Chapter 3: Review of Basic Vacuum Calculations: Las Positas College Vacuum Technology 60A & 60B
Chapter 3: Review of Basic Vacuum Calculations: Las Positas College Vacuum Technology 60A & 60B
Chapter 3: Review of Basic Vacuum Calculations: Las Positas College Vacuum Technology 60A & 60B
Vacuum: from a practical sense, vacuum may be defined as the condition of a gas
under less than atmospheric pressure.
Table 3.1: Vacuum ranges
Vacuum Description Range
Low vacuum 25 to 760 Torr
Medium vacuum 10-3 to 25 Torr
High vacuum 10-6 to 10-3 Torr
Very high vacuum 10-9 to 10-6 Torr
Ultrahigh vacuum 10-12 to 10-9 Torr
Extreme Ultrahigh vacuum below 10-12 Torr
Atmosphere: The blanket of gases that surrounds the surface of the earth and extends
outward to a distance of about 25 miles is referred to as "air" or "the atmosphere". This
mixture of gases exerts a pressure that presses uniformly on all objects on the surface
of the earth. This pressure is about 15 pounds per square inch at sea level.
If we remove some amount of atmospheric gas from a leak-free vessel we will have
created an environment that is drastically different in many respects: mechanically,
chemically and physically.
Mechanical Effects of Vacuum: Have you ever placed a half full 2 liter plastic soft
drink container that is at room temperature into a refrigerator, and noticed later after it
has cooled that its sides are distorted and pulled inwards? What you have inadvertently
done is create a condition in which the internal pressure of the plastic container was
reduced, causing its surface to buckle. Vacuum engineers are acutely aware of this
phenomenon, and design vacuum vessels to be sturdy enough to withstand the external
atmospheric pressure of 14.7 pounds per square inch (at sea level) in the absence of
compensating internal pressure. Structures and components that are particularly
susceptible to distortion under vacuum conditions include flat, unsupported surfaces,
thin sections, and flexible lines or bellows.
Sample Problem:
3.1 Calculate the approximate total force that will be exerted on a 4" diameter glass
view port used in a vessel under high vacuum conditions.
Chemical Effects of Vacuum: The removal of gases from a container will reduce the
number of gas atoms that are available to interact with materials in the container. For
this reason many materials that are hydroscopic (have a tendency to absorb water from
the atmosphere) are stored under vacuum. Materials that readily oxidize are also often
stored either under high vacuum, or in an inert atmosphere (nitrogen or argon gas) after
the air has been removed from the storage vessel.
Sample Problem:
3.2 List as many reactive elements or compounds that you know of which you would
consider storing under vacuum or inert gas conditions.
Physical Effects of Vacuum: Many of the physical properties of gases are strongly
affected by the pressure of the gas. Thermal conductivity, electrical conductivity,
propagation of sound, optical transmission, optical absorption are just a few. In addition
to the effect of reduced pressure on the physical properties of gases, under vacuum
solids and liquids also show markedly different behavior. Liquids, such as water, can be
made to boil in a vacuum vessel without the application of heat. This occurs as soon as
the vapor pressure of the water exceeds that of the vacuum environment.. Similarly,
atoms of solid material under vacuum conditions will spontaneously leave the surface of
the solid. The rate at which materials vaporize under vacuum is a function of the
pressure in the system and the vapor pressure of the material. A more in-depth
discussion of vapor pressure will be presented later.
Sample Problem:
3.3 We have suggested that physical changes in the thermal and electrical
conduction of gases are brought about by a decrease in pressure. What are the trends
you would expect in these two physical characteristics as pressure is decreased from
atmospheric? (Increase or decrease?)
Gas Laws
Gases are composed of independent, randomly moving atoms or molecules that
spontaneously expand to fill any container. The collective behavior of these atoms or
molecules in a contained volume can be described when one knows any three of the
four following quantities:
1. Pressure: The force per unit area a gas exerts on its surroundings. (in our
calculations we will use primarily Torr or atmospheres).
Boyle's Law: Under conditions of constant temperature, Boyle's Law gives the
relationship between volume and pressure for a fixed quantity of gas.
P1 × V1 = P2 × V 2
TC1 TC2
Figure 3.1
Assuming that the temperature is constant everywhere in our system, and that we can
accurately measure the pressure in both vessels, we should be able to apply Boyle's
law to calculate the volume of vacuum vessel 2.
If we know that at the beginning of our experiment the volume of vessel 1 is 120 liters,
and the pressure of gas inside vessel 1 is 760 Torr, and that vacuum vessel 2 has been
rough pumped to about 10 mTorr we can write:
Now, if we open the valve between vessels 1 and 2, and allow sufficient time for the
system to equilibrate, we read pressures at TC1 and TC2 to be 500 Torr.
Solving for V2 we find the second vessel has a volume of 62 liters (note that we include
the tubulation to the right of the valve as part of the volume of vessel V2.).
Sample Problem:
3.4 What would be the volume of vessel 2 in figure 3.1 if the final pressure read on TC1
and TC2 was 350 Torr rather than 500 Torr?
Charles' Law: Under conditions of fixed volume and amount of gas, Charles' Law
describes the relationship between the temperature and pressure of a gas.
TC1 TC1
Figure 3.2
Sample Problem:
3.5 If the initial pressure and temperature of the leak-free vessel in figure 3.2 were 50
mTorr and 25 °C respectively, and the vessel was heated uniformly to 100 °C
what would be the new pressure reading?
The Ideal Gas Law: The relationship between pressure, volume, amount of gas and
temperature of gas for "ideal" gases is given by the Ideal gas law. Fortunately, most
gases behave "ideally" under subatmospheric conditions.
P= pressure [Atmospheres]
PV = nRT
V=volume [Liters]
n=moles of gas [moles]
R=Ideal gas Law constant
(0.08206 L-atm/K-mole)
T=absolute temperature [Kelvin]
Sample Problem:
3.6 If a 100 liter vessel at room temperature is evacuated to a pressure of 50 mTorr,
how many moles of gas are in the vessel? How many molecules is this? How
many molecules per cubic centimeter is this?
3) The distances between individual gas molecules are large compared with
the diameter of the molecules.
Velocity of Gas Molecules: The speed at which gas molecules travel is independent of
pressure, but is a function of the temperature and molecular weight of the gas.
Sample Problem:
3.7 Calculate the velocity of a nitrogen molecule at 100 °C. (to convert from
centigrade to kelvin, add 273).
Mean Free Path: The distance a gas molecule can travel (on the average) is a function
of total pressure and the diameter of the gas molecules.
Sample Problem:
3.8 For a vacuum system at room temperature having a volume of 50 liters, and
containing nitrogen gas at a pressure of 5 x 10-6 Torr, find the number density, N, and
the mean free path, L {the molecular diameter of N2 is 3.8Å or 3.8 x 10-8 cm }
For most clean vacuum systems the majority of the gas load may be assumed to be
nitrogen, and at room temperature the following approximation may be used to calculate
the mean free path for N2 molecules:
4 cm − sec 2
Usually, the quantities that we can easily measure are pressure and temperature, so,
the same equation expressed in terms of these units is:
P 1
I = 3.5 x1022
WmT cm − sec
2
Sample Problem:
3.9 What is the impingement rate for nitrogen molecules on the inner surface of a
vacuum vessel having a pressure of 5 x 10-6 Torr and a temperature of 25 °C?
What is I for the same system at 5 x 10-9 Torr?
Motion of Gas Molecules: As collisions occur between gas molecules and the inner
exposed surfaces of a vessel, the molecules are "diffusely" reflected, that is there is no
relationship between the arrival angle and the departure angle following a collision. The
angle of departure from a planar surface has been studied and was observed to follow a
cosine distribution as shown in figure 3.4
100
97
90°
87
75°
60° 71
45°
50
30° 26
Flow of Gas Through an Orifice: Let's do another thought experiment. Imagine a leak
free vacuum system comprised of two vessels separated by a closed valve. One vessel
contains nitrogen gas at a pressure of 5 x 10-5 Torr and the other vessel is under
extreme high vacuum (5 x 10-10 Torr). Both vessels are at room temperature. If we
suddenly open the valve what will happen during the pressure equilibration time? Only
those molecules that randomly impinge {molecular flow, right?} upon the opening
between the vessels will leave the vessel at higher pressure and move into the vessel at
lower pressure. Let me make the point clear by stating the reverse: those molecules in
the vessel at initially higher pressure that don't impinge upon the opening between the
vessels can not leave the vessel they are in. What this suggests is that the flow rate for
gas molecules leaving a vessel is a function of the collision rate of molecules per unit
surface area. The number of gas molecules leaving is:
Upon initiating a pump down, the flow of gas molecules is often turbulent, exhibiting
eddies and currents much like a raging rapid.
Figure 3.6 Gas molecules in transition flow conditions. Mean free path is roughly
equivalent to the pipe diameter.
Figure 3.7 Gas molecules in molecular flow conditions. Mean free path is greater than
1.5 times the pipe diameter.
Gas Flow Rates
Volumetric: Flow rate (S) is the volume amount of gas that passes by a point per unit
time. Examples of units are: liters/second or cubic feet/ minute. The volumetric flow rate
may be considered to be the pumping speed of a system at a specified point in the
conductance path.
Quantitative: Flow rate (Q) is the amount of gas that passes by a point per unit time.
Units are: Torr-liters/second. The quantitative flow rate is also referred to as the
throughput, or mass flow, and is constant everywhere in the vacuum system, unless gas
is leaking or is being captured or condensed along the path.
Q
chamber vent
Vacuum Chamber
IG1 TC1 chamber vent valve
rough valve
head gate
valve IG2
Q
DP vent TC3
TC2
foreline
valve
Figure 3.8 Gas flowing through a vacuum system beginning at the inlet to the vacuum
vessel and exiting at the exhaust of the roughing pump. At all locations in the vacuum
circuit the quantitative flow rate (Q) is the same.
Z= resistance [sec/liter]
P −P
Z= 1 2 P= pressure [Torr]
Q=flow rate [Torr-L/s]
Q
Conductance is the inverse of resistance and therefore,
C= conductance [liter/sec]
1 Q
C= =
Z P1 − P2
Even very simple vacuum systems are comprised of many conductance elements,
some are connected in series, some in parallel. Let's examine how to calculate the
effect of various components in simple systems.
valve trap
pump
C1
Vacuum C2
chamber
CT = C1 + C2 + C3 + ... = ∑ Ci
etc. which are connected in Parallel in
figure 3.10
Sample Problems
3.10 For the vacuum system shown in figure 3.9, if C1= 50 L/s, C2=100 L/s and C3=
100 L/s what is the total conductance of the three elements?
3.11 In figure 3.10, if C1 and C2, have the same values as in the previous problem,
what is the net conductance of the assembly?
Calculation of Conductance
In this section we will present several "general use" formulas for calculation of
conductance's under commonly encountered situations.
Viscous Flow: For the situation in which the mean free path, L, is approximately the
same as the diameter of the conductance element; the throughput, Qv, for dry air is
given by:
P= average pressure
3000 PD 4 Torr − liters
Qv = ( P1 − P2 )
(P1+P2)/2
L sec D= tube diameter [inches]
L= tube length [inches]
Qv 3000 PD 4 liters
Cv = Cv =
( P1` − P2 ) L sec
{Note: conductance element length and diameter (L and D , respectively) are in inch
units.}
Molecular Flow: For the situation in which the mean free path of molecules is much
larger than the diameter of the conductance element, the relationships for throughput, Q
and conductance, Cm are given by:
80 D 3
Qm = ( P1 − P2 )
L
Qm 80 D 3
Cm = Cm =
( P1 − P2 ) L
Now let's apply this information to the calculation of pumping speeds in a simple
vacuum system.
P1 P2
Q C
S S
t p
At any location in the vacuum circuit the volumetric flow rate or pumping speed at that
point can be found if we know the pressure at that point, the pressure at the pump, and
the conductance of the path connecting these two. At the chamber side of the system
P1= Q/St, and similarly at the pump side, P2=Q/Sp. We will make use of the relationship
between mass flow (Q), pressure drop (P1-P2), and conductance (C):
Q = ( P1 − P2 )C
Substituting Q/St for P1 and Q/Sp for P2 we get:
Q Q
Q = − C
S S
t p
Sample Problem:
3.12 For the simple vacuum system pictured in figure 3.11, calculate the pumping speed
at the chamber if the pump has a speed of 200 L/s, the pressure at the vacuum
pump is 5 x 10-6, and the conductance element is a tube 30" long by 2" in
diameter.
8"Ø 3"Ø
While accurate equations for aperture flow are complex in the viscous flow regime, this
approximation is often reasonably valid:
In the molecular flow regime the following is valid for Nitrogen near room temperature:
Pressure Interval 1: Time required to pump from 760 Torr to 100 Torr.
A. Calculate the conductance of the tube between the pump and vessel (be sure to
check for viscous or molecular flow conditions).
B. Use a pump efficiency curve to determine the volumetric pumping speed of the
pump for the pressure interval of interest.
C. Calculate the delivered pump speed.
D. Calculate the time to pump from P1 to P2.
viscous flow
4
3000 PD
C=
L
3
80 D
C=
L
transition flow 4 3
molecular flow
C= 3000 PD +80 D
L
Pressure
Figure 3.1 Conductance vs. pressure for dry air being pumped through a tube of
circular cross section.
100
Pump Speed [Liters/sec]
10
.1
.01 .1 1 10 100 1000
Pressure [Torr]
Figure 3.2 Pump speed vs. pressure for an oil sealed mechanical pump.
High Vacuum Technology, Hablanian, Marsbed, M., Marcel Dekker, INC., New York,
New York. 1990.
A User's Guide to Vacuum Technology, O'Hanlon, John F. John Wiley & Sons New
York, New York. 1980.
Practical Vacuum Systems, LaPelle, Roland R. , McGraw-Hill Book Co. New York, New
York. 1972.
3.2 Sodium (reactive metal), pure iron (oxidizes rapidly in moist air), and lithium
(reactive metal).
3.3 As pressure decreases, thermal conductivity and electrical conductivity of air
should both decrease.
3.4 140 liters.
3.5 63 mTorr.
3.6
A. Solve for the number of moles, n in the vessel.
step 1: convert pressure 50 mTorr/760 Torr = 6.58 x 10-5atm
step 2: convert temperature 25 °C + 273= 298k
step 3: PV=nRT (6.58 x 10-5atm)(100 L)=n(0.08206L-atm/k-mol)(298k)
n= 2.69 x 10-4 moles of gas molecules.
B. Solve for the number of molecules in the vessel.
{there are 6.02 x 1023 molecules per mole}
(2.69 x 10-4 moles)(6.02 x 1023 molecules per mole)=1.62 x 1020 molecules.
3.12 First calculate the conductance of the conductance element.given: tube is 30" long,
2" in diameter, assume molecular flow. C= 80 x (4")3/30"=21.33 L/s = 171 L/s.
Then use 1/S1=1/C + 1/S2 to solve for S1. S1= 92 L/s.
P1 P2
TC1 TC2
Q C
S S
t p
Figure 3.13 Experimental setup for measurement of pumping speed at the vacuum
chamber.
Discussion:
Did the change in conductance element length between the pump and chamber
cause the expected change in pumping speed as measured at the chamber?
Why or why not?