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Titration Curves Lab Report

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Olivia Martin, Lindsay Koepke, Titration Curves, 04/12/2021

Procedures
This titration curves lab entailed using our skills in titration to generate an acid-base titration curve. The
lab started with standardizing a sodium hydroxide solution. From there we generated a titration curve for
the titration of our weak acid with a strong base and determined the equivalence point. Lastly, we
calculated the initial concentration of the weak acid and the Ka for the weak acid using our data from the
titration. The purpose of this lab was to practice using titrations and equivalence points to calculate the
pH. This is important because it provides a better understanding of how the equivalence point relates to
the Ka value.

Results
Titration Curve:

Standardization of NaOH

Trial 1 Trial 2 Trial 3

Mass of KHP 0.501 g 0.501 g 0.501 g

Final buret reading, NaOH 16 mL 32 mL 48 mL

Initial buret reading, NaOH 0 mL 16 mL 32 mL

Total volume, NaOH 16 mL 16 mL 16 mL

Molarity of NaOH 0.153125 0.153125 0.153125

Average molarity of NaOH 0.153125


Initial pH of acid solution: 2.03
Volume of NaOH solution required to reach equivalence point: 34.5 mL
pH at equivalence point: 10.12
Initial concentration of acid: (2.45 x 10^-3) / (0.016) = 0.153125
½ volume of base required to reach equivalence point: 17.25
pH of solution at this half-way point: 2.70

Interpretation of Data & Conclusion


There were no issues or mistakes that I am aware of from this lab. From the titration curve and other
information gathered from this experiment, it can be determined that unknown 7 is a strong acid and
NaOH is a strong base. The equivalence point helps confirm this observation (shown in the photo of the
titration curve). The recording of pH time intervals helped to find the equivalence point since the change
in pH value is very evident, (34.5 mL, pH 5.0 - pH 10.12), which indicates the equivalence point.

Ka Calculations:
Ka initial: 0.153125/2.03 = 0.07543103448
Ka halfway: 2.70/17.25 = 0.1565217391
The Ka values have a difference of 0.08109070465. The Ka value for the halfway point is greater than the
Ka value for the first full equilibrium point.

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