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Assignment 1 Stat Eval of Data

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Assignment in Statistical Evaluation of Data

1. Consider the following sets of replicate measurements:

B C E F
69.94 0.0902 69.65 0.624
69.92 0.0884 69.63 0.613
69.80 0.0886 69.64 0.596
69.88 0.1000 69.21 0.607
69.84 0.0935 69.45 0.582

For each set, calculate the (Observe rules on significant figures)


a.) mean,
b.) median,
c.) range,
d.) standard deviation,
e.) coefficient of variation,
f.) standard deviation of the mean
g.) 95% confidence limit of finding the value for µ

Table 2. Values of t for Various Levels of Probability


Degrees of Factor for Confidence Interval
Freedom 80 % 90% 95 % 99% 99.9%
1 3.08 6.31 12.7 63.7 637
2 1.89 2.92 4.30 9.92 31.60
3 1.64 2.35 3.18 5.84 12.90
4 1.53 2.13 2.78 4.60 8.60
5 1.48 2.02 2.57 4.03 6.86
6 1.44 1.94 2.45 3.71 5.96
7 1.42 1.90 2.36 3.50 5.40
8 1.40 1.86 2.31 3.36 5.04
9 1.38 1.83 2.26 3.25 4.78

2. Apply Q-test to the following set of data and determine whether the outlying result is
retained or rejected.
a.) 7.295, 7.284, 7.388, 7.292
b.) 85.10, 84.62, 84.70, 84.65

Number of Qcritical ( Xq is rejected if: Qexp ≥ Qcritical )


Observations 90 % 95 % 99 %
3 0.941 0.970 0.994
4 0.765 0.829 0.926
5 0.642 0.710 0.821
6 0.560 0.625 0.740
7 0.507 0.568 0.680
3. The sulfate ion concentration in natural water can be determined by measuring the turbidity
that results when an excess of BaCl 2 is added to a measured quantity of the sample. A
turbiditimeter, the instrument used for this analysis, was calibrated with a series of standard
Na2SO4 solutions. The following data were obtained for the calibration:
Cx , mg SO42– /L Turbiditimeter reading, Y
0.00 0.06
5.00 1.48
10.00 2.28
15.00 3.98
20.00 4.61

Assume that a linear relationship exists between the instrument reading and concentration.
a) Derive an equation of a line that tells us the relationship of C x and Y.
b) What is the concentration of sulfate when the turbiditimeter reading was 3.67?

4. Estimate the absolute deviation(or uncertainty) for the results of the following
calculations. Round each result so that it contains only significant digits. The numbers in
parentheses are absolute standard deviations. Finally, write the answer and its uncertainty.
a) Y= 6.75 (± 0.03) + 0.843(±0.001) - 5.021 (±0.001) = 2.572
b) Y= 19.97(± 0.04) + 0.0030(±0.0001) + 4.29(±0.08) = 24.263
c) Y= 143(± 6) - 64(±3) = 5.9578 x10-2
1249 (±1) +77 (±8)

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