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Safety Data Sheet

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Printing date 06/13/2015 Reviewed on 06/13/2015

1 Identification
· Product identifier
· Trade name: Lapox AH-416
· Article number: PO05445
· Relevant identified uses of the substance or mixture and uses advised against
Curing agent (Hardener) for epoxy resins for coating applications.
· Sector of Use SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
· Application of the substance / the mixture Curing agent for epoxy resins
· Details of the supplier of the safety data sheet
Atul USA Inc
6917 Shannon Willow Road, 400
Charlotte, NC 28226
Tel: 704 540 8460
· Manufacturer/Supplier:
Atul Limited
Polymers Division
North Site, Atul-396020
Gujarat State, INDIA
Contact: +91 2632 230473
Web site: www.atul.co.in
· Information department:
Corporate Product Safety & REACH
product_safety@atul.co.in
· Emergency telephone number:
During normal opening times: 0044 (0)1625 539209 ( in Europe)
+91 (0)2632 230473, +91 9687369677 ( in Non-Europe)

2 Hazard(s) identification
· Classification of the substance or mixture

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H312 Harmful in contact with skin.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
(Contd. on page 2)
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(Contd. of page 1)
Benzyl alcohol
4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with 3-
aminomethyl-3,5,5-trimethylcyclohexylamine
· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P260 Do not breathe dusts or mists.
P280 Wear protective gloves.
P280 Wear protective gloves / protective clothing.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 3
1 Fire = 1
3 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH *3 Health = *3
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: No data available
· vPvB: No data available

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
(Contd. on page 3)
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(Contd. of page 2)
· Dangerous components:
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 25-50%
Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317
100-51-6 Benzyl alcohol 25-50%
Acute Tox. 4, H302; Acute Tox. 4, H332
38294-64-3 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, 10-25%
reaction products with 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Skin Sens. 1, H317
· SVHC Does not fall under SVHC substance

4 First-aid measures
· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the
accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture Emits toxic fumes under fire conditions.
· Advice for firefighters
Fire fighters to wear self-contained breathing apparatus and suitable protective
clothing if risk of exposure to vapour or products of combustion.
· Protective equipment:
Wear self-contained respiratory protective device.
Mouth respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Particular danger of slipping on leaked/spilled product.
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
(Contd. on page 4)
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(Contd. of page 3)
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: Do not spray on a naked flame or any incandescent material.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Conditions of Storage: Keep tightly closed. Store in a cool dry place.
· Information about storage in one common storage facility:
Do not store together with reducing agents, heavy-metal compounds, acids and alkalis.
Do not store together with oxidizing and acidic materials.
· Further information about storage conditions:
Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from
incompatible materials described in Section 10. Keep containers closed when not in use
- check regularly for spills.
Keep receptacle tightly sealed.
· Specific end use(s) Hardener for epoxy resins for protective coating applications

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
100-51-6 Benzyl alcohol
WEEL Long-term value: 10 ppm
· Additional information:
The lists that were valid during the creation were used as basis.
3-Aminomethyl-3,5,5-trimethylcyclohexylamine: 2855-13-2: worker: inhalation
Acute/short term exposure - systemic effects: 20,1 mg/m3
3-Aminomethyl-3,5,5-trimethylcyclohexylamine: 2855-13-2: worker: inhalation
Acute/short term exposure - local effects: 20,1 mg/m3
3-Aminomethyl-3,5,5-trimethylcyclohexylamine: 2855-13-2: general population: oral
Long term exposure - systemic effects: 0,526 mg/kg bw/day

Exposure time : 4 hrs

Observation time: 14 days
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
(Contd. on page 5)
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(Contd. of page 4)
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical
mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies
from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove
material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
Form: Liquid
Color: Light yellow
· Odor: Amine-like
· Odour threshold: Not determined.
· pH-value: Alkaline
· Change in condition
Boiling point/Boiling range: 205 °C (401 °F)
· Flash point: 101 °C (214 °F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 435 °C (815 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: 1.3 Vol %
Upper: 13.0 Vol %
· Vapor pressure at 20 °C (68 °F): 0.1 hPa
· Density at 20 °C (68 °F): 0.98 g/cm³ (8.178 lbs/gal)
(Contd. on page 6)
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(Contd. of page 5)

· Relative density at 25 °C (77 °F) 1.03 g/cm³ (8.595 lbs/gal)

· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): No data available
· Viscosity:
Dynamic at 25 °C (77 °F): 400-600 mPas (ASTM D 2196)
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
· Possibility of hazardous reactions
Reacts with acids, alkalis and oxidizing agents.
Reacts with epoxy functional compounds with exothermic reaction liberation of fumes.
· Conditions to avoid No further relevant information available.
· Incompatible materials: Strong oxidising agents, Strong acids, epoxy functional compounds
· Hazardous decomposition products: Carbon monoxide, Carbon dioxide & Nitrogen oxides.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
100-51-6 Benzyl alcohol
Oral LD50 1230 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye: Strong caustic effect.
· Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and
stomach.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
(Contd. on page 7)
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(Contd. of page 6)
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· Results of PBT and vPvB assessment
· PBT: No data available
· vPvB: No data available
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT, ADR, IMDG, IATA UN2735
· UN proper shipping name
· DOT Amines, liquid, corrosive, n.o.s. (Isophoronediamine)
· ADR 2735 Amines, liquid, corrosive, n.o.s. (Isophoronediamine)
· IMDG, IATA AMINES, LIQUID, CORROSIVE, N.O.S. (ISOPHORONEDIAMINE)
· Transport hazard class(es)
· DOT

· Class 8 Corrosive substances

(Contd. on page 8)
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(Contd. of page 7)

· Label 8
· ADR, IMDG, IATA

· Class 8 Corrosive substances

· Label 8
· Packing group
· ADR, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: NO
No
· Special precautions for user Warning: Corrosive substances
· EMS Number: F-A,S-B
· Segregation groups Alkalis
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: NA
On cargo aircraft only: NA
· ADR
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN2735, Amines, liquid, corrosive, n.o.s. (Isophoronediamine), 8, III

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
100-51-6 Benzyl alcohol
(Contd. on page 9)
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(Contd. of page 8)
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with 3-
aminomethyl-3,5,5-trimethylcyclohexylamine
· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P260 Do not breathe dusts or mists.
P280 Wear protective gloves.
P280 Wear protective gloves / protective clothing.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
(Contd. on page 10)
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(Contd. of page 9)
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: Corporate Product Safety & REACH
· Contact:
Contact Person : Mr. A. Venkaiah
E-Mail : <product_safety@atul.co.in>
Phone : +91 (0)2632 230473
Mob. No : +91 9687369677
· Date of preparation / last revision 06/13/2015 / 1
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
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