 moles ofNifs = 17 x 4 x 10-2
:. WNH 3 = 17 X 4 X 10-2 g
� 8 5 8 8
sin(45 - 0c ) > sin r
Now, for section aa, we have
1 1 . sin 45°
⇒ lo cos0c - lo sm 0c > - - 14
v2 v2 µ ⇒ WN = x 17 x 4 x 10-2
� gR
1µ 2 1 17
1 1 �
⇒ � - - > - ⇒ -vµ 2 - 1 > 2 _l__J 21 = 0.56 g
µ µ µ 0.56
irG�
⇒ µ > .J5 . . . (iv) a b % of N = x 100 = 28%
2
73. (d) Let the equivalent weight of
Common solution of Eqs. (iii) and (iv) is Ris = + 1) R
ir G�
µ > .J5.
metal M = x
be i.
70. (d) Let current through resistor X is Ri s = R)
(eq)ca (eq)H 2 , released
. . 34 =
⇒ =is X - (eq)M (eq)H 2 , released
� 21
2 1125
Hence, current i is
i = ir + is ⇒ 20 - (eq vol)H 2
Q a c . . . 2 185
= + 34 = 55
b d
Now, we consider section dd,

� 21 � 21 � x (eq vol. )H 2
55 2 1 · X -- 1. 125
=- X i1 - -
= 55i1 = 55 X 10-3 A
21 20 1.85
X 20
1. l25
(·: i1 = lmA, given) ⇒ X=
1.85
Req = 34 k Q
Total resistance across PQ is
Equating potential across dd, we get
d = 12. 16 = 12
55 74. (a) When coke is heated with lime
i,fi = i1 (2R)
34 x 1000 Q (CaO), then CaC2(X) is formed which
or then reacts with water to form acetylene
55
Hence, current i is (Y) as a major product. This acetylene on
So, potential drop across, PQ
� = � + i2 = i1 + 2� = 3� 34 passing over red hot iron at 873 K
3
Now, we consider section cc, = i Req = 55 X 10- X X Hf V
55 produces benzene (Z).
i5 c i3 d = 34V
71 . (b) 18 g of Hp = 1 mole (Coke)
CaO + c - CaC2
Calcium carbide
_L_J
� +- 2R X R = 2R
- 2R + R 3
0
1
lH20
Fe (red hot)
3.6 of Hp = - x 3.6 = 0.2 mole
18
c d
(Trimerisation)
2H2 (g) + 02 (g) - 2H20(l) CH= CH + Ca(OHb
Initially x mol (10 - x) mo! 0 Acetylene
373 K
Equating potentials, we get y
After reaction x - 0.2 10 - x - � 0.2 mol

z
2
i4 R = � ( R + 1 R ) Benzene
WWW.JEEBOOKS.INl
75. (a) The ETC occurs in the plasma membrane On the other hand, the second beaker
Br of prokaryotes and the inner contains 10% sucrose solution which is
(i) Alc. KOH mitochondrial membrane of eukaryotes. more concentrated than the
77. (c) Colourblindness is X-linked

Br �Ph (ii) NaNH2 semipermeable bag's sucrose
(Dehydrohalogenation) concentration. Hence, water will move
recessive disorder.
out of the bag to the beaker and make the
H- C=C - Ph xxc X xcy bag flaccid (exosmosis). Thus, the answer
(X) Heterozygous Colourblind (b) is correct.
HgSOJdil. H2SO4,
woman man
79. (a) Phenylketonuria is an autosomal
j1,, (Acidic hydration
recessive disorder with mutation in gene
�
of alkyne)
for enzyme Phenylalanine Hydroxylase
� Tautomerism
==� H2C = r- Ph xxc xcxc xcy (PAH), making it non-functional.
l
CH3- XY
fi � PAR
0 OH Ratio Phenylalanine � Tyrosine
Conc. HNO:ifH2SO4 Genotype F_i ratio Such person cannot metabolise the above
nitration
Carrier daughter 1 reaction leading to accumulation of
�o, Colourblind daughter 1
phenylalanine. So, are given food low in
phenylalanine and supplemented with
Normal son XY 1
tyrosine.
Colourblind son 1
80. (a) Ganga is more polluted than
78. (b) Osmosis is the net movement of Kaveri ➔ lower DO [Dissolved Oxygen]
0 (m-isomer)
(Y) indicates polluted water
76. (c) Respiratory reactions occur in the

solvent molecules into a region of higher
solute concentration through a 2% ----+ Ganga water (P)
mitochondria and cytoplasm. Respiratory semipermeable membrane. In the given
DO{
question, one of the 2 sucrose containing
reactions include glycolysis, Kreb's cycle
bags (semipermeable) is placed in a water 1 0% ----+ Kaveri water (0)
and Electron Transport Chain (ETC). The
containing beaker. Clearly, the Dissolved oxygen refers to the level of
glycolysis always occurs in the cytoplasm concentration in the bag is more than the free oxygen present in water levels that
of all living cells. The Kreb's cycle occurs beaker and as a result, water will move are too high or too low can harm aquatic
in the cytoplasm of all prokaryotes and in through the semipermeable membrane life and affect water quality.
the mitochondrial matrix in eukaryotes. (endosmosis) and make the bag turgid.
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions
::> PART-I (1 Mark Questions)

MATHEMATICS 5. Let x, y, z be non-zero real numbers such that
1 . Let x, y, z be three non-negative integers such that x y z y z x :l' ,J zP
- + - + - = 7 and - + - + - = 9 then - + - + - - 3
x + y + z = 10. The maximum possible value of y z x x y z ' ,J zP :l'
xyz + xy + yz + zx is is equal to
(a) 52 (b) 64 (c) 69 (d) 73 (a) 152 (b) 153 (c) 154 (d) 155
2. If a, b are natural numbers such that 2013 + a 2 = b2 , 6. In a L1ABC withLA < LB < LC, points D, E, F are on
then the minimum possible value of ab is the interior of segments BC, CA, AB respectively.
Which of the following triangles cannot be similar to
MBC?
(a) 671 (b) 668
(c) 658 (d) 645
(a) f1ABD (b) f1BCE (c) f1CAF (d) f1DEF
7. Tangents to a circle at points P and Q on the circle
3. The number of values of b for which there is an
isosceles triangle with sides of lengths b + 5, 3b - 2
and 6 - b is intersect at a point R. IfPQ = 6 and PR = 5, then the
wo �1 �2 00 3 radius of the circle is
4. Let a, b be non-zero real numbers. Which of the (a) 13 (b) 4
3
following statements about the quadratic equation
(c) 15 (d) 16
ax2 + (a + b)x + b = 0 is necessarily true? 4 5
I. It has at least one negative root. 8. In an acute angled L1ABC, the altitudes from A, B, C
II. It has at least one positive root. when extended intersect the circumcircle again at
III. Both its roots are real. points A1 , Bi , C1 respectively. If LABC = 45 °, then
(a) I and II only (b) I and III only LA1.Bi_C1 equals
(c) II and III only (d) All of them (a) 45° (b) 60° (c) 90° (d) 135°
WWW.JEEBOOKS.INl
9. In a rectangle ABCD, points X and Y are the

mid-points of AD and DC, respectively. Lines BX and
PHYSICS
CD when extended intersect at E, lines BY and AD 1 6. A man inside a freely falling box throws a heavy ball
when extended intersect at F. If the area of ABCD is towards a side wall. The ball keeps on bouncing
60, then the area of BEF is between the opposite walls of the box. We neglect air
(a) 60 (b) 80 (c) 90 (d) 120 resistance and friction. Which of the following figures
1 0. In the figure given below, ABCDEF is a regular depicts the motion of the centre of mass of the entire
hexagon of side length 1, AFPS and ABQR are system (man, the ball and the box)?
squares. Then, the ratio ar (APQ) /ar (SRP) equals
A B
1 7. A ball is thrown horizontally from a height with a

F C
certain initial velocity at time t = 0. The ball bounces
repeatedly from the ground with the coefficient of
restitution less than 1 as shown below.
E D
+1
(a) -/2 (b) -/2 (c) 3-J3 (d) 2
2 4
1 1 . A person X is running around a circular track
completing one round every 40 s. Another person Y
running in the opposite direction meets X every 15 s. Neglecting air resistance and taking the upward
The time, expressed in seconds, taken by Y to complete direction as positive, which figure qualitatively
one round is depicts the vertical component of the ball's velocity vy
as a function of time t?
1 2. The least positive integer n for which
(a) 12.5 (b) 24 (c) 25 (d) 55
-Jn+i - -Jn - 1 < 02 is

(a) 24 (b) 25 (a)
1 3. How many natural numbers n are there such that

(c) 26 (d) 27
n ! + 10 is a perfect square?
(a) 1 (b) 2
(c) 4 (d) infinitely many
(c) (d)
1 4. Ten points lie in a plane so that no three of them are
collinear. The number of lines passing through
exactly two of these points and dividing the plane
into two regions each containing four of the 1 8. A tall tank filled with water has an irregular shape
remaining points is as shown. The wall CD makes an angle of 45° with
(a) 1 the horizontal, the wall AB is normal to the base BC.
(b) 5 The lengths AB and CD are much smaller than the
(c) 10 height h of water (figure not to scale).
(d) dependent on the configuration of points
1 5. In a city, the total income of all people with salary
below � 10000 per annum is less than the total
income of all people with salary above � 10000 per
annum. If the salaries of people in the first group
increases by 5% and the salaries of people in the
second group decreases by 5%, then the average h
income of all people
(a) increases
(b) decreases
(c) remains the same
(d) cannot be determined from the data B C
WWW.JEEBOOKS.INl
Let Pi p2 and p3 be the pressures exerted by the

water'on the wall AB, base BC and the wall CD
23. In a car, a rear view mirror having a radius of
respectively. Density of water is p and g is

curvature 1.50 m forms a virtual image of a bus
located 10.0 m from the mirror. The factor by which
acceleration due to gravity. Then, approximately the mirror magnifies the size of the bus is close to
(a) A = p2 = P3 (b) A = 0, p3 = 1 P2 (a) 0.06 (b) 0.07 (c) 0.08 (d) 0.09
-/2
(d) A = Pa = 0, P2 = hpg
24. Consider the following circuit shown below.
I
1 9. The accompanying graph of position x uersus time t

represents the motion of a particle. If p and q are
describes the acceleration a of the particle is

both positive constants, the expression that best
All the resistors are identical. The ratio of I I I' is

X
ws �6 �5 00 4
25. The figure shows a bar magnet and a metallic coil.
Consider four situations:
(I) Moving the magnet away from the coil.
(II) Moving the coil towards the magnet.
(III) Rotating the coil about the vertical diameter.
(a) a = - p - qt (b) a = - p + qt (IV) Rotating the coil about its axis.
(c) a = p + qt (d) a = p - qt
20. Two stones of masses mi and m2 (such that mi > m2)
are dropped M time apart from the same height
towards the ground. At a later time t, the difference An emf in the coil will be generated for the following
in their speed is �u and their mutual separation is �s. situations.
While both stones are in flight (a) I and II only (b) I, II and IV only
(a) du decreases with time and ds increases with time (c) I, II, and III only (d) I, II, III, and IV
(b) Both du and ds increase with time 26. A current of 0.1 A flows through a 25 Q resistor
son
(c) du remains constant with time and ds decreases with represented by the circuit diagram. The current in
time 80 Q resistor is
(d) du remains constant with time and ds increases with
time
21 . The refractive index of a prism is measured using
three lines of a mercury vapour lamp. If µ1 , µ2 and µ3
are the measured refractive indices for these green,
blue and yellow lines respectively, then V 20n
20n 600
(a) µ 2 > µ3 > µ 1 (b) µ 2 > µ 1 > µ3
(c) µ3 > µ 2 > µ 1 (d) µ 1 > µ 2 > µ3
22. A horizontal parallel beam of light passes through a
(a) 0. 1 A (b) 0.2 A (c) 0.3 A (d) 0.4 A
vertical convex lens of focal length 20 cm and is then
to a point I. The distance PI is 10 cm.

reflected by a tilted plane mirror, so that it converges 27. Solar energy is incident normally on the earth's
surface at the rate of about 1.4 kW m-2 • The distance
E and mass m are related by Einstein equation

I between the earth and the sun is 1.5 x 101 1 m. Energy
E = mc2 , where c = 3 x 108 ms-1 is the speed of light in

free space. The decrease in the mass of the sun is
(a) 109 kg s-1 (b) 1o'3° kg s-1
1
26
(c) 10 kg s- (d) 1011 kg s-1
28. If the current through a resistor in a circuit increases
the mirror. The distance PM is 10 cm. The angle
M is a point at which the axis of the lens intersects by 3%, then the power dissipated by the resistor
(a) increases approximately by 3%
which the mirror makes with the horizontal is
(b) increases approximately by 6%
(a) 15° (b) 30° (c) 45° (d) 60° (c) increases approximately by 9%
(d) decreases appro�x�
im
---=-='a� y=b_..,y�3'"""'¾""o��
te'"""l,._
WWW.JEEBOOKS.INl
29. An ideal gas filled in a cylinder occupies volume V. 36. Which ofthe following molecules has no dipole moment?
The gas is compressed isothermally to the volume (a) CH 3 Cl (b) CHC1 3 (c) CH2 Cl2 (d) CC14
V 1 3. Now, the cylinder valve is opened and the gas is 37. The decay profiles of three radioactive species A, B
allowed to leak keeping temperature same. What and C are given below
percentage of the number of molecules should escape
to bring the pressure in the cylinder back to its
original value?
(a) 66% (b) 33% (c) 0.33% (d) 0.66%
C:
0
30. An electron enters a chamber in which a uniform C:

0
Cl)
magnetic field is present as shown below.

u0
C:
These profiles imply that the decay constants

kA , kB and kc follow the order
(a) kA > kB > kc (b) kA > kc > kB
� � > � > kc OO kc > � > �
38. A specific volume of H2 requires 24 s to diffuse out of
a container. The time required by an equal volume of
Magnetic field 02 to diffuse out under identical conditions, is
(a) 24 s (b) 96 s (c) 384 s (d) 192 s
An electric field of appropriate magnitude is also
applied, so that the electron travels undeviated 39. Acetic acid reacts with sodium metal at room
without any change in its speed through the temperature to produce
chamber. We are ignoring gravity. Then, the (a) CO2 (b) H 2 (c) Hp (d) CO
direction of the electric field is 40. The equilibrium constant, kc for
(a) opposite to the direction of the magnetic field
(b) opposite to the direction of the electron's motion
3 C2H2 (g) ===
C6H6 (g)
(c) normal to the plane of the paper and coming out of the is 4 L mor • If the equilibrium concentration of
2 2
plane of the paper benzene is 0.5 mol L -1 , that of acetylene in mol L - 1

(d) normal to the plane of the paper and into the plane of must be
the paper (a) 0.025 (b) 0.25 (c) 0.05 (d) 0.5
CHEMISTRY
41. The weight per cent ofsucrose (formula weight = 342
g mor1 ) in an aqueous solution is 3.42. The density of
the solution is 1 g m L -1 , the concentration of sucrose
31. The molecule having a formyl group is in the solution in mol L -1 is
(a) acetone (b) acetaldehyde (a) o.oi (b) 0.1 (c) 1.0 (d) 10
(c) acetic acid (d) acetic anhydride 42. The order of reactivity of K, Mg, Au and Zn with
32. The structure of cis-3-hexene is water is
(a) K > Zn > Mg > Au (b) K > Mg > Zn > Au
(a) (b) � (c) K > Au > Mg > Zn (d) Au > Zn > K > Mg
�
43. Which of the following is an anhydride?
0 0
(c) � (d) �
(a) )l_ o )l___ CH
H3C
33. The number of sp2 -hybridised carbon atoms in 3
0
0
(c) 0 (d)
II H3C� ( '-..CH3
HC - C-CH2- C - CH2 -CH = CH2 , is 0
(a) 3 (b) 5 (c) 4 (d) 6 44. Which of the following metals will precipitate copper
34. The number of valence electrons in an atom with from copper sulphate solution?
electronic configuration ls22s2 2p63s23p3 is (a) Hg (b) Sn (c) Au (d) Pt
(a) 2 (b) 3 (c) 5 (d) 1 1 45. The radii of the first Bohr orbit of H (rH ), He+ (rHe + )
35. The pair of atoms having the same number of and Li2+ (rLi 2 + ) are in the order
neutrons is (a) rHe + > rH > rLi 2 + (b) rH < rHe + < rLi 2 +
(a) �2 C, fiMg (b) ff Na, � F (c) ff Na, fiMg (d) ff Na, ftK (c) rH > rHe + > rL; 2 + IWWW:� E EBOOKS.IN]
1
BIOLOGY 53. Animal cells after removal of nuclei still contained

DNA. The source of this DNA is
46. The Bowman's capsule, a part of the kidney is the (a) nucleosomes (b) mitochondria
site of (c) peroxisomes (d) lysosome
(a) filtration of blood constituents 54. Which one of the following combinations is found in
(b) reabsorption of water and glucose DNA?
(c) formation of ammonia (a) Guanine and guanidine (b) Guanidine and cytosine
(d) formation of urea (c) Guanine and cytosine (d) Adenine and guanidine
47. In human brain, the sensation of touch, pain and 55. Which one of the following is not a mode of asexual
temperature is controlled by the reproduction?
(a) parietal lobe of cerebrum (a) Binary fission (b) Multiple fission
(b) limbic lobe of cerebrum (c) Budding (d) Conjugation
(c) temporal lobe of cerebrum
(d) frontal lobe of cerebrum 56. Which one of the following classes of animals
constitutes the largest biomass on the earth?
48. A pathogen which cannot be cultured in an artificial (b) Fishes
(a) Insects
medium is (c) Mammals (d) Reptilians
(a) protozoan (b) virus (c) bacterium (d) fungus
57. In the digestive system, the pH of the stomach and
49. Meiosis-I and meiosis-II are characterised by the the intestine, respectively are
separation of
(a) alkaline, acidic (b) acidic, alkaline
(a) homologous chromosomes; sister chromatids (c) acidic, neutral (d) acidic, acidic
(b) sister chromatids; homologous chromosomes
(c) centromere; telomere 58. The major nitrogenous excretory product in
(d) telomere; centromere mammals is
(a) amino acids (b) ammonia
50. People suffering from albinism cannot synthesise
(c) urea (d) uric acid
(a) suberin (b) melanin (c) keratin (d) collagen
59. Which of the following plant traits (characters) is not
51. Short-sightedness in humans can be corrected by using an adaptation to dry (xeric) habitats?
(a) concave lens (b) convex lens
(a) Sunken stomata on leaves
(c) cylindrical lens (d) plain glass
(b) Highly developed root system
52. A person with blood group 'A' can (i) donate blood to (c) Thin epidermis without a cuticle on stem and leaves
and (ii) receive blood from (d) Small leaves and photosynthetic stem
(a) (i) person with blood group 'AB' and (ii) persons with 60. Biological diversity increases with the productivity of
any blood group
an ecosystem. In which of the following habitats do
(b) (i) person with blood group 'A! or 'AB' and (ii) 'A! or 'O'
blood groups we see the greatest diversity of species?
(c) (i) person with blood group 'B' or 'AB' and (ii) 'B' or 'O' (a) Tropical dry grasslands
blood groups (b) Temperate deciduous forests
(d) (i) person with any blood group and (ii) 'O' blood group (c) Alpine grasslands
only (d) Tropical evergreen forests
MATHEMATICS are 16, 24 and 3 1. The volume of the cuboid lies

between
progression such that a + b + c + d + e is the cube of

6 1 . Let a, b, c, d, e be natural numbers in an arithmetic (a) 7 and 14 (b) 14 and 21
an integer and b + c + d is square of an integer. The

63. Let ABCD be a square and let P be a point on
(c) 2 1 and 28 (d) 28 and 35
least possible value of the number of digits of c is

segment CD such that DP : PC = 1 : 2. Let Q be a point
on segment AP such that LBQP = 90 °. Then, the ratio
(a) 2 (b) 3
of the area of quadrilateral PQBC to the area of the
(c) 4 (d) 5
62. On each face of a cuboid, the sum of its perimeter and square ABCD is
its area is written. Among the six numbers so 1 1
(a) 3 (b) 37 (c) 39 (d) 4
written, there are three distinct numbers and they 60 60 60 60
WWW.JEEBOOKS.INl
64. Suppose the height of a pyramid with a square base Note That irrespective of speed ofP, ball always
is decreased by p% and the lengths of the sides ofits leaves Ps hand with speed 2 ms-1 with respect to the
square base are increased by p% (where, p > 0). If the ground. Ignore gravity. Balls will be received by Q.
volume remains the same, then (a) One every 2.5 s in case (I) and one every 3.3 s in
(a) 50 < p < 55 (b) 55 < p < 60 case (II)
(c) 60 < p < 65 (d) 65 < p < 70 (b) One every 2 s in case (I) and one every 4 s in case (II)
65. There are three kinds of liquids X, Y, Z. Three jars

J1 , J2 , J3 contains 100 ml ofliquids X, Y, Z
(c) One every 3.3 s in case (I) and one every 2.5 s in
case (II)
(d) One every 2.5 s in case (I) and one every 2.5 s in
respectively. By an operation we mean three steps in case (II)
the following order
68. A 10.0 W electrical heater is used to heat a container
into J ,
- stir the liquid in J1 and transfer 10 ml from J1 filled with 0.5 kg of water.It is found that the
- stir the liquid in J2 and transfer 10 ml from J2

2 temperature of the water and the container rose by
3 K in 15 min. The container is then emptied, dried
into J3 , and filled with 2 kg of an oil. It is now observed that
- stir the liquid in J3 and transfer 10 ml from J3 the same heater raises the temperature of the
into J1 . container-oil system by 2 K in 20 min. Assuming no
After performing the operation four times, let x, y, z other heat losses in any of the processes, the specific
be the amounts ofX, Y, Z respectively, in J1 .Then, heat capacity of the oil is
(a) x > y > z (b) x > z > y (c) y > x > z (d) z > x > y (a) 25 x 10 3 JK- 1 kg-1
(b) 5. l x 10 3 JK- 1 kg-1
PHYSICS
(c) 3.0 x 10 3 JK-1 kg- 1
(d) 15 X 10 3 JK-1 kg-1
69. A ray of light incident on a transparent sphere at an
angle 1t I 4 and refracted at an angle r, emerges from
66. Two identical uniform rectangular blocks (with
longest side L) and a solid sphere of radius R are to
be balanced at the edge of a heavy table such that the the sphere after suffering one internal reflection. The
centre of the sphere remains at the maximum total angle of deviation of the ray is
possible horizontal distance from the vertical edge of (a)
31t
- 4r (b) ..'.: - 4r
the table without toppling as indicated in the figure. 2 2
1t 51t
(c) - - r (d) - - 4r
4 2
70. An electron with an initial speed of4.0 x 106 ms-1 is
brought to rest by an electric field. The mass and
charge of an electron are 9 x 10-31 kg and 1.6 x 10-1 9 C,
respectively. Identify the correct statement.
(a) The electron moves from a region of lower potential
to higher potential through a potential difference of
Table 11.4 µV
(b) The electron moves from a region of higher potential
L R to lower potential through a potential difference of
Ifthe mass ofeach block is M and ofthe sphere is M 12,

X 11.4 µV
(c) The electron moves from a region of lower potential to
then the maximum distance x that can be achieved is higher potential through a potential difference of 45 V
(a) SL / 15 (b) 5L / 6 (d) The electron moves from a region of higher potential to
(c) (3L / 4 + R) (d) (7L / 15 + R)
lower potential through a potential difference of 45 V
67. Two skaters P and Q are skating towards each other.

Skater P throws a ball towards Q every 5 s such that CHEMISTRY
it always leaves her hand with speed 2 ms-1 with 7 1 . The degree of dissociation of acetic acid (0. 1 mol L -1 )
in water (Ka of acetic acid is 10-5 ) is
respect to the ground. Consider two cases:
(I) P runs with speed 1 ms-1 towards Q, while Q
remains stationary. (a) o. o i (b) 0.5
(II) Q runs with speed 1 ms-1 towards P, while P

(c) 0.1 (d) 1.0
remains stationary.
WWW.JEEBOOKS.INl
72. Compound X on heating with Zn dust gives 77. A diabetic individual becomes unconscious after
compound Y which on treatment with 0 3 followed by self-administering insulin. What should be done
reaction with Zn dust gives propionaldehyde. The immediately to revive the individual?
structure of X is (a) Provide him sugar
Br Br (b) Give him higher dose of insulin
(c) Provide him salt solution
(a) (b)
(d) Provide him lots of water
Br Br 78. A regular check on the unborn baby of a lady towards
Br Br the end of her pregnancy showed a heart rate of 80
�
(c) (d ) � beats per minute. What would the doctor infer about
the baby's heart condition from this?
Br Br (a) Normal heart rate
(b) Faster heart rate
73. The amount of metallic Zn (atomic weight = 65.4)
required to react with aqueous sodium hydroxide to (c) Slower heart rate
produce 1 g of H2 , is (d) Defective brain function
(a) 32.7 g (b) 98.1 g (c) 65.4 g (d) 16.3 g 79. Three uniformly watered plants i, ii and iii were kept
74. Natural abundances of 12 C and 1 3C isotopes of carbon in 45% relative humidity, 45% relative humidity with
are 99% and 1 %, respectively. Assuming they only blowing wind and 95% relative humidity,
contribute to the mol. wt. of C2 F4, the percentage of respectively. Arrange, these plants in the order
C2 F4 having a molecular mass of 101 is (fastest to slowest) in which they will dry up.
(a) 1.98 (b) 98 (c) 0.198 (d) 99 (a) i ➔ ii ➔ iii (b) ii ➔ i ➔ iii
75. 2,3-dimethylbut-2-ene when reacted with bromine (c) iii ➔ ii ➔ i (d) iii ➔ i ➔ ii
>----<
forms a compound which upon heating with alcoholic 80. Many populations colonising a new habitat show a
>r----i<
KOH produces the following major product. logistic population growth pattern over time, as
shown in the figure below
(a) (b)
Br OH
>r----i<
OH "cii
�
C
� _,,,,,--- OH 0
(c) (d ) � =i
Cl.
0
OH OH 0...
BIOLOGY
Time
In such a population, the population growth rate

76. Sister chromatids of a chromosome have
(a) stays constant over time
(a) different genes at the same locus
(b) increases and then reaches a asymptote
(b) different alleles of the same gene at the same locus
(c) decreases over time
(c) same alleles of the same gene at the same locus
(d) increases to a maximum and then decreases
(d) same alleles at different loci
Answers
PART-/
(c) 2 (c) 3 (c) 4 (b) 5 (c) 6 (a) 7 (c) 8 (c) 9 (c) 10 (d)
11 (b) 12 (c) 13 (a) 14 (b) 15 (b) 16 (a) 17 (b) 18 (a) 19 (d) 20 (c)
21 (b) 22 (d) 23 (b) 24 (a) 25 (c) 26 (c) 27 (a) 28 (b) 29 (a) 30 (c)
31 (b) 32 (c) 33 (a) 34 (b) 35 (c) 36 (d) 37 (d) 38 (b) 39 (b) 40 (d)
41 (b) 42 (b) 43 (a) 44 (b) 45 (c) 46 (a) 47 (a) 48 (b) 49 (a) 50 (b)
51 (a) 52 (b) 53 (b) 54 (c) 55 (d) 56 (a) 57 (b) 58 (c) 59 (c) 60 (d)
PART-I/
61 (b) 62 (d) 63 (d) 64 (c) 65 (b) 66 (a) 67 (a) 68 (a) 69 (a) 70 (d)
71 (a) 72 (c) 73 (a) 74 (a) 75 (b) 76 (c) 77 (a) 78 (c) 79 (b) 80 (d)
M/WW.JEEBOOKS.IN]
Solutions
1 . (c) We have, x + y + z = 10 4. (b) We have, In l'J'RM,
Let three number x + 1, y + 1, z + 1 RM2 = PR2 - PM2 = 25 - 9 = 16
2
⇒ ax + (a + b)x + b = 0
AM � GM ⇒ ax2 + ax + bx + b = 0 RM = 4
⇒ (ax + b) (x + 1) = 0 PM = �
(x + 1) + (y + 1) + (z + 1) > In l'J'RM, tan0 = . . . (i)
- b RM 4
3 ⇒ x = - -, - 1 OP r
a In l'J'OR, tan0 = - = - . . . (ii)
[(x + 1) (y + 1) (z + 1)]113 PR 5
It has at least one negative root, i.e. - 1
x+ y + z+ 3>
- = - ⇒r =-
⇒ So, it has both roots are real. From Eqs. (i) and (ii), we get
3 3 r 15
:. Option (b) is correct.
5. (c) Given,
(xyz + xy + yz + xz + x + y + z + 1)113 4 5 4
3 8. (c) Given, ABCis an acute angle
⇒ (1 J � xyz + xy + yz + xz + 1 1 ⇒ � + l_ + =. = 7 ⇒ 1- + =. + � = 9
y Z X X y Z
3 triangle.
Now, x, y , z are integer.
LB = 45°
We know that,
A
:. xyz + xy + yz + xz + l lis also integer. a3 + b3 + c3 - 3abc = (a + b + c)
3 (a2 + b2 + c2 - ab - be - ca)
:. ( 1 is also integer. 3 3 3
3J :. a + b + c - 3abc
= [(a + b + c)2 - 3(ab + be + ca))]
3
r-
= 81 ·.- = 8137
[( 13 J ] [ ( 1: J ] ⇒ +( +( - 3= + +
l
(f J iJ �J (f ; � )
:. xyz + xy + yz + xz + l l '.,'.; 81
⇒ xyz + xy + yz + xz '.,'.; 70 + + 3 + +
[( ; ; � (� � ;J
:. Maximum value of xyz + xy + yz + xz is
69. y3
i_3 + + z3 - 3 = (7) [72 - 3 X 9] A1
2. (c) Given, 2013 + a2 = b2 y z3 i3 LADC = 90°
= 7 (49 - 27) = 7 x 22 = 154
6. (a) In MBC, LA < LB < LC

⇒ b2 - a 2 = 2013 [·: AD is altitude]
LBAD = 45° = LBAA'
⇒ (b - a) (b + a) = 3 x 1 1 x 61
Similarly, LBCC1 = 45°
ab is minimum. LBAA1 = LBB1A1
When b - a = 33 and b + a = 61 [·: angle on same segment are equal]
On solving, we get a = 14 and b = 47 LBCCi = LBBi C1
In MED,
:. Minimum value of ab = 14 x 47 = 658 [·: angle on same segment are equal]
LD > LC
3. (c) We have sides of triangle are, LA1SiC1 = LBBiA1 + LBB1Ci
So, MBD not similar to MBC.
7. (c) Given,
= 45° + 45° = 90°
9. (c) Given, ABCD is rectangle.

b + 5, 3b - 2, 6 - b
Triangle are isosceles.
PR and QR are tangents. AB = CD, BC = AD
:. Two sides are equal.
Case I b + 5 = 3b - 2 2x
b = '!_
2
. 17 17 5
So, sides are - , - , -. 2y
2 2 2
Case II 3b - 2 = 6 - b ⇒ b = 2
:. Sides are 7, 4, 4
Case III b + 5 = 6 - b ⇒ b = I_
2 PQ = 6
11 1 11 PR = 5
1 es are - , - - , - wh'1ch 1s
S.d . not
2 2 2
2
possible. PM = I_PQ
F
:. Only for two values of b, triangles are
PM = I_ x 6= 3 X and Y are mid-point of AD and CD
isosceles. 2
reWWW.JEEBQQKS.IN]
Let AB= 2x , BC= 2y x AQ x AP x sin 30° 1 3. (a) Given, n! + 10

:.AX = XD = y . Area of /J.PAQ _ i
· · Area of/J.RS - Put n = 1, 2, 4, 5
P _!_ x RS x PS x sin 30°
DY = YC=x 2 n ! + 10 is not a perfect square.
Area of rectangle ABCD = 4xy= 60 x Put n = 3, 3! + 10 = 6 + 10 = 1 6 is a perfect
= -J2 -J2 = 2 square.
If
⇒ xy=15
[·: AQ = AP = ,./2, RS = PS = �
1
In MBX and /'JJEX, n>5
n ! is multiple of 10.
n ! = lOk
MBX "" /'JJEX 1 1 . (b) Given,
X complete one round in 40 s.
n ! + 10 = 10k + 10 = lO(k + 1)
DE=AB = 2x
(when, k is even)
Similarly, /J.CBY "" /'JJFY 21t = 40 s
= 10 (2m + 1)
:. FD = BC=2y
= 2 X 5 (2m + 1)
:. Area of /J.BEF
= Area of /J.EFX + Area of /J. BFX
:. Product of odd and even is not a perfect
=�FX - DE+ � FX - AB square.
2 2
= - X 3yx 2x+
1 1 1 4. (b) We have 10 points lie a plane
-x 3yx 2x such that no three of them are collinear.
2 2
= 6xy 2 3
4
= 6x 15= 90 [·:xy=1 5]
1 0. (d) Given,
In one second, he complete, ( !� ) round
2 15
In 15 s, he complete ( 1t � ) round
6
A B
4
10
Let Y complete one round in t s 9
2 1t = t
t)
According to question only 5 ways are
F C 2 possible i.e. 1- 6, 2- 7, 3- 8, 4- 9 and 5- 10.
In one second Y complete ( round
t)
1 5. (b) Let total number of people whose
2 salary less than � 10000 per annum = x
In 15 s, Y complete ( x 15 round
E D and annual salary of each person = a
ABCDEF is a regular hexagon of side Since, both are move in opposite direction. :. Total salary = ax
X 15 + X 15 = 2 1t
length 1. 2 1t 21t and total number of people whose salary
40 t
( _I_
ABQR and AFPS is a square of each side more than � 10000 per annum = y
length also 1. ⇒ 15 + �) = 1 and annual salary of each person = b
40 t
-1 = -
1 -
-
ADCDEF is a regular hexagon :. Total salary = bx
1
LFAB = 120° ⇒
t 15 40 When 5% increase of salary of people x
105ax-
AB = BQ = 1
In square ABQR, 1 8- 3 1.e. x(a + 5% of a) = -
⇒ 100
120
5 1 and 5% decrease of salary of people y
i.e. y (b - 5% of b) =
AQ is a diagonal of square
= .jAB + BQ = -J2
120 24 95by
2 2
AQ
t = 24 s
=> LBAS = LFAB - LFAS
100
1 2. (c) We have,
105ax 95by
+
Average salary after
= 120° - 90° = 30° ,Jn+l - � < 0.2, nE N = 1 00 J OO
=> LSAR = LBAR - LBAS
( ax -
Average salary before ax + by
⇒ ,Jn+1 < 0.2 + �
= 90° - 30° = 60° 5 by
=> LASR = 60°
On squaring both side, we get = 1+ )
100 ax + by
n + 1< 0.04 + n - 1 + 0.4 �
ax - by < 0
=> LRSP = LASP - LASR
[·: /J.ARS is an equilateral triangle] ⇒ n + 1 - n + 1 - 0.04 < o.�
:. Average salary after be decreases.
⇒ -2 - 0.04
- < -vr;;--=-,
n - _,_1
= 90° - 60° = 30° 0.4 1 6. (a) As centre of mass is subjected to
=> LFAB = LFAP + LPAQ + LQAB ⇒ 49< � a downward external force only, so its
⇒ n - 1 > (49) 2 motion is along the direction of external
⇒ 120° = 45° + LPAQ + 45° force, i.e. downwards. Any internal force
[·: LFAP = LQAB = 45° ⇒ n > 1 + 2 401
does not change position of centre of
FA = FP and AB = BQ] ⇒ n > 25.01
mass.
:. LPAQ = 30° :. Minimum value of n = 26
WWW.JEEBOOKS.INl
1 7. (b) When ball is released, vertical As both g and M are constants. 23. (b) Rear view mirror is a convex
component of ball's velocity first :.dv is constant and its value does not mirror.
increases in negative direction changes with time t. Here, u = - lO m
The mutual separation ds of the stones is f = � = + (\
(downwards), then on collision with floor,
its velocity is reversed (upwards).
5
)m
i i
dS = Si - &i
As acceleration remains constant, so lines
are parallel to each other as given in = - gt 2 - (- g (t - M )2 ) Now, from mirror equation,
1 1 1 1 1 1 2 1
v u f f u L5 �l�
option (b). - + - = - or - = - - - = - - - -
1 8. (a) Pressure of a fluid column = � g ((t - M )2 - t 2) V
2 4 1 43 30 m
depends only on height of fluid column = - + - = - or v = -
and as pressure is scalar, its magnitude = � g (t 2 + M 2 - 2tM - t 2) 3 10 30 43
2 Now, magnification,
does not depend on orientation of surface
over which pressure acts. = � g (- 2tM + M 2)
2
m=
-v =
(!�)
= 0.069 or m = 0.07
u
1 9. (d) We have following observations
from position x versus time t graph. ⇒ ds = � g (M 2 - 2tM) - 10
24. (a) first we distribute current in
2
Velocity or slope
is again negative
Clearly, ds decreases with time and
X
becomes zero when 2t = dt. circuit given as
Slope or velocity 21 . (b) Refractive index of a material is
is negative inversely proportional to wavelength of
x
decreases
I _____ Slope or velocity
is positive
light.
Slope or velocity changes

from negative to positive Now, A-yellow > A-green > AbJue
1
⇒ µ yellow < µgreen < µ blue 12+!3
From above graph we can draw following or µ3 < µ 1 < µ 2 Current distribution must follows
velocity v versus time t graph.
22. (d) As focal length oflens is 20 cm, Kirchhoffs junction rule.
V
point of Now, from closed loops marked 1, 2, 3
Slope or acceleration and 4, we have following set of equations
is positive Slope or by application of Kirchhoff's loop rule,
acceleration 11 = 12 + 13 . . . (i)
13 = 12 + 14 . . . (ii)
14 = 12 - 14 + 15
⇒ 214 = 12 + 15 . . . (iii)
convergence of a parallel beam of light is 15 = 2 (12 - 14 - 15 )
So, acceleration of given particle is also 20 cm.
⇒ 15 = 212 - 214 - 215 . . . (iv)
initially positive but with time it becomes Now, given PM = 10cm
315 = 212 - 214 . . . (v)
negative.
Hence, a = p - qt is best suited option.
So, PI' = PM + MI = 20 cm
From Eqs. (iii) and (v), we have
20. (c) Let first stone mass mi is dropped
or MI = 20 - 10 = 10 cm
315 = 212 - (12 + 15 )
at instant t= 0.
As, PI = 10cm
⇒ 415 = 12 . . . (vi)
.-. d?MI is an equilateral triangle of side
From Eqs. (iii) and (vi), we have
Then at time t, its velocity and 10 cm. 5
displacement respectively, are Now, if MN is normal to mirror, as angle 214 = 415 + 15 ⇒ 14 = -1 . . . (vii)
2 5
Vi = - gt and Si = - -1 gt 2 of incidence and reflection are equal, we
From Eqs. (ii), (vi) and (vii), we have
2 have following situation
As, second stone mass "½ is dropped M 13 = 415 + _15_/5 = 13 15 . . . (viii)
2 2
at instant t respectively, are
time after, so its velocity and displacement
Now, marked currents I and I' in the
given circuit are
V2 = - g(t - M )
and s2 = - � (g) (t - M)2 I' = (12 - 14 - 15 ) = ( 415 - � /5 - 15 )
2
-2 J =�
Difference in speeds of stones is From above figure, we have = (8 -: ) 5 . . . (ix)
I = 12 = 4/5
dV = v1 - v2
a + 30° = 90° ⇒a = 60°
= (- gt) - (- g (t - M )) And
= - gt + gt - gM = - gM
Hence, mirror makes an angle of 60° with Hence, ratio of I I I' = (415 ) / (/5 / 2) = 8.
the horizontal.
WWW.JEEBOOKS.INl
25. (c) An emf is induced in the coil _

-
4 X 22 x 14 X Hf X (15 x 1Q1 1 )2 3 1 . (b) A formyl group is one which
when there is a flux change in the coil or 7 x (3 x 108 ) 2 consists of a carbonyl group attached to a
when field lines are cut by the coil. 1 hydrogen, i.e.,
R - f( - H group.
= 10 kg s-
9
When coil rotates about its axis, there is
So, mass reduction per second is around
no change in flux as no field line is cut by 109 kg.
the coil. The structure of the given organic
= UI
28. (b) Power dissipated by resistor is
P = I2R ⇒
compounds are as follows
: ------0-------- p I
f..P
B
(i) Acetone - CH3- C - CH3
II
p I
So, no emf is generated in coil when it is or
f..P l
x 100 = U. x 100
0
rotated about its axis. In all other cases
an emf is induced in the coil. Per cent change in power dissipation - -
(ii) Acetaldehyde - CH3+- c-=-=-H :
26. (c) Given circuit is : II
= 2 x Per cent change in current :
= 2 X 3% = 6%
I O
L _ _ _ _ _ _ ..
I
A
0.1A 29. (a) Initially let pressure is p, then (iii) Acetic acid - CH30H
+
Finally pressure is p and volume is V .
p V = n.i RT
V
-- 20 Q
(iv) Acetic anhydride-CH3 - C- 0-C-CH3
II II
--
60 Q ) 3 0 0
As acetaldehyde has R -C - H group,

Let number of moles of gas left is n2, then
B
p V = n�T II
20 x 60 = 15 n 3
Re =
q 20+ 60 Dividing both equations, we get Thus, the correct option i s (b).
We can redraw the circuit as n2 n -
= _! or 1 - 2 = 1- _! or n1 n2 = � 32. (c) The structure of cis-3-hexene is
A n1 3 n.i 3 n1 3 2
5
0.1A n1 - n2 x �6
80 Q Hence' 100 = � x 100 = 66%
25 Q n1 3 H H
20 Q or percentage of number of molecules 33. (a) Generally a sp 2-hybridised
15 Q escaped = 66%. carbon atom is one which has a double
30. (c) Using right hand rule, direction
bond.
B 0
Let current through 20 Q resistor is /2, then of magnetic force can be found. It acts II
outward from the plane of paper in given HC= C - CH2- C - CH2- CH =CH2
VAB = 0.1 (25 + 15) = /2 x 20 case. sp sp sp3 sp2 sp3 sp2 sp2
or 12 = 0.l x 40 = 0.2 A
20 j B Thus, the given structure has
So, by Kirchhoffs junction rule, current 3sp2-hybridised carbon atoms.
I = 0.1 + 0.2 = 0.3 A.

through 8 Q resistance is 34. (b) Valence electrons are those
electrons which are present in the
outermost shell of an element.
27. (a) Energy from sun is radiated in a
0 v ,._ In the given electronic configuration,
sphere of radius (r = 15 x l d1 m).
ls22s22p6 3s2 3p3 , 3p is the outermost
-k Fm shell, thus the number of valence
To avoid deflection of electron, electric electrons are 3.
field must be applied normal to the plane 35. (c) Number of neutrons in the pairs
of paper (XOY-plane in diagrams) and given in options are as follows
pointing outward. 1 2 24
(a) 6C , 1 2Mg
y
B No. of neutrons in C = 12 - 6 = 6
No. of neutrons in Mg = 24 - 12 = 12
So, total energy radiated per second from 19
sun 1s (b) 23
1 1 Na , 9 F
f..E = 41tr X 14 X l(r
2
No. of neutrons in Na = 23 - 1 1 = 12
= 4 X 22 X 14 X l(r X (15 X l d 1 ) 2 No. of neutrons in F = 19 - 9 = 10
From E = mc2 , we have Fm

7 23 24
(c) 1 1 Na , 12 Mg
⇒ !J.m = f..E Magnitude of electric field applied is such No. of neutrons in Na = 23 - 1 1 = 12
c that Fm = F,.
2
No. of neutrons in Mg = 24 - 12 = 12
WWW.JEEBOOKS.INl
40. (d) For the reaction, 45. (c) According to Bohr's radius of an
23 39
(d) 1 1 Na , 1 9K
atom
6 (g)
r = 0.529 x - ⇒ r oc -
No. of neutrons in Na = 23 - 11 = 12 3C2 H
2 (g) � C6 H
2
K =
n 1
[C 6 6]
z z
H
No. of neutrons in K = 39 - 19 = 20 ⇒4= �
3
Thus, option (c) is correct. c [C2 H
2J [C2 i H
36. (d) A molecule which has a

where, Z is the atomic number.
0.5
[C2 2f =
H = _l_ Thus, more is the atomic number lesser
symmetrical geometry will have no dipole 4 8 will the Bohr's radius. Therefore, the
moment, as the magnitude of all the bond 1 correct order is
[C2H
2]
= - = 0.5 mol/L
moments cancel each other. 2 > rHe+ > ru 2 +
46. (a) In Bowman's capsule
rH
41 . (b) Given,
The structure of compounds given in
options are as follows ultrafiltration of blood occurs. Bowman's
3.42
Cl H Weight of sucrose = = 0.0342 g capsule is a cup-like sack at the
C
It C
It 100 beginning of the tubular component of a
Molar mass of sucrose = 342 g nephron in the mammalian kidney that
-?
H ll �H c1�tl �c1 Mass of solution = 100 g performs the first step in the filtration of
H Cl
CH3CI CHCl3 Density of solution = 1 g m:C-1 blood to form urine. Fluids from blood in
(µ = 0) (µ = 0) 0.0342 the glomerular are collected in the
No. of moles of sucrose =
342 Bowman's capsule (i.e. glomerular
Cl filtrate) and further processed along the
Mass
l1 .
Also, density = - - - nephron to form urine. This process is
Volume
known as ultrafiltration.
47. (a) Parietal lobe is sensory lobe for
ci�a�CI Volume =
lOO
= 100 mL
CCl4
Cl 1
Symmetrical molecule, µ =0
touch, pain and temperature. The
Concentration of solution is calculated in
cerebral cortex is divided into four
terms of molarity
Thus, CC14 has no dipole moment. sections, called 'lobes'. Out of these, the
Mo1an•ty = - - - - - - -
37. (d) As the species are radioactive, so
No. of moles of sucrose
parietal lobe is associated with
Vol. of solution in litres
movement, orientation, recognition and
they follow 1st order kinetics. 0.0342 0.0342
= = x 1000= 0.l mol/L perception of stimuli. Thus, the parietal
For 1st order c = C e-kt t o
100 100
k oc _l_
lobe functions in registration of sensory
1000
42. (b) The reactivity of K, Mg, Au and
perception of touch, pain, heat and cold,
t knowledge about position in space, taking
From the graph it can be concluded that Zn with water can be determined by the in information from environment,
while species C takes least time. Thus,

species A takes maximum time to decay reactivity series of metals. organising it and communicating to rest
of brain.
48. (b) Virus cannot be cultured in an
According to reactivity series, the
decay constant follows the order decreasing order of reactivity will be
kc > kB > kA- K>Mg>Zn>Au artificial medium. It multiples only in
38. (b) The ratio of rate of diffusion of 43. (a) An anhydride is a compound that
living cells. Viruses are obligate
0 2 and H 2 can be given as
intracellular parasites.
two gases, has two acyl groups bonded to same
ro 2
=
✓M H2
oxygen atom, i.e. They lack metabolic machinery to
generate energy or to synthesise proteins,
R-C-0-C-R
II II
rH 2 Mo 2 instead they rely on their host cells to
= =
lf.
carry out these functions.
49. (a) Meiosis-I Reduction division
0 0
�:: 1 This type of structure is given in option (a). (2n ➔ n), separation of homologous
ro 2 : rH 2 = 1: 4 I O o: chromosomes results in reduction of
Also, rate of diffusion chromosome ploidy to half.
J,)l_o�
CH3 - - - - - - - - CH3 Meiosis-II Similar to mitosis where
= Volume of diffused gas
sister chromatids separate.
r0 2 - 50. (b) Melanin pigment synthesised
Time of diffused gas 2- acyl groups
tH attached to O-atoms
1 24
- = 2 = - = - = 96 s from tyrosine amino acid, imparts colour
Thus, option (a) is correct.
44. (b) More reactive metal than Cu can
rH 2 to 2 4 to 2
to skin. People suffering from albinism
39. (b) Whenever an acid reacts with a precipitate copper from copper sulphate
cannot synthesise melanin. Albinism is a
metal, hydrogen gas is evolved. So, when disease, in which a person has partial or
solution. The increasing order of
acetic acid reacts with a sodium metal, complete loss of pigmentation (colouring)
reactivity of given element is
of the skin, eyes and hair. There is a cell
hydrogen gas is produced. Au < H g < Cu < Sn called the melanocyte that is responsible
As Sn is more reactive than Cu, so it
would precipitate Cu from CuS04 •
for giving eyes, skin and hair
pigmentation.
WWW.JEEBOOKS.INl
In albinism, there occurs genetic 57. (b) In the digestive system, the pH of 62. (d) Let the length, breadth and
mutation in melanocytes which interfere height of cuboid be x, y and z respectively.
:. Perimeter of face PQRS = 2(x + y)
stomach and intestine are acidic and
5 1 . (a) Short-sightedness (myopia) is

with their pigment. alkaline, respectively. The pH of stomach
is 1.5-2.5 (i.e. acidic) and the pH of
S�- R
-�·
58. (c) The major nitrogenous excretory
corrected by using concave lens. These intestine is 7.4-7.6 (i.e. alkaline). - -
lens work by bending the light rays y p-'>-- --+-___,, Q
slightly outwards, so that they can focus product in mammals is urea. Nitrogenous x-
further back on the retina. wastes in the body of animals tend to z
Myopia is an eye defect in which the form toxic NH 3 , which must be excreted. o's--- -+- - -�c"
eyeball grows slightly too long. This NH 3 is converted to urea in hepatocytes y
A;<-- -
x- -� a
59. (c) Thin epidermis without a cuticle
of the body.
Area of PQRS = xy
means that light does not focus on the
2 (x + y) + xy = 16
light sensitive tissue (retina) at the back
of the eye properly. Instead, the light rays on stem and leaves is not an adaptation
Similarly, for face APSD,

. . . (i)
focus just in front of the retina, resulting to dry habitat. This is because the cuticle
2(y + z) + yz = 24
in distant objects appearing blurred. is a waxy layer on the epidermis which
52. (b) A person with blood group 'O' is a
and for face APQB,
prevents the entire leaf from losing water . . . (ii)
2(x + z) + xz = 3 1
universal donor, whereas person with from the surface. Thus, thick cuticle
60. (d) Diversity of species is highest in

blood group 'AB' is a universal recipient. prevents water loss. . . . (iii)
(x - y) (2 + z) = 7
Blood group 'O' do not have any antigen From Eqs. (ii) and (iii), w e get
on their REC whereas blood group 'AB' the tropical evergreen forests primarily
. . . (iv)
do not have any antibody in their blood because there are fewer ecological
4x = 2 + 5y
obstacles for biodiversity. Like the From Eqs. (ii) and (iv), we get
plasma, but both the antigens A and B on
their REC. climate is wet and warm, plants and . . . (v)
x = 3, y = 2, z = 5
Therefore, a person with blood group 'A' animals have the greatest access to On solving Eqs. (i) and (v), we get
consistent energy, water and carbon, etc.
:. Volume of cuboid = xyz = 3 x 2 x 5 = 30
can donate blood to a person with blood
group 'A' or 'AB' and can receive blood This reduces the selection for traits that
from a person with blood group 'A' or 'O'. emphasise the ability to withstand
53. (b) Mitochondria are structures

Hence, option (d) is correct.
63. (d) Given, ABCD is a square.
environmental stresses such as cold and
drought, etc., and promotes higher rates
within cells that convert the energy from
of speciation. _ �c
61 . (b) We have,
o�_ x_ ----.-P_ _ 2x
food into a form that cells can use.
a, b, c, d, e are natural number and in AP.

Although most DNA is packaged in
chromosomes within the nucleus,
mitochondria also have a small amount of Let D is common difference of AP. Q
their own DNA. This genetic material is c=C 3x
a = C - 2D
:. Let 3x
known as mitochondrial DNA or
mtDNA. Thus, after the removal of
nuclei, the cell still have mtDNA. b=C-D
54. (c) The correct combination present d =C+ D
e = C + 2D
A �- - - - - - a
�
AB = BC = CD = AD = 3x
3x
a + b + c + d + e = 5C
in DNA is guanine and cytosine. The
DNA consists of four types of nitrogen
PD : PC = 1: 2
Let
b + c + d = 3C
bases, i.e. adenine (A), thymine (T),
Given, a + b + c + d + e is a cube of PD = x
guanine (G) and cytosine (C). Whereas and
PC = 2x
guanidine is a strong base that found in
In /'JJAP and !J.QBA,

urine as a normal product of protein number
55. (d) Conjugation is the transfer of

metabolism and not present in DNA. 5C = A3
and b + c + d is a square of number LDAP = LQBA
. . . (i)
3C = u LD = LQ = 90°
genetic material between bacterial cells 2
/'JJAP - !J.QBA
• • • (ii)
by direct cell to cell contact or by a
DA AP DP
bridge-like connection between two cells From Eqs. (i) and (ii), we get
2
')..,,3
QB BA QB
(e.g. bacteria). Thus, conjugation is a u - - - - -
process of genetic recombination not 5 3
⇒ � = -JTij X �
56. (a) Insects (class-Insecta or =
asexual reproduction.
')..,,3 and u 2 is a multiple of 15.
QB 3x QA
u = 45
:. Smallest possible value of ')..,, = 15 and
[·: AP = .J9x2 + x2 = M x]
Hexapoda) are the animals constituting
the largest biomass on the earth. In the
2
x ⇒ QA = ----,=
u2
.Jw ...no
(45)
QB = - x
world, about 900 thousand different c=-= - - = 675 9 3
kinds of living insects are known. This 3 3
represents approximately 80% of the :. Number of digits = 3
world's animal species.
WWW.JEEBOOKS.INl
Area of quadrilateral BQPC = area of 3x _

square ABCD - (area of MPD + area of
65.(b) We have, three kind of liquids ⇒ !:_ - !:. - !:. = o
x, y, z and three jars J1 , J2 , J3 contains
+ x
2 2 3 2
MBQ) 100 ml of liquids X, Y, Z respectively. ⇒
5x 4L
---
= (3x) - ( I x 3x x x + I. x� xx-3 When 10 ml of J1 transfer to J2 2 3
:. J1 = 90 ml ofX, J2 = lO0 ml ofY and
2
- x)
2 2 J
- io -f[o SL
⇒ X= -
123x 2
lO ml ofX. 15
= 9x2 - (� x2 + 27 x2 ) =
2 20 20 When 10 ml of J2 transfer to J3 67. (a) Case I P runs towards Q, while Q
100
J2 = - 1000- ofY and - of X, J3 = 100 ml
Area of quadrilateral PQBC _ 20
123x2 is stationary.
11 11
Area of square ABCD
- 100 10 Po--
----------eQ
� of Z1 , - ofY and - ofX
11 11 First ball is received at time ti = � .
41
When 1 0 ml of J3 transfer to J1 2
- ofY1 ,- of X and
60
1 100 1 100 1 10 :. Next ball is received at time t2
64. (c) Let the side of square base of J3 = - - of Z1 , -
pyramid is x m and height of pyramid is
11 11 11 = x- 5 + 5= � + �
1
2
100 2 2 2
y m. J1 = 90 + 10 x ( - - ) of X1 , - ofY and 5 s = 2.5 s
11 121 So, M = t2 - ti = -
2
Case II Q runs towards P, while P is
lOO of Z
11
stationary.
amount of X, Y, Z in J1 .
Similarly, we can find four operation of
We get x > z > y.

p
First ball is received at time ti = �-

66. (a) For system to be in equilibrium 3
without toppling, following conditions :. Next ball is received at time t2
must be fulfilled. x-5
=- -+5
(i) Centre of mass C1 of sphere and upper 3
= -X + -
block must lie inside the edge of lower 10
block. 3 3
10
So, M = t2 - t1 = - s = 3.3 s
3
68. (a) Energy supplied by heater = Heat
Volume of pyramid
= _! area of base x height = _! x2y
3 3 absorbed by water + Heat absorbed by oil
When x is increased by po/o, So, with water in container,
PM = rr1ws,,/1T + m0 s/1T
⇒ lO x 15 x 60 = 0.5 x 4200 x 3 + m0 s0 x 3
then new length= x + p% of
m0 s0 = 900J K-1
x = ( lOO + P ) x
100 Taking origin of axes choosen at C, we ⇒
When y is decreased by po/o, have Now with oil in container,
then new height � X y = M ( i - y) P!it = m0 s0 !1T + mcsc!iT
= Y - p% of Y = ( 100 - P ) Y ⇒ 10 X 20 X 60 = 2 X S X 2 + 900 X 2
y
⇒ s0 =
L L
0
100 ⇒ - + y = - or y = - 10200
= 25 X lo'3 J K-1 kg-1
2 2 3 4
Now, volume is same.
69. (a) According to condition given in
2 (ii) Centre of mass of both of block and
-
:. __! x2y = I_ ( 100 + p x) ( 100 p ) Y sphere must lie inside the edge of table.
question, ray diagram of sphere is
3 3 100 100
⇒
100 +
1= (
p) 2
100 -
( 100
p) I
� - - - -=--<""', I
100 I
I
,----�- �=;:::;;::��---:�:: R ::
I
⇒ (100)2 (100) = (10000 + 200p + p2)
(100 - p)
⇒ p 2 + lO0p - 1002 = 0 I I
X -----+I :
⇒ p 2 + lO0p + (50)2 = (100)2 + (50)2
⇒ (p + 50)2 = 12500
⇒ p + 50 = ✓12500 = 1 1 180 So, again taking centre of mass C2 as
⇒ p = 1 1 180 - 50 origin,
So, deviations are
p = 6180
3
⇒ � (x - � ) + M (x - ½ - � ) = o
Oi_ = �-r
60 < p < 65 4
WWW.JEEBOOKS.INl
02 = 1t - 2r 73. (a) revive the individual we need to provide

1t
o3 = - - r Zn + 2NaOH(aq) -----t Na�nO4 + H2 t him sugar, so that the blood sugar level
4 1 mole of H2 is produced by 1 mole of Zn, becomes normal.
78. (c) A normal Foetal Heart Rate

o = 01 + o2 + o3 = -
Total deviation of light ray is i.e. 2 g of H2 is produced by 65.4 g of Zn
31t 65.4 (FHR) usually ranges from 120-160 beats
- 4r :. 1 g of H2 is produced by = g = 32.7 g
74. (a) In molecular formula of C2F4

2 2 per minute. It is measurable
70. (d) From, qV = I mv2

sonographically. Therefore in this case,
there are 4 F atoms. F has atomic mass of where the foetal heart rate is 80 beats
2
19, so 4 F would have atomic mass of per minute is a slower heart rate (foetal
where, V is stopping potential. 76 g. So, possible molar mass of C�4 are bradycardia).
V=-
mv2 79. (b) The plants in the order (fastest to
100 (76 + 12 + 12), 102 (76 + 13 + 13) or
101 (76 + 12 + 13).
2q slowest) in which they will dry up is
Now according to % abundance
31 6 2 ii ➔ i ➔ iii.
_ 9 x 10- x (4 x 10 ) % of C2F4 of molar mass 100 (when both
- 12 Relative humidity is the amount of water
2 x 16 x 10-19 the C are C)
vapour present in air expressed as a
1 1
= 45 V = -- x -- x 100= 0.01% percentage of the amount needed for
100 100 saturation at the same temperature. As
So, electron must move across a potential % of C2F4 of molar mass 102 (when both plants transpire, the humidity around
difference of 45 V from higher to lower the C are 13 C) saturates leaves with water vapour.
potential.
7 1 . (a) Given,
99 99 0 When relative humidity levels are too
= - X - X 100= 98.011/o
Concentration of acetic acid, C = O.lM

100 100 high or there is a lack of air circulation, a
% of C2F4 of molar mass 101 plant cannot make water evaporate by
transpiration or draw nutrients from the
75. (b) 2,3 dimethylbut-2-ene when
= 100 - (98.01+ 0.01) = 198%
K of acetic acid = 10-5
a soil. Therefore 95% relative humidity will
According to Ostwald dilution law, reacts with bromine forms 2,3 dibromo dry up the slowest, and the 45% relative
Ka = a 2 C 2,3 dimethyl butane which upon heating humidity with blowing wind will dry up
10-5 = a 2 X 0.1 with alcoholic KOH produces 2,3 the fastest.
80. (d) The population growth pattern
>=<
10-5 dimethylbut-1,3-diene as a major
- -- -a2
- 10-5 X 10- product. The reaction can be written as
0.1 shown here is S-shaped (Sigmoidal
2 Br Br
a = 10-4 curve). It is a population growth curve
>---<
a = l0-2 BriCCl4 that shows an initial rapid growth
72. (c) Skeletal diagram of given

�
(exponential growth) and then it slows
2, 3 dimethyl 2, 3 dibromo 2, 3 dimethyl butane down (decreases) as the carrying capacity
information can be drawn but-2-ene is reached. Carrying capacity is the
OsfZn, H20 ale. KOH
maximum number of individuals in a
X� 2CH3 CH2CHO
y
Propionaldehyde population that the environment can
2, 3 dimethylbut-1 , 3-diene
support.
76. (c) Sister chromatids contain the
On retro synthesis.
same allele of the same gene at the same Carrying capacity

Zn, H2O
Ozonolysis loci whereas non-sister chromatids
o�o
,, I -----------/ --
r
contain different alleles of the same gene
in the same loci. ;�;:ih rate
Ozonide Sister chromatids are the two chromatids I decreasing
Ozonolysis 03 of a replicated chromosome, which are "cii
connected by the centromere. They are
r
C
0
identical to each other since they are
� (Y) produced by DNA replication. � Growth rate
77. (a) Insulin lowers blood sugar level

Br a Zn dust � increasing
�
and in this case, brain is getting
inadequate sugar/glucose. Therefore, the Time -
Br (X) person becomes unconscious. In order to
WWW.JEEBOOKS.INl
KVPY
Stream :SA
MM : 1 00
Instructions
MATHEMATICS 22 + 42 + 62 + . . . + (2n)
2
1 . Let f(x) be a quadratic polynomial with f(2) = 10 and 1 + 3 + 5 + . . . + (2n - 1)

5. For to exceed 1.01, the
maximum value of n is
2 2 2 2
f(- 2) = - 2. Then, the coefficient of x in f(x) is
6. In MBC, let AD, BE and CF be the internal angle

(a) 99 (b) 100 (c) 101 (d) 150
Wl �2 �3 00 4
bisectors with D, E and F on the sides BC, CA and AB

3
(0.75)
respectively. Suppose AD, BE and CF concur at I and

2. The square root of + [0.75 + (0.75)2 + 1] is
1 - (0.75)
Wl �2 �3 00 4 B, D, I, F are concyclic, then LIFD has measure
in an arithmetic progression. If the smallest side is

3. The sides of a triangle are distinct positive integers (a) 15°
(b) 30°
10, the number of such triangles is (c) 45°
(a) 8 (b) 9 (d) any value '.,'.; 90°
(c) 10 (d) infinitely many
4. If a, b, c, d are positive real numbers such that
7. A regular octagon is formed by cutting congruent
� = a + b = a + b + c = a + b + c+ d a square. If the square has side length 1, the side

isosceles right angled triangles from the corners of a
then length of the octagon is
3 4 5 6 ' b + 2c + 3d
lS (a) -/2 - 1 (b) -/2 - 1
2
(a) � (b) 1
(c) .J5 - (d) .J5 -
1 1
2
(c) 2 (d) not determinable 4 3
WWW.JEEBOOKS.INl
8. A circle is drawn in a sector of a larger circle of hand, working alone, B would need 4 � h more to
radius r, as shown in the figure given below. 2
complete the work than if both worked together. How
much time would they take to complete the job
working together?
(a) 4 h (b) 5 h (c) 6 h (d) 7 h
13. When a bucket is half full, the weight of the bucket
and the water is 10 kg. When the bucket is
two-thirds full, the total weight is 11 kg. What is the
total weight (in kg), when the bucket is completely
full?
The smaller circle is tangent to the two bounding (a) 12 (b) 12_1_ (c) 12-2 (d) 13
radii and the arc of the sector. The radius of the 2 3
small circle is 14. How many ordered pairs of (m, n) integers satisfy
m _ 12 ?
12 n
(a) � (b) �
-
(c) 2/3r
2 3
(d) _!_ (a) 30 (b) 15 (c) 12
15. Let S = {1, 2, 3, ... , 40) and let A be a subset ofS such
5 ,,/2
(d) 10
9. In the figure, AHKF, FKDE and HECK are unit

that no two elements in A have their sum divisible by
squares, AD and BF intersect in X. Then, the ratio of
5. What is the maximum number of elements
the areas of triangles AXF and ABF is
possible in A?
(b) 13 (c) 17 (d) 20
A F E (a) 10
PHYSICS
H >-----,�--+K
- - �o
16. A clay ball of mass m and speed v strikes another
metal ball of same mass m, which is at rest. They
stick together after collision. The kinetic energy of
the system after collision is
1 1 2 2 2
(a) - (c) -
2
(a) mv !2 (b) mv I 4 (c) 2 mv (d) mv
6
10. Suppose Q is a point on the circle with centre P and
4 17. A ball falls vertically downward and bounces off a
horizontal floor. The speed of the ball just before
radius 1, as shown in the figure, R is a point outside reaching the floor (u1 ) is equal to the speed just after
the circle such that QR = 1 and L QRP = 2 °. Let S be leaving contact with the floor (u2 ), Ui = u2 • The
the point where the segment RP intersects the given corresponding magnitudes ofaccelerations are
circle. Then, measure of LRQS equals denoted respectively by a1 and a2 . The air resistance
during motion is proportional to speed and is not
negligible. If g is acceleration due to gravity, then
(a) ll:i_ < � (b) ll:i_ > a2
(c) ll:i_ = a2 "# g (d) ll:i_ = a2 = g
R 18. Which of the following statements is true about the
p
flow of electrons in an electric circuit?
(a) Electrons always flow from lower to higher potential
(b) Electrons always flow from higher to lower potential
(c) Electrons flow from lower to higher potential, except
(a) 86° (b) 87° (c) 88° (d) 89° through power sources
(d) Electrons flow from higher to lower potential, except
11. Observe that, at any instant, the minute and hour
through power sources
19. A boat crossing a river moves with a velocity v
hands of a clock make two angles between them
whose sum is 360°. At 6:15 the difference between
relative to still water. The river is flowing with a
velocity v / 2 with respect to the bank. The angle with
these two angles is
(a) 165° (b) 170° (c) 175° (d) 180°
respect to the flow direction with which the boat
12. Two workers A and B are engaged to do a piece of should move to minimize the drift is
work. Working alone, A takes 8 h more to complete (a) 30° (b) 60° (c) 150° (d) 120°
the work than, if both worked together. On the other
WWW.JEEBOOKS.INl
1 10 KVPY Question Paper 2012 Stream : SA
8
20. In the Arctic region, hemispherical houses called
Igloos are made of ice. It is possible to maintain a
temperature inside an Igloo as high as 20° C because
(a) ice has high thermal conductivity
(b) ice has low thermal conductivity
(c) ice has high specific heat R
(a) P < Q < R < S (b) P < Q < R = S
21. In the figure below, PQRS denotes the path followed
(d) ice has higher density than water
(c)R < Q R > Q > S
by a ray of light as it travels through three media in 25. A circular metallic ring ofradius R has a small gap of
succession. The absolute refractive indices of the width d. The coefficient of thermal expansion of the
media are µ1 , µ 2 and µ3 , respectively. (The line
segment RS in the figure is parallel to PQ).
metal is a in appropriate units. If we increase the
temperature of the ring by an amount t-,.T, then width
p of the gap
(a) will increase by an amount dw1T
(b) will not change
(d) will decrease by an amount dw1T

(c) will increase by an amount (21tR - d) MT
26. A girl holds a book of mass m against a vertical wall

Then, with a horizontal force F using her finger, so that the
(b) µ 1 = µ 3 < µ 2 book does not move. The frictional force on the book
by the wall is
(a) µ 1 > µ 2 > µ 3
(c µ 1 < µ 2 < µ 3 (d) µ 1 < µ 3 < µ 2
e-
(a) F and along the finger but pointing towards the girl
22. A ray of white light is incident on a spherical water (b) µF upwards, where µ is the coefficient of static friction
drop whose centre is C as shown below. (c) mg and upwards
(d) equal and opposite to the resultant of F and mg
27. A solid cube and a solid sphere both made of same
material are completely submerged in water but to
different depths. The sphere and the cube have same
When observed from the opposite side, the emergent surface area. The buoyant force is
light (a) greater for the cube than the sphere
(b) greater for the sphere than the cube
(a) will be white and will emerge without deviating
(c) same for the sphere and the cube
(b) will be internally reflected
28. ��8 U atom disintegrates to 4 Po with a half of

(d) greater for the object that is submerged deeper
(c) will split into different colours such that the angles of
deviation will be different for different colours �!
(d) will split into different colours such that the angles of
4.5 x 109 years by emitting six a-particles and
n electrons. Here, n is
deviation will be the same for all colours
23. A convex lens of focal length 15 cm is placed in front
of a plane mirror at a distance 25 cm from the mirror.
(a) 6 (b) 4 (c) 10 (d) 7
Where on the optical axis and from the centre of the 29. Which statement about the Rutherford model of the
lens should a small object be placed such that the atom is not true?
final image coincides with the object? (a) There is a positively charged centre in an atom called
(a) 15 cm and on the opposite side of the mirror the nucleus
(b) 15 cm between the mirror and the lens (b) Nearly all the mass of an atom resides in the nucleus
(c) 7.5 cm and on the opposite side of the mirror (c) Size of the nucleus is comparable to the atom
(d) 7.5 cm and between the mirror and the lens (d) Electrons occupy the space surrounding the nucleus
24. Following figures show different combinations of 30. A girl brings a positively charged rod near a thin
identical bulb(s) connected to identical battery(ies). neutral stream of water from a tap. She observes that
Which option is correct regarding the total power the water stream bends towards her. Instead, if she
dissipated in the circuit? were to bring a negatively charged rod near to the
0
stream, it will
(a) bend in the same direction
(b) bend in the opposite direction
(c) not bend at all
p (d) bend in the opposite direction above and below the rod
Q
WWW.JEEBOOKS.INl
CHEMISTRY 39. The major product in the following reaction is

Ha C-C-C- H + HBr (excess)
31. The weight of calcium oxide formed by burning 20 g
Br
of calcium in excess oxygen is
(a) 36 g (b) 56 g (c) 28 g (d) 72 g (b) H C- C - CH
I
s I s
NaOH
32. The major products in the reaction Br3 CCHO Br
are Br
H /
A
0 (c) H 3 C- C- CH2 (d) H 3 C-CH2-�H
(a) CHBr3+
I I '\_
Br
\C=CI
ONa Br Br
H
H Br 40. The major product in the following reaction at 25°C
3
CH CH NH 2 2
(b) NaBr + is CH3 COOH
I \ (a) CH3CONHCH2CH3
H Br
A
0 (b) CH3CH = NCH2CH3
(c) NaOBr + (c) NH; cH2CH3 · CH3Coo-
D H (d) CH3CON = CHCH3
Br Br 41. A reaction with reaction quotient Qc and equilibrium
Br, I Br
OH + constant Kc , will proceed in the direction of the
(d) � ONa
Br� Br products when
0 (a) Qc = Kc
(c) Qc > Kc
33. The number of electrons plus neutrons in {gK+ is
42. Acetyl salicylic acid is a pain killer and is commonly
(a) 38 (b) 59 (c) 39 (d) 40 known as
34. Among the following, the most basic oxide is (a) paracetamol (b) aspirin
(a) Al203 (b) Pp5 (c) Si02 (d) Na 20 (c) ibuprofen (d) penicillin
35. By dissolving 0.35 mole of sodium chloride in water, 43. The molecule which does not exhibit strong hydrogen
1.30 L of salt solution is obtained. The molarity of the bonding is
resulting solution should be reported as (a) methyl amine (b) acetic acid
(a) 0.3 M (b) 0.269 M (c) diethyl ether (d) glucose
(c) 0.27 M (d) 0.2692 M 44. The following two compounds are
36. Among the quantities, density (p), temperature (T),
enthalpy (H), heat capacity (Cp), volume (V) and CH3
�
pressure (p), a set of intensive variables are
(a) ( p, T, H) (b) (H, T, V )
H3C
(c) (V , T , CP ) (d) ( p, T , p) (a) geometrical isomers
37. The value of x in KAl(SO4 )x · 12H20 is

(b) positional isomers
(c) functional group isomers
W l �2 �3 00 4 (d) optical isomers
38. Among the following substituted pyridines, the most 45. The graph that does not represent the behaviour of
basic compound is an ideal gas is
C f
Me Me
'\_N/ t constant T p
�) 6
(b) �
0
(a) P p
(a)
N N V 1 /V
6 6
at constant p
CH3 Cl
(c) PV t= (d)
(c) (d)
N N
T - 273°C T
WWW.JEEBOOKS.INl
BIOLOGY 53. Myeloid tissue is a type of

(a) haematopoietic tissue (b) cartilage tissue
46. A smear of blood from a healthy individual is stained (c) muscular tissue (d) areolar tissue
with a nuclear stain called hematoxylin and then 54. The heart of an amphibian is usually
observed under a light microscope. Which of the
(a) two-chambered (b) three-chambered
following cell types would be highest in number?
(c) four-chambered (d) three and half-chambered
(a) Neutrophils (b) Lymphocytes
(c) Eosinophils (d) Monocytes 55. Gigantism and acromegaly are due to defects in the
function of which of the following glands?
47. Which of the following biological phenomena involves
(a) Adrenals (b) Thyroid (c) Pancreas (d) Pituitary
a bacteriophage?
(a) Transformation (b) Conjugation 56. The pH of 10-8 M HCl solution is
(c) Translocation (d) Transduction (a) 8 (b) close to 7 (c) 1 (d) 0
48. In which compartment of a cell does the process of 57. Which one of the following organelles can synthesise
glycolysis take place? some of its own proteins?
(a) Golgi complex (b) Cytoplasm (a) Lysosome (b) Golgi apparatus
(c) Mitochondria (d) Ribosomes (c) Vacuole (d) Mitochondrion
49. Huntington's disease is a disease of the 58. Maltose is a polymer of

(a) nervous system (b) circulatory system (a) one glucose and one fructose molecule
(c) respiratory system (d) excretory system (b) one glucose and one galactose molecule
(c) two glucose molecules
50. A cell will experience the highest level of endosmosis (d) two fructose molecules
when it is kept in
(a) distilled water (b) sugar solution 59. The roots of some higher plants get associated with a
(c) salt solution (d) protein solution fungal partner. The roots provide food to the fungus
while the fungus supplies water to the roots. The
51. When the leaf of the 'touch-me-not' (chui-mui, Mimosa structure so formed is known as
pudica) plant is touched, the leaf droops because (a) lichen (b) Anabaena
(a) a nerve signal passes through the plant (c) mycorrhiza (d) Rhizobium
(b) the temperature of the plant increases
(c) water is lost from the cells at the base of the leaf 60. Prehistoric forms of life are found in fossils. The
(d) the plant dies probability of finding fossils of more complex
organisms
52. If you are seeing mangroves around you, which part (a) increases from lower to upper strata
of India are you visiting? (b) decreases from lower to upper strata
(a) Western Ghats (b) Thar desert (c) remains constant in each stratum
(c) Sunderbans (d) Himalayas (d) uncertain

MATHEMATICS 64. A train leaves Pune at 7:30 am and reaches Mumbai
61 . Let a, b, c be positive
at 1 1:30 am. Another train leaves Mumbai at
. . mtegers
. a./2 + b .
sueh that rn 1s a 9:30 am and reaches Pune at 1:00 pm. Assuming that
bv2 + c the two trains travel at constant speeds, at what time
rational number, then which of the following is do the two trains cross each other?
always an integer? (a) 10:20 am
2a2 + b2 a2 + b2 - c2 a2 + 2b2 a2 + b2 + c2 (b) 11:30 am
(a) --2 2
(b) - - - (c) --
2 2
(d) - - -
2b + c a+ b- c b + 2c a+ b- c (c) 10:26 am
62. The number of solutions (x, y, z) to the system of

(d) data not sufficient
65. In the given figures, which has the shortest path?
such that at least two of x, y, z are integers is
equations x + 2y + 4z = 9, 4yz + 2xz + xy = 13, xyz = 3,
W3 �5 �6 00 4 (a) ;;
( b)
63. In a L1ABC, it is known that AB = AC. Suppose D is a
the mid-point of AC and BD = BC = 2 . Then, the area
of the L1ABC is
(c) (d)
(a) 2 (b) 2./2 (c) ,J7 (d) 2-J7
m e
WWW.JEEBOOKS.INl
KVPY Question Paper 2012 Stream : SA 1 13
PHYSICS
66. In the circuit shown, n-identical resistors R are
connected in parallel (n > 1) and the combination is
connected in series to another resistor R0 . In the
adjoining circuit n resistors of resistance R are all
connected in series alongwith Ro-
R
A clockwise current is induced in the loop when loop
R is pulled towards
WN �E �W
Cl
n�
Ro R R R 00 S
n
Ro 70. 150 g of ice is mixed with 100 g of water at
R
temperature 80°C. The latent heat of ice is 80 cal/g
R and the specific heat of water is 1 cal/g°C. Assuming
E no heat loss to the environment, the amount of ice
which does not melt is
(a) 100 g (b) 0 (c) 150 g (d) 50 g
power dissipated in the n resistors in both circuits is CHEMISTRY

The batteries in both circuits are identical and net
same. The ratio R0 /R is

7 1 . Upon fully dissolving 2.0 g of a metal in sulphuric
(a) l (b) n (c) n 2 (d) l/n acid, 6.8 g of the metal sulphate is formed. The
67. A firecracker is thrown with velocity of 30 ms-1 in a equivalent weight of the metal is
direction which makes an angle of 75° with the (a) 13.6 g (b) 20.0 g (c) 4.0 g (d) 10.0 g
vertical axis. At some point on its trajectory, the 72. Upon mixing equal volumes of aqueous solutions of
firecracker splits into two identical pieces in such a 0.1 M HCl and 0.2 M H2S04, the concentration of H+
way that one piece falls 27 m far from the shooting in the resulting solution is
point. Assuming that all trajectories are contained in
(a) 0.30 mol/L (b) 0.25 mol/L (c) 0. 15 mol/L (d) 0.10 mol/L
the same plane, how far will the other piece fall from
the shooting point? (Take, g = 10 ms-2 and neglect air 73. The products X and Y in the following reaction
6
resistance) sequence are
(a) 63 m or 144 m N02
(b) 72 m or 99 m
(c) 28 m or 72 m (d) 63 m or 11 7 m
68. A block of mass m is sliding down an inclined plane
'"'�", x (i) NaNO:fHCI
y
with constant speed.At a certain instant t0, its height
6
(ii) CuBr, t.
above the ground is h . The coefficient of kinetic
x6
NO
friction between the block and the plane is µ. If the
block reaches the ground at a later instant t g , then
the energy dissipated by friction in the time interval (a) Y:
Xe , 6
(tg - t0 ) is
m Br
(b)
x&
h
Br
0
(b) µmgh I sine Cl Cl
(c) Y:
(c) mgh (d) µmgh I cos0

(a) µmgh
Cl
infinitely long wire carrying a constant current i.

69. A circular loop of wire is in the same plane as an
x
NO Cl
W, and S as shown below. ClCl Cl Cl

Four possible motions of the loop are marked by N, E, Y:
(d)
M/WW.JEEBOOKS.IN]
74. A plot of the kinetic energy (½ mv2) of ejected BIOLOGY
radiation for four alkali metals (M1, M2, M3 , M4) is

electrons as a function of the frequency (v) of incident 76. A baby is born with the normal number and
distribution of rods, but no cones in his eyes. We
shown below. would expect that the baby would be
(a) colourblind (b) nightblind
(c) blind with both eyes (d) blind with one eye
77. In mammals, pleural membranes cover the lungs as
well as insides of the ribcage. The pleural fluid in
between the two membranes
(a) dissolves oxygen for transfer to the alveoli
(b) dissolves CO2 for transfer to the blood
(c) provides partial pressure
v-
The alkali metals M1, M2, M3 and M4 are,

(d) reduces the friction between the ribs and the lungs
78. At which phase of the cell cycle, DNA polymerase
respectively activity is at its highest?
(a) Li, Na, K and Rb (a) Gap 1 (G1) (b) Mitotic (M)
(b) Rb, K, Na and Li (c) Synthetic (S) (d) Gap 2 (GJ
(c) Na, K, Li and Rb
(d) Rb, Li, Na and K 79. Usain Bolt, an olympic runner, at the end of a
100 metre sprint, will have more of which of the
75. The number of moles of Br2 produced when two moles following in his muscles?
of potassium permanganate are treated with excess (a) ATP (b) Pyruvic acid
potassium bromide in aqueous acid medium is (c) Lactic acid (d) Carbon dioxide
(a) 1
80. Desert temperature often varies between 0-50°C. The
(b) 3
DNA polymerase isolated from a camel living in the
(c) 2
desert will be able to synthesise DNA most efficiently at
(d) 4
(a) 0°C (b) 37° C (c) 50° C (d) 25°C
PART-/
Answers
(c) 2 (b) 3 (b) 4 (a) 5 (d) 6 (b) 7 (b) 8 (b) 9 (b) 10 (b)
11 (a) 12 (c) 13 (d) 14 (a) 15 (c) 16 (b) 17 (a) 18 (c) 19 (d) 20 (b)
21 (b) 22 (a) 23 (a) 24 (d) 25 (a) 26 (b) 27 (b) 28 (b) 29 (c) 30 (a)
31 (c) 32 (a) 33 (c) 34 (d) 35 (c) 36 (d) 37 (b) 38 (b) 39 (b) 40 (c)
41 (b) 42 (b) 43 (c) 44 (b) 45 (b, c) 46 (a) 47 (d) 48 (b) 49 (a) 50 (a)
51 (c) 52 (c) 53 (a) 54 (b) 55 (d) 56 (b) 57 (d) 58 (c) 59 (c) 60 (a)
PART-I/
6 1 (d) 62 (b) 63 (c) 64 (c) 65 (d) 66 (a) 67 (d) 68 (c) 69 (b) 70 (d)
7 1 (b) 72 (b) 73 (b) 74 (b) 75 (*) 76 (a) 77 (d) 78 (c) 79 (c) 80 (b)
WWW.JEEBOOKS.INl
Solutions
1 . (c) Let f(x) = ax2 + bx + c 5. (d) We have, ⇒ LFBD + LFID = 1 80°
[·: f (x) is quadratic polynomial] 22 + 42 + 62 + ... + (2n) 2 > 10 1 [·: sum of interior opposite angle of cyclic
2 2 2
1 + 3 + 5 + ... + (2n - 1)
2 quadrilateral is 1 80°]
/ (2) = 4a + 2b + c = 1 0 . . . (i)
Now, LFID = LADC + LICD
[·: f (2) = 1 0] ----'---- -
2
⇒ -L(2n)
----'---- 2 >
-
10 1
[·: sum angle properties]
/ (-2) = 4a - 2b + c = - 2 . . . (ii) L(2n - 1) 1 00
[·: f (-2) = - 2] ⇒ LFID = LBAD + LABD + LICD
4Ln 2 10 1
On subtracting Eq. (ii) from Eq.(i), we get ⇒ >- = � + B+Q
0
L(4n • - 4n + 1) 1 00 2 2
4b = 12 ⇒ b = 3 A + C + 2B
4Ln 2 10 1
:. Coefficient of x in /(x) = b = 3 ⇒ >-
2. (b) Let x = 0.75
4Ln - - 4Ln + Ll
'}
1 00 2
A +B+C+B
_ _ 4-----'(n ) (n + l)('----2n + 1)_
----'-----'�_:....: _-'
_
_
According to the question, ⇒ _ 2
6 101
> 1 80
°
+B
±_ + (x + x2 + 1) ·ln (n + 1) ( 211 + 1) -1n -( n +- l) + n 1 00
1- X 2 2
6
2 4n(n + 1)(2n + 1) 10 1
.> - :. LFBD + LFID = 1 80°
i3 + (1 - x)(l + x + x ) ⇒ � 1 80
0
+B
= n [4(2n • + 3n + 1) - 1 2n - 1 2 + 6] 1 00 =B+ = 1 800
1- X 2
4(n + 1)(2n + 1) 1 0 1
i3 + 1 - i3 1 ⇒ ___,__ 2_,_.'____'_ > - ⇒ 3B = 1 80° ⇒ B = 60°
8n - 2 1 00
1- X 1- X LB 60
4(2n + l)(n + 1) 1 0 1 ... LIFD = - = - = 300
⇒ >- 2 2
7. (b) Given,
Now, put the value of x
2(2n + 1)(2n - 1) 1 00
1 - -- 1
- 2n + 2 1 0 1
1 - 0.75 0.25 ⇒ - ->- 1 -2x T x C
2n - 1 1 00
1 00
= =4
25 ⇒ 200n + 200 > 202n - 1 0 1
So, square root of the equation = -/4 = 2 ⇒ 2n < 30 1
s
3. (b) Given, sides of triangle are positive
30 1
⇒ n< -
integer in an AP and the smallest side is 2
1 0. :. Maximum value of n = 1 50
:. Sides of triangle are 6. (b) Given, w R
1 0, 1 0 + d, 1 0 + 2d , dE N A
We know in triangle sum of two sides is
greater than third sides.
A p Q B
1 0 + 1 0 + d > 1 0 + 2d . . . (i)
1 0 + 1 0 + 2d > 1 0 + d . . . (ii) ABCD is square of length 1 unit and a
regular octagon is formed by cutting
lO + d + 10 + 2d > 10 . . . (iii)
congruent isosceles triangle.
Let DUV is isosceles right angled triangle.
From Eqs. (i), (ii) and (iii), we get
d < 10
LD = 90°
d = 1 , 2, 3, 4, 5, 6, 7, 8, 9
LDVU = 45°
Hence, there are 9 triangles possible.
In MJVU,
4. (a) We have, x
cos45° = __
AD, BE, CF are angle bisectors of angle
� = a + b = a + b + c = a + b + c + d =k 1 - 2x
A,B and C respectively. 1 X

3 4 5 6
⇒
On solving, we get .J2 - 1 - 2x
I is the concurrent point of angle bisector
a = 3k, b = k, c = k, d = k and BD IF are concyclic. ⇒ .J2 = 1 - 2x
a 3k Now, BDIF is concyclic. X
b + 2c + 3d k + 2k + 3k LB ⇒ .J2 =--1: - 2
LIFD = LIBD =
3k 1 2 X
6k 2 [·: angle on same segments are equals ] ⇒ --1: = 2 + ./2

X
WWW.JEEBOOKS.INl
1 -12 - 1 In MXF and t.BAF, 1 2. (c) Let the time taken by A to

LF = LF
⇒ X
B to complete the job = y h
-/2(-/2 + 1) v'2 (common) complete the job = x h and time taken by
:. Side of regular octagon = 1 - 2x LX = LA = (90° )
MXF - t.BAF A and B together works then they
= 1 - 2(-/2 - 1)
-12 ar(MXF) AF2 _1_
= =
complete the work = � + ; in 1 h
( )
= 1 - -/2(-12 - 1) ar(BAF) BF2 5
1 0. (b) Given,
Let the complete work in t h
= 1 - 2 + -/2
_1_ = t + 8
= -12 - 1 t _l_ +
8. (b) Given, OA = OB = r
(X y) X
t 8
⇒ . . . (i)
B y X
[B would 4- h more to
1
R p 2
complete the work]
9
t+
t _l_ + _1_ = 2
LQRP = 2°
(X y) y
t
PQ = QR = 1
9
X 2y
⇒ . . . (ii)
LQPR = 2°
LRQP = 180° - 4° = 176°
From Eqs. (i) and (ii),
t 2 = 36
SP = SQ radii of circle
Also, OC is radius of sector LSQP = LQSP
⇒ t = 6h
OC = r 1 3. (d) Let the weight of bucket be x kg
Now, OC = OB + BC
180° - 2° and the weight of water completely full
OC = OB + R [BC is radius of circle]
2 be y kg.
In t.OPE, = 178°
According to the problem,
= 890
BP x + Z = lO
2
[ ·: LBOP = 30°] LRQS = LRQP - LSQP
. . . (i)
OB
sin 30° = 2
x + Y =11
= 176° - 89° = 87° 2
1 1 . (a) At 6: 1 5,
1 R and . . . (ii)
2 OB
⇒ 3
OB = 2R
On solving Eqs. (i) and (ii), we get
x = 7, y = 6
⇒ 12
OC = 2R + R = 3R
r = 3R
:. Total weight, when bucket is completely
⇒
R =T"_
full is (x + y) kg i.e. 7 + 6 = 13 kg
⇒ 1 4. (a) We have,
3 9
9. (b) We have,
m 12
12 n
A E ⇒ mn = 144
⇒ mn = 24 x 32
6 Total number of divisor of 144 is
(4 + 1)(2 + 1) = 1 5
When m and n are positive integers.
the minutes hand makes an angle is a.
a = 90 + 1 5 x rn
If m and n are negative integers, then
°
K
H 1----�-+-- -+--- - -_____::,,J D
r
a=
5 also number of divisor is 1 5.
n are integers = 1 5 + 1 5 = 30
c: r :. Total ordered pairs of (m,n) when m and
1 5. (c) We have,
and hour hand is �
S = {1, 2, 3, 4,... , 40}

a �- - ---'
- C Given, a + � = 360°
AHKF,FKDE and HBCK is a unit square.

� = 360° - a
5 A is subset of S whose sum of two
= 3600 - 5
= (5
element of A is not divisible by 5.
Possible set A = { 1, 2, 5 , 6, 7, 1 1 , 12, 16,
AD and BF intersect at X.
AB = 2
c: r : r
In MBF, Difference between their angles
AF = l 1 0 17, 2 1, 22, 26, 27, 31, 32, 36, 37}
= 52 5 _ 95 = 33 =1650 :. Maximum number of elements in A
:. FB2 = AB2 + AF2 = 4 + 1 = 5 2 2 2
is 17.
WWW.JEEBOOKS.INl
1 6. (b) Given situation is 1 9. (d) To minimize drift, let angle at 24. (d) Power consumed in each case is
@ Initially one of
which boat is directed by 0, as shown
below. (P) P=v
-2
u2 = 0 the ball is at rest 3R
v/2
Finally both balls moves � '
,
with same speed together � v � Vres
l 90'
'I z
0 (Q) 3V 2
P = - v- = -
Conservation of momentum, gives R /3 R
mv = 2m V ⇒ V = ,!!
2 From above velocity triangle,
So, kinetic energy after collision is sine = � = _! or 0 = 30°
(.!!)
E
2 V 2
K1 = _! (2m) V 2 = _! x 2m x So, angle with respect to direction of flow
2 2 2 +I
is 90° + 0 ° = 90° + 30° = 120°.
= _! mv2 20. (b) Ice is a bad conductor of heat, its
y2
(R) P=-
1 7. (a) Air resistance is same in both

thermal conductivity is very low. So, no
exchange of heat from outside
case.When ball is moving down, air surrounding occurs in an Igloo. Thermal -
resistance is directed away from g. conductivity of ice is 16 Wm -l K- 1 .
21 . (b) Light ray bends towards normal
at point R.
at point Q and it bends away from normal
consumption is P>R> Q>S.

So, order of increasing power
25. (a) Gap or cavity also expands at

So, acceleration of ball moving
downwards is
ll:i_ = -� --
mg - kv same rate as that of metal.
R
m Hence, width of gap also increases by
same amount.
or
:. Width of gap increases by t.d = dat.T.
where, k is constant. 26. (b) f=µN
When ball is moving up, air resistance Also, the emergent ray is parallel to
and g both are directed downwards. incident ray.
Hence, µ 1 = µ 3 < µ 2 is correct option.
22. (a) As, incident light is normal to the
F
surface, so no deviation or dispersion N
j�j
occurs.
mg
Emergent Incident
Air g beam beam
resistance
Minimum force F must be such that
So,acceleration while moving upwards is generated friction is able to balance
23. (a) If object is placed

k weight mg of book.
a2 = g + - v
□
m f = µN = µF.
27. (b) Given,
So,
Clearly,
1 8. (c) The free electrons experiences Surface area of cube = Surface area of
G
electrostatic force in the direction sphere
opposite to the direction of electric fired 0
being is of negative charge. The electric
field always directed from higher
potential to lower potential. Therefore
electrostatic force and negative charge or at the focus of lens on opposite side of
a
6a2 = 41tr 2
electrons always flows from lower to mirror, then light rays after refraction
higher potential until the potantials from lens become parallel to the principal ⇒ . . . (i)
axis.
become equal.
These parallel rays are reflected back over ⇒
Hence, option (c) is correct.
same path and again converges at focus.
WWW.JEEBOOKS.INl
Now, buoyant force is & = Vm ·Pr · g 34. (d) All the central atom of the given The increasing order of basicity of
So, ratio of buoyant force on cube and oxide belong to 2nd period, as we move compounds given in options will be
sphere is from left to right in a period the basicity Me Me
=
6<o<0<6
(& )cube Vcube of oxide decreases.
(& )sphere Vsphere :. The order of increasing basicity of oxide
would be
a3 3 21t
= - = - X ( - )2 P2O5 < SiO2 < Al2O3 < Na2O
j 1tr3 41t 3 Thus, the most basic oxide would be N N N N
6 ""
3 Na20. Me Me
35. (c) Given,
9 x 8 x n3 "'-. N/
= = {n
16 X 1t 2 X 27 �6 Number of moles of solute NaCl
(& )cube < (& )sphere = 0.35 mole
28. (b) Decay is
Thos. bas City of b e ma,dmom
Volume of the solution = 1.30 L N
Mo1an· ty = - Number of moles of solute
39. (b)
��8 U ----t �!4 Po + 6:He + ne - - - - - - - - -
Conservation of mass number and atomic Volume of solution in litres
number gives, 0.35 H3C-C= C-H + HBr Marko;vnikoff
= = 0.269 = 0.27M add1t1on
1.30 (Excess)
36. (d) Intensive variables are those

⇒ 92 = 84 + 12 - n ⇒ n = 4
29. (c) In Rutherford model, positive I
Br
I I
charge acquires a very small place at variables which don't depend upon the H3C-C-CH3 f-- H3C-C=CH2
HBr
centre of atom in nucleus. quantity or size of matter. Among the

given quantities density, temperature Br Br
So, option (c) is incorrect.
30. (a) Neutral objects are always
(Major)
and pressure are intensive variables
whereas heat capacity, enthalpy and This is an electrophilic addition reaction
attracted towards both positively and which proceeds via carbonium ion
volume are an extensive variables. Thus,
negatively charged objects. So, water formation and follows Markownikoff rule.
40. (c) As the reaction is occurring at
the correct option is (d).
37. (b) KAl(SO4 )x - 12H2O is an empirical
stream still bends in same direction.
3 1 . (c) 2Ca + 02 � 2CaO room temperature, (25°C) so it will be an
Excess formula for potash alum which is double acid base reaction.
20 salt.
= .!. mole
°
Ila C - COOR + Clia CH2NH2 -25 C

Number of moles of Ca = .--+
40 2 Potash alum is K2SO4 - Al2 (SO4 )2 · 24H2O Acid-base
:. Empirical formula is KAl(SO 4 ) 2 - 12H2O reaction
Thus, x = 2 .
1 mole of Ca produces 1 mole of CaO
NIia + CH2Clia · Clia coo-
38. (b) Pyridine is basic in nature due to 4 1 . (b) For an equilibrium reaction,
:. _!_ mole of Ca will produces _I mole
2 2
of CaO the presence of free lone pair. Its basicity A + B � C + D;
1 mole of CaO = 56g gets affected by the presence of different _ [C] [D]
Q -
_!_ mole of CaO = 56 x _!_ = 28g substituents attached to it. The electron c [ A ] [ B]
2 2 withdrawing group decreases the basicity If Qc = Kc , the reaction is in equilibrium.
Thus, 28 g of CaO is formed by burning of pyridine, whereas electron releasing If Qc > Kc , the reaction proceeds in
20 g of Ca in excess oxygen. groups increases its basicity.
32. (a)
backward reaction.
Substituents like N(Me)2 and CHa are If Qc < Kc , the reaction proceeds in
electron releasing but N(Me)2 is more
II
NaOH forward reaction.
B13 CCHO ----t CHB13 + HC O-Na + activating group than CHa . Thus, the reaction will proceed in the
0 So, H3C CH3 direction of products i.e., forward reaction
"'-. / when Qc < Kc .
42. (b) Acetyl salicylic which is a pain
This reaction is known as bromoform N
reaction where the carbonyl carbon gets
oxidised by sodium hydroxide to sodium killer commonly known as aspirin.
salts of corresponding carboxylic acid
having one carbon atom less than of
carbonyl compound and the methyl group r&��OH
is converted to bromoform. basicity would be maximum while Cl
33. (c) For, fgK+
6
is an electron withdrawing group, so
Acetyl salicylic acid
Number of electrons in K+ = 18 Cl (aspirin)
43. (c) Hydrogen bonding occurs in a

Number of neutrons in K+ = 40 - 19 = 2 1
⇒ Sum of electron + neutron is basioity would be least. molecule when a hydrogen atom is
= 18 + 2 1 = 39 N directly linked to an electronegative atom
like F, 0 and N.
WWW.JEEBOOKS.INl
KVPY Question Paper 2012 Stream : SA 1 19
In case of diethyl ether (II,, C2OC2IJ,, ), H is 46. (a) A smear of blood from a healthy when any external pressure is applied
not directly linked to oxygen atom and individual if viewed under the microscope like shaking or touching (seismonastic
hence will not exhibit strong hydrogen will show highest number of neutrophils. movement), activates the certain
There are three types of blood cells in an contractile proteins including potassium
bonding.
44. (b)
individual, i.e. red blood cells ions. These chemicals make water and
H electrolytes flow/diffuse out of the cell,
�
(erythrocytes), white blood cells
CH 3 � (leukocytes) and platelets (thrombocytes). resulting in a loss of cell pressure. This
CH 3 H RBCs and platelets are devoid of nucleus, causes the cell to collapse, which
CH3
(But-2-ene) (But-1 -ene) thus are not stained by haematoxylin squeezes the leaves close. Stimulus, in
nuclear stain. Therefore, only WBCs are the form of touch is sometimes
Both the compounds, but-2-ene and stained. In a healthy individual, there transmitted to neighbouring leaves as
but-1-ene are positional isomers of each are five types of WBCs, i.e.neutrophils well and causing the closing of other
other because they differ in the position (accounts for 40-75% of leukocytes), neighbour leaves too.
eosinophils (1-6%), basophils (0-1%), 52. (c) The Sundarbans delta is the
= nRT
of double bond.
45. (b, c) p V
lymphocytes (20-45%) and monocytes largest mangrove forest in the world and
47. (d) Transduction is a method of gene

(2-10%).
p=
is intersected by a complex network of
RT (for 1 mole) tidal waterways, mudflats and small
V islands of salt-tolerant mangrove forests.
At constant T, p would be inversely
transfer in bacteria from donor to
recipient using bacteriophage. In It lies at the mouth of the Ganges.
proportional to V. transduction, at first bacteriophage A mangrove is a shrub or small tree that
So, plot of p versus V would

53. (a) The process by which new blood
infects donor bacteria and then carries grows in coastal saline or brackish water.
some part of donor genome with it. When
this bacteriophage infects new bacterial cells are formed is called haematopoiesis.
cell, it transfers that DNA into recipient The group of cells performing
p at constant T cell. haematopoiesis are called hematopoietic
48. (b) Glycolysis is the first stage of tissue. These are of two kinds, i.e.
cellular respiration that involves the myeloid tissue and lymphoid tissue.
breaking down of glucose into smaller Myeloid tissue is red bone marrow, which
V molecules to produce ATP (cellular produces erythrocytes, platelets and most
energy). Glycolysis occurs in the of the leukocytes (including the
Thus, plot (a) is correct.
cytoplasm of all living organisms because B-lymphocytes). Lymphoid tissue consists
According to ideal gas equation. of the lymphatic nodules, lymph nodes,
that is where glucose and other related
p V = nRT or P V = nR enzymes can be found in high spleen and thymus (which produces only
T T-lymphocytes).
54. (b) Vertebrate hearts can be
concentrations.
49. (a) Huntington's disease is a disease
As R is a gas constant, so plot between
p V versus T would be linear and slope categorised by the number of chambers
of the nervous system. It is a fatal genetic
will be n. i.e. they have, like two-chambered (one
disorder that causes the progressive
breakdown of nerve cells in the brain. It atrium and one ventricle) in fishes,
deteriorates a person's physical and three-chambered (two atria and one
mental abilities during their prime ventricle) in amphibians and reptiles;
pV working years and has no cure. and four-chambered (two atria and two
50. (a) A cell will experience the highest

55. (d) Gigantism and acromegaly are
ventricles) in birds and mammals.
level of endosmosis when it is kept in

T syndromes of excessive secretion of
distilled water. Endosmosis is the process
Also, from ideal gas equation p is directly
growth hormone from pituitary gland.
by which water molecules move into the
Acromegaly is a condition that affects
cell. Distilled water has far less solute
proportional to J:__ Therefore, plot adults, usually between the age of 30 and
V concentration than cell fluid. Thus, it is a
50, while gigantism affects children with
between p versus J:_ is a straight line, i.e.
hypotonic solution which allows
the same excess growth hormone but in a
V maximum endosmosis. Other solutions way that can delay puberty as well as
like sugar solution, salt solution and
56. (b) The pH of 10-3 M HCl is close to
causes excessive physical growth.
= - log [H.i o+ 1 we get pH equal to 8. But

protein solution are hypertonic solutions
compared to distilled water. Cell
7, i.e., 6.98. It can be calculated as, pH
performs exosmosis in hypertonic
p /- solutions.
51 . (c) The leaves of touch-me-not plant
lp this is not correct because an acidic
solution cannot have pH greater than 7.
(Mimosa pudica) are very sensitive, they It may be noted that in very dilute acidic
droop on touching because of autotrophic +
solution, when H concentrations from
1 /v effect. As, water within the cells of this
acid and water are comparable, the
Thus, plot (b) is incorrect. plant applies a turgour pressure, which
concentration of W from water cannot be
makes to leaves its stay upright. So,
neglected.
WWW.JEEBOOKS.INl
Since HCl is a strong acid and is

+
Therefore, [H+ ltotal = [H l acid + [H lwater 2
= 2ab - be+ (b 2- ac)-/2
2b� - c
:. Solutions are ( 3, 2, i) ( 4,
completely ionised � lHcI = 1.0 x 10-8 Since a , b, c are positive integers and 3
Put z = -, then x + 2y = 6
The concentration of H+ from ionisation
is equal to the [OH-] from water, �1
w2 + C
+ b is
rational.
4
xy = 4
[H+ ]H2o = [OIr ]H2o = x (say) b2 - ac = O On solving, we get x = 4, y = l and x = 2,
[W ltotal = 1.0 x 10-8 + x y=2
:. a,b,c are in GP.
But [H+ ] [Oir] = 1.0 x 10-14 Let a = a, b = ar, c = ar 2, where r is also :. Solutions are ( 4, 1, � ) and ( 2, 2, n
(LO x 10-8 + x) (x) = 1.0 x 10-14
At least two of x, y, z are integer is
positive integer.
x2 + 10-8 x - 10-14 = 0
Solving of x, we get x = 9.5 x 10-8
2a 2 + b-2
(a) --
2b2 + c2 (3, 1, 1), 2, ¾ 1} ( 3, 2,
(
i}
Therefore [W ] = 1.0 x 10-8 + 9.5 x 10-8 2 2 2
2a + a r = - 1 not . teger
= 10.5 X 10-8 = 1.05 X 10-7 -----
2a 2r 2 + a 2r 4 r 2
m ( 4, 1, � } (2, 2, � )
pH = - log [H ] = - log (1.05 x 10-7 ) = 6.98
+
57. (d) Mitochondria have their own

2
+ b2 - c2 a2 + a2r 2 - a2r 4 Hence, 5 solutions.
63. (c) Given, in MBC,
(b) a =
DNA and ribosomes. Ribosomes are the a+ b- c a + ar - a r·,
A
site of protein synthesis. Therefore, l + r2 - r4
=a( not integer
mitochondria are capable of making their 1 + r - r2 )
own protein. Mitochondria are also
capable of synthesising their own genetic a 2 + 2b-2
(c) -- D
material. b2 + 2c2
58. (c) Maltose is a polymer composed of a2 + 2a 2r 2 = 1 not . teger
a 2r2 + 2a 2r4 2r
two glucose molecules. It is a m
disaccharide formed when two units of 2
+ b2 -+ c2 a 2 + a2r 2 + a2r 4
(d) - a - C
glucose are joined with a (1➔ 4) bond. B
= .,
Maltose is also known as malt sugar and a+ b- c a + ar - ur· AB = AC
= a [ 1 + r + r9 ]
is found in foods in which starch is 2 2 4 D is mid-point of AC.
fermented by yeast or enzymes, such as AC AB
in bread or brewed beverages. a 1+ r - r· AD = CD = - = -
59. (c) A mycorrhiza is a symbiotic
2 2
= a(l + r + r 2) integer
In MBD,
association between roots of higher plant 62. (b) We have,
x + 2y + 4z = 9
and a fungus. The plant makes organic AB2 +- AD- 2 -- 22
cosA = - -
. . . (i)
4yz + 2xz + xy = 13
molecules such as sugar by 2 - AB - AD
. . . (ii)
xyz = 3
photosynthesis and supplies them to the 4AD 2 + AD 2 - 4
cosA =
D .,·
x + 2y = 9 - 4z 4A
fungus and the fungus supplies to the
⇒
plant water and mineral nutrients, such [·: AB = 2AD]
as phosphorus, taken from the soil. From Eq. (ii),
2z(2y + x) + xy = 13 5AD 2 - 4
Lichen is a symbiotic partnership of a cosA = . . . (i)
4AD 2
fungus and an alga. Rhizobium are ⇒ 2z(9 - 4z) + � = 13
nitrogen-fixing bacteria found in root z In MBC,
nodules of legumes. Anabaena is a genus ⇒ 8z3 - 1 8z2 + 13z - 3 = 0 AB- 2 +- AC- 2 -- 22-
of filamentous cyanobacteria. ⇒ (z - 1)(2z - 1)(4z - 3) = 0 cosA = -
60. (a) During the course of evolution

2AB - AC
⇒ z = J., � �
2, 4 4AD 2 + 4AD 2 - 4
simple organisms evolved first while cosA = ·)
complex organisms evolved later. Put z = ], then x + 2y = 5 and xy = 3 SAD ·
Fossilisation of complex organisms took On solving, we get x = 3, y = 1 8AD 2 - 4
cosA = . . . (ii)
later in upper strata of earth crust. and x = 2, y = 3
6 1 . (d) We have, a,b,c are positive
SAD 2
2
m -/2 + b 1s
. tegers and ab-/2 . a rat1ona
. 1 :. Solutions are (3, 1, 1) and ( 2, � ,1}
5AD 2 - 4 8AD 2 - 4
2 +c
1 4AD 2 8AD 2
number. Put z =-, then x + 2y = 7
2
:. (j: !)(�=:) -J2 On solving, we get

xy = 6 ⇒
⇒
10AD 2 - 8 = 8AD 2 - 4
AD = -/2
x = 3, y = 2 and x = 4, y = -3
2ab - ac-/2 + b2 - be 2
2
⇒ AB = 2 ✓
2b2 - c 2
WWW.JEEBOOKS.INl
�•�:-��,2m/
Area of MBC = --1:AB - AC sinA Path = ./5 + 2 + ./5 + ./5 = 3./5 + 2 67. (d) Given situation is
2 = 3(223) + 2 = 8.69
(d) In figure
�P;h�f�;,e - ,
'jn �--- -m - - of mass , m
. V-rs
[·: cosA = U 2
( - 27,0) ____,, (27 m, O)
First particle's
(45,0) (x,O)
position
� I
64. (c) Let the distance between Pune

As explosion force which splits the
firecracker is internal to system, path of
and Mumbai be x km. centre of mass of system remains same.
Time taken by 1st train = 4 h Path = 2 + .JI3 + ./5 Now, range of centre of mass of system is
R = u sin 20
= 2 + 3.60 + 223 = 7.83 2
:. Speed of 1st train = � km/h
4 :. Shortest path have option fig (d). g
Hence, option (d) is correct. u = 30 ms-1 , 0 = 15°
66. (a) In case I,
Time taken by 2nd train = '!... h Here,
x
2
:. Speed of 2nd train = __ =
30 x 30 x sin (2 x 15° )
2x km/h R
R= = 45 m
10
(7/2) 7
So, position (or x-coordinate) of centre of
1st train starts from 7 : 30 am and 2nd n mass is at 45 m distance from origin.
Now using, XcM = TlliXi ll½X2, we get
� - 'V\/\N\A'lr-- --+ - - - - - - - - - >-+
train starts from 9 : 30 am. - �
+
Distance travelled by 1st train in 2 h mi + "½
= � km m (± 27) + mx
m+ m
2 45 =
Let they meet at time t.
(1 X t)+ ( � }
+ ± 27 + X
I I I--- - - - -
� ⇒ 45 =
�= E 2
Solving, we get
nRo + R
Total circuit resistance,
Req = Ro + "!!:_ =
⇒ t = G: ) h x = 90 ± 27 ⇒ x = 63 m or x = 1 1 7 m
n n
. . current = lei = - ⇒ i.1 = - nE-
. E
So, other piece may fell at 6 3 m o r 1 1 7 m
C1rcu1t
⇒ t = G: x 6o) min = 56 min mark.
Req nR0 + R 68. (c) As block is sliding with a
Power dissipated in n resistors,
:. They meet at 9: 30 + 56 = 10: 26 am
65. (d)
constant speed, so change in kinetic
-rs nE2R
energy of block when it reaches bottom is
Pi_ = if _ ( °!!:. ) =
n (nR0 + R)2
(a) In figure zero.
Now, by work-energy theorem,
Total work done = Change in kinetic
- 1
energy
{8
⇒ Wfriction + Wgravitation = dKE
⇒ Wfriction = - Wgravitation
Path = 1 + ./5 + ✓10 + .Js or Wfriction = - mgh
= 1 + 223 + 3.16 + 2.82 = 9.2 1 � ----1 1 1 1>-- - -�
So, energy dissipated due to friction
Total circuit resistance, Req = R0 + nR

(b) I n figure E
= mgh.
69. (b) Magnetic field linked with loop is
E E
Current in circuit is downwards.
i2 = - = - -
Req R0 + nR
.
X
Power dissipated in n resistors,

nE2R '-x- ----> E
P2 = (i-22) (nR) =
X
(R0 + nR)2
Path = 1 + 2 + ✓10 + .Js
Pi_ = P2
= 1 + 2 + 3.16 + 282 = 8.98 X X
-rs
As,
nE
(c) In figure 2 When loop is pulled away from wire, flux
(nRo + R)
⇒ ----2 linked with loop decreases. This induces
⇒ nR0 nR
2 a current in loop which tries to oppose
(n - l)R0 = (n - l)R
+ R = R0 + this change (in accordance with Lenz's
R
⇒ law).
R0 = R or _Q_ = 1
R
⇒ So, current induced in loop is clockwise.
WWW.JEEBOOKS.INl
70. (d) Let m gram of ice melts and this 73. (b)
0
2 x 5 = 2 x moles
causes final temperature of mixture at = moles8,2 = 5 mol
0°C. Further melting of ice is then
76. (a) Absence of cone cells in eyes is
stopped. As there is no heat loss Sn/HCI (i) NaN02/HCI
known as total colour blindness or
Heat lost by ice = Heat gained by water [Reduction/ [Diazotisation]
monochromacy. This person views
6
⇒ mL= mu,� (/J.T) Nitrobenzene Aniline everything as if it were in a black and
⇒ m 80 = lO0 x l x (80 - 0)
X + - white television. Monochromacy occurs
Br N== NCI
when 2 or all 3 of cone pigments are
⇒ m 80 = 100 x 80
lO0 x 80 missing and colour and light vision is
(ii) CuBr, l!.
⇒ m= - - - 6
77. (d) Pleural fluid is a serous fluid

reduced to one dimension.
80 Sandmeyer I
reaction / ✓
⇒ m = 100 g produced by the serous membrane

y Diazonium
So, 50 g of ice does not melts. Bromo salt
7 1 . (b) Let the equivalent weight of

covering normal pleurae. The pleural
benzene
74. (b) According to the conservation of

fluid acts as a lubricant and allows the
metal be x g. pleurae to slide effortlessly against each
energy, the kinetic energy of the ejected other during respiratory movements,
Number of equivalents of metal
electron is given as thus reducing the friction between the
= Number of equivalents of metal sulphate
78. (c) DNA polymerase is an enzyme

1 2 1 2 ribs and the lungs.
Wt. of metal
=
Wt. of metal sulphate hv = hv0 + - mv ⇒ - mv = hv - hv0
2 2
or - mv2 = hv - W0
Eq. wt. of metal Eq. wt. of metal sulphate that synthesises DNA molecules from
1
� = � = 6. 8x = 2x + 96 deoxyribonucleotides, the building blocks
X X + 48 2
of DNA. These enzymes are essential for
where, W0 = hv0 = Work function DNA replication. S-phase or synthetic
4. 8x = 96
(minimum energy required to eject the phase is significant due to DNA
96
X= = 20.0 g electron). synthesis. Thus, DNA polymerase
72. (b) Let the volume of HCl and H2SO4

4.8
79. (c) During vigorous muscular

Higher is the threshold frequency (v 0 ) activity is highest at S-phase of cell cycle.
more will be the work function, Thus,
be V [No. of moles = Molarity x Basicity M ➔ Rb, M ➔ K, M ➔ Na, M ➔ Li activity like running, muscles perform
75. (*) KMnO4 + KBr + H2SO4
1 2 3 4
x Volume] anaerobic respiration after a while due to
scarcity of oxygen. During anaerobic
Moles of Ir ions in HCl
- ➔ MnSO 4 respiration in muscles, lactic acid is
= 0.1 x 1 x V = 0.1 V produced as a byproduct. Thus a runner
+ K2SO4 + Br2 + H2O
Moles of Ir ions in H2SO4 will have lactic acid in his muscles after a
Balancing the above equation,
80. (b) Camel belongs to

= 0.2 x 2 x V = 0. 4 V 100 metre sprint.
2KMnO4 + lOKBr + 8H2SO4 ➔ 2MnSO4
Thus, resulting moles of Ir ions in + 5Br2 + 6K2SO4 + 8H2O
solution = (0.1 + 0.4) V = 0.5 V class-Mammalia. Both birds and
No. ofeq. of KMnO4 = No. of eq. ofBr2 mammals are homeothermic and have a
Resulting volume of a solution = 2 V
Moles 0.5 V
Mole x nKMno 4 = Mole x n8,2 fixed 37° C body temperature. So, the
[H+ ] = =
=5
2V where, n is the balancing factor DNA polymerase isolated from a camel
Volume
will work efficiently at temperature near
=2
nKMno 4
= 0.25 mol L its body temperature.
nBr2
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions
MATHEMATICS 4. Let a, b, c, d be real numbers such that I a - b I = 2,

1. Suppose a, b, c are three distinct real numbers, let I b - c l =3, I c - d i =4. Then, the sum of all possible
values of I a - d I is
P(X) = -
(x - b)(x - c) (x - c) (x - a) (x - a)(x - b)
- -+ - - -+- - - -. (a) 9 (b) 18
(a - b)(a - c) (b - c)(b - a) (c - a)(c - b) (c) 24 (d) 30
When simplified, P(x) becomes 5. Below are four equations in x. Assume that 0 < r< 4.
(a) 1 Which of the following equations has the largest
(b) X solution for x?
x2 + (a + b + c)(ab + be + ca)
(c) (a) 5 (1+ � r = 9 (b) 5 (1+ r = 9
(a - b)(b - c)(c - a) ;7
(c) 5(1+ 2rf = 9

(d) 0
2. Let a, b, x, y be real numbers such that a2 + b2 = 81,
x2 + y2 = 12 1 and ax + by = 99. Then, the set of all 6. Let ABC be a triangle with LB = 90°. Let AD be the
t t
possible values ofay - bx is bisector of LA with D on BC. Suppose AC = 6 cm and
the area of the t:..ADC is 10 cm2 • Then, the length of
2
(a) ( 0, ] (b) (0, ) (c) {0}
1 1 BD in cm is equal to
3. If x + � = a, x2 + ; = b, then x3 + ) is (a) �
5
(b)
10
10
3 2
(a) a + a - 3a - 2 - b 3 2
(b) a - a - 3a + 4 - b (c) � (d)
3 3
(c) a3 - a 2 + 3a - 6 - b (d) a3 + a 2 + 3a - 16 - b
WWW.JEEBOOKS.INl
7. A piece of paper in the shape of a sector of a circle 13. A frog is presently located at the origin (0, 0) in the
r
(see Fig. 1) is rolled up to form a right-circular cone XY-plane. It always jumps from a point with integer
(see Fig. 2). The value of the angle 0 is coordinates to a point with integer coordinates
6
moving a distance of 5 units in each jump. What is
the minimum number ofjumps required for the frog
to go from (0, 0) to (0, 1)?
12 W2 �3 �4 00 9
l
14. A certain 12-hour digital clock displays the hour and
the minute of a day. Due to a defect in the clock
whenever the digit 1 is supposed to be displayed it
displays 7. What fraction of the day will the clock
Fig. 1 +--- 5 ➔ show the correct time ?
(c) -3
Fig. 2
(a) -1 (b) -5 (d) _!"!
(a) l 01t (b) 91t (c) 51t (d) 61t 2 8 4 6
13 13 13 13
15. There are 30 questions in a multiple-choice test. A
8. In given figure, AB = 12 cm, CD = 8 cm, BD = 20 cm, student gets 1 mark for each unattempted question,
LABD = LAEC = LEDC =90°. If BE = x, then 0 mark for each wrong answer and 4 marks for each
A correct answer. A student answered x questions
correctly and scored 60. Then, the number of possible
value of x is
(a) 15 (b) 10 (c) 6 (d) 5
C PHYSICS
16. A simple pendulum oscillates freely between points A
and B.
8 X E D
(a) x has two possible values whose difference is 4
(b) x has two possible values whose sum is 28
(c) x has only one value and x � 12
(d) x cannot be determined with the given information C
9. Three circles each of radius 1 touch one another A ---------------- B A ------------ ___ '. a
externally and they lie between two parallel lines. D
The minimum possible distance between the lines is We now put a peg (nail) at the point C as shown in
(a) 2 + ./3
(c) 4
(b) 3 + ./3
(d) 2 + -1 above figure. As the pendulum moves from A to the
right, the string will bend at C and the pendulum
will go to its extreme point D. Ignoring friction, the
10. The number of distinct prime divisors of the number point D
(512)3 - (253)3 (259)3 is (a) will lie on the line AB
(b) will lie above the line AB
-
(c) will lie below the line AB

W4 �5 �6 00 7
11. Consider an incomplete pyramid of balls on a square (d) will coincide with B
base having 18 layers, and having 13 balls on each
side of the top layer. Then, the total number N of 17. A small child tries to move a large rubber toy placed
balls in that pyramid satisfies on the ground. The toy does not move but gets
(a) 9000 < N < 10000 (b) 8000 < N < 9000 deformed under her pushing force F, which is
(c) 7000 < N < 8000 (d) 10000 < N < 12000 obliquely upward as shown in the figure.
12. A man wants to reach a certain destination. Then,
One-sixth of the total distance is muddy while half
the distance is tar road. For the remaining distance
he takes a boat. His speed of travelling in mud, in
water, on tar road is in the ratio 3 : 4 : 5. The ratio of
the durations he requires to cross the patch of mud,
stream and tar road is (a) the resultant ofthe pushing force F, weight ofthe toy,
(a) -1 : -4 : -5 (b) 3 : 8 : 15 (c) 10 : 15 : 18 (d) 1 : 2 : 3 normal force by the ground on the toy and the
2 3 2 frictional force is zero
WWW.JEEBOOKS.INl
(b) the normal force by the ground is equal and opposite to B

the weight of the toy
(c) the pushing force F of the child is balanced by the
equal and opposite frictional force
(d) the pushing force F of the child is balanced by the total
internal force in the toy generated due to deformation
A C
u. At the instant, it reaches its maximum height H,

1 8. A juggler tosses a ball up in the air with initial speed
he tosses up a second ball with the same initial The minimum value of the refractive index of the
speed. The two balls will collide at a height prism is close to
3 (a) 1 . 10 (b) 1.55 (c) 1.42 (d) 1. 72
(a) H (b) H (c) H
4 2 4 V4
(d) @_H
24. A convex lens is used to form an image of an object on
a screen. If the upper half of the lens is blackened, so
1 9. On a horizontal frictionless frozen lake, a girl 36 kg and
that it becomes opaque, then
a box 9 kg are connected to each other by means of a
(a) only half of the image will be visible
rope. Initially, they are 20 m apart. The girl exerts a
horizontal force on the box, pulling it towards her. How (b) the image position shifts towards the lens
(c) the image position shifts away from the lens
far has the girl travelled when she meets the box?
25. A cylindrical copper rod has length L and resistance

(d) the brightness of the image reduces
(a) 10 m
R. If it is melted and formed into another rod of

(b) Since, there is no friction, the girl will not move
length 2L, then the resistance will be

(c) 16 m
(d) 4 m
20. The following three objects ( 1) a metal tray, (2) a
26. Two charges +Q and -2Q are located at points A and
(a) R (b) 2R (c) 4R (d) SR
B on a horizontal line as shown below.

block of wood and (3) a woolen cap are left in a closed
room overnight. Next day, the temperature of each is
recorded as 7;_ , T2 and I's, respectively. The likely +Q -2Q
situation is A B
(a) T1 = T2 = ½ (b) ½ > T2 > T1 The electric field is zero at a point which is located at
(c) T3 = T2 > T1 (d) ½ > T2 = T1 a finite distance
21 . We sit in the room with windows open. Then, (a) on the perpendicular bisector ofAB
(c) between A and B on the line

(a) air pressure on the floor of the room equals the (b) left of A on the line
atmospheric pressure but the air pressure on the
ceiling is negligible (d) right of B on the line
(b) air pressure is nearly the same on the floor, the walls 27. A 750 W motor drives a pump which lifts 300 L of
and the ceiling water per minute to a height of 6 m. The efficiency of
(c) air pressure on the floor equals the weight of the air the motor is nearly
(Take, acceleration due to gravity to be 10 m / s2)
column inside the room (from floor to ceiling) per unit
area
(d) air pressure on the walls is zero, since the weight of air (a) 30% (b) 40% (c) 50% (d) 20%
acts downward 28. Figure below shows a portion of an electric circuit
22. A girl standing at point P on a beach wishes to reach
a point Q in the sea as quickly as possible. She can
with the currents in amperes and their directions.
portion PQ is
The magnitude and direction of the current in the
run at 6 kmh -1 on the beach and swim at 4 kmh-1 in
the sea. She should take the path 3A
Q
p_ _ _ _ _ _.
_
Q 1A
Sea
2A
Beach
1
8A
T
p
(a) PAQ (b) PBQ (c) PCQ (d) PDQ 4A 2A
23. Light enters an isosceles right triangular prism at
(b) 3 A from P to Q
internal reflection at face BC as shown below.
normal incidence through face AB and undergoes total
(c) 4 A from Q to P (d) 6 A from Q to P
(a) zero
WWW.JEEBOOKS.INl
29. A nucleus of lead Pb:�4 emits two electrons followed When the partition is removed, the gases mix. The
by an a-particle. The resulting nucleus will have changes in enthalpy (1',,.H) and entropy (1',,.S) in the
(a) 82 protons and 128 neutrons process, respectively, are
(b) 80 protons and 130 neutrons (a) zero, positive (b) zero, negative
(c) 82 protons and 130 neutrons (c) positive, zero (d) negative, zero
(d) 78 protons and 134 neutrons 36. The gas produced from thermal decomposition of
30. The number of air molecules in a (Sm x Sm x 4m) (NH4 )iCrp7 is
room at standard temperature and pressure is of the (a) oxygen (b) nitric oxide
order of (c) ammonia (d) nitrogen
(a) 6 x 1023 (b) 3 x 1024 (c) 3 x 1027 (d) 6 x lo'3° 37. The solubility curve ofKNO3 in water is shown below.
,,v
CHEMISTRY
V
cii 250
o ,,"'
�
V
200
31. Two balloons A and B containing 0.2 mole and 0.1 mole E
of helium at room temperature and 2.0 atm, /
Ol 1 50
respectively, are connected. When equilibrium is 0
0
�
established, the final pressure of He in the system is /
(a) 1.0 atm (b) 1.5 atm
? 1 00
V
(c) 0.5 atm (d) 2.0 atm g 50
/
0
32. In the following set of aromatic compounds
o 0
Cf)
0 10 20 30 40 50
Temperature (0C)
0 The amount ofKNO3 that dissolves in 50 g of water at

40°C is closest to
6CH
(i) ( ii) (a) 100 g (b) 150 g (c) 200 g (d) 50 g
0 38. A compound that shows positive iodoform test is
(a) 2-pentanone (b) 3-pentanone
(c) 3-pentanol (d) 1-pentanol
39. After 2 hours the amount of a certain radioactive
(iii) substance reduces to 1116th of the original amount
The correct order of reactivity toward Friedel-Crafts (the decay process follows first-order kinetics). The
alkylation is half-life of the radioactive substance is
(a) i >ii > iii > iv (b) ii > iv > iii > i
(a) 15 min (b) 30 min (c) 45 min (d) 60 min
(c) iv > ii > iii > i (d) iii > i > iv > ii
40. In the conversion of a zinc ore to zinc metal, the
33. The set of principal (n), azimuthal Cl) and magnetic process of roasting involves
(m1 ) quantum numbers that is not allowed for the (a) ZnCO3 ➔ ZnO (b) ZnO ➔ ZnSO4
electron in H-atom is (c) ZnS ➔ ZnO (d) ZnS ➔ ZnSO4
(a) n = 3, l = 1, m1 = - 1
(b) n = 3, l = 0, m1 = 0 41. The number of P-H bond(s) in Ha PO2 , HaPO3 and
(c) n = 2, l = 1, m1 = 0 H3 PO4 , respectively, is
(d) n = 2, l = 2, m1 = - 1 (a) 2, 0, 1 (b) 1, 1, 1 (c) 2, 0, 0 (d) 2, 1, 0
34. At 298 K, assuming ideal behaviour, the average 42. When chlorine gas is passed through an aqueous
kinetic energy of a deuterium molecule is solution of KBr, the solution turns orange brown due
(a) two times that of a hydrogen molecule to the formation of
(b) four times that of a hydrogen molecule (a) KCl (b) HCl (c) HBr (d) Br 2
(c) half of that of a hydrogen molecule 43. Among
(d) same as that of a hydrogen molecule
�
35. An isolated box, equally partitioned contains two
ideal gases A and B as shown
A B
0 (i)
�
(ii) (iii) (iv)
° ° the compound which is not aromatic is
1 atm 25 C 1 atm 25 C
Wi � ii � ili ��
WWW.JEEBOOKS.INl
44. Among the following compounds 49. The gall bladder is involved in
(a) synthesising bile
r-<.
H3C �
CH3
(b) storing and secreting bile
(c) degrading bile
CH3
(d) producing insulin
H3C
50. Which one of the following colours is the least useful
(i) (ii) for plant life?
(a) Red (b) Blue
(c) Green (d) Violet
5 1 . At rest, the volume of air that moves in and out per
breath is called
(a) resting volume (b) vital capacity
(c) lung capacity (d) tidal volume
(iii) (iv) 52. How many sex chromosomes does a normal human
2,3-dimethylhexane is inherit from father?
(a) i (b) ii (c) iii (d) iv (a) 1 (b) 2
45. The major product formed in the reaction, (c) 23 (d) 46
Br 53. In the 16th century, sailors who travelled long
distances had diseases related to malnutrition,
e, NaCN because they were not able to eat fresh vegetables
-
□-M--
SO,- at➔ product
he- and fruits for months at a time. Scurvy is a result of
r the deficiency of
(a) carbohydrates (b) proteins
(c) vitamin-C (d) vitamin-D
54. Which of the following structures is not found in
plant cells?
(a) Vacuole (b) Nucleus
(c) Centriole (d) Endoplasmic reticulum
55. The cell that transfers information about pain to the
CN brain is called a
Q,) r c,
(a) neuron (b) blastocyst
(c) histoblast (d) haemocyte
56. The presence of nutrients in the food can be tested.
Benedict's test is used to detect
(a) sucrose (b) glucose
(a) i (b) ii (c) iii (d) iv (c) fatty acid (d) vitamins
BIOLOGY
57. Several minerals such as iron, iodine, calcium and
phosphorus are important nutrients. Iodine is
found in
46. If parents have free earlobes and the offspring has (a) thyroxine (b) adrenaline
attached earlobes, then the parents must be (c) insulin (d) testosterone
(a) homozygous (b) heterozygous
(c) codominant (d) nullizygous 58. The principle upon which a lactometer works is
(a) viscosity (b) density
47. During meiosis, there is (c) surface tension (d) presence of protein
(a) one round of DNA replication and one division
(b) two rounds of DNA replication and one division 59. Mammalian liver cells will swell up when kept in
(c) two rounds of DNA replication and two divisions (a) hypertonic solution (b) hypotonic solution
(d) one round of DNA replication and two divisions (c) isotonic solution (d) isothermal solution
48. Blood clotting involves the conversion of 60. The form of cancer called 'carcinoma' is associated
(a) prothrombin to thromboplastin with
(b) thromboplastin to prothrombin (a) lymph cells (b) mesodermal cells
(c) fibrinogen to fibrin (c) blood cells (d) epithelial cells
(d) fibrin to fibrinogen
WWW.JEEBOOKS.INl

MATHEMATICS When the spring object system is immersed in a liquid
6 1 . Let f(x) =
of density Pi as shown in the above figure, the spring
a:c + bx + c; where a, b, c are integers, stretches by an amount Xi (p > Pt)- When the
Suppose f(1) =0, 40 < f(6) < 50, 60 < /(7) < 70 and
lO00t < f(50) < 1000 (t + 1) for some integer t. Then,
experiment is repeated in a liquid of density � < Pt),
the spring stretches by an amount .'.½· Neglecting any
the value of t is buoyant force on the spring, the density of the object is
(a) 2 (b) 3 (c) 4 (d) 5 or more
(a) p = Pt -Xi - 11r2 (b) p = Pt 2 - PA
X
62. The expression Xi - -½ X2 - Xi
2 2 + 1 32 + 1 42 + 1 (2011)2 + 1 p -½ + Pri p + Pn
- 2 -+- 2 -+- 2 - + .... + - - - (c) = Pt (d) = Pt Xi
2 -1 3 -1 4 -1 (2011)2 - 1 Xi + X2 Xi + -½
lies in the interval 67. A body of 0.5 kg moves along the positive X-axis
(a) ( 2010, 2010i) (b) (20 1 1 - -- , 20 1 1 - -- )
1 1 under the influence of a varying force F ( in newton)
20 1 1 2012 as shown below.
(c) ( 2011,2011i) (d) ( 2012 , 2012 i)
V
3
63. The diameter ofone ofthe bases of a truncated cone
is 100 mm. If the diameter of this base is increased /
by 2 1% such that it still remains a truncated cone /

with the height and the other base unchanged, the
volume also increases by 21%. The radius of the other /v
base (in mm) is
(a) 65 (b) 55 (c) 45 (d) 35 0,0 2 4 6 8 10
64. Two friends A and B are 30 km apart and they start x ( m)
simultaneously on motorcycles to meet each other. The If the speed of the object at x = 4 m is 3.16 ms-1, then
speed of A is 3 times that ofB. The distance between its speed at x = 8 m is
them decreases at the rate of 2 km per minute. Ten
(a) 3. 1 6 ms-1 (b) 9.3 ms-1 (c) 8 ms-1 (d) 6.8 ms-1
minutes after they start, A's vehicle breaks down and
A stops and waits for B to arrive. After how much time 68. In a thermally isolated system, two boxes filled with
(in minutes) A started riding, does B meet A? an ideal gas are connected by a valve. When the
valve is in closed position, states of the box 1 and 2
respectively, are (1 atm, V, T) and (0.5 atm, 4 V, T).
(a) 1 5 (b) 20 (c) 2 5 (d) 30
65. Three taps A, B, C fill up a tank independently in 10 h, When the valve is opened, then the final pressure of
20 h, 30 h, respectively. Initially the tank is empty and the system is approximately
exactly one pair oftaps is open during each hour and (a) 0.5 atm (b) 0.6 atm (c) 0.75 atm (d) 1 . 0 atm
every pair oftaps is open at least for one hour. What is
the minimum number of hours required to fill the tank? 69. A student sees the top edge and the bottom centre C
of a pool simultaneously from an angle 0 above the
(a) 8 (b) 9 (c) 10 (d) 11
horizontal as shown in the figure. The refractive
index of water which fills up to the top edge of the
PHYSICS pool is i. If 'I!_ = 2. then cos0 is
3 X 4
66. An object with uniform density p is attached to a
spring that is known to stretch linearly with applied
force as shown below. 0
(a) 2
(b) 8
(c) 8
(d) 8
7 3J45 3:J53 21
WWW.JEEBOOKS.INl
P . If the resistor is replaced by 9 n, the power

70. In the following circuit, lQ resistor dissipates power
BIOLOGY
dissipated in it is 76. You remove four fresh tobacco leaves of similar size
3Q and age. Leave 'leaf 1' as it is, smear 'leaf 2' with
vaseline on the upper surface, 'leaf 3' on the lower
surface and 'leaf 4' on both the surfaces. Hang the
1 Q leaves for a few hours and you observe that 'leaf 1'
wilts the most, 'leaf 2' has wilted, 'leaf 3' wilted less
than 'leaf 2' and 'leaf 4' remains fresh. Which of the
following conclusions is most logical?
(a) p (b) 3P (c) 9P (d) � (a) Tobacco leaf has more stomata on the upper surface
3
(b) Tobacco leaf has more stomata on the lower surface
CHEMISTRY
(c) Stomata are equally distributed in upper and lower
surfaces
(d) No conclusion on stomatal distribution can be drawn
71 . An aqueous buffer is prepared by adding 100 mL of from this experiment
0.1 mol L - 1 acetic acid to 50 mL of 0.2 mol L -1 of
77. Vestigial organs such as the appendix exist because
sodium acetate. If pKa of acetic acid is 4. 76, the pH of
the buffer is (a) they had an important function during development
which is not needed in the adult
(a) 4.26 (b) 5. 76 (c) 3. 76 (d) 4. 76
(b) they have a redundant role to play if an organ with
72. The maximum number of structural isomers possible similar function fails
for the hydrocarbon having the molecular formula (c) nature cannot get rid of structures that have already
C 4H6 , is formed
(a) 12 (b) 3 (c) 9 (d) 5 (d) they were inherited from an evolutionary ancestor in
which they were functional
73. In the following reaction sequence, X and Y,
respectively, are 78. Mendel showed that unit factors, now called alleles,
A � p ___r_
exhibit a dominant/recessive relationship. In a
monohybrid cross, the .......... trait disappears in the
� OH first filial generation.
(a) H2O2 ; LiAlH4 (b) C6IJ,, COOR; LiAlH4 (a) dominant (b) codominant
(c) C6IJ,, COOH;Zn/Hg - HCl (d) alk. KMnO4 ; LiAlH4 (c) recessive (d) semi-dominant
74. Among (i) [Co(Nll:i \]Cla , (ii) [Ni(Nll:i \]Cl2 , 79. If a man with an X-linked dominant disease has six
(iii) [Cr(H2 O\]C1a, (iv) [Fe(H2 O\]Cl2 the complex sons with a woman having a normal complement of
which is diamagnetic is genes, then the sons will
Wi � ii � ili (a) not show any symptoms of the disease
75. At 783 K in the reaction, H2 (g) + I2 (g) � 2HI(g), the
00 �
(b) show strong symtpoms of the disease
(c) three will show a disease symptom, while three will not
molar concentrations (mol L -1 ) of H2 , I2 and HI at
(d) five will show a disease symptom, while one will not
some instant of time are 0.1, 0.2 and 0.4,
respectively. If the equilibrium constant is 46 at the 80. In evolutionary terms, an Indian school boy is more
same temperature, then as the reaction proceeds closely related to
(a) the amount of HI will increase (a) an Indian frog
(b) the amount of HI will decrease (b) an American snake
(c) the amount ofH2 and 12 will increase (c) a Chinese horse
(d) the amount ofH2 and 12 will not change (d) an African shark
WWW.JEEBOOKS.INl
Answers
PART-/
1 (a) 2 (c) 3 (a) 4 (b) 5 (b) 6 (d) 7 (a) 8 (a) 9 (a) 10 (c)
11 (b) 12 (c) 13 (b) 14 (a) 15 (c) 16 (a) 17 (a) 18 (c) 19 (d) 20 (a)
21 (b) 22 (c) 23 (c) 24 (d) 25 (c) 26 (b) 27 (b) 28 (d) 29 (a) 30 (c)
31 (d) 32 (c) 33 (d) 34 (d) 35 (a) 36 (d) 37 (a) 38 (a) 39 (b) 40 (c)
41 (d) 42 (d) 43 (b) 44 (b) 45 (c) 46 (b) 47 (d) 48 (c) 49 (b) so (c)
51 (d) 52 (a) 53 (c) 54 (c) 55 (a) 56 (b) 57 (a) 58 (b) 59 (b) 60 (d)
PART-I/
61 (c) 62 (c) 63 (b) 64 (d) 65 (a) 66 (b) 67 (d) 68 (b) 69 (c) 70 (a)
71 (d) 72 (c) 73 (b) 74 (a) 75 (a) 76 (b) 77 (d) 78 (c) 79 (a) 80 (c)
Solutions
1 . (a) Given, All A,B,C,D are in the form of (at = b
(x - b)(x - c) (x - c)(x - a) (x + 1) = a
Now, squaring both sides, we get
2
x is largest when a is smallest.
:. In A, B, C, D
P(x) = + 2
(a - b)(a - c) (b - c)(b - a) �
+ (x - a)(x - b) ⇒ x + ---1:_2 + 2 = a2
2
. . . (i) 0< r < 4
(c - a)(c - b) x
1 + !_ is smallest
On cubing both sides, we get
:.
P(a) = l + 0 + 0 = l 17
P(b) = 0 + 1 + 0 = 1 (x + �) = x3 + j + 3(x + � ) = a 3
• • • (ii) Option (b) is correct.
6. (d) Given,
ABC is right angled triangle with B is 90°.
P(c) = 0 + 0 + l = l
On adding Eqs. (i) and (ii), we get
) ) + (x3 + : ) + 2 + 3(
P(x) is a polynomial of degree atmost 2
2 A
and also attains same value i.e. 1 for (x + 2
X+ �)
distinct values of x (i.e. a, b, c).
= a3 + a2
b + ( x3 + :2 ) + 2 + 3a = a3 + a2
to 1 for all R.
:. P(x) is an identity with only value equal
⇒
6
x3 + ---1:_2 = a3 + a - 3a - b - 2
(x - b)(x - c) (x - c)(x - a) 2
+ + ⇒
(a - b)(a - c) (b - c)(b - a) x
(x - a)(x - b) 1 4. (b) Given, I a - b l = 2, I b - cl = 3 and oo
g
(c - a)(c - b) l c -dl = 4
:. a - b = ± 2, b - c = ± 3 and c - d = ± 4
B D C
2. (c) Given, a + b = 81
2 2
AD is angle bisector of LA.
Possible value of (a - d) are AB BD
AC DC
2 2
⇒ x + y =121 ±9, ± 5, ± 3, ± 1 . ---
⇒ ax + by = 99
AB - CD = BD - AC
I a - di = 9, 5, 3, 1
2
Now, (a + b )(x2 + y2) = 81x 121 ⇒
5. (b) Given, 0 < r < 4
2
Sum of l a - d l = 9 + 5 + 3 + 1 = 18
a 2x2 + b2y2 + a 2y2 + b2x2 = 81x 121 . . . (i) Area of MDC = 10
and (ax + by) = 99 A = 5 ( 1+ � = 9 ⇒ 1 x AB - CD = 10
⇒ (ax + by)2 = 992
r 2
⇒ . . . (ii) ⇒ ( 1+ � r = � ⇒ 1 x BD - AC = 10
2
BD = �
On subtracting Eq. (i) from Eq. (ii), we get
AC
a 2y2 + b2x2 - 2axby = 0 B = ( l+ ; = ⇒
7r �
BD = [·: AC = 6]
⇒ (ay - bx)2 = 0 20
C = (1 + 2rt = � ⇒
⇒ ay - bx = 0 5 6
3 . (a) Given, x + _! = a and x2 + ---1:_ = b BD = 10
x3
D = (l + � = ⇒
X r � 3
WWW.JEEBOOKS.INl
AB 1 3. (b) We have, initial position of

7. (a) We know, 0 =
OB
1 0. (c) We have,
(5 12)3 -(253)3 - (259)3 frog = (0,0)
⇒ (5 12) + (-253)3 + (-259)3
3
(0 , 6)
Now, 512 - 253 - 259 = 0
We know that, a + b + c = O then 5 2nd
a3 + b3 + c3 = 3abc
(0 , 1 ) A(4, 3)
(512)3 - (253)3 - (259)3
From first figure, = 3(5 12)(-253)(-259) 5
AB = 21tr
1 st
= 3 . 512· 253- 259
OB = 13
0 (0, 0)
= 3 - 29 - l l x 23 x 7 x 37
l01t :. There are 6 distinct prime divisors.
1 1 . (b) Given, square base pyramid
21t(5) = 130 ⇒0 =
13
8. (a) MEE - JillDC is incomplete.
After 1st jump position of frog at (4 , 3).
At 2nd jump position of frog at (0,6).
A
°
At 3rd jump position of frog at (0,1).
90 -0 :. Minimum number of jumps required for
the frog to go from (0,0) to (0, 1) and each
distance is 5 units is 3.
12 C 1 4. (a) Digit 1 appears in 1, 10, 11, and
12 in hour.
0
:. The clock will show the incorrect time
°
between 1 - 2, 10 - 1 1, 1 1 - 12, 12- l day
0 90 ---B
B and night both incorrect time
X E(20--x) D The top layer = 13 balls
(8 x 60) = 480 min
AB ED
20 There are 18 layer completed.
Digit 1 appear in minutes 1, 10, 11, 12,
BE CD
- - - So, total number of balls 13, 14, 15, 16, 17, 18, 19, 21, 31, 41, 5 1
N = l32 + 142 + 152 + 162 + ... + 302
:. It will shows the incorrect time
12 20 - X- = 15 min
⇒ - - - N = (12 + 22 + 32 + 42 + ... + 302)
x 8
- (12 + 22 + 32 ••• 122) = 1 6 x 15
⇒ 96 = 20x - x2 30 x 3 1 x 61 _ 12 x 13 x 25
⇒ 2
x - 20x + 96 = 0 ⇒ N= = 240 min
6 6
⇒ (x - 12)(x - 8) = 0 Total incorrect time = 240 + 480
⇒ N = 5 x 3 1 x 6 1 - 2 x 13 x 25
⇒ X = 8, 12
= 720 min
= 9455- 650
Hence, x has two values 8 and 12 and Correct time = 24x 60 - 720
= 8805
their difference is 4. Fraction of correction time
9. (a) Given, radius of each circle = 1
8000 < N < 9000 24 x 60 - 720
1 2. (c) Let the total distance = x 24x 60
1
Muddy distance = �
6 2
Water distance = � - � =� 1 5. (c) Let the student answered correct
2 6 3
=X
d Tar distance = �
2 Student answer wrong = y
Speed travelling in mud = 3y Student unattempted = z
Speed travelling by stream = 4y According to the question,
x + y + z = 30, and 4x + z = 60
Speed travelling in tar = 5y
x/6 x/3 x/2 X = 15, y = 15, Z = 0
X = 14, y = 12, Z = 4
touch externally
0A = 0B = AB = 2
Ratio of time =
3y 4y 5y
: :
OD -
-- .-.-
1 . 1 . 1 X = 13, y = 9, Z = 8
X = 12, y = 6, Z = 12
ln 1'J..OAD, sin 60° =
OA 18 12 10
X = 1 1, y = 3, Z = 16
⇒ OD = 0A sin 60° = 2 x 3 = -J3
-J _ 10 . 15 . 18
- . .
2 180 180 180 X = 10, y = 0, Z = 20
:. d = 1 + OD + 1= 1 + -J3 + 1 =-J3 + 2 = 10 : 15 : 18 Total number of cases = 6
WWW.JEEBOOKS.INl
1 6. (a) Total length of a pendulum 1 9. (d) As there is no external force, 23. (c) As total internal reflection occurs
remains same, so extreme point D lies on centre of mass of a system remains at at angle of incidence, i = 45°.
the line AB, as shown below. same position.
Initially, °
I 45
I
I goo
I °
I
I 45
---------<
Box
_-::,7D--
I
l I
C� �
A - - - - - 1�_ B
This can be proved by applying energy

conservation between extreme positions ol l
So, using µ = __ , we have
A and D (its given friction is abscent), (20,0)
KA + UA = KB + UB = Kn + Un
sin C
= -1-° = -J2 or µ = 142
Position of centre of mass of a system
0 + UA =
0+ UB = 0+ Un
taking girl at origin is µ
sin 45
UA UB = Un ⇒ hA = hB = hn 24. (d) When a lens is cut into half or its
⇒
_ 36 X 0 + 9 X 20 _ 9 X 20
= XCM -
1 7. (a) Taking boy, toy and ground as a

⇒
36 + 9 45
half part is blackened, image is formed at
Finally, same place but its intensity is reduced.
25. (c) As material of rod is not changed,
composite system, we can say that there
is no external force acting on the system,
=0 =0
net acceleration of the system is zero. resistivity of both rods is same.
Asystem ⇒ (Fnet ) system
⇒ F + (mghoy + (N)ground + (/) friction = 0
Also, volume of material is same for both
1 8. (c) Let first ball reaches upto height

rods, so
H and it fells by a distance H - h, where A1 L = Ai2L)

Al � = A2�
or
upto height h.
IHt-h
it collided with second ball which rises (20,0) Al
⇒ A2 =
Position of centre of mass when girl and 2
( -\
I T Now, using R = p _l_, we have
box are at same position is
I _ (36 x x) + (9 x x) _ 36x + 9x A
1I 0
X'CM -
R2 = p� = 4( PL )
-
I I 36 + 9 45
I 0 _ 9 x 20 _ 36x + 9x
As, XCM - X'CM ⇒ - (A1 / 2) Al
4R
--- - -
⇒ 9 x 20 = 45x ⇒ x = 4 m
I 45 45
or R2 =
I
H
26. (b) As direction of fields of charges at
: : I
h So, girl travelled b y 4m, when she meet

with box. points A and B,
20. (a) Most likely each of the object is in EA
f-----'--'-
EA
�
Ea
+---
surroundings. So, T1 = T2 =
thermal equilibrium with its �Ea + Q � Ea - 2Q � EA
'fa .
21 . (b) Gas molecules move randomly
Equation of motion for first and second A B
ball, are in opposite directions to left of A or
H-h 'I. gt 2
and effect of gravity on them is
= . . . (i) right of B, so fields can be zero in these
1
insignificantly low. So, pressure exerted
h = ut - - gt 2
2 regions. But in right side of B, field
by gas molecules is same everywhere.
22. (c) To reach point Q, using Fermat's
. . . (ii) cannot be zero as EA is very smaller than
2
EB (charge at A is smaller magnitude and
u 2 l 2g = u
H = --
From Eqs. (i) and (ii), we have principle, girl must bend her path
H = ut or t = -
its distance from B is also large).
2g
towards normal as on beach velocity of
- - So, field can be zero in region left of A.
27. (b) Useful power
u u girl is more than her velocity at sea.
Substituting the value of t in Eq. (ii), we Q
w
have =
Work done by motor
h = u x - - - g x -2
2
u Time duration
2g 2
1 u
Sea C
=
u u g
4g ⇒ Pinput X rt -
h = - - -2 mgh
2 2 Beach M
2g 8g
t
⇒ Pinput X rt =
h=- -- = - - So, correct path is PCQ to reach in = = 0.4

2 2 2 2 p
2g 8g 8g
u u 4u - u 300 X 10 X 6
⇒ rt
4 x g = 4 • H l·: H = 2g J
Note Laws of refraction of light follows
shortest time. 60 X 750
or h = 3u 2 I 8g =
2
u7
from Fermat's principle.
3 u 3 r So, per cent efficiency is, rt = 40%
WWW.JEEBOOKS.INl
28. (d) Using Kirchhoffs junction rule, (i) values of l should range from O to n - 1 (c) OH
directions and magnitudes of currents (ii) values of m should range from -l to l I H+1H 2 o
are as, Clf:i CH2 C HCH2Clf:i + 12 /NaOH
Thus, the set that is not allowed for 3-pentanol
3A
p
electron in H- atom is No reaction
Q
6A 3A 1A n = 2, l = 2, m = - 1 It doesn't give positive iodoform test.
10A 4A The allowed set of quantum numbers for (d) Clf:i CH2CH2CH2CH2OH + 12 / NaOH
2A
H - atom having n = 2 will be 1-pentanol
6A H + /H 20 .
8A
l = O to 1 -----t no reaction
mz = - 1, 0, 1
34. (d) Average kinetic energy depends
It also give negative iodoform test.
39. (b) For first order reaction
4A 2A
Clearly, current in the portion PQ is from

upon the temperature and not on the
type of gases involved. k=
2.303
t
log (-a-)
a-x
Q to P is 6A. 3kT
29. (a) Decay scheme is as given below
For any gas, (K. E)avg = - - per molecule 0.693
2 also k =
t112
(-a-)
21 2
4 Pb - 1 4 A + 2oe The (K.E) avg of a deuterium molecule is
82 8 "= 1 " 7
same as that of hydrogen molecule. 2. 303
35. (a) t.H for this process = Cvt.T = 0
4 0.693 = log
21 o
82
X
2
+
4 He �
t112 t a-x
Following conservation of mass number (at constant temperature) According to question,
and atomic numbers, we have t.S for this process will be positive that is 0.693 = 2.303 log _ a_
Number of neutrons in X is t.S > 0, the randomness increases the t112 2 X 60 a / 16
N = A - Z = 2 10 - 82 = 128 molecules of gases A and B gets
⇒ t112 = 30 min
40. (c) In the process of roasting,
intermixed with each other, when the
and number of protons is 82.
30. (c) From ideal gas equation,
partition is removed.
sulphide ore is converted into an oxide
Thus, the correct option is (a).
36. (d) The thermal decomposition of
pV ore with a regular supply of air in a
p V = nRT ⇒ p V = NkB T or N =
kB T furnace at a temperature below the
(NH4 )2 Cr2O7 gives chromium oxide melting point of the metal.
Substituting given values, we get (Cr2O3 ), nitrogen gas and water.
105 X 100
Thus, the conversion of sulphide ore into
⇒ N = ------- (NH4 )2 Cr2O7 ---t Cr2O3 + N2 + 4H2O metal oxide is given the reaction
37. (a) From the graph it can be seen
23
138 X 10- X 273 ZnS ---t ZnO, hence option (c) is correct.
4 1 . (d) The structures of given
27
N = 3 x 10 molecules
3 1 . (d) Since the pressure of the helium
⇒
that solubility of KNO3 in water at 40°C
is approximately 200 g per 100 of water. compounds can be drawn as follows :
gas in both the balloons A and B are
:.Amount of KNO3 that dissolve (or 0 0 0
same. Therefore, the final pressure of He
will not change. Hence, the correct option
solubility) in 50 g of water will II II II
200 p p
"-
H/ I OH ,
/ "-
HO I H ,
"-
32. (c) The electron releasing groups

is (d). = X 50= 100 g
100 HO/ 1 oH
38. (a) Iodoform test with sodium
H OH OH
attached to benzene increases the H3 P02 H3 P03 H3 P0
4
reactivity towards Friedel-Crafts hypoiodite is used for the detection of
Thus, the number of P- H bond(s) in
alkylation whereas the electron Clf:i CO group or Clf:i CH(OH) group
If:i PO 2 , If:i PO3 and If:i PO4 respectively
withdrawing groups decreases the which produces Clf:i CO group on
are 2, 1, 0.
42. (d) When chlorine gas is passed
reactivity. oxidation.
Among the given groups,-NO 2 and Iodoform reaction with the given
COOCif:i are electron withdrawing group compounds are as follows : through an aqueous solution of KBr, the
where NO2 shows stronger -I effect than

EWG, so they will decrease the reactivity solution turns orange brown due to the
(a) Clf:i-CH2- CH2- C- Clf:i + Lj
II NaOH evolution of bromine gas. The equation
COOCif:i . So, the reactivity of 0 for the above reaction can be written as
nitrobenzene towards Friedel-Craft 2,.pentanone
alkylation will be least. OCif:i is an H /H 20

+ Cl 2 + 2KBr ---t 2KC1 + Br2 t
+ Orange brown
43. (b) The conditions for a compound to

electron donating group, so it will -----t Clf:i CH2CH2COOH CHL3
Butanoic acid Iodoform
increasing the reactivity.
If gives positive iodoform test due to the be aromatic are
Thus, the order of reactivity towards
presence of Clf:i CO group. (i) the molecule should be planar.
Friedel-Craft alkylation is
(iv) > (ii) > (iii) > (i)
(b) Clf:i-CH2- C-CH2- Clf:i + 1/NaOH (ii) it should be cyclic with alternate
33. (d) For any set of principal (n),

II
0
single and double bonds.
3-pentanone H + /H 0
azimuthal (l) and magnetic (m;) quantum 2 . (iii) it should follows Huckel's rule, i.e.
� no react10n
numbers, the conditions that are allowed should have (4n + 2) 1t electrons.
It gives negative iodoform test.
for an electron is
WWW.JEEBOOKS.INl
1t electrons present in given compounds This reaction involves SN 2 mechanism Total lung capacity refers to the total
are as follows where CN - is substituted over c1- as it is amount of air in the lungs after taking
H a good leaving group as compared to Br
0
the deepest breath possible.
and I, and occurs at a primary carbon
52. (a) A normal human inherits only
(sp3 -hybridised).
46. (b) Attached earlobes is an autosomal
(i) one sex chromosome (either X or Y
(4n+2)1t electrons = 61t electrons
chromosome) from father. Sex
recessive trait. Thus, a heterozygous chromosomes, determine whether an
:. Follows Huckel's rule parent with free earlobes will have individual is male or female. In human
offspring with attached earlobes.
(ii) � (4n +2)1t electrons
and other mammals these are designated
CY Free earlobes Free earlobes by scientists as X and Y. In humans, the
� = 81t electrons Aa x Aa <;> Parents
sex chromosomes comprise one pair of the
�
Doesn't follow Huckel's rule. total of 23 pairs of chromosomes. The
other 22 pairs of chromosomes are called
AA Aa Aa aa
autosomes.
53. (c) Scurvy is a result of the deficiency
(iii) � (4n+2)1t electrons L__J Offsprings
�-- Free earlobes Attached
= 1 07t electrons earlobes
of vitamin-C. Vitamin-C is mainly found
Follows Huckel's rule. 47. (d) For a complete meiotic cell
in fruits such as oranges, grapefruit,
division, there takes place one round of
0
(4n +2)1t electrons DNA replication during the S-phase and lemons, strawberries and melons or it is
(iv) (_) found in vegetables such as broccoli and
= 61t electrons two divisions. This is because meiosis is a
process where a single cell divides twice bell peppers. Therefore, malnutrition
Follows Huckel's rule. to produce four cells containing half the causes vitamin-C deficiency. Protein
original amount of genetic information. deficiency malnutrition is known as
48. (c) Blood clotting involves the
Thus, compound (ii) is not aromatic.
44. (b) The IUPAC nomenclature of the
kwashiorkor and marasmus. Vitamin-D
conversion of fibrinogen to fibrin. The deficiency causes rickets. Carbohydrates
structures given in the options are as
blood clotting mechanism takes place as deficiency causes weakness, nausea,
follows
dehydration, etc.
Hi 54. (c) Centriole is not found in plant
2 follows
Injury in blood vessels
(i) CH3 - 3, 4-dimethyl cells, it is found only in animal cells.
hexane Platelets clump at the wound These paired organelles are typically
6
H 3C CH3 located together near the nucleus in the
Platelets release thrombokinase centrosome, a granular mass that serves
5
4 as an organising centre for microtubules.
J
H 3� 1 - 2 3-dimethyl Thrombin E 1 Prothrombin Centriole is involved in the development
(ii) >r 3 CH3 Thrombokinase
2 h�xane � of spindle fibres in cell division.
Vitamin - K
H3C / \ 55. (a) The brain and spinal cord are
Fibrin Fibrinogen
made up of many cells, including neurons
l
1 CH3
H3C and glial cells. Neurons are cells that
Clot forms to prevent send and receive electro-chemical signals
49. (b) The gall bladder is involved in

(iii) - 3, 4-dimethyl further blood loss for pain or pleasure to and from the brain
�6
hexane and nervous system.
H 3C CH 3
storing and secreting bile. The gall • Blastocyst is a structure formed in the
CH3 bladder is a pear-shaped, hollow early development of mammals. It
structure located under the liver and on possesses an Inner Cell Mass (ICM)
CH3 �
the right side of the abdomen. Its which subsequently forms the embryo.
(iv) �H3 - 2, 4-dimethyl
hexane primary function is to store and • Histoblast is a cell or cell group
H3C 1 2 3 4 5 6
concentrate bile, a yellow brown digestive possessing broad histogenetic capacity,
Hence, the correct option is (b).
45. (c)
enzyme produced by the liver.
50. (c) Green light is not at all useful for
i.e. capable of forming tissue.
• Haemocyte is a cell of the haemolymph
photosynthesis. This is because, plant of various invertebrates, especially
reflects green light and due to this same arthropods.
reason, plants appear green in colour. 56. (b) Benedict's test is used to detect
51 . (d) Tidal volume is the volume of reducing sugars such as glucose. Sucrose
inspired/expired air moving in and out of is a non-reducing sugar, it gives negative
the lungs with each breath. result for Benedict's test. Benedict's
Vital capacity is the volume that can be reagent is a complex mixture of sodium
inspired/expired after full carbonate, sodium citrate and copper (II)
expiration/inspiration. sulphate petahydrate.
WWW.JEEBOOKS.INl
57. (a) Iodine is found in thyroxine. /(x) = 2x2 - 5x + 3 12 1 V 1th I (605) 2 + 6O5OOr + (1 00r)2 l
⇒ =
Thyroxine, also called / (50) = 2(50)2 - 5(50) + 3 1 00 3l (1 00)2 J
3, 5, 3' , 5'-tetraiodothyronine or T4, is one = 5000 - 250 + 3 = 4753
of the two major hormones secreted by Now, lOOOt < /(50) < lOOO(t + 1) ⇒
12 1
x 1th (25 + 5r + r 2)
the thyroid gland (the other is 1 00 3
lOOOt < 4 753 < lOOO(t + 1)
triiodothyronine). Thyroxine's principal ⇒ t < 4753 < t + l =
1th (605) 2 + 6O5OOr + (1 0Or) 2
[ ]
function is to stimulate the consumption 3 1 0000
:. t = 4 , t is integer.
of oxygen and thus the metabolism of all
cells and tissues in the body. Thyroxine is 62. (c) Let ⇒ 1 00(3025 + 6O5r + 1 2 lr 2)
22 + 1 32 + 1 42 + 1 (20 1 1)2 + 1 = 366025 + 6O5OOr + (1 0Or) 2
formed by the molecular addition of S = 2 + 2 + 2 + ... +
iodine to the amino acid tyrosine while 2 -1 3 -1 4 -1 (20 1 1)2 - 1 ⇒ l OO x 1 2 1r 2 - 1 0OOOr 2
the latter is bound to the protein
Here, Tr = -r +1
2 = 366025 - 302500
thyroglobulin. .,
58. (b) Lactometer is a device used for
r· - 1 ⇒ 2 10Or 2 = 63525
r2 - 1 + 2
63525 =
Tr =
⇒ r2 = 30.25
testing the purity of milk. It measures ⇒ 2 1 00
,. '!.
relative density of milk with respect to -1 r = ✓30.25 = 5.5 cm = 55 mm
⇒
64. (d) Let the speed of B = x km/h
water, which is also called specific 2 2
= 1 + -- = 1 +
gravity. If the specific gravity of a sample 2 (r - l)(r + 1)
r -1
of milk is within the approved ranges, the and the speed of A = 3x km/h
milk is pure. If it is not, then there is 1 1
⇒ Tr = l + - - - - - Distance between A and B = 30 km
some adulteration in milk. r -1 r + 1
59. (b) When mammalian liver cells are 2011 Given, distance between them decrease
⇒ S = I, Tr at 2 km per minutes.
kept in a hypotonic solution, endosmosis
occurs as the cell is hypertonic. Due to r=2 :. Distance decrease in one hour
2011 r
the endosmosis, the cellular protoplasm 1 1 1 = 2 x 60 = 1 20 km
= l+ -
is filled with water, it swells and the cells �l r - 1 r + 1J :. Total distance travelled by A and B in
become turgid. Swelling is seen because
⇒ S = T2 + 'fa + T4 + ··· + T201 1
one hour = (x + 3x) km = 4x km
the water flows from lower concentration 1 20
:. Speed = - = 30 km/h
of solute to the higher concentration of ⇒ S = ( 1 + { - ½) + ( l + i - 1 ) 4
solute. Hence, speed of B = 30 km/h
60. (d) Carcinoma is a category of types
( 1 + _1_ _ _1_ ) + ... + ( 1 + __ - __ )
1 1
+ Speed of A = 90 km/h
of cancer that develops from epithelial 3 5 20 1 0 20 1 2 Distance travelled by A and B after
cells. Lymphoma is the cancer that occurs
in lymph cells. Leukemia is blood cancer ⇒ S = 2O 1 0 + 1 + _l_ _ _ l
_ -- 1
- 1 0 min = 2 x 1 0 = 20 km
2 20 1 2 20 1 1 So, remaining distance = (30 - 20) = 1 0 km
Time taken by B to distance travelled
that originates in the blood and bone
G�
1 1
marrow. Mesoderm is one of the germ ⇒ S = 2O 1 1 + _1_ - [-- + --]
layer from which skeletal muscle, bone, 2 20 1 1 20 1 2
1 0 km = x 60) = 20 min
connective tissue, heart and the ⇒ S is lie between ( 20 1 1, 20 1 1 }
urogenital system originate. i
6 1 . (c) We have, 63. (b) Given,
Total time taken by A = 20 + 1 0 = 30 min
65. (a) Taps A,B,C fill up a tank
2
/(x) = ax + bx + c, a, b, c,E Z Diameter of base = 1 00 mm independently 10 h, 20 h, 30 h,
Also /(1) = 0, 40 < /(6) < 50, 60 < /(7) < 70 l OO respectively.
:. Radius of base = mm = 50mm = 5 cm
:. a + b + c = O, 40 < 36a + 6b + c < 50, Given, exactly one pairs of taps is open
c=-a- b
Let other radius of base = r during each hour and every pairs of taps
And height of truncated cone = h
60 < 49a + 7b + c < 70
. . . (i)
is open at least one hour.
B and C and then C and A

40 < 36a + 6b - a - b < 50 Volume of initially truncated cone = V First A and B are open for one hour, then
V = 1th {(5)2 + 5r + r 2}
:.(i�
and 60 < 49a + 7b - a - b < 70 1
3 1 1 1
⇒ 40 < 35a + 5b < 50 + ) + CO + 30 ) + ( 30 + 1� )
When radius increase by 2 1 % 20
and 60 < 48a + 6b < 70 12 + 6 + 4
:. Radius of base = 5 + � x 5 = 605
1 1 1
=- + - + - = - - -
7
⇒ 8 < 7a + b < l O and 1 0 < Sa + b < o 1 00 1 00 5 10 1 5 60
Now, a and b are integer

When volume increase by 2 1 % 22 1 1
-- - -
2 1 V = 12 1 V 60 30
7a + b = 9 and 8a + b = 1 1 Then, vi = V +
1 00 In three hours the tank will be filled
1 00
O n solving these equation, we get 2
Now, vi = 1th 605 605 2 ( �� ) th part. Now, for minimum time,
a = 2, b = - 5 [ ( ) + 1 00 r + r ]
3 100
[·: r and h are same]
Put the value of a, b in Eq (i), we get the rest of tank must be filled with A and
c= 3 B taps.
WWW.JEEBOOKS.INl
1 1 30 Now, by gas equation, we have These are as follows :

n1 + n2 = n
( + )
G�)
10 20 = 20 As, CH 2 = C = CH - CH 3 , CH 3 CH 2 C = CH,
So, the rest of ( 1 - �� ) th = th part V 4V x- 0.5 = --
5V x A
--=---'- CH 3 - C = C - CH 3 ,
⇒ -+ -
RT RT RT CH 2 = CH - CH = CH 2
of tank will taks 5 h more. ⇒ p = 0.6 atm
So, the tank will be filled in 8 h. 69. (c) Ray diagram for pool is as shown
66. (b) For equilibrium of block hung below.
73. (b) In the first sequence of reaction,
from string,
Spring force + Buoyant force = Weight of an alkene is getting converted into epoxy
block
group, so an oxidising agent is required
both Hp2 and C6If;; COOR are oxidising
1�
h agent but C6If;; COOR is used as they are
not very sensitive to solvent polarity
while, in 2nd sequence of reaction, the
� x/2 ➔
Using n1 · sin i = n2 · sin r, we have
epoxy group is being reduced into an
i sin r
So, we have alcoholic group, thus a reducing agent is
k:ri + p1Vg = p Vg . . . (i) 1 x sin (90° - 0) = . . . (i) required. Thus, the suitable reagents are
3
A
and . . . (ii)
Also, X
tan r = - =-
4 2
-=- c��H )j__O
o
Eliminating k, we get 2h 7 x 2 7 ;\
- 2
p = P1 -½ Pri . r = -- (Peroxide attack) (Epoxy group)
⇒ s1n
-
,½ Xi ,,/53
COS 0 = i X -- = -
67. (d) By work-kinetic energy theorem,
LiAJH4 1Reduction
Substituting sin r in Eq. (i), we have
2 8 ->-OH
work done is equal to change in kinetic -
3 ,,/53 3,,/53
70. (a) From given circuit, if i = circuit
energy.
r Fdx = M
74. (a) The magnetic character of the
Jx = 4
x= 8
So, given complexes are as follows :
current, then
10 (i) Co(NH 3 )6 ]
3+
F V = iReq ⇒ i = = 2.5A
4 Oxidation state of Co in [Co(NHa )6 ] 3+ is
So, power dissipated by circuit is +3.
P = i 2R = (2.5) 2 x 1= 25 W The electronic configuration of Co3 + is
□
4 3d 6 4so .
When lQ resistor is replaced by a 9Q 3d 4s 4p
_,__ _-+--
4
-+--+-➔X
8 10
resistor, then power dissipated in 9 Q
resistor is 1 1 1 1 1 1 1 1 1 1 1 I I
⇒ Area under force-displacement graph
from x = 4 to x = 8= -1 m (v12 - V;2)
As NH3 is a strong field ligand, paring of
electrons occur
2
So, P' = P
[Co(NH3)5] 3+ 3d
I (3 - 15) x (8 - 4) = I x I
B
⇒ 4s 4p
71 . (d) Meq of CH3COOH = 100 x 0. 1 = 10

2 2 2 l 1l l 1 l l 1 l lx xlx xl lx xlx xlx xl
X (vJ - (3. 16) 2)
hybridised
d2sp3
⇒ Meq of CH3 COONa = 50 x 0.2 = 10
68. (b) Given situation is
Thus, the complex is diamagnetic.
According to Henderson equation
[salt] (ii) [Ni(NH 3 )6 ] 2+
pH = pKa + log
[acid] Oxidation state of Ni in [Ni (NIia ) 6 ]2+ is
p = 1 �m �- ��- � p = � 5 �m
pH = pKa +
V 4V log [CH3 COO-] +2.
T T log [Clfs COOH] The electronic configuration for Ni 2 + is
10 3d s 4so .
Let final temperature after opening the pH = 4.76 + log -
10 3d
valve is T1 , then d Wext = 0 and dQext = 0
pH = 4.76+ log 1
So, from first law of thermodynamics, I 1l I 1l I 1 l I 1 1 1 I
⇒ pH = 4.76
72. (c) Nine structure isomers are
dU = 0 4s 4p 5d
⇒ n1CvT + n2CvT = (ni + n2) CvTr
⇒
possible for the hydrocarbon having
molecular formula C4 H 6 •
I I I .__
I .__IL........Jl'--L........J
WWW.JEEBOOKS.INl
Though NH 3 is a strong ligand pairing As Hp is a weak field ligand, pairing of ears, etc. are some examples o f vestigial
will not occur because, if pairing would electrons will not occur and thus the organs in human body.
occur then also 2,d-orbitals will not be complex will be paramagnetic. 78. (c) Gregor Mendel studied
available for hybridisation. 75. (a) For the reaction,
= 46]
inheritance of traits in pea plants. In a
3d
I 1l I 1l I 1l I 1 1 1 I
H 2 (g) + l 2 (g) � 2HI(g) [Kc monohybrid cross, the recessive trait
[Ni(NH3)5] 2+
[HI]2 disappears in the first filial generation.
Qc = - The traits that were visible in the
4s 4p 5d
[H2] [l2]
� Ix xix xix xi Ix xix xi I QC = 0.4 X 0.4 ⇒ QC = 8
F1 -generation are referred to as dominant
traits. This happens because recessive
0.1 X 0.2
sp3d2 allele does not express itself in the
As Qc < Kc presence of dominant allele.
79. (a) An individual gets one sex
Thus, the complex is paramagnetic.
3+ So, the reaction will proceeds in forward
(iii) [Cr(Hp)6 ]
3+ direction. Hence, amount of HI increases.
76. (b) Tobacco is a dicot plant, thus its
Oxidation state of Cr in [Cr (H20 6 )] is chromosome from each parent during
+ 3. fertilisation.
3+ leaves have more number of stomata on
The electronic configuration of Cr is 'i' XX 'Xi �
[Ar] 3d3 4s0 . its lower surface. If you cover the leaves
of a healthy plant with vaseline, it will
[Cr(H2O) 6] 3 + �'X'(
block its stomata and therefore it will not
3d 4s
Girl Boy Girl Boy
I 1 I 1 I 1 lxxlx xl
lose water through transpiration, so the
We see from the above cross that sons get
upward movement of the water in the
� their Y-chromosome from father and
plant will stop. This will not allow the
X-chromosome from mother.
d2sp3 plant to wilt quickly.
As Hp is a weak field ligand pairing of The leaf '2' is smeared with vaseline on Therefore, if a man with an X-linked
electrons will not occur and the complex the upper surface, so the plant will lose dominant disease has six sons with a
is paramagnetic. water from the lower surface and in leaf woman having a normal complement of
2+ '3', vaseline is smeared on the lower genes, their sons will show no symptom
(iv) [Fe(HP) 6 ]
80. (c) In evolutionary terms, an Indian

surface therefore the water is lost from of the disease.
Oxidation state of Fe in [Fe (H20 6 )]2+ is
the upper surface. But the number of
+ 2.
stomata are more on the lower surface school boy is more closely related to
The electronic configuration ofFe 2 + is
[Ar] 3d 6 4s0 •
therefore leaf '2' will wilt more quickly Chinese horse. Human and horse
than leaf '3'.
77. (d) Vestigial organs are those organs
irrespective of their country are more
3d generally similar in their chromosomal
which are no longer in use. They were management, than to rest of the species
used to play an important role in our mentioned here. This is because human
4s 5d and horse both belong to class
ancestors, but as and when we developed
� and evolved, some of these organs lost Mammalia. Other options like frog, snake
their functionality but managed to stay and shark belong to class- Amphibia,
in our body. Appendix, coccyx, external Reptilia and Chondrichthyes.
WWW.JEEBOOKS.INl
KVPY
Stream :SA
M M : 100
Instructions

MATHEMATICS 5. The sides of a L1ABC are positive integers. The
smallest side has length 1. Which of the following
1. A student notices that the roots of the equation
statements is true?
(a) The area of MBC is always a rational number
:x? + bx + a = 0 are each 1 less than the roots of the
equation :x? + ax + b = 0. Then, a + b is (b) The area of MBC is always an irrational number
(a) possibly any real number (b) -2 (c) The perimeter of MBC is an even integer
any of the statements A, B or C above

(c) -4 (d) -5 (d) The information provided is not sufficient to conclude
2. Ifx, y are real numbers such that
3(x/ y) + 1 _ 3(x/ y) - 1 = 24, 6. Consider a square ABCD of side 12 and let M, N be
the midpoints of AB, CD respectively. Take a point P
on MN and let AP = r, PC = s. Then, the area of the
then the value of (x + y)l(x - y) is
wo �1 �2 00 3 triangle whose sides are r, s,12 is
3. The number of positive integers n in the set {1, 2, 3, (a) 72 (b) 36 (c) "0. (d) "0.
. . . . . . . . . , 100} for which the number 2 4
12 + 2 2 + 3 2 + ..... + n2 . 7. A cow is tied to a corner (vertex) of a regular
- - - - - - - - 1s an integer is
1 + 2 + 3 +.... + n hexagonal fenced area of side a m by a rope of length
5a
m in a grass field. (The cow cannot graze inside
2
(a) 33 (b) 34 (c) 50 (d) 100
4. The three different face diagonals of a cuboid the fenced area). What is the maximum possible area
(rectangular parallelopiped) have lengths 39, 40, 41. of the grass field to which the cow has access to
The length of the main diagonal of the cuboid which graze?
joins a pair of opposite corners is
(a) 51ta2 (c) 61ta2 (d) 31ta2
(a) 49 (b) 4W2 (c) 60 (d) 6W2
WWW.JEEBOOKS.INl
8. A closed conical vessel is filled with water fully and is 13. A soldier with a machine gun, falling from an
placed with its vertex down. The water is let out at a airplane gets detached from his parachute. He is able
constant speed. After 21 min, it was found that the to resist the downward acceleration, if he shoots 40
height of the water column is half of the original bullets a second at the speed of 500 m/s. If the weight
height. How much more time in minutes does it of a bullet is 49 g, what is the weight of the man
require to empty the vessel? with the gun ? Ignore resistance due to air and
(a) 21 (b) 14 (c) 7 (d) 3 assume the acceleration due to gravity, g = 9.8 ms-2 •
9. I carried 1000 kg of watermelon in summer by train. (a) 50 kg (b) 75 kg (c) 100 kg (d) 125 kg
In the beginning the water content was 99%. By the 14. A planet of mass is moving around a star of mass M
time I reached the destination, the water content had and radius R in a circular orbit of radius r. The star
dropped to 98%. The reduction in the weight of the abruptly shrinks to half its radius without any loss of
watermelon was mass. What change will be there in the orbit ofthe
(a) 10 kg (b) 50 kg (c) 100 kg (d) 500 kg planet?
10. A rectangle is divided into 16 sub-rectangles as in the (a) The planet will escape from the star
figure, the number in each sub-rectangle represents (b) The radius of the orbit will increase
the area of that sub-rectangle. What is the area of (c) The radius of the orbit will decrease
the rectangle KLMN ? (d) The radius of the orbit will not change
which P, Q, R and S are fixed resistances, G is a

10 4 15. Figure (i) below shows a Wheatstone's bridge in
galvanometer and B is a battery. For this particular

case, the galvanometer shows zero deflection. Now,
only the positions ofB and G are interchanged, as
N M 12 15
25 shown in figure (ii). The new deflection of the

galvanometer
K L
(a) 20 (b) 30 (c) 40 (d) 50
PHYSICS
11. A hollow pendulum bob filled with water has a small
hole at the bottom through which water escapes at a
describes the variation of the time period T of the

constant rate. Which of the following statements
I I,___�
pendulum as the water flows out?
�--1
B
(a) T decreases first and then increases Figure (i) Figure (ii)
(b) T increases first and then decreases
(c) T increases throughout (a) is to the left
(d) T does not change (b) is to the right
(c) is zero
12. A block of mass M rests on a rough horizontal table. (d) depends on the values of P,Q,R and S
A steadily increasing horizontal force is applied such
that the block starts to slide on the table without 16. 12 positive charges of magnitude q are placed on a
toppling. The force is continued even after sliding has circle of radius R in a manner that they are equally
started. Assume the coefficients of static and kinetic spaced. A charge Q is placed at the centre, if one of
friction between the table and the block to be equal. the charges q is removed, then the force on Q is
frictional force f, exerted by the table on the block

The correct representation of the variation of the (a) zero
(b) ____<J_(}___2 away from the position of the removed charge
with time t is given by 41te0R
I (c) l lq Q2 away from the position of the removed charge
L
(b ) 41te0R
(a/�
(d) ____<J_(}___2 towards the position of the removed charge
41te0R
(0, 0) t
I
(0, 0) t
17. An electric heater consists of a nichrome coil and runs
under 220 V, consuming 1 kW power. Part of its coil
L
(d) burned out and it was reconnected after cutting off
(cl= the burnt portion.The power it will cunsume now is
�
t
(a) more than 1 kW (b) less than 1 kW, but not zero
(0, 0) (0, 0)
(c) 1 kW (d) 0 kW
WWW.JEEBOOKS.INl
1 8. White light is split into a spectrum by a prism and it 25. Among NHa , BC½ , Cl2 and N2 , the compound that
is seen on a screen. If we put another identical does not satisfy the octet rule is
inverted prism behind it in contact, what will be seen (a) NH.i (b) BC13 (c) Cl2 (d) N2
on the screen ? 26. The gas produced on heating MnO2 with cone. HCl is
(a) Violet will appear where red was
(b) The spectrum will remains same
(a) Cl 2 (b) H2 (c) 0 2 (d) 03
(c) There will be no spectrum, but only the original light 27. The number of covalent bonds in C 4H7Br, is
with no deviation (a) 12 (b) 10 (c) 13 (d) 11
(d) There will be no spectrum, but the original light will
be laterally displaced 28. An aqueous solution of HCl has a pH of 2.0. When
water is added to increase the pH to 5.0, the
1 9. Two identical blocks of metal are at 20° C and 80°C, hydrogen ion concentration
respectively. The specific heat of the material of the (a) remains the same (b) decreases three-fold
two blocks increases with temperature. Which of the (c) increases three-fold (d) decreases thousand-fold
following is true about the final temperature Tr when
the two blocks are brought into contact (assuming 29. Consider two sealed jars of equal volume. One
that no heat is lost to the surroundings)? contains 2 g of hydrogen at 200 K and the other
(a) Tr will be 50°C contains 28 g of nitrogen at 400 K. The gases in the
(b) Tr will be more than 50° C two jars will have
(c) Tr will be less than 50°C (a) the same pressure
(d) Tr can be either more than or less than 50° C (b) the same average kinetic energy
depending on the precise variation of the specific heat (c) the same number of molecules
with temperature (d) the same average molecular speed
20. A new temperature scale uses X as a unit of 30. Identify the stereoisomeric pair from the following
temperature, where the numerical value of the choices.
temperature T by tx = 3T + 100. If the specific heat of

temperature tx in this scale is related to the absolute (a) CH 3 CH2 CH2OH and CH 3 CHpCH3
H
(b) CH 3 CH 2 CH 2 Cl and CH 3 CHC1CH 3
I
a material using this unit is 1400 J kg-1K -1 , its
6CH
specific heat in the SI system of units is (c) CH3 -C = C-CH3 and Clfs -C - C -CH3
(a) 4200 J kg-1 K-1 I I I
(b) 1400 J kg-1 K-1 H H H
=d
(c) 466. 7 J kg-1 K-1
(d) impossible to determine from the information provided ,
CHEMISTRY (d) O
BIOLOGY
2 1 . The boiling point of 0.01 M aqueous solutions of
sucrose, NaCl and CaC12 would be
(a) the same (b) highest for sucrose solution
3 1 . Which of the following is a water borne disease?
(c) highest for NaCl solution (d) highest for CaC12 solution (a) Tuberculosis (b) Malaria
22. The correct electronic configuration for the ground (c) Chicken pox (d) Cholera
state of silicon (atomic number = 14) is 32. In his seminal work on genetics, Gregor Mendel
2 2 2 2 2 2 4
(a) 1s 2s 2p 6 3s 3p (b) 1s 2s 2p 6 3p described the physical traits in the pea plant as being
(c) 1s 2s 2p 3s 3p 4
2 2 4 2
(d) 1s2 2s2 2p 6 3s1 3p5 controlled by two 'factors'. What term is used to
23. The molar mass ofCaCO3 is 100 g. The maximum define these factors today?
amount of carbon dioxide that can be liberated on (a) Chromosomes (b) Genes
heating 25 g of CaCO3 is (c) Alleles (d) Hybrids
(a) 11 g (b) 5.5 g 33. A majority of the tree species of peninsular Indian
(c) 22 g (d) 2.2 g origin fruit in the months of
(a) April-May (b) August-September
24. The atomic radii of the elements across the second
period of the periodic table (c) December-January (d) All months of the year
(a) decrease due to increase in atomic number 34. In frogs, body proportions do not change with their
(b) decrease due to increase in effective nuclear charge growth. A frog that is twice as long as another will be
(c) decrease due to increase in atomic weights heavier by approximately
(d) increase due to increase in the effective nuclear charge (a) two-fold (b) four-fold (c) six-fold (d) eight-fold
WWW.JEEBOOKS.INl
35. Which of the following has the widest angle of (b )bacterial metabolism inside the dung releases heat
binocular vision? (c) undigested material releases heat due to oxidation by
(a) Rat (b) Duck (c) Eagle (d) Owl air
(d) dung is dark and absorbs a lot of heat
36. The two alleles of a locus which an offspring receives
from the male and female gametes are situated on 39. Which one of these is the correct path for a reflex
(a) two different homologs of the same chromosome action?
(b) two different chromosomes (a) Receptor ➔ Motor neuron➔ Spinal cord ➔ Sensory
(c) sex chromosomes neuron➔ Effector
(d) a single chromosome (b) Effector➔ Sensory neuron➔ Spinal cord ➔ Motor
neuron➔ Receptor
37. Ants locate sucrose by (c) Receptor➔ Sensory neuron➔ Spinal cord➔ Motor
(a) using a strong sense of smell neuron➔ Effector
(b) using a keen sense of vision (d) Sensory neuron ➔ Receptor➔ Motor neuron➔ Spinal
(c) physical contact with sucrose cord➔ Effector
(d) sensing the particular wavelength of light 40. Insectivorous plants digest insects to get an essential
emitted/reflected by sucrose nutrient. Other plants generally get this nutrient
38. The interior of a cow dung pile kept for a few days is from the soil. What is this nutrient?
quite warm. This is mostly because (a) Oxygen (b) Nitrogen
(a) cellulose present in the dung is a good insulator (c) Carbon dioxide (d) Phosphates

MATHEMATICS
1. In a L1ABC, D and E are points on AB, AC
respectively such that DE is parallel to BC. Suppose
BE, CD intersect of O. If the areas of the triangles
area of the L1ABC, with justification.

ADE and ODE are 3 and 1 respectively. Find the
E tJJ
2. Leela and Madan pooled their music CD's and sold
them. They got as many rupees for each CD as the
total number of CD's they sold. They share the
money as follows: Leela first takes 10 rupees, then ��
1--------------
Madan takes 10 rupees and they continue taking 10

rupees alternately till Madan is left out with less
Ohm's law Rest = .!'::, where V and J are the readings
In each case, the resistance is estimated by using
I
than 10 rupees to take. Find the amount that is left
out for Madan at the end, with justification.
3. (a) Show that for every natural number n of the voltmeter and the ammeter, respectively. The
relatively prime to 10, there is another natural meter resistances Ry and RA are such that
number m all of whose digits are l's such that RA << R << Ry . The internal resistance of the battery
n divides m. may be ignored. The absolute error in the estimate of
the resistance is denoted by oR = I R - Rest I.
(b) Hence or otherwise show that every positive (a) Express oRp in terms of the given resistance values.
rational number can be expressed in the form
for some natural numbers a, b, c.
(b) Express o� in terms of the given resistance values.
10 b(lOC - 1)
a (c) For what value of R will oRp = o�?
5. A point source is placed 20 cm to the left of a concave
PHYSICS
lens of focal length 10 cm.
(a) Where is the image formed?
4. Consider the two circuits P and Q shown below,

(b) Where to the right of the lens would you place a
concave mirror of focal length 5 cm, so that the final
which are used to measure the unknown resistance image is coincident with the source?
(c) Where would the final image be formed, if the concave
R. mirror is replaced by a plane mirror at the same
position?
WWW.JEEBOOKS.INl
6. A block of mass m is sliding on a fixed frictionless C02H
V
� CH s �
point P which is at a height of H << R from the lowest
concave surface of radius R It is released from rest at
point Q.
V III
NH2
N
The following observations were made.
(i) The compound in the bottle A did not dissolve
in either 1 N NaOH or 1 N HCL
(ii) The compound in the bottle B dissolved in
1 N NaOH but not in 1 N HCL
(iii) The compound in the bottle C dissolved in both
1 N NaOH and 1 N HCL
(iv) The compound in the bottle D did not dissolve
Q
(Fill up the blanks)

in 1 N NaOH but dissolved in 1 N HCL
(a) What is the potential energy as a function of0, taking
(a) Indicate the compounds in : bottle A = ...... , bottle B =
the lowest point Q as the reference level for potential
energy?
(b) What is the kinetic energy as a function of0? ...... , bottle C = ...... and bottle D = ...... .
point P to the lowest point Q?

(c) What is the time takes for the particle to reach from (b) The compound with the highest solubility in distilled
(Indicate the answers by the compound

water is ...... .
surface at the point Q? numbers)
(d) How much force is exerted by the block on the concave
CHEMISTRY
9. Assume that a human body requires 2500 kcal of
energy each day for metabolic activity and sucrose is
the only source of energy, as per the equation
7. Copper in an alloy is estimated by dissolving in cone. C12 H22 C\ 1 (s) + 12 Oig) -----+ 12 COig) + 1 1H2 0(l);
nitric acid. In this process, copper is converted to
1',.H = - 5.6 x 106 J.
cupric nitrate with the evolution of nitric oxide (NO).
The mixture when treated with potassium iodide
forms cupric iodide, which is unstable and (a) The energy requirement of the human body per day is
decomposes to cuprous iodide and iodine. . . . . . . . . . kJ.
The amount of copper in the alloy is estimated by (b) The mass of sucrose required to provide this energy
titrating the liberated iodine with sodium is . . . . . . . . . g and the volume of CO2 (at STP) produced
thiosulphate. The reactions are is . . . . . . . . . litres.
f Cul2 ➔ g Cu2 l2 + h 12 BIOLOGY

a Cu + b HN03 ➔ c Cu(N03 )2 + d NO + e H2 0
i Na2 S2 0 3 + j 12 ➔ k Na2 S4 0 6 + l Nal

1 0. Mohini, a resident of Chandigarh went to Shimla
with her parents. There she found the same plant
(a) The coefficients are : a = ...... , b = ...... , c = ...... , d = ..... . that they have in their backyard, at home. However,
and e = ...... . she observed that while the plants in their backyard
(b) The coefficients are : / = ...... , g = ...... and h = ...... . bore white flowers, those in Shimla had pink flowers.
(c) The coefficients are : i = ...... , j = ...... , k = ...... and l = She brought home some seeds of the plant from
Shimla and planted them in Chandigarh. Upon
(d) If 2.54 g ofl2 is evolved from a 2.0 g sample of the performing self-breeding for several generations she
alloy, what is the percentage of copper in the alloy?
(atomic weights of iodine and copper are 127 and 63.5, found that the plant from Shimla produced only
respectively). white flowers.
8. You have been given four bottles marked A, B, C and D (a) According to you what might be the reason for
each containing one of the organic compounds given this observation, genetic or environmental factors?
below (b) Suggest a simple experiment to determine whether
this variation is genetic in nature.
NH2 C02H (c) Suggest another experiment to check whether this
U U
variation in flower colour is due to environmental
I II
factors.
WWW.JEEBOOKS.INl
1 1 . The breakdown of glucose in a cell occurs in any one After a period of growth, the following observations
of the following pathways were made
CO2 + H20 (in the presence of 02 , A. Lime water turns milky; the dye colour
e.g. in mitochondria) remains the same.
Glucose - Pyruvic Ethanol + CO2 (in the absence of 02, B. The dye colour changes; lime water does not
acid e.g. yeast) turn milky.
Lactic acid (in the absence of 02
C. Lime water turns milky; the dye colour
Three experiments (A, B, C) have been set up. In
e.g. lactic acid bacteria)
(a) Question Identify which of the reactions in the

remains the same.
each experiment, a flask contains the organism
in growth medium, glucose and a brown dye pathways depicted above is taking place in each
that changes its colour to yellow when the pH experiment. Give reasons for your answer.
decreases. (b) Question Identify which of the reactions in
the pathways depicted above is expected to
occur in Red Blood Cells (RBCs).
1 2. A scientist has a house just beside a busy highway.
He collects leaves from some plants growing in his
garden to do radio-carbon dating (to estimate the age
::f
----- Lime
water
of the plant by estimating the amount of a
radioisotope of carbon in its tissues). Surprisingly the
Organism in culture radio-carbon dating shows that the plant is a few
medium
+ Glucose + Dye thousand years old.
The mouth of the flask is attached to a test tube (a) Was the result of the radio-carbon dating wrong or can
in the figure). In C, but not in A and B, air is

containing lime water (calcium hydroxide as shown you propose a reason for such an observation?
(b) What simple experiment can be done to test the reason
removed from the flask before beginning the that you have proposed?
experiment.
Answers
PART-/
(c) 2 (d) 3 (b) 4 (a) 5 (b) 6 (b) 7 (a) 8 (d) 9 (d) 10 (d)
11 (b) 12 (a) 13 (c) 14 (d) 15 (c) 16 (d) 17 (a) 18 (d) 19 (b) 20 (c)
21 (d) 22 (a) 23 (a) 24 (b) 25 (b) 26 (a) 27 (a) 28 (d) 29 (c) 30 (c)
31 (d) 32 (c) 33 (a) 34 (d) 35 (d) 36 (a) 37 (c) 38 (b) 39 (c) 40 (b)
WWW.JEEBOOKS.INl
Solutions
PART 1 6. (b) Given ABCD is square
1 . (c) We have,
41 ,' \
--- ✓
,: _ _ �\.. D N C
x2 + bx + a = 0
-
x2 + ax + b = 0
. . . (i)
. . . (ii) ' ,
;:
h ,' ' 40
x2 + bx + a = 0
Let a, � are the roots of equation
,' 12
- -39 c
h
a + � = - b; a� = a b
,_ --
Now, given roots of the equation
l2 + h 2 = 3g2
A B 6
AB = BC = 12 units
A M B
x2 + ax + b = 0 is greater than 1 of the Given,
M is mid-point of AB,
roots of Eq. (i).
⇒ b2 + h 2 = 402
:.a + 1 + � + 1 = - a and (a + 1)(� + 1) = b
a + � + 2 =- a and a� + a + � + 1 = b
⇒ l2 + b2 = 412 N is mid-point of CD,
⇒ 2(l2 + b2 + h 2) = 392 + 402 + 412 P is point of MN and CP = S
⇒ -b + 2 = - a and a - b + 1 = b
⇒ l2 + b2 + h 2 = 2401 ·: APB is an isosceles triangle,
⇒ b - a = 2 and 2b - a = 1
:. Length of longest diagonal
= ✓�l_
AP = PB = r
a = - 3, b = - 1,
On solving these equations, we get 2 _ _ --
+ b2 + h 2 OP = MB = 6 units
= ✓240 1 = 49
5. (b) We have,
a + b = - 3 - 1 =- 4
2. (d) We have,
p
g,xty) + 1 _ g,xty) - 1 = 24 sides of MBC are positive integer and

3xlY length of smallest side is 1.
⇒ 3 . 3xlY - = 2 4 ⇒ _!3_ 3xlY = 24
3 3 A B 12 C
⇒ 3xlY = 9 ⇒ 3xly = 32
are the area of l'J'BC
Area of triangle whose sides r ,s and 12
⇒ �=2
y C B
= .!. x Base x Height = .!. x BC x OP
Using componendo and dividendo, we get 2 2
x+y =2+1⇒x+y
=3 = .!. x 12 x 6 = 36 sq units
x -y 2 - 1 x -y 2
7. (a) Total area of the grass field graze
B a= 1 C
3. (b) We have, We know that the sum of two sides of
triangle is greater than third side. by the cow = 2 (area of sector APQ + area
12 + 22 + 32 + 42 + ... + n 2
b + l> C of sector BQR + area of sector CRS)
1 + 2 + 3 + 4 + ... + n
n (n + 1) (2n + 1) ⇒ c - b< l s
6 l+c> b
n (n + 1) ⇒ b -c< 1
2 -l< b - c < l Q
=
2n + 1
= k (let) b, c are integers.
3 b -c = 0 ⇒ b = c
3k - 1 a+b+c
n=- - Sem1-penmeter
. . =- - -
2 2
Now, 1 - < 3k - 1 - < 100 2b + 1 .!.
2 = = b+
2 2 5a/2
⇒ 2 '.,'.; 3k - l'.,'.; 200 Area A = .Js(s - a)(s - b)(s - c)
⇒ 2 + l'.,'.; 3k '.,'.; 200 + 1
⇒ 3 '.,'.; 3k '.,'.; 201 = ✓(b + ½)(b + ½ - 1) (b + ½ - b) (b + ½ - b)
201 p
⇒ l '.,'.; k '.,'.;
✓
2 2
3 = (b + �) (b - �) G) G) = � b2 -� 120 5a 60 3a
� X 1t( - ) + - X 1t X ( - )
⇒ l'.,'.; k '.,'.; 67 360 2 360 2
= 2[ ]
2
Number of odd integer = 34
4. (a) Let the length, breadth and height
Since, b is integer. 60
+ - X 1t ( � )
:. Area of MBC is always irrational 360 2
of cuboid is l, b and h respectively. number.
WWW.JEEBOOKS.INl
ae bd
- X - X ef =-
10 12
X - X 25 1 5. (c) B
be de 4 15
⇒ a/ = 50
Area of rectangle KLMN = af = 50 A
8. (d) Let r and h be radius and height of

1 1 . (b) Time period of a pendulum
T oc ,JI
depends on its length as
cone, respectively.
where, l = length of pendulum. + D
-----
� - 8- - -�
As water flows out of the bob of
pendulum, centre of mass of bob go down
In case (i), galvanometer shows zero
as the level of water falls. But when bob
deflection.
is completely emptied, centre of mass of
p Q
h bob again reaches to its centre. Hence,
:. VB = VD
S R
effective length of pendulum first ⇒ . . . (i)
increases then decreases.
So, time period of pendulum first When battery B and galvanometer G are
increases then decreases. interchanged, position of galvanometer is
:. Volume of cone = I rcr 2h
as shown below,
1 2. (a) Force of friction is self adjusting.
3 B
When applied force is increased friction,
then h changes to -
h
Given, rate of outflow of water in 21 min, first increases till it reaches a maximum
p Galvanometer is
value called limiting friction. connected across
2 A and C
If applied force is further increased, then +
:. Rate of outflow of water
1
( rcr h -
2 rcr
2
h)= 2 1mm friction does not increases further and
body begins to move.
A C
4 2
= x
3 Force of friction then remains constant s R
2 2 and its value is given by
⇒-
7rcr h
- . ⇒ 1 - rcr h = 3 m1n
= 2 1mm .
- -
Sx 3 3 8 / = µN
:. Time required to empty vessels in 3 min. 1 3. (c) In given case, rate of momentum
9. (d) We have,
Now, ratio of resistances across
S R
change of bullets is equal to weight of galvanometer is
p Q
soldier.
1000 kg of watermelon in which 99% are - and
i
water. If M = mass of soldier and his gun and
:. 990 kg water and 10 kg rest.
m = mass of bullet. Then,
As from Eq. (i), =�
M
N
Now, x kg watermelon has Mg = x m (v - 0)
Hence, galvanometer still shows zero
= � x water + � rest
100 100 (N I M ) x mv deflection because Wheatstone's bridge is
⇒ M=
g
1 6. (d) Force on charge Q is initially zero
Weight of solid part should remain same balanced.
where,
N is the number of bullets fired
� = 10 ⇒ X = 500
100 M as forces of 12 charges balances each
:. Weight reduction = (1000 - 500)kg per second. other.
,
, /8[-- --°081
I
40 X 49 X 10-3 X 500 \ q3 --�-q2 I
1 0. (d) Given,
= 500kg ⇒ M= -
9.8
'0-, \
I
q4/ \ I / ',,
= 100 kg ,,,,
1 4. (d) When star shrinks without losing

\ /
10 4
' ,. I
I .,,J8fq12
'
-------$--
C
// ...... \ / \
', \ I
.,,,,.
a
--©------
b q5 , ,,,, ,,,, \
its mass, its gravitational acceleration on +
its surface increases but there is no \ ,,,,,. ,,,, ,,,,,
I \
',, / Q11
N d M 12 d 15 .,,,.
I \ ', ,'
a change in force exerted by this star on a q5\ _,.,.
b ,.,-� I \ �
f 25 distant object like a planet. Force of /
'
q ;Y/5__
', I : \ t/q10
K L gravitational attraction of star on planet
I
� _)8
- --q;,--- qg \
IS q8 1
Area of rectangles are
GMm
ae = 10 F = ,. 2 As shown in above figure, forces of
diametrically opposite charges balances
bd = 12
be = 4
where, M = mass of star, m = mass of each other, hence net force on Q is zero.
planet and r = orbital radius of planet. When one of the charge q (let <Ji) is
ef = 25
de = 15 removed, net force on Q is now the
e
As, this force remains same there is no
unbalanced force of diametrically
change in orbital radius of planet.
0
YwwW. J EEBOOKS■ INl

i.e. Force F = kqQ = ___<I__(}__ 20. (c) Given, tx = 3T + 300 respective octets (i.e., 8 electrons in their
' R2 41te0R 2 outermost shell or 2 electrons in case of
So, change in temperatures in two
H, Li and Be to attain stable nearest
and this force vector points towards the systems are related as
noble gas configuration).
position of the removed charge.
= 3 (T2 - T1 )
tx2 - tx1 = (3T.2 + 300) - (3'fi + 300)
(a) Power P = -
v2 as V remains
R
The Lewis structures of given molecules
1 7. are as follows
or
constant in given condition, while current (a) NH3 - H x " N "X H
N1 1ti = N2U 2
Now to convert units, we use
changes as resistance is reduced. H
R
Power consumed by heater coil P oc _!__ 1400J N2 J As the octet is complete, hence it follows
=
Mx kg t.T kg octet rule.
On cutting part of coil, its resistance
1400 N2 xx
decreases. So, power consumed by coil ⇒ = xx CJ xx
increases and it will be more than 1 kW. MT t.T X
xx • xx
1 8. (d) First prism separates white light _ 1400t. T (b) BCls xx CJx • B• x CJxx
⇒ N2 xx xx
into its constituent colours which are - 3t.T
Octet rule is not followed in this case as
then recombined by the second inverted 1400
⇒ N2 = = 466.7 there are total 6 electrons in the
prism into white light. 3 outermost shell of B even after bonding.
is c = 466.7 J kg-1 K-1 .

Hence, in SI system, value of specific heat •• xx
(c) Cl2 , :Cl• x CJxx
21 . (d) As boiling point is a colligative
•• xx
Octet rule is followed in case of Cl 2 •
property, it depends only on the number
of particles present in a solution. (d) N2 , :Ni :N:
Aqueous solution having more number of
As both the N have complete octet. Thus,
particles will have highest elevation in
it follows octet rule.
boiling point.
Hence, the correct option is (b).
C12H2p 1 1 (aq) � No ions
As two prisms combinedly form a glass + 26. (a) On heating MnO2 with cone. HCl,
NaCl � Na + c1- (Total ions = 2)
slab, light beam is deviated on a parallel 2+ MnC1 2 and Hp are released with the
CaC1 2 � Ca + 2c1- (Total ions = 3)
path. evolution of Cl2 gas. The chemical
Thus, CaC12 will have highest boiling equation for it can be written as
1 9. (b) When blocks are brought into point.
22. (a) As silicon belongs to group 14
contact, hotter one lost heat and colder MnO2 + 4HCI � MnCl 2 + 2H2O + Cl 2
27. (a) The structure of C4 H.rBr can be
Let T = final temperature of the blocks.
one gains that heat. 2
whose general configuration is ns np 2•
Thus the correct electronic configuration written as
Then, of Si is ls2 2s2 2p 6 3s2 3p 2. H H H H
23. (a) CaCO3
Heat lost by hotter block = Heat gained 21 I 11 2110
CaO + CO2 3
�
H...L c 4 c-tcicn..Br
= mf½ (Tr - 'f; )cold block
by colder block
25 1
No. of moles of CaCO3 = � = - mole Is In
⇒ mSi_ ('f; - Tr ) Hot block H H
100 4
Thus, total number of covalent bonds in
_ti_ (Tf - 'f; ) coldblock 1 mole of CaCO3 gives 1 mole of CO2•
or = C 4 H 7Br is 12.
28. (d) As we know
I½ ('I'; - Tr ) Hot block
_. _ _! mole of CaCO3 gives _! mole of CO2 •
4 4
Here, we are using two different specific pH = - log [H + ]
heats 8i and I½ as it is given that specific 1 mole of CO2 = 44 g
heat of material increases with 44 As the initial pH of aqueous solution = 2
So, _! mole of CO2 = = 11 g 2
temperature. So, 8i_ > I½· 4 4 :. Concentration of W, [H + ] = 10-
⇒ !i_ > l Thus, 11 g of CO2 is released on heating As the final pH of aqueous solution = 5
24. (b) On moving across the second

S2 25 g of CaCO3 • � ] = 10-5
--
__r = 10-
(Tr - 'f; ) Coldblock 5
⇒ >l [W ]
('f; - Tr ) Hot block period of the periodic table, the atomic
� ]; 10-2
=
radii of the elements decrease, due to
T - 20 1
⇒ > increase in effective nuclear charge, the 10-3
80 - T electrons of all the shells are pulled little +
Thus, H concentration decreases by
⇒ T - 20 > 80 - T closer to nucleus thereby making each
thousand fold.
individual shell smaller and smaller.
25. (b) According to octet, the atoms of
2T > 100
⇒ T + T > 80+ 20
2
29. (c) For 1st jar
⇒
different elements combine with each No. of moles of H 2 = - = 1
⇒ T > 50°C other in order to complete their 2
WWW.JEEBOOKS.INl
34. (d) A frog that is twice as long as

= 6.022 X 10
:. No. of molecules of H2 in 1 mole The sensory nerve fibres bring sensory
23 another will be heavier by approximately impulses from the receptor organ to the
eight folds. It is because their weight is central nervous system (brain and spinal
=-
For 2nd jar
=1
28 determined by their folds, so by applying cord). The motor nerve fibres relay the
No. of moles ofN 2 unitary method it is eight folds. Frog motor impulses from the central nervous
28
shape is triangular. system to the effector organs. Reflex
= 6.022 X 1023
:. No. of molecules ofN2 in 1 mole action is a form of animal behaviour in
which the stimulation of a sensory organ
Thus, the gases in two jars will have (receptor) results in the activity of some
organ without the intervention of will.
40. (b) Insectivorous plants mostly
same number of molecules.
30. (c) The type of isomers in the given
13 23
options are as follows thrive in marshes and rocky outcrops or
=1 =8
(a) CH.i CH2CH2OH and CH.i CH2OCH.i other nitrogen poor areas where sunlight
Initial size
35. (d) Owl's eye have the widest angle
Final size
and water are abundant. These plants
They are functional isomers.
have evolved the ability to trap and
(b) CH.i CH2CH2Cl and CHCHClCH.i of binocular vision among rat, duck and digest insects, which are an excellent
They are positional isomers. eagle. Binocular vision is the vision using source of nitrogen as they contain around
two eyes with overlapping fields of view, 10% nitrogen by mass. Insectivorous
(c) H 3 C-C= C-CH3
allowing good perception of depth. Unlike
I I many birds with eyes that sit at an angle,
plants are able to obtain between 10-80%
H H of their total nitrogen from insects.
Cis owl's eye face directly forward giving
them incredible binocular vision. PART 2
1 . Given in MBC, D and E are points on
H
Although their large eyes cannot move or
I
AB,AC respectively such that DE is
roll-like human eyes can, owls can move
parallel to BC.
and CH3C= C-CH3
I their heads nearly all the way around,
BE and CD intersect at 0.
H allowing them to have a 270 degree range
Area of MDE = 3 sq units

Trans of vision without moving their bodies.
36. (a) An allele is a varient form of
Area of WOE = 1 sq units
As they are cis and trans form, so they
Area of Af3EC = Area of Af3DC

are geometrical isomers which are a type gene. Some genes have a variety of
of stereoisomers. different forms, which are located at the
same position on a chromosome. Humans A
are called diploid organisms because they
have two alleles at each genetic locus,
with one allele inherited from each
parent. Each pair of alleles represents
These are structural isomers. the genotype of a specific gene.
37. (c) Ants locate sucrose by physical
Thus, the correct option is (c).
3 1 . (d) Water borne diseases such as contact with sucrose. Ants can smell food
cholera is caused by drinking using their antennae, which can detect
contaminated or dirty water. Cholera is minute odours. But sugars actually do B C
caused by the bacterium Vibrio cholerae.
32. (c) The term allele was formerly ⇒
not have a smell. Therefore, when the [same base between same parallels]
scout worker ants locate sugar while
(BOD) + ar(DOE) = ar(COE) + ar(DOE)

used by Mendel for the factors foraging, they take a piece back home to
⇒ ar(BOD) = ar(COE) = x
representing the two alternate forms of a the colony, while doing this, the ant will
⇒ ar(BOC) = y
character, e.g. tallness and dwarfness in leave a chemical trial which the other
ants can follow.
38. (b) The interior of a cow dung pile
case of height in pea (T and t).
33. (a) This happens because the We know that area of two triangle having
temperature starts to increase all over kept for a few days is quite warm. This is equal altitude is the same as the ratio of
� = BO 1
their respective bases.
=
the country in March and by April. The because bacterial metabolism inside the
1 OE x
interior parts of the peninsular record dung releases heat in the form of biogas
⇒
mean daily temperature of 30-35°C.
y = x2
(CH4 + CO 2 ). This happens by anaerobic
Now, MDE and MBC are similar.

Maximum temperature rises sharply digestion of cow dung by methanogenic
exceeding 45°C by the end of May. The
ar(ADE) DE2 ar(ODE)
bacteria.
39. (c) The correct path for a reflex = =
warm temperature can affect the
ar(ABC) BC2 ar(OBC)

ripening process of fruits and vegetables
action is
by speeding up the production of ethylene
⇒ - - 3 - - -1
4 + 2x + y y
gas which rushes the ripening or fruiting Receptor ➔ Sensory neuron ➔ Spinal
process. cord ➔ Motor neuron ➔ Effector
WWW.JEEBOOKS.INl
⇒ 3y = 4 + 2x + y Consider 9m, which has only 9 as its (b) In case Q,

⇒ 2y = 2(2 + x) digits and b divisible by t.
⇒ y=x+2 9m R
Let k=
t
⇒ x2 - x - 2 = 0 [·: Y = x2] I
9k = 9m· 2r · 58 = (10c - 1)2r · 58
⇒ (x - 2)(x + 1) = 0
where, c is the number of digits in m. E
⇒ x = 2, x ;t -l
:. Area of MBC = 4 + 2x + y We can find d such that + -
qd = ld'(lOc - 1) V = I (R + RA )
= 4 + 4 + 4 = 12 sq units
[such that Hi' is a suitable power of 2 ⇒ = (: ) - RA = Rest - RA
2. Let the total number of CD's sold by R
if s > r and a suitable power of s if r > s]
the Leela and Madan together = x
p _ pd _ a So, error in case Q is
Total money obtained by them - -
q q d Hf (lOC - 1) ⇒ O¾ = I Rest - Rl = RA
= (x x x) = x2
where, pd = a. (c) If R = -JRARv then,
4. (a) In case P,
They divided x2 in such that,
x2 = 10 (an odd number) + a number less
than 10 IR R
⇒ x = lOq + r [·: 0 '.,'.; r < 10]
5. Given situation is
⇒ x2 = (lOq + r)2
⇒ x2 = 100q2 + 20qr + r 2
2
r = 10 (an odd number ) + a number less I
than 10 E � 20 cm
+ -
O '.,'.; r < 10
:. Taking r = 0, 1, 2, 3, ... , 9, we get r = 4 or 6 Current through cell is f= - 1 0 cm
r = 16 or 36 I = IR + Iv = V I R + V I Rv (a) We use lens formula to get position of
r 2 = 10 + 6 or 3(10) + 6 where, V = potential drop across image u = - 20 cm, f = - 10 cm.
Hence, the amount left for Madan at the resistance R. 1 1 1
v( ½ + ; ) = v(
As, - - - -
end is 6 rupees. R V U /
⇒ 1= ; v
)
R: 1 1 1 -1 1
3. (a) We have, v ⇒ -=-+ -=---
A natural number 'rri whose all digits are 1 = V (R + Rv )
V f u 10 20
⇒
1
RRv
:. m = 1, 1 1 1, 1 1 1 1, 1 1 1 1 1 , ... , (1 1 1 1 ... 1) 1 - 2 - 1 -3
⇒ -=- - =-
⇒ (Rv - � ) R = V�v V 20 20
A natural number 'n' which is relatively
-20
prime to 10 when n + l number ⇒ v = - cm
1, 1 1 1 , 1 1 1 1, 1 1 1 1 1, . . . , (1 1 1 1 . . . 1) divides ⇒ R=
VNv 3
by n, then n + 1 remainder obtained. I (Rv - V II) Image is virtual and it is in front of lens
:. Possibilities of remainder are 0, 1, 2, 3,
20
at cm.
.... , n - 1 which are n in numbers, where
two remainder are same.
⇒ R=
�-[R 1: V l
V I (b) Concave mirror again converge rays
y = 1 1 1 ... 1 having say i digits and j digits

Let two numbers x = 1 1 1 ... 1 and and its image formed is coincident with
But V = Rest = estimated resistance object.
respectively which leave the same I
remainder after division by n.
i< j
R = ReSt ( 1
)
We take, R v � -Rest
((i-t
y - x is divisible by n;
But y - x = 1 1 ... 1000 ... 0 where j- i
0
- R.. n I
number of l's and remaining zero. Since,
n is coprime to 10. We see that n divides
m = 1 1 1 ... l a number having l's as its
= R
est (1 + �;t )
digits. �X�
Using binomial approximation and
(b) Let the positive rational number is
E, where q ;c 0
neglecting higher order terms. Let mirror is placed at distance x behind
Now, error in case P is the lens. Now, first image 11 of lens acts
q like object for mirror.
. 8r oRp = I Rest - RI
and q = 2 5 • t where t is coprime to 10 Hence, for mirror,
Choose any number m having only is as = R!st 2
its digit and is divisible by t. Rv
u = - ( ° + x) cm.
3
WWW.JEEBOOKS.INl
N = mg + 2mgH
R
Given, / = - 5 cm As there is lens in between, so final ⇒
By lens equation, we get position of image formed is calculated as
image /2 from concave mirror as 1 1 1 2
⇒ N = mg ( 1 + : )
1 1 1 V U /
-+ -=-
V U / 1 1 1 2 This is the force by block on the concave
-=-+ - =--
1 1 1 v -10 1 2 1 2 0 surface.
or -=--+ -
V U / v = - 60cm 7. The balanced chemical equations for
1 So, final image is formed at a distance of the given equations can be written as
⇒
60 cm left of lens. (i) 3Cu + 8HN03 ----t 3Cu(N03 )2 + 2NO
6. (a) Mass m is at height H from point Q,
V
+ 4H20
where potential energy is taken zero. (ii) 2 Cul2 ----t CuJ2 + 12
1 (iii) 2Na2S203 + 12 ----t Na2S4 06 + 2Nal
⇒ A
V
Thus,
(a) The coefficients are : a = 3, b = 8,
c = 3, d = 2 and e = 4
1 _ - (3x + 5) _ - (3x + 5)
- -
� l5 20 + X) 5 (20 + 3x) (b) The coefficients are : / = 2 , g = 1, h = 1
(
3
and l = 2
(c) The coefficients are : i = 2 , j = 1, k = 1
As this image is acting like an object for h
lens, so we have from lens equation,
(d) No. of moles of l2 = · 54 = O.Ol mol
Q 2
5 (20 + 3x) 2 54
u=- cm, / = - 10 cm From geometry of above figure, if at some
(3x + 5) angle 0, height of mass m above lowest Moles of Cul2 = 2 moles of l2
cos0 = R - h ⇒ h = R (1 - cos0)
and v = + 20 cm point Q is h, then from MBC, = 1 mole of Cu
R
1 1 1
v u f
⇒ -+ -=- = 2 X 0.01= 0.02
Weight = mole x atomic weight
1 (3x + 5) -1 Hence, potential energy of m as a Weight of Cu = 0.02 x 63.5 = 12 7 g
⇒
20 5 (20 + 3x) 10 function of 0 is
PE = U(0) = mgh
% of copper present in the alloy
5 (20 + 3x) - 20 (3x + 5) = _ _!_
U(0) = mgR (l - cos0)
⇒ 12 7
= X 100 = 63.5%
2 0 X 5 (2 0 + 3x) 10 ⇒ 2
100 + 15x - 60x - 100 1 (b) Kinetic energy at position 0 = Loss of 8. Conclusions that can be made from the
⇒
2 000 + 300x 10 potential energy that occurred in given observations are as follows
reaching this position
⇒ Kinetic energy is K(0) = mgH - U (0)
2 000 = 150x (a) (i) As the compound in the bottle A did
⇒ K(0) = mgH - mgR(l - cos0)

2 000
-=x not dissolve in either 1 N NaOH or 1 N
-
= mg (H - R (1 - cos0))
150 HCl. This indicates that the molecule is
40 neutral. Thus, the compound A is (III).
(c) For H < < R, mass m will oscillate
⇒ x=cm = 13.33 cm
5
CH 3
So, mirror is placed at 13.33 cm behind about mean position in SHM. Time
V
(ii) As the compound in the bottle B
the concave lens. period of oscillation of m is
T = J:__ {JI
2n fg
(c) When a plane mirror is placed at same
position, then dissolved in 1 N NaOH but not in 1 N
Time taken to travel from P to Q is
For plane mirror is / = oo, HCl shows that the compound is acidic in
20
nature, thus the compound in bottle B is
one-fourth of this time period.
l
U = - ( + x) (II).
3
=-( +
20 :o) i.e. t=
8� C02H
3
point, if m has velocity v, then (iii) The compound in bottle C dissolved
(d) From energy conservation at lowest V
=- 60 = - 1 2 cm
- mv2 = mgH
5 1 in both 1 N NaOH and 1 N HCl indicates
nature. Thus, the compound in bottle C is

Now, by mirror equation, 2
mv2 = 2mgH or mv = 2mgH
that the compound is amphoteric in
1 1 1
v u f R R
2
- + -=- ⇒
(IV).
1 1
u force of normal reaction N and weight of
or But this centripetal force is resultant of
V
body.
mv2
⇒ ; = - ( �;)
N - mg = -
R
⇒ (amphoteric because of its Zwitter ion)
So, v = 1 2 cm
WWW.JEEBOOKS.INl
(iv) The compound in bottle D dissolved = 342 X 1866 In experiment C, since the lime water
in both 1 N NaOH, but dissolve in 1 N = 638.172 g turns milky, ethanol fermentation is
HCl shows that the compound is a base, occurring. In addition, since removal of
thus the compound is (I).
1 mole of C1zH22011 gives 12 moles of CO2 air did not affect the reaction, the
:. 1.866 moles of C12H22011 gives
fermentation is anaerobic and yeast must
VNH2
= 1866 x 12 moles of CO2 be the organism in the flask.
= 22392 moles of CO2 (b) In RBCs, lactic acid fermentation
At STP 1 mole of CO2 = 224 L occurs.
(b) The compound with highest solubility
in distilled water is (iv), 22.392 moles of CO 2 = 224 x 22.392 L 1 2. (a) The result of radio-carbon dating
was correct.
�COOH = 5015808L
Reason Vehicles running on the highway
1 0. (a) Difference in flower colour is most
beside the house emitted carbon dioxide
likely due to environmental factors.
from the combustion of petrol or diesel,
(b) Perform cross-breeding between the which are fossil fuels. The carbon in this
This is due to Zwitter ion formation plants from Chandigarh and those from carbon dioxide, coming from living
which can be shown as
Shimla to find out whether we get any material that has been converted into
coo-
v)::
pink flowers or flowers with any shade of petroleum millions of years ago, would
colour between pink and white in the get assimilated into the tissues of the
9. C12H2p11 (s) + 12 Oz(g)

I\-generation. plant as it uses carbon dioxide from the
(c) Grow the plants from Chandigarh in surrounding atmosphere for
Shimla and check whether they still photosynthesis. Therefore, tissues of the
-----t 12C02 (g) + 1 1H20(l) produce white flowers or bear pink plant, when used for radio-carbon dating,
t,.H = - 5.6 x lff J flowers. would show the age of the plant to be
many thousands of years old.
(a) l kcal = 4.18kJ 1 1 . (a) In experiment A, ethanol
:. 2500 kcal = 2500 x 4.18 kJ = 10450 kJ fermentation occurs producing CO2, (b) A simple experiment to test the
turning lime water milky. Since acid is validity of this explanation would be to
So, the energy requirement of the human
collect seeds from the plants and grow
body per day is 10450 kJ. not produced, the dye colour does not
them in a plot of land away from the
(b) No. of moles of sucrose change.
highway or other sources of CO2 coming
10450 x l(f J In experiment B, lactic acid fermentation from the burning of fossil fuels.
= = 1866 mol takes place, which produces acid but does
6 Radio-carbon dating of plants growing
5.6 X 10 J
not produce CO 2• Hence, dye colour from these seeds should show them as
Weight of sucrose changes to yellow but the lime water does young plants.
= molar mass x number of moles not turn milky.
WWW.JEEBOOKS.INl
KVPY
OUESTION PAPER 2009

Stream :SA
M M : 100
Instructions
2. This question paper contains two parts; Part I and Part I I . There are four sections; Mathematics , Physics, Chemistry
MATHEMATICS 6. Let Pi_ , P2 , Pa , P4 , I/; be five equally spaced points on

1
5 x+
the circumference of a circle of radius 1, centred at 0.
1 . The real numbers x satisfying ✓ > 1 are precisely
that are closer to O than any of Pi_ , P2 , Pa , P4 , I/; . Then,

1-x Let R be the set of points in the plane of the circle
those which satisfy
(a) x < l (b) O < x < l (c) - 5 < x < 1 (d) - 1 < x < 1 R is a
2. Let tn denote the number of integral-sided triangles (a) circular region
t20 - t19 equals

with distinct sides chosen from {1, 2, 3, .... , n}. Then, (b) pentagonal region
(c) rectangular region
(a) 81 (b) 153 (c) 163 (d) 173 (d) oval region that is not circular
3. The number of pairs of reals (x, y) such that 7. A company situated at (2, 0) in the XY-plane charges
x = x2 + y2 and y = 2xy is '{ 2 per km for delivery. A second company at (0, 3)
charges '{ 3 per km for delivery.
W4 �3 �2 00 1 The region of the plane where it is cheaper to use the
4. How many positive real numbers x satisfy the first company is
equation x'3 - 3 1 xi + 2 = 0 ? (a) the inside of the circle (x + 5.4)2 + y2 = 18. 72
Wl �3 �4 00 6 (b) the outside of the circle (x + 1.6)2 + (y - 5.4) 2 = 18. 72
5. Let (1 + 2x)20 = a0 + a1x + a2x2 + . . . + a20x2° .Then, (c) the inside of the circle (x - 1.6)2 + (y + 5.4) 2 = 18. 72
(d) the outside of the circle (x - 5.4)2 + (y + 1.6)2 = 18. 72
3a0 + 2a1 + 3a2 + 2a3 + 3a4 + 2a5 + . . . + 2a19 + 3a20
equals 8. In a right L1ABC, the incircle touches the hypotenuse
5. 320 - 3 5- 320 + 3 5- 320 + 1 5- 320 -1 AC at D. If AD = 10 and DC = 3, the inradius of ABC is
(a) (b) (c) (d)
2 2 2 2 W5 �4 �3 00 2
WWW.JEEBOOKS.INl
9. The sides of a quadrilateral are all positive integers

and three of them are 5, 10, 20. How many possible
value are there for the fourth side?
(a) 29 (b) 31 (c) 32 (d) 34
10. If the volume of a sphere increases by 72.8%, then its © (d)
surface area increases by
(a) 20% (b) 44% (c) 24.3% (d) 48.6% 17. Consider two spherical planets ofsame average
density. Second planet is 8 times as massive as first
11. If the decimal 0. d25d25d25. . . is expressible in the
planet. The ratio of the acceleration due to gravity of
form n / 2 7, then d + n must be
the second planet to that of the first planet is
(a) 9 (b) 28 (c) 30 (d) 34
Wl �2 �4 00 8
18. Two immiscible liquids A and B are kept in an
12. At what time between 10 O'clock and 11 O'clock are the
U-tube. If the density of liquid A is smaller than the
two hands of a clock symmetric with respect to the
density of liquid B, then the equilibrium situation is
vertical line (give the answer to the nearest second)?
(a) 10h 9m 13s (b) 10h 9m 14s
(c) 10h 9m 22s (d) 10h 9m 50s
13. A woman has 10 keys out of which only one opens a
lock. She tries the keys one after the another (a) (b) A
(keeping aside the failed ones) till she succeeds in

A
opening the lock. What is the chance that it is the

seventh key that works?
7 1 3
(a) - (b) - (c) - (d) J_
10 2 10 10
A
14. In a certain school, 74% students like cricket, 76% (c)
students like football and 82% like tennis. Then, all (d) None of these
the three sports are liked by at least
(a) 68% (b) 32% (c) 77% (d) 36%
15. Let Sn be the sum of all integers k such that 19. In the figure given below, a ray oflight travelling in
2 n < k < 2 n + 1 , for n ;::>: 1. Then, 9 divides Sn if and a medium of refractive index µ passes through two
only if different connected rectangular blocks of refractive
(a) n is odd (b) n is of the form 3k + 1 indices µ1 and µ2 (µ 2 > µ1 ).
(c) n is even (d) n is of the form 3k + 2
PHYSICS
16. A boy standing on the footpath tosses a ball straight
up and catches it. The driver of a car passing by µ
moving with uniform velocity sees this.
The angle of incidence 01 is increased slightly. Then,

the angle 02 is
(a) increases (b) decreases (c) remains same
(d) increases or decreases depending on the value of
(µ 1 ! µ 2)
The trajectory of the ball as seen by the driver will be 20. Two charges of same magnitude move in two circles
of radii Hi = R and � = 2R in a region of constant
uniform magnetic field B0 .
The work W1 and W2 done by the magnetic field in
the two cases respectively, are such that
(a) wl = W2 = 0 (b) wl = W2 "# 0
(a) (b) (c) WI = W2 (d) wl < W2
WWW.JEEBOOKS.INl
21. Two charges + q and - q are placed at a distance b The bulb will light up, if
apart as shown in the figure given below. (a) Si_ , S2 and Sa are all closed
(b) Si_ is closed but S2 and Sa are open
(c) S2 and Sa are closed but Si_ is open
(d) Si_ and Sa are closed but S2 is open
Ct
: A 29. Two bulbs, one of 200 W and the other of 100 W are
connected in series with a 100 V battery which has
----•----------- '------------•---
b/2 no internal resistance.
1 00V
+q ---q �------1 I I f---�
The electric field at a point P on the perpendicular
b
bisector as shown is
(a) along vector A (b) along vector C
(c) along vector B (d) zero
22. A block of mass M is at rest on a plane surface Then,
inclined at an angle 0 to the horizontal. The (a) the current passing through the 200 W bulb is more
magnitude of force exerted by the plane on the than that through the 100 W bulb
block is
(b) the power dissipation in the 200 W bulb is more than
(a) Mg cos 0 (b) Mg tan 0 (c) Mg sin 0 (d) Mg that in the 100 W bulb
23. We are able to squeeze snow and make balls out of it (c) the voltage drop across the 200 W bulb is more than
because of that across the 100 W bulb
(a) anomalous behaviour of water (d) the power dissipation in the 100 W bulb is more than
(b) large latent heat of ice that in the 200 W bulb
(c) large specific heat of water 30. A solid cube and a solid sphere of identical material
(d) low melting point of ice and equal masses are heated to the same
24. Which of the following phenomena can be temperature and left to cool in the same
demonstrated by light, but not with sound waves in surroundings. Then,
an air column? (a) the cube will cool faster because of its sharp edges
(a) Reflection (b) Diffraction (b) the cube will cool faster because it has a larger surface
(c) Refraction (d) Polarisation area
(c) the sphere will cool faster because it is smooth
25. The temperature of a metal coin is increased by (d) the sphere will cool faster because it has a larger
100°C and its diameter increases by 0.15%. Its area surface area
increases by nearly
CHEMISTRY
(a) 0. 15% (b) 0.30% (c) 0.60% (d) 0.0225%
26. The note "Saa" on the Sarod and the Sitar have the
same pitch. The property of sound that is most 31. The element X which forms a stable product of the
important in distinguishing between the two
type XC14 is
instruments is
(a) Al (b) Na (c) Ca (d) Si
(a) fundamental frequency (b) displacement amplitude
(c) intensity (d) waveform 32. A mixture of NH4Cl and NaCl can be separated by
27. �� U atom disintegrates to :g1 Pb with a half-life of
5 (a) filtration (b) distillation
9
10 yr. In the process, it emits 7 a particles and (c) sublimation (d) decantation
n �- particles. Here, n is 33. The pair in which the first compound is ionic and the
(a) 7 (b) 3 (c) 4 (d) 14 second compound is covalent, is
28. Consider the following circuit given below. (a) Fe(OH) 2 , Clf:i OH (b) Fe(OH)2 , Cu(OH)2
=
(c) Clf:i OH, Clf:i CH20H (d) Ca(OH) 2 , Cu(OH)2
!
[--------•�------
S1
34. In the reaction, S02 + 2H2S � 3S + 2H2 0, the
---+--� substance that is oxidised is
•
S2 (a) S02 (b) H20 (c) S
111,,.::. 35. Sodium oxide dissolves in water to give sodium
hydroxide which indicates its
1□s,
1 1 1''
(a) acidic character (b) basic character

(c) amphoteric character (d) ionic character
WWW.JEEBOOKS.INl
36. For an ideal gas, Boyle's law is best described by Given the solubility curves of KN03 and KCl, which
of the following statements is not true ?
a (a) At room temperature, the solubility of KNO3 and KCl
( ) P� r ( ) � are not equal
bP (b) The solubilities of both KNO3 and KCl increase with
v temperature
(c\ (c) The solubility of KCl decreases with temperature
�
v
(d) The solubility of KNO3 increases much more compared
(d)P to that of KCl with increase in temperature
�
BIOLOGY
T
37. The pH values of (i) 0.1 M HCl (a,q), (ii) 0.1 M KOH,
(iii) tomato juice and (iv) pure water follow the order. 46. Which one of the following is the smallest in size?
(a) (i) < (iii) < (iv) < (ii) (b) (iii) < (i) < (iv) < (ii) (a) Bacteria (b) Mitochondrion
(c) (i) < (ii) < (iii) < (iv) (d) (iv) < (iii) < (ii) < (i) (c) Mammalian cell (d) Virus
38. When calcium carbide is added to water, the gas that 47. If birds are moved from 3 0° C - 10°C, their body
is evolved is temperature
(a) carbon dioxide (b) hydrogen (a) changes from 30°C - 10° C
(c) acetylene (d) methane (b) increases by 10°C
(c) does not change at all
39. The atomic radii of the alkali metals follow the order
(d) decreases by 10°C
(a) Li > Na > K > Cs (b) K > Cs > Li > Na
(c) Na > K > Cs > Li (d) Cs > K > Na > Li 48. Ascorbic acid is a/an
40. The number of possible structural isomers of C3 H4 is (a) strong inorganic acid (b) hormone
(c) vitamin (d) enzyme
Wl �2 �3 00 4
49. Bile salts
41. Among the four compounds, (i) acetone, (ii) propanol,
(iii) methyl acetate and (iv) propionic acid, the two (a) breakdown polypeptide chains
that are isomeric are (b) emulsify fats and solubilise them
(a) methyl acetate and acetone (c) digest fats
(b) methyl acetate and propanol (d) help breakdown of polysaccharides
(c) propionic acid and methyl acetate 50. Dietary fibres are composed of
(d) propionic acid and acetone
(a) cellulose (b) proteins
42. One mole of nitrogen gas on reaction with 3 .01 x 1023 (c) amylase (d) unsaturated fats
molecules of hydrogen gas produces 51. 'On the Origin of Species, by Means of Natural
(a) one mole of ammonia Selection' was written by
(b) 2.0 x 1023 molecules of ammonia
(a) Hugo de Vries (b) Charles Dickens
(c) 2 moles of ammonia (c) Charles Darwin (d) Alfred Russell Wallace
(d) 3.01 x 1023 molecules of ammonia
52. Unlike humans, dogs cannot perspire to get rid of
43. Saponification is excess metabolic heat. They lose metabolic heat by
(a) hydrolysis of an ester (b) hydrolysis of an amide
(a) panting
(c) hydrolysis of an ether (d) hydrolysis of an acid chloride
(b) taking a bath
44. A concentrated solution of lead nitrate in water can (c) running in windy conditions
be stored in (d) rolling in the mud
(a) an iron vessel (b) a copper vessel
(c) a zinc vessel (d) a magnesium vessel 53. Haemodialysis is a treatment option for patients with
Solubility malfunctions of
45.
g/L (a) kidney (b) liver
250 (c) heart (d) lungs
200 54. An individual has 'O' blood group if his/her blood sample
1 50 (a) clumps only when antiserum A is added
1 00 (b) clumps only when antiserum B is added
(c) clumps when both antiserum A and antiserum B are
50 -t-=c"-------- added
0+----------- (d) does not clump when either antiserum A or antiserum
20 40 60 80 1 00 B is added
Temperature (0C)
WWW.JEEBOOKS.INl
55. In warmer weather, curd from milk forms faster 58. The part of the human brain that governs memory
because and intelligence is
(a) bacteria diffuse better in warmer milk (a) cerebrum
(b) the rate of bacterial multiplication increases (b) medulla
(c) lactogen is better dissolved (c) hypothalamus
(d) it is easier to separate protein from water (d) cerebellum
56. Seedlings grown in dark are 59. Saturated dietary fats increase the risk of heart
disease by
(a) similar to those grown in light
(a) widening arteries by thinning their walls
(b) taller than those grown in light
(b) narrowing veins by carbohydrate deposition
(c) shorter than those grown in light
(c) narrowing arteries by fat deposition
(d) they do not grow at all
(d) narrowing arteries by carbohydrate deposition
57. In humans, Rhesus condition can arise when 60. Rotation of crops is carried out to
(a) father is Rh+ and mother is Rh- (a) increase variation in the mineral content of the soil
(b) father is Rh- and mother is Rh + (b) increase diversity of plant habitats
(c) either father or mother is Rh+ (c) increase in nitrogen content of the soil
(d) either father or mother is Rh- (d) increase convenience for the farmer
::> PART- I I (2 Marks Questions)
MATHEMATICS PHYSICS
6 1 . Let loga b = 4, loge d = 2, where a, b, c, d are natural
suspended from it. Another balance B reads 3 kg
66. A spring balance A reads 2 kg with a block of mass m
numbers. Given that b - d = 7, the value of c - a is
(a) 1 (b) - 1 when a beaker with a liquid is put on its pan. The
(c) 2 (d) - 2 two balances are now so arranged that the hanging
mass m is fully immersed inside the liquid in the
:c
62. Let P(x) = 1 + x + + :13 + x4 + :1 . What is the beaker as shown in the figure given below.
remainder when P(lf2 ) is divided by P(x)?
(a) 0 (b) 6
2 4
(c) l + x (d) l + x + x + x3 + x
63. In a L1ABC, the altitudes from B and C on to the

opposite sides are not shorter than their respective
opposite sides. Then, one of the angles of ABC is
(a) 30° (b) 45 °
(c) 60 °
(d) 72°
64. In a L1ABC, AB = AC = 37. Let D be a point on BC

such that BD = 7, AD = 33 . The length of CD is In this situation,
(a) 7 (b) 11 (a) the balance A will read 2 kg and B will read 5 kg
(c) 40 (d) not determinable (b) the balance A will read 2 kg and B will read 3 kg
(c) the balance A will read less than 2 kg and B will read
65. A line segment l of length a cm is rotated about a between 3 kg and 5 kg
vertical line L keeping the line l in one of the (d) the balance A will read less than 2 kg and B will read
following three positions (I) l is parallel to L and is at 3 kg
a distance of rcm from L, (II) l is perpendicular to L 67. According to the quantum theory, a photon of
and its mid-point is at a distance rcm from L, (III) l
E = hv, where h is known as Planck's constant.
electromagnetic radiation of frequency v has energy
and L are in the same plane and l is inclined to L at
an angle 30° with its mid-point at a distance rcm
mass m has equivalent energy E = mc2 , where c is
According to the theory of relativity, a particle of
from L. Let A1 , �' Ai be the areas so generated. If
r> (a /2),then
speed of light. Thus, a photon can be treated as a
(a) A1 < Ai < A2 (b) A2 < A1 < Ai . 1e havmg
partic "' . mass m = hv .
. ef1ective
(c) A1 = Ai < A2 (d) A1 = A2 = A:i 2 C
WWW.JEEBOOKS.INl
If a flash of light is sent horizontally in earth's

gravitational field, then photons while travelling
CHEMISTRY
a horizontal distance d would fall through a 71 . Reaction of NaCl with cone. H2SO4 liberates a gas, X
distance given by
(b) !!._ (c) mcd
that turns moist blue litmus paper red. When gas X is
2 2
passed into a test tube containing egg shell powder
(a) gd2
me h
(d) zero
2c suspended in water another gas, Y is generated which
when passed through lime water makes it milky. The
68. A solid square plate is spun around different axes gases X and Y, respectively, are
with the same angular speed. In which of the (a) HCl and CO2 (b) Cl2 and CO2
following choice of axis of rotation will the kinetic (c) SO2 and CO2 (d) SO2 and HCI
energy of the plate be the largest?
(a) Through the centre, normal to the plate 72. 10 mL of an aqueous solution containing 222 mg of
(b) Along one of the diagonals of the plate calcium chloride (mol. wt. = 111) is diluted to 100 mL.
The concentration of chloride ion in the resulting
(c) Along one of the edges of the plate
(d) Through one corner normal to the plate solution is
(a) 0.02 mol/L (b) o. o i mol/L
69. An object is placed 0.40 m from one of the two (c) 0.04 mol/L (d) 2.0 mol/L
lenses L1 and L2 of focal lengths 0.20 m and
73. Aluminium reduces manganese dioxide to manganese at
0.10 m respectively, as depicted in the figure. The high temperature. The amount of aluminium required to
separation between the lenses is 0.30 m. reduce one g mole of manganese dioxide is
(a) 1/2 g mol (b) 3/4 g mol
1__ _ _ _ _ _ _ _ _ _ _ _ - - - - - - - - - - - - - - -
(c) 1 g mol (d) 4/3 g mol
74. Ethanol on reaction with alk. KMnO4 gives X which
when reacted with methanol in the presence of an acid
gives a sweet smelling compound Y, X and Y
respectively, are
(a) acetaldehyde and acetone
The final image formed by these two lenses (b) acetic acid and methyl acetate
system is at (c) formic acid and methyl formate
(a) 0. 13 m to the right of the second lens (d) ethylene and ethyl methyl ether
(b) 0.05 m to the right of the second lens 75. The pH of a 10 mL aqueous solution of HCl is 4. The
(c) 0. 13 m to the left of the second lens amount of water to be added to this solution in order to
(d) infinity change its pH from 4 to 5 is
70. 5 charges each of magnitude 10-5 c and mass 1 kg (a) 30 mL (b) 60 mL (c) 90 mL (d) 120 mL
central charge of magnitude 5 x 10-5 C and mass

BIOLOGY
are placed (fixed) symmetrically about a movable
0.5 kg as shown in the figure given below. The

charge at Pi is removed. The acceleration of the 76. Proteins are synthesised on
?
central charge is (a) cytoskeleton (b) mitochondria
P1
(c) ribosomes (d) Golgi apparatus
- . 77. Which of the following allows light to focus in visual
· .
_ __ .. .- - - -- ··· · .. .. .. .. . perception?
- . (a) Retina (b) Iris
P, ,/\ O• P, (c) Retinal pigment (d) Cornea
78. During cell division, if there is one round of chromosome
•------------------•
duplication followed by one round of cell division, the
number of chromosomes the daughter cells will have as
P3 P4
compared to the mother is
[Given, (a) equal (b) double (c) half (d) one fourth
O.Pi = OP2 = 0Pa
1
= OP = OJ/; =
4 1 m, - - = 9 x 10 9] 79. Similar type of vegetation can be observed, in the same
4mo (a) latitude (b) longitude (c) country (d) continent
(a) 9 ms-2 upwards 80. Which of the following ecological food chains does not
(b) 9 ms-2 downwards represent an erect pyramid of numbers ?
(c) 4.5 ms-2 upwards (a) Grass-Rodent-Snake (b) Tree-Bird-Avian parasite
(d) 4.5 ms-2 downwards (c) Grass-Deer-Tiger (d) Insect-Chicken-Human
WWW.JEEBOOKS.INl
Answers
PART-/
(d) 2 (a) 3 (a) 4 (a) 5 (c) 6 (b) 7 (b) 8 (d) 9 (a) 10 (b)
11 (d) 12 (b) 13 (d) 14 (b) 15 (c) 16 (b) 17 (b) 18 (c) 19 (b) 20 (a)
21 (a) 22 (a) 23 (*) 24 (d) 25 (b) 26 (d) 27 (c) 28 (c) 29 (d) 30 (b)
31 (d) 32 (c) 33 (a) 34 (d) 35 (b) 36 (c) 37 (a) 38 (c) 39 (d) 40 (b)
41 (c) 42 (b) 43 (a) 44 (b) 45 (c) 46 (d) 47 (c) 48 (c) 49 (b) 50 (a)
51 (c) 52 (a) 53 (a) 54 (d) 55 (b) 56 (b) 57 (c) 58 (a) 59 (c) 60 (a)
PART-I/
61 (a) 62 (b) 63 (b) 64 (c) 65 (d) 66 (c) 67 (a) 68 (d) 69 (d) 70 (c)
71 76 78 79 80
(a) 72 (c) 73 (d) 74 (b) 75 (c) (c) 77 (d) (a) (a) (b)
Solutions
1 . (d) We have, So, the number of triangle with largest
,jx + 5
4. (a) We have,
side 20 and middle side.
- ->1 x3 - 31 xi + 2 = 0
1- X a = 1 1, then other sides are 2 1 - 1 1, 1 1 - 1
Case I x > 0
i.e. 10, 10 (11, 10, 10) 1 triangle. Similarly
,Jx+5 > 0, 1 - x > 0 a = 12, (smallest sides are (9, 10, 1 1) = 3 x3 - 3x + 2 = 0
x> - 5 . . . (i) 1
triangle a = 3, smallest sides are ⇒
⇒
(x - 1) (x - 1) (x + 2) = 0
x< l . . . (ii) (8, 9, 10, 1 1 , 12) = 5 triangle x = ], - 2
-
,,1x + - o :. Total number of triangles on Since, x> 0
Again, >l X ;c - 2
1- X 1 + 3 + 5 + 7 + .... + 1 7 = 81
x= l
⇒ ,Jx+6 > 1 - x 3. (a) We have, Case II x < 0
2
⇒ X + 5 > (1 - x) x = x2 + y2 . . . (i) x3 + 3x + 2 = 0
[squaring both sides] and y = 2xy . . . (ii) Graph of x3 + 3x + 2
⇒ x + 5 > 1 + x2 - 2x y - 2xy = O y
⇒ x2 - 3x - 4 < 0 ⇒ y (1 - 2x) = 0
⇒ (x - 4) (x + 1) < 0 ⇒ y = 0, X =
1
⇒ XE (- ), 4) . . . (iii) 2
From Eqs. (i), (ii) and (iii), we get Put y = 0 in Eq. (i), we get
11
X E (- , ) x = x2 + O
- 1< x < 1 ⇒ x - x2 = O
2. (a) tn denotes the number of integral ⇒ X (1 - X) = 0
sided triangle with distincts sides from ⇒ x = O, x = 1 Y'
rnr
{l, 2, 3, ... , n}. t19 is the number of Clearly, from graph.
Put x = � in Eq. (i), we get
triangle formed by the sides from 2 It has one solution lie between (- 1, 0).
{l, 2, 3, ... , 19} and t20 is the number of
+ y2
:. Positive value of x = 1
triangle formed by the distinct sides from
{l, 2, 3, ... , 20}.
½= Hence, only one solutions.
⇒ 2= 1-1 5. (c) We have,
Any triangle counted in t19 is also Y 2 4
counted in t20 , but t20 - t19 is the number 1 1 (1 + 2x)20 = Go + £liX + Gr2 + ... + G20X20
of triangle counted in t20 but not in t19 • y2 = - ⇒ y = ± -
A triangle is counted in t20 but no ti_9 if
⇒
4 2 Put x = , 1
:. Value of (x, y) are (0, 0) (0, 1) 320 = ao + Gi + a2 + ... + a20 . . . (i)
and only if its largest side is 20.
G,i) ( ½ �1
Put x = - 1,
The middle side of is a and the smallest
side can be 2 1 - a to a - 1 } 1 = a0 - Gi + � - a.i + ... + a20 . . . (ii)
WWW.JEEBOOKS.INl
8. (d) We have,
ABC is a right angled triangle. AC is
On adding Eqs. (i) and (ii), we get Volume of sphere after increase is V ' and
hypotenuse of t.ABC. The incircle touch

320 + 1 radius is r'.
- - = ao + a2 + a4 + . . . + a20
the hypotenuse at D.
2 V ' = i nr'3
3
On subtracting Eq. (ii) from Eq. (i), we get A ⇒ V ' = (V + 728% of V )
320 - 1 728 1728v
-- = + a.i + £1:; + . . . + 9 = v (1 +
2 ll:i_ ll:!_ )=
1000 1000
Now, we have 1728
⇒ V' = i 3
( nr )
3a0 + 2ll:J_ + 3a2 + 2a.i + . . . + 2£li_9 + 3�0 1000 3
= 3 (a0 + a2 + a4 + . . . + a20 ) 1 728 . i 1tr3 = i 1tr,3
+ 2 (ll:i_ + a.i + ... + ll:!_9 ) 1000 3 3
_
20
3 +1 320 - 1 r'3 r'
- 3 (- - ) + 2 (- - ⇒ :i"" = 1. 728 ⇒ - = 1.2
2 )
7r
2 C r r
:. Increase in surface area of sphere
CD = 3
5 . 320 + 1 Given, AD = lO
OE = OF = r(radius of circle)
2 =( = 1.44 = 144%
6. (b) Pi , P2 , F's , P4 , El; be five equally
OE = BE = BF = r
:. Surface area increase = (144 - 100)%
spaced points on the circumference of = 44%
circle of radius 1. 1 1 . (d) Let
AD = AF = lO . . . (i)
x = 0. d25d25d25
[AD and AF are tangents on a circle
Similarly, CD = CE = 3
from external points are equal] lO00x = d25. d25d25 . . . (ii)
In L'>.ABC, AC2 = AB2 + BC2

999x = d25 ⇒ x = d25
999
(13)2 = (10 + r) 2 + (3 + r) 2 n
⇒ 169 = 100 + 20r + r 2 + 9 + 6r + r 2 But given, X= -
27
d25-
- = - n=-
⇒ 2r 2 + 26r - 60 = 0 n d25
⇒
⇒ r 2 + 13r - 30 = 0 27 999 37
d E {l, 2, 3, 4, 5, 6, 7, 8, 9}
Let R which is near to point 0.
⇒ (r + 15) (r - 2) = 0
:. OR is lie between the pentagonal region

⇒ r = 2, r'#- 15 n is integer.
9. (a) We have three sides of :. d25 is a multiple of 37.
Q1 , Q2 , Q3 , Q4 , Q5 . quadrilateral are 5, 10, 20. When, put d = 9
7. (b) Let P(x, y) be any point lie in Let the fourth sides of quadrilateral = x Then, n is multiple of 37.
We know that in quadrilateral. Sum of 925 = 25
XY-plane. n=
three side is greater than fourth sides 37
( )
B (0 , 3)1---�p x, y 5 + 10 + 20 > x . . . (i) n + d = 25 + 9 = 34
5 + 10 + x > 20 . . . (ii) 1 2. (b) Exactly at 10 O'clock the hour
5 + 20 + x > 10 . . . (iii) hand has travelled 300° from 12 O'clock.
P (2 , 0) 10 + 20 + x> 5 . . . (iv) One hour = 60 minute.
From Eq. (i) x < 35 One minute hand moves 1° and hour
From Eq. (ii) x > 5 30 0 ( 1 0
clock hand move ( - ) = -)
From Eq. (iii) x > - 15 360 12
According to problem, 2PA < 3PB From Eq. (iv) x > - 25 Assuming we have made it to 10 O'clock
Now, x is a positive integer. and now the hour and the minute hand
4PA 2 < 9PB2
:. From Eqs. (i), (ii), (iii) and (iv), start moving spontaneously.
⇒ 4 [(x - 2)2 + (y - 0) 2] < 9 12
5 < x < 35
[(x - 0)2 + (y - 3)2]
:. Value of x is 6, 7, 8, 9, 10, 1 1 , 12, 13, 14,
⇒ 4 (x2 - 4x + 4 + y2) < 9 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25,
(x2 + Y2 - 6x + 9) 26, 27, 28, 29, 30, 31, 32, 33, 34
2 2
⇒ 5x + 5y - 54y + 16.x + 65 > 0 9 3
:. There are 29 possible values of x.
1 0. (b) Let initial volume of sphere is V

⇒ x2 + y2 - 10.8y + 3.2x + 13 > 0
8 4
i nra
⇒ (x + 1.6) 2 + (y - 5.4) 2 > 18. 72 and radius is r.
Hence, the region is outside the 5
V=
(x + 16) 2 + (y - 5 - 4)2 = 18.72 3
WWW.JEEBOOKS.INl
If the hands of the watch are symmetric =

(2n - 1)(2n ) · 3 length column of B must appear above
Sn
with vertical line. 2 this line in other limb of U-tube. It is as
(6x)0
Supposing this happens when x minutes But Sn = 9m, mE I shown below.
have passed x minutes = have been (2n - 1)2n · 3 =
- - - -- 9m
�r
covered our hour hand would cover.
2
[<6x)C�)J Gx =
r
⇒
⇒
(2n - 1)2n - l = 3m
2n (2n - 1) = 6m
:. Our hand has covered ( 300 + It is possible when, n is even.
1 6. (b) Velocity of a ball is measured
�r �r
On subtracting this from 360° to find the
angle from 12 O'clock anti-clockwise, relative to a fixed object or frame. If
This is shown in option (c).
1 9. (b) Given situation is

frame of reference is moving, then object
we get
will have a velocity opposite to that of
360° - (300 + =
(60 - frame of reference. In given case, car is
frame of reference. Due to motion of car,
So, they are symmetric. the ball has two velocities
60 - � = 6x (i) vertical velocity
2
120 =
0 (ii) horizontal velocity opposite to
⇒ =
x ( ) 9 mm 13.8 s motion of car.
13 Because of there two velocities, path of
:. Time = 10 h 9 m 14 s ball will be parabolic in car frame.
l
1 3. (d) Woman has 10 keys out of which
When 01 is increased at point A following

only one opens a lock.
Trajec tory of ,,- -, f-- Car
The first keys works with probability J:. ball is a / �\ frame Snell's law (i oc r), then r1 increases.
When r1 increases, r2 decreases at point B.
10 parabola ---J'"
The conditional probability that the second from fro n t / V1 = - Vear \
'-
keys works given that first failed = I.. to bac k -' Decrease of r2 causes a decrease of r3 as
9 (i oc r).
So, trajectory of ball will be as that of
:. Required probability (seventh key Also r3 = r4, so when 7a decreases, r4 also
option (c).
= P (I fails) · P (2nd/I fails) · P (III /2 fails) 1 7. (b) Given, mass of second planet
works) decreases. This causes a decrease in
P (7th/6th fails)
value of 0 2•
=
M2 = 8 M1
8 x mass of first planet So, a increase of 01 causes a decrease in 02•
20. (a) Force on a charged particle

9 8 7 6 5 4 1 1 ⇒ ••• (i)
= - X- X- X- X - X - X-= -
10 9 8 7 6 5 4 10
1 4. (b) Given, 74% students like cricket
⇒ i n� x p = 8 x i n.Rl x p
F = q(v x B)
moving in region of magnetic field is
3 3
� = 8.Rl
76% students like football :. Density of both planets is same.
Clearly, F is perpendicular to both v and B.
R2 = 2R,,_
82% students like tennis ⇒
As, magnetic force is perpendicular to
:. 26% student not like cricket or . . . (ii)
velocity of moving charged particle. So,
24% student not like football So, ratio of acceleration due to gravity of work done in time M is
W
the second planet to that of the first
18% student not like tennis = (F · v) M = 0
planet is
Student all the three sports like at least Hence,
= 100% - (sport not likes)
2 1 . (a) Given situation is
.!
= 100% - (26 + 24 + 18)%
E1 sin 0 • E1
= 100% - 68% = 32%
1 5. (c) We have, 2n < k < 2n + 1, k E N

E o s 0 + E2 c o s 0
0 1 c
�
_/ : 0 Re s ultant
Number of integer between 2n and 2n +
1
,-/ i: .·E2.
. - < �
is i.e k = 2n + - 2n - 1
1
---<±5-J________ ,________�>- .
/ E n2 si·. 0
First term = 2n + 1
So, g2 = 2g1 . i 1_-0,
1 8. (c) As density of B is more than that
Last term = 2n + 1 q q
- 2n - l [2n + 1 +
- 1
= 2n + 1 n+ 1
of A, a small volume of B weighs equals to
a large volume of A.
Sn 2 - l] As charges are of equal magnitude,
2 direction of resultant field is along the
2n + 1 - 2n - l n
bottom of column of A, then a lesser
Sn = (2 )(l + 2) Hence, if we draw a horizontal line from angle bisector of the angle formed by field
2 vectors.
WWW.JEEBOOKS.INl
22. (a) Weight of mass M can be resolved amplitude rises or falls in a given time So, power dissipation is more in the 100 W
into components parallel and duration. bulb. This makes option (d) correct.
30. (b) Area of cube is more than that of
perpendicular to inclined plane as This is shown by waveform of sound
shown below. wave. Two waves can have same
N=M a sphere for same mass and density.
amplitude and frequency but can have
Cube also have sharp edges that radiates
different waveforms. As shown here.
more effectively than a flat surface.
A So, rate of cooling for cube is much rapid
Mg sin 0
than sphere. Effect of sharp edges is
prominent only at very high
Force of block on incline is Mg cos0, so temperatures. So, option (b) is correct.
3 1 . (d) As element Xis forming a stable
product of the type XC14 , so X must be
force exerted by block on mass M is
Mg cos0 directed perpendicularly up the
plane. tetravalent. Among the given elements Al
27. (c) Given, 7 a particles are emitted
is trivalent, Na is monovalent, Ca is
23. (No option is matching)
divalent and Si is tetravalent. Thus,
When we squeeze the snow due to from ��5 U. option (d) is correct.
ig7A + 7(�He) 32. (c) A mixture ofNH4 Cl and NaCl can
increased pressure, melting point of ice
(snow) is lowered and it melts. As ⇒ ��5 U -----t
be separated by the process of
pressure is removed, water formed is Now, n13- particles are emitted to produce sublimation. In this process, solid directly
again frozen because melting point is �r Pb.
again raised. This process is called changes to gaseous state without passing
regelation of ice. ⇒ ig7A -----t �rPb + n � �)1
into liquid state. NH4 Cl sublimes to
gaseous NH.i and HCl upon heating
None of the option given is correct. Conservation of atomic number, gives
24. (d) Polarisation is a process of
whereas NaCl does not sublime, the
78 = 82 - n ⇒ n = 82 - 78 = 4 reaction can be written as
alignment of electric vectors (or plane of So, 4 �- particles are emitted in given NH4 Cl(s) ---t NH.i (g) + HCl(g)
oscillation of particles) in a particular nuclear reaction. 33. (a) An ionic compound is formed
28. (c) In given circuit, when Si_ and Sa
direction when an electromagnetic wave when metal and a non-metal reacts
(or a mechanical transverse wave) passes whereas covalent compound is formed
through a narrow slit. Sound waves in air both are closed, then source is short when 2 non-metals react with each other.
are longitudinal waves, so they cannot be circuited. Closing either Si_ or Sa does not
In the given options, Fe(OHb Ca(OH) 2
polarised. Polarisation is shown only by completes any of path. Hence, they
transverse waves. and Cu(OH)2 are ionic while CH.i OH,
produce no change in circuit.
25. (b) Percentage increase in area
CH.i CH20H are covalent.
=
Final area - Initial area x 100 =
S1 Thus, the correct pair in which first
compound is ionic and the second compound
Initial area is covalent is given in option (a).
34. (d) In the given reaction,
nr/
7t (r; - r/)
= x 100
Reduction
(r + r) 2 - r' x 100
r/
= 1 A
Oxidation
where, lir = increase in radius.
Here, H2S is getting oxidised to H20.
35. (b) Na20 + H20 ---t 2NaOH
r/ + 2ri r2 - On closing S2 alone the circuit containing
=( /i� ; A 1/ ) X 100
i bulb is complete. Hence, bulb will light
up when S2 is closed alongwith Sa but Si_ Sodium Oxide Sodium
2
2r1lir 11r x 100 hydroxide
; is open. Option (c) is correct.
29. (d) Resistance of bulb is inversely
r1 As Na 20 is a metal oxide which on
dissolving with water gives NaOH which
v
As lir is small, we can neglect 11r 2. proportional to its rated power. is metal hydroxide, indicates the basic
r/
= 2r1lir x 100 2 character of Na 20.
36. (c) According to Boyle's law, the
1 _
⇒ R = rated ⇒ R oc _
P,.ated P,.ated pressure of a given mass of an ideal gas is
= 2 ( �: x 100) As bulbs are in series, so same current inversely proportional to its volume at a
constant temperature.
v
flows through them at all instances.
p
= 2 X 0.15% = 0.30% Power dissipation in a series combination 1
26. (d) Property of sound that makes
OC -
IS
difference between two sounds having P = l2R ⇒ P oc R Both option c and b is showing
same frequency and amplitude is called 1 relationship between p and V but the
or P oc -- correct option is (c), as it is showing
timber or quality of sound. This is how P,.atetl
WWW.JEEBOOKS.INl
inverse relationship and option (b) is have different functional groups, so they much more compared to that of KCl
showing a linear relationship. are functional isomers. with increase in temperature. Thus,
p 42. (b) N2 + 3H2 � 2Nlla the statement (a) is correct.
6.022 x 1023 molecules of H2 = 1 mole 46. (d) Virus is the smallest in size
among bacteria, mammalian cell and
:. 3.011 x 1023 molecules of H2 = 0.5 mole.
mitochondrion. Virus ranges in size from
3 moles of H2 reacts with 2 moles of NIia . about 20-400 nm in diameter. Bacterial
2 cells range in size from 0.2-10 µm.
So, 1 mole of H2 reacts = - moles of NIia .
3 Mammalian cells are between 10-100 µm
in diameter. Mitochondria are commonly
:. 0.5 mole of H2 react with � x 0.5 between 0.75-3 µm in diameter.
47. (c) Birds and mammals are
V 3
37. (a) pH stands for potenz (power) of = _! mole

3 endothermic animals, i.e. their core body
hydrogen. The pH values for acidic
1 mole of NIia contains 6.022 x 1023 temperature is kept nearly constant
solution ranges from O to 7, for pure through thermal homeostasis. Therefore,
molecules.
water its value is 7 and for basic solution, if birds are moved from 30° -10°C their
it ranges from 7-14. So, _! mole of NIia will have
body temperature does not change at all.
48. (c) Ascorbic acid is also known as
3
As HCl is a strong acid, the pH value will
= 6.022 X 1023 X_!
be least. On the other hand, KOH is a 3
23
vitamin-C, a vitamin found in citrus
strong base, its pH value will be = 2.0 x 10 molecules.
43. (a) Saponification is the process of
fruits and is an essential nutrient
maximum, tomato juice contains citric
involved in the repair of connective tissue
acid which is a weak acid, so its pH value
hydrolysis of glyceryl ester of stearic acid and the enzymatic production of certain
will be more than HCl, but will be less
with sodium hydroxide, which produces neurotransmitters. In the body, it acts as
than H2O and KOH.
glycerol and soap. The reaction can be an antioxidant, helping to protect cells
Thus, the correct order of pH values will be from the damage caused by free radicals.
(i) < (iii) < (iv) < (ii)
written as
0
49. (b) Bile salts consist of sodium
38. (c) When calcium carbide is added to II bicarbonate, sodium glycocholate and
C H2-0-- -C----C 1 7H35
-
water, acetylene gas is evolved. The sodium taurocholate. These are the
reaction can be written as I primary components of bile produced in
�
CaC2 + 2H2O ---t Ca(OH) 2 + CH=CH C H-O----C- C17 H 3 5 the liver. Their main function is
(Calcium (Acetylene) +3Na0H �
emulsification of fat (i.e. breakdown of
carbide) I
3C 1 7H3 5COO- Na+ large fat molecules into small droplets)
39. (d) On moving down the group, as C H2-0----C----C17 H 35 (soap) and their solubilisation.
50. (a) Dietary fibres are composed of
II
0
the atomic number of alkali metal +
increases, their atomic radii also CH20H
increases because here shielding effect I non-starch polysaccharides such as
predominates over nuclear charge. CHOR cellulose, dextrins, inulin, lignin, chitins,
Thus, the correct order of atomic radii of
I pectins, beta-glucans, waxes and
CH20H oligosaccharides. Dietary fibres, also
alkali metal is Glycerol
44. (b) A concentrated solution of lead

known as roughage is the portion of plant
Cs>K>Na> Li
40. (b) Two structural isomers of C;i H4
derived food that cannot be completely
nitrate in water can be stored in copper broken down by digestive enzymes.
are possible, which are propyne and vessel as copper can not react with lead Rest others, i.e. amylase, proteins and
cyclopropane. nitrate solution because it is less reactive unsaturated fats are although basic
than lead. Whereas, all other given components of diet but are not considered
CHa C = CH metals are more reactive than lead and as dietary fibres.
(Propyne) can easily react (displace) it from its
(Cyclopropene) 5 1 . (c) 'On the Origin of Species, by
4 1 . (c) The molecular formulas for the 45. (c) The solubility ofKCl increases
solution.
Means of Natural Selection' or 'The
given compounds are as follows Preservation of Favoured Races in the
with increase in temperature. Thus, the
acetone - C;i H6 O propanol - <; H8 O Struggle for Life', published on
statement (c) is incorrect.
24 November 1859 is a work of scientific
methyl acetate - <; H6 O2 (a) From the graph, it is clear that at literature by Charles Darwin which is
propionic acid - <; H6 O2• room temperature the solubility of considered to be the foundation of
As molecular formula for both propionic KNO3 and KCl are not equal. Thus, evolutionary biology.
52. (a) Panting refers to breathing
acid (Clla CH2 C OH) and methyl acetate the statement (a) is correct.
II (b) The solubility of both KNO3 and KCl
0 increases with temperature. Thus, quickly and loudly through mouth. It
statement (b) is correct. helps dogs to get rid of excess metabolic
functional (Clla -C OCHa ) are same but heat when they are hot or engaged in
II (d) From the graph, it can be seen that
0
vigorous exercise.
the solubility of KNO3 increases
WWW.JEEBOOKS.INl
58. (a) The part of the human brain that 63. (b) ABC is a triangle in which BE
and CF are altitude.
This happens because panting helps dogs
to circulate the necessary air through governs memory and intelligence is
their bodies to cool down. cerebrum. It is the largest part of the
53. (a) Haemodialysis is a process of
A
human brain associated with most
critical and intelligent brain function
purifying the blood of a person whose such as thoughts and actions.
59. (c) Saturated dietary fats increase
kidneys are not working normally. It
helps to filter waste, removes extra fluid
and balances electrolytes (sodium, the risk of heart disease by narrowing
potassium, bicarbonate, chloride, arteries by fat deposition. Saturated fat
calcium, magnesium and phosphate). raises the level of cholesterol in your
During haemodialysis, blood is removed blood. High levels of Low Density Lipid
(LDL) cholesterol in blood are
BE '?. AC
from the body and filtered through a B C
man-made membrane called a dialyser, responsible for their deposition in blood Given,
vessel, thus narrowing the lumens and CF '?. AB
BE
or artificial kidney and then the filtered
In MBE, sin A =
blood is returned to the body. increasing the risk of heart diseases and
54. (d) An individual has 'O' blood group AB

stroke.
60. (a) Rotation of crops is carried out to AB sinA = BE
AB sin A '?. AC [·: BE '?. AC] . . . (i)
if his/her blood sample does not clump
increase variation in the mineral content
when either antiserum 'A' or antiserum
Similarly in MCF,
of the soil. Prolonged planting of the
'B' is added. Antiserum is a blood serum
sinA = CF
same crop type leads to the depletion of
containing antibodies against specific
AC
specific nutrients in the soil.
61 . (a) We have, loga b = 4,
antigens. Clumping or Agglutination is
AC sinA = CF
the process that occurs if an antigen is
⇒
AC sinA '?. AB [·: CF '?. AB] . . . (ii)
mixed with its corresponding antibody. loge d = 2, a, b, c, d E N
A person with 'O' blood group neither ⇒
⇒ b = a4 , d = c2
b - d = 7 = a 4 - c2
(AB + AC) sin A '?. (AB + AC) ⇒ sin A '?. 1
have 'A' nor 'B' antigens on his/her red
blood cells, but both 'a' and 'b' antibodies ⇒
in his/her plasma. Thus, they are also ⇒ 7 = (a2 + c) (a2 - c) ⇒ sinA = 1 [O '.,'.; sinA '.,'.; 1]
called as universal donor. ⇒ 7 x 1 = (a2 + c) (a2 - c) ⇒ A = 90 °
[·: sin 90° = 1]
55. (b) The rate of bacterial a2 + c = 7 and a 2 - c = 1 Now, from Eqs. (i) and (ii), we get
multiplication increases in warmer On solving, we get a = 2 and c = 3 AB '?. AC
weather thereby forming curd from milk c- a = 3-2=1 and AC '?. AB
62. (b) We have, AB = AC
faster. This happens because
Lactobacillus (i.e. bacteria that turns
P(x) = 1 + x + x2 + x3 + x4 + :x!' Hence, angles are 45°, 45° , 90°.
64. (c) Given, AB = AC = 37
milk into curd) is more active in summers
and develops more, which inturn 1 - x6
AD = 33
P(x) = - -
accelerates the fermentation process. 1- X
56. (b) Seedlings grown in dark are
taller than those grown in light as they
l·:
1
a + ar + ar 2 + . . . + ar n = - - -J
a ( - r n )l
1- r
BD = 7
A
develop long hypocotyls (embryonic shoot)
It has 5 roots let a1 , a 2 , a3 , a 4 , a5 they
and their cotyledons remain closed
are 6th roots of unity
around the epicotyl in an apical hook.
This process is referred to as etiolation. Now, 37
57. (c) In humans, Rhesus condition can
P(x12) = 1 + x12 + x24 + ;x:36 + x48 + x6o
arise when either father or mother is :. P(i1 2) = P(x) • Q(x) + R(x)
Rh positive. Rhesus (Rh) factor is an Here, R(x) is a polynomial of maximum
inherited protein found on the surface of degree 4.
B 7 D E C
In MBE,
red blood cells. If an individual's blood Put x = a1 , a 2 , a3 , a4 , a5 ; we get
has the protein, he/she is Rh positive and
AB2 = AE2 + BE2
R(a1 ) = 6 = R(a 2) = R(a3 )
if his/her blood lacks the protein, he/she is • . . (i)
In MDE,
Rh negative. A baby may have the blood = R(a 4 ) = R(a5 )
AD 2 = AE2 + DE2
type and Rh-factor of either parent or a :. R(x) - 6 = 0 has 6 roots, which
• . . (ii)
AB - AD = BE - DE
combination of both parents. Rh factor contradicts that R(x) is maximum of
degree 4. ⇒ 2 2 2 2
AB2 - AD 2 = (BE + DE) (BE - DE)

follows a common pattern of law of
dominance because Rh-positive gene is a :. So it is an identity. ⇒
dominant gene. R (x) = 6
WWW.JEEBOOKS.INl
⇒ AB2 - AD 2 = (CE + DE)(BD) 1 B I -C

[·: BE = CE]
- -
⇒ ⇒
2 a/2
AB - AD = CD · BD
2 2 BC = �
AB2
⇒ CD = - - - AD
- - As = 1ta (r - 1
2
BD + r + �)
⇒ CD = -37 - - -33 ⇒ As
2 2
Al A2 = As
[given] = 21tra
⇒
7
CD =
= By lens equation,
(37 + 33) (37 - 33) 1 1 1
66. (c) When block is dipped in water, it
⇒
7 V U /
CD =
70 x 4 displaces some water which exerts
= 40 1 1 1 1 1
reading on scale A will be lower than 2 kg.
buoyant force on block. As a result, or -=-+ -=-+ - -
7 v f u 0.2 (-0.4)
⇒
segment l is curved surface area of
65. (d) Case I Area is generated by line Due to reaction of block (which is equal to 1 1
So, reading of scale B will be more ⇒

buoyant force), beaker of water is pushed. V 0.4
= 21tra
cylinder = 21tra v = 0.4m
A1 than 3 kg. Now, this image acts like a virtual object
67. (a) In time t, a particle of mass m for second lens.
falls by a distance For second lens, u = + 0.lm, f = - 0.l m
h = }. gt 2
Now, distance covered horizontally = d

2
a
and speed in horizontal direction = c.

Time to travel distance, d = t = <!:
. ---·::· .- . . · · · - .. . !
·
----- d ----�
L C Final _ . . - - - -_·_ . . . - · ·---*
image - - - -- - u = +0.1 m
Case II Area is formed in circle. at oo
By lens equation,
So, photons falls through a distance, 1
gd
(i )
}. = � + _! = __ + 2
h = _! gt 2 = }_ x g x
2 2 V f U - 0.1 0.1
⇒
=
2 2 C 2c2
68. (d) Kinetic energy of a rotating body

V
Hence, final image is formed at infinity.
lS
K = J:. 1co2
L
Alternate Method For lens Li_,
distance. Now, image distance for L2 is

u = - (2/) so image is formed at 2/
2
[(r � r - (r - �r]
Area of circular region
A2 =
0.1 m and focal length of ½ is also 0.1 m.
1t + Hence, object for ½ is at focus, so its
= 21tra
image is formed at infinity.
70. (c) Forces on charge at point 0,

Case III Area generated to form a
initially balances each other as it is given
frustrum. that acceleration occurs when charge at
of force due to charges at points P2 , , P4

point Pi_ is removed. This means resultant
where, I = moment of inertia of a body.
Pa
For square plate, moment of inertia is and El; is equal and opposite to force due
Hence, acceleration of charge at point 0

largest along an axis perpendicular to to at point Pi_.
plane of plate and through its one of
corner. As mass distribution is now
is directed along OPi_.
farthest from axis of rotation. F
So, kinetic energy of plate is largest in Acceleration =
m
( K<Ji q2 )
option (d).
69. (d) Image of first lens acts like object _ � _ 9 X 10

9
X 10-5 X 5 X 10-5
- m -
for second lens. (1) 2 x l
ln MBC, Now, for first lens,
BC u = - 0.40 m, f = + 0.20 m
AC
sin 30° =
WWW.JEEBOOKS.INl
7 1 . (a) When concentrated sulphuric 4

:. 1 mole of MnO 2 reacts = - moles of Al Ribosomes can be found floating within
acid reacts with NaCl, then sodium 3 the cytoplasm or attached to the
bisulphate and HCl gas (X) is formed. ⇒ Amount of Al required to reduce 1 g endoplasmic reticulum.
77. (d) The cornea acts as the eye's outer

The HCl gas released is acidic in nature 4
mole ofMnO 2 = - g mol.
and turns blue litmus red. 3
74. (b) Ethanol on reaction with alkaline

most lens. It functions like as window
2NaCl + H2SO 4 -----t Na2SO4 + 2HC1 that controls and focusses the entry of
(X) Kl\foO 4 gives acetic acid (X), which when light into the eye (visual perception). The
When HCl gas (X) is passed into a testtube reacts with methanol in the presence of cornea contributes between 65-75
containing egg shell powder which an acid gives methyl acetate (Y), which is per cent of the eye's total focussing
contains calcium carbonate suspended in a sweet smelling compound. power. When light strikes the cornea, it
water another gas CO 2 (Y) is released, e bends or refracts the incoming light on to
CJ.J
i -'3 CH2OH Alkalin i -'3 COOH(X)
CJ.J
Ethanol Acetic Acid
the lens. The cornea covers the pupil (the
which turns lime water milky. KMnO4
opening at the centre of the eye), iris (the
HCl + CaCO3 ----t CaCO 2 + CO 2 + H2O
(X) Egg shell ( Y)
CH.i COO H + CH.i OH � coloured part of the eye), and anterior
Methanol
powder chamber (the fluid filled inside of the
CH.i COOCH.i (Y) + H2O eye).
Methyl acetate
CO2 + Ca(OH) 2 ----t CaCO3 + H2O
78. (a) One round of chromosome
Milky
(Sweet smell)
Thus, the gases X and Y respectively are Thus, X and Y respectively are acetic acid duplication followed by one round of cell
HCl and CO 2• division leads to equal number of
72. (c) Initial concentration of CaC12 in
and methyl acetate.
75. (c) Given,
chromosomes in the daughter cells as
compared to the mother cell.
222 X 10-3
79. (a) Latitude and temperature are
. pH of 10 mL of H Cl solution = 4
solution = ------ = 0.2 M
l l l x lO x 10-3 :. Concentration of W ions = 10-4 M
related to each other in a way that, as we
On dilution, After dilution,
approaches the equator, the temperature
M1 V1 = M2V2 pH of HCl becomes = 5 gets warmer and as we approaches the
:. Concentration of W ions = 10-5 M poles, it gets cooler. Since, same
0.2 X 10 = M2 X 100
As we know, vegetation grows in the same climatic
M2 = 0.02 M zone, therefore similar type of vegetation
:. On dilution, the final concentration of M1 V1 = M2V2
can be observed in the same latitude.
80. (b) Tree-Bird-Avian parasite does

CaC12 will become 0.02 M. = 10-4 X 10 = 10-5 X V2
CaC12 ----t Ca 2+ + 2Cr V2 = lO0 mL

not represent an erect pyramid of
0.02M 0. 02M 2 x Q02 So, 90 mL of water should be added for
number. Instead, it is an inverted
:. The concentration of er ion in the the pH change from 4 to 5.
76. (c) Ribosomes are the site where RNA

pyramid of number. All ecological
resulting solution = 0.04 mol/L. pyramids of number are erect except in
73. (d) 4Al + 3MnO2 ----t 3Mn + 2Al 2O3 is translated into protein. This process is parasitic food chain, where one primary
called protein synthesis. Protein is needed producer supports numerous parasites
3 moles ofMnO2 reacts with 4 moles for many cell functions such as repairing which further support more
of Al. damage or directing chemical processes. hyperparasites.
WWW.JEEBOOKS.INl
PRACTICE
SETS ( 1 -5)
WWW.JEEBOOKS.INl
WWW.JEEBOOKS.IN]
KVPY
PR ACTICE SET 1
Stream :SA
M M : 100
Instructions
MATHEMATICS 4. When 10 is subtracted from each of the given

1 observation, the mean is reduced to 60%. If 5 is
1. If x = ../3 + 1, then value of x4 + � is added to all the given observation, the mean will be
X
(a) 25 (b) 30 (c) 60 (d) 65
(a) 54 (b) 55
(c) 58 (d) 56 5. In the given figure, AB is the diameter of the circle
2. Three friends Ajay, Vijay and Sanjay move along a centered at 0. IfLCOA = 60° , AB = 2r, AC = d and
circular path oflength 1.2 km with speeds of 6 km/h, CD = l, then l is equal to
8 km/h and 9 km/h respectively. Ajay and Vijay move
in the same direction but Sanjay move in opposite
direction, if they all start at the same time and from
same place. How many time will Ajay and Sanjay
meets anywhere on the path by the time Ajay and
Vijay for the first time anywhere on the path?
(a) 6 times (b) 7 times
(a) d../3 (b) d

(c)S times (d) 9 times
(d) .f§d
3. A cone is within the cylinder and cylinder is within a ../3 (c) 3d
2
cube touch by all vertical faces with same bases and
height, then the ratio of their volume will be 6. The sum of all integers x for which x4 + :13 + :x? + x + 1
(a) 14 : 1 1 : 13 (b) 42 : 33 : 11 is a perfect square
(c) 56 : 36 : 22 (d) None of these (a) 2 (b) 4 (c) 3 (d) 6
WWW.JEEBOOKS.INl
168 KVPY Practice Set l Stream : SA
7. The sum of all 3-digit numbers which are equal to 11

times the sum of squares of their digits is
PHYSICS
(a) 1212 (b) 1353 (c) 1452 (d) 1364 16. A solid cylinder of mass m and length
8. If2/(xy) = {f(xW + { f(y)Y for all x, y E R, and f(1) = 2, l is placed vertically on the ground.
then the value /(5) - /(3) is equal to IfY = Young's modulus of cylinder's
(a) 12 (b) 24 (c) 36 (d) 48 material, then strain energy stored is
9. A job has to completed by 12 boys in 15 days. If three (a)
m2g2z (b)
m2g 2z
(c)
m2g 2z (d)
m2g 2z
boys are absent from the first day, then by what 3AY 6AY 2AY AY
percentage should the remaining boys increase their 17. A metallic wire is loaded at ends with two masses is
rate of working to complete the job placed over a slab of ice.
(a) 33_1_% (b) 22_1_ %
3 2
2
(c) 40-%
3
10. The number of positive integer x which satisfies the
cond1t10n
99
l-J l-J,
. . 1 x 7 = 1 x 7 where x 1s
101
. greatest mteger
.
This wire passes through slab without splitting it
into two pieces. This is due to
functions (a) depression of melting point
(a) 2499 (b) 2500 (b) elevation of melting point
(c) 2501 (d) None of these (c) high conductivity of metal wire
11. In a regular heptagon ABCDEFG the side of (d) high specific heat of ice
1 1 18. Two identical boxes one of them is filled with
heptagon is 1, then diagonals -- + -- is equal to
AC AD nitrogen and other is filled with helium are put on a
1 fast moving train.
(a) -
2
(b) �
3
(c) 1 (d) _l_
4 If train is suddenly stopped, then what will be the
ratio of rise of temperature of two boxes nearly?
12. In the given figure, the length ofAB is
19. A gas expands from state a to state b as shown below.

(a) 2 : 1 (b) l : 4 (c) 4 : 7 (d) l : 1
A B
(a) 3 (b) U6 (c) 3-J6 (d) 4

---+ - - ------> V
13. There are 20 units cubes all of whose faces are white,
and 44 units cubes all of whose faces are red. They Temperature of gas during the above expansion
are put together to form a bigger cube (4 x 4 x 4). process
What is the minimum number of white visible on this (a) decreases continuously (b) increases continuously
larger cube? (c) decreases then increases (d) increases then decreases
(a) 20 (b) 14 (c) 12 (d) 8
20. An elastic ball of mass m is suspended with an ideal
14. A larger tanker can be filled by two pipes A and B in thread. Another ball of same mass hits ball with
60 min and 40 min respectively. How many minutes velocity v0 as shown below.
will take to fill the empty tanker if only B is used in
the first half of the time and A and B are both used in
the second half of the time?
(a) 15 (b) 20 (c) 27.5 (d) 30
15. Ifa and� are acute angles such that
cos2 a + cos2 � = � and sin a - sin� = �. then a + � m

2 4
equals Impulsive tension in the string due to collision is
(a) � (b) � (c) � (a) mv0
5
(b) - mv0
18
(c) - mv0
4
(d) - mv0
6 4 3 7 17 9
WWW.JEEBOOKS.INl
KVPY Practice Set l Stream : SA 169
21 . A stationary radioactive nucleus decays as: 27. A body falls through a viscous fluid starting from rest
X -------+ :He + Y towards ground. Then, after a long time, which of the
If speed of a-particle is v, then speed of daughter most likely to be correct?
nucleus Y will be (a) No energy is dissipated by body
(b) Rate of potential energy dissipation is constant
(a) � (b) � (c) Rate of kinetic energy dissipation is constant
A-4 A-4
(d) Whole of the energy of body can be dissipated before
(c) � (d) � reaching ground
A+ 4 A+ 4
28. Identical blocks of wood are piled over each other as
22. 30 g ice at 0° C is mixed with 25 g of steam at 100° C. shown below.
The resulting mixture is
(Latent heat of fusion = 80 cal/g, latent heat of D
vapourisation = 540 cal/g and specific heat of C
B
water = 1 cal) A
If length of each block is l, then maximum possible

(a) water and ice at 0°C �I�
(b) water at 100°C
(c) water and steam at 100°C projection for topmost block is
(d) water, ice and steam at 50°C l
(a) - (b) -l (c) -
l
29. For a two particle systems, kinetic energy K and

23. An object falling freely from rest covers a distance s 2 3 4
potential energy U varies with separation rof

in 5th second. Then, distance travelled by object in
7th second is
13 s
(a)- (b) -9 s 9
(c) - s (d) � s particles as
9 13 11 9
24. A pendulum bob is given a push when it is suspended
freely.
T ---➔ K
-�-+- - A+--- -+B - Ct---------> E

� u
The system is a bound system for

If bob successfully completes the vertical circle, then (a) r = rA (b) r = rB
(c) r = re (d) all points A, B and C
30. A point source of light S, placed at a distance L in
least ratio of kinetic energies at bottom and top of the
circle is
(a) 2 : 1 (b) 5 : 1 (c) 7 : 1 (d) l : 2 front of the centre of a plane mirror of width 1 m,
25. A wood block is floating in benzene at 0°C. hangs vertically on a wall.
�
A man walks in front of mirror along a line parallel.
It is given,
To the mirror at a distance 2L from mirror as shown

Density of wood = 880 kg m -3
Density of benzene = 900 kg m -3
4 1 in the above figure. Distance upto which source is
Cubical expansion coefficient of wood = 1.5 x 10- K - visible to man is
= 12 X 10-3 K -1
Cubical expansion coefficient of benzene (a) 1 m (b) 2 m (c) 3 m (d) 4 m
Minimum temperature at which wooden block just

sink in is
CHEMISTRY
(a) 22°C (b) 10°c (c) 12°C (d) 15° C 3 1 . The correct order of the lattice energies of the
26. Mass of the largest stone that can be moved by following ionic compounds is
flowing water stream depends on density of water, (a) NaCl > MgBr2 > CaO > Al203
acceleration due to gravity and velocity of flow. Then, (b) NaCl > CaO > MgBr2 > Al203
mass m is proportional to (c) Al203 > MgBr2 > CaO > NaCl
(a) v2 (b) v4 (c) v6 (d) Al203 > CaO > MgBr2 > NaCl
��w
w �w� E�
.J� E�
B�O�
O�K�S�.l�
(d) v-1
Nl
32. Average volume available to a molecule in a sample 43. Clemmensen reduction of ketone is carried out in the
of ideal gas at STP is presence of which of the following reagents?
(a) 3.72 x 10-20 cm3 (b) 2. 69 x 1019 cm3 (a) Zn-Hg with HCl (b) LiAlH4
(c) 22400 cm3 (d) 22400 x 6.02 x 1023 cm3 (c) H2 and Pt as a catalyst (d) Glycol with KOH
Z are - 1 . 2 V, + 0.5 V and - 3.0 V, respectively.

33. Among the quantities, boiling point (I), entropy (II), 44. Standard electrode potential of three metals X, Y and
pH (III) and emf of a cell (IV), intensive properties
are The reducing power of these metals will be
(a) Both I and II (b) I, II and III (a) Y > X > Z (b) Z > X > Y
(c) I, III and IV (d) All of these (c) X > Y > Z (d) Y > Z > X
34. The number of radial nodes of 3s and 2p -orbitals are 45. When white phosphorus is heated with caustic soda,
respectively the compounds formed are
(a) 2, 0 (b) 0, 2 (c) l, 2 (d) 2, 1 (a) PIia + NaH2PO3 (b) PIia + NaH2PO2
(c) PIia + Na 2HPO3 (d) PIia + NaH2PO4
BIOLOGY
35. A sulphur containing species that cannot be a
reducing agent is
(a) S02 (b) sot (c) H2S04 (d) S2-
36. The energy (in J) corresponding to light of 46. During urine formation, the filtration of blood at the
wavelength 45 nm, is closest to glomerulus is
(h = 6.63 x 10-34 Js, speed of light = 3 x 108 ms-1 ) (a) an active process
(a) 6.63 X 108 (b) 6.67 X 1011 (b) an osmotic process
(c) 4.42 x 10- 15
(d) 4.42 x 10-18 (c) a pressure dependent physical process
(d) a non-energy-mediated transport process
37. The reaction N2 + 3H2 � 2NR:i is used to produce
ammonia. When 450 g of hydrogen was reacted with 47. Grave's disease is associated with
nitrogen, 15 7 5 g of ammonia were produced. The (a) insufficiency of thyroid hormones
percentage yield of reaction is closest to (b) excess of thyroid hormones
(a) 61.8 (b) 72.4 (c) 51.8 (d) 89. 1 (c) insufficiency of corticosteroids
38. The number of isomers for the compound with the (d) excess of growth hormones
molecular formula C 2BrClFiis 48. 'Imperfect fungi' is a group represented by fungal
W3 �4 �5 00 6 species which have
39. Time required to deposit one millimole of aluminium (a) simple mycelia
metal by the passage of 9.65 A through molten (b) no known mechanism of sexual reproduction
electrolyte containing aluminium ion is (c) unknown phylogenetic relationship
(a) 30 s (b) 10 s (c) 30,000 s (d) 10,000 s (d) lost its survival mechanism against harsh environment
40. The IUPAC name of the following compound is 49. Which of the following is not a characteristic of
phylum Chordata?
(a) Pharyngeal slits (b) Amniotic egg
(c) Post-anal tail (d) Notochord
(a) 4, 4, 3-trimethyl hex-1-yne 50. The energy rich fuel molecules produced in the TCA
(b) 4, 4, 3-trimethyl hex-1-ene cycle are
(c) 3, 4, 4-trimethyl hex-1-yne
(a) 2 GTP, 2 NADH and 1 FADH2
(d) 3, 4, 4-trimethyl hex-1-ene
(b) 1 GTP, 2 NADH and 2 FADH2
41. Which of the following com pounds will not undergo (c) 1 GTP, 3 NADH and 1 FADH2
aldol condensation? (d) 2 GTP and 3 NADH
(a) Methanal (b) 2-methyl pentanal 51. In Drosophila melanogaster males, homologous
(c) Cyclohexanone (d) 1-phenyl propanone chromosomes pair and segregate during meiosis but
42. Which is the most basic compound among the given crossing over does not occur. At which stage of
options? meiosis does segregation of 2 alleles of a gene take
place in their individuals?
0 N
I
(a) Zygotene
(c) Anaphase-1
(b) Diakinesis
(d) Anaphase-II
52. Excess oxygen consumed after a vigorous exercise is
H (a) to pump out lactic acid from muscle
I II III (b) to increase the concentration of lactic acid in muscle
foWww�:rEEBOOKS.INl
(a) I (b) II (c) III (d) Both I and III (c) to reduce dissolved carbon dioxide in blood
(d) to make ATP
53. Mark the correct relationship (d) Evolution need not always lead to a better phenotype
(a) 'l'w = 'l'p - ('I'" + 'I'm ) (b) 'l'w = 'l'p + 'l's + 'I'm 57. Which one of the following compounds is generally
(c) 'l'w = 'IfP + "'" - 'I'm (d) None of these translocated in the phloem?
54. Hydrogen bonds occur between which of the following (a) Sucrose (b) D-glucose
constituents of DNA? (c) D-mannose (d) D-fructose
(a) Sugar and base (b) Phosphate and base 58. Which organelles would be more prominent in a
(c) Complementary bases (d) Phosphate and sugar secretory cell than in a non-secretory cell?
55. Which one of the following neurotransmitters is (a) Golgi bodies (b) Lysosomes
secreted by the pre-ganglionic neurons of (c) Mitochondria (d) Pinocytic vesicles
sympathetic nervous system? 59. In the conversion of RuBP to GP (PGA)
(a) Epinephrine (b) Acetylcholine (a) a molecule of carbon dioxide is accepted
(c) Dopamine (d) Nor-epinephrine (b) a stable six-carbon molecule is produced
56. Which of the following statements about evolution is (c) ATP is generated
(d) hydrogen is combined with oxygen to form water
incorrect?
(a) Evolution is the product of natural selection 60. Adventitious roots develop in
(b) Evolution is goal-oriented (a) creepers (b) trailers
(c) Prokaryotes evolve faster than eukaryotes (c) twinners (d) All of these
::> PART- I I (2 Ma rks Questions)

MATHEMATICS PHYSICS
61. Let P(a, b) be a variable point satisfying 66. A thin rod of length f 13 is placed along the principal
4 � a2 + b2 � 9 and b2 - 4ab + a 2 � 0. Let R be the axis of a concave mirror of focal length f such that its
P can lie, the area of region R is

complete equation represented in XY-plane in which image which is real and elongated just touches the
rod. Linear magnification obtained is
2 5
(a) 1t (b) 1t (c) 41t (d) 1t (a) 1 (b) �
2
3 3 3 1
(c) - (d) .!°!
62. Let S1 (n) be the sum of first n terms of arithmetic 2 2
progression 8, 12, 16, ... and let S2 (n) be the sum of 67. Cube of side a is located in three dimensional
the first n terms of arithmetic progression 1 7, 19, 21, cartesian space as shown in the figure given below .
. . . if for some value of n, S1 (n) = Sin), then this
z
common sum 1s
(a) 216 (b) 260
(c) 200 (d) None of these a__�c
_
63. On a card, the following three statements are found
1. on this card exactly one statement is false
2. on this card exactly two statement are false
3. on this card exactly three statement are false
The number of false statement on the card is exactly
wo �1 �2 00 3
64. MBC is right angled at A The circle with centre A Unit vector in the direction PQ (from centre of face
and radius AB cuts BC and AC internally at D and E ABOG to centre of face OGEF) is
respectively. If BD = 20 and DC = 16, then the length (a) - .J2J - .J2 fc
AC equals
(a) 6J21 (b) 6J26 (c) 30 (d) 32 (b) - .J2J + .J2 fc
1 :J - 1 '
(c) .J2
65. The coefficient of x3° in the expansion of k
.J2
(1 + 2x + 3x2 + . . . + 20x1 9 + 21x2° )2 is 1: 1 k,
(d)- J + .J2
(a) 2706 (b) 2450 (c) 1481 (d) 256 2
WWW.JEEBOOKS.INl
Light Na/ ether

68. In given circuit, cells have zero internal resistances. C
Power dissipated in resistors Hi = 20 Q and � = 20 Q
lS
Only one structure is possible for B. Identify A, B and
C in the reaction
(a) CH.i C(Cil.i ) 2 Cil.i , CH.i C(Cil.i )2 CH2Cl,
CH.i C(Cil.i ) 2 CH2CH2C(Cil.i )2 Cil.i
+ (b) CH.i CHCH2Cil.i , CH.i C(Cl)(Cil.i )CH2Cil.i CH.i ,
CH2C(Cil.i ) 2 C(Cil.i ) 2 CH2Cil.i
(a) Pi = 5W, P2 = OW (b) Pi = lOW, P2 = 5W

10V (c) Both (a) and (b)
(c) Pi = 5W, P2 = 5W (d) Pi = 5W, P2 = lOW

(d) None of the above
69. A piece of wood of mass 0.03 kg is dropped from the

top of a 100 m high building. At same instant, a
BIOLOGY
bullet of mass 0.02 kg is fired from the ground, with a 76. Which one of the following statements regarding
velocity of 100 ms-1 along same vertical line. Bullet plant growth hormones is correct?
gets embeded in block of wood. Height to which (a) Gibberellins do not play any role in flowering
is (Take, g = 10 ms-2)
combined system rises above the top of the building (b) Auxin and cytokinin inhibit cell division
(c) ABA inhibits root growth and promotes shoot growth
(a) 10 m (b) 40 m (c) 30 m (d) 20 m at low water potential
(d) ABA promotes leaf senescence independent of ethylene
70. If force F, length L and time T are chosen as
fundamental quantities, then mass is 77. A woman with one gene for haemophilia and a gene
(a) [FL-1 T-2] (b) [FL-1 T2] for colourblindness on one of the X-chromosomes
(c) [FL T-2] (d) [FL0 T-2] marries a normal man. How will the progeny be?
(a) All sons and daughters haemophilic and colourblind
CHEMISTRY
(b) 50% haemophilic colourblind sons and 50% colourblind
carrier daughters
71 . 10 dm3 of an ideal monoatomic gas at 27°C and
(c) 50% haemophilic daughters and 50% colourblind
daughters
1.01 x 1()5 N - m-2 pressure heated at constant (d) Haemophilic and colourblind daughters
pressure to 127° C. Thus, entropy change in JK- 1 is
78. Which one of the following relationships is true in
(a) 2.422 (b) 5.98
(c) - 2 .422 (d) - 5.981 water at 25° C?
(a) [Oir ] = [H2O- ] (b) [Ir ] = [H20]
72. What is the mass of precipitate formed when 50 mL
of 16.9% solution of AgNO3 is mixed with 50 mL of (c) Kw > l x 10-14 (d) [H+ ] = [Oir ]
5.8% NaCl solution ? 79. Identify the correct match between the animal
(Molar mass of Ag = 107.8, N = 14, 0 = 16, Na = 23 and (flatworm, earthworm, roundworm) and its body
Cl = 35.5) cavity type (acoelomate, coelomate,
(a) 28 g (b) 3.5 g (c) 7 g (d) 14 g pseudocoelomate).
73. Which of the following diatomic molecules would be (a) Roundworm-Pseudocoelomate;
stabilised by removal of an electron? Earthworm-Acoelomate; Flatworm-Coelomate
(b) Roundworm-Acoelomate; Earthworm-Coelomate;
(a) C2 (b) CN Flatworm-Acoelomate
(c) N2 (d) 02
(c) Roundworm-Pseudocoelomate;
74. When calcium carbide is hydrolysed, compound X is Earthworm-Coelomate; Flatworm-Acoelomate
formed as a major product, which then reacts with (d) Roundworm-Coelomate;
dilute sulphuric acid in the presence of mercuric Earthworm-Pseudocoelomate; Flatworm-Acoelomate
sulphate, a compound Y is formed.
amino group (-NH2 ) or a carboxyl group (-COOR).
80. A sequence of amino acids may end in either an
Compounds X and Y are
(a) C2H2 and CH.i CHO What is the theoretical number of chemically
(b) CH4 and HCOOH different dipeptides that may be assembled from
(c) C2H4 and CH.i COOR 20 different amino acids?
(d) C2H2 and CH.i COOR (a) 40 (b) 80 (c) 160 (d) 400
WWW.JEEBOOKS.INl
Answers
PART-/
(d) 2 (b) 3 (b) 4 (b) 5 (a) 6 (a) 7 (b) 8 (b) 9 (a) 10 (a)
11 (c) 12 (c) 13 (c) 14 (d) 15 (c) 16 (b) 17 (a) 18 (a) 19 (d) 20 (c)
21 (a) 22 (c) 23 (a) 24 (b) 25 (a) 26 (c) 27 (b) 28 (d) 29 (d) 30 (c)
31 (d) 32 (a) 33 (c) 34 (a) 35 (c) 36 (c) 37 (a) 38 (d) 39 (a) 40 (c)
41 (a) 42 (b) 43 (a) 44 (b) 45 (b) 46 (c) 47 (b) 48 (b) 49 (b) 50 (c)
51 (c) 52 (d) 53 (b) 54 (c) 55 (b) 56 (b) 57 (a) 58 (a) 59 (a) 60 (a)
PART-I/
61 (d) 62 (b) 63 (c) 64 (b) 65 (a) 66 (b) 67 (b) 68 (a) 69 (b) 70 (b)
71 (a) 72 (c) 73 (d) 74 (a) 75 (a) 76 (d) 77 (b) 78 (d) 79 (c) 80 (d)
Solutions
1 . (d) We have, x = -13 + 1 n:x:3 . n:x:3
- :x:3 '. 4 DB = DC = l
.·. V1 '· V2: '· V:3 - ' 12 [·: two tangents are equal
Both sides squarring, we get
LBOD = LCOD = _!. LBOC

= 1 •. -2: .- -2:_ from external points]
⇒ x2 = 3 + 2J3 + 1 = 4 + 2J3
4 4 4 4 12 ⇒
LBOC = 180° - LCOA

⇒ 22 22 2
x2 4 + 2J3 2(2 + -/3) = 1: :
28 84 ⇒
= 2(2 - -/3) = 4 - 2J3
= 42 : 33 : 1 1
COD = _!. LBOC = ] x 120° = 60°
= 180° - 60° = 120°
4. (b) Let the observation are
2
⇒ x4 + 164 = (x2 + ±2 ) - 8 ⇒
CD
x x 2 2
In t.OCD, tan LCOA = -
Xi ' � , Xa , . . . , Xn
r�
= (4 + 2/3 + 4 - 2/3)2 - 8
oc
tan 60 = }_
= (8)2 - 8 = 64 - 8 = 56
2. (b) Time taken by Ajay and Vijay to X = i=l ⇒ °
observation, then mean = x - 10

n
l = d-/3
meet first time anywhere on the path
�r
When 10 is subtracted from each
6. (a) Let y2 = x4 + x3 + x2 + x + 1
Distance 12 ⇒
= = 0.6 h
x - lO = � x
Relative speed 8.6
:. x - 10 = 60% of x
Consider (x2 + = x4 + x3 + �
Time taken by Ajay and Sanjay to meet
⇒
⇒x - � x = 10 ⇒ x = 25
anywhere 100
= x4 + x3 + x2 + x + 1 - (1 x2 + x + 1)
= 2 = 0_8 h
Distance
Relative speed 9 + 6
The number of times Ajay and Sanjay When 5 is added to each observation,
= y2 - .!. (3x2 + 4x + 4)
5. (a) Given, LCOA = 60°
meets anywhere on the path by the time then new mean is 25 + 5 = 30 4
Ajay and Vijay meets each other for the
As discriminant of 3x2 + 4x + 4 is
AO = OB = OC = r
�r
. 36 1 . . negative.
In MOC, AO = CO = r and L COA = 60°
fiirst time = - = 7-, 1.e. 7 times.
48 2
3. (b) Let the side of cube = x
3:x:3 + 4x + 4 > 0
:. Radius of cylinder = Radius of cone = � __-.'.;'.-.c:::-------::::'71 O

Thus, (x2 + < y2
2
Volume of cube (V1 ) = x3
Height of cylinder = Height of cone = x
(�r
⇒ l y l > l x2 + � 1
But x2 + � = (x + i)
Volume of cylinder
X = 1t:
x is non-negative,
'dx E I
(V2) = 1t
:.MOC is an equilateral triangle.

:x:3
Volume of cone
AC = d = r
2
(� ) . X = 1t
l x2 + i l = x2 + i < l y l
(V3 ) = _!. 1t
3 2 12
WWW.JEEBOOKS.INl
If x is even, then I y I � x2 + � + 1 8. (b) We have, LABC = 51t

2 2/(xy) = {f (x)V + {f (yW 7
⇒ y 2 � x4 + x3 + x2 + x + 1 + � x2 Putting y = 1 BC = AC
4
i
2/(x) = f(x) + {/ (lW LBAC = LBCA
⇒ 5 =
f(x) = 2x = ( 1t -
)
; �
which is not possible. /(5) = 'i5 = 32 and /(3) = z3 = 8
LGAC + LGAD' = 41t + 31t = 1t
/(5) - /(3) = 32 - 8 = 24
9. (a) M1 = 12 boys, D1 = 15 days,
If x "# 0, then x = 0 is the only solution 7 7
when x is even.
Hence, CAD' are collinear.
If x is odd, then x2 + � + _! is an integer. R,_ = Rate of working
M2 = 9 boys, D2 = 15 days, R2 = Rate of
i
2 X LGCA = LGD'A = ..'.:
7
2
So, I y I � (x + �) + working ⇒ LCAB = LACB
M1 D1R,_ = M��2 !J.GCD' - /J.BAC
In
;��:::,x3 + x + x + 1 + ( x _ � _ � )
2
2 ⇒ 12 x 15 x R,_ = 9 x 15 x R2
R,_ = � = �
GC CD' GD'
BA AC BC
Y �Y + 4-2- 4
4 2 4 ⇒
•
1.e. 2 (x 2 3)
2
X
R2 12 4
R2 i
⇒
AC CD' CA + AD'
-=-=
BA GC AD
⇒ =
R,_ 3 [·: GC = GD = AD]
= Y2 + _! (x2 - 2x - 3) (R - ) AC AC + AD
4 Percentage increase = 2 R,_ x 100 ⇒
R,_ AB AD
and hence _! (x2 - 2x - 3) '.,'.; 0 1 AC + AD 1 1
4 ⇒ -= - - =-+-
x2 - 2x - 3 '.,'.; O X E [-1, 3] =( - 1) x 100 AB AC - AD AC AD
�
:. There are exactly 3 integer 0, -land 3 _!_ __ 1 = __ 1
⇒ + =1 [·: AB = l]
for which the expression is perfect square = (1 - 1) x 100 AC AD AB
and sum = 0 - 1 + 3 = 2 1 2. (c) We have, radius of circle are 3, 2
7. (b) Let three-digits number are = _!_ X 100
3
and 1.5, respectively.
100a + lOb + c
= 33_!_ %
Given, 100a + 10b + c = l l(a2 + b2 + c2) ••• (i) 3
(99a + l lb) + (a - b + c) = l l(a2 + b2 + c2) 1 0. (a) We know,
l- J l·- J
99a + l lb is divisible by 1 1 . 1 x l 1 x l
= when K � 2
: . a + b + c i s must divisible b y 1 1. K- 1 K+ l
Hence, so, a - b + c
K2 - 4
-8 '.,'.; a - b + c '.,'.; 18 Then, x = - - when K is even and ln !J.ORS,
We conclude a - b + c is either 0 or 1 1 . 2
4
OR = OP - RP
K -5· . Odd.
Now, putting b = a + c in Eq. (i), w e get - - lS When K lS
4 ⇒ OR = 3 - 2 = 1 [·: RP = SQ = 2]
lOOa + lO(a + c) + c = l l [a2 + (a + c)2 + c2] ⇒ OS = 3 + 2 = 5
⇒ 2a2 + (2c - 10) a + 2c2 - c = 0 RS2 = PQ 2 = OS2 - OR2
:. The first two terms of this expression are
K = 100 which is even. = (5)2 - (1)2 = 25 - 1 = 24
even third term should be even as well
2 ⇒ PQ = HA = 2-16
⇒ c is even . . m
:. Pos1tive . tegers of x = -100- - 4-
D = (2c - 10)2 - 4 x 2(2c2 - c) 4 ln !J.SMT,
= 4(-3c2 - Sc + 25) is a square of c = 0 = (25)2 - 1 = 2500 - 1 SM = QM - SQ
When c = 0 = 2499 = 45 - 2 = 25
2a2 - 10a = 0 ⇒ a = 5, a "# 0 1 1 . (c) Reflect the heptagon with AG as [·: QM = AP - BT]
b = a + c⇒b= 5+ 0= 5 an axis to obtain another heptagon ST = 2 + 15 = 3.5
:. Number are 550
AB'C' D' E' F'G' MT 2 = ST 2 - SM2
Now, when b = a + c - 1 1 = (3.5)2 - (25)2
:. 2a 2 + (2c - 32a) + 2c2 - 23c + 1 3 1 = 0 = 12.25 - 6.25 = 6
D = 4(-3c2 + 14c - 16) is square c = 3 MT = ./6
2a2 - 26a + 80 = 0, a = 5, a "# 8 D D' AB = AN + NB
b= a+ c = 5+ 3 = 8 = PQ + MT
Number are 803 = 2-16 + ..J6 = 3./6
Sum = 550 + 803 = 1353
WWW.JEEBOOKS.INl
13. (c) Given, 4 x 4 x 4 cubes is made 64 1

⇒ cos (a + �) = - and cos (a - �) = 1 2 1 . (a) By momentum conservation,
faces 1 x 1 x 1 cubes. 2 4v = (A - 4)v'
Total cubes = 64, White = 20, Red = 44 a+�= � , 4v
A-4
3 ⇒ V = -
1 6. (b) dU = _! ( g ) - A - dx
To find minimum number of visible white
22. (c) Heat required to melt ice
2
m x
2 9A
box counting total visible faces of unit
cube. = Q1 = mL = 30 x 80 = 240 cal
Total number of faces of small cube on u = � m2g2A r l x2 dx Heat taken by water formed to reach at
bigger cube except boundary cubes 2 l2A 2l' J o 100° C, Q2 = ms!J.T = 3000 cal
= 4 x 6 = 24 m2g 2l Heat given by steam on condensation
=
Counting boundary cubes 6AY = Q3 = mL = 25 x 540 = 13500 cal
= 16 + 8 + 8 = 32 1 7. (a) Ice melts at lower temperature As heat taken by ice is less than heat
:. Total visible faces = 56 due to increase in pressure. As wire given by steam on condensation. So,
But we have 44 red cube. passes, the water formed is again freezes resulting mixture is at 100°C.
:. Minimum number of white faces cubes
and hence wire passes without cutting Steam condensed
ice.
1 8. (a) Conservation of energy gives,
which are visible = 56 - 44 = 12 Maximum heat absorbed by ice
14. (d) Let x minute will be taken. In Latent heat of vapourization
-.! mu 2 = /J.U = 5400 = 10g
one minute A can fill the J:_ part of 2
60 50
tanker and in one minute B can fill the ⇒ � mu 2 = nCv!J.T So, resulting mixture contains
1
- part of tanker. 2 (30 + 10 = 40 g) of water and
40 (25 - 10 = 15 g) of steam at 100°C.
Both can fill in t minute
23. (a) For a freely falling body,
_!_ + _!_ = 1 distances travelled in each successive
60 40
second increases in the ratio of successive
⇒ t = 24 min odd integers.
Both can fill in one minute � part of i.e. Si :&i: s3 :s4 : s5 :s6 :s7 : : 1 : 3 : 5 : 7 : 9 : 1 1 : 13
24 21 2 9
=-=- ⇒
S
-5 = - ⇒ S7 = - S5
13
tanker 10 1
1 9. (d) We plot process along with
s7 13 9
isotherms. 24. (b) For successful rotation,

l!J,ottom = .J5il
p
Vtop = .fgl
These values are minimum possible
values.
⇒ x = 30 min So, ratio of kinetic energies,
15. (c) We have,
1
-m 2
Kbottom = 2 lJJ,ottom
= 5 :1
⇒ cos2 a + cos2 � = � Ktop 1 mv2
2 2 to p
1 + cos2a 1 + cos2� 3 Clearly, temperature initially increases
⇒ - - - + ---- = - 25. (a) Wooden block sinks, when
2 2 2 then decreases.
20. (c) Linear momentum is conserved in
Density of wood = Density of benzene
⇒ cosfu + cos2� = 1 Pw Pb
⇒
⇒ 2 cos (a + �) cos (a - �) = 1 the horizontal direction. 1 + rw!J.T 1 + 7i,/J.T
⇒ cos (a + �) cos (a - �) = _! ... (i) ⇒ mv0 sin 37° + 0 = m V - mv sin 37°
2 ⇒ = 21. 7°C
Along common normal, Pw rw - Pb rb
and sina sin � = � e(v0 - 0) = V sin 37° + v So, at 22°C wood block sinks in benzene.
26. (c) m = k p0gV
4 27 11
⇒ V=- v0 and v = - v0
⇒ 2 sina sin � = � 34 34
2
So, impulsive tension ⇒ [M] = [MaL-3 a + b + cT-2b - c ]
1
⇒ cos (a - �) - cos (a + �) = - ... (ii) ⇒ a = 1, b = - 3, c = 6
1)
2 = mv0 cos 37° + mvcos37°
m oc v6
27. (b) After a long time, terminal
From Eqs. (i) and (ii), we get = mv0 ( � ) + mvo ( �! x
G�)
cos (a + �) cos (a - �) - cos (a - �) velocity is attained to kinetic energy is
+ cos (a + �) = 0 = mv0 constant and only potential energy is
dissipated at a constant rate.
WWW.JEEBOOKS.INl
28. (d) 2wx = wG - x) ⇒ x = i 35. (c) If the specie is a reducing agent, 39. (a) 1 mole of Al requires
it means it can be oxidised easily thus it = 3 x 96500 C
should have an oxidation number less
D 10-3 moles of Al requires
than the maximum values of oxidation
C = 3 x 96500 x 10-3 C
number. Oxidation number of S in the
given species are = 3 x 96.5 C [lC = As]
(i) S02 = 3 x 9.65As
x + 2(-2) = 0 3 x 96.5 As = 30 s
Time (s) =
2- x
x=+ 4 9.65 A
29. (d) As total energy of system (U + K)

(ii) sot 40. (c) The IUPAC name of the following
X + 3(-2) = - 2 compound is
is negative for all values of r, system is a
bound system. x- 6= - 2 1
30. (c) From ray diagram, x=+ 4 6�
(iii) H2 S04
3, 4, 4-trimethylhex-1-yne .
4 1 . (a) Aldehydes or ketones having
A 2(1) + X + 4(-2) = 0
2+ x- 8= 0
atleast one a -H atom undergo aldol
x=+ 6
- condensation. The structures of given
(iv) S2
(a) HCH (c) H3C-CH- CH
compounds are as follows:
x=- 2
0 CH3 0
As the maximum value of oxidation
number of S is - 2. Thus, H2S04 can not
II I II
Methanol 2-methyl pentanal
B act as a reducing agent.
Distance, AB = d + d + d = 3d
(No a-H atom) (1-a-H atom)
to its energy by the equation E = he 0
36. (d) The wavelength of light is related
:. Distance required = 3 m. ')..,, Ph
3 1 . (d) Lattice energy is defined as the Given, ')..,, = 45 nm I
amount of energy required to completely = 45 x 10-9 m (b) (d) CH�C-CH3
0
seperate one mole of a solid ionic [·: 1 nm = 10-9 m] II
compound into gaseous constituent ions. Cyclohexanone
It is directly proportional to the charge of 6.63 x 10-34 Js x 3 x 108 ms-1 (4-a-H atoms) 1-phenyl propanone
Hence, E = - - - - - - - - - -
the ions. Thus, greater the ionic charge, 45 x 1 0-H m (5-a-H atoms)
larger is the lattice energy. = 442 X 10-18 J Thus, among the given compounds,
Hence, correct order is 37. (a) N2 + 3H2 ---t 2Nlia methanal has no a-H atom.
Al203 > CaO > MgBr2 > NaCl Hence, it will not give aldol condensation.
32. (a) One mole of ideal gas at STP 42. (b) Compound II is most basic among
6 g of hydrogen produces 34 g of NIia
:. 450 g of hydrogen produces
(22.4 L) contains 6.022 x 1023 atoms 34 the given compounds. This is because the
= - X 450 = 2550 g of NIia lone pair present on nitrogen in pyridine
i.e., 6.022 x 1023 atoms are present in 6
22400 mL. does not take part in delocalisation and
Actual ammonia produced in the solution
hence they are available for donation.
:. Average volume per molecule = 1575 g
22400 Whereas, in compound I and III the lone
cm3 1575 pair on N atom takes part in resonance
6.022 X 1023 % yield = x 100
2550 and will not be available for donation, so
= 3. 72 x 10-20 cm3 = 61. 76 % = 61.8% their basicity will be less.
33. (c) Intensive properties are those 38. (d) The possible isomer of C2BrClFI 43. (a) In Clemmensen reduction,
properties which do not depend upon the are as follows ketones are reduced to alkanes with the
quantity or size of matter. Among the help of Zn-Hg in the presence of HCL
given quantities, boiling point (I), pH (III) For example,
and emf (IV) are intensive properties
whereas entropy (II) is an extensive Zn-Hg
property. HCI
34. (a) Number of radial nodes
= n - l- 1 44. (b) Higher the reduction potential of
For 3 s-orbital a metal, lesser will its reducing power.
n = 3, l = 0 Br I As the reduction potentials of a metal is
/
(v) decreasing in the order Y > X > Z, thus
"--
:. Number of radial nodes = 3 - 0 - 1= 2 C=C
For 2p-orbital,n = 2, l = 1
Cl / ,F
order Z > X > Y.
the reducing power will decrease in the
Therefore, the above compound has
Number of radial nodes = 2 - 1 - 1= 0 6 isomers.
WWW.JEEBOOKS.INl
45. (b) When white phosphorus is heated 53. (b) Water potential ('l/w ) is actually y
with caustic soda , then sodium determined by taking into account factors
hypophosphite with phosphine is formed. like osmotic (or solute) potential ('l's)
'
4P + 3NaOH + 3H20 ----t pressure potential ('l/ p) and matrix or
White Caustic capillary potential ('l/m ). The formula for
phosphorus soda
= 'l's + 'Ifp + 'lfm

NaH2P0 2 + Plfs calculating water potential is
Sodium Phosphine
'lfw
54. (c) Hydrogen bonding in DNA occurs
hypophosphite
46. (c) The filtration of blood at the

between complementary bases in order to Y'
(�r-�
glomerulus is a pressure dependent
keep the two strands of DNA helix
physical process known as renal Let E. = tan 0
ultrafiltration. The force of hydrostatic
together. These bonds occur as 2 a
pressure in the glomerulus (the force of hydrogen bonds between adenine and + 1 '.,'.; o
pressure exerted from the pressure of the thymine and 3 hydrogen bonds between
cytosine and guanine. 2
55. (b) Both sympathetic and

blood vessel itself) is the driving force ⇒ tan 0 - 4 tan 0 + 1 '.,'.; 0
that pushes filtrate out of the capillaries ⇒ tan 0 E [2 - ../3, 2 + ../3]
and into the slits in the nephron. 0 E [15° , 75° ]
47. (b) Grave's disease is an immune
parasympathetic preganglionic neurons ⇒
are cholinergic meaning they release
Area of region = � (32 - 22 )
system disorder that results in the Acetylcholine (Ach) at the synapse in the 3
control of skeletal muscles via activation

overproduction of thyroid hormones ganglion. Ach basic functions involve the � 51t
= (9 - 4) =
(hyperthyroidism). Its symptoms include 3 3
62. (b) Given,
anxiety, irritability, tremor, heat of the motor neurons as well as
sensitivity, enlargement of thyroid gland, stimulating the muscles of the body.
56. (b) Evolution is not goal oriented.
!!'. !!'..
change in menstrual cycle, etc. Si_ (n) = 8 + 12 + 16 + ... + n terms
48. (b) The 'imperfect fungi' belongs to Evolution simply depends on the Si_ (n) = [16 + (n - 1) 4] = (12 + 4n)
class Deuteromycetes. They are called as 2 2
environment, which the organisms live
!!'.. [34 + (n - 1) 2] = .!!'.

imperfect because sexual reproduction is and S2 (n) = 17 + 19 + 2 1 + ...+ n terms
and try to survive. The environment is fit
absent in these forms. They reproduce for strongest individual who can survive S2 (n) = (32 + 2n)
= S2 (n)
only by asexual spores called conidia. 2 2
49. (b) Presence of amniotic egg is not a
and reproduce. Evolution uses the theory
!!'.. (12 + 4n) = .!!'. (32 + 2n) ⇒ n = 10

of natural selection where there is Si_ (n)
characteristic of phylum Chordata. The variation. We have variations of traits,
four features shared by all chordates are heredity and different reproductive 2 2
presence of a single notochord, a dorsal strategies as a result of natural selection. Si_ (10) = 5(16 + 36) = 260 = S2 (10)
57. (a) The sucrose is actively
hollow nerve cord, pharyngeal slits and a
Common sum = 260
63. (c) If any
post-anal tail. Amniotic eggs are present
in reptiles, birds and mammals only. transported against its concentration statement is true, then
50. (c) TCA cycle or Citric acid cycle is a

gradient into the phloem cells using the remaining 2 are false.
series of reactions that produces one GTP
electrochemical potential of the proton 64. (b) Given, MBC is right angled at A.
gradient. This is coupled to the uptake of
or ATP as well as three NADH molecules A is centre of circle and AB is radius of
sucrose with a carrier protein called the
BD = 20
and one FADH2 molecule in each turn, circle.
sucrose-ff' symporter.
58. (a) A secretory cell would need
which will be used in further steps of
cellular respiration to produce ATP for CD = 16
the cell.
5 1 . (c) During anaphase-1, no crossing
secretory enzymes and glycoproteins
C
required in secretions, which are
produced in Golgi bodies.
59. (a) Riboluse 1,5-Biphosphate (RuBP)
over leads to segregation of alleles.
Anaphase-1 begins when the two
chromosomes of each bivalent (tetrad) is the first acceptor of CO2 in the
separate and start moving toward formation of two molecules of
opposite poles of the cell as a result of the 3 -Phosphoglyceraldehyde (PGA) during
action of the spindle, but their the Calvin cycle of photosynthesis.
60. (a) Horizontal stem of creepers often
centromeres are still attached.
52. (d) After vigorous exercise, excess F
In MBC, AC + r = BC
develop adventitious roots from the
oxygen is required by the body to make 2 2 2
= (36) 2
nodes. Adventitious roots are the roots
ATP for gluconeogenesis, to metabolise 2 2
CB and CF are secant of circle.

which arise from an organ other than a AC + r ... (i)
lactic acid, to replenish phosphocreatine
CE - CF = CD x CB
root. They generally develop from stem
and glycogen and to pay back any oxygen
nodes, internodes, leaves, etc.
6 1 . (d) Given, 4
that has been borrowed from
2 2
haemoglobin. '.,'.; a + b '.,'.; 9 ⇒ (AC - r) (AC + r) = 16 x 36
b2 - 4ab + a2 '.,'.; 0
2 2
and AC - r = 16 x 36 ... (ii)
WWW.JEEBOOKS.INl
1 78 KVPY Practice Set l Stream : SA
72. (c) 16.9% solution of AgNO3 means

2AC2 = 36(36 + 16) = 36 x 52
From Eqs. (i) and (ii), we get Time at which bullet and block collide is
t = i = ___!QQ__ = l s 16.9 g AgNO3 is present in 100 mL
⇒ AC = 6-126 V 100 - 0 solution.
= gt = 100 ms-1
65. (a) We have, Speed of wood just before collision :. 8.45 g AgNO3 will be present in 50 mL
Speed of bullet at t = l s is
(1 + 2x + 3x2 + . . . + 2 1x20 )2 solution.
= (1 + 2x + 3x2 + . . . + 2 1x20 )
= v - gt = 100 - lO x 1 = 90 ms-1 .
Similarly, 5.8 g NaCl is present in
(21x20 + 20x19 + . . . + 3x2 + 2x + 1)
100 mL solution.
Let v' = velocity of bullet + block system :. 2.9 g NaCl is present in 50 mL solution.
Coefficient of :x:3° is after collision. Then, by momentum
l l x 2 1 + 12 x 20 + ... + 2 1 x 1 1 AgNO 3 + NaCl ➔ AgCl + NaNO 3
conservation, we have
= 2(1 1 x 2 1 + 12 x 20 + 13 x 19 + 14 x 1 8 Initial 8.45 2.9 0 0
- (0.03) X 10 + (0.02) X 90 = (0.05) v' moles 169.8 58.5
+ 15 X 17) + 16 X 1 6 ⇒ v' = 30 ms-1 = 0.049 = 0.049
= 2(23 1 + 240 + 247 + 252 + 255) + 256 Now, maximum height reached After
= 2(1225) + 256 = 2450 + 256 = 2706 reaction 0 0 0.049 0.049
66. (b) Given situation is
=- v2 - distance through
2g Mass of compound = moles x molar mass
which block fells in 1 s
30 X 30
:. Mass of AgCl precipitated
2
=( ) - ( � X 10 X 1 ) = 45 - 5 = 0.049 x 143. 5 = 7.03 g
73. (d) The species formed after removal
B' A' A B 2 x 10 2
= 40 m
70. (b) M = kFaIJT c
C F of an electron from the given diatomic
(a) C2 - ➔ c; + e-
molecules are as follows
where, k is a constant.
By mirror formula, [M] = [MLT-2]° :Ll'Tc (b) CN - ➔ CW + e-
1 - 1 = 1 5/ Equating dimensions, we have (c) N2 - ➔ N; + e-
a= 1 (d) 02 - ➔ o; + e-
- ⇒ 14J = - -
% fj_ f f 2 . . . (i)
b+ a = 2
3
t( � - 2) = �
. . . (ii) The stability of diatomic molecule can be
Hence, image length is l' = -2a + c = 0 . . . (iii) determined by calculating its bond order.
f /2 = -3 Putting value of a from Eq. (i) in Eq. (ii), More is the bond order, more is the
. m = -l' = -
l f/3 2
. 1s
S o' magnifi1cat1on stability of a molecule.
we get
b+ a = 0
1
67. (b) Coordinates of points P and Q are
B.0 = - (Nb - Na )
b+ 1= 0
2
P : ( � , 0, � ) and Q : ( � , 1, 0) b = -1 . . . (iv)
:. The bond orders of diatomic molecules
Again putting value of a from Eq. (i) in

with their ionic species are given below.
So, unit vector along PQ is Eq. (iii), we get B.O
-2a + c = 0
--a :J + ak
- ' (i) C2 2.0
PQ = PQ = 2 2
-2 x l+ c = 0
(ii) c� 1.5
-2 + c = 0
I PQI la2 a2 (iii) CN 2.5
+
c= 2
t4 4 (iv) CN+ 2.0
= "'2 <- J + k) ⇒ a = 1, b = -land c = 2
(v) N2 3
68. (a) By KVL, 11 = -
10 (vi) N; 2.5
So, [M] = [FL-1 T 2]
71 . (a) From ideal gas equation,
fl_ = ffRi = lOO X 20 = 5 W
20 (vii) 02 2
o;
pV = nRT
⇒ (viii) 2.5
pV
400
when an e- is removed from 02 molecule
As the bond order increases from 2 to 2.5
1 0 1 x l05 N - m-2 x 10 x 10-3 m3
RT
and 12 = 0 ⇒ P2 = 0 n = - = ------------
69. (b)
8. 314J mol-1 K-1 x 300 K (O; ), so it become stabilised.
u=O
= 0.405 mol
,
[lN - m = 1 J] 74. (a) Calcium carbide on hydrolysis
For monoatomic gases, CP = fj_R = 2 .5R gives acetylene as a major product which
2
T1 = 300 K and T2
then reacts with dil H2SO4 in the
R = 8. 314J moi-1 K-1

= 400 K presence of HgSO4 to give acetaldehyde.
CaC2 + 2H2O ---t C2H2 + Ca(OH) 2
1 00 m Calcium
t.S = 2. 303 nCP log T2
(X)
carbide Acetylene
Tl
400 ffiH dil H2S04/HgS04
= 2.303 X 0.405 X 2. 5 X 8.314 log -
v = 1 00 ms-1 300 CH
(Y)
t.S = 2. 422 JK-1 Acetaldehyde
WWW.JEEBOOKS.INl
75. (a) As only one structure of B with 76. (d) ABA or Abscisic Acid promotes water is neither acidic nor basic, but
have Ir = Oir.
neutral. Therefore, water at 25° C will
thus the structure of B would be
molecular formula C5 H11 Cl is possible, leaf senescence independent of ethylene.
79. (c) Acoelomate Animals like

Other statements can be corrected as
I
CH3 Gibberellins play the most important role
in flowering. It is seen that treatment of sponges, coelenterates and flatworms are
CHa - - CH2 Cl. gibberellin on biennials or long day without a coelom or any other internal
?
plants, stem elongation occurs before cavity except the digestive tract.
CH3
flower primordia are formed. Auxin and Pseudocoelomate Roundworms have a
I
CH3 cytokinin promote cell division. body cavity derived directly from the
Light It is seen that ABA and ethylene can blastocoel of the embryo. It is called
CHa - - CH + Cl 2 < control and induce root and shoot growth
? 3 pseudocoel because like true coelom, it is
under water stress or low water not lined by peritoneum but is bounded
CH3
77. (b) The cross for the given question

(A) potential. with ectoderm on the outer side and
endoderm on the inner side.
would be Coelomate Animals with a tube within a
xhcx X X y tube body plan have a fluid-filled body
cavity between the body wall and the
digestive tract as like in earthworms. It
xhcx xhcy XX is derived from embryonic mesoderm and
XY
Wurtz 1 Colourblind Colourblind Normal Normal is lined by peritoneum.
80. (d) A dipeptide is made up of 2
reaction Na I ether
haemophilic haemophilic girl boy
carrier girl boy
CH3 CH3
-?-
amino acids which may be same or
I I :. The progeny be 50% haemophilic
different. The total possible number of
CHa - - CH2 -CH2 Clia colourblind sons and 50% colourblind
?
carrier daughters. different dipeptides that may be
78. (d) In pure water, the concentration
CH3 CH3 assembled from 20 different amino acids
= 2Q2 = 20 X 20 = 400
will thus be
(C) of hydrogen ions and concentration of
hydroxyl ions are equal. Consequently 20n
WWW.JEEBOOKS.INl
KVPY
PRACTICE SET 2
Stream :SA
M M : 100
Instructions
MATHEMATICS 4. Difference between the corresponding roots

1. The remainder when 599 is divided by 13
:c + ax + b = 0 and :x? + bx + a = 0 is same and a ,t. b,
(a) 6 (b) 8 then

(c) 9 (d) 10 (a) a + b + 4 = 0 (b) a + b - 4 = 0
2. A polynomial p(x) when divided by :c - 3x + 2 leaves (c) a - b - 4 = 0 (d) a - b + 4 = 0
5. Let P be a point in the interior of the rectangle
remainder 2x - 3, then ABCD, which of the following sets of numbers can
(a) p(x) must have a root between 0 and 3 form the areas of the four triangles PAB, PBC, PCD,
(b) p(x) cannot have a root between 0 and 3 PDA in same order
(c) p(x) must have a real root but may or may not be (a) 10, 9, 12, 5 (b) 21, 15, 6, 12
between 0 and 3 (c) 10, 9, 8, 6 (d) 12, 8, 7, 5
6. Let Xi_, ;s, . . . , xn be n observation such that
(d) p(x) need not have a real root
3. A shopkeeper increases the price of a commodity by n n
x% some time later, he reduces the new price by y% L, x'f = 400 and I, X; = 80. Then, a possible value of
n among the following is
and notices that the price is now the same as it was i=l i=l
originally. The value of ! - ! is (a) 15 (b) 18 (c) 9 (d) 12

y X
7. The set S = {1, 2, 3, . . . , 12} is to be partitioned into
1
(a) - -_ (b) 0
three sets A, B, C of equal size. Thus, A u B u C = S,
A n B = B n C = A n C = q>. The number of ways of
100
partition S is
1
(c) -- (d) None of these
(d) 12!4
100
(a) � (b) �4 (c) 12!3
3! (4!)3
3! (3!) ( 4!) (3!)
WWW.JEEBOOKS.INl
KVPY Practice Set 2 Stream : SA 181
8. You have a measuring cup with capacity 25 ml and

another with capacity 110 ml, the cups have no
PHYSICS
markings showing intermediate volumes. Using large 16. A box is falling freely inside the box, a particle is
container and as much tap water as you wish. What projected with some velocity v with respect to the box
is the smallest amount of water you can measure at angle 0.
accurately?
(a) 1 ml (b) 5 ml
(c) 10 ml (d) 25 ml
V
9. Let A, B, C, D be collinear points in that order.
Suppose AB : CD = 3 : 2 and BC : AD = 1 : 5. Then,
AC : BD is
(a) 1 : 1 (b) 1 1 : 10 For an observer sitting in the box, path of particle is
(c) 16 : 1 (d) 17 : 13
(a)
10. Let ABC be triangle with AB = AC = 6. If the
circumradius of the triangle is 5, then BC equals
(a) 25 (b) 9
3
(c) 48 (d) 10
5 17. Potential energy of a system as a function of a
11. Two cars start together in the same direction from parameter x is U (x) = (x + 1) (x + 2).
the same place. The first goes with a speed of Then, consider following statements:
10 km/h. The second goes at a speed of 8 km/h in the -3
I. Point x = , corresponds to an equilibrium
first hour and increase the speed by � km each 2
2 position.
succeeding hour.
II. Points x = - 1 and x = - 2, corresponds to
After how many hours will the second car overtake equilibrium position of system.
the first, if both go non-stop. -3
(a) 9 h (b) 5 h III. At point x = , system is in stable equilibrium.
2
(c) 7 h (d) 8 h -3
.
IV. At pomt x = - , system 1s . m
. unstable
12. If x, y are natural numbers such that :x? + 2013 = /, 2
then the minimum value of xy is equilibrium.
(a) 645 (b) 658 (a) All statements are correct
(c) 668 (d) 671 (b) Statements I and IV are correct
13. A cube has each edge 2 cm and a cuboid is 1 cm long, (c) Statements I and III are correct
2 cm wide and 3 cm high. The paint in a certain (d) Only statement II is correct
container is sufficient to paint an area equal to 18. On a temperature scale X, water boils at - 60° X and
54 cm2 • Which one of the following is true? freezes at - 180° X. What would be a room
(a) Both cube and cuboid are painted temperature of25 ° C on X-scale?
(b) Only cube can be painted (a) - 18° X (b) - 38° X (c) - 150° X (d) -130° X
(c) Only cuboid can be painted 19. In given nuclear reaction,
(d) Neither cube nor cuboid can be painted
i
� Be + a ➔ 2c + X, particle X is
14. How many positive real number x are there such that
(a) �He (b) �1 e (c) � H (d) � n
(x/ ✓x = (x✓x/?
20. Two blocks of masses 0.2 kg and 0.5 kg are placed
(a) 1 (b) 2 22 m apart on a rough flat horizontal surface (µ = 0.5).
(c) 4 (d) Infinite At time t = 0, blocks are pushed towards each other
15. Let O < a < b < c be three distinct digits. The sum of with equal forces of 3 N on each of the block.
all 3-digit number formed by using all the 3-digit Blocks collide with each other in time duration
number once each is 1554. The value of b is (a) 1 s (b) -J2 s
Wl �2 �3 00 4 (c) J3 s (d) 2 s
WWW.JEEBOOKS.INl
182 KVPY Practice Set 2 Stream : SA
21 . A table-tennis ball is floating in air by a jet of water (a) 1 (b) 0.5

emerging from a nozzle. (c) 0.25 (d) 1.25
-. }Jt.- T 26. If a low pressure centre is developed in atmosphere

(very common in India in summer), the wind will flow
\M/ I
radially towards centre. The whirlpool of wind
'"'" formed will rotate in India as
(a) clockwise only
Ground (b) anti-clockwise only
(c) clockwise or anti-clockwise
®
level
(d) whirlpools are not formed in India
27. Which of these paths correctly describes motion of
If mass of ball is m and water stream rises to height h
moon around observed from a space station?
above ground, then water flow rate is
m Hh
(a) -
.J2
-
m lg
(b) -
.J2
-
( a) ®
oo c
( b) Moo e
(c) m.J2gh (d) mfff
22. A system under goes three processes listed in table (c)

below. All quantities are (in kJ). (d)
Process !:,.Q t,.W t,.U
Process 1➔ 2 a 100 100
Process 2 ➔ 3 b - 50 C
Process 3 ➔ 1 100 d - 200 28. Correct variation of velocity of a table-tennis ball
Then, value of c is
dropped from top of a 14-story building is
V
( a) V (b)
(a) 200 kJ (b) 50 kJ
(c) 100 kJ (d) 0 kJ
10 ms-2 vertically upwards is (Take, g = 10 ms-2)

23. Force necessary to accelerate a mass of 1 kg at
(a) 1 N (b) 2 N (c) 10 N (d) 20 N (C) V

V
24. In Rutherford's scattering experiment, choose the (d)
correct statements are given below.
I. Only a-particles are scattered backwards but
not protons.
II. a-particles cannot be effectively scattered by 29. A vessel with water is placed on a weighing pan, it
volume 50 cm3 is kept immersed in water by tying it

electrons because a-particles are positively reads 600 g. Now a hollow ball of mass 40 g and
charged.
-
9.6 x 10-15 m to 4.8 x 10-15 m.
III. Radius nucleus of target is between to bottom with a thread of negligible mass.
-· -- - - -- -- -- -- -- -- -- - · -· -· -· -· -· ·· -· · · -- ·- --
::.·::::::O::::·.·.·::
-- -- - - -- -- -- -- -- -- - - -- -- -- -- -- -- -- .- --
IV. a-particles with energy greater than a certain --- ------ - - - - - - -- -
--- --- - -- --· --- --- --- --- -·- --- - - -- --- --- --- --- --- - -- -·- --- ---
critical value are not scattered back. -- -- - - -- -- -- -· -- -- -- - .-. -. -. -. -. -. - . -. -. -.
(a) Only statement II is correct

� �
(b) Only statement III is correct
(c) Statements I, III and IV are correct
(d) All statements are correct Reading of pan is now
(a) 690 g
25. The ratio of the height above the surface of earth to
(b) 550 g
the depth below the surface of earth for gravitational (c) 650 g
acceleration to be same (assuming small height) is (d) 610 g
WWW.JEEBOOKS.INl
30. Plane face of a plano-convex lens is silvered. Given, (b) 3, 5-dimethyl-1-cyclohexene

radius of convex face is 12 cm and refractive index of (c) 1, 5-dimethyl-5-cyclohexene
medium is 3 /2. (d) 1, 3-dimethyl-5-cyclohexene
36. Which of the following isomerisms is shown by
pentan-2-one and 3 -methylbutanone?
(a) Stereoisomerism (b) Position isomerism
(c) Functional isomerism (d) Chain isomerism
37. What is the maximum number of orbitals that can be
Power of resulting system is identified with the following quantum numbers?
(a)
25 D
(b) - 25 D n = 3, l = l and mz = 0
3 3 (a) 1 (b) 2
- 25 25 m (c) 3 (d) 4
(c) - m (d)
3 3 38. The major product of the following reaction is
CHEMISTRY
_CiJ_o_
3 --➔
CH CH= CHCH2Clla
3 (ii) hydrolysis, Zn
(a) Clla CHO + Clla CH2CHO
31. By heating 10 g CaCO3 , 5.6 g CaO is formed. The (b) CHa COOH + CHa COCHa
weight of CO 2 obtained in this reaction is closest to (c) Clla COOR + Clla CH2COOH
(a) 5.6 g (b) 2.4 g (d) CHa COOH + CO2
(c) 4.4 g (d) 3.6 g
39. Among the following, which is an incorrect statement.
32. Which of the following plot obeys the Raoult's law at
(b) pre - drc bonds are present in S02
(a) PH,, and BiC15 do not exist
all concentration?
L
'"Q);:, '" (c) SeF4 and CH4 have same shape
a'" a
Q)
;:, (d) � has bent structure
(b) ;:,'"
00 00
00 00
Q) Q)
40. Predict the effect of increased pressure on the

"'" '""'"
(a)
;:, following reaction equilibrium,
0
> � 2SOig) + Oig) � 2SO3 (g)

Mole fraction of solvent Mole fraction of solvent (a) equilibrium shift to the right
'" '"
(b) equilibrium shift to the left
(c) no effect on equilibrium
'""'"
Q) Q)
� �
'" (d) "'"
'";:,
00
Q)
00
Q)
(d) reaction stops
41. The solubility product of BaC12 is 4 x 10-9 _ Its
"'" '""'"
(c)
'"
0
solubility in mol L -1 is
> > (a) 4 x 10-3 (b) 4 x 10-9
Mole fraction of solvent Mole fraction of solvent (c) l x 10- 3 (d) l x 10-9
33. The correct order of increasing ionic character is 42. Chlorobenzene on treatment with sodium in dry
ether gives diphenyl. The name of the reaction is
(a) BeC12 < MgC12 < CaC12 < BaC12
(b) BeC12 < MgC12 < BaC12 < CaC12 (a) Fittig reaction
(b) Wurtz-fittig reaction
(c) BeC12 < BaC12 < MgC12 < CaC12
(d) BaC12 < CaC12 < MgC12 < BeC12 (c) Sandmeyer reaction
3Br2 + 6COt + 3H2O -----t 5Br- + BrO3 + 6HCO3

(d) Gattermann reaction
34. In the reaction,
43. A sample of unknown gas is placed in a 2.5 L bulb at
a pressure of 360 torr and at a temperature of 22.5°C
(a) Bromine is oxidised and the carbonate radical is reduced
and is found to weight 1.6616 g. The molecular
(b) Bromine is reduced and the carbonate radical is oxidised
weight of the gas is closest to
(c) Bromine is neither reduced nor oxidised
(d) Bromine is both reduced and oxidised (a) 80 g (b) 55 g
(c) 34 g (d) 55 g
35. IUPAC name of the following com pound
44. Consider the isoelectronic ions
K+ ,s2- , c1 - and Ca 2+
IS The radii of these ionic species follow the order
- -
(a) Ca 2+ > K+ > Cr > S2 (b) Cr > S2 > K+ > Ca 2+
2- + 2+ + -
(c) S > Cr > K > Ca (d) K > Ca2+ > S2 > Cr
(a) 3, 5-dimethyl cyclohexene
WWW.JEEBOOKS.INl
45. The reaction of toluene with Cl2 in the presence of (a) � (b) � (c) X (d) 2x
FeCia gives predominantly 4 2
(a) benzoyl chloride (b) benzyl chloride 53. Kreb's cycle was discovered by Krebs in pigeon
(c) o and p-chlorotoluene (d) m-chlorotoluene muscles in 1940. Which step is called gateway
step/link reaction/transition reaction in respiration?
BIOLOGY
(a) Glycolysis
(b) Formation of acetyl Co-A
46. Most common type of phospholipids in the cell (c) Citric acid formation
membrane of nerve cell is (d) ETS terminal oxidation
(a) phosphatidylcholine (b) phosphatidylinositol 54. Which homeostatic function of the liver is controlled
(c) phosphatidylserine (d) sphingomyelin and monitored in the pancreas?
47. Graft rejection does not involve (a) Deamination of amino acids
(b) Release of glucose
(a) erythrocytes
(c) Release of iron
(b) T-cells
(d) Release of toxins
(c) macrophages
(d) polymorphonuclear leukocytes 55. During generation of an action potential,
depolarisation is due to
48. Horse-shoe crabs belong to the group + +
(a) K efflux (b) Na efflux
(a) Onychophora (b) Chelicerata + +
(c) Na influx (d) K influx
(c) Uniramia (d) Crustacea
56. If liver from body is removed then which component
49. The first living being on the earth were anaerobic
of blood increases?
because
(a) Ammonia (b) Protein
(a) there was no oxygen in air
(c) Urea (d) Uric acid
(b) oxygen damages proteins
(c) oxygen interferes with action of ribozymes 57. In his classical experiments on pea plants, Mendel
(d) they evolved in deep sea did not use
50. The presence of Salmonella in tap water is indicative (a) seed shape (b) flower position
of contamination with (c) seed colour (d) pod length
(a) industrial effluents (b) human excreta 58. In phylum, which group contains the greatest
(c) agricultural waste (d) None of these number of species?
51. The secondary order of protein structure is
(a) Class (b) Family (c) Genus (d) Order
(a) the sequence of amino acids in the polypeptide chain 59. Cell division is initiated by
(b) the formation of peptide bonds between amino acids (a) centrosome (b) centromere
(c) the coiling of the polypeptide chain (c) centriole (d) None of these
(d) the folding of the coiled polypeptide chain 60. The part of human hindbrain that is responsible for
hand-eye coordination is
52. The amount of DNA in a mammalian cell in early
prophase-I is x. What is the amount ofDNA in the (a) cerebellum (b) pons Varolii
same cell in anaphase-I of mitosis? (c) medulla oblongata (d) thalamus

MATHEMATICS 63. If there are three different kinds of mangoes for sale
in a market. Then, number of ways of purchase of
61. A circle is inscribed in an equilateral triangle with
side length of 6 units. Another circle is drawn inside 25 mangoes are
the triangle (but outside the first circle), tangent to (a) 2925 (b) 325
the first circle and two of the sides of the triangle. (c) 351
64. Four natural number m, n if
(d) 2600
The radius of the smaller circle is
(1 - Yr (1 + yf = 1 + al y + a2 I + . . . and al = a2 = 10,
then (m, n) is
(a) � (b) � (c) _! (d) 1
62. If x2,J = 6. Then, the minimum value of 3x + 4y for

�3 3 2
(20, 45) (35, 20)

positive values of x and y is (a) (b)
(c) (45, 35) (d) (35, 45)
(a) 6 (b) 8 (c) 10 (d) 12
WWW.JEEBOOKS.INl
65. In a MBC, with LA = 90°, the bisector of the angle

B and C meet at P. The distance from P to the
When a very distant object is viewed by this lens
hypotenuse is 4'/2. The distance AP is

system, choose the correct option.
(a) Final image is formed at mid-point of lens separation
(a) 8 (b) 4 (c) 8,/2 (d) 4,/2 (b) Final image is virtual
PHYSICS
(c) Diverging lens increases the magnification five times
(d) Final image is inverted and diminished
cross-sectional area A, under an applied potential

66. A planet contains a single type of gas in its 70. Current is flowing through a uniform thick rod of
atmosphere having molecular mass of 1.38 x 10-28 kg.
Distribution of speeds in atmosphere is given below. difference V across its ends.
1 Percentage of molecules
Speed (ms- )
100 10
200 30
500 20
+ -
800 20
1000 20 V
1 Let electrons flow through the thick rod with velocity
Escape speed for the planet is 900 ms- . Assuming
stable atmospheric conditions, the possible estimated vd . A hole is drilled in the rod and its central portion
I A
of area - is removed.
reduction in temperature of the planet in few years
2
will be (Use, temperature,
velocity vd • Then, ratio vd I vd will be
Let electrons flow through the hollow rod with
m 23
T = v2nns and KB = 1.38 x 10- ) 2 2 i
K
3 B
(a) 100 K (b) 200 K (c) 70 K (d) 20 K (a) 2 (b) _! (c) 1 (d) 4
2
drafting hangs from rest from a peg P as shown
CHEMISTRY
67. A right angle ruler used generally in tailoring or
below.
p 7 1 . A bomb calorimeter has a heat capacity of 783 J0 c-1
and contains 254 g of water, which has a specific heat
of 4. 184 g-1 0c-1 . Heat absorbed/evolved by a
reaction when the temperature changes from 23.73°C
to 26.01 °C is closest to
(a) 1. 78 kJ absorbed (b) 2.42 kJ absorbed
(c) 1. 78 kJ evolved (d) 4.21 kJ absorbed
One arm is L cm long and other arm is 2 L cm long.

72. Isostructural species are those species which have
the same shape and hybridisation. Among the given
Value of angle 0 is such that
species, identify the isostructural pairs.
(a) tan0 = _! (b) sine = _! (a) NI<ii and B!<ii (b) BF4- and Ntt:
4 4
(c) BC13 and BrC13 (d) NIia and N03
(c) cos 0 = _! (d) sec 0 = _!
4 4 73. Which among the following will form geometrical
0
68. 1 kg of steam at 100 C and 101 kPa occupies 1.68 m3
° isomers?
space. What per cent of heat of vaporisation of water
is used for expansion of water into steam?
(a) Nearly 7% (b) Nearly 17%
(a) F\ (b) (c) � (d) H
(c) Nearly 70% (d) Nearly 12% 74. Consider the following reaction,
I
69. A telephoto lens system consists of a converging lens CH
(f = + 6.0 cm) placed 4 cm in front of a diverging lens
(f = - 2.5 cm).
(CH;iCH20-Na + )
I
CH;iCH20H
B --"--.c....____ CH C---Br ----- A
(Maior) (CH3CH20H) 3
(Major)
A and B respectively are

CH
---0- :i n-
(a) (Clla )3 COCH2Clia in both cases
(b) (Clla )2 C =CH2 in both cases
(c) (Clia )3 COCH2Clia and (Clia )2 C= CH2
f=6 cm f= -2.5 cm
(d) (Clia )2 C = CH2 and (Clia )3 COCH2Clia
WWW.JEEBOOKS.INl
75. Which of the following species contains equal number 77. Which one of the following genotypes cannot occur
of cr and 1t-bonds? amongst the offspring from a mating between a person
(a) HCO3 (b) Xe04 of blood group A and a person of blood group B?
(c) (CNh (d) CH2 (CN)2 (a) AA (b) AB (c) AO (d) BO
BIOLOGY
78. The weed killer DCMU blocks the flow of electrons
from the electron transport chains in
photophosphorylation. Why does this kill the plant?
76. A piece of mammalian tissue was homogenised and
(a) Active transport of mineral ions is prevented
subjected to differential centrifugation. The diagrams
(b) ATP and reduced NADP are not produced
below indicate the relative activity certain
(c) Photoactivation of the chlorophyll cannot occur
biochemical processes in these fractions. Which of the
(d) Photolysis of water does not occur
following fractions indicates the maximum hydrolytic
enzyme activity? 79. Which one of the following is the correct description
Activity of a certain part of a normal human skeleton?
Activity
(a) Parietal bone and the temporal bone of the skull are
(a) Nuclei (b) Nuclei joined by fibrous joint
(b) First vertebra is axis which articulates with the
Mitochondria Mitochondria
occipital condyles
Lysosomes Lysosomes (c) The 9th and 10th pairs of ribs are called the floating ribs
(d) Glenoid cavity is a depression to which the thigh bone
Ribosomes Ribosomes articulates
80. Which of the following statements correctly describes
Activity Activity a codon?
(a) A length of DNA which codes for a particular protein
(c) (d) Nuclei
(b) A part of the transfer RNA molecule to which a specific
Mitochondria Mitochondria amino acid is attached
(c) A part of the transfer RNA molecule which recognises
Lysosomes Lysosomes the triplet code on the messenger RNA
(d) A part of the messenger RNA molecule that has a
Ribosomes Ribosomes sequence of bases coding for an amino acid
Answers
PART-/
(b) 2 (a) 3 (c) 4 (a) 5 (b) 6 (b) 7 (c) 8 (b) 9 (d) 10 (c)
11 (a) 12 (b) 13 (a) 14 (b) 15 (b) 16 (b) 17 (c) 18 (c) 19 (d) 20 (d)
21 (a) 22 (c) 23 (d) 24 (c) 25 (b) 26 (b) 27 (d) 28 (d) 29 (c) 30 (b)
31 (c) 32 (c) 33 (a) 34 (d) 35 (a) 36 (d) 37 (a) 38 (a) 39 (c) 40 (a)
41 (c) 42 (a) 43 (c) 44 (c) 45 (c) 46 (a) 47 (a) 48 (b) 49 (a) 50 (b)
51 (c) 52 (c) 53 (b) 54 (b) 55 (c) 56 (a) 57 (d) 58 (a) 59 (a) 60 (a)
PART-I/
61 (a) 62 (c) 63 (c) 64 (d) 65 (a) 66 (c) 67 (a) 68 (a) 69 (c) 70 (c)
71 (d) 72 (b) 73 (a) 74 (c) 75 (b) 76 (c) 77 (a) 78 (b) 79 (a) 80 (c)
WWW.JEEBOOKS.INl
Solutions
1. (b) 599 = 59s . 5 = (52)49 . 5 ⇒a2 + � 2 - 2a� = '¥2 + 02 - 2yo 9. (d) Given, ABCD is collinear.
= (25) · 5 = 5(26 - 1) ⇒ (a + �)2 - 4a� = (y + o)2 - 4yo
a2 - 4b = b2 - 4a
49 49
C
= 5(26k - 1) [·: (a - ht = nk - (ht] :.AB + BC + CD = AD
A B
⇒
D
= 5 x 26k - 5 = 5 x 26k - 13 + 8 ⇒ (a2 - b2) + 4(a - b) = 0 AB 3

= 13(10k - 1) + 8 ⇒ (a - b) (a + b + 4) = 0 CD 2
:. When 599 is divided by 13 the ⇒ a + b+ 4= 0 [·: a "# b] BC 1
and
remainder is 8. 5. (b) P be an interior point of AD 5
2. (a) Let rectangle ABCD. AB 3
CD 2
⇒
p(x) = q(x) (x - 3x + 2) + (2x - 3)
AC - BC 3
2
p(x) = q(x) (x - 1) (x - 2) + (2x - 3) ⇒

BD - BC 2
p(l) = 0 + (2 - 3) = - 1
p(2) = 0 + (4 - 3) = 1 ⇒ 2AC - 2BC = 3BD - 3BC
⇒ BC = 3BD - 2AC ... (i)
BC 1
:. p(l) < 0 and p(2) > 0
AD 5
:. p(x) has one root lie between 1 and 2. and
5BC = AD
A B
:. p(x) must have a root lie between 0
and 3. :. Area of MPB + area of f..PCD
= Area of f..PBC + Area of t.PAB 5BC = AB + BC + CD

3. (c) Let the original price of commodity
⇒
=P :. In option (b), 2 1 + 6 = 15 + 12 ⇒ 4BC = AB + CD
Price of commodity when price x% increase :. Option (b) is correct. ⇒ 4BC = AC - BC + BD - BC
6BC = AC + BD
= p + x% of p = P(lOO + x) 6. (b) We have, ⇒ ... (ii)
100 From Eqs. (i) and (ii), we get
Price of commodity when price Y% Ln x,2 = 400and I,n x, = 80 6(3BD - 2AC) = AC + BD
decrease from the increase of x% i=l i=l
⇒ 18BD - 12AC = AC + BD
100 + _ _!___ P(lO0 + x)
x) We know, ⇒ 13AC = 17BD
=p( x
2 + X2 + 2 + . . . + X2 AC 17
⇒ Xi :i Xj
100 100 100
P(lO0 + x) 100 - BD 13
⇒
= (
y) n
10. (c) We have,

n
100 100 � ( .ti + x2 + - � + . . . + x, r
Given, the reduces price is equal to In MBC,
AB = AC = 6
original price. LX;2
( ) ue; 2
⇒ ->-
p ( 100 + X)(
100 - y)=p
2
n - n Circumradius (R) = 5
100 100 400 � (80)2 6400
100 + X) 100 - y) ⇒ ⇒ n� = 16
( ( =l n n2 400
100 100
n � 16
⇒ 1 + � - _J__ - �2 = 1 7. (c) The set S is divided into three
B�
100 100 (100)
equal size.
⇒ a C
�-L =� :. Each set has 4 elements.
100 100 (100)2 We know,
:. Total number of ways in partition is
abc
⇒ x- y=� R=
4t.
12c4 X sc4 X 4C4 .
100
1 1 1 12! 8! 4! 12!
. . de by xy, we get - - - = -
D1vi - X - X - = --
y X 100 4! 8! 4! 4! 0! 4! (4!)3
4. (a) Let a , � are roots of equation a. (b) Put x time of water of 110 ml to
x2 + ax + b = 0 container and take y time of water of
a + � = - a, a� = b
25 ml from container.
Then, container contains 1 10x - 25y
⇒ 5=
36a
and y, o are roots of equation
x2 + bx + a = 0
= 5(22x - 5y) (12 + a) (a) (a) (12 - a )
4 i
y + o = - b, yo = a
Given, I a - � I = I y - o I
:. Container contains multiple of 5. \ 16
:. Smallest amount of water be measure 36
⇒ 5 = --,==--
(a - �) 2 = (y - o)2
accurately 5 ml. \I1 l 4 4 - a2
WWW.JEEBOOKS.INl
- F + µ"½g _
x (-!x - �) = 0
5
a2 _
2
"½
36 - --- �- - - 1ms-
2
⇒ 144 - a2 = ( )
36 ⇒ ✓X = � , x ;t O ⇒ x = � Now, from equation of motion, we have

⇒ a2 = 144 - ( 2 4
5r s = ut + .! at 2
:. Hence, two solution x = 1, � 2
22 = 0 + _! (10 - (- 1)) t 2
144 X 16 4
= 144 (l - � ) =
1 5. (b) Given, 0 < a < b < c
25 25
2
⇒ ✓
a2 = 144 x 16 = 48 Here, a, b, c are distinct. ⇒ t = 2s
2 1 . (a) Force on ball, F = v
25 5 11m
:. Three digits number formed by using a,
t hours. llm = flow rate of water.

1 1 . (a) Let the second car overtakes in b, c where digits are not repeated is 3! = 6 M
Sum of all the three digits number are where, -
llm =
:. Distance covered by first = Distance M
u- mg
2! (a + b + c) (102 + 10 + 1)
= 2(a + b + c) (100 + 10 + 1)
i)
covered by second car
lOt = 8 + ( 8 + + (8 + 2 G)) = 222(a + b + c)
⇒
llm = mg = _111,_ �
M
l)) ⇒
0
+ (8 + �) + . . . + (8 + ( t ;
Given, 222(a + b + c) = 1554 M ,J 2gh -J2 'Vh
22. (c) For a cyclic process,
1554 = 7
a+ b+ c=
lOt = St + _! (1 + 2 + 3 + . . . + t - 1)
222
1➔2➔3➔ 1
Lll U = 0
⇒ The possible digits whose sum seven are
(t) (t - l)
2
⇒ lOt = St + _!
1, 2, 4
b= 2 ⇒ 100 + c + (- 200) = 0 or c = 100 kJ
16. (b) With respect to observer, there is 23. (d) From free body diagram,
2 2
⇒ t 2 - t = 8t ⇒ t - 1 = 8 ⇒ t = 9
no acceleration in the vertical velocity F - mg = ma
F = m(g + a)
:. The second car overtake the first car in
component. So, path of particle is a ⇒ la
9 h.
1 2. (b) We have,
1 7. (c) F = - d U = - (2x + 3)
straight line as in option (b). = 1 (10 + 10)
⇒ x2 + 2013 = y2 dx = 20 N mg
y2 - x2 = 2013 For stable equilibrium, 24. (c) Electrons are not effective in
F = 0⇒x = - �
⇒
⇒ (y + x) (y - x) = 3 x 11 x 61 scattering a-particles because they are
d2u
2 about 7000 times lighter than a-particles.
xy is minimum when
dx2 25. (b) gh = g(l- � )
y - X = 33 : y + X = 61 Also, =2
x = 14, y = 47
gd
So, there is a minima ofU.
:. Minimum value of xy = 14 x 47 = 658 i.e. system is in stable equilibrium. and = g(l- � )
1 3. (a) We have, 1 8. (c) By principle of thermometry, gh = gd ⇒ 2h = d
X - (- 180° X) - - 25 - 0-
Edge of cube = 2 cm ⇒
:. Total surface area of cube - 600 X - (- 180° X) 100 ⇒ � = _! = 0.5
X + 180° X 1
2d
26. (b) India is in northern hemisphere
= 6 (side)2 = 6(2)2 = 24 cm 2
⇒
Length, breadth and height of cuboid are 120° X 4
⇒ X + 180 X =
1, 2 and 3 respectively 1200
X and due to rotation of earth, radially
° = 30° X rushing wind will tend to rotate in
Total surface area of cuboid 4
= 2(lb + bh + hl) X = -180° X + 30° X ⇒ X = - 150° X
anti-clockwise sense.
27. (d) Imagine earth rotating around
= 2(2 + 6 + 3) 19. (d) Following conservation of mass sun and moon around earth.
= 22 cm 2 number and atomic number, we have
Total surface area of both cube and � Be + iHe ----t },2c + t n
cuboid is 24 + 22 = 46 t
So, particle n is a neutron.
20. (d)
which is less than 54 cm2.
:. Both cube and cuboid can be painted.
1 4. (b) Given, (x?✓x = (x-fx?
m =0.2 m =0.5
= (x)
3
X-
2 =X2
3x
=f4J � earth
28. (d) Velocity increases with time and

Case I When base x = 1
22 m �
I(-
Case II When base x ,,,_ 1 F - h F - µ7ni g 10 ms-2

Acceleration of blocks are then reaches terminal velocity. Velocity
remains constant after reaching terminal
Tni Tni
_ 3x £ii - -- - - ---- -
Then, :x!"'2 - speed.
2
WWW.JEEBOOKS.INl
29. (c) As density of ball The IUPAC name of the above given direction where there are less number of
compound is 3, 5-dimethyl cyclohexene. moles (according to Le-chatelier
36. (d) As pentan-2-one
( = :� = O.S g cm-3 }s less than water, it
principle).
tends to float. (CH.iCOCH2CH2CH.i ) and 3-methyl 2SO2 (g) + O2 (g) � 2S0a (g)
When ball is kept immersed, downthrust butanone (CH.i COCH(CH.i )CH.i ) have Hence, the reaction will more towards
similar molecular formula, but different right.
4 1 . (c) Given,
= weight of 50 cm3 of water = 50 g
carbon skeletons. Thus, they are chain
So, scale reading = 600 + 50 = 650 g
isomers and will exhibit chain isomerism.
30. (b) Pcombination = 2(fl.en, ) + pmirror solubility product of BaC12 ,Ksp = 4 x 10-9
that the shell is 3. For n = ], l has 3
37. (a) The given value of n = 3 suggests
_ 2 x 100 Let the solubility of BaC1 2 be S.
+0 BaC12 � Ba 2+ + 2Cr
S S 2S
fiens (in cm) values, i.e. + ], 0 and - lhence there occur
200 3 orbitals in p-subshell namely Px , Py and
- 1 2 / (15 - 1) Pz · Thus, the given values for n = 3, l = 1 Ksv = [Ba2+ ] [Cr]2 = (S) (28) 2 = 4S 3
4 X 0-9
and m1 = 0 suggests that the orbital is
S = ( �P i = (
= 100 _ 25
= D 3py - Hence, the maximum number of � r
- 12 3 orbitals that can be identified with given
3 1 . (c) CaCO3 ---t CaO + CO2 quantum number is only 1.
= 1 x 10-3 mol 1-1
42. (a) Chlorobenzene on treatment with
Molar mass of CaCO3 38 (a)
" CH3CH=CHCH2CH3 �
= 40 + 12 + 16 x 3 = 100 g sodium in dry ether gives diphenyl. The
0
Molar mass of CaO = 40 + 16 = 56 g / 0� reaction is known as Fittig reaction.
Molar mass of CO2 = 12 + 16 x 2 = 44 g CH3CH : : CHCH2CH3
I I
Q+?1__�-?��- -�-- ��---:
i :
0-0
100 g of CaCO3 produces 44 g of CO2
44
:. 10 g of CaCO3 produces = - x 10= 44g
o-f---;;-o
ozonide
100
32. (c) According to Raoult's law the 1 H30+/Zn0 Dry ther
: + NaCl
vapour pressure of volatile component is
directly proportional to its mole fraction. CH3CHO + OHCCH2CH3
Diphenyl
43. (c) According to ideal gas equation,
If the solution obeys Raoult's law at all This reaction is known as ozonolysis
concentration its vapour pressure would reaction in which the addition of ozone
vary linearly from zero to the vapour molecule to alkene gives ozonide and p V = nRT
pressure of pure solvent. Thus, the then cleavage of ozonide by Zn-H2O to Given,
correct plot will be (c). smaller molecules occurs. 360
39. (c) PH5 does not exist due to very
Pressure = 360 torr = atm
33. (a) The ionic character is decided by 760
Fajan's rule. According to this rule, larger less electronegativity difference between Volume = 2 .5
is size of cation, smaller the size of the P and H. Hydrogen is slightly more Temperature = 22 .5 + 273 = 295.5 K
anion and lesser is the charge on the electronegative than phosphorus, thus
cation or high, thus more will be the ionic Weight of a gas = 16616
could not hold significantly the sharing
character. As the anion and charge of n
electrons. On the other hand, BiC� does n = pV
the cation in all the given compounds are RT
same. So, the ionic character is only not exist due to inert pair effect. This is
because on moving down the group, +5 o = W W p V = = WRT
dependent on the size of cation. As the Als n ⇒ = M
oxidation state becomes less stable while M M RT pV
size of cation increases in the order
Be 2+ < Mg 2+ < Ca 2+ < Ba 2+ +3 oxidation state become more stable Substituting the values,
M = 1.6616 x 0.082 x 295.5 = 3 426 g
due to inert pair effect.
:. The ionic character will also increase in
In SO 2, pre-dre and pre - pre both types of 360
the same manner, i.e. X 2.5
bonds are present. 760
BeC12 < MgC12 < CaC12 < BaC12
SeF4 has sp3 d-hybridisation whereas CH4 = 34g
44. (c) Isoelectronic species are those
0
+ B rO3 + 6HCO3
34. (d) 3Br2 + 6COt + 3H2O ----t 5&- has sp3 -hybridisation. Thus, they both
+5 have different geometry. species which have same number of
Jt has a bent shape due to the presence of electrons.
In the reaction, Br2 is reduced to Br 2 lone pairs on central I atom. As all the given elements are
(oxidation number decreases from zero to
40. (a) Any change in the concentration, isoelectronic with each other. Thus, the
- 1) and Br2 is oxidised to BrO3 (oxidation
pressure and temperature of the reaction radii/size of isoelectronic species is
z
number increases from zero to +5 ).
results in change in the direction of inversely proportional to the atomic
35. (a) equilibrium. This change in the direction 1
number, 1.e.
. size. oc
of equlibrium is governed by
Le-Chatelier's principle. Thus, the correct order is
On increasing pressure, volume S2- > Cr > K+ > Ca2+
decreases. The reaction will move in the
WWW.JEEBOOKS.INl
45. (c) The reaction of toluene with 51 . (c) The structures adopted by 59. (a) Centrosomes are made up of a
Cl2 in the presence of FeC13 gives polypeptides can be divided into four pair of centrioles and other proteins. The
predominantly o and p chlorotoluene. levels of organisation, i.e., the primary, centrosomes are important for cell division
This reaction follows electrophilic secondary, tertiary and quaternary and produce microtubules that separate
+ structures. The secondary structure
substitution mechanism and Cl act as as DNA into two new identical cells.
0
60. (a) The cerebellum is the part of
pertains to the coiling of the polypeptide
electrophile.
chains into regular structure such as
52. (c) At prophase-1, DNA replication

a-helices and �-pleated sheets. hindbrain responsible for hand-eye
CI2, FeCl3
r('Y CHs has already occurred and the original
coordination. It is responsible for
maintaining equilibrium, transfer of
Cl+ � amount of DNA has been doubled to x. information, fine adjustments to motor
CC
(Chlorination) Cl At anaphase-1, the amount of DNA in the actions, coordinating eye movements, etc.
Toluene p-chlorotoluene cell remains the same because no Coordination and body balance, posture
cytokinesis has occurred yet to separate during walking, riding, standing,
CH3
53. (b) If 02 is not available, pyruvic acid
the cytoplasm. swimming, running are all maintained by
+ the cerebellum.
Cl undergoes anaerobic respiration / 6 1 . (a) Given, ABC is an equilateral
o-chlorotoluene fermentation, but under aerobic
46. (a) Phosphatidylcholine is a class of

triangle.
condition, the pyruvic acid enters into
A
mitochondria and converted to acetyl
phospholipids that are a major Co-A. Acetyl Co-A functions as substrate
component of biological membranes entrant for Krebs' cycle. So, it is a
(i.e. nerve cell membrane). It functions in connecting link between glycolysis and
the production of brain chemical called
54. (b) Glucose is stored in the liver as
Kreb's cycle.
acetylcholine used for nerve impulse
transmission at the synapse.
47. (a) Graft rejection does not involve
glycogen. Glycogen can be converted to
erythrocytes. Transplant or graft

free glucose by the process of
glycogenolysis, which involves the
a ;c:__.::,._o""','------_.:,,.,_o-!..-<,c::...________; c
rejection occurs when transplanted tissue activation of a phosphorylase enzyme by
AB = BC = AC = 6
is rejected by the recipient's immune the hormone glucagon. Glucagon is made
system, which destroys the transplanted by the pancreas and is released when the BD = _! BC = 3
blood sugar levels fall. There release of 2
tissue. Rejection is an adaptive immune
AD = 6 x sin 60°
response via cellular immunity (mediated glucose is a homeostatic function of liver AD = AB sin B
by killer T-cells), macrophages and that is controlled and monitored in the
55. (c) As the membrane potential is =

pancreas.
AD = 6 x -./3 3-/3
polymorphonuclear leukocytes (i.e.,
neutrophils, eosinophils and basophils).
48. (b) Horse-shoe crabs are marine and
2
increased, sodium ions channels open,
+
allowing the influx of Na ions into the OD = _! AD = _! x 3-/3 = -./3
In ,'J.. 0' PO, LOO' P = 30°

brackish water arthropods. They 3 3
cell. The inward flow of sodium ions
resemble crustaceans but belong to
increases the concentration of positively
separate subphylum of the arthropods,
00' = -./3 + r
charged cations in the cell and causes OP = OD - PD = -./3 - r
i.e. Chelicerata. The entire body of the depolarisation, where the potential of the
horse-shoe crab is protected by a hard cell is higher than the cell's resting
carapace. ° OP = � + r
49. (a) The first living being on the earth
sin 30 =
56. (a) Ammonia is toxic waste product
potential.
00' "';3 - r
were anaerobic or heterotrophic bacteria which is converted into urea in the liver. 1 = -./3 + r
⇒
because the primordial atmosphere was This urea then enters the excretory 2 -/3 - r
-./3 - r = 2-./3 + 2r
virtually oxygen-free. These organisms system to get eliminated from the body.
⇒
r=
must have degraded simple compounds High levels of ammonia in blood is an
1
57. (d) Mendel did not choose pod
present in the primordial oceans. They indication of liver damage. ⇒
-./3
62. (c) We have, x2/ =6
may have had RNA genomes and used
RNA as biological catalysts.
50. (b) Salmonella bacterium causes 3x 3x + 4y + 4y + 4y
length. The seven contrasting traits he
took were
+ 115
• Plant height • Flower position 2
salmonellosis infection. The bacteria 2 2 3 ;3 3 � ( 9x X 64/ )
spread through human or animal faeces. • Pod colour • Pod shape 5 4 27
Thus, the presence of Salmonella in tap • Flower colour • Seed shape
[:. AM � GM]
58. (a) The levels of classification from (1: = 6]

• Seed colour
3x + 4y � 5
water is due to contamination through 5
human excreta. Salmonella outbreaks ⇒ X 6r [x2/
3x + 4y � 10
are commonly associated with eggs, meat the broadest to the narrowest, i.e. in term
and poultry, but these bacteria can also of having highest members to the lowest
:. Minimum value of 3x + 4y is 10.
⇒
contaminate other foods such as fruits members are kingdom, phylum, class,
and vegetables. order, family, genus and species.
WWW.JEEBOOKS.INl
63. (c) We have three different kinds of 66. (c) Present temperature, 69. (c)
mangoes and we can select 25 mangoes in 138 X 10-28 X (10 X (100) 2 + 30 X (200) 2
all. Hence, we select 0 or 1 or 2 or 3 ... R
+ 20 X (500) 2 + 20 X (800) 2 + 20 X (1000) 2 ) �
mangoes from each kind of mangoes. Tl from 8' B"
3 x 138 x 1 ri-23 object �
Let Xi_ , Xi and 41 be different kinds of
10-5 x 104 (10 + 30 x4 + 20 x25 +20
mangoes.
X 64 + 20 X 100) �
:. Xi_ + x2 + 4! = 25 ⇒ Xi_ , ,½, 4! � 0 A"
3
:. Total number of selection = 25 + 3 - 1 c.i _ 1
10-l X (10 + 120 + 500 + 1280 + 2000) For convex lens, image is at focal distance
= 21c2 3 6 cm from the lens.
27 X 26 = 3910 = 130.33 � 130 K
= = 351 For concave lens,
lx 2 30
u = + 2 cm, f = - 2.5 cm
64. (d) We have, (1 - yr (1 + Yt In few years, all the molecules with speed 1 1 1 1 1
> 900 ms-1 will left the atmosphere. ⇒ -=-+-=- - +-
= (1 _ my + m(�
- 1) 2 v f u -2.5 2
Y + .. ·) So, then temperature will be
⇒ v = + 10cm
138 X 10-28 X (10 X (100)2 + 30 X (200)2
T2. -
n(n - 1) 2 + . . . Linear magnification, produced by
(l + ny + y ) 2 2
10
2 _ +20 x (500) + 20 x (800) ) . . 1ens 1s
d1verging . m= - V =- =5
23
⇒ (1 - yr (1 + Yt = 1 + (n - m) y 3 x 138 x 10- u 2
n (n - 1) m(m - 1) 10-5 X 104 X (10+ 30 X 4 So, diverging lens increases the
+ (--- + --- - nm) y2 + . . . magnification five times.
70. (c)
2 2 + 20 x 25 + 20 x 64)
I = nevdA
I V IR
Here, £li = n - m = 10 ... (i) 3
n(n - 1) m(m - 1) _ 10-l X (10+ 120+ 500+ 1280)
a2 = + nm = 10 = ⇒ Vd = - = - -
2 2 3 neA neA
1910
n 2 - n + m2 - m - 2mn = = 63.66 K ⇒ Vd = -
⇒ a2 = - - - - - - - - = 10 30 plne
2
Reduction in temperature is nearly, So, drift speed is independent of area of
⇒ (n - m)2 - (n + m) = 20 ... (ii) t.T = Tl - T2 = 130 - 63.66 conductor.
From Eqs. (i) and (ii), we get = 66.34 K = 70 K Hence, the ratio of vd Ivd is 1.
2 i
n + m = 80 ... (iii) 71. (d) Given, specific heat of water
67. (a) Let x = mass per unit length of
From Eqs. (i) and (ii), we get = 4. 184 g-1 ° C-l
ruler.
n = 45, m = 35
Forces on ruler are as shown below. Heat capacity of calorimeter = 783 J0c-1
(m, n) = (35, 45) Mass of water = 254 g
65. (a) We have,
ABC is a right angle triangle.
t.T = 26.0 1 - 23. 73 = 2 .28°C
<7bomb = Cf.T = 783 X 2 .28 J = 1 785.24 J
B qwater = m X specific heat X t.T
dq:,
= 254 X 4.184 X 2 .28
Qi XL
= 2423.04J
Heat absorbed = 1785 .24 J + 2423.04 J
2xL = 4208.28 J = 4.2 1 kJ
Equating moments about P, 72. (b) The hybridisation of any molecule
can be calculated using formula
!:. (x · L) sin (90 - 0) = L (2xL) sine
LA = 90°, the angle bisector of B and C
M A
2 X = � (valence electrons number of atoms
2
meet at P sine monoatomic ± anion/cation)
⇒ = tan0 = �
The distance from P to hypotenuse is 4/2 cos0 4
The shape and hybridisation of given
PQ = W 68. (a) 1 kg of water expands from molecules are as follows
Here, PQ is the radius of incircle of MBC. 1000 cm3 to 1.68 m3 .
Molecule Shape Hybridisation
MBC
:. PQ = PM = PN = radii of incircle of t. V = 168 - 0.001 = 168 m3
NF3 Pyramidal sp 3
So, work done in expanding against
2 2
AP = PM + AM 2
pressure is BF3 Triangular sp 2
planar
AP2 = (4/2)2 + (4/2)2 t. W = pt.V = lOl x 10 3 x 168 = 169 kJ
[·: AM = PN] BF4- Tetrahedral sp 3
AP2 = 32 + 32
Now, AW = 169 = 0.0748 NHt Tetrahedral sp 3
AP = M = 8
mLv l x 2260
WWW.JEEBOOKS.INl
Molecule Shape Hybridisation

BC13 Triangular sp 2
planar
BrC1 3 T-shaped sp 3d
l
NH3 Pyramidal sp a f la
CH3 - O CH2C la IAI0 X IBIB
sp 2
? l
NO 3 Triangular (ii)
As BF4- and NH! have same shape and

planar Clla �
(Major)
(A) IAIB IAIB IBI0 IBI0
hybridisation. Thus, they are As in the given compound is 3 alkyl °
isostructural pair. halide, so it can either go SN l or Ei IAIA X IBIB

73. (a) Geometrical isomers are those reaction, which is dependent on the (iii) �
isomers, which have same molecular nutrophile. As CHa CH2O- Na+ is a strong
formula, but different spatial Nu 8, so it will prefer to undergo E1 IAIB IAIB IAIB IAIB
arrangement of atoms about the double reaction whereas CHa CH2OHis a weak
Nu• which undergoes SN 2
75. (b) Number of 1t and cr bands in
bond. In geometrical isomers, both the
carbon atoms of a double bond should
contain different substituents. given species are as follows
No. of cr and
Structure
1t bonds Thus, in all four possibilities for
(a) cr bonds = 4 F;_-generation can be IA IB , IA I°, IBJ°, I°I°
1t bonds = 1 but never IA IA or AA.
78. (b) Only the electron transport
As both the substituents are different
hence, they will show geometrical
isomerism. system produces ATP and reduced NADP
(b) 0 cr bonds = 4
Y H3 C CH 3 X
in the plant. Without these compounds,
cr l ln 1t bonds = 4
H the Calvin cycle cannot proceed and
(b) �Xe �
0'1tcrl In 1f:o carbon-fixation cannot occur and their is
y CH3 CH 3 X no respiratory substrate available for
It does not show geometrical isomerism. respiration.
;H x 79. (a) Immovable / fixed / fibrous joints
(c) 21t O' 21t cr bonds = 3
N eaa C - C eaaN
(c) X /��
(J (J 1t bonds = 4
are present between the skull bones. So,
Y H j\ H x
(d) H cr bonds = 6
between parietal bone and the temporal
l a O' 1t bonds = 4
I
21t
N=C -C-
O'
C eaa N
21t
bone of the skull are joined by fibrous
It does not show geometrical isomerism. O' O'
joint. Other statements can be corrected
Hx
cr
H as First cervical vertebra is atlas not
(d) CX 76. (c) The graph (c) is correct as, it
axis. The 1 1th and 12th pairs of ribs are
Hx shows the highest biochemical activity in
called floating ribs. Glenoid cavity is
located at the end of scapula close to
It does not show geometrical isomerism. the lysosomes. These are membrane
coracoid process.
80. (c) The triplet codon is made up of
bound organelles which contain enzymes
CH3
that degrade polymers into their
74. (c) CH3 -C = CH2
I CH;PH 2 0- Na+ monomeric subunits, i.e. hydrolytic 3 nucleotide bases and is located at the
---
enzymes. centre of the middle loop of tRNA
77. (a) There are four possible mating
E1
molecule and base pairs with the
crosses which can occur with persons of complementary bases on an mRNA
blood group A and blood group B. molecule during protein synthesis.
WWW.JEEBOOKS.INl
KVPY
PRACTICE SET 3
Stream :SA
M M : 100
Instructions
MATHEMATICS (a) is at least 30

1 . Let E(n) denote the sum of the even digits of n. For
(b) is at least 20
(c) is exactly 25
example E(1243) = 2 + 4 = 6, then the value of (d) cannot be determined by the data
E(l) + E(2) + E(3) + . . . + E(lO0) is equal to
(a) 200 (b) 300 (c) 400 (d) 500
6. Let a, b and c such that a + b + c = 0 and is defined as
2 2 2
a b c
2. The greatest possible perimeter of right angle P= + + , then the value of P
triangle with integer side length if one of the sides 2a 2 + be 2b2 + ac 2c2 + ab
has length 12 is is equal to
(a) 80 (b) 84 (c) 72 (d) 82 (b) _!
2
3. In a party, each man danced with exactly four women
and each woman danced with exactly three men. (d) 2
7. In a rectangle ABCD, AB = 8 and BC = 20, let P be a

Nine men attended the party, then number of woman
point on AD such that LBPC = 90 °. If r1 , r2 and r3 are

attended the party is
radii of the incircles of L1APB, BPC and CPD

4. If 3 + 2 = 985 and 3
(a) 12 (b) 9 (c) 6 (d) 8
x x
Y - 2Y = 4 73, then the value of xy
respectively, then the value of r1 + r2 + r3 is equal to
lS
8. If sin 0 + cos 0 = ./3, then the value of tan 0 + cot 0 is

(a) 6 (b) 8 (c) 10 (d) 12
(a) 36 (b) 72 (c) 48 (d) 54
5. A certain school has 300 students. Every student
reads 5 newspapers and every newspaper is read by (a) 1 (b) .J2
60 students. Then, the number of newspaper (c) 2 (d) None of these
WWW.JEEBOOKS.INl
9. Numbers 1, 2, 3, ... 100 are written down each of the The correct option is
cards A, B and C. One number is selected at random (a) Hr > Hn > Hm
from each of the cards. The probability that the (b) Hr < Hn < Hm
numbers so selected can be the measures (in cm) of (c) Hr = Hn < Hm
three sides of the right angled triangles no two of (d) data insufficient to conclude
which are similar is
4 3 17. Potential energy of a spring when stretched through
(a) - (b) - (c) _1!_ (d) None of these a distance x is 10 J. Ratio of work done for every
10o'3 5o'3 10o'3
additional distance is
10. In a triangle with integer side length, one side is (a) 1 : 1 : 1 : ... . (b) 1 : 2 : 4 : .....
three times as long as a second side and the length of (c) 1 : 3 : 5 : ... . (d) 1 : 4 : 9 : 16 : ...
the third side is 17. What is the greatest possible
perimeter of the triangle? 18. At what temperature, the celsius and farenheit scale
(a) 46 (b) 47 (c) 48 (d) 49 give the same temperature value?
(a) 0°C (b) - 10°F
11. One morning, each member of Kanchan's family (c) - 40°C (d) - 20°C
drank 8 ounce mixture ofcoffee and milk. The
amount of coffee and milk varied from cup to cup, but 19. In given nuclear transformation,
1 238 � ThA � Pac �
92 U 92 U
234
were never zero. Kanchan drank -th of the total B D
7 A, B, C, D and E are
amount of milk and � th of the total amount of (a) A = 234, B = 90, C = 234, D = 91, E = �
(b)A = 234, B = 90, C = 238, D = 94, E = a
17
(c) A = 238, B = 93, C = 234, D = 91, E = �
coffee, then the number of people are there in
(d)A = 234, B = 90, C = 234, D = 93, E = a
Kanchan's family are
(a) S (b) 9 (c) 7 (d) 17
20. A particle is subjected to two simple harmonic
12. Let ABC be a triangle with LABC = 90°. Let P and Q
motions
are mid-point of legs AB and BC, respectively.
Suppose that AQ = 19 and PC = 22, then length ofAC (x = .J2 sin rot) cm and [x = .J2 sin (ro t + �)] cm
is equal to
(a) 24 (b) 25 (c) 26 (d) 30 time t is in seconds. Maximum speed of the particle,
rad .
13. Number of natural numbers n between 1 and 2019 1"f (J) = 1 - lS
. . s
(both inc
. lus1ve
. ) 1s. - - Sn - an mteger 1s ,./6 cm
9999 - n (a)
;,
(a) 0 (b) 1 (c) 2 (d) 3
(c) ,./2 cm
14. A ray oflight originating at the vertex A of a square ;,
ABCD passes through the vertex B after getting
21. A man crosses a 320 m wide river perpendicular to
reflected by BC, CD and DA in that order. If0 is the
the current in 4 min. If in still water, he can swim
angle of the initial position of the ray with AB, then
sin e equals with a speed � times that of the current, then the
2 3 3
(a) ---= (b) - (c)-
3
(d) � speed of the current (in m/min) is
,/13 ,/f::j 5 5
(a) 30 (b) 40 (c) 50 (d) 60
15. Let m be the number of ways in which two couples
can be seated on 4 chairs in a row, so that no wife is 22. Consider a 16 cm x 8 cm uniform rectangular sheet
next to her husband and n be the number of ways in with its sides parallel to axes and its centre at origin.
which they can be seated in 4 chairs in a circle. In the
other case rotation are considered different
configurations. Then,
(a) m = n (b) m = 2n (c) m = 4n (d) m = Sn
PHYSICS
(0,0)
16. A sample of pure ice is taken and following are If exactly one quarter of this sheet is removed,
recorded. coordinates of centre of mass of remaining sheet are
I. Heat to melt the ice.
(d) ( -4 , -2 )
(a) (4/ 3, 2 / 3) (b) (0, 2 / 3)
II. Heat to warm ice cold water to 100° C.
(c) (4/ 3, 0)
III. Heat to vaporize the water at 100° C. 3 3
WWW.JEEBOOKS.INl
23. For four processes A, B, C and D, loge p versus loge V u

graph are given below. (a)
F
(b)
ln p
u
.> r
r
(d)
(c)
-+ - - - - - - - ----+ In V
Isothermal process is
(a) A (b) B (c) C (d) D
24. In given set up,
focal length of mirror = 20 cm,
focal length of lens = 15 cm
29. A metal sphere is held suspended along a wall as
and separation of mirror and lens = 40 cm.
A point source S of light 'S' is placed on principal axis
shown below.
at distance d from lens.

If the final beam comes out parallel to the principal
axis, then value of d is
f= 1 5 cm
f=20 cm
s
If string can break at a pull of 15 N, then maximum
density of material of sphere can be
(a) 44 kg m-3 (b) 64 kg m-3 (c) 54 kg m-3 (d) 74 kg m-3
d 40 cm
(a) 4 cm (b) 8 cm (c) 12 cm (d) 16 cm 30. An object at infinity forms an image of size 2 cm by a
25. A gas satisfies the relation p V513 = K, where
convex lens of focal length 30 cm.
p = pressure, V = volume and K = constant. The Now, a concave lens of focal length 20 cm is placed
dimensions of constant K are between the convex lens and image at a distance of
(a) [ML4r2] (b) [ML2r2] (c) [M0L0T 0] (d) [MLr2] 26 cm from convex lens. Image size now will be
(a) 1.25 cm (b) 2.5 cm (c) 1.05 cm (d) 2 cm
26. When temperature of a semiconductor is raised, then
choose the correct option.
(a) None of electron jump to higher energy level CHEMISTRY
(b) All electrons likely to jump at higher energy levels 31. If 500 mL of a 5M solution is diluted to 1500 mL.
(c) Electrons whose energies are close to fermi energy are What will be the molarity of the solution obtained?
likely to jump to higher energy levels (a) 1.5 M (b) 1.66 M (c) 0.Q l 7 M (d) 1.59 M
(d) Electrons having lesser energy than fermi energy are
likely to jump to higher energy level 32. A plot of volume (V) versus temperature (T) for a gas
at constant pressure is a straight line passing
27. An incense stick is lighted in a closed room in which
through the origin.
there is no flow of air. Then, choose the correct option
given below.
(a) Flow of smoke is initially turbulent, then laminar
(b) Flow of smoke is initially laminar, then turbulent
(c) Flow of smoke is turbulent only
(d) Flow of smoke is laminar only
28. Which of these graphs correctly shows potential
energy and force between two atoms in a diatomic
molecule? (!] = potential energy, F = force, r= distance) Temperature (K) �
WWW.JEEBOOKS.INl
The plot of different values of pressure are shown in 44. The correct IUPAC name ofthe following compound
figure. Which of the following orders of pressure is ?"
correct?
WA>�>� >� �A =�=� =� IS
�A < �<� < � 00 A < � = � < �
33. A substance X gives brick red flame and breaks down
on heating to give oxygen and a brown gas. The (a) 3-(1-ethyl propyl) hex-1-ene
substance X is (b) 4-ethyl-3-propyl hex-1-ene
(a) magnesium nitrate (b) calcium nitrate (c) 3-ethyl-4-ethenyl heptane
(c) barium nitrate (d) strontium nitrate (d) 3-ethyl-4-propyl hex-5-ene
34. The major product obtained when 1 butyne reacts 45. The period number in the long form of the periodic
with excess HBr is table is equal to
(a) 2, 2-dibromobutane (a) magnetic quantum number of any element of the
(b) 2-bromobutane period
(c) 1, 1, 2, 2-tetrabromobutane (b) atomic number of any element of the period
(d) 1, 2-dibromobutene (c) maximum principal quantum number of any element
of the period
35. Which of the following sulphides when heated (d) maximum azimuthal number ofany element of the period
strongly in air gives the corresponding metal?
(a) Cu 2S (b) CuS (c) Fe28s (d) HgS
BIOLOGY
36. Sulphur in + 3 oxidation state is present in
(a) dithionous acid (b) sulphurous acid 46. Which of the following biomolecules is common to
(c) dithionic acid (d) pyrosulphuric acid respiration-mediated breakdown of fats,
carbohydrates and proteins?
37. The correct order of boiling points of given
compounds is n-butylamine (I), diethyl amine (II), (a) Glucose-6-phosphate
N, N-dimethylethylamine (III). (b) Fructose-1,6-bisphosphate
(c) Pyruvic acid
(a) III < II < I (b) I < II < III
(d) Acetyl Co-A
(c) III < I < II (d) II < I < III
38. The value of Planck's constant is 6.63 x 10-34 Js. The 47. You are given a tissue with its potential for
velocity oflight is 3 x 108 ms-1 . Which value is closest differentiation in an artificial culture. Which ofthe
to the wavelength in nanometer of a quantum of light following pairs of hormones would you add to the
medium to secure shoots as well as roots?
with frequency of8 x 10-15 s-1 ?
(a) 2 X 10-25 (a) IAA and gibberellin
(b) 3 X 107
(c) 4 x 10 1 (d) 5 x 10-18 (b) Auxin and cytokinin
(c) Auxin and abscisic acid
39. The correct order of electron affinities ofN, 0, S and (d) Gibberellin and abscisic acid
Cl is
(a) N < 0 < S < Cl (b) 0 < N < Cl < S 48. The partial pressure of oxygen in the alveoli of the
(c) 0 = Cl < N = S (d) 0 < S < Cl < N lungs is
(a) equal to that in the blood
40. The number of lone pairs on central metal atom Xe in (b) more than that in the blood
XeF2 , XeF4 and XeF6 , respectively are (c) less than that in the blood
(a) 2, 3, 1 (b) 1, 2, 3 (c) 4, 1, 2 (d) 3, 2, 1 (d) less than that of carbon dioxide
41. When aqueous solution of benzene diazonium 49. When cell has stalled DNA replication fork, which
chloride is boiled, the product obtained is checkpoint should be predominantly activated?
(a) C6If;; CH20H (b) C6 H6 + N2 (a) G 1 / S
(c) C6If;; COOR (d) C6If;; OH (b) G2 / M
42. The set of quantum number for 19th electron of (c) M
chromium (Z = 24) is (d) Both G2 / Mand M
(a) 4, 0, 0, + -1 (b) 4, - 1, 1, - 1, + -1 50. Which of the following is the least likely to be
2 2 involved in stabilising the three-dimensional folding
1
(c) 3, 2, 2, + - (d) 3, 2, - 2, + -1 of most proteins?
2 2 (a) Hydrogen bonds
43. Among the given carbocations, the most stable (b) Electrostatic interaction
carbocation is (c) Hydrophobic interaction
(a) methyl (b) allyl (c) benzyl (d) vinyl (d) Ester bonds
WWW.JEEBOOKS.INl
5 1 . Name a peptide hormone which acts mainly on (c) release bicarbonate ions by the liver
hepatocytes, adipocytes and enhances cellular (d) reduce the rate of heartbeat
glucose uptake and utilisation. 56. Lack of relaxation between successive stimuli in
(a) Insulin (b) Glucagon sustained muscle contraction is known as
(c) Secretin (d) Gastrin (a) fatigue (b) tetanus
52. If a colourblind man marries with a woman who is (c) tonus (d) spasm
homozygous for normal colour vision, the probability
57. Which of the following guards the opening of
of their son being colourblind is
hepatopancreatic duct into the duodenum?
(a) 0 (b) 0.5
(c) 0. 75 (d) 1 (a) Ileocaecal valve (b) Pyloric sphincter
(c) Sphincter of Oddi (d) Semilunar valve
53. One of the major components of cell wall of most
fungi is 58. Which one of the following cell organelles is enclosed
(a) peptidoglycan (b) cellulose by a single membrane?
(c) hemicellulose (d) chitin (a) Chloroplasts (b) Lysosomes
(c) Nuclei (d) Mitochondria
54. A tall true breeding garden pea plant is crossed with
a dwarf true breeding garden pea plant. When the 59. Which of the following features is not present in the
F1 -plants were selfed, the resulting genotypes were in phylum Arthropoda?
the ratio of (a) Metameric segmentation
(a) 1 : 2 : 1 :: Tall heterozygous : Tall homozygous : Dwarf (b) Parapodia
(b) 3 : 1 :: Tall : Dwarf (c) Jointed appendages
(c) 3 : 1 :: Dwarf : Tall (d) Chitinous exoskeleton
(d) 1 : 2 : 1 :: Tall homozygous : Tall heterozygous : Dwarf 60. Water soluble pigments found in plant cell vacuoles
55. Reduction in pH of blood will are
(a) reduce the blood supply to the brain (a) chlorophylls (b) carotenoids
(b) decrease the affinity of haemoglobin with oxygen (c) anthocyanins (d) xanthophylls

MATHEMATICS 65. In a L1 ABC, let I denotes the incenter. Let the line AI,
6 1 . Let S be a set of real numbers with mean m. If the
BI and CJ intersects the incircle at P, Q and R,
means of set S u {15} and S u {15, 1} are m + 2 and
L QPR in degree is
respectively. If LBAC = 40 °, then the value of
m + 1 respectively. Then, number of elements S has
�5 �6 (a) 50° (b) 65°
W4 00 7
62. For natural numbers x and y, let (x, y) denote the
(c) 55° (d) 60°
natural number x and y with x � y satisfy the PHYSICS

greatest common divisor of x and y. The pairs of
equation xy = x + y + (x, y) is
c + t3
W2 �3 �4 00 5 66. Power is given by P = a + bt 2 + ( } where t is
d
63. In a L1 ABC, X and Y are points on the segment AB
and AC respectively, such that AX : XB = 1 : 2 and time. Then,
A Y : YC = 2 : 1. If the area of L1 AXY is 10, then the I. [a] = [ML2r3 ]
II. [b] = [ML2r5 ]
area of L1 ABC is
III. [c] = [T3 ]

(a) 30 (b) 45 (c) 60 (d) 27
64. Let 4 , x2 , 43 , . . . , ;s019 be the real numbers different
from 1, such that 4 + ;s + 43 + . . . + ;s019 = 1 and IV. [d] = [ML- 2r6 ]
x20 19 Which of the above statements are correct?
_3__ + ----5L_ + . . . + = 1, then the value of
9
1 - 4 1 - X2 1 - .'.So19 (a) Statements I and IV are correct
X.-
1
- + - �-- �20 19 • (b) Statements I and III are correct
- - + . . . + -=� 1s equa1 to
1 - 4 1 - X2 1 - .'.So19 (c) Statements I, II and III are correct
(a) 0 (b) 1 (c) 2019 (d) None of these (d) All statements are correct
WWW.JEEBOOKS.INl
67. A rolling sphere collides with a cube of equal mass. U = -2x

Surface is frictionless. Radius of sphere is 1 cm and x2 + 4
its initial angular speed is 1 radian per second. Then, angular frequency of small oscillations of the
body about the position of stable equilibrium is
(a) 5 rad s-1 (b) 10 rad s-1
(c) 1t rad s- 1 (d) 25 rad s-1
If side of cube is 2 cm and collision is elastic, then
after collision,
(a) co,phere = 0 and Vcube = 0.0 l ms-1
CHEMISTRY
(b) co,phere = 1 -
rad and
Vcube = 0.0 l ms-1 7 1 . The heat of formation ofC12H22 O1 1 (s), COig) and
s H2 0(l) are -530, - 94.3 and -68.3 kcal/mol,
(c) co,phere = 0 and Vcube = 0 respectively. The amount ofC12H22 O11 required to
(d) co,phere = 1-
rad and
Vcube = l ms-1 supply 2700 kcal of energy is
s (a) 382. 70 g (b) 832. 7 4 g
68. A current of 1 mA enters the network of resistors as (c) 463.9 g (d) 682.6 g
shown below. 72. The following alcohol after treatment with acid gives
2kQ compound A. Ozonolysis ofA gives nonan -2, 8 dione.
The compound A is
O
CHOHMe H+
�A
cc
A 1 kQ 1 kQ 1 kQ B
Me
2kQ
Now, consider the following statements: (a) o--<: (b)
O=< C(
I. Current through 2 kQ resistor is � mA.
5
(c) (d)
II. Current through lower 2 kQ resistor is � mA.
5
III. Current through middle 1 kQ resistor is � mA. 73. An electric current is passed through silver nitrate
5 solution using silver electrodes. 10. 79 g of silver was
IV. Current through middle 1 kQ resistor is � mA. found to be deposited on the cathode. If the same
5 amount of electricity is passed through copper
Which of the above statements are correct? sulphate solution using copper electrodes, the weight
(a) Only statement I is correct of copper deposited on the cathode is
(b) Statements II and III are correct (a) 1.6 g (b) 2.3 g
(c) Statements I and III are correct (c) 3.2 g (d) 6.4 g
(d) Statements III and IV are correct 17
74. Suppose 10- J oflight energy is needed by the
69. A steel ball travels through a hollow U-tube with interior of human eye to see on object. Calculate the
separation in limbs 1 m, as shown below. number of photons of green light (A = 550 nm) needed
to generate this minimum amount of energy.
(a) 26 (b) 27 (c) 28 (d) 29
75. The Gibbs' free energy change, t:,.G , for the following
1m 0
reaction is 63.3kJ
Ag 2CO3 (s) � 2Ag+ (a,q ) + cot (aq)
V
Radius of U-tube is slightly greater than ball such

that ball travels through it and leaves from other end The Ksp ofAg 2CO3 (s) in water at 25°C is closest to
with same uniform speed of 3 ms-1 . (a) 3.2 X 10-26 (b) 8 X 10-12
Mass of steel ball is 0.02 kg. What is the approximate (c) 29 X 10- (d) 7.9 X 10-2
BIOLOGY
3
reading on spring balance attached to the tube?

(a) 0. 1 N (b) 0.2 N (c) 0.5 N (d) 0 N
70. A body of mass m (= 5 g), is moving in one dimension 76. Impulses travel very rapidly along nerves to the leg
under influence of a conservative force. Potential muscles of a mammal. Which fact accounts for the
energy of the body is given by speed at which they travel?
WWW.JEEBOOKS.INl
(a) A nerve impulse is an all-or-nothing phenomenon

(b) The nerves contain myelinated fibres
(c) There is high concentration of Na+ ions inside the
axons
(d) There is a potential difference across the axon
membranes
Substrate Substrate
77. In a certain plant, yellow fruit colour (Y) is dominant concentration concentration
to green (y) and round shape (R) is dominant to oval 79. Assume that the average amino acid residue have a
(r). The two genes involved are located on different
molecular weight of 1 10. The DNA strand coding for
chromosomes. Which of the above will result when
plant YyRr is self-pollinated? a polypeptide chain of molecular weight 20,000 has a
(a) 9 : 3 : 3 : 1 ratio of phenotypes only length of
(b) 9 : 3 : 3 : 1 ratio of genotypes only (a) 182 nucleotides
(c) 1 : 1 : 1 : 1 ratio of phenotypes only (b) 252 nucleotides
(d) 1 : 1 : 1 : 1 ratio of phenotypes and genotypes (c) 540 nucleotides
(d) 760 nucleotides
78. Which graph shows the expected relationship
between enzyme activity and substrate 80. Which of the following is a correct statement?
·B"
concentration? (a) Salvinia, Ginkgo and Pinus all are gymnosperms
(b) Sequoia is one of the tallest trees
"
<=I
"' "'
(c) The leaves of gymnosperms are not well-adapted to
(b) '"
·.;a
'" extremes of climate
"' "'
(a)
'a 'a (d) Gymnosperms are both homosporous and
��
heterosporous
Substrate Substrate
concentration concentration
Answers
PART-/
(c) 2 (b) 3 (a) 4 (c) 5 (c) 6 (a) 7 (b) 8 (d) 9 (d) 10 (d)
11 (a) 12 (c) 13 (b) 14 (a) 15 (c) 16 (b) 17 (c) 18 (c) 19 (a) 20 (a)
21 (d) 22 (d) 23 (c) 24 (c) 25 (a) 26 (c) 27 (b) 28 (d) 29 (a) 30 (b)
31 (b) 32 (c) 33 (b) 34 (a) 35 (d) 36 (a) 37 (a) 38 (c) 39 (a) 40 (d)
41 (d) 42 (a) 43 (c) 44 (b) 45 (c) 46 (d) 47 (b) 48 (b) 49 (a) so (d)
51 (a) 52 (a) 53 (d) 54 (d) 55 (b) 56 (b) 57 (c) 58 (b) 59 (b) 60 (c)
PART-I/
61 (a) 62 (b) 63 (b) 64 (a) 65 (c) 66 (c) 67 (b) 68 (b) 69 (b) 70 (a)
71 (d) 72 (d) 73 (c) 74 (c) 75 (b) 76 (b) 77 (a) 78 (b) 79 (c) 80 (b)
WWW.JEEBOOKS.INl
Solutions
1 . (c) E(l) + E(2) + E(3) + . . . + E(lOO) 5. (c) We have, 7a = 6 - 2./5
= Sum of all even digits from 1 to 100 Total number of students = 300 :. r1 + r2 + r3 = 12 - 4v'5 +
6v'5 - 10 + 6- 2./5
One student read = 5 newspapers =8
8. (d) Given, sin 0 + cos 0 = -/3
= Sum of all even digits in
[01 + 02 + 03 + . . . + 98 + 99 + 100] Number of newspaper read by 300
= 0 x 20 + 2 x 20 + 4 x 20 + 6 x 20 + 8 x 20 students = 5 x 300 = 1500 Squaring both sides,
[·: there are 2 x 100 = 200 digits and Number of different newspaper sin 2 0 + cos2 0 + 2 sin 0 cos 0 = 3
. . appears -
each d1git 200 = 20 times
. l = 1500 = 25 ⇒ 1 + 2 sin 0 cos 0 = 3
60
6. (a) Given,a + b + c = O
10 ⇒ sin 2 0 = 2
= (2 + 4 + 6 + 8) X 20 = 20 X 20 = 400
a3 + b3 + d3 = 3abc
:. Maximum value of sin 0 = 1
2. (b) Let the other sides of right angle Hence, sin 0 + cos0 = -13 not possible.
Now, P = --- 9. (d) Given,
triangle be x and y. a2 b2 c2
2a + be 2b + ac 2c + ab
2
+ ---2
+ ---
2
Number 1, 2, 3, ... 100 are written on card
Let a = 1, b = - 1, c = 0 A, B and C.
P= _ 1_ _
+
1_
+ 0 :. Total number of outcomes
2+ 0 2+ 0 = 100 X 100 X 100 = 1003
R 12 Q ⇒ P = _! + _! = l Numbers are selected such that formal
2 2 three sides of right angle triangle and
x2 = 122 + Y2 7. (b) Given, ABCD is a rectangle. triangle are not similar.
AB = 8, BC = 20
2
⇒ x - y2 = 144 For a right angle triangle
⇒ (x + y) (x - y) = 72 x 2 Let AP = x (2n + 1)2 + (2n 2 + 2n) 2 = (2n 2 + 2n + 1)2 ,
x and y are integer. PD = 12 - x nEN
:. Maximum value of x + y = 72 for n = 1, 2, 3, 4, 5, 6. If n > 6 then length
:. Maximum perimeter of triangle of longest side is greater than 100.
= 12 + x + y :. n(E) = 6 X 3!
= 12 + 72 = 84 6 X 3!
P(E) =
3. (a) There are 9 men and each man (100)3
danced with 4 women. 6x 6
---- - --
9
⇒ Number of dancing pairs = 9 x 4 = 36 :i X (50) 2(50)3
3
1 0. (d) Given,
12 C
In MPB and /'JJPC,
B
Now, let number of women = x
M'BA - 11CPD
:. Each woman danced with 3 men. One side of triangle is three times the
AB AP
:. Number of dancing pairs = 3x second side and third side is 17.
3x = 36, X = 12 PD CD
--- Let the sides of triangle are x, 3x, 1 7.
Hence, 12 women attended the party. 8 X We know, in triangle sum of two sides is
⇒ greater than third side.
4. (c) Given, 12 - X 8
3x + 2y = 985 ... (i) ⇒ x + 3x > 17
⇒ x2 - 20x + 64 = 0
y 17
x
3 - 2 = 473 ... (ii) ⇒ (x - 16) (x - 4) = 0 ⇒ x> -
On adding Eqs. (i) and (ii), we get X = 4, 16
In MPB,
2 · 3x = 1458 and x + 1 7 > 3x
� x AB x AP
17
11
3x = 729 x< -
r1 = - = - -=--
2 - -- - -
2
3x = 36
⇒ x= 6 s � (AB + PB + BP) 17 < < -
- X
17
2 4 2
r1 = ----
On subtracting Eq. (ii) from Eq. (i), we get
8 x4 425 < x < 8.5
2 , 2Y = 512
[·: BP2 = AP2 + BA 2
8 + 4 + 4/5 Since, sides of triangle are integer.
X = 5, 6, 7, 8
� = 256
� = 28 BP = ..)16 + 64 = 4/5]
⇒ y= 8 r1 = 12 - 4v'5 :. Maximum value of x = 8
xy = 6 X 8 Similarly, :. Sides of triangle are 8, 24, 1 7
= 48 r2 = 6'/5 - 10 :. Perimeter = 8 + 24 + 17 = 49
WWW.JEEBOOKS.INl
4 4 1 5. (c) m = Number of ways in which two

5 5
1 1 . (a) Let the total milk is 7M ounce ⇒ AC2 = - (36 1 + 484) = - X 845
and total coffee is 17C ounce. couples can be seated in 4 chairs in a row
The ratio of total milk and coffee drank ⇒ AC2 = 4 x 169 such that no wife is next to husband.
by Kanchan's must be integer. ⇒ ✓
AC = 4 x 169 = 26
1 3. (b) Let
H1
7M + 17C . the
. teger (wh'1ch 1s Sn
:. - -- be an m = ')..,,
M + 2C 9999 - n
Total number of people in Kanchan's H, O W,
Sn = 9999')..,, - An
n = -9999')..,,
-
family)
7M + 1 7C = 7 + � ⇒
8 + ')..,,
m = 2! x 2! x 2! = S ways H1 x W1X
M + 2C M + 2C W1
⇒ n E [1, 2019]
0< � < �
M + 2C 2 l'.,'.; 9999')..,, '.,'.; 2019 n = Number of ways in circular
8 + ')..,, permutation = 2! = 2
�=1 9999')..,, m = 4n
1 6. (b) Let m kg of ice is taken.
M+ 2C ⇒ �l
8 + ')..,,
Then, H1 = mL1 = 334mJ
[·: - 3C - 1s
. m 3
. teger less than - ]
⇒ 9999')..,, � 8 + ')..,,
and Hu = mct.T = m (419) (100)
M + 2C 2
S 9999')..,, '.,'.;
C= M ⇒ ')..,, � __ and 2019
9998 8 + ')..,, = 419 mJ
Hill = mLv = m (2260) = 2260 m J
:. Total number of people in Kanchan's
⇒ 9999')..,, '.,'.; 16132 + 2019')..,,
f'.am1. 1y - 7M+
- 17M- =8 16132 :. Hr < Hu < Hill .
')..,, '.,'.;
1 7. (c) For additional extension x, work
M + 2M ⇒
7990
1 2. (c) Given, 8_ '.,'.; ')..,, '.,'.; 16132
ABC is a right angled triangle
_ done is
W = !_ k (2x)2 - !. kx2
9998 7990
LABC = 90° ')..,, = 1, 2, ')..,, is an integer. 2 2
P and Q are mid-points of sides AB and For ')..,, = 2, n is not an integer.
W = !_ k(4x2) - !_ kx2 = !_ k (3x2)
BC respectively. 2 2 2
1 4. (a) Let side of square ABCD
Hence, only one value is possible.
AB = x
:. Ratio is 1 : 3 : 5 : ....
1 8. (c) Let x = temperature value.
C
D �- �F�e�� C Then,
Q -
C - 0- - - F- - 32 -
100 - 0 212 - 32
when C= F = x,
� X - 32
A P B ⇒ = ⇒ X = - 40
BQ = !_ BC = CQ
100 180
- 40°C = - 40°F
In MBE, 1 9. (a) We have,
2 A B
AP = !_ AB = BP
BE n u 2ss � 90Th2s4 � 91 Pa2s4
AB
2
In l'J'BC,
tan 0 =
�92 u 234
PC2 = BC2 + PB2 BE = x tan 0 20. (a) Amplitude of resultant motion is
PC2 = BC2 + !_ AB2 CE = BC - BE = x(l - tan 0)
A = .JA12 + A; + 2A1A2 COSq>
In t.CEF,
... (i)
CE
4
In MQB, ⇒ CF = x(cot 0 - 1) ✓
= 2 + 2 + 2 x -/2 x .J2 x � = .J6
AQ = AB + !_ BC CF
tan 0 =
Now in t.GHF,
2 2 2
... (ii)
FH CE
4 So, maximum acceleration = cn2A
= 12 x .J6 = .J6 cm
GH DF
On adding Eqs. (i) and (ii), we get
PC2 + AQ 2 = � (AB2 + BC2)
tan0 = - = -
s2
CE x(l - tan0) 2 1 . (d) v; = v! - v2
DC - CF x(2 - cot0)
4 =
2 320
⇒ PC2 + AQ 2 = 5AC v= = 80 m/min
i (PC
1 - tan0 4
v,
4 tane =
⇒ AC = 2 2
+ AQ ) 2 2 - cote
5
AC2 = � (1 92 + 222)
⇒ 2 tan 0 - 1 = 1- tan0 ⇒ tan0 = �
⇒ 3
5
[·: PC = 19, AQ = 22]
WWW.JEEBOOKS.INl
r-
5 35. (d) HgS, when heated strongly in air
Vm = - Vr
i
3 gives mercury and sulphur dioxide.
v; = ( vr (80) 2 HgS + 02 Roasting ) Hg + S02
The process is known as roasting where
l6 2 the sulphide ore is directly heated in
vr = (80)2
9 presence of air (02) to get the respective
3 x3
vr = o = 60 m/min metal.
4 36. (a) The oxidation state of S in the
22_ (d) X = Mx mx' =
41t X (5)2 X (10-4 )
- 4M(0) - M(4) 14
Density of sphere = given options are as follows
M- m 4M - M (i) Dithionous acid
=--
4 = 44 kg m-3 0 0
3 I II
y= My - my' 4M(O) - M(2) = _ � H0-S-S-0H
=
M- m 4M - M 3 2(x) + 2(-2) + 2(- 1) = 0
23. (c) For isothermal process, 2x - 4 - 2 = 0
p V = constant 2x = 6
p = - ⇒ log p = - log V + log K
26 cm 4 cm
K x=+ 3
⇒ . 1 1 1
V For concave 1ens using, - - - =- (ii) Sulphurous acid
we have I - I = __ ⇒ v = 5 cm
V U /
This is a straight line with negative
l
slope. II
24. (c) As emergent beam is parallel, so
V 4 -20 8
H0 / '-..... OH
u
mirror must forms image at focus of lens. Magnification of concave lens = _!'.__ = 1.25
l(x) + 1(- 2) + 2(- 1) = 0
As size of 11 is 2 cm. X= + 4
s
:. Size of 12 = 2 x 125 = 25 cm (iii) Dithionic acid
31 . (b) Given that,
� �
M1 = 5 M, V1 = 500 mL, H0- � - � -0H
V2 = 1500mL
0 0
For dilution, M1V1 = M2V2
2(x) + 2(- 1) + 4(- 2) = 0
[MLr2J . t3 5t3
5 x 500 = M x 1500
Clearly, d = 12 cm. 2x -2 - 8 = 8
51
25_ (a) [K] = [p] [V 3 ] =
M = � = 1.66M
32. (c) According to Boyle's law, at

3 2x = 10
[ ] x=+ 5
[L2]
constant temperature, the volume of a (iv) Pyrosulphuric acid
= [ML4r2] given mass of a gas is inversely 0 0
26. (c) Electrons which have maximum .
proportiona1 to its . p oc -
. pressure, 1.e. 1
II II
energies are near to fermi energy level. V H0- � -0- �-0H
These electrons can jump to higher As, V1 > V2 > V3 > V4
energy levels. 0 0
33. (b) Calcium nitrate gives brick red
A < P2 < P3 < P4
27. (b) As smoke rises up in air, speed of 2(x) + 5(- 2) + 2(- 1) + = 0
flame which breaks down on heating to 2x - 10 - 2 = 0
smoke increases and flow becomes 2x = + 12
give oxygen and N02 which is a brown
28. (d) As, F = - d U _ option (d) is
turbulent. x=+ 6
gas 2Ca(N03 ) � 2Ca0 + 02 + 4N02
34. (a) When but-1-yne reacts with
Thus, the correct option is (a).
dr
correct. excess HBr, the major product obtained is 37. (a) Boiling point of a compound is
29. (a) T cos0 = mg and T sin0 = N 2,2 dibromobutane. This reaction follows dependent of on H-bonding present in it.
Intermolecular H-bonding is more in
13 w
T=� =
Markownikoffs rule
⇒ primary than in secondary amines as
Cif:i CH2C== CH + HBr ---t
cos0 12 there are two H-atoms available for
T = 1 5 N and w = mg,
Butyne
At H-bonding. Tertiary amines do not have
intermolecular H-bonding due to the
15 = 13 mg [·: g = lO ms-2] absence of H-atom. Therefore, the order
12
Br of boiling points of the given amines is as
15 x 12 = 13 x 10m follows
12 x 15
m_ - - - - 14 kg Clia CH2- -Clia
? nC4H9 NH2 > (Cif:; )2 NH > Ci\ N(Cif:i )2
13 X 10
n-butylamine diethylamine N,N dimethylethylamine
Br
2, 2 dibromobutane (1 °) (2°) (3°)
WWW.JEEBOOKS.INl
38. (c) Given velocity of light 43. (c) Among the given carbocations 48. (b) The partial pressure of oxygen
= 3 x 108 ms-1 benzyl and allyl carbocations are more (p02 ) in alveoli of lungs is 104 mm Hg,
stable than methyl and vinyl carbocations which is more than that of blood in the
C 3 x 108 ms-1
Frequency of light = 8 x ld- 5 s-1
because they have delocalised electrons. blood capillaries of lung alveoli (40 mm
v S x ld-5 s-1
As we know, ').., = - = ----- An allylic carbocation has two resonance Hg). This difference allows passive
structures whereas in benzylic diffusion of 02 from air filled in the lungs
carbocation has five resonance
49. (a) Stalled fork activates checkpoint
= 3.75 X 10-8 m to the blood vessels of lung alveoli.
structures. Thus, benzyl carbocation is
1 m = 109 nm the most stable one.
signaling and pauses replication. Since
RCH=CHCH2 RCH-CH=CH2
:. 3.75 x 10-8 m = 3.75 x 10-8 x 109 nm +
�+ 0 1 / S checkpoint checks DNA damage, cell
= 3. 75 x ld-nm = 4 x ld-nm �
39. (a) Electron affinities of II period

size prior to S-phase (i.e. DNA replication
(Allylic carbocation) phase) this checkpoint would be activated
element are less negative as compared to by stalled DNA replication fork.
corresponding III period element. This is 50. (d) Ester bonds are the least likely to
because of small size of II period be involved in stabilising the 3-D folding of
elements. Also, nitrogen has the most proteins. A long protein chain gets
least electron affinity due to stable folded upon itself like a hollow woolen ball,
half-filled configuration. Thus, the giving rise to a tertiary (3D) structure. This
correct order of electron affinity is structure is stabilised by several types of
40. (d) Xe atom has 8 electrons in its

N < O < S < Cl. bonds, i.e. hydrogen bonds, ionic bonds, van
der Waal's interactions, covalent bonds and
outermost shell. In case of XeF2, out of hydrophobic bonds.
these 8 electrons, 2 are used for bond Ester bond is formed between sugar and
formation, while 3 pairs remains
(Benzyl carbocation)
phosphate in a nucleotide and is not
non-bonded, i.e. it has 3 lone pairs.
44. (b)
involved in stability of a polypeptide
In case XeF4 , 4 electrons of Xe are used chain. Thus, option (d) is correct.
for bonding. Thus it has 2 lone pairs. 5 1 . (a) Insulin is the peptide hormone
2 1
In case of XeF6 , 6 electrons are involved CH=CH 2 which enhances the uptake of glucose
_,) CH...__,__ 4 ,.,....- H2C ......,__ s
5
,.,....- CH2 ......,__
for bond formation, thus, it has only 1 I molecules by liver cells (hepatocytes) and
lone pair. CHs CH2 CH CH3 fat cells (adipocytes) for its cellular
F I utilisation. Such an activity of insulin
,.,....-CH 2 brings down the level of glucose in the
: - Xe , .
I /.
-..._
I
H3C
52. (a) The cross for the question is

blood.
F
Thus, the correct IUPAC name of the
given compound is 4-ethyl-3-propyl XX XGy
XeF2 XeF4 XeF5
X
45. (c) Since, each period starts with the �

hex-1-ene.
(3 lone pairs) (2 lone pairs) (1 lone pair)
4 1 . (d) When aqueous solution of filling of electrons in a new principal xxc XY XY
benzene diazonium chloride is boiled, it quantum number, therefore the period Carrier Normal Carrier Normal
gives phenol. number in the long form of the periodic daughter son daughter son
table refers to the maximum principal Since the male offsprings get
quantum number of any element in the X-chromosome from their mother who is
period. Thus, period number = maximum normal homozygous, thus, none of the son
n of any element.
53. (d) Cell wall of the most fungi is
would be colourblind.
46. (d) Carbohydrates, fats and proteins

(where, n = principal quantum number)
Benzene Phenol
N-acetyl glucosamine. It is found in the
made up of chitin. Chemically it is
diazonium
chloride
all can be used as a substrate in cellular
42. (a) The electronic configuration of

respiration. All of them first get exoskeleton of insects.
converted to acetyl Co-A to enter Kreb's 54. (d)
chromium (Z = 24) is cycle of aerobic cellular respiration. Thus, Parents TT X tt
1s2 2s2 2p 6 3s2 3p 6 4s1 3d5
it is the common factor of respiration (Tall) (Dwarf)
F1 -generation Tt (Heterozygous tall
entering Kreb's cycle after breakdown of
n=4
for 19th electron the orbital is 4s
On selfing)
47. (b) When a tissue with a potential of
carbohydrates, fats and proteins.
Thus, T t
T
l = 0 to 3 differentiation is grown in an artificial TT Tt
m = - 3 to 3 medium containing auxin and cytokinin (Tall) (Tall)
1 F2- generation
s=+ - in a specific ratio, it starts Tt tt
2 differentiating. Thus, root and shoot t (Tall) (dwarf)
Thus, among the given options, only (a) differentiation occurs. Auxin initiates
corresponds to the above given values. Phenotypic ratio 3 : 1 [Tall : Dwarf]
root formation while cytokinin starts
So, option (a) is correct. Genotypic ratio 1 : 2 : 1
shoot formation.
WWW.JEEBOOKS.INl
55. (b) Reduction of pH of blood, i.e.

rl._.�.
(x - 1) (y - 1) = (x, y) + 1 = - (Xi + X2 + "· + X:!019 )
increase in acidity favours the dissociation
of oxyhaemoglobin thereby giving up more
Put x = 2, y = 3
(2 - 1) (3 - 1) = GCD of (2, 3) + 1
+ _
l X
+ _ _ 2_ + . . . +
1 - Xi 1 - ,½
X �J
1 - X2019
7
02• When this phenomenon occurs due to

2 = 1+ 1 = - 1+ 1= 0
65. (c) Given,
increase in CO2 concentration, then it is
:. (2, 3)
x = 3, y = 3
called Bohr effect.
56. (b) Sustained muscle contraction due In MBC, I is incentre of MBC.
(3 - 1) (3 - 1) = 4 = GCD of (3, 3) + 1
x = 2, y = 4
to repeated stimulus is known as tetanus. A
This results due to muscle fatigue.
57. (c) Sphincter of Oddi guards the also satisfies
opening of hepatopancreatic duct into the When x > 3 not satisfies the equation.
duodenum. Hepatopancreatic duct brings :. Only 3 pairs (2, 3), (3, 3) and( 2, 4)
secretion of liver as well as pancreas to satisfy the equation.
63. (b) In MBC, X and Y are points on
the duodenum.
58. (b) Lysosomes are hydrolytic AB and AC respectively.
AI, BI and CI intersect the circle at P, Q,
B C
enzymes containing cell organelles which
R respectively.
AX � and AY �
YC 1
are bounded by a single membrane. = =
XB 2
In MBC, LBIC + LIBC + LICB = 1 80°
Other organelles like chloroplast,
Area of MXY 1
Area of ti.BXY 2 LC
mitochondria and nuclei have double
L BIC + + = 1 80°
membrane system.
59. (b) Parapodia are present in aquatic
LB
LC
⇒ Area of ti.BXY = 20 2 2
LBIC = 1soo - ( � )
animals, i.e. annelids like Nereis which LB
[·: area of ti.AXY = 1 0]
help them in swimming. Other three Area of MEY = Area of ti.AXY
⇒
features, i.e. metameric segmentation, LA
+ Area of ti.BXY = 1 800 - ( 180 ; )
jointed appendages and chitinous
exoskeleton are present in phylum = 1 0 + 20 = 30 LA
= 90° + - = 90 + 20 = 1 1 0
i2i
Arthropoda. Out of these, metameric 2
segmentation is visible as tagmetisation.
60. (c) Anthocyanins are water soluble LBIC = L QIR = 40
[·: LA = 40° ]
°
LQPR = � QIR
vacuolar pigments that may appear red,
purple or blue depending on pH. It is 2
impermeable to cell membranes of plants [·: angle in a segment is half of angle
and can leak out only when membrane is
Area of MBY
B C on a centre segment of circle]
LQPR
damaged or dead.
6 1 . (a) Let the set S has n elements.
2
Area of ti.CBY
⇒ = � x 1 1 0° = 55°
1 2
Area of ti.CBY = 30 = 15 66. (c) By homogenity principle,
S + 15
:. Mean of S and {15}
m+ 2= 2 [a] = dimensions of power
:. Area of MBC = Area of MBY
n+l
T
W = [ML2r3 ]
(m +
+ Area of ti.CBY
⇒ (n + 1) 2) = S + 15
(n + 1) (m + 2) = nm + 15
[bt 2] = dimensions of power
[·: m = �] = 30 + 1 5 = 45 [MrJT-3 ] = [ML2r5 ]
m + 2n = 13 64. (a) We have,
⇒ [b] =
⇒ ... (i) [T2]
Also, mean of S and {15, l} is Xi + ,½ + 4l + · · · + X2019 = 1 [c] = dimensions of t3 = [T3 ]
m + l=
S + 15 + 1 and _3__ + � + . . . + X20 I � = 1
n+2
1 3
[d- t ] = dimensions of power
1 - Xi 1 - ,½ 1 - X2019 [T3 ] = [M-1 L-2r6 ]
⇒ [d] =
⇒ (n + 2) (m + 1) = S + 16 ⇒ _3___ + __::L_ + __5_ + . . . + -�019
i 2 2
1 - Xi 1 - Xi 1 - 4l
[ML2T-s ]
= nm + 2m + n + 2 = nm + 16
= �
� - x.i + Xi + . . .
1 - X:!019
n + 2m = 14
So, statement IV is incorrect.
⇒ ... (ii) Xi2 - .xi + Xi + ----
_- ---- 67. (b) Before collision, velocity of
= vcube = rm = l cms-1 = 0.0 l ms-1

From Eqs. (i) and (ii), we get 1 - Xi l - x2
n=4
translation of sphere
2 - +
+ �019 X:!019 X:!019
- � Xi Xi �-- + - -½ - + Xi x.i
:. S has 4 elements. l - X:!019 As collision is elastic, translational
62. (b) We have, (x, y) = GCD of x and y. _ ( - 1) ( --
�
1)
+ Xi
kinetic energy of sphere is transferred to
Given, xy = x + y + (x, y)
the cube but its rotational kinetic energy
1 - Xi 1 - Xi l - x2
xy - x - y = (x, y)
remains constant.
X - l)
+ . . . + ,½019 2019 + X21Jl9 :. After collision, Vsphere = 0,
xy - X - y + 1 = (X, y) + 1 1- X2019 l - X:!019 1
Vcube = 0. 0 lms- and m,phere = l rad s-1 .
WWW.JEEBOOKS.INl
68. (b) By KVL, 71 . (d) 75. (b) t,,G 0 is related to Ksp by the
C12H22O11 (s) + 12O2 (g) ---t 12COig) equation
+ 1 1H2O(l) t,,G 0 = - 2.303 RT log Ksv
0 0
t,,H� [12t,,rH (CO2) + 1 Mr H (H2O)]
= t,,G 0 = + 63.3 kJ = 63.3 X 1 03 J
- [t,, r Ho (C12H22O11 )l 63.3 x Hf = - 2.303 x 8.314 x 298 x log.K,,P
= [12(-943) + 1 1 (- 68.3)] - [- 53 0] logKsv = - 1 1. 09
1 -a- b 2kQ = - 1352 .9 J kcal mo1- 1 K8p = 8.0 x 1 0-12
we have, VAD = 2a = 1 - a + b Thus, number of moles of C12H22O11 76. (b) The nerves are myelinated with
Also, Ven = 2 (1 - a - b) = b + a + b required for 2700 kcal of energy unmyelinated segments called nodes of
2 2700 = 2 mol = 682.6 g Ranvier. The high phospholipid content
=
a= - 1352.9 of the myelin sheath offers electrical
5
72. (d) The alcohol on treatment with
insulation, thus saltatory conduction
and b = _! occurs as impulse jumps from one node to
5 acid gives an alkene (A) which on the next. This form of conduction
Hence, current through 2 kn resistor ozonolysis will give nonan-2, 8 dione. The facilitates a very rapid transmission of
reaction can be shown as impulses.
77. (a) The cross for the question is
a = � mA.
=
5 0HMe
0< :: �a
and current through middle 1 kQ resistor YyRr x YyRr
b = _! mA. l l Garnets
� �
=
5 A
69. (b) Change in momentum of steel
IK
:Ct
103
ball = - 2mv YR yR Yr yr
2mv = 2mv
Force on U-tube =
M YR YYRR YyRR YYRr YyRr
( ) 6 7 8 9
;:
Nonan-2, 8 dione
73. (c) Number of equivalents of silver

4mv 2 yR YyRR yyRR YyRr yyRr
= - = - 4 x -0.02- x 9-
red 3.14 x 1
formed = number of equivalents of copper Yr YYRr YyRr YYrr Yyrr
= 0.23 N formed.
YyRr yyRr Yyrr
-
= 0.2 N yr yyrr
In AgNO3 , Ag is in + 1 oxidation state.
70. (a) As, U = 2 2x In CuSO4 , Cu is in + 2 oxidation state. The given Punnett square shows
x +4
d U = � (- 2x) (- 1) (2x)
:. Equivalent weight of Ag =
1 08 =
1 08 9 : 3 : 3 : 1 ratio of the phenotypes only.
78. (b) As the substrate concentration
⇒ + 1
dx x2 + 4 (x 2 + 4 ) 2 Equivalent weight of Cu
2 63.6 = increases, the rate of reaction increases
---2 + ---4x = 31.8
=
2 until a maximum, when saturation of all
x2 + 4 (x2 + 4)2 the enzymes active sites occurs. When this
dU
Weight of silver _ Eq. wt of silver
2 = 4x2 happens, the limiting factor is enzyme
- = 0 when -- --- Weight of copper Eq. wt of copper concentration. Thus, graph (b) is correct.
dx x + 4 (x2 + 4)2
2
10.79 1 08 79. (c) Average amino acid residues
⇒ 2(x2 + 4) = 4x2 3 1.8 molecular weight = 1 1 0
⇒ 2x2 = 8 10.79 X 31.8 Polypeptide chain of molecular weight
Wcu = 20,000 = 182 amino acids
⇒ x=± 2 1 08 20,000 =
= 3.2 g 1 10
F = -d U = 0
As U is minimum at x = + 2 .
74. (c) Energy of one photon = -
he A triplet of bases in the DNA molecule
')..,, codes for one amino acid in a polypeptide
dx chain.
Now, restoring force constant. 6.626 x 1 0-34 Js x 3 x 1 08 ms-1 To translate 182 amino acids, there must
550 x 10- 9 m
k = 2u2 l
d be a minimum of 182 x 3 = 546
= _! units
= 3.61 X 1 0- 19 J nucleotides.
80. (b) Sequoia is one of the tallest tree
dx at x = 2 8
:. Number of photons
energy required species, known as red wood tree. It is a
= = =
m l ( ) gymnospermic plant.
� 8 x 5 : 1 0-3 energy of one photon
Salvinia is an angiosperm, but Ginkgo
o 1 0-17
= ---- and Pinus are gymnosperms.
= P� 3.61 x 1 0-19 Gymnosperms are well-adapted to
extremes of climate and are
= 5 rad s-1 = 2 7.67 = 28 heterosporous.
WWW.JEEBOOKS.INl
KVPY
PRACTICE SET 4
Stream :SA
M M : 100
Instructions
MATHEMATICS 5. If a, b, c ;::>: 4 are integers, not all equal and

1 . A natural number K is such that K < 2019 < (K + 1) .
2 2 4abc = (a + 3) (b + 3) (c + 3), then (a + b + c) is equal to
Then, the largest prime factor ofK is (a) 14 (b) 15 (c) 16 (d) 18
6. In a MBC, right angled at A, the altitude through A
and the internal bisector of LA have lengths 3 and 4
(a) 11 (b) 13 (c) 7 (d) 5
2. If real number a, b, c, d, e satisfy
respectively. Then, the length of median through A is
a + l= b + 2 = c+ 3 = d + 4= e+ 5
= a + b + c + d + e + 3, then the value of
(a) 20 (b) 24 (c) 15 (d) 10
a 2 + b2 + c2 + d2 + e2 is equal to 7. A rectangular floor that is 10 feet wide and 1 7 feet
(a) 8 (b) 9 (c) 10 (d) 1 1 long is tiled with 170 one-foot square tiles. A bug
3 . Let a semi-circle with centre O and diameter AB. Let
walks from one corner to the opposite corner in a
straight line including the first and the last tile, how
P and Q be points on the semi-circle and R be a point
on AB extended such that OA = QR < PR if
many tiles does the bug visit?
LPOA = 102 °, then LPRA is equal to
(a) 17 (b) 25 (c) 26 (d) 27
(a) 51 ° (b) 34° 8. Ashwani computes the mean µ, the median M and
(c) 25.5° (d) None of these the modes of the 365 values that are the dates of
4. If x = cos 1 ° cos 2 ° cos 3 ° . . . cos 89° and 2019. Thus his data consists of 12 ls, 12 2s ... , 12 28s,
1 1 29s, 1 1 30s and 7 31s. Let d be the median of
y = cos 2 ° cos 6° cos 10° . . . cos 86°, then the integer modes. Which of the following is correct?
nearest to � log 2 (�) is (a) µ < d < M (b) M < d < µ
(c) M = d = µ (d) d < µ < M
(a) 16 (b) 17 (c) 18 (d) 19
WWW.JEEBOOKS.INl
9. A sequence of numbers is defined recursively by

3 an - 2 · an - 1
2an - 2 - an - 1
a1 = 1, a2 = - and an = - - - - for all n ;::>: 3.
7
Then, a2019 can be written as E, where p and q are
q
relatively prime number, then the value of p + q is
equal to Now, consider the following statements:
(a) 6057 (b) 8087 (c) 8078 (d) 4039 I. Force acting on particle is 50 N.
10. A child builds towers using identically shaped cube of II. Force stops at t = 3 s.
different color. Then, number of different tower with
III. Force stops at t = 4 s.
a height 8 cubes can the child build with 2 red cubes,
3 blue cubes and 4 green cubes (one cube is left out) IV. Particle receives an impulse at t = 4 s.
lS Which of the above statements are correct?
(a) 24 (b) 288 (c) 312 (d) 1260 (a) Statements II and IV are correct
11. The least possible value of (b) Statements I, II and IV are correct
(x + 1) (x + 2) (x + 3) (x + 4) + 2019 is (where, x is real) (c) Statements I, III and IV are correct
(a) 2017 (b) 2018 (c) 2019 (d) 2020 (d) Statements III and IV are correct
12. Two circles of radius 5 are externally tangent to each 17. Correct graph of experimental values of specific heat
other and are internally tangent to a circle of radius of a constant volume of hydrogen gas is
13 at points A and B, as shown in the figure. The (a) Cv (b ) Cv
distance AB can be written in the form !!!._ when m

n
and n are relatively prime. 5/2 R
3/2 R
80_ T(K) --+-80-----'-- - 6--'-- T(K)

_ 3� 00
4
--+-�_ 00_
0_____.
(c) Cv (d) Cv
A B
7/2 R ··················· -- --' 7/2 R ·····························
Then, m + n is 5/2 R ·············

(a) 21 (b) 29 (c) 69 (d) 58 3/2 R 3/2 R
---1-- 8� - ------' T(K) -+- 8'--- - 6-'--- ----i ( )
13. A person X is running around a circular track 0--
30�
00 0 000 T K
00 3-'-
completing one round in 40 s. Another person Y
running in opposite direction meets X every 15 s. The 18. Ratio of nuclear density of nuclei 112 1 and 1f Ba is
time, expressed in seconds, taken to Y to complete (a) 142 : 139 (b) 53 : 56
one round is (c) 139 : 142 (d) None of these
(a) 12.5 (b) 24 (c) 25 (d) 55 19. A particle starts from origin, it accelerates first
14. Consider all 6-digit numbers ofthe form abccba, t0 second and then deaccelerates at same rate till 2 t0
where b is odd. Then, number of all such 6-digit second along the positive x-direction. Variation of
numbers that are divisible by 7 is displacement x with time t for the particle is given by
(a) 70 (b) 80 (c) 75 (d) 85 ( a) X (b) X
15. Let ABCD be trapezium in which AB is parallel to

CD and AD is perpendicular to AB. Suppose ABCD
has incircle which touches AB at Q and CD at P.
Given that PC = 36 and QB = 49, then length PQ is
(a) 85 (b) 84 (c) 76 (d) 80
2t0
(d) x
PHYSICS
(C) X
16. Velocity-time graph of a particle of mass 10 kg

pushed along a frictionless surface by an external
force is as shown below. 2t0
to 2t0
WWW.JEEBOOKS.INl
20. A mass m initially at rest is pulled with a force F.

If force is proportional to instantaneous time t, then
kinetic energy of the particle is proportional to
(a) t 2 (b) t-2 (c) t 4 (d) t 0
21. Density of ice is x (glee) and that of water is g (glee).
Change in volume in cc when m grams of ice (a) 20Q (b) l OQ
(c) 5Q (d) 25Q
completely melts is
(a) m (y - x) 26. Fermi energy level for an electron is
(a) a possible energy value that an electron can have in
(c) mxy (y - x)
free state
(b) an unfilled energy level that can be occupied by two
22. How much work is required in units of electron-volt electrons of opposite spins
to carry an electron from the positive terminal of a (c) lowest energy value possible for a bound electron
12 V battery to the negative terminal in external (d) highest occupied energy level at absolute zero kelvin
circuit? upto which every possible energy levels are filled
(a) 12 eV (b) - 12 eV 27. Solar cookers are not very popular because
(c) 6 eV (d) - 6 eV (a) they are bulky
23. Following graph shows atmospheric pressure, gauge (b) they are not put into kitchen
pressure and absolute pressure. (c) they cook food in large time
p (d) sun changes its position rapidly
28. A cubical block of side 1 m and mass 10 kg is placed
P2 on a rough surface. Block can be toppled by applying
a force horizontally at its upper edge. Minimum
value of F is
Then, choose the correct option.

(a) Pi = gauge pressure, p2 = atmospheric pressure, (a) 100 N (b) 200 N
p3 = absolute pressure (c) 50 N (d) 25 N
(b) Pi = atmospheric pressure, p2 = gauge pressure,
p3 = absolute pressure
29. Potential energy between two molecules as a function
(c) Pi = absolute pressure, p2 = atmospheric pressure, of their separation is as shown below.
p3 = gauge pressure u
(d) Pi = gauge pressure, p2 = absolute pressure,
p3 = atmospheric pressure
24. A man can walks on hard ground with a speed of
o. 6 A 1 .s A
5 ms-1 and on sandy ground with 3 ms-1 .
oA A ! 1 .2 A
-+��----!f- - +- -�---<,__- ➔X
Let he is standing on border of sandy and hard
ground and wishes to reach the tree situated on the
sandy ground as shown below.
Force between particles is zero at
D /' Tree (a) x = 0.4A (b) x = 0.6A
(c) x = 12 A (d) x = 1sA
Man
:I
. :: 1 20 m 30. Using following figures,
r-r
� E // i
A lllJJJJ777JJ77JJ/jJJJJlm/J777JJlll)JJlll?l B
� 1 00 m � C
He can reach tree in least time when he walks on
hard ground upto point E and then he walks straight
µ
towards tree along EO. Distance AE is

(a) lO m (b) 20 m
(c) 30 m (d) 50 m Relation between refractive indices µ1 and µ 2 is
25. Equivalent resistance between A and B is 6 n. Value (a) µ l < µ 2 (b) µ 1 µ 2 µ
=
2
of resistance R 1 is (c) µ 1 > µ 2 (d) µ 1 = µ 2
WWW.JEEBOOKS.INl
Cu 2+ /Cu(s), E 0 = + 0.34
CHEMISTRY l2 (s) / r, E 0 = + 0.54
31 . How many moles of magnesium phosphate (a) Cu will reduce Br- (b) Cu will reduce Ag
Mg3 (PO 4 \ will contain 0.25 mole ofoxygen atom? (c) Cu will reduce 1- (d) Cu will reduce Br2
(a) 0.02 (b) 3.125 X 10-2 39. The carboxylic acid which reduces Tollen's reagent is
(c) 125 X 10-2 (d) 2.5 X 10-2 (a) acetic acid (b) oxalic acid
32. At what temperature will the r.m.s velocity ofSO 2 be (c) formic acid (d) lactic acid
the same as that ofO 2 at 303 K ? 40. The correct order of C-Obond length among
(a) 350 K (b) 505 K CO, cot, CO 2 is
(c) 606 K (d) 100 K
(a) CO2 < cot < co (b) CO < cot < CO2
33. When acidified sodium extract of organic compound (c) cot < co2 < co (d) co < co2 < cot
is treated with acetic acid and lead acetate, a black
41. When 22.4 L ofHig) is mixed with 11.2 L ofC1 2 (g)
precipitate is obtained. This suggests that the
organic compound contains each at STP, the moles of HCl(g) formed is equal to
(a) chlorine (b) phosphorus (a) 1 mole of HCl (g) (b) 2 moles ofHCl (g)
(c) sulphur (d) nitrogen (c) 0.5 mole ofHCl (g) (d) 1.5 moles ofHCl (g)
34. Acetone is treated with excess of ethanol in the 42. A 1 L flask contains 32g ofO 2 gas at 27° C. What
presence of hydrochloric acid. The product obtained is mass ofO 2 must be released to reduce the pressure in
0 the flask to 12.315 atm?
II (a) 8 g (b) 16 g (c) 24 g (d) 0 g
(a) CH.i CH2CH2 C CH.i
0 43. What is the orbital angular momentum of an electron
in /-orbital ?
(d) -J3h
II
(b) CH.i CH2CH2 C CH2CH2CH.i (a) 15h (b) -.J6h (c) -✓3h
1t 1t 1t 1t
/ OH
(c) (CH3hC 44. Aluminium trifluoride is treated with anhydrous HF
"'- OC2H5 and then with NaF. When gaseous BF3 is passed
through the solution obtained, a precipitate X is
formed. The formed pricipitate X is
(a) Na3 [AlF6 ] (b) Na[BF4] (c) AlF3 (d) H3 [AlF6 ]
45. Which one of the following will be aromatic?
35. The electronegativity of the following elements
increases in the order
(a) C < N < Si < P (b) N < Si < C < P
(a)
0
(c) Si < P < C < N (d) P < Si < N < C
36. The de-Broglie wavelength associated with particle of
mass ofl0-6 kg moving with a velocity of 10 ms-1 is
(b) 6.63 x 10-16 m
()
c 0
BIOLOGY
(a) 6.63 x 10-7 m
21
(c) 6.63 x 10- m (d) 6.63 x 10-29 m
37. The product formed when 1-bromo-3- 46. Which cells of 'crypts of Lieberkuhn' secrete
chlorocyclobutane reacts with two equivalents of antibacterial lysozyme?
metallic sodium in ether, is (a) Argentaffin cells (b) Paneth cells
Cl (c) Zymogen cells (d) Kupffer cells
(a) }=J (b) d 47. Which among the following are the smallest living
cells, known without a definite cell wall, pathogenic
Br to plants as well as animals and can survive without
oxygen?
() � (d) C2:J
c (a) Bacillus (b) Pseudomonas
38. E 0 values of some redox couples are given below. On
(c) Mycoplasma (d) Nostoc
the basis of these values choose the correct option. 48. The cell organelle responsible for extracting energy
Br2 /Br- , E 0 = + 1.90 from carbohydrates to form ATP is
Ag+ / Ag(s), E 0 = + 0.80
(a) lysosome (b) ribosome
(c) chloroplast (d) mitochondrion
WWW.JEEBOOKS.INl
49. DNA fragments are 55. Fruit and leaf drop at early stages can be prevented
(a) positively charged by the application of
(b) negatively charged (a) cytokinins
(c) neutral (b) ethylene
(d) either positively or negatively charged depending on (c) auxins
their size (d) gibberellic acid
50. An important characteristic that hemichordates 56. Which one of the following options best represents
share with chordates is enzyme composition of pancreatic juice?
(a) absence of notochord (a) Amylase, peptidase, trypsinogen, rennin
(b) ventral tubular nerve cord (b) Amylase, pepsin, trypsinogen, maltase
(c) pharynx with gill slits (c) Peptidase, amylase, pepsin, rennin
(d) pharynx without gill slits (d) Lipase, amylase, trypsinogen, procarboxypeptidase
5 1 . Lungs are made up of air-filled sacs, the alveoli. They 57. In the fruit fly, Drosophila melanogaster, the diploid
do not collapse even after forceful expiration, because number of chromosomes is 8. In the absence of
of crossing over or mutation, how many genetically
(a) Residual Volume (RV) unique kinds of gamete might be formed by one
(b) Inspiratory Reserve Volume (IRV) individual?
(c) Tidal Volume (TV) (a) 4 (b) 8
(d) Expiratory Reserve Volume (ERV) (c) 16 (d) 32
52. Viroids differ from viruses in having 58. Biochemical analysis of a sample of DNA shows that
(a) DNA molecules with protein coat cytosine forms 40% of the nitrogenous bases. Which
(b) DNA molecules without protein coat percentage of the bases is adenine?
(c) RNA molecules with protein coat (a) 10% (b) 20%
(d) RNA molecules without protein coat (c) 40% (d) 60%
53. Plants, which produce characteristic pneumatophores 59. The first stable product of fixation of atmospheric
and show vivipary belong to nitrogen in leguminous plant is
(a) mesophytes (b) halophytes (a) NO2 (b) ammonia
(c) psammophytes (d) hydrophytes (c) NO3 (d) glutamate
54. Spliceosomes are not found in cells of 60. Treponema pallidum pathogen is a cause of
(a) plants (b) fungi (a) leprosy (b) plague
(c) animals (d) bacteria (c) syphilis (d) pertussis
MATHEMATICS respectively. Let AI1 and AI2 meet BC in E and F

respectively. If LBI1E = 60 °, then L CI2F is (in
a 2 + b2 - c2 + 1 = 0, then the sum of all possible values

6 1 . Integer a, b, c satisfy a + b - c = 1 and degree)
(a) 30° (b) 45° (c) 75° (d) 60°
of a 2 + b2 + c2 is equal to 64. Let P(x) = a0 + a1x + a2x2 + . . . + an x' be a polynomial
(a) 17 (b) 18 (c) 20 (d) 24 in which a; is a non-negative integer for each
62. There are several tea cups in the kitchen, some with i E (0, 1, 2, 3, . . . , n). If P(l) = 4 and P(5) = 136, then P(3)
handles and others without handles. The number of lS
ways of selecting two cups without a handle and (a) 25 (b) 30 (c) 32 (d) 34
three with a handle is exactly 1200. Then, the 65. In a quadrilateral ABCD, it is given that
maximum possible numbers of cups in the kitchen is AB = AD = 13, BC = CD = 20, BD = 24. If ris the
equal to radius of the circle inscribed in the quadrilateral,
(a) 25 (b) 27 (c) 28 (d) 29 then the integer closest to ris
63. Let D be an interior point of the side BC of a MBC. (a) 6 (b) 8 (c) 9 (d) 10
Let 11 and 12 be the incenters of MED and MCD
WWW.JEEBOOKS.INl
PHYSICS 69. Velocity-time graph of an object moving along a

straight line is as shown below.
66. Two earthworms climb over a rough thin wall of an V
earthen pot 10 cm high placed in a lawn. (ms-1 )
8
9
----f- -�- -
- -��- -- -t(s)
3 5 7
One of the worm is 20 cm long and other is only -8 ---- ---------··----------··-----------------------

10 cm long and mass of both earthworms is 20 g.
Ratio of work done by worms when they crosses half
of their length across top of the wall is If x = displacement (in m) and a = acceleration (in ms-2).
(a) 1 : 1 (b) 2 : 3 Then, correct graph is
(c) 2 : 1 (d) 1 : 2
( a)x ( m) ( b) x (m)
67. A jar of height 20 cm is filled with water (nw = 4 / 3).
At centre of jar on the bottom surface, a red dot is 28
made.
--+ - - - �------, t(s)
----,'-- - - - �------, t(s) 9
rn
9
I t "t
a
(c) (ms-2)
·------ ---- - - -- - ---------· 2.6? e---- - --------
· -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- ·
· «<------« - - - =<<< - - - - - - - - - - - - c- c-� Wate,
· --- --- --- --- --- --- --- --- --- --- --- --- -- --- --- --- --- --- --- --- --- --- --- --- -·
------ ----- -----------
--+
Dot - - - �------- t(s)
9 -+- �-_,5,-----�------> t(s)
3
Minimum radius of an opaque plastic disc that
makes the dot invisible from top is
(a) 20 cm (b) 23 cm
70. A vessel has a hole of radius r= 1 cm. Vessel is
(c) 12 cm (d) 2 cm
initially full of water and hole is sealed by a ball of
68. Consider arrangements A and B for making a torch: mass m = 1t g. Depth of water is now slowly reduced
h0, the ball rises out of the hole.

using a syphon and when it reaches a certain value
+
(B)
Value of h0 is
(A)
(Radius of ball is slightly larger than hole but for
Now, consider the following statements. calculation both can be taken same, g = 10 ms-2)
I. Torch A is brighter. (a) 65 cm (b) 72 cm (c) 84 cm (d) 110 cm
CHEMISTRY
II. Torch B is brighter.
III. Torch A lasts longer.
IV. Torch B lasts longer.
7 1 . A solid compound X on heating gives CO 2 gas and a
Which of the above statements are correct?
(a) Statements I and III are correct
residue. The residue mixed with water form Y. On
solution Z is formed. On boiling Z, compound X is

passing an excess of CO 2 through Y in water, a clear
(b) Statements II and IV are correct
(c) Statements I and IV are correct
reformed. The compound X is
(d) Statements II and III are correct
(a) Ca(HCOa )2 (b) CaCO3 (c) Na2CO3 (d) K2CO3
WWW.JEEBOOKS.INl
72. Standard entropies ofX2 , Y2 and XY3 are 60, 40 and 77. Haemophilia is caused by a sex-linked, recessive
50 JK- 1mor1, respectively. For the reaction, allele. A couple have a haemophilic son, a normal son
and a haemophilic daughter. What are the most
! X2 + � Y2 � XY3 ; 1',.H = - 30 kJ likely genotypes of the parents?
2 2
Mother Father
To be at equilibrium, the temperature should be
(a) 750 K (a) XHX XHY
(b) 1000 K (c) 1250 K (d) 500 K
73. A (C 4 H6 ) ------. B (C 4 H8 ) ------+
/ H2 Ni O /H zO/Zn (b) XHY
XHY
3
CH3CHO
l mol (c) X X
H H
XHY
Identify A and B in the above reaction. (d) xH yH xH y
(a) � and � 78. Which of the following statements is correct in
relation to the endocrine system?
(b) � and � (a) Adenohypophysis is under direct neural regulation of
(c) CH 3 CH 2 C = CH and CH 3 CH = CHCH 3 the hypothalamus
(d) CH 2 = CHCH = CH 2 and CH3 CH = CHCH3 (b) Organs in the body like gastro-intestinal tract, heart,
kidney and liver do not produce any hormones
74. In the Kjeldahl's method for the estimation of (c) Non-nutrient chemicals produced by the body in trace
nitrogen present in a soil sample, ammonia evolved amount that act as intercellular messenger are known
from 0. 75 g of sample neutralised 10 mL of 1 M as hormones
H2SO 4 . The percentage of nitrogen in the soil is (d) Releasing and inhibitory hormones are produced by
(a) 37.33 (b) 45.33 (c) 35.33 (d) 45.33 the pituitary gland
75. A carbon compound contains 12.8% of carbon, 2. 1% of 79. If the nucleus of a human motor neuron contains
hydrogen and 85. 1% of bromine. The molecular 6.8 picograms (pg) ofDNA, what mass of DNA is the
weight of the compound is 187.9. The molecular nucleus of an actively dividing human skin cell likely
formula of the compound is to contain at the end of interphase?
[Atomic weight of H = 1.008, C = 12.0 and Br = 79.9] (a) 3.4 pg (b) 6.8 pg
(a) CH3 Br (b) CH 2 Br2 (c) C2 H4Br2 (d) C2H 3 Br3 (c) 13.6 pg (d) 20.4 pg
80. The diagram represents a reaction with and without
BIOLOGY an enzyme. What is the activation energy of the
enzyme catalysed reaction?
76. The complete oxidation of one mole of glucose yields
2880 kJ of energy. The addition of one phosphate
molecule to ADP requires 30.6 kJ of energy per mole.
In aerobic respiration, 38 molecules ofATP are
formed as a result of the breakdown of each glucose
molecule. Which figure best represents the efficiency
Reaction
of aerobic respiration in trapping the energy released
by the glucose molecule?
(c) C
(a) A (b) B
(a) 23% (b) 36% (c) 40% (d) 45% (d) D
Answers
PART-/
(a) 2 (c) 3 (d) 4 (d) 5 (c) 6 (b) 7 (c) 8 (d) 9 (c) 10 (d)
11 (b) 12 (c) 13 (b) 14 (a) 15 (b) 16 (b) 17 (d) 18 (d) 19 (c) 20 (c)
21 (d) 22 (a) 23 (b) 24 (a) 25 (b) 26 (d) 27 (d) 28 (c) 29 (a) 30 (a)
31 (b) 32 (c) 33 (c) 34 (d) 35 (c) 36 (d) 37 (d) 38 (d) 39 (c) 40 (d)
41 (a) 42 (b) 43 (d) 44 (b) 45 (d) 46 (b) 47 (c) 48 (d) 49 (b) 50 (c)
51 (a) 52 (d) 53 (b) 54 (d) 55 (c) 56 (d) 57 (c) 58 (a) 59 (b) 60 (a)
PART-II
61 62 63 64 65 66 67 69
I
68
I I
(b) (d) (a) (d) (b) (b) (b) (c) (d) 70 (a)
71 (b) 72 (a) 73 (d) 74 (a) 75 (c) 76 (c) 77 (a) 78 (c) 79 (c) 80 (b)
M/WW.JEEBOOKS.IN]
Solutions
1 . (a) We have, 1 ( II sin 4r)2
22
- --
2
K < 201 9 < (K + 1) 2
266 -J2 r = l
K2 < 2019 1 22
. 4r
K < -v'2 019
= -- II sm ⇒
⇒ 266 -J2 r = l
K < 4493 1 22
⇒ b = 4 or 5 for b = 4, e = -
⇒ = -- II sin (92 - 4r) 49
K = 44 2 66 -J2 r =l EI
1 22 5
⇒ K = 4 X ll = 66 ro II cos (4r - 2) For b = 5, e = 7
a + b + e = 4 + 5 + 7 = 16
The largest prime factor of K is 1 1 . 2 -v 2 r = l
2. (c) We have,
1 ⇒
⇒ x = -- y
266 -J2 6. (b) Given,
a + l= b + 2 = e + 3 = d + 4 = e + 5 ABC is a right angled triangle
LA = 90°
133
66 + !2
= a+ b+ e+ d + e+ 3 ⇒1' = 2 =2 2
X
b=a- ie=a- �d = a- �e= a - 4
� log 2 1' = � X
133 C
⇒ a+ b+ e+ d + e= a - 2 = 19
7 X 7 2
a = 2, b = 1, e = 0, d = - 1, e = - 2 5. (c) We have,
:. a2 + b2 + e2 + d 2 + e2 4abe = (a + 3) (b + 3) (e + 3) b
= (2)2 + (1)2 + (0)2 + (-1) 2 + (-2)2 a, b, e � 4, a, b, e are integers.
= 4 + 1 + 0 + 1 + 4 = 10
3. (d) Given, AB is diameter of
(1 + � ) ( 1 + � ) (1 + � ) = 4
A B
semi-circle. ⇒ 4� a � b� e
---
Altitude AL = 3
⇒ .!. > .!. > .!. AN = 4 (AN is angle bisector of LA)
a- b- e
AM is median of MBC
.....
', \ Q
�J �
⇒ 1+ � � 1+ � � 1+ �
a b e Area of MBC = _!_ be = .!._ AL a
2 2
R' r A 0 (1 + 4 ⇒ 1 + � � (4)113 ⇒ be = 3a
Since, R can be any point. Let A and R'
B
Area of MBC = Area of MEN + Area of
< -3- = �
and hence, its corresponding point Q lie ⇒ a- MNC
.!. be = .!. AB - AN sin 45°
4113 - 1 4113 - 1
on the arc AQ'. ⇒
Hence, LPRA cannot be determined.
= 43'3 + 4113 + 1 2 2
4. (d) We have,
⇒ a� 3+ 2+ 1 + _!_ AC - AN sin 45°
2
a < 6 ⇒ a = 4 or 5
l ) (1 + � ) = �
°
X = COS 1 COS 2 COS 3 . . . COS 89
° ° °
⇒ .!._ be = _!_ x 4 x ----1:_ (b + e)
and y = cos 2° cos 6° cos 10° . . . cos 86° For a = 5, ( 1 + 2 2 -/2
89 ⇒ be = 2-12 (b + e)
Let x = 1t cos r 0
r=l ⇒ 2 2
b e = 8(b2 + e2 + 2be)
89
9 + 1 - r)0 ⇒ 9a2 = 8(a2 + 6a)
⇒x = IT cos r 0 cos ⇒
r=l ⇒ 9a2 - 8a2 = 48a
1 89 II sin 2r 0 ⇒ a = 48
- 89 r = l
2 BC a
AM = MC = MB = - = -
1 44 2 2
AM =
- ( II sin 2r 0 ) sin 90°
89 r = l
2
48
2 ⇒ b < 6 ⇒ b � 5, b = 5 (b � a) = 24
2
7. (c) The number of tiles the bug visits
44
1 1 + � = 25
e 16
= -- II sin 2r 0 ⇒
244 -J2 r = l
16 . is equal to 1 plus the number of times it
1 44 ⇒ e = - em teger
- -- II sin 2r 0 sin 2 (44 + 1 - r) 3 crosses a horizontal or vertical line. As it
244 -J2 r = l must cross 16 horizontal lines and
⇒ a ;c 5
- --
1 44
II sin 4r
266 -J2 r = l
For a = 4, ( 1 + l) (
1 + � ) = 1;
9 vertical lines. It must be that bug visits
a total of 16 + 9 + 1 = 26 squares.
WWW.JEEBOOKS.INl
8. (d) Mean (µ) of 365 values of the takes 1 1 . (b) We have, So, (a, = {(9, 2) (8, 1) (7, 0) (2, 9) (1, 8)
2019 are (x + 1) (x + 2) (x + 3) (x + 4) + 2019 (9, 9) (8, 8) (7, 7) (6, 6) (5, 5) (4, 4) (3, 3)
12(1 + 2 + 3 + . . . + 28) = (x + 1) (x + 4) (x + 2) (x + 3) + 2019
(2, 2) (1, 1)}
+ l l x 29 + l l x 30 + 7 x 3 1 = (x2 + 5x + 4) (x2 + 5x + 6) + 2019
Number of pairs of (a, b) = 14
µ= Also b can be 5
365 = (x2 + 5x) 2 + 10(x2 + 5x) + 24 + 2019
12 X 28 X 29 = (x2 + 5x) 2 + 10(x2 + 5x) + 25
·: Total number of 6-digit number
+ 319 + 330 + 217
2 = 14 x 5 = 70
1 5. (b) Given, PC = 36
µ= = 15.7
365 - 25 + 24 + 2019
BQ = 49
= (x2 + 5x + 5) 2 + 2018
Median = 366th observation
2 :. Minimum value of x2 + 5x + 5 is 0
= 183 th observation :. Minimum value of (x + 1) (x + 2) (x + 3) C 36 P x D
(x + 4) + 2019is 2018.
1 2. (c) Given, PA = 13 = PB
= 16 X
d (Median of modes)
Mode of data = 1, 2, 3, . . . , 28 QA = RB = 5 49
28 28 X
( )th + ( + 1)th
Median of data = 2 2
8 1 3 T 36 Q X A
BT = BQ - TQ
2
= 49 - 36 [·: TQ = PC]
14 + 15 =
= 14.5
BT = 13
2
d<µ <M
9. (c) We have, In /'J3TC, BC2 = TC2 + BT 2
⇒ (85)2 = PQ 2 + (13)2 [·: TC = PQ]
PQ 2 = (85)2 - (13)2
3
0i = l, a2 = 7
an 2 , an 1
⇒
PQ 2 = (85 + 13) (85 - 13)
-- - - -
= 13 - 5 = 8
PR = PB - RB = 8
⇒
2an 2 - an 1 PQ 2 = 98 x 72
an = -
- - QR = 2QA = 10
⇒
M'QR - M'AB
⇒ PQ = ✓- 4_
9_x_2_x_3_6_x_
2
PQ QR ⇒ PQ = 7 x 6 x 2 = 84
PA AB 1 6. (b) F =
-- - !1p = 10 x 15 =
50 N
AB =
3
As velocity is constant after t = 3 s, hence
10 x 13 65 M
- ⇒ =
a4 = a 2 � 8 4
2� - a.a force stops.
1 7. (d) At low temperature, H2 molecule
m = 65, n = 4
3 3
Hence, m + n = 65 + 4 = 69
1 3. (b) Distance travelled by X in 40 s.
3
2 (�)- t1
7 11 has only translational degrees of freedom
15 /=3
0 = 21t X 15 ... (i) Above 600 K molecule be given to vibrate
3 3 3 3 3 40
·: Sequence are 1, - , - , - , - , . . . , -- and at above 3000 K molecule dissociates.
7 1 1 15 19 4n - 1 1 8. (d) Nuclear density is a constant
3 -
an = - (p = 238 x l d-7 kg m-3 ). It is independent
4n - 1 of nuclear size and number of nucleons.
3 3 So, ratio is 1 : 1.
1 9. (c) x0 = _! atJ
⇒ a2019 = =
4(2019) - 1 8075
·: p 3, q
2
= = 8075 Distance travelled by Y in n second
p + q = 8078 and
1 0. (d) We have,
2 ... (ii)
0 = 21t - ( : X 15)
So, correct graph is (c).
Total number of cubes = 9 From Eqs. (i) and (ii), we get 20. (c) :. F = kt
mJ;dv = k t dt
J;
2 Red cubes, 3 Blue cubes, 4 Green cubes 21t 21t
X 15 = 21t - ( X 15) ⇒
Number of ways making tower of height 40 n
8 cubes n = 24 ⇒ mv = kt 2
1 4. (a) We have, 6-digit numbers
9 C 7G.i 4C
2 4
abccba, b is odd.
2
⇒ V= � t
9! 7! -9! - m
If abc - cba is divisible by 7
⇒ - X - X l= -
2! 7! 3! 4! 2! X 3! X 4! Kinetic energy is
=
9 X 8 X 7 X 6 X 5 X 4! =
1260 ⇒ abc - cba = 99(a - c) = 7M K = _! mv2 ⇒ K oc t 4
2 X 3 X 2 X 4! 2
WWW.JEEBOOKS.INl
2 1 • (d) - Mass
- - = Density :. 0.25 moles are present in Mg3 (PO 4 ) 2 37. (d) The product formed when
Volume 1-bromo-3-chlorocyclobutane reacts with
� x 0.25 = 3.125 x 10-2 mol .
=
As mass remains same, 8 two equivalents of metallic sodium in
vice X Pice = Vwater X Pwater
32. (c) From kinetic gas, vrm, = �
3 ✓ ether is bicyclo [1. 1.0]. This reaction is
known as Wurtz reaction.
⇒ Vwater = !!!
✓3RTso2
;=:i:�; - ;)
y 3RTso2 Cl
vrms of SO2 = =
⇒ AV � MS02 64 � + 2Na � �
)------J
✓3RT02
bicylo [1.1 .0]
/3RT x 303 Br
vrms of 02 = = + 2NaCl + NaBr
38. (d) Given E0 values are
M02 � 32
22. (a) W = qdV = e [(V_) - <V+ )l
According to question, vrm, rso2 J = vrm, ro2 J
Br2 / Br = + 190V
Ag I Ag+ = - O.S0V
= - e (0 - 12) = + 12 eV
An electron will move from negative to �= ✓

3RT 303
positive terminal by itself. So, positive 3� 2+
Cu /Cu (s) = + 0.34 V
work is required to carry electron in
T,S02 _
-
303 X 64 r llis) = - 0.54
reverse direction.
23. (b) Pabsolute = Patmospheric + Pgauge
32 If the E;ell values of the redox reaction is
T502 = 606 K positive, then only copper can reduce that
Also, Pgauge > Patmospheric • 33. (c) The formation of black precipitate element. (the reaction will be feasible)
24. (a) Let AE = x, then EC = 100 - x. indicates the presence of sulphur in an For the reaction,
So, ED = ✓(100 - x)2 + (120)2

organic compound. The sodium extract of Cu ---t Cu 2+ + 2e- E0 = - 0.34V
organic compound contains Na 2S which Br2 + 2e- ---t 2Br- ; E0 = + 109V
- - - - -
forms a black precipitate of PbS when
(lOO - x)2 + 1202 Cu + Br2 ---t CuBr2 ; E0 = + 0.75V
:. Time taken � + \I/
= treated with lead acetate.
5 3 Since, E;ell of this reaction is positive,
Na 2S + (CH.i COO)2Pb ---t PbS .j, . therefore Cu can reduce Br2. While in
This is minimum when t = 10m. Sodium Lead Lead sulphide
25. (b) R -
15 x .lli extract acetate (black ppt.) other reaction E�alue will be negative and
+ 2 CH.i COONa hence Cu cannot reduce other elements.
AB 15 + Hi
15.Ri 34. (d) When carbonyl compounds are 39. (c) Tollen's reagent is ammoniacal
⇒ 6= treated with excess of alcohol, first silver nitrate. It is reduced to silver by
15 + Hi compounds having -C-H group.
hemiacetals are formed and then acetals
⇒
6 x 15 = .Ri .Ri =
⇒ lO Q are formed, i.e. II
+•s
9 0 0
26. (d) Fermi energy level is last filled
C CH
� 3
Ethanol
T
energy level at zero kelvin. 0 Fomrio acid l -�-H group
Acetone
27. (d) As sun changes its position
1 / OH
(CH3hC
rapidly, so reflector of solar cooker is to be "'-
OC2H 5 Thus, it reduces Tollen's reagent.
Hemiketal
adjusted nearly in every � hour duration.
28. (c)
2 1 C2H 50H(Excess)
[2Ag(NH 3 )2 t + HCOOH ---t 2Ag .j, + CO2
Silver
+ 2NH!
(CH3hC
/ OC2H 5 40. (d) Greater is the s-character, shorter
"'--
OC2H 5 is the bond length. The C-atom in cot is
Acetal
Rotational equilibrium about O gives,
sp2-hybridised as shown.
35. (c) On moving across a period from / o- 0
l left to right in periodic table O=C +-----t o--C /
F x l = mg - "'-- o- "'-- o-
1
2 electronegativity increases. This is
/ o
mg because across the period the size of an
⇒ F= = 50 N atom decreases. While on moving down 0-C
2 �O
the group, electronegativity decreases.
29. (a) Force is zero when potential Thus, the correct order of The C-atom in CO2 is sp-hybridised with
energy is minimum. electronegativity is
30. (a) From first ray diagram,
bond distance of carbon oxygen is 122 pm.
Si < P < C < N O = C = o � o+ =c-0-
µ = µ1 (1.8) (2.1) (2.5) (3.0) � o- -e = o+
36. (d) According to de-Broglie relation,
A = !!_
From second ray diagram, The C-atom in sp-hybridised with C-O
µ < µ 2 ⇒ µ1 < µ 2 bond distance 110 pm.
3 1 . (b) Mg3 (PO4 )2 ---t 3Mg + 2P + 80 mv
C=O
6.63 X 10-34 =
As 8 moles of O-atoms are present in 6.63 X 10-29m Thus, the correct order of bond length is
1 mole ofMg3 (PO4 )2. 10..,, X 10 CO < CO 2 < COt
WWW.JEEBOOKS.INl
4 1 . (a) H2 (g) + Cl2 (g) ----t 2HCl(g) As compound given in option (d) follows These plants are adapted to grow in
22.4 L at STP is occupied by 1 mole ofC12 Huckel's rule. Thus, it is aromatic in highly saline areas such as mangroves.
nature. Pneumatophores help these plants in
46. (b) The mucosa present in between
11.2 L will be occupied by Cl2
l x 112 respiration as they do not get sufficient
= = 0.5 mol oxygen from the soil. On the other hand
224 the bases of villi of small intestine (crypts
vivipary aids in perennation.
54. (d) Spliceosome is a large molecular
As per equation, of Lieberkuhn) contain Paneth cells,
which secrete antibacterial lysozyme.
1 mole of Cl2 produces 2 mole of H Cl
Kupffer cells are phagocyte cells of liver. complex found in nucleus of eukaryotic
:. 0.5 mole of Cl2 produces = 2 x 0.5 = 10 Zymogen cells produce enzyme. cells of plants, animals and fungi, etc. It
mole of HCl.
42. (b) From ideal gas equation,
Argentaffin cells produce hormones. is assembled from snRNAs and protein
47. (c) Mycoplasma is triple layered
p V = nRT
complexes that play an important role in
smallest living cells. It does not have splicing of introns. Spliceosome is absent
w
n=- in the cells of bacteria.
55. (c) Auxin delays abscission of leaves
Also, definite cell wall. It is an anaerobic
p V = _l))_ RT
M organism. It causes disease in plants
(little leaf of brinjal) as well as in and fruits at early stages. Whenever leaf
M
animals (pleuromorphic pneumonia in or fruit fall occurs, the organ concerned
p VM
W= man). stops producing auxin. However, it
48. (d) Mitochondria is referred as
RT promotes abscission of older, mature
Substituting the values, we get leaves and fruits.
56. (d) Pancreas consists of exocrine and
powerhouse of the cell. It contains the
12.315 X l x 32
= 16 g enzymes for cellular respiration. It
0.082 1 X 300
oxidises carbohydrate to produce ATP endocrine parts. Exocrine part secretes
:. 02 to be released = 32 - 16 = 16 g
43. (d) Orbital angular momentum
molecules in the process of aerobic alkaline pancreatic juice. This juice
respiration. contains trypsinogen, chymotrypsinogen,
49. (b) DNA fragments are negatively
= .!!__ -Jl(l +
procarboxypeptidase, lipase, amylase and
1)
57. (c) As the diploid number is 8, there

charged molecules. The reason why DNA elastase.
21t
is negatively charged is the phosphate
For /-orbital, l = 3
(PO�) group that constitutes every would be 4 pairs of homologous
:. Orbital angular momentum for /-orbital
nucleotide. chromosome pairing. This gives rise to a
h 2
= !!__ -J3(3 + 1) = -J§ During the formation of phosphodiester combination of 4 = 16 kinds of gametes.
44. (b) Anhydrous HF is a covalent

21t 1t
bond, nucleotides retain one of the two 58. (a) According to Chargaffs rule,
negative charge, while the other is lost to A + T = G + C and A = T and G = C.
compound and is strongly H-bonded.
50. (c) The important characteristic that

form ester bond to new pentose. Guanine + Cytosine
Therefore, it does not give F - ions and
hence AlF3 does not dissolve in HF. NaF 40% 40%
is an ionic compound. It contains F - ions hemichordates share with chordates is Adenine + Thymine
which combine with electron deficient pharynx with gill slits. These slits are
10%
59. (b) N2 ➔ N2H2 ➔ N2H4 ➔ 2Nlia
narrow openings in the pharynx. The 10%
AlF3 to form the soluble complex.
3NaF + AlF;i ----t Na3 [AlF6 ] position of these pharyngeal gill slits is
lateral in chordates, while dorsal in Nitrogen Dimide Hydrazine Ammonia
Boron due to its small size and higher
hemichordates. The fixation of atmospheric nitrogen to
51 . (a) In lungs, even after the most
electronegativity has greater tendency to
form complexes than Al. Hence, ammonia is given as
precipitation of AlF3 takes place when BF;i forceful expiration, some of the volume of N2 + Se- + SW + 16ATP �
air remains. This volume is termed Nitrogenase
is passed through Na3 [AlF6 ] solution.
Residual Volume (RV). Due to this, 2Nlia + H2 + 16ADP + 16Pi
Na3 [AlF6 ] + 3BF;i ----t 3Na[BF4 ] .,J,
(X)
lungs do not collapse even after the most The process in which atmospheric
45. (d) The compound which follows

+ AlF;i (s) forceful expiration. RV is about nitrogen gets converted into inorganic
52. (d) Viroids differ from viruses in

1100-1200 mL. nitrogenous (nitrate, ammonia)
Huckel's rule [(4n + 2)1t] will be aromatic compounds through microorganisms is
+
in nature. having RNA molecules without protein called biological nitrogen-fixation.
0 60. (a) Treponema pallidum pathogen is

coat. Viruses on the other hand possess
(:]
41t electrons 41t electrons
DNA or RNA with a protein coat as their
genetic material. Viruses can infect a
a cause of syphilis. It is a sexually
transmitted infection that causes infected
Does not follow Does not follow wide range of organisms including plants,
Huckel's rule
sores, blisters or ulcers on your genitals,
Huckel's rule
0 0
animals or bacteria, while viroids infect anus (bottom) or mouth.
only plants.
53. (b) Plants that produce
6 1 . (b) Given, a + b - c = l ... (i)
a2 + b2 - c2 + 1 = 0
p
pneumatophores i.e. negatively geotropic and ... (ii)
81t electrons 61t electrons
()'
a2 + b2 - (a + b - 1) 2 + 1 = 0
roots and show vivipary i.e. germination From Eqs. (i) and (ii), we get
Does not follow Follow
Huckel's rule
of seeds inside the fruits are halophytes.
Huckel's rule
WWW.JEEBOOKS.INl
⇒ a2 + b2 - a - b - 1 - 2ab + 2a 64. (d) We have, 66. (b) 1 0 cm 20 cm

2 2
+ 2b + 1 = 0 2 n worm worm
P(x) = a0 + �x + ar + . . . + anx
⇒ (a + b) - ab = 0 P(5) = a0 + 5� + 25a2 + 125a.i + • 12.5 cm 5 cm
⇒ (a - 1) (b - 1) = 1 . . . + (5t an
⇒ a - 1 = l and b - 1 = 1 ⇒ 136 = a0 + 5� + 25� + 125a.i + 7.5 cm
5 cm
⇒ a = b = 2⇒c = 3 . . . + (5t an
⇒ a - 1 = - 1 and b - 1 = - 1 ai � l for i � 4 , then RHS > 136 For 10 cm worm centre of mass is raised
⇒ a = b = 0 and c = - 1 :. a4 = £1:; = a 6 ... = an = 0 upto height of 7.5 cm, while for 20 cm
2
:. a + b + c
2 2
= (2) 2
+ (2)2 + (3)2 worm height of centre of mass is 5 cm
a0 + 5� + 25a2 + 125a.i = 136 ... (i)
from ground.
= 4 + 4 + 9 = 17 :. a.i can be O or 1 only
So, ratio of work done by 20 cm worm to
a2 + b2 + c2 = (0) 2 + (0)2 + (-1) = 1 Now, P(l) = a0 + � + a2 + a.i = 4 ... (ii)
W1 = mgh.i = � = 50 = 2 : 3
that of 10 cm worm is
:. Sum of all possible value is 18. If a.i = 0, then
62. (d) Let the number of cups with W2 mgh2 7.5 75
handle be m and number of cups without
a0 + 5� + 25a2 '.,'.; 4 + 20 + 100
handle be n.
= 124 < 136 67. (b) Let d = diameter of disc. Spot is
If a.i = l invisible, if incident rays from dot
mc2 n� = 1200 ⇒ a0 + 5� + 25a2 = 1 1 [from Eq. (i)]
n
Let � is divisible by 1200. reaching top surface at !I:_ are at the
⇒ a2 = 0 2
:. n '.,'.; 20 when n = 2 1 , then 21 � > 1200 ⇒ a0 + 5� = 1 1 critical angle.
r, = - n (n- - 1)
.'. n'--'3 (n - 2) .
- - - IS . "ble by
d"lVlSl Also from Eq. (ii), a0 + � = 3 Then by sin ic = _!
3
1200 ⇒ � = 2, a0 = 1
12
h
⇒ n "# p, p + 1, p + 2, where p prime � 7 Hence, P(x) = 1 + 2x + i3 a nd - d - = tan i
P(3) = 1 + 6 + 27 = 34
65. (b) Given, in quadrilateral ABCD
⇒ n "# 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 17, 18,
⇒
19, 20
:. Possible value of n = 3, 4, 5, 6 AB = AD = 13
When n = 4, then m = 25 ⇒ m + n = 29 BC = CD = 20 So, minimum radius of disc = 23 cm.
and n = 10, then m = 5 ⇒ m + n = 15 BD = 24
68. (c) In case A, voltage across bulb is
and n = 5, then m = 16 ⇒ m + n = 21 D 20 C higher, so lamb will burn brighter.
Maximum value of (m + n) = 29 In case B, voltage is same as either of
63. (a) Let LCI,? = 0 battery but each battery supplies only
1 3 LSJ � half of current, hence the batteries will
LBAE = x = LEAD
lasts twice as long.
69. (d) From v-t graph,
and LDAF = y = LFAC
LA = 2x + 2y 13
LA
A B
Area of MBD For 0 < t < 3 s,
⇒ x+ y = -
2 8 -1
= ,J25(25 - 13) (25 - 13) (25 - 24) a = � = 2.67 ms-2
3s
A = ,J25 X 12 X 12 X 1
For 3s < t < 5s, a = 0
= 60
For 5s < t < 9s,
Area of f..BCD
a=- -
-16 ms-1 = 4 -2
= ,J32(32 - 20) (32 - 20) (32 - 24) - - ms
4s
= ,J32 X 12 X 12 X 8 70. (a) Forces on the ball are
= 192 (i) weight of ball = mg
B "-----'-----'----�- �- ��c :.Area of quadrilateral ABCD (ii) weight of fluid column above ball
= 1tr 2pgh
E F
LB = Area of MBD + Area of f..BCD
(iii) Buoyant force = ( i 1tr3 ) pg
LAEF = LEBII + LBIIE = + 60° = 60 + 192
2
LC = 252
when mg = � 1tr3 pg - 1tr 2pgh, ball will
and LAFE = - + 0
2 Radius of incircle
tend to rise corresponding height h0 of

In MEF, Area of quadrilateral 3
LB LC LA Semiperimeter of quadrilateral
- + 600 + 0 + - + - - 1800 water in vessel is given by
2 2 2 252 = 7.63
mg = - 1tr 2pg - 1tr2pgh0
= 2
⇒ 0 = 180° - 60° - 90° ⇒0 = 30 33
:. Nearest integer of r is 8.
3
LCI,#' = 30°
WWW.JEEBOOKS.INl
2 18 KVPY Practice Set 4 Stream : SA
Substituting given values, we get Thus, the correct option is (d). 76. (c) The total amount of energy used
CH2 = CH-CH = CH2 Hz/Ni )
2
.l in forming 38 ATP is
1t X 10-3 X 10 = � X 1t X ( O ) X 1000 X 10 1, 4-addition
3 100 (A) 38 x 30.6 kJ = 1 162.8 kJ
Cif:i CH = CH- Cif:i
Thus efficiency of aerobic respiration is
- 1t (-- ) x 1000 x 10 x h0
1
2 (B) 1 1628
X 100% = 40%
100 1 03'H20/Zn 2800
1 2
⇒ - = - - ho 2CH3CHO 77. (a) Since there is both a haemophilic
100 3 and normal son, the mother must have a
⇒ h0 = (0.66 - 0.01) m = 65 cm 74. (a)ln Kjeldahl's method, percentage heterozygous genotype.
7 1 . (b) Compound X is CaCO3 of N is given by Since there is a haemophilic daughter,

1.4x normality of acid x volume of acid the X-chromosome from the father must
CaCO3 � CaO + CO2 t = have the recessive allele.
Residue weight of compound
xhy
X
Also, 1 M H2SO4= 2 N H2SO4
�
CaO + H2O ----t Ca(OH)2
Residue y [M = N x Basicity/Acidity]
XY
Ca(OH) 2 + CO2 + H2O ----t Ca(HCO3 )2
xhxh xhy xhx
1.4 x 2 x 10
Excess :. % of N = = 3 7.33 %
Haemophilic Carrier Normal
Y
Ca(HCO3 )2 � CaCO3 + H2O + CO2 t 0.75
75. (c) daughter I daughter son
72. (a) For the reaction,
X
Haemophilic
Element % of Atomic No. of Simple son
78. (c) Endocrine cells are present in

I_ X2 + � Y2 � XYa (11H = - 30 kJ) element weight moles ratio
2 2
o o
- 115<.xr: l - 1 1 Sx
ol
L -2
3 12 different parts of the gastro-intestinal
2 + - s;,.,2
11S 0 _ C 12.8 12.8/12 1.06/
3 2 J = 1 .06 1.06= 1 tract, e.g., gastrin, secretin, GIP. Atrial
= 50- 1L21 X 60 + 23 X 407
wall of our heart secretes a peptide
H 2.10 1 210 / 1 2.10/
J hormone called ANF (Atrial Natriuretic
= 2.10 1.06
Factor). Releasing and inhibitory
= 50 - [30 + 60] =2
hormones are released by hypothalamus.
= 50 - 90 = - 40 JK-1 mor1 Br 85. 1 80 85.11 80 1. 06 / Adenohypophysis is not under direct
Also, 110 = 11H0 - Tl1S0
° = 1.06 1.06= 1 control of hypothalamus.
At equilibrium, 110 ° = 0 79. (c) The amount of DNA in the 2
11H = Tl1S Hence, the empirical formula becomes somatic cells, the motor neuron and the
11Ho CH2Br skin cell should be the same.
T = -0 Empirical weight of CH2Br
11S After interphase where DNA has already
- 30 x Hf J mor1 = 12 + 2 + 80 = 94 replicated, the amount of DNA is
= = 750 K As we know that, doubled, i.e. 6.8 x 2 pg= 13.6 pg.
80. (b) The reaction that is
- 40 x JK-1 mor1
molecular -wt.
n=- - - -
empirical wt. enzyme-catalysed has lower activation
187.9 energy and is represented by the dotted
= =2
By considering the molecular formula 94 line. The energy input required to raise
C4H6 • We can conclude that, it is an Thus molecular formula the energy of the reactants to a certain
alkene, CH2 = CH-CH = CH2 which on = n x empirical formula level before the reaction is triggered is
reduction with H2 gives Cif:i CH = CH = 2 x (CH2Br) called the activation energy. This is
Cif:i . Also ozonolysis ofClI;i CH = CHCif:i represented by the increase in energy of
= C2H4 Br2
will only give 2 moles of acetaldehyde. the reactants to the top of the 'hill', B.
WWW.JEEBOOKS.INl
KVPY
PRACTICE SET 5
Stream :SA
M M : 100
Instructions
MATHEMATICS 5. The parabola y = a:2 - 2 and y = 4 - b:x? intersect the

coordinate axes in exactly four points and these four
1 . How many positive integers less than 1000 are points are the vertices of area 12, then a + b is equal to
6 times the sum of their digits?
(a) 1/2 (b) 1 (c) 3/2 (d) 2
wo �1 �2 00 3
point on the circle such that LABC = 30 ° and O lies
6. Let AB be a chord of circle with centre 0. Let C be a
2. Divya inscribed a circle inside a regular pentagon,
LDCO = LOCB = 20 °, then the measure of LCDO in

circumscribed a circle around the pentagon, and inside the MBC. Let D be a point on AB such that
calculated the area of region between the two circles.
Mansi did the same with a regular heptagon. The degree is
areas of two regions A and B respectively. Each
(a) 1 10° (b) 70° (c) 80°
7. Let a and b be natural numbers such that
(d) 20°
polygon had a side length of 2. Which of the following
(a) 7A = 5B (b) 5A = 7B
is true?
(d) 25A = 49B

2a - b, a - 2b and a + b are all distinct squares, the
(c) A = B least possible value of b is
(a) 2 1 (b) 22 (c) 24 (d) 25
3. A box contains a collection of triangular and square
tiles. There are 25 tiles in the box containing 84 edge 8. The wealth of a person A equals the sum of that of B
and C in the ratio 2 : 1, then the wealth of B equals

total. The number of square tiles in the box are and C. Ifhe distributes half of his wealth between B
(a) 5 (b) 7 (c) 9 (d) 1 1
the sum of that A and C. Then, the fraction of wealth
by /(1) = 2, f(n) = f(n - 1) + 2 if n is even, and
4 . Define a function on the positive integers recursively that A should distribute between B and C in the ratio
1 : 2, so that the wealth of C equals the sum of that of
Then, f(2019) is equal to
f (n) = f(n - 2) + 2 if n is odd and greater than one. A and B is
1 2 3
(a) 2019 (b) 2020 (c) 2021 (d) 2018 (a) - (b) - (c) - (d) 1
2 3 4
WWW.JEEBOOKS.INl
9. For some positive integer K, the repeating base-K (c) melting point of solid
(d) triple point of phase equilibrium
17. In the cyclic process, process A ➔ B is isothermal.
representation of the (base-ten) fraction 2 is
0.23K = 0232323 ... K, then the value of K is

51
p
(a) 13 (b) 14 (c) 15 (d) 16
10. The number 1, 2, 3, ... , 9 are randomly placed into the
9 square of a 3 x 3 grid. Each square gets one number
and each of the numbers is used once. What is the
probability that the sum of the numbers in each row --+ - - - - ---> V
Correct V-T graph for the cycle is
and each column is odd?
(a) -1 (b) -1 (c)-5 (d) _! ( b) V
21 14 63 21 ( a) V
11. A quadrilateral is inscribed in a circle of radius
200-v'2. Three sides of this quadrilateral have length
200, then length of the fourth side is
(a) 200 (b) 20°'1'2 (c) 400 (d) 500 --+ - - - - ----> T --+- - - - ----> T
12. Let T he the smallest positive integer which, when
divided by 1 1, 13, 15 leaves remainder in the sets
squares of the digit of T is

(c) V
{7, 8, 9}, {(1,2,3}, {4, 5, 6} respectively. The sum of
(a) 50 (b) 81 (c) 89 (d) 90

13. If roots of equation :x? - bx + c = 0 be two consecutive
--+ - - - - - -➔ T --+ - - - - -➔ T
integers, then b2 - 4c equals
(a) -2 (b) 3 (c) 2 (d) 1 18. Consider the following nuclei:
3 14
2 He , 7 N ' 92
u23s
14. How many different words can be formed by jumbling
1 H ' 6 c1 ' 92
the letters in the word MISSISSIPPI in which no two 3 13 u235
'S' are together Choose the correct statements given below.
(a) 3. 6 C4 .1 C4 (b) 6- 7 8 C4
I. 2 He3 and 1 H3 are isotopes.
6
(c) 7. C4 .s C4 (d) 6- 8-7 C4
II. 92 U235 and 92 U238 are isobars.
15. A man standing on a railway platform noticed that a
train took 21 s to cross the platform which is 88 m III. 6 Cl13 and 7 N14 are isotones.
long and that it took 9 s to pass him. Assuming that (a) All statements are correct
the train was moving with uniform speed. What is (b) Both statements I and II are correct
the length of the train in meters? (c) Both statements II and III are correct
(a) 55 (b) 60 (c) 66 (d) 72 (d) Only statement III is correct
19. Consider two identical copper spheres A and B. One
PHYSICS is placed over a thermally insulating plate,while the
16. p- T curve representing phase equilibrium is given by; other hangs from an insulating thread.
p
--+-""""-----➔ T Equal amounts of heat are given to the two spheres

and temperatures are recorded, then
The point Pi is (a) TA = TB (b) TB < TA
(a) boiling point of liquid (c) TB > TA (d) cannot be concluded
(b) condensation point of vapour
WWW.JEEBOOKS.INl
20. A boy throws a stone to hit a pole at some distance. 25. Given, A = Boltzmann constant, B = Planck's constant
Kinetic energy K of stone varies with horizontal and C = speed of light.
displacement x as shown in figures given below. Then, quantity with dimensions of A4F3 2 is c-
(b) K
( a) K (a) universal gas constant
(b) specific heat capacity
(c) Stefan's constant
(d) heat energy
26. Considering air resistance, if 4 = time for a thrown
K K ball in upward journey and t2 = time taken for
(c) (d) downward journey, then
(a) t1 = t2 (b) ti > t2
(c) t2 > ti (d) 3 t2 = 2 t1
-+- - - - -� x --+ - - - ------> X 27. A car accelerates from rest at a constant rate a for
sometime after which it deaccelerates at a constant
21 . Ratio of time periods of small oscillations of the rate � to come to rest.
(�) t
insulated spring and mass system (shown) before and If total time is t, then maximum speed of car is
after charging the mass is 2 2 2 2
a +� )
(b) ( � ) t (c) ( - t (d) ( )t
a -�
(a)
� a+� a� a� a�
(a) equal to one (b) greater than one
(c) less than one (d) greater than or equal to one
28. A lawn roller of mass 10 kg, radius 1 m is pulled
horizontally by a handle attached to axle of the
22. The lights on a car are inadvertently left on. They roller.
dissipate 95 W.
Fully charged 12 V car battery is rated 150 Ah. Time
after which the car lights go OFF due to battery run
down is
(a) 12 h (b) 24 h (c) 18 h (d) 36 h Necessary minimum pull to raise roller above a step
23. In the arrangement shown below. of 0.4 m is
(a) 128 N (b) 134 N
(c) 2 13 N (d) 112 N
29. Geodesic is a
(a) straight line
(b) curve
(c) circle
(d) may be a straight line or curve
30. In given combination of lenses, a parallel beam is
Accelerations of masses A and B just after cutting the
made incident from left as shown below.
string C are
(a) 0, g (b) g, g (c) f g (d) 2g, g
24. For streamlined flow of water, consider the following

statements. 0.75 m
I. Two streamlines does not cross each other. Emerging light rays are as shown by
( a) ---- ( b) � (c) � (d) --
II. Streamlines are straight.
III. Streamlined flow is more likely for fluids with � ----
CHEMISTRY
low density and high viscosity.
IV. Streamlined flow is more likely for liquids with
high density and low viscosity.
Which of the above statements are correct? 3 1 . Haemoglobin contains 0.33% of iron by weight. The
(a) Statements I and III are correct molecular weight of haemoglobin is approximately
(b) Statements II, III and IV are correct 67200. The number of iron atoms (at. wt. of Fe is 56)
(c) Statements III and IV are correct present in one molecule of haemoglobin is closest to
(d) Statements I, III and IV are correct Wl �6 �4 �2
WWW.JEEBOOKS.INl
32. Which of the following statements is incorrect? 42. Sodium peroxide which is a yellow solid, when
(a) Angular quantum number signifies the shape of the exposed to air becomes white due to the formation of
orbital (a) H2 02 (b) Na 20
(b) Energies of stationary states in hydrogen like atoms is (c) Na20 and 03 (d) NaOH and Na2C03
inversely proportional to the square of the principle
quantum number 43. The products formed when the following compound is
(c) Total number of nodes for 3s-orbital is three treated with Br2 in the presence of FeBr3 are
(d) The radius of first orbit of He+ is half that of the first
orbit of hydrogen atom
33. The solubility of saturated solution of calcium
fluoride is 2 x 10-4 mol 1 -1 . Its solubility product is
closest to �CHa
(a) 12 x 10-2 M 3 (b) 14 x 10-4 M 3
11
(c) 22 x 10- M 3
(d) 32 X 10-12 M 3
34. The brown ring complex compound is formulated as
[Fe(HP)s(NO ) ] S0 4 . The oxidation state of iron is (a) and
Wl �2 �3 00 0
35. Which one of the following has the maximum dipole Br
moment?
(a) CO2 (b) CH 4 (c) NH 3 (d) NF3 CH3 CH3
©('
36. Which of the following is a chiral? B
(a) 1,1-dibromo-1-chloropropane
(b) 1, 1 - dibromo -3-chloropropane
(b) �
0 and
(c) 1, 3-dibromo-1-chloropropane CH3 CH3
(d) 1, 3-dibromo-2-chloropropane CH3 CH3
37. The correct order of acidic character of the following B
compounds is �
I. phenol, II. o-cresol (c) and
III. p-nitrophenol IV. p-chlorophenol CH3 �CHa
(a) I > II > III > IV (b) III > IV > I > II Br
(c) IV > III > II > I (d) III > II > IV > I
38. Which of the following is the correct order of size of
the given species?
(a) I > 1- > 1+ (b) I+ > l- > I
(d)
(c) I > 1+ > i- (d) 1- > I > 1+
39. Which of the following is the correct representation of
Gay-Lussac's law?
44. How many enantiomeric pairs are obtained by
(a) p ) p
monochlorination of 2, 3 -dimethyl butane ?
� � W4 �2 �3 00 1
� 45. If bond enthalpies of Cl-Cl bond, H-H bond and
1/V V
H-Cl bond are 243 , 43 5 and 4 3 1 kJ mol -1
respectively, then calculate the t-,. H 0 in kJ mo1 -1
(c) p (d) p
1
of HCl.
� � (a) - 184 (b) - 92 (c) 170 (d) - 88
BIOLOGY
1/T T
40. A compound that gives a positive iodoform test is

(a) pentanol (b) pentan-3-one
(c) pentan-2-one (d) pentanal 46. Which of the following components provides sticky
character to the bacterial cell?
41 . Which of the following compounds of xenon has (a) Cell wall (b) Nuclear membrane
pyramidal geometry? (c) Plasma membrane (d) Glycocalyx
(a) XeOF4 (b) XeF2 (c) Xe03 (d) XeF4
WWW.JEEBOOKS.INl
47. Life cycle of Ectocarpus and Fucus respectively are of animal cells. If APC is defective in a human cell,
(a) haplontic, diplontic which of the following is expected to occur?
(b) diplontic, haplodiplontic (a) Chromosomes will not condense
(c) haplodiplontic, diplontic (b) Chromosomes will be fragmented
(d) haplodiplontic, haplontic (c) Chromosomes will not segregate
48. Which of the following are not polymeric? (d) Recombination of chromosome arms will occur
(a) Nucleic acid (b) Proteins 55. Zygotic meiosis is a characteristic of
(c) Polysaccharides (d) Lipids (a) Marchantia (b) Fucus
49. In case of poriferans, the spongocoel is lined with (c) Funaria (d) Chlamydomonas
flagellated cells called 56. Which one of the following generally acts as an
(a) ostia (b) oscula antagonist to gibberellins?
(c) choanocytes (d) mesenchymal cells (a) Zeatin (b) Ethylene
50. A decrease in blood pressure/volume will not cause (c) ABA (d) IAA
the release of 57. The ornithine cycle removes two waste products from
(a) renin (b) atrial natriuretic factor the blood in liver. These products are
(c) aldosterone (d) ADH (a) CO2 and urea (b) ammonia and urea
5 1 . The vascular cambium normally gives rise to (c) CO2 and ammonia (d) ammonia and uric acid
(a) phelloderm (b) primary phloem 58. Phellogen and phellem respectively denote
(c) secondary xylem (d) periderm
(a) cork and cork cambium
52. Which of the following options best represents (b) cork cambium and cork
enzyme composition of pancreatic juice? (c) secondary cortex and cork
(a) Amylase, peptidase, trypsinogen, renin (d) cork and secondary cortex
(b) Amylase, pepsin, trypsinogen, maltase
(c) Peptidase, amylase, pepsin, renin 59. Which one of the following enzymes shows the
greatest substrate specificity?
(d) Lipase, amylase, trypsinogen, procarboxypeptidase
(a) Lipase (b) Nuclease
53. Which of the following are found in extreme saline (c) Pepsin (d) Sucrose
conditions?
(a) Archaebacteria (b) Eubacteria
60. Albinism in humans is controlled by a recessive
allele. How many copies of this allele will be found at
(c) Cyanobacteria (d) Mycobacteria
one of the poles of a cell at telophase-I of meiosis in
54. Anaphase Promoting Complex (APC) is a protein an albino person?
degradation machinery necessary for proper mitosis (a) 23 (b) 4 (c) 2 (d) 1

MATHEMATICS 64. If MBC is a right angle triangle with LACE as its
right angle. The measure of LABC = 60° and AB = 10.
6 1 . A positive integer K is said to be good if there exists a Let P be randomly chosen inside ABC, and extend BP
partition of {1, 2, 3, . . . , 20} in to disjoint proper subsets to meet AC at D. Then, the probability that BD > 5-J2
the partition is K. Then good number are there
such that the sum of the numbers in each subset of lS
1
(a) -
2- -/2 (c) 3 -
,,/3 5-
W5 �6 �7 00 4 2
(b)
2 3
(d)
5
-/5
62. Let C1 and C2 be circles defined by (x - 10)2 + y2 = 36 65. Let P(x) = (x - 1) (x - 2) (x - 3). For how many
and (x + 15)2 + y2 = 81 respectively. The length of the polynomials Q(x) does there exist a polynomial R(x) of
to C2 at Q is
shortest line segment PQ that is tangent C1 at P and degree 3 such that P(Q(x)) = P(x) · R(x)?
(a) 22 (b) 24 (c) 27 (d) 32
63. Suppose that a and b are digits, not both nine and PHYSICS
(a) 15 (b) 18 (c) 20 (d) 24
not both zero, and the repeating decimal 0. ab is

expressed as a fraction in lowest terms. Then, the 66. Two stones are thrown up simultaneously from the
different denominators are possible, are edge of a cliff 200 m high with initial speeds 15 ms -l
W3 �4 �6 00 5 and 30 ms-1 .
WWW.JEEBOOKS.INl
Correct graph of time variation of the relative 70. A calorimeter contains some ice and 10 kg water.
position of the second stone with respect to first is This calorimeter is heated over a slow burner which
( b) provides heat at a constant rate.
(a) E Temperature of calorimeter and its contents varies
>f with time as shown below.
(\J
2$.. T(OC)
t(s) -- --
-- 8�� t(s) 1 0 -------------------------------
8 10 + 10
-----)
0 1-- - - -c-,----------+-----------►
(c) (d)
E E -+ - - ---' - ---' - -----) t( min)
- 5 50 60
>f
(\J
2$.. Amount of ice initially present is nearly
t(s)
(a) 17 kg (b) 14 kg (c) 10 kg (d) 5 kg
t(s)
CHEMISTRY
8 10 --
-----¥-- 8��1�
0➔
mirror by u-v method, a student prepares following

67. In an experiment of finding focal length of a concave
graph of u versus v graph. 7 1 . The heat liberated from the combustion of 0.5 g of
carbon raised the temperature of 2000 g of water
y
from 24°C to 26°C. The heat of combustion of
( -2 2.5,0) carbon (per mole) is
u(cm) (-45,0) ( - 30,0) (a) -4 kcal (b) -8 kcal
X (c) -62 kcal (d) -96 kcal
(0, - 22.25) 72. An organic compound of molecular formula C 4H6 "
(0, - 30) A forms precipitates with ammoniacal silver nitrate
and ammoniacal cuprous chloride. A is an isomer B,
(0, -45) one mole of which reacts with one mole of Br2to form
1, 4-dibromobut-2-ene. A and B are
(a) CH 3 CH 2 C = CH and CH 2 = CHCH = CH 2
(b) CH 3 C == CCH 3 and CH 3CH = C = CH 2
v(cm) CH2 "'- CH2 - CH

Focal length of mirror is nearly
(c) I /C
=CH2 and I II
CH2 CH2 - CH
(a) - 45 cm (b) - 30 cm (c) - 2225 cm(d) - 15 cm
68. In given circuit, bulb that glows with maximum / CH "'-
intensity is and CH2 I CH2
"'- CH
/
2Q 4Q
73. A gas bulb of 1 mL capacity contains 2.0 x 102 1

molecules of nitrogen exerting a pressure of 7.57 x 103
Nm-2 . The root mean square speed of the gas
molecules is
(a) 274 ms-1 (b) 494 ms-1
+ - (c) 690 ms- 1
(d) 988 ms-1
20 V
74. Which of the following statements is not correct from
(a) 4Q bulb (b) 2Q bulb
the view point of molecular orbital theory?
(c) 3Q bulb (d) 6Q bulb
(a) Be2 is not a stable molecule
69. For a linear oscillator, potential energy as a function (b) He2 is not stable, but He; is expected to exist
k
of its displacement x is (c) Bond strength of N 2 is maximum amongst the
U(x) = :<
homonuclear diatomic molecule belonging to the
2 second period
where, k = spring constant = 0.5 Nm-1 . (d) The order of energies of molecular orbitals in N 2
= 1t2py ) < (1t* 2px = 1t* 2py )

molecule is
cr2s.< cr * 2s < cr2pz (1t2px
If total energy of the particle is 1 J, then maximum
amplitude of oscillation of particle is < O" 2pz
(a) 1 m (b) 2 m (c) 3 m (d) 1.5 m
WWW.JEEBOOKS.INl
75. The atomicity of a molecule, M, if 10 g of it combine The most likely explanation of the fact that the graph
with 0.8 g of oxygen to form an oxide is closest to levels off at 180 Jm-2 s-1 is that the system is
[specific heat of molecule, M is 0.033 cal deg-1 g-1 and (a) light limited and carbon dioxide saturated
molecular mass of molecule is 199.87 g] (b) light limited and the temperature is below optimum
Wl �2 �3 00 8 (c) light saturated and carbon dioxide is unlimited
BIOLOGY
(d) light saturated and the temperature is above optimum
78. Certain drug acts at synapses and affects the action
of neurotransmitter substances. The table shows the
76. The following statements describe the structure of effects of four different drugs.
certain protein molecule.
Drug Effect
(I) The molecule consists of two polypeptide chains
which are folded around each other. I. Inhibits the enzyme cholinesterase.
(II) In each chain the amino acids are held in a II. Prevents the release of acetylcholine.
helix by hydrogen bonds. III. Competes with acetylcholine at receptor sites.
Which orders of structure are described by these IV. Inhibits the enzyme which destroys
Statement (I) Statement (II)

statements? nor-adrenaline.
Which two drugs would prevent a skeletal
(a) Primary Tertiary muscle from responding to an electrical
(b) Secondary Tertiary stimulus in the presynaptic neuron?
(c) Tertiary Secondary W I �d ll � I �d N
(d) Quaternary Secondary (c) ll and III (d) ll and N
77. The graph shows the relationship between oxygen 79. The diagram shows some chromosomes at late
production in photosynthesis and light intensity prophase of mitosis.
for a unicellular green organism in 0.02% sodium
hydrogencarbonate solution
Oxygen production/mm3h -1
7
5
How many chromosomes would be present in one
4 nucleus at telophase-II of meiosis?
3 (a) 6 (b) 12
(c) 18 (d) 24
2
1
80. Pyrimidine bases contain four carbon atoms and
purine bases contain 5.
60 80 100 120 140 160 180 200 How many carbon atoms are there in a nucleotide
-1 Light intensity/Jm- 2 s -1 containing cytosine?
- 2
(a) 8 (b) 9 (c) 10 (d) 1 1
Answers
PART-/
(b) 2 (c) 3 (c) 4 (b) 5 (c) 6 (c) 7 (a) 8 (d) 9 (d) 10 (b)
11 (d) 12 (b) 13 (d) 14 (c) 15 (c) 16 (d) 17 (a) 18 (d) 19 (c) 20 (c)
21 (a) 22 (c) 23 (d) 24 (a) 25 (c) 26 (c) 27 (a) 28 (b) 29 (d) 30 (b)
31 (c) 32 (c) 33 (d) 34 (a) 35 (c) 36 (c) 37 (b) 38 (d) 39 (d) 40 (c)
41 (c) 42 (d) 43 (c) 44 (d) 45 (b) 46 (d) 47 (c) 48 (d) 49 (c) 50 (d)
51 (c) 52 (d) 53 (a) 54 (c) 55 (d) 56 (c) 57 (b) 58 (b) 59 (d) 60 (c)
PART-I/
61 (b) 62 (c) 63 (d) 64 (c) 65 (a) 66 (d) 67 (d) 68 (a) 69 (b) 70 (a)
71 (d) 72 (a) 73 (b) 74 (d) 75 (a) 76 (d) 77 (d) 78 (c) 79 (a) 80 (b)
M/WW.JEEBOOKS.IN]
Solutions
1. (b) Number less than 1000 can write 3. (c) Let the number of triangular tiles C
where a, b, c E {O, 1, 2, 3, ... , 9} and

abc = 100a + 10b + c =X
and the number of square tiles = y
a + b + c> 0 A triangle has three edges and square
The sum of digits of this number is has four edges.
(a + b + c). X + y = 25 ... (i)
Given, 100a + 10b + c = 6(a + b + c) and 3x + 4y = 84 ... (ii)
94a + 4b - 5c = 0 On solving Eqs. (i) and (ii), we get
X = 16, y = 9
a = 0 then 4b = 5c OA = OC
Clearly, a > 0. No solution
dOAC is an equilateral
Hence, number of square tiles in box is 9. Now,
4. (b) We have, / (1) = 2
LCAO = LAGO = 60°
This is possible only
LACD = 60° - 20° = 40°

b = 5 and c = 4 ⇒
Hence, only one number i.e., 54.

and /(n) = f(n - 2) + 2, n is odd
OC = OB
:. Number is 54. ⇒
/(3) = /(1) + 2 = 2 + 2 = 4
2. (c) In ,�.OPB, /(5) = /(3) + 2 = 4 + 2 = 6
LOBC = LOCB = 20°
:. Similarly, / (2019) = 2020 LOBA = 10° = LOAB
5. (c) We have, LDAC = 70°
cos � = !_ ⇒ r = R cos � ⇒
5 R 5
LCDA = 70°
⇒
LCDA = LCAD = 70°

Equation of parabola In MCD,
CD = CA = CO
y = ax2 - 2 . . . (i) ⇒
y = 4 - bx2
In dCDO, CD = CO and LDCO = 20°
and . . . (ii) ⇒
y
LCDO = 1so - 20 = soo
o 0
⇒
2
7. (a) We have,
B 2a - b, a - 2b and a + b are squares.
Area of region = 1t (R2 - r 2) :. Let 2a - b = x2 ... (i)
= 1tR2 (1 - cos2 i) a - 2b = y
a + b = z2
2
... (ii)
i(
and ... (iii)
= 1t cosec2 1 - cos2 i) A ( 0, -2)
where x, y, Z E N
From Eqs. (ii) and (iii), we get
5 - RJ
Y'
1· · s1·n 17
x intercept are ± , II ,------------;-
1t - 2a - b = y2 + z2
L. On solving Eqs. (i) and (ii), we get
i - i)
x2 = Y2 + z2 ... (iv)
n
= 1t (cosec 2
cot 2
= 1t V ,1 a + b From Eqs. (i) and (iii), we get
3a = x2 + z2
Similarly in heptagon, i.e. coordinate of points x2 + z2 is multiple of 3 ⇒ x and z is also
multiple of 3.
A (0, - 2), B u
a! b , 0} C(0, 4) From Eqs. (ii) and (iii), we get
and D = - ✓ 6
z - y is a multiple of 3 ⇒ y and z is also
2 2
3b = z2 - y2 ••• (v)
a+ b
Area of kite ABCD = __! AC x BD
multiple of 3.
Let X = 3xi , Y = 3yl , Z = 3-zi ⇒ .xi2 = Ji + Z{
Let us assume every two of x, y, z are
2
⇒ 12 = _! 6 X 2 ✓
6
⇒
6 ✓=2
7 7
2 a+ b a+ b coprime.
· = 1t cosec 1t ( 1 - cos2 1t )
Area of reg10n 2
6_ ⇒ Xi_ , y1 , zi are pythagorean triplet.
⇒ _ =4
a+b ⇒ Out of y1 and zi , one even � 4 and other
= 1t ( cosec 1t 2
- cos 2 1t
odd � 3.
7 7) ⇒ a + b = _§ = � From Eq. (v), we get
6. (c) Given, LABC = 30°
4 2
= 1t
b = 3(z; - l) = 3(zi + Y1 ) (zi - Y1 )
A=B LAOC = 2 LABC = 60°
:. Both have same area.
⇒ min b = 3(4 + 3) (4 - 3) = 2 1
WWW.JEEBOOKS.INl
8. (d) Let the wealth of A, B and C are each even be with another even in each 14. (c) We have, MISSISSIPPI
x, y and z respectively. row or column. There are 9 ways to this. Other than S, seven letters, M, I, I, I,P, P,
Given, A=B+ C They are 5! ways to permute odd and 4! I can be arranged in
X= y+ Z
ways to permute even number. 7!
� = 7x 5 x 3
A distributes half of his wealth to B and C 1 1ty = - 5! ---
:. Required prob ab'l'
x 4! x 9 1 4! 2!
9! 14
11. (d) Given,
in the ratio 2 : 1.
i (�)
Now, 4 S can be placed in 8 spaces,
AB = BC = CD = 200
Wealth ofB = y + i (� ) and C = z + i.e. 8 C4 •
OA = OB = OC = OD = 200v'2
:. Total number of arrangement
B=A + C
LAOB = LBOC = LCOD
Now, = 7- 5 · 3 - 8 C4
y+ + z+ ⇒ y-z=
3 2 6 3
X X X X = 7 X 15 X 8C4
=
= 7 x 6C4 X 8C4
Let 'a' be the fraction that A should 15. (c) Let the length of train is x m.
distribute and the ratio of distribution is
1 : 2. Length of train and platform = (x + 88) m
1 2 Time taken by train to cross the platform
-<- = 21s
3 3
Now, A = (l - a) x Speed =
x + 88
... (i)
B=y+ ax 21
2ax
3 Time taken by train to cross the man = 9 s
C z+ - In dOAB and MBE, Speed = � ... (ii)
LBAE = LAOB
=
9
2ax = y + -
3
z+ - + (1 - a) x LABO = LABE
ax
dOAB - dABE
3 3 X + SS
3z + ax = 3y + 3x - 3ax
= � ⇒ 12x = 88 X 9
OA AB OB
⇒ 21 9
⇒ 4ax = 3(y - z) + 3x AB BE AE ⇒ x =
88 x 9
= 66 m
[·: y - z = �] AB = AE [·: OA = OB]
12
⇒ 4ax = 3 ( � ) + 3x
Similarly in dOCD and WFE,
1 6. (d) Point Pi is called triple point,
4ax = 4x ⇒ a = l CD = DF
where fusion curve vaporisation curve
⇒
9. (d) We can expand the fraction
OE = 100v'2 = OB
and sublimation curve meets.
17. (a) Process AB is isothermal
0. 23K as follows
0. 23K = 2 - K-1 + 3 - K-2 + 2 - K-3 BC
2 expansion, so
EF =
+ 3 · K-4 + . . .
and = 100
= 2(K- + K-3 + K- + ... ) + 3(K-2 + K-4

2
1 5 AD = AE + EF + FD
+ K-6 + . . . ) = 200 + 100 + 200 = 500
12. (b) T = {4, 5, 6} (mod 15)
or T = {19, 20, 2 1}, {34, 35, 36}, {49, 50, 5 1}, Process BC is isobaric, so
= ; (1 + + ;4 + " ' )
2 (1 + __!__ + __
;
2
;J ��:
4 + . . .)
l
K2 K2 K
+ {64, 65, 66}
l[
{79, 80, 81}, {94, 95, 96}, {109, 1 10, 1 1 1},
{124, 125, 126}
- (! :,
1
+ {139, 140, 141}, {154, 155, 156},
1- {169, 170, 171}, {184, 185, 186} (mod15)
18. (d) Number of neutrons,
N=A - Z
- 7 Now, by direct checking we get smallest
Given, 0. 23K = -
51 T = 184
13
2K + 3 7 For 6 Cl , N = 13 - 6 = 7
K2 - 1 5 1
:. Required sum = 12 + 82 + 42 = 81
13. (d) We have,
and 7 N14 , N = 14 - 7 = 7
x - bx + c = 0
⇒ 7K2 - 102K - 160 = 0 2 So, they contains same number of
neutrons.
⇒ 7K2 - 1 12K + lOK - 160 = 0 Let a, � are the roots of the equations.
19. (c) Part of heat given to A is used up
a + � = b, a� = c
K = 16, K ;t -l0
⇒ (7K + 10) (K - 16) = 0
in doing work (against) gravitational force.
⇒ Given, a-�=1 So, temperature of B will be slightly higher.
20. (c) Kinetic energy of stone decreases
(a + �)2 - (a - W = 4a�
7
1 0. (b) Sum odd only be formed b2 - 1 = 4c then increases. It is never zero in entire
(even, even, odd) or (odd, odd, odd). So can ⇒ 2
b - 4c = l flight of stone.
focus on placing evens, we need to have
WWW.JEEBOOKS.INl
2 1 . (a) In absence of charge, time period If surface over which points are located is 35. (c) CO2 and CH4 have zero dipole
a plane, then Geodesic is a straight line. moment as these are symmetrical in
Tl = 21t�
On the surface of a planet, Geodesic is a nature. Between NH3 and NF3 , NH3 has
great circle joining two points. greater dipole moment though in both
30. (b) Image of first lens is formed at
In presence of charge, time period NH3 and NF3 , N possesses one lone pair
= 2 1t� of electrons.
T2 focal point of second lens.
This is because in case of NH3 , the net
So, ratio of time period is equal to one. N-H bond dipole is in the same direction
22. (c) Total output energy of battery as the direction of dipole of lone pair but
in case of NF3 , the direction of net bond
= V (It) = 12 V x 150 Ah
= 12 X 150 X 3600 J
dipole moment of three N-F is opposite
to that of the dipole moment of the lone
--
So, emerging rays are parallel.
31 . (c) 100 g of haemoglobin contains
= 6.48 X 106 J pair which cancel out the resultant dipole.
Energy consumed by car lights in time t H
= 95t
= 0.33 g Fe
:. 67200 g of haemoglobin contains
It
Equating both values, we get H ? n� H
0.33 X 67200 O=C=O
6.48 x 106 g Fe
t= = 18. 9 h 100 H
95
= 221.76g Fe
23. (d) When string C is cut, spring :. Number of Fe atom present in one
snaps back to regain its unstretched 221.76
molecule of haemoglobin = =4
length. So, spring force on m remains 56
32. (c) (a) Angular quantum number, l
same. Hence, accelerations of m and 2m
are 2g and g, respectively.
24. (a) Streamlines may be straight or
signifies the shape of the orbital. e.g.
µ net µ net
When l = 0, the shape of orbital is = 4.90 x 10·30cm = 0.80 x 10-3o cm
36. (c) A molecule is set to be chiral, if
curved. spherical.
In fluids, with low viscosity streamlined When l = ], the shape of orbital is
all the four groups attached to central
25. (c) [A 4B-3 C2]

flow occurs only at low flow speed. dumb-bell.
carbon atom are different.
Thus, statement (a) is correct.
Br
2 2 1 2 1 1 2
= [ML r K- ]4 . [ML r r3 . [Lr r
(a) H3C-CH;r-C-Cl
(b) According to Bohr's theory 3 2 11
z
= [M4 - 3 L8 - 6 - 2 T-s + s + 2 K-4 ] For hydrogen like atom
r 2l I
= [ML0r3 K-4 ] En = - 13.6 � eV Br
ln J
= Stefan's constant.
26. (c) Time for downward journey is
1, 1-dibromo-1-chloropropane
Thus, statement (b) is correct. It is an achiral molecule.
higher as ball can be thrown with any (c) Total number of nodes in orbital
Br
velocity but its downward velocity is = n - l- 1
3 I1 2
always less than or equal to terminal For 3 s-orbital, n = 3, l = 0 (b) Cl- CH2-CH2-CH
velocity. Number of nodes = 3 - 0 - 1= 2 I
27. (a) Let car accelerates for time ti Thus, statement (c) is incorrect. Br
and then it deaccelerates for time t2•
Then, ati - �t2 = 0 and t = ti + t2
(d) According to Bohr's radius 1, 1-dibromo-3 chloropropane
r = __
o
a n 2 It is an achiral carbon.
v = ati = (� ) t .I
Br
Maximum speed, 2 2 3 2 1
a+ � ao (1) ao (1)
rHe + = -- , rH - (c) BrCH -CH -CH
28. (b) Taking moments about point of
- 2 2
2 1 I
contact 0.
Thus, statement (d) is correct. Cl
33. (d) Let the solubility of CaF2 be S. 1, 3 -dibromo-1-chloropropane
G�
o_
For the reaction, It is a chiral molecule with chiral carbon
2S
2+ position at 1(*).
CaF2 � Ca (aq) + 2F- (aq)
S Cl Br
3
2 2 2
K,,p = [Ca + ] [F -] = (S) (2S) = 4S 3 21 1 1
H2 C-C-CH2
�
F x 0.6 = 100 x 0.8 2 (d)
Ksp = 4 (2 X 10- ) =32 x 10- M3
4 3 1
34. (a) Let, the oxidation state of Fe in
I I
⇒ F = lOO x 0.3 = 133.3 N "" 134 N Br Cl
0. 6 [Fe(H 2O)5 (NO)] SO4 be x .
1, 3-dibromo-2-chloropropane
29. (d) Shortest distance between two x + 5(0) + 1= + 2
It is an achiral molecule.
points is called Geodesic. ⇒ x= + l
WWW.JEEBOOKS.INl
37. (b) When an electron withdrawing As it contains -C CH3 group. Due to the presence of chiral centre (*), it
group, like N02, Cl is attached to the II shows the optical activity and its mirror
phenol ring, it stabilises the negative image are non-superimposable.
Thus, it will sho� positive iodoform test.
charge on the oxygen of the phenoxide Hence, it shows one enantiomeric pair.
45. (b) H2 (g) + Cl 2 (g) ------t 2HCl(g)
ion. Due to this reason, acidic character (d) CH 3 CH 2 CH 2 CH 2 CHO
t.H = [(BE)H H + (BE)c,.ci l - 2 [(BE)Hci ]

of phenol increases. Between compound (Pentanal)
41 . (c) The structures of given species = [435 + 243] - 2 [43 1] =

It gives negative iodoform test.
- 184kJ moi-1
III and IV, III is more acidic as N02 is
-
more stronger EWG than Cl.
0 F
But when an electron donating group, are shown below: The moles of HCl(g) are formed from its
F "- II / F _."- I
t.r H O( HCI) = - 184 = - 92 kJ moi-1
like CH3 is attached to the phenol ring, it element, hence
Xe ,..Xe-:
F / � "- F
destabilises the ring and hence acidic
.,., I
F
character of phenol decreases. Thus, the 2
46. (d) Glycocalyx is the outermost
correct order of acidic character is
OH OH OH OH XeOF4
XeF2 mucilage layer of the cell envelope. It gives
Square pyramidal
Linear
(sp3d2)
(sp3d2)
� �{� � CHa sticky character to the bacterial cell.
47. (c) Ectocarpus and Fucus
F
!�·£71 F
> >
G diplontic life cycle. In Ectocarpus, sporic
Xe
respectively show haplodiplontic and
N02 Cl
0� 1 1 � 0 F Lec-'.'.':. f)" _'::-,J F meiosis occurs and haploid biflagellate
III IV II meiozoospores are formed. They
XeF4
38. (d) Anion is formed by the gain of Square planar
Xe0 3 germinate to produce gametophytic
Pyramidal (sp3d2) thalli. The gametophytes liberate
electron to the neutral atom and cation is
(sp 3) gametes which fuse to form diploid zygote
42. (d) Sodium peroxide which is a
formed after the loss of electron from the
In Fucus, there is a single somatic
which gives rise to a diploid plant.
neutral atom. Hence, cation has smaller
size due to increased nuclear charge yellow solid, reacts with moisture and
CO2 of air (when exposed to air) and phase. It is diploid and produces haploid
whereas anion has bigger size than its
becomes white due to the formation of gametes. They fuse during fertilisation to
neutral atom.
48. (d) Among the given options, except

NaOH and Na2 C03 • give rise to diploid individual.
Thus, the correct order of size is I- > I>i+ .
39. (d) According to Gay Lussac's law, at
2Na2 02 + H2 0 ------t 4NaOH + 02
2NaOH + CO2 -----t Na2 C03 + H 2 0 lipids all are polymers. These are formed
43. (c) As CH3 group is ortho-para

constant volume, the pressure of given by the polymerisation of monomers. The
mass of the gas is directly proportional to basic unit of lipid are fatty acids and
its absolute temperature, i.e. directing, so the major products will be glycerol molecules that do not form
p oc T or p = kT formed at o and p-position only. repetitive chains. Instead they form
CH 3 triglycerides from 3 fatty acids and one
Thus, the correct representation is given CH 3 glycerol molecules. Protein monomers are
in option (d).
� Br2/FeBr3 Br' amino acids and they bond together in
� Electrophilic Q repetitive chains just as carbohydrate
CH s substitution
49. (c) The body wall of a common
©l monomers are monosaccharides.
CH3
+
p� sponge consists of three layers i.e.
1 Br2/FeBr3
40. (c) Positive iodoform test are given
pinacoderm, choanoderm and mesophyll
layers. Choanoderm is inner cellular
by those carbonyl compounds which layer which consists of highly specialised
contain CH 3 -C group. flagellated cells called choanocytes. The
II � CH 3 beating of their flagella creates water
50. (d) A decrease in blood

0 Br current.
(a) CH 3 CH 2 CH 2 CH 2 CH 2 0H
(Pentanol) Not possible due pressure/volume stimulates the
to steric Hindrance
It gives negative iodoform test. hypothalamus to release ADH
44. (d) CH 3 - ?H - ?H -CH 3 + Cl2

Thus, the correct option is (c). (Antidiuretic Hormone) as well as JGA
(b) H 3 C-CH 2 -C-CH2 -CH 3
cells to release renin. Renin by renin
II angiotensin mechanism activates the
0
(Pentan-3-one) CH3 CH3 adrenal cortex to release aldosterone.
2, 3- dimethyl butane ANF (Atrial Natriuretic factor) is
It does not show iodoform test.
CH3 produced by atria of heart during
(c) H 3 C-CH 2 -CH 2-C-CH 3 increased blood pressure. It can cause
II -----t CH 3 - CH - CH -CH 2 Cl vasodilation and thereby decrease the
0 *
I blood pressure. Therefore, option (d) is
(Pentan-2-one) CH3 correct.
l-chloro-2, 3 dimethyl butane
WWW.JEEBOOKS.INl
5 1 . (c) Vascular cambium located pair of sister chromatids at this stage When expressed in lowest term, the
between xylem and phloem in the stems each chromosome and hence each end denominator of this fraction will always
and roots of vascular plants. It produces would have two copies of the allele. be a divisor of 99 = 3 · 3 - 11
secondary xylem towards the pith and
6 1 . (b) Let us partition in to n parts and
each part has sum = K, then {l, 3, 9, 11, 33, 99}. As a and b both are not
This gives us the possibilities
secondary phloem towards the bark.
52. (d) Pancreas consists of exocrine and nK = 1 + 2 + 3 + ... + 20 both 9 and not both zero the denominator
nK = 2 10
endocrine parts. Exocrine part secretes 1 cannot be possible.
:.K divides 2 10.

⇒
alkaline pancreatic juice. This juice :. Possible denominators are
Also, K must be � 20.

contains trypsinogen, chymotrypsinogen, {3, 9, 11, 33, 99}.
64. (c) In MBC,
procarboxypeptidase, lipase, amylase,
LC = 90°, AB = 10, LB = 60°

elastase.
53. (a) Archaebacteria are the most
Now, 2 10 = 2 x 3 x 5 x 7
So, proper divisor of 210 are {], 2, 3, 5, 6,
⇒ K can be 2 1, 30, 35, 42, 70,105

primitive form of bacteria. These live in 7, 10, 14, 15, 2 1, 30, 35, 42, 70, 105, 2 10}
diverse habitat, e.g. extreme hot
For K = 2 1, we have (1, 20) (2, 19) ...
temperature, saline condition, variable
pH, etc. Saline bacteria are called
�
(10, 11)
halophiles (e.g. Halobacterium,
For K = 42, join two-two pairs

Halococcus). ⇒ 2 1 is a good number.
54. (c) If anaphase promoting complex is C D A
For K = 105, join five-five pairs
BC = AB cos B = 10 x cos 60° = 5
defective in a human cell, the In MBC,
chromosome will not segregate
For K = 30, we have AC = AB sin B = 10 x sin 60° = 5--/3
⇒ 42 and 105 are also good numbers
during anaphase of mitosis. APC triggers
the transition from metaphase to
such that BD' = 5-/2
{20, 10}, {19, 11}, {18, 12}, {17, 13}, {16, 14}, Choose a P' and get a corresponding D'
anaphase by tagging specific proteins for
⇒ K = 3 0 is also good number BD >

{15, 9, 6}, {1, 2, 3, 4, 5, 7, 8}
55. (d) Zygotic meiosis is represented in

degradation.
5-/2 > .j�B_C__+_C__ > .J25 + CD
2
'D
2 2
Similarly, 35 and 70 also good numbers.

including Chlamydomonas. In such a Thus, the point P may only lie in the
the haplontic life cycle of many algae ⇒ CD > 5
MBD'
:. There are total 6 good numbers.
62. (c) We have,
Area of MBD'
life cycle, all cells are haploid except
Ci : (x - 10) 2 2
= 36
Area of MBC
zygote. This is because meiosis occurs in . d prob ab'l'
+ y Reqmre 1 1ty = - - - - -
the zygote itself resulting into four 2 2
The ratio of AD' to AC because the

C2 : (x + 15) + y = 81
haploid cells that give rise to haploid
plants. Centre of Ci = (10, 0) and radius = 6
56. (c) Gibberellins and ABA are
. = AD' AC - CD'
Centre of C2 = (-15, 0) and radius = 9 triangle have identical altitudes.
AC AC
antagonistic to each other. Gibberellins So, ratio - - =- - -
_ _ CD' _ _
promote seed germination whereas ABA
AC
promotes seed dormancy. 5 _ ,./3 - 1
57. (b) Ornithine cycle removes both

-1 -1 -
5,./3 --/8
ammonia and urea from the blood. It :. Required probability
converts ammonia into urea (in liver) (,./3 - 1) X -J3 - -3 - -J3-
and transports it to kidneys by the blood.
65. (a) We have,

Hence, it plays a key role in detoxification The length of smallest line segment PQ is
P(x) = (x - 1) (x - 2) (x - 3)
of our blood. This cycle occurs in the liver.
58. (b) In the dicot stem, the cortical PQ = .jAB2 - (r1 + r2) 2
the indirect common tangent of circle
:. P[Q(x)] = [Q(x) - 1] [Q(x) - 2] [Q(x) - 3]

P[Q(x)] = P(x) • R(x)
PQ = (25)2 - (9 + 6)2
and
✓
cells get differentiated to give rise to
= (x - 1) (x - 2) (x - 3) R(x)
another meristematic tissue, which is ⇒
[·: AB = (10 + 15)2 - 02 , AB = 25]

✓
called cork cambium or phellogen. On the
other side, it forms phellem (cork) and in Since, degree of P(x) = 3
PQ = ,.)625 - 225
PQ = v'400 = 20
the inner region it forms secondary ⇒
and degree of R(x) = 3
cortical cells (phelloderm).
59. (d) Sucrose shows the most substrate
⇒
63. (d) The repeating decimal 0. ab is
:. Degree of [P(x) · R(x)] = 6
Q(x) = 2
Thus, degree of P(Q(x)) = 6, so degree
specificity since it hydrolyses only the
x = 0. abababab
equal to
disaccharide, sucrose.
60. (c) Since the allele is recessive, both lO0x = ab · abababab
...(i) P(Q(l)) = (Q(l) - 1) (Q(l) - 2) (Q(l) - 3) = 0
...(ii)
P (Q(3)) = (Q(3) - 1) (Q(3) - 2) (Q (3) - 3) = 0

homologous chromosomes in a somatic P(Q(2)) = (Q(2) - 1) (Q(2) - 2) (Q(2) - 3) = 0
cell of an albino person would have the
99x = ab
ab lOa + -b
X= - =-
allele. After meiosis-I, each end would Hence, we conclude Q(l), Q(2) and Q(3)
have a homologous chromosome with the ⇒ - must each be 1, 2, 3. Since, a quadratic is
allele. As the chromosome is existing as a 99 99 uniquely determined by the three points.
WWW.JEEBOOKS.INl
There can be 3 x 3 x 3 = 27 different series and current remains same in both, Thus, terminal alkyne (A) with molecular
quadratic. so IRAB < IRBc · formula C4H6 is CH 3CH 2C =
CH. Thus,
v 2 or P oc -.1
However, we have included Q(x) which Now, for a parallel combination, option (a) is correct.
CH2G_CH ftH2
are not quadratic. They are line.
P=-
Then, Q(l) = Q(2) = Q(3) = 1 R R
⇒ Q(x) = 1 B
Hence, a larger potential drop occurs (Isomer of A)
Q(l) = Q(2) = Q(3) = 2 across 4Q bulb.
⇒ Q(x) = 2 Hence, 4Q bulb glows brightest in given
circuit. CH2-CH=CH- CH2
69. (b) At extreme positions, total
Q(l) = Q(2) = Q(3) = 3
⇒ Q(x) = 3 1 Br2
Q(l) = 1, Q(2) = 2, Q(3) = 3 energy is potential energy.
CH2-CH=CH- CH2
kx2 0.5x2
Br Br
⇒ Q(x) = X So, U(x) = ⇒1= I I
Q(l) = 3, Q(2) = 2, Q(3) = 1 2 2
⇒ x2 = 4 ⇒ x = ± 2m 1, 4 dibromobut-2 -ene
73. (b) Number of moles of the gas

⇒ Q(x) = 4 - X
So, these linear function are not included So, particle turns back after reading 2 m
mark. 2.0 X 102 1 mol
:. Total number of polynomials -----
:.Amplitude of oscillation of particle is 6.023 X 1023
= 27 - 5 = 22
66. (d) For first stone,
2 m.
70. (a) Let m = mass of ice initially
= 3.32 x 10-3 mol
1
Xi_ = ut + - at 2 present. From ideal gas equation
2
Heat absorbed from t = 0 to t = 50 min is p V = nRT
T = pV =
= 15t - 5t2 [·: a = g = - 10 ms-2] 7.57 X l(r X 10-3
QI = miceL
Now, Xi_ = - 200 m nR 3.32 x 10-3 x 8.314
= m (kg) 333 (J/g)
⇒ 15t - 5t 2 = - 200
2 = m (3.33 X Hf ) J = 27425 K
⇒ 5t - 15 t - 200 = 0
and heat absorbed from t = 50 min to Root mean square speed,
⇒ 5t 2 - 40t + 25t - 200 = 0 t = 60 min,
⇒ 5t (t - 8) + 25 (t - 8) = 0 Q2 = mst.T
3
Vrms = � ✓
⇒ t = 8 s or t = - 5 s = (10 + m) (4186 X l(r ) (10 - 0)
-------
3 x 8.3 1 4 x 274.25
(·: t = -5 s not acceptable) = (10 + m) (4186 X l(r ) (10) 28 x 10-3
:. Time for which first stone remains in
Given that, rate of heat supply is = 49426 ms-1
74. (d) (a) Electronic configuration of
air = 8 s. constant.
So, graph is x2 - Xi_ = 15t
So , §__ = �
(For t = 0 to t = 8 s) f.t1 f,_ t2
Br2 = er ls2 er* ls2 er 2s2 er* 2s2
and x2 - Xi_ = 200 + 30t - 5t 2 4- 4
m (3.33 x Hf ) (10 + m) (4186 x l(r ) (10) B.0 = =0
=
(For t > 8 s to t = 10 s) 10
2
67. (d) When object is placed at 2/

50
m(3 a 33) = (10+ m)(4186) Thus, it does not exist. Hence, statement
⇒ (a) is correct.
distance, image formed is also at 2/. 5
⇒ 33.33 m = 209.3 + 20.93 m (b) He = crls2 er * ls2 B.O = -2 - 2- = 0
So, from graph, 2
2
2/ = - 30 cm ⇒ 12.4 m = 209.3 . w1·11 not exist.
Hence, 1t .
2-1
f = - 1 5 cm ⇒ m = 16.87 kg He+2 = crls2er * ls2, B.O = - - = 0.5
71 . (d) Amount of heat liberated by
⇒
68. (a) Circuit can be redrawn as Since, the bond order is not z�ro, this
0.05 g of C molecule is expected to exist.
2n 4n = mCt.T (c) N 2 = crls2cr * ls2 cr2s2 er* 2s2
/�-- 3 ,,.------&�
C = 2000 X 1 (26 - 24)
10 - 4
n2p; = n2py2 cr2p;
= 4000 cal = 4 kcal B.O = =3
2
Calorific value = - 4 kcal
. - - x l = 8 kcal per g
Thus, it has the maximum bond strength
0.5
[/ """ ':>�<� :. Heat of combustion = - 8 x 12

among the other diatomic molecule
belonging to the second period.
+ - = - 96 kcal per mol
72. (a) As the organic compound forms
20 V (d) The correct electronic configuration of
N 2 is er ls2 er* ls2cr 2s2 er* 2s2
As RAB and RAC are nearly 1 Q and 2Q white precipitate with AgNO3 /NH4 OH n2p; = n2p; cr2p;
occurs across BC. As AB and BC are in
respectively, a larger potential drop and red precipitate with Cu 2ClJNH4OH,
Thus, statement (d) is incorrect.
it must be a terminal alkyne.
WWW.JEEBOOKS.INl
75. (a) Equivalent mass of M quaternary structure. Tertiary structure 79. (a) There are 12 chromosomes
mass of metal of protein is a single polypeptide chain present. In a mitotic division, the number
= x8
mass of oxygen folded and twisted. Primary structure of of chromosomes remains the same, i.e.
= X 8 = 100
10 protein is amino acids joined end to end 2n ➔ 2n. In a meiotic division, the
with each other. Secondary structures number is halved, i.e., 2n ➔ n so, there
0.8
are folded into a-helix and �-pleated should only be 6 chromosomes in the
Approximate atomic mass
= � = 193.3 g
sheets. nucleus.
80. (b) Phosphate group, ribose or
6.4
77. (d) The amount of light given is
specific heat 0.033
Valency of M = - - = 1.98 = 2
saturated, not limited. Therefore the deoxyribose group and cytosine group
193.93 answer is (d). The concentration of carbon form the nucleotide.
100 dioxide is in short supply, hence limiting Phosphate (H 3 P04 )
So, accurate atomic mass the rate of photosynthesis.
78. (c) The drugs will only prevent the
Ribose (C5 H 1005 )
= 100 X 2 = 200 g
= equivalent mass x valency
Deoxyribose (C 5 H 1004 )
response of the muscle to an electrical
= =1
Cytosine has 4 carbon atoms, as it is a
molar mass 199.87 stimulus if it prevents the release of
Atomicity pyrimidine.
atomic mass 200 acetylcholine and so inhibits the increase
in membrane permeability to sodium Therefore, the nucleotide should have
76. (d) The folding of two or more ions, and if the drug competes with 5C + 4C = 9C
polypeptide chains constitutes the
acetylcholine at the receptor sites.
WWW.JEEBOOKS.INl

Kvpy Past Year

Uploaded by

Copyright:

Available Formats

Kvpy Past Year

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Kvpy Past Year

Uploaded by

Copyright:

Available Formats

Join Telegram-@mainchannelpdf

Kishore Vaigyanik Protsahan Yoiana

!Ii Administrative & Production Offices

!Ii Head Office

!Ii Sales & Support Offices

Published by Arihant Publications (India) Ltd.

QUESTION PAPERS PATTERN

SNSX/SB during 1st to lllrd year

CONTINUATION/ RENEWAL OF FELLOWSHIP

KVPY Timeline 2021

QUESTION PAPER QUESTION PAPER QUESTION PAPER

QUESTION PAPER QUESTION PAPER QUESTION PAPER

QUESTION PAPER QUESTION PAPER QUESTION PAPER

QUESTION PAPER QUESTION PAPER QUESTION PAPER

KVPY PRACTICE SETS (1-5) 167-232

OUESTION PAPER 2020

� PART-I (1 Mark Questions)

::p::. .: 1:c 1,; ·: :·· s:i. ,+i,:� :: ,; . l: :! l "J. 2+ .h

:+L:: Ee!�-,;,,'.::_,.:: .i4.J:'. :: 111 j '. :) :�_, _ j.h

36. A closed 10 L vessel contains 1 L water gas

45. The first ionisation potential (IP) of the elements Na,

Velocity (m/s) Veloc ity (m/s)

AB and CD are isothermal processes while BC and

temperature (T) - entropy (S) plane is

54. A plant with genotype AABBCC is crossed with Column I Column II

� PART-II ( 2 Mark Questions)

62. Let ABC be a triangle such that AB = 4, BC = 5 and

CA = 6. Choose points D, E, F on AB, BC, CA

respectively, such that AD = 2, BE = 33, CF = 4. Then

66. A charge + q is situated at a

L shaped sheet as shown in the

height h contains some water. When its base is

(a) Zero (b) 32 s

Cl.. (c) 3,600 (d) 1,200

✓fJ ✓<J + ✓r ✓fJ + ✓r✓<J + (✓r)2 E Q

are in AP :. Let LDAB = 0 - a, LABC = 0

CJi (x) = - q2 (x) = q(x) (say)

3. (c) ·: p, q, r E Q and ✓P + .J<i + -Jr E Q

LAOB = 2LACB When x = y = 1 , then 2 + 3 = 5

x, y E z LHS is not equal to 1 as both

8 . (b) Total number of digits used till 1 1 . (a) We have, (a - 1) - 0 = O ⇒la = 11

and in MDE, tan0 = -

PB BD PD ⇒ 2tan0 28- 7 ⇒ t=�

25. (d) The value of acceleration due to

:. Finally, relative speed of spacecraft h _ 1 ⇒ m - 1= !±.

20. (b) As, 1° = (60 x 60) s

Vi 27. (b) Given, velocity of projection of

For critical angular displacement, mg

tan 0 = � So, time taken by the ball to the hoop,

CO 2 + H2O � H2CO3� HCO3 + Ir

molecular speeds is Vrms >V > Vmp

Step 1 (A ➔ B) : Process involved is

isothermal expansion, i.e. TA = TB .

Step 2 (B ➔ C) : Process involved is

0 Therefore, TB > Tc,

ci Step 3 ( C ➔ D) : Process involved is

isothermal compression, i.e. Tc = Tn , Here,

40. (c) Electronic configuration of Step 4 (D ➔ A) : Process involved is

= q Lr\/ "' 2 towards 0

In the graph, at Ti , the gas cannot be

C 6Hio , when treated with HBr, forms a gem