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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: Lapox® K-41
· 1.2 Relevant identified uses of the substance or mixture and uses advised against Curing agent for epoxy resin
· Application of the substance / the mixture Curing agent for epoxy resin
· 1.3 Details of the supplier of the safety data sheet
Atul Europe Limited
1 | B Dean Row Court
Summer fields Village Centre,
Dean Row Road
Wilmslow SK92TB, Cheshire
United Kingdom.
Tel : + 44(0) 1625 539209
· Manufacturer/Supplier:
Atul Ltd
Polymers Business
Atul 396 020
Gujarat, India
Contact: +91 2632 230473
Web site: www.atul.co.in
· Further information obtainable from:
Corporate Product Safety & REACH
product_safety@atul.co.in
· 1.4 Emergency telephone number:
During normal opening times: 0044 (0)1625 539209 ( in Europe)
+91 (0)2632 230473, +91 9687369677 ( in Non-Europe)

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
According to Commisision Regulation(EU)2015/830

GHS08 health hazard

Muta. 2 H341 Suspected of causing genetic defects.

Carc. 1A H350 May cause cancer.
Repr. 1B H360Df May damage the unborn child. Suspected of damaging fertility.
STOT SE 1 H370 Causes damage to organs.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS09 environment

Aquatic Acute 1 H400 Very toxic to aquatic life.

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

GHS07

(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 1)
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
According to Commisision Regulation(EU)2015/830
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS07 GHS08 GHS09

· Signal word Danger

· Hazard-determining components of labelling:
4,4' diamino diphenyl methane
dibutyl phthalate
· Hazard statements
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360Df May damage the unborn child. Suspected of damaging fertility.
H370 Causes damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P321 Specific treatment (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: No data available
· vPvB: No data available

SECTION 3: Composition/information on ingredients

· Description: Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 2)
· Dangerous components:
CAS: 84-74-2 dibutyl phthalate 25-50%
EINECS: 201-557-4 Repr. 1B, H360Df; Aquatic Acute 1, H400
Index number: 607-318-00-4
CAS: 101-77-9 4,4' diamino diphenyl methane 25-50%
EINECS: 202-974-4 Muta. 2, H341; Carc. 1A, H350; STOT SE 1, H370; STOT RE 2, H373; Aquatic
Index number: 612-051-00-1 Chronic 2, H411; Skin Sens. 1, H317
· SVHC
[101-77-9] 4,4'-diamino diphenyl methane
84-74-2 dibutyl phthalate
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the
accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
Fire fighters to wear self-contained breathing apparatus and suitable protective
clothing if risk of exposure to vapour or products of combustion.
· Protective equipment:
Wear self-contained respiratory protective device.
Mouth respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Keep people at a distance and stay on the windward side.
Mount respiratory protective device.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 3)
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Keep away from heat and direct sunlight.
Do not get in eyes, on skin or clothing.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Conditions of Storage: Keep tightly closed. Store in a cool dry place.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) Curing agent for epoxy resins. Used for chemical resistant coatings, grout and linings.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-
contained respiratory protective device.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 4)
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical
mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can
not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
Form: Liquid
Colour: Brown
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Alkaline
· Change in condition
Melting point/Melting range: No data available
Boiling point/Boiling range: 245 °C
· Flash point: 121 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 390 °C
· Decomposition temperature: No data available
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: 0,1 Vol %
Upper: 2,0 Vol %
· Vapour pressure at 20 °C: 0,1 hPa
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 5)

· Density at 20 °C: 1,1 g/cm³

· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): No data available
· Viscosity:
Dynamic at 25 °C: 3800-5800 mPas (ASTM D 2196)
· Solvent content:
Organic solvents: 0,0 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions Reacts with epoxy functional compounds with exothermic reaction liberation of fumes.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidising agents, Strong acids, epoxy functional compounds
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity
Harmful if swallowed.
· LD/LC50 values relevant for classification:
84-74-2 dibutyl phthalate
Oral LD50 8000 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
101-77-9 4,4' diamino diphenyl methane
Oral LD50 662 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation
May cause an allergic skin reaction.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity
Suspected of causing genetic defects.
· Carcinogenicity
May cause cancer.
· Reproductive toxicity
May damage the unborn child. Suspected of damaging fertility.
· STOT-single exposure
Causes damage to organs.
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 6)
· STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark:
Very toxic for fish
Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Toxic for aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: No data available
· vPvB: No data available
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN2810
· 14.2 UN proper shipping name
· ADR 2810 TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-
DIAMINODIPHENYLMETHANE, dibutyl phthalate),
ENVIRONMENTALLY HAZARDOUS
· IMDG TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-
DIAMINODIPHENYLMETHANE, dibutyl phthalate), MARINE
POLLUTANT
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 7)

· IATA TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-

DIAMINODIPHENYLMETHANE, dibutyl phthalate)
· 14.3 Transport hazard class(es)
· ADR, IMDG

· Class 6.1 Toxic substances.

· Label 6.1
· IATA

· Class 6.1 Toxic substances.

· Label 6.1
· 14.4 Packing group
· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Product contains environmentally hazardous substances:
dibutyl phthalate, 4,4' diamino diphenyl methane
· Marine pollutant: YES
Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Toxic substances.
· Danger code (Kemler): 60
· EMS Number: F-A,S-A
· Stowage Category A
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II of Marpol and
the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 2
· Tunnel restriction code E
· IMDG
· Limited quantities (LQ) 5L
(Contd. on page 9)
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Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 8)

· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN 2810 TOXIC LIQUID, ORGANIC, N.O.S. (4,4'-
DIAMINODIPHENYLMETHANE, DIBUTYL PHTHALATE),
6.1, III, ENVIRONMENTALLY HAZARDOUS

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category
H3 STOT SPECIFIC TARGET ORGAN TOXICITY – SINGLE EXPOSURE
E1 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 28, 30, 43, 51b
· National regulations:
· Additional classification according to Decree on Hazardous Materials, Annex II:
Carcinogenic hazardous material group III (dangerous).
· Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can
be made by the authorities in certain cases.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
84-74-2 dibutyl phthalate
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360Df May damage the unborn child. Suspected of damaging fertility.
H370 Causes damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing SDS: Corporate Product Safety & REACH
· Contact:
Contact Person : Mr. A. Venkaiah
E-Mail : <product_safety@atul.co.in>
(Contd. on page 10)
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Safety data sheet
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Printing date 03.11.2016 Version number 2 Revision: 03.11.2016

Trade name: Lapox® K-41

(Contd. of page 9)
Phone : +91 (0)2632 230473
Mob. No : +91 9687369677
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity – Category 4
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 2: Germ cell mutagenicity – Category 2
Carc. 1A: Carcinogenicity – Category 1A
Carc. 1A: Carcinogenicity – Category 1A
Repr. 1B: Reproductive toxicity – Category 1B
STOT SE 1: Specific target organ toxicity (single exposure) – Category 1
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
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