Thermal Pr0perties of Ceramics

Thermal properties of ceramics
Dr. Dmitri Kopeliovich
The following thermal properties of ceramic materials are important in various design
considerations:
 Thermal conductivity
 Thermal expansion
 Heat capacity
 Thermal shock resistance
 Maximum service temperature
Thermal Conductivity
Thermal Conductivity (λ) is amount of heat passing in unit time through unit surface in a
direction normal to this surface when this transfer is driven by unite temperature gradient under
steady state conditions.
Thermal conductivity may be expressed and calculated from the Fourier’s law:
ΔQ/ Δt = λ*S *ΔT/ Δx
Where
Q -heat, passing through the surface S;
Δt - change in time;
λ - thermal conductivity;
S - surface area, normal to the heat transfer direction;
ΔT/Δx-temperature gradient along x – direction of the heat transfer.
Fourier’s law is analogue of the First Fick’s law, describing diffusion in steady state.
In contrast to Metals Ceramics have low thermal conductivity due to Ionic-Covalent Bonding
which does not form free electrons.
Compare:
λ of alumina = 47 BTU/(lb*ºF) (6.3 W/(m*K)).

λ of Al = 1600 BTU/(lb*ºF) (231 W/(m*K)).
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Coefficient of Thermal Expansion
Thermal Expansion (Coefficient of Thermal Expansion) is relative increase in length per

unite temperature rise:
α= ΔL/ (LoΔT)
Where
α -coefficient of thermal expansion (CTE);
ΔL – length increase;
Lo – initial length;
ΔT – temperature rise.
Thermal expansion of ceramic materials is generally lower, than that of metals.
Compare:
CTE of SiC = 2.3 ºFˉ¹ (4.0 ºCˉ¹).
CTE of Al = 13 ºFˉ¹ (23 ºCˉ¹).
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Specific Heat Capacity
Heat Capacity is amount of heat required to raise material temperature by one unit.
Specific Heat Capacity is amount of heat required to raise temperature of unit mass of material
by one unit:
c= ΔQ/(mΔT)
Where
c -specific heat capacity;
ΔQ – amount of heat;
m – material mass;
ΔT – temperature rise.
Specific Heat Capacity of ceramic materials is higher, than that of metals.
Compare:
“c” ofalumina = 0.203 BTU/(lb*ºF) (850 J/(kg*K)).
“c” ofsteel = 0.115 BTU/(lb*ºF) (481 J/(kg*K)).

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Thermal Shock Resistance
Thermal Shock Resistance is an ability of material to withstand sharp changes in temperature.
If a ceramic material is rapidly cooled, its surface reaches the temperature of cooling
environment and tends to contract (thermal contraction). Since the interior regions of the material
are still hot, thermal contraction of the skin surface is impossible.
This leads to formation of tensile stress (thermal stress) in the skin. Such thermal stresses may
cause cracks and consequent failure.
Thermal shock resistance of a material may be estimated in accordance to the formula:
Rs = (λ*σF)/(α*E)
Where
Rs – thermal shock resistance;
λ - thermal conductivity;
σF – flexural strength
α -coefficient of thermal expansion (CTE);
E – modulus of elasticity.
Sensitivity of ceramic materials to thermal shock may be also determined by experimental

method (Hasselmann Method).
In this method a specimen (flexural test specimen) is heated to a specified temperature and then
quenched. The specimen cools rapidly by temperature ΔT (the difference between the specimen
temperature before and after cooling).
After quenching the flexural strength of the quenched material is measured by standard flexure
(bending) test.
The test results are plotted on the graph Strength vs. ΔT.
When ΔT reaches a certain value the specimen strength falls sharply. This value of ΔT is a
parameter indicating thermal shock resistance of the material.
Some ceramic materials have very low coefficient of thermal expansion therefore their resistance
to thermal shock is very high despite of low ductility (e.g. fused silica):
Rs of fused silica / Rs of soda-lime-silica glass = 45
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Maximum Service Temperature
Ceramic materials retain their properties at elevated temperatures due to the strong ionic-
covalent bonding.
Ceramics working at high temperature are called refractory ceramic materials.
Some Borides, carbides and nitrides, having melting temperature above 5500 ºF (3040 ºC), are
used in high temperature applications up to 3300 ºF (1800 ºC)… 5430 ºF (3000 ºC).
Compare:
Scaling (oxidation) temperature of refractory stainless steel AISI 310 is 2100 ºF (1150 ºC).

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Thermal properties of ceramics

Dr. Dmitri Kopeliovich

ΔQ/ Δt = λ*S *ΔT/ Δx

Q -heat, passing through the surface S;

S - surface area, normal to the heat transfer direction;

ΔT/Δx-temperature gradient along x – direction of the heat transfer.

λ of alumina = 47 BTU/(lb*ºF) (6.3 W/(m*K)).

Coefficient of Thermal Expansion

Thermal Expansion (Coefficient of Thermal Expansion) is relative increase in length per

α -coefficient of thermal expansion (CTE);

Thermal expansion of ceramic materials is generally lower, than that of metals.

CTE of SiC = 2.3 ºFˉ¹ (4.0 ºCˉ¹).

CTE of Al = 13 ºFˉ¹ (23 ºCˉ¹).

Specific Heat Capacity

c -specific heat capacity;

Specific Heat Capacity of ceramic materials is higher, than that of metals.

“c” ofalumina = 0.203 BTU/(lb*ºF) (850 J/(kg*K)).

“c” ofsteel = 0.115 BTU/(lb*ºF) (481 J/(kg*K)).

Thermal Shock Resistance

Thermal Shock Resistance is an ability of material to withstand sharp changes in temperature.

Thermal shock resistance of a material may be estimated in accordance to the formula:

Rs – thermal shock resistance;

α -coefficient of thermal expansion (CTE);

Sensitivity of ceramic materials to thermal shock may be also determined by experimental

Rs of fused silica / Rs of soda-lime-silica glass = 45

Maximum Service Temperature

Ceramics working at high temperature are called refractory ceramic materials.

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ΔQ/ Δt = λS ΔT/ Δx

λ of alumina = 47 BTU/(lbºF) (6.3 W/(mK)).

“c” ofalumina = 0.203 BTU/(lbºF) (850 J/(kgK)).

“c” ofsteel = 0.115 BTU/(lbºF) (481 J/(kgK)).