Re Soooo

® P6A-19
(AIOT-1)
(JEE MAIN PATTERN)
CODE TARGET : JEE (MAIN)
1
COURSE : ALL INDIA TEST SERIES (VIKALP) | CLASS : XII/XIII
Time (le;) : 3 Hours (?k.Vs) Maximum Marks (vf/kdre vad) : 300
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
(Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose).
INSTRUCTIONS TO CANDIDATES
Question paper has three (03) parts: Physics, Chemistry ç'u&i=k eas rhu (03) Hkkx gS % (HkkSfrdh ] jlk;u foKku ,oa
and Mathematics.
xf.kr)
Each part has a total twenty five (25) questions divided çR;sd Hkkx esa dqy iPphl (25) iz'u gS tks nks (02) [kaMks esa
into two (02) sections (Section-1 and Section-2). foHkkftr gS ¼[kaM 1 vkSj [kaM 2)
Total number of questions in Question paper are Seventy iz'u&i=k esa ç'uksa dh dqy la[;k % fipgÙkj (75) ,oa vf/kdre
Five (75) and Maximum Marks are Three Hundred only vad % rhu lkS (300) gSaA
(300).
ç'uksa ds çdkj vkSj ewY;kadu ;kstuk,¡ (Type of Questions and Marking Schemes)
[kaM–1 ¼vf/kdre vad : 80½ | SECTION-1 (Maximum Marks : 80)
This section contains TWENTY (20) questions bl [kaM esa chl (20) iz'u gSaA
Each question has FOUR options (1), (2), (3) and (4) izR;sd iz'u esa pkj fodYi (1), (2), (3) rFkk (4) gSaA bu pkj
ONLY ONE of these four option is correct) fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 Marking scheme:  vadu ;kstuk
 Full Marks : +4 If the corresponding to the
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
answer is darkened
 Zero Marks : 0 If none of the options is chosen  'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS
(i.e. the question is unanswered). ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 Negative Marks : –1 In all other cases.  _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
[kaM–2 ¼vf/kdre vad : 20½ | SECTION – 2 : (Maximum Marks : 20)

This section contains FIVE (05) questions. The answer to bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed
each question is NUMERICAL VALUE with two digit eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad rFkk
integer and decimal upto one digit.
n'keyo ,dy vadu eas gSA
If the numerical value has more than two decimal places ;fn laa[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS] rks la[;kRed eku dks
truncate/round-off the value to ONE decimal placed. n'keyo ds ,d LFkku rd VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 Marking scheme  vadu ;kstuk
 Full Marks : +4 If the corresponding to the
answer is darkened
 Zero Marks : 0 If none of the options is  'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS
chosen (i.e. the question is ¼vFkkZr~ iz'u vuqÙkfjr gS½A
unanswered).
ijh{kkFkhZ dk uke : ………………………………………………………………jksy uEcj : ………………………..…………………

eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk eSusa ijh{kkFkhZ dk ifjp;] uke vkSj jksy uEcj
vo'; ikyu d:¡xk@d:¡xhA dks iwjh rjg tk¡p fy;k gSA
------------------------ ------------------------
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj
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vkWfIVdy fjLikal 'khV (ORS) Hkjus ds funsZ’'k (INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
Darken the appropriate bubbles on the original by applying Åijh ewy i`"B ds vuq:i cqycqyksa (BUBBLES) dks i;kZIr ncko
sufficient pressure. Mkydj dkyk djsaA
The original is machine-gradable and will be collected by the ewy i`"B e'khu&tk¡p gS rFkk ;g ijh{kk ds lekiu ij fujh{kd ds
invigilator at the end of the examination. }kjk ,d=k dj fy;k tk;sxkA
Do not tamper with or mutilate the ORS. vks-vkj-,l- dks gsj&Qsj@fod`fr u djsaA
Write your name, roll number and the name of  the viuk uke] jksy ua- vkSj ijh{kk dsanz dk uke ewy i`"B esa fn, x,
examination centre and sign with pen in the space provided [kkuksa esa dye ls Hkjsa vkSj vius gLRkk{kj djsaA buesa ls dksbZ Hkh
for this purpose on the original. Do not write any of these
details anywhere else. Darken the appropriate bubble
tkudkjh dgha vkSj u fy[ksaA jksy uEcj ds gj vad ds uhps vuq:i
under each digit of your roll number. cqycqys dks dkyk djsaA
ij cqycqyksa dks dkyk djus dh fof/k % (DARKENING THE BUBBLES ON THE ORS) :
ORS
Use a BLACK BALL POINT to darken the bubbles in the Åijh ewy i`"B ds cqycqyksa dks dkys ckWy ikbUV dye ls dkyk
upper sheet. djsaA
Darken the bubble COMPLETELY. cqycqys dks iw.kZ :i ls dkyk djsaA
Darken the bubble ONLY if you are sure of the answer. cqycqyksa dks rHkh dkyk djsa tc vkidk mÙkj fuf'pr gksA
cqycqyksa dks dkyk djus dk mi;qDr rjhdk ;gk¡ n'kkZ;k x;k gS %
The correct way of darkening a bubble is as shown here :
There is NO way to erase or "un-darkened bubble. dkys fd;s gq;s cqycqys dks feVkus dk dksbZ rjhdk ugha gSA
The marking scheme given at the beginning of each section
 gj [k.M ds izkjEHk esa nh x;h vadu ;kstuk esa dkys fd;s x;s rFkk dkys
gives details of how darkened and not darkened bubbles
are evaluated.
u fd;s x;s cqycqyksa dks ewY;kafdr djus dk rjhdk fn;k x;k gSA.
For example, if answer ‘SINGLE DIGIT’ integer type below : mnkgj.k ds fy, , ;fn mÙkj ‘,dy vadh;’ iw.kkZad gS rc :
0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
For example, if answer ‘DOUBLEDIGIT’ integer type below : mnkgj.k ds fy, , ;fn mÙkj ‘f)&vadh;’ iw.kkZad gS rc :
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE : n'keyo iw.kkZad@la[;kRed vadksa ds fy, ORS fuEu çdkj gS :
COLUMN COLUMN
1 2 . 3 4 1 2 . 3 4
0 0 0 0 0 0 0 0
1 1 1 1 1 1 1 1
2 2 2 2 2 2 2 2
3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4
5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9
If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in ;fn mÙkj 3.7 gS rc 3 dks 1st ;k 2nd dkWye esa Hkjsa rFkk 7 dks 3rd
3rd or 4th column. ;k 4th dkWye esa HkjsaA
column ‘0’ in 3rd ;fn mÙkj 3.07 gS rks 3 dks 1 dkWye ;k 2 dkWye esa Hkjsa rFkk ‘0’
st nd
If answer is 3.07 then fill 3 in 1 st or 2nd
column and 7 in 4th column. dks 3 dkWye esa rFkk 7 dks 4 dkWye esa HkjsaA
rd th
If answer is, 23 then fill 2 & 3 in 1 st and 2nd column ;fn mÙkj 23 gS rc 2 dks 1st dkWye esa ] 3 dks 2nd dkWye esa tcfd
respectively, while you can either leave column 3 & 4 or fill rd
3 vkSj 4th dkWye dks [kkyh NksM+ nsa ;k ‘'kwU; Hkj nsaA
‘0’ in either of them.
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PART-A
SECTION – 1 : (Maximum Marks : 80)
 This section contains TWENTY (20) questions.
 Each question has FOUR options (1), (2), (3) and (4) ONLY ONE of these four option is correct
 Marking scheme :
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 1 : (vf/kdre vad : 80)
 bl [kaM esa chl (20) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (1), (2), (3) rFkk (4) gSaA bu pkjksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 vadu ;kstuk :
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
1. Slab A is resting on a frictionless floor. Its mass is 35 kg. Another block of mass 7 kg is resting on it as
shown in the diagram. The co-efficient of static friction between the block and slab is 0.5, while kinetic
friction is 0.4. If a force of F N is applied to m 2 : (g = 10 m s 2)
ifêdk A ?k"kZ.kghu Q'kZ ij fojke ij j[kh gSA bldk nzO;eku 35 kg gS] ,d vU; CykWd tks 7 kg dk gS dks ifêdk ds
Åij fp=kkuqlkj j[kk tkrk gSA CykWd rFkk ifêdk ds e/; LFkSfrd ?k"kZ.k xq.kkad 0.5 gS tcfd xfrd ?k"kZ.k xq.kkad
0.4 gSA ;fn CykWd m2 ij F U;wVu dk cy yxk fn;k tk, rks : (g = 10 m s 2)
The minimum value of force to cause m 2 to move with respect to m 1 is:

m1 ds lkis{k m2 dh xfr gksus ds fy, cy dk U;wure eku D;k gksxk &
(1) 72 N (2) 42 N (3) 35 N (4) none dksbZ ugha
2. In Fraunhofer diffraction due to a narrow slit a screen is placed 2 m away from the lens to obtain the
pattern. If the slit width is 0.2 mm and the first minima are 5 mm on either maximum, The wavelength of
light is
lafd.kZ fNnz ds dkj.k ÝkugkQj foorZu esa foorZu izfr:i izkIr djus ds fy,] ,d inkZ ysal ls 2 m dh nwjh j[kk gSA
;fn fLyV dh pkSM+kbZ 0.2 mm gS] rFkk mPpfp"B ds fdlh Hkh vksj izFke fuEufu"B 5 mm gSA rc izdk'k dh rjaxnS/;Z
gksxhA
(1) 2000 Å (2) 3000 Å (3) 4000 Å (4) 5000 Å
3. In the figure shown a ball rolls without sliding. On a horizontal surface, it ascends a curved track upto
height h and returns. Value of h is h1 for sufficiently rough curved track to avoid sliding and h 2 for
smooth curved track, then: (Assume speed of centre of mass of ball to be same in both cases)
fn[kk;s x;s fp=k esa] ,d xsan fcuk fQlys yq<+drh gS ¼{kSfrt /kjkry ij½A ;g ,d oØh; iFk ij h Å¡pkbZ rd p<+rh
gS fQj okil uhps vkrh gSA h dk eku i;kZIr [kqjnjs oØh; iFk ¼ljdus ls cpus ds fy,½ ds fy, h1 gS rFkk fpdus
oØh; iFk ds fy, h2 gS rks (ekfu;sa fd xssUn dk nzO;eku dsUnz nksuksa fLFkfr;ksa esa leku gSA)
(1) h1 = h2 (2) h1 < h2 (3) h1 > h2 (4) h2 = 2 h1
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4. A metre stick swinging in vertical plane about an fixed horizontal axis passing through its one end
undergoes small oscillation of frequency f 0. If the bottom half of the stick were cut off, then its new
frequency of small oscillation would become :
,d fLFkj {kSfrt v{k ds lkis{k Å/okZ/kj ry esa >wy jgh ,d ehVj NM+ f0 vko`fÙk ls NksVs nksyu fp=kkuqlkj djrh gSA
vxj NM+ dk uhps dk vk/kk Hkkx dkV fn;k tk, rks NksVs nksyuksa dh u;h vko`fÙk D;k gksxh&
(1) f0 (2) 2 f0 (3) 2f0 (4) 2 2 f0
5. A refrigerator removes heat from a freezing chamber at –5ºC and discharges it at 95ºC. What is its
maximum coefficient of performance ?
,d jsfÝtjsVj –5ºC ij 'khryd d{k ls Å"ek vo'kksf"kr djds 95ºC ij Å"ek dks R;kxrk gSA bldk vf/kdre
dk;Z xq.kkad gksxkA
(1) 3.75 (2) 2.68 (3) 0.27 (4) 1.75
6. A capillary tube with very thin walls is held vertical and is attached to an end of a light horiozontal rod
which is pivoted at its midpoint. A mass is suspended through the other end to keep the rod in
horizontal position. Now the lower end of the capillary tube is just brought in contact with the surface of
water. An additional mass 0.157 g is attached to the other end to keep the rod in horizontal position.
What is the radius of the capillary tube ? Surface tension of the water is 0.075 N/m. Contact angle
between tube and water is 0º.
,d iryh nhokjks okyh ds'k ufydk e/; fcUnq ij fdyfdr gYdh NM+ ds ,d fljs ij Å/okZ/kj :Ik ls tqM+h gqbZ gSA
NM+ ds nqljs fljs ij ,d nzO;eku bl izdkj j[kk tkrk gS] fd NM+ {kSfrt voLFkk esa jgsA vc ds'kuyh dk uhpyk
fljk ty dh lrg ds lEidZ esa yk;k tkrk gS rFkk ,d vfrfjDr nzO;eku 0.157 g dks nwljs fljs ij tksM+k tkrk gS
rkfd NM+ {kSfrt voLFkk esa jgsA ds'kufydk dh f=kT;k fdruh gSA ty dk i`"B ruko 0.075 N/m gS rFkk ty o
ufydk ds e/; lEidZ dks.k 0º gSA
(1) 3.3 mm (2) 6.6 mm (3) 9.9 mm (4) 1.1 mm
7. A horizontal tube, open at both ends contains a column of liquid. The length of this liquid column does
not change with temperature. If  = co-efficient of volume expansion of liquid and  = coefficient of
linear expansion of the material of the tube. Then
nksuks fljks ij [kqyh {kSfrt ufydk fdlh nzo dk LrEHk j[krh gSA bl LrEHk dh yEckbZ rkieku ds lkFk ifjofrZr
ugh gksrh gSA ;fn vk;ru izlkj xq.kkad o js[kh; izlkj xq.kkad gS rks
(1)  =  (2)  = 2 (3)  = 3 (4)  = 0
8. A coal based thermal power plant producing electricity operates between the temperatures 27ºC and
227ºC. The plant works at 80% of its maximum theoretical efficiency. Complete burring of 1 kg of coal
yields 3600 KJ of heat. A house needs 10 units of electricity each day. Coal used for supplying the
amount of energy for the house in one year is
,d dkW;ys ij vk/kkfjr rkih; 'kfDr IykaV rkieku 27ºC rFkk 227ºC ds e/; /kkjk mRiUu djrk gSA Iykad viuh
vf/kdre lS)kfUrd {kerk dk 80% dk;Z djrk gSA ;gk¡ 1 kg dks;ys ds iw.kZ tyus ij 3600 KJ Å"ek mRiUu gksrh
gSA ;fn ,d ?kj dks 10 bdkbZ /kkjk dh izfrfnu vko';drk gSA rc ?kj dks ,d o"kZ rd ÅtkZ nsus esa fdrus dks;ys
dh vko';drk gksxh
(1) 1141 kg (2) 580 kg (3) 605 kg (4) 765 kg
9. Moment of inertia of a uniform solid cone about an axis passing through its centre of gravity and parallel
to its base is(m is mass of cone, its height is h and its radius R = h)
,dleku Bksl 'kadq dk blds nzO;eku dsUnz ls xqtjus okyh rFkk blds vk/kkj ds lekUrj] v{k ds lkis{k tM+Ro
vk?kw.kZ ('kadq dk nzO;eku m gS rFkk bldh Å¡pkbZ h rFkk f=kT;k R = h gS) Kkr djks&
10 3 3 3
(1) MR2 (2) MR2 (3) MR2 (4) MR2
3 5 10 16
10. During the propagation of electromagnetic waves in a medium :
(1) Electric energy density is double of the magnetic energy density.
(2) Electric energy density is half of the magnetic energy density.
(3) Electric energy density is equal to the magnetic energy density.
(4) Both electric and magnetic energy densities are zero.
,d ek/;e esa fo|qr pqEcdh; rjaxksa ds lapj.k ds nkSjku %
(1) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo dk nqxquk gSA
(2) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo dk vk/kk gSA
(3) fo|qrh; ÅtkZ ?kuRo pqEcdh; ÅtkZ ?kuRo ds cjkcj gSA
(4) nksuksa fo|qrh; ,oa pqEcdh; ÅtkZ /kuRo 'kwU; gSA
11. In the given figure the fixed pulley is smooth and light where as movable pulley is rough and has some
mass. There is no slipping between the pulley and the string. Then magnitude of acceleration of the
point P on the movable pulley is. (If block is moving with an acceleration a)
fp=kkuqlkj fLFkj f?kjuh gYdh rFkk fpduh gS rFkk xfreku f?kjuh [kqjnjh gS rFkk dqN nzO;eku gSA f?kjuh rFkk jLlh
esa dksbZ fQlyu ugh gS rks P fcUnq ds Roj.k dk ifjek.k gS % (;fn CykWd a Roj.k ls xfr djrk gS)
P
a a
(1) a (2) (3) 2a (4)
2 2
12. A slightly tapering wire of length  and end radii 'a' and 'b' is subjected to tension F. Y is the Young's
Modulus. The extension produced in the wire is.
,d FkksM+s Vsifjx rkj ftldh yEckbZ rFkk fljks dh f=kT;k;s 'a' rFkk 'b' gS] ij F ruko yxk;k tkrk gSA Y ;ax
xq.kkad gSA rkj esa mRiUu izlkj gksxkA
F F ab F ab F a  b
(1) (2) (3) (4)
Yab Y a  b2 2 Y a  b Y a 2  b 2
13. A non conducting ring of radius 4 cm has varying linear charge density which is given by  = 3cos c/m.
The net electric dipole moment of the ring is given by
4 cm f=kT;k dh vpkyd oy; ij ifjofrZ js[kh; vkos'k ?kuRo  = 3cos c/m gS rks oy; dk dqy f}/kqzo vk?kw.kZ
gksxkA

–4 –4
(1) 48 Cm (2) 12 × 10 Cm (3) 12 Cm (4) 48 × 10 Cm
14. From ideal instruments current measured is I = 10.0 A, potential difference measured is V = 100.0 volt,
length of wire is 31.4 cm and diameter of wire is 2.00 mm. The resistivity of wire will be (in correct
significant figures) ( = 3.14)
fdlh vknZ'k midj.kks ls ekih xbZ /kkjk I = 10.0 A, foHkokUrj V = 100.0 oksYV, rkj dh yEckbZ 31.4 cm rFkk rkj
dk O;kl 2.00 mm. gS rks rkj dh izfrjks/kdrk gksxh (lgh lkFkZd vadks esas) ( = 3.14)
–4 –4 –4 –4
(1) 1.00 × 10  m (2) 1.0 × 10  m (3) 1 × 10  m (4) 1.000 × 10  m
15. Initially spring is compressed by distance x0 from equilibrium position. At this compression block is
3K
given velocity v = x0. So that the compression in the spring increases and block start SHM (Spring
m
constant K). Equation of motion of block is.
3K
izkjEHk esa fLizax ewy yEckbZ ls x0 lihfM+r gSA bl laihMu ij CykWd dks v = x0 osx fn;k tkrk gS rkfd Lizhax es
m
laihMu c<s rFkk CykWd ljy vkoZr xfr djsa (fLizax fu;rkad K) CykWd dh xfr dh lehdj.k gSA
v
K
x0
 K   K 
(1) y = y  3x 0 sin t  (2) y  2x 0 sin t 
 m 3  m 6 
  
 K   K 
(3) y  3x 0 sin t  (4) y  2x 0 sin t 
 m 6  m 3 
  
16. The frequency of sonometer wire is f, but when the weight producing the tension is completely
f
immersed in water the frequency becomes and on immersing the weight in a certain liquid the
2
f
frequency becomes . The specific gravity of liquid is.
3
f
lksuksehVj rkj dh vko`fr f gS ijUrq ruko mRiUu djus okys Hkkj dks iw.kZ:Ik ls ty esa Mqcksus ij vko`fr gks tkrh
2
f
gS] fdlh vksj nzo esa Hkkj dks Mqcksus ij vko`fr gks tkrh gS rks bl nzo dk fof'k"V xq:Ro gS
3
4 10 15 32
(1) (2) (3) (4)
3 9 12 27
17. The combination of the gates in figure produces

fp=k es iznf'kZr }kjks dk la;kstu mRiUu djsxk %
A
(1) AND gate }kj (2) XOR gate }kj (3) NOR gate }kj (4) NAND gate }kj
18. A parent radioactive nucleus A (decay constant A) converts into a radioactive nucleus B of decay
constant B. Initially number of nuclei of B is zero. At any time NA and NB are number of atoms of
nuclide A and B respectively then maximum value of NB is.
,d jsfM;ks lfØ; ukfHkd A ({k; fu;rkad A), jsfM;kslfØ; ukfHkd B ({k; fu;rkad B) es {kf;r gksrk gSA B ds
izkjfEHkd ukfHkdks dh la[;k 'kwU; gSA ;fn NA o NB, A rFkk B ds ukfHkdks dh fdlh le; la[;k gS rks NB dk
vf/kdre eku gS %
(1)
 ANA
(2)
 BN A
(3)
 A  B NB (4)
B
NA
B A B  A  B
19. When the light of wavelength 400 nm is incident on a metal surface of work function 2.3 eV
2+ + rd
photoelectrons are emitted. A fastest photoelectron combines with a He ion to form He ion in its 3
excited state and a photon is emitted in this process. Then the energy of the photon emitted during
2+
combination is. (Assume energy of He to be zero)
tc 400 nm rjax nS/;Z dk izdk'k 2.3 eV dk;ZQyu okys /kkrq lrg ij vkifrr gksrk gS rks izdk'k bysDVªkWu ckgj
fudyrs gSA ,d lcls rst izdk'k bysDVªkWu He2+ vk;u ls tqM dj He+ vk;u cukrk gS tks rhljh mrsftr voLFkk
es gksrk gS rFkk ,d QksVksu bl izfØ;k es fudyrk gS] rks QksVksu dh ÅtkZ tks feyus ds nkSjku fudyrk gS] gksxh
2+
(He dh ÅtkZ 'kqU; ekus)
(1) 4.2 eV (2) 5.7 eV (3) 6.5 eV (4) 6.8 eV
20. A particle moves along x-axis in positive direction. Its acceleration 'a' is given as a = cx + d, where x
denotes the x-coordinate of particle, c and d are positive constants. For velocity-position graph of
particle to be of type as shown in figure, the value of speed of particle at x = 0 should be.
x-v{k ds vuqfn'k /kukRed fn'kk esa xfr djrs gq;s ,d d.k ds fy, Roj.k 'a' fn;k tkrk gS a = cx + d tgk¡ x d.k
dk x-funsZ'kkad iznf'kZr djrk gS] c rFkk d /kukRed fu;rkad gSA osx&foLFkkiu xzkQ fn[kk;s x;s fp=kkuqlkj gksus ds
fy, x = 0 ij d.k dh pky dk eku gksuk pkfg, &
4d2 d2 2d2 8d2

(1) (2) (3) (4)
c c c c

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value to ONE decimal
placed.
 Zero Marks : 0 In all other cases
[kaM 2 ¼vf/kdre vad% 20)

 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh; iw.kkZad
rFkk n'keyo ,dy&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA
21. Inside a uniformly charged infinitely long cylinder of radius R and volume charge density . There is a
R
spherical cavity of radius . A point P is located at a distance 2R from the axis of the cylinder as
2
xR
shown. The electric field strength at the point P is , where value of x is :
54 0
R
R f=kT;k ds le:Ik vkosf'kr vkos'k ?kuRo okys vuUr csyu ds vUnj f=kT;k dh xksykdkj xqfgdk gSA
2
xR
fp=kkuqlkj ,d fcUnq P csyu dh v{k ls 2R nwjh ij gSA P fcUnq ij fo|qr {kS=k gS rks x dk eku gSA
54 0
R/2 R
P
O
22. An open rectangular tank of height 3m and length and width respectively 5m and 3m contains water
upto height 2m. It is accelerated horizontaly along the longer side. The acceleration that tank can be
108 2 2
given so that 10% of water spills out is (in m/s ), then the value of N is : (g = 10 m/s )
N
,d [kqys vk;rkdkj VSad es ftldh ÅpkbZ 3m o 5m gS] 2m dh ÅpkbZ rd ty Hkjk gSA ;fn ;g yEch Hkqtk ds
108 2
vuqfn'k Rofjr gksrk gSA Roj.k dk eku (m/s esa) gS] ftlds fy, 10% ty ckgj vk tkrk gS] rks N dk eku gS:
N
2
(g = 10 m/s )
23. In the circuit shown, the switch 'S' is closed at t = 0, then current through the battery after steady state
126
is reached is Ampere, where value of x is :
x
fn[kk;s x, fp=k esa t = 0 ij dqWth S dks pkyq dj fn;k tkrk gS rks LFkkbZ voLFkk ds Ik'pkr~ cSVjh ls izokfgr /kkjk
126
,Eih;j gS] tgkW x dk eku gS :
x
4 2 1F
2F 4 5mH
6 3
24V
24. A source of sound is moving along a circular orbit of radius 3 m with angular velocity of 10 rad/s. A
sound detector located far away from the source is executing SHM along the line BD with amplitude
5
BC = CD = 6 m. The frequency of oscillation of the detector is per second. The source is at the point

A when detector is at the point B. If the source emits a sound of frequency 340 Hz. If the minimum
frequency recorded by the detector (velocity of sound = 330 m/s) is 10 x (in Hz) then value of x is :
,d /ofu L=kksr 3 m dh f=kT;k ds o`r ij 10 rad/s ds dks.kh; osx ls ?kwe jgk gSA ,d /ofu lalqpd tks BD js[kk ds
vuqfn'k ljy vkoZrxfr dj jgk gS] ftlds fy, BC = CD = 6 m vk;ke gS] cgqr nwj j[kk gqvk gSA lalqpd dh
5
vko`fr izfr lsd.M gSA L=kksr A fcUnq ij gS tc lalqpd B ij gSA ;fn L=kksr dh vko`fr 340 Hz gS rks lalqpd

}kjk izsf{kr dh xbZ U;qure vko`fr 10 x (Hz esa) gS rks x dk eku gS % (/ofu dk osx = 330 m/s)
A
B C D
25. A uniform rod of length L and mass M is placed on a smooth horizontal surface. The rod is hinged at
the end A and is free to rotate in horizontal plane about a vertical axis passing through A. As shown in
L
figure there is a nail N at a perpendicular distance from end A of rod. At t = 0 and impulse P0 is
4
3L
applied at a distance from end A. The impulse is in the horizontal plane and is perpendicular to the
4
8ML
rod. At t  , the rod returns to its initial position. If the impulse of the force exerted by the nail on
27P0
390P0
the rod is , then value of x is
x
,d L yEckbZ o M nzO;eku dh le:Ik NM+ {kSfrt fpduh lrg ij j[kh gSA NM+ ,d fljs ij A fcUnq ij fdyfdr
3L
gS rFkk A ls xqtjus okyh Å/okZ/kj v{k ds lkis{k ?kweus ds fy, LorU=k gSA fp=kkuqlkj A fljs ls yEcor~ nwjh ij
4
8ML
,d vkosx P0 yxk;k tkrk gSA vkosx {kSfrt o NM+ ds yEcor~ gSA t  ij NM+ iqu% izkjfEHkd fLFkfr ij vk
27P0
390P0
tkrh gSA ;fn fdy }kjk NM+ ij yxk;s x, cy dk vkosx gS rks x dk eku gSS
x
N
L/4
A 3L/4 P0
PART – B (Hkkx – B)
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]


 vadu ;kstuk :
26. Decomposition of A follows first order kinetics by the following equation.


4A(g)  B(g) + 2C(g)
If initially, total pressure was 800 mm of Hg and after 10 minutes it is found to be 650 mm
of Hg. What is half-life of A ? (Assume only A is present initially)
A dk fo;kstu fuEu lehdj.k }kjk izFke dksfV dh cyxfrdh dk ikyu djrk gSA

4A(g)  B(g) + 2C(g)
;fn izkjEHk esa] dqy nkc 800 mm Hg ik;k x;k rFkk 10 feuV i'pkr~ ;g 650 mm Hg ik;k x;kA A dh
v)Z&vk;q D;k gS ? ¼ekuk fd izkjEHk esa dsoy A mifLFkr gSa½
(1) 10 minute ¼feuV½ (2) 5 minute ¼feuV½
(3) 7.5 minute ¼feuV½ (4) None of these (buesa ls dksbZ ugha)
27. Identify the correct order of wavelength of light absorbed by the following complex ions.
fuEu ladqy vk;uksa ds }kjk vo'kksf"kr çdk'k dh rjaxnS/;Z dk lgh Øe igpkfu,A
[Co(H2O)6]3+ ; Co(CN)6]3– ; [Co(F)6]3– ; [Co(en)3]3+
I II III IV
(1) III > I > IV > II (2) II > IV > I > III
(3) III > I > II > IV (4) None of these (buesa ls dksbZ ugha)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
®
C01JRAIOT115122020C1-1
28. The incorrect statement amongs the following is :
(1) beryllium oxide is amphoteric in nature
(2) solubility of sulphates of second group elements decreases down the group
(3) reducing power of hydride of alkali metal decreases down the group
(4) berylium has diagonal relationship with alumunium
fuEu esa ls xyr dFku gS &
(1) csjhfy;e vkWDlkbM mHk;/kehZ izd`fr dk gksrk gSA
(2) f}rh; oxZ ds rRoksa ds lYQsVksa dh foys;rk oxZ esa uhps dh vksj ?kVrh gSA
(3) {kkjh; /kkrqvksa ds gkbMªkbM dh vipk;d {kerk oxZ esa uhps dh vksj ?kVrh gS
(4) csfjfy;e] ,Y;qfefu;e ds lkFk fod.kZ laca/k j[krk gSA
29. Mn2  S2O82  H2O X  SO24  H

The magnetic moment (spin only) of [X] is :
[X] dk pqEcdh; vk?kw.kZ ¼dsoy pØ.k½ gS &
(1) 0 (2) 3 BM (3) 15 BM (4) 24 BM
30. The graph of compressibility factor (Z) v/s P for 1 mol of a real gas is shown in following diagram.
 dZ   1 
The graph is plotted at 273 K temperature. If slope of graph at very high pressure   is  
 dP   2.8 
–1
atm then calculate volume of 1 mol of real gas molecules in (L/mol).
23 22.4 –1 –1
[Given NA = 6× 10 and R = L atm K mol ]
273
,d eksy okLrfod xSl ds fy, lEihM~;rk xq.kkad (Z) rFkk P ds e/; xzkQ fuEu vkjs[k esa n'kkZ;k x;k gSA 273
rki ij xzkQ vkysf[kr fd;k x;k gSA ;fn vfr mPp nkc ij xzkQ dk <+ky 
dZ   1  –1
K ,  atm gS] rc 1
 dP   2.8 
eksy okLrfod xSl v.kqvksa dk vk;ru (L/eksy) ifjdfyr dhft,A
22.4 –1 –1
[fn;k x;k gS NA = 6× 1023 rFkk R = L atm K mol ]
273
Z  dZ  1
 dP   2.8 atm
–1
 
1
P
(1) 1 (2) 2 (3) 3 (4) 4
31. Which of the following statements are correct ?

(A) Principle of chromatographic operation is adsorption.
(B) For adsorption : G < O, S < O, H < O
(C) Zeolites are used as catalyst in petrochemical industries during cracking.
(D) In chemical adsorption, multilayer may be formed on adsorbent.
(1) A, B, D (2) B, C (3) A, B, C (4) B, D
®
C01JRAIOT115122020C1-2
fuEu esa ls dkSuls dFku lgh gSa \
(A) o.kZysf[kdh (chromatographic) izØe dk fl)kUr vf/k'kks"k.k gSA
(B) vf/k'kks"k.k ds fy, : G < O, S < O, H < O
(C) ftvksykbV] isVªksfy;e m|ksxksa esa Hkatu (cracking) ds nkSjku mRizsjd ds :i esa iz;qDr gksrk gSA
(D) jklk;fud vf/k'kks"k.k esa] cgqijr vf/k'kks"kd (adsorbent) ij cu ldrh gSA
(1) A, B, D (2) B, C (3) A, B, C (4) B, D
32. In order to refine ‘blister copper' it is melted in furnace and is stirred with green logs of wood. The
purpose is:
(1) to expel the dissolved gases in blister copper
(2) to reduce the metallic oxide impurities with hydrocarbon gases liberated from the wood
. (3) to bring the impurities to surface and oxidize them
(4) to increase the carbon content in the copper
^QQksysnkj dkWij* dks 'kksf/kr djus ds fy, bldks HkV~Vh esa xyk;k tkrk gSa ,oe~ ydM+h ds gjs yV~Bksa ds lkFk
fgyk;k tkrk gaSA bldk m)s'; fuEu gSa&
(1) QQksysnkj dkWij esa ?kqyh xSlksa dks fudkyukA
(2) ydM+h ds yV~Bksa ls fudyus okyh gkbMªksdkcZu xSlksa ds }kjk /kkfRod vkWDlkbM v'kqf);ksa dks vipf;r
djuk
(3) lrg ij v'kqf);ksa dks ykdj vkWDlhd`r djukA
(4) dkWij esa dkcZu vo;o dh o`f) djukA
33. Let the plasma cell wall of shark is a semipermeable membrane. When these cells were kept in a
series of NaCl solution of different concentration at 25°C, these cells remain intact in 0.7% (w/w)
NaCl solution, shrank in more concentrated solution and swelled in dilute solution. What is the
–1
osmotic pressure of the cell cytoplasm at 25°C? Given Kf of water = 1.86 kgmol K and water
freezes from the 0.7% (w/w) salt solution at – 0.418°C. Assume solution is dilute in each case.
(R = 0.08 atm L / mol K)
ekuk 'kkdZ dh IykTek dksf'kdk fHkfÙk ,d v)ZikjxE; f>Yyh gS] tc bu dksf'kdkvksa dks 25°C ij fofHkUu
lkUnzrk ds NaCl foy;u dh Js.kh esa j[krs gSa rks ;s dksf'kdk,sa 0.7% (w/w) NaCl foy;u esa v[kf.Mr jgrh gS]
;s dksf'kdk,¡ vf/kd lkfUnzr foy;u esa fldqM+ tkrh gS rFkk ruq foy;u esa Qwy tkrh gSA 25°C ij dksf'kdk ds
dksf'kdk nzO; (cytoplasm) dk ijklj.k nkc D;k gS \ fn;k gS % ty ds fy, Kf = 1.86 kgmol–1K rFkk
– 0.418°C ij 0.7% (w/w) yo.k ds tyh; foy;u esa ty terk gSA ekuk foy;u izR;sd fLFkfr esa ruq gSA
(R = 0.08 atm L / mol K)
(1) 2.3 atm (2) 4.7 atm (3) 5.3 atm (4) 10.1 atm
34. Bromine water reacts with SO2 to form :

(1) H2O and HBr (2) HBr and S (3) H2SO4 and HBr (4) S and H2O
czksehu ty] SO2 ds lkFk fØ;k dj cukrk gS&
(1) H2O o HBr (2) HBr o S (3) H2SO4 o HBr (4) S o H2O
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C01JRAIOT115122020C1-3
35. For H-atom some spectral lines were observed as shown. (n1 to n5 are successive shells). If 'E'
belongs to visible region, then correct statements for the following transition.
n5
C
n4
D B
n3
A
n2
E
n1
(A) There cannot be any line in UV region (B) B and D lines belongs to Infrared region.
(C) Line having shortest wavelength is A (D) Line having least energy is C
(1) (A), (B) and (C) (2) (A) and (B) (3) (C) and (D) (4)(A), (B), (C) and (D)
H-ijek.kq ds fy, dqN LiSdV~e js[kk;s izsf{kr fd x;h gS og fuEu gS] ¼ n1 ls n5 yxkrkj dks'k gS½A ;fn E n`';
{ks=k ls lEcfU/kr gS] rc fuEu laØe.kks ds fy, lgh dFku gS&
n5
C
n4
D B
n3
A
n2
E
n1
(A) ;gka UV {ks=k esa dksbZ js[kk ugha gSA (B) B rFkk D js[kk;sa] vojdÙk Hkkx ls lEcfU/kr gSA
(C) y/kqre rjax )sX;Z j[kus okyh js[kk A gSA (D) U;wure ÅtkZ j[kus okyh js[kk C gSA
(1) (A), (B) rFkk (C) (2) (A) rFkk (B) (3) (C) rFkk (D) (4)(A), (B), (C) rFkk (D)
36. To prepare a buffer solution of pH = 4.04, amount of Barium acetate to be added to 100 mL of
–
0.1 M acetic acid solution [pKb(CH3COO ) = 9.26] is :
(1) 0.05 mole (2) 0.025 mole (3) 0.1 mole (4) 0.005 mole
pH = 4.04 dk cQj cukus ds fy, 0.1 M ,flfVd vEy ds 100 mL ds lkFk csfj;e ,flVsV dh feyk;h xbZ
ek=kk fuEu gS% [pKb (CH3COO–) = 9.26]
(1) 0.05 eksy (2) 0.025 eksy (3) 0.1 eksy (4) 0.005 eksy
37. When borax is dissolved in water, then :

(1) B(OH)3 is formed only (2) [B(OH)4]– is formed only
(3) both B(OH)3 and [B(OH)4]– are formed (4) [B3O3(OH)4]– is formed only
tc cksjsDl dks ty esa ?kksyk tkrk gS] rc&

(1) dsoy B(OH)3 curk gSA (2) dsoy [B(OH)4]– curk gSA
(3) nksuksa B(OH)3 rFkk [B(OH)4]– curs gSaA (4) dsoy [B3O3(OH)4]– curk gSA
38. In which of the following species, the O–O bond length is expected to be longest ?
fuEu esa ls fdl iztkfr esa] O–O caèk yEckbZ lokZf/kd gksxh \
(1) BaO2 (2) RbO2 (3) O2 (4) O2[PF6]
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C01JRAIOT115122020C1-4
39. An optically active aldotetraose which retains its optical activity with aqueous Br 2 but looses its
optical activity with conc. HNO3 has the following structure :
,d izdkf'kd lfØ; ,YMksVsVªksl ftldh tyh; Br2 ds lkFk vfHkfØ;k djus ij bldh izdkf'kd lfØ;rk
;FkklEHko jgrh gS ysfdu lkUnz HNO3 ds lkFk ;g izdkf'kd lfØ;rk [kks nsrk gSA vr% mijksDr ;kSfxd dh
lajpuk gksxh %
CHO CHO CHO CHO
H OH H OH
(i) H OH (ii) (iii) (iv)
CH2OH CH2OH CH2OH CH2OH
(1) i,ii (2) i,iii (3) ii, iii (4) ii,iv
40. Which of the following is not aromatic cation ?

fuEu esa ls dkSulk ,sjkseSfVd /kuk;u ugha gS\
(1) (2) (3) (4)
41. Which of the following is not correctly matched?
(1) Ethyl 2-methyl-2-phenyl propanoate
(2) 1,1,1-Trichloro-2,2-diphenyl ethane
(3) 6-Ethyl-3,3-dimethyl cyclohex-1-ene
(4) 3-Amino-2-formyl-1, 4-butane dinitrile
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C01JRAIOT115122020C1-5
fuEu esa ls dkSulk lgh lqesfyr ugha gS \
O
(1) ,fFky 2-esfFky-2-Qsfuy izksisukW,V
(2) 1,1,1-VªkbZDyksjks-2,2-MkbZQsfuy ,Fksu
(3) 6-,fFky-3,3-MkbZesfFky lkbDyksgsDl-1-bZu
(4) 3-,ehuks-2-QkWfeZy-1,4-C;wVsu MkbZukbVªkby
42. Which of the following is strongest base?

fuEu esa ls dkSulk izcyre {kkj gS \
H H H H H
N N N N N N N
(1) (2) (3) (4)
N
43. The reductive ozonolysis product of Ph–CH=CH–CH3 can be distinguished with the following
reagents/tests :
(1) Fehling solution (2) Tollen's reagent (3) Lucas reagent (4) 2,4-D.N.P. test
Ph–CH=CH–CH3 vip;h vkstksuhvi?kVu mRikn dks fuEu vfHkdeZd@ijh{k.kks ds }kjk foHksfnr dj ldrs gSA
(1) Qsgfyax foy;u (2) VkWysu vfHkdeZd (3) Y;qdkWl vfHkdeZd (4) 2,4-D.N.P. ijh{k.k
44. The end product of following reaction is
fuEu vfHkfØ;k dk vfUre mRikn gS &
tyh; NaOH ( ty vi?kVu ) 


(2)
(1) (2) (3) (4)
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C01JRAIOT115122020C1-6
45. Which of the following is used as artificial sweetener
(1) Bithionol (2) Norethindrone (3) Alitame (4) Equanil
fuEu esa ls dkSu ÎÑf=ke e/kqje gS\
(1) ckbFkk;ksukWy (2) ukWj,fFkuMªku (3) ,sfyVse (4) bDoSfuy

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with
two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal placed.
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh;
iw.kkZad rFkk n'keyo f)&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
46. The e.m.f. of a cell corresponding to the reaction :

Zn + 2H+ (aq)  Zn2+ (0.1M) + H2(g) (1 bar)
is 0.169 volt at 25ºC. Calculate the pH of the solution at the hydrogen electrode.
E ºZn 2+ /Zn = – 0.76 volt and EHº + /H = 0 (2.303 RT/F = 0.059 V)
2
vfHkfØ;k % Zn + 2H+ (aq)  Zn2+ (0.1M) + H2(g) (1 bar)
ls lacaf/kr lsy dk e.m.f. 25°C ij 0.169 oksYV gS rks gkbMªkstu bysDVªksM ij] foy;u ds pH dh x.kuk
dhft,A
E ºZn 2+ /Zn = – 0.76 oksYV rFkk EHº + /H = 0 (2.303 RT/F = 0.059 V)
2
47. The reaction CH4(g) + Cl2(g)  CH3Cl(g) + HCl(g) has H = –25 kcal. The bond energies of
C–Cl and H–Cl bonds are 84 and 103 kcal respectively. The ratio of bond energies of C–H and Cl–
Cl bonds is x : y. If x : y = 9 : 5, from the given data, what is the bond energy of Cl–Cl bond (in
kcal)?
vfHkfØ;k CH4(g) + Cl2(g)  CH3Cl(g) + HCl(g), H = –25 kcal j[krk gS C–Cl rFkk H–Cl dh ca/k
ÅtkZ;sa Øe'k% 84 rFkk 103 kcal gS C–H rFkk Cl–Cl ca/k dh ca/k ÅtkZ x : y esa gS ;fn x : y = 9 : 5 gS rc fn;s
x;s vkadM+ks ls Cl–Cl ca/k ÅtkZ D;k gS (in kcal) ?
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C01JRAIOT115122020C1-7
48. For given simultaneous reaction :
2
X(s) A(g) + B(s) + C(g) KP1 = 500 atm
2
Y(s) D(g) + A(g) + E(s) KP2 = 2000 atm
Find equilibrium partial pressure of gas D (in atm).

fuEu le{kf.kd lkE; vfHkfØ;kvksa ds fy;s fn;k x;k gS&
2
X(s) A(g) + B(s) + C(g) KP1 = 500 atm
2
Y(s) D(g) + A(g) + E(s) KP2 = 2000 atm
xSl D dk lkE; ij vkaf'kd nkc (atm esa) Kkr dhft;s&
49. Which of the following ethers are not cleaved by HI

fuEu es ls dkSuls bZFkj HI }kjk fonfyr ¼fo[kf.Mr½ ugha gksrs gS\
(P) —O—CH3 (Q) —O—
CH3
O
(R) H3C—C—O—CH2—CH3 (S)
O
CH3
O
(T)
O
2
50. The number of sp carbon atoms present in peptide, Ile-Arg-Pro, is…….
isIVkbM] Ile-Arg-Pro, esa mifLFkr sp2 dkcZu ijek.kqvksa dh la[;k……gSA
®
C01JRAIOT115122020C1-8
PART – C (Hkkx – C)
 vadu ;kstuk :
2 2 2 2
51. A tangent to the circle x + y = 4 intersects the hyperbola x – 2y = 2 at P and Q. If locus of mid
point of PQ is (x – 2y ) = (x + 4y ), then  equal to
2 2 2 2 2
o`Ùk x2 + y2 = 4 dh Li'kZ js[kk] vfrijoy; x2 – 2y2 = 2 dks P vkSj Q ij feyrh gSA ;fn PQ ds e/; fcUnq dk
fcUnqiFk (x2 – 2y2)2 = (x2 + 4y2) gS] rc  cjkcj gS&
(1) 2  (2) 4 (3) 6 (4) 8
52. Let A: (0,  ) B: (–2, 0) and C: (1, 1) then the value of ‘  ’ so A of BAC is obtuse.
ekuk A: (0,  ) rFkk B: (–2, 0) rFkk C: (1, 1) gS rc '' dk eku gS blfy, BAC dk dks.k A vf/kd dks.k
gS&
2
(1) (–1, 2) (2) (2, 3) (3) (–1, 2) –   (4) (–, -1)  (2, )
3
53. An ellipse with major axis 8 and minor axis 6 is drawn such that lines x – 3y + 2 = 0 and
3x + y – 4 = 0 are tangents to it, then locus of its centre is
,d nh?kZo`Ùk ftldh nh?kZv{k 8 rFkk y?kqv{k 6 gS] bl izdkj cuk;k tkrk gS fd js[kk,a x – 3y + 2 = 0 rFkk
3x + y – 4 = 0 bl ij Li'kZ js[kk,a gS blds dsUnz dk fcUnqiFk gS&
(1) x + y – 2x – 2y – 25 = 0 
2 2 2 2
(2) x + y – 4x – 4y – 23 = 0
2 2 2 2
(3) x + y – 2x – 2y – 23 = 0 (4) x + y – 4x – 4y – 25 = 0
54. The lower corner of a leaf in a book is folded over so as to just reach the inner edge of the page.
The fraction of width folded over if area of the folded part is minimum is:
,d iqLrd esa ,d iUus ds fupys dksus dks bl izdkj eksMk trk gS fd og ist ds vkUrfjd fduksj rd igqaprk
gSA eksMs x, Hkkx dk fHkUu :i gksxk tcfd eksMs x, Hkkx dk {ks=kQy U;wure gS -
1 2 3 4
(1) (2) (3) (4)
3 3 4 5
®
C01JRAIOTMAIN115122020C1-1
55. Consider the following statements
p : you want to success
q : you will find a way,
then the negation of ~(p  q) is
(1) you want of success and you find a way
(2) you want of success and you do not find a way
(3) If you want of success then you cannot find a way
(4) If you do not want to succeed then you will find a way
ekukfd fuEu dFku gS&
p : vki lQy gksuk pkgrs gSA
q : vkidks ,d jkg izkIr gksxh
rc ~(p  q) dk udkjkRed dFku gS&
(1) vki lQy gksuk pkgrs gS rFkk vki ,d jkg izkIr djrs gSA
(2) vki lQy gksuk pkgrs gS rFkk vki ,d jkg izkIr ugha djrs gSA
(3) ;fn vki lQy gksuk pkgrs gS rc vki ,d jkg izkIr ugha dj ldrs gSA
(4) ;fn vki lQy gksuk ugha pkgrs gS rc vki ,d jkg izkIr djrs gSA
10 10
m
56. Value of  tan
n 1 m 1
1
n
is:
10 10
m
 tan
n 1 m 1
1
n
dk eku gS -
(1) 20 (2) 100 (3) 50 (4) 25

2 2
57. Area bounded by the curves y = –x + 6x – 5, y = –x + 4x – 3 and y = 3x – 15 is
oØ y = –x2 + 6x – 5, y = –x2 + 4x – 3 vkSj y = 3x – 15 ls ifjc) {ks=kQy gS&
73 73 73
(1) (2) (3) (4) 73
2 3 6
58. If the range of values of 'a' for which the function f : R  R defined by
f(x) = 2sin 2x – 3cos x – (a + a – 7) x + 5, a  R is strictly increasing is [p, q], where p, q   , then
2 2
|p + q| is equal to
;fn a ds ekuksa dk ifjlj ftuds fy, Qyu f : R R tgk¡ f(x) = 2sin 2x –3cos2x – (a2 + a – 7) x + 5,
a  R, fujUrj o/kZeku Qyu] vUrjky [p, q] gS tgk¡ p, q   rc |p + q| cjkcj gS&
(1) 0 (2) 2 (3) 1 (4) 3
59. If H1,H2,H3…H100 are 100 harmonic means between ‘a’ and ‘b’ (a > 0, b > 0) then value of
H1  a H100  b
+ is
H1 – a H100 – b
H1  a H100  b
;fn H1,H2,H3…H100 la[;kvksa 'a' vkSj 'b' (a > 0, b > 0) ds e/; 100 gjkRed ek/; gS rc + dk
H1 – a H100 – b
eku gS -
(1) 100 (2) 50 (3) 200 (4) 25
 2 1 –1
 
60. If A = 0 1 4  , then tr(adj (adj A)) is equal to
0 0 3 
 2 1 –1
 
;fn A = 0 1 4  , rc tr(adj (adj A)) cjkcj gS&
0 0 3 
(1) 18 (2) 24 (3) 36 (4) 48
®
–1 –1
61. Let A is a non – zero matrix of order ‘2’ such that A + adj A = A then determinant of (2A ) is
equal to
ekuk A, ‘2’ Øe dk v'kwU; vkO;wg gS tcfd A + adj A = A–1 rc (2A–1) dk lkjf.kd eku gS -
(1) 2 (2) 4 (3) 1 (4) 8
62. The number of possible arrangements of letters of the word REVISION such that there are exactly
two vowels between E and V is
'kCn REVISION ds v{kjksa ds mu lHkh laHkkfor foU;klkas dh la[;k] ftueas E vkSj V ds e/; Bhd nks Loj gks] gS&
(1) 4320 (2) 480 (3) 600 (4) 720
x  sin 2  y  cos  z
63. The shortest distance between the line   and plane x  2 y  2 z  3 is
8 1 5
p  p  is [p, q] then p + q is   R 
then range of
x  sin  y  cos  z
2
js[kk   vkSj lery x  2 y  2 z  3 ds e/; y?kqre nqjh p  gS rFkk p 
8 1 5
dk ifjlj [p, q] gS rc p + q dk eku gS   R 
(1) 1 (2) 2 (3) 3 (4) 4
64. Unit vectors a, b and c are coplanar, unit vector d is perpendicular to them. If
i  2 j  2k
  
ab  c d   6
o
and angle between a and b is 30 then c can be
bdkbZ lfn'k
a, b vkSj c leryh; gS bdkbZ lfn'k d muds yEcor~ gS ;fn
i  2 j  2k
  
ab  c d 
6
 rFkk a vkSj b ds e/; dks.k 30o gS rc c dk eku gks ldrk gS -
i jk i  2 j  2k 2i  j  k i – 2 j  2k
(1) (2) (3) (4)
3 3 6 6
If , are roots of x – 2px + q = 0 and ,  are roots of x – 2rx + s = 0 where , , , , are in

2 2
65.
arithmetic progression, then s – q =
;fn , lehdj.k x2 – 2px + q = 0 ds ewy gS rFkk ,  lehdj.k x2 – 2rx + s = 0 ds ewy gS] tgk¡ , , ,
, lekUrj Js<h esa gS] rc s – q =
2 2 2 2 2 2 2
(1) r – p (2) r + p (3) p – r (4) pr – p
In a ABC C = 60 , A = 75 . If D is a point on AC such that area of the BAD is 3 times the

o o
66.
area of BCD, then ABD =
ABC esa ;fn C = 60 , A = 75 ;fn D, AC ij ,d fcUnq bl izdkj gS fd BAD dk {ks=kQy] BCD ds
o o
{ks=kQy dk 3 xq.kk gS rc ABD =

   
(1) (2) (3) (4)
6 12 8 15
67. The mean square deviation of a set of n observations x 1, x2 …. xn about –2 and 2 are 18 and 10
respectively then variance of this set of observation is :
n izs{k.k x1, x2 …. xn dk –2 vkSj 2 ds lkis{k ek/; oxZ fopyu Øe'k% 18 vkSj 10 gS rc izs{k.kksa ds bl leqPp;
dk izlj.k gS -
(1) 8 (2) 9 (3) 10 (4) 5
®
2
68. Tangents are drawn from point (0, –3) to the parabola x = 4y then radius of the smallest circle
touching both tangents and directrix of given parabola is.
fcUnq (0, –3) ls ijoy; x2 = 4y ij Li'kZ js[kk,a [khph tkrh gS rc fn, x, ijoy; dh fu;rk vkSj nksuksa Li'kZ
js[kkvksa dks Li'kZ djus okys lcls NksVs o`Ùk dh f=kT;k gS -
(1) 2 / 3 (2) 1 / 3 (3) 1 (4) 1 / 2
69. Let w1 and w2 be the set of words which can be formed using all the letters of the words
"SHREYANSH" and "SANIDHYA" respectively. A set is randomly selected and a word is selected
from it. If the probability that it contains two alike letters together is  p  , p, q  N then the least
q  
value of (q – 3p) is
ekuk w1 rFkk w2 mu 'kCnksa
dk leqPp; gS tks 'kCnksa "SHREYANSH" rFkk "SANIDHYA" ds lHkh v{kjksa dh
lgk;rk ls cuk;k tk ldrk gSA ,d leqPp; ;kn`fPNd pquk tkrk gS rFkk blls ,d 'kCn dks ;kn`fPNd pquk
p
tkrk gSA ;fn blds nks] ,d leku v{kjksa ds lkFk j[kus dh izkf;drk  q  , p, q  N gS] rc (q – 3p) dk
 
U;wure eku gS&
(1) 4 (2) 3 (3) 5 (4) 7
n n-1 n-2
70. If a1, a2, a3 …. an are real numbers and cos + i sin is a root of equation x + a1 x + a2x + ….
an–1x + an = 0 then value of | a1 cos + a2 cos2 + ….. + an cosn| is
(1) greater than 1 (2) less than 1 (3) 1 (4) depends on ‘’
;fn a1, a2, a3 …. an okLrfod la[;k,a gS rFkk cos + i sin lehdj.k xn + a1 xn-1 + a2xn-2 + …. an–1x + an
= 0 dk ,d ewy gS rc | a1 cos + a2 cos2 + ….. + an cosn| dk eku gS -
(1) 1 ls vf/kd (2) 1 ls de (3) 1 (4) ‘’ ij fuHkZj gSA

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with
two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal placed.
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh;
iw.kkZad rFkk n'keyo f)&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd
VªadsV@jkmaM vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
71. Consider f x   x  1  2x    x  3 and gx   sin 1 x  tan1 x . The value of x for which f gx  is

minimum is k sin where k,   N then find k + .

ekukfd f x   x  1  2x    x  3 rFkk gx   sin 1 x  tan1 x gSA ;fn f gx  dk U;wure eku

k sin gS tcfd x =k gS tgk¡ k,   N rc k + dk eku gS&

®
x2 – 1
1
dx + 2  1– x dx is equal to
1
72. The value of x
–1
2
1 0 1 x
x2 – 1
1
dx + 2  1– x dx
1
x
–1
2
1 0 1 x
dk eku cjkcj gS&
x  2 2 y  3 3z  4
73. Distance of point of (–2, 3, –4) from the line   measured parallel to the
3 4 5
plane 4x + 12y – 3z + 1 = 0 is then  is
x  2 2 y  3 3z  4
fcUnq (–2, 3, –4) dh js[kk   ls] lery 4x + 12y – 3z + 1 = 0 ds lekUrj ekih
3 4 5
xbZ nwjh  gS rc  dk eku gS -
74. Let p(x) be a real polynomial of least degree which has a local maximum at x = 2 and a local
1
minimum at x = 4. If p(2) = 8, p(4) = 1 , then p(0) + is
2
ekuk fd p(x) U;wure ?kkr dk og okLrfod cgqin (real polynomial) gS ftldk ,d LFkkuh; mPpre (local
maximum) x = 2 ij gS vkSj ,d LFkkuh; U;wure (local minimum) x = 4 ij gSA ;fn p(2) = 8 vkSj p(4) = 1
1
gS rc p(0) + dk eku gS&
2
75. The number of integral values of p for which the equation 99cos3 – 20sin3 = 20p + 35 will have
a solution is
p ds iw.kk±d ekuksa dh la[;k gksxh ftlds fy, lehdj.k 99cos3 – 20sin3 = 20p + 35 dk ,d gy gS&
®
ANSWER KEY_(Code-1)
1. (2) 2. (4) 3. (3) 4. (2) 5. (2) 6. (1) 7. (2)
8. (1) 9. (4) 10. (3) 11. (4) 12. (1) 13. (4) 14. (1)
15. (2) 16. (4) 17. (4) 18. (1) 19. (1) 20. (2) 21. (12.50)
22. (22.50) 23. (31.50) 24. (25.50) 25. (32.50) 26. (2) 27. (1) 28. (3)
29. (1) 30. (2) 31. (3) 32. (2) 33. (3) 34. (3) 35. (4)
36. (2) 37. (3) 38. (1) 39. (2) `40. (2) 41. (4) 42. (2)
43. (1) 44. (4) 45. (3) 46. (10.50) 47. (57.85) 48. (40.00) 49. (02.00)
50. (04.00) `51. (2) 52. (3) 53. (3) 54. (2) 55. (4) 56. (4)
57. (3) 58. (3) 59. (3) 60. (3) 61. (4) 62. (4) 63. (2)
64. (2) 65. (1) 66. (1) 67. (2) 68. (1) 69. (2) 70. (3)
71. 12.00 72. 00.00 73. 08.50 74. 42.50 75. 10.00
® Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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1.
m2 g 1m
Sol. maximum acceleration of m1 is a1max = 
m1 sec 2
m2 g 1m
m1 dk vf/kdre Roj.k a1max = 
m1 sec 2
F = (m1 + m2) a1max = 42 N
2.
Sol. a sin = 
 sin ~ tan = x/D
ax
= = 5000 Å
D
3.
Sol. If the track is smooth (case A), only translational kinetic energy changes to the gravitational potential
energy.
But, if the track is rough (case B), both translational and rotational kinetic energy changes to potential
energy.
Therefore, potential energy (=mgh) will be more in case B than in case A.
Hence h1 > h2
Hence (3).
;fn Vªsd fpduk gS (fLFkfr A), rks dsoy js[kh; xfrt mtkZ] xq:Roh; fLFkfrt mtkZ esa ifjofrZr gksxh] ;fn Vªsd
[kqjnjk gS (fLFkfr B), rks js[kh; rFkk ?kw.kZu xfrt mtkZ esa fLFkfrt mtkZ esa ifjofrZr gksxh
vr% B esa A dh rqyuk esa ÅtkZ T;knk gksxh (=mgh)
vr% h1 > h2
4.
1 mg
Sol. f0 =
2 
where,  is distance between point of suspension and centre of mass of the body.
Thus, for the stick of length L and mass m :
tgk¡  yVdu fcUnq o nzO;eku dsUnz ds e/; nwjh gSA
vr% NM+ dh yEckbZ L o nzO;eku m ds fy,

L
m.g.
1 2 1 6g
f0 = 2
=
2 (mL /12) 2 L
when bottom half of the stick is cut off
tc NM+ dk fupyk vk/kk fgLlk dkV fn;k tkrk gSA
m L
.g.
f0’ =
1 2 4 = 1  12g = 2 f0 Ans.
2 m (L / 2)2 2 L
2 12
5.
Sol. For a carnot refrigerator, Qe/W = Tc/(Th – Te). Use absolute temperatures then
dkuksZaV jsfÝtjsVj ds fy,] Qe/W = Tc/(Th – Te) ije rki dks iz;qDr djrs gq,A
Qe 5  273 268
= =  2.68
W 95  5 100
6.
Sol. T.2r cos = mg
7.
Sol. V = A × 
AT = AT
 =  = 2
8.
 T 
Sol. Maximum efficiency of engine u =  1  2   100 = 40%
 T 
 1
  overall efficiency = 0.4 x 0.8 = 0.32
Requirement of house in one year
= 10 × 365 units = 3650 kwh = 3650 × 3600 kJ
3650  3600 Input

 input  kJ  coalrequired   1141 kg
0.32 36000
9.
A
Sol.
B
R
M  x2 
AB = 
0
1 2
R .R
.x 2 .dx 
 4
 x2 

3
R
3M  x 4 
= 3 

R 0 4 
 x 4  dx


3M  R5 R5  3
= 3 
  = MR2

R  20 5  4
Applying parallel axis theorem, lekUrj v{k çes; ls
2
 3R  3
 AB = cm +   = 4 MR
2
 4 
3MR 2
cm = Ans.
16
10.
Sol. Both the energy densities are equal.
nksuksa ÅtkZ ?kuRo leku gSaA

11.
Sol.
P a/2
a/2
a
a/2
2
a
=
2R
12.
b
F dr F
Sol. e=  KY
a
r 2
=
Yab
ba
K=

13.
Sol. P=  3R cos d 2R cos 
–4
= 48 × 10 cm
14.
D 2 V (3.14) (2.00  103 )2 100.0
Sol. = = 
4Li 4  (0.314) 10.0
–4
= 1.00 × 10
15.
Sol. 
v =  A2  x2 
 Amplitude vk;ke A = 2x0
16.
Sol. f T
4
0  w
3
32
L  w
27
17.
Sol. Y  AB (NAND gate}kj)
18.
Sol. For maximum vf/kdre ds fy,
BNB = ANA
19.
Sol. E = 3.1 eV
K.E.max = 0.8 eV
EHe  = – 3.4 eV
E = K.E.max – E4
= 4.2 eV
20.
dv
Sol. (Moderate) a= v = cx + d
dx
Let at x = 0 v=u
ekuk x = 0 ij v=u
v x

u
 v dv   (cx  d)dx
0
or v2 = cx2 + 2dx + u2
v shall be linear function of x if cx2 + 2dx + u2 is perfect square
v, ;gk¡ x dk jsf[kd Qyu gksxkA ;fn cx2 + 2dx + u2 ,d iw.kZ oxZ gksA
21.
Ans. 12.50
R R
Sol. E= 
40 540
22.
Ans. 22.50
Sol.
y

5
3–y
5
1 90
× 5 × y × 3 + (3 – y) × 5 × 3 = 5 × 2 × 3 ×
2 100
12
y=
5
y a
tan = =
5 g
24
a =
5
23.
Ans. 31.50
Sol. In steady state
LFkkbZ voLFkk esa
4
6 3
24 V
63
Req = 4 + =6
63

I=  4A
R eq
24.
Ans. 25.50
Sol. Min frequency is recorded when source is at N and detector is at C
tc L=kksr N ij o lalqpd C ij gS rks U;qure vko`fr izkIr gksrh gS
V  V0  330  ( A)det ector 
Fmin = F =   × 340

V  Vs  330  (R)source 
25.
Ans. 32.50
Sol.

P
L/4
0
3L/4 P0
3L M 2
P0  0
4 3

t1 =
20
8ML
t2   t1
27P0

=
2t 2
M 2
P
L
= 0  
4 3
P = 12P0
26.

Sol. 4A(g)  B(g) + 2C(g)
t=0 800 – –
t = 10 minute, 800 – 4p p 2p
800 – p = 650
 p = 150
Pressure of A (A dk nkc) = 200, so (blfy;s)
 2 x t1/2 = 10 minute (t3/4 = 2 × t1/2)
t1/2 = 5 minute
27.
hc
Sol.  corresponds to the wave length of the visible light and  =

The order of ability to produce d-orbital splitting of various ligands :
CO > CN– > NO2– > en > NH3 > H2O > OH– > F– > Cl– > Br– > I–
strong field weak field
ligands ligands
(larger ) (smaller )
hc
Sol.  n`'; çdk'k dh rjaxnS/;Z ls lacaf/kr gS rFkk  =

d-d{kd ds foikVu ds fy, fofHkUu fyxs.Mksa dh {kerk dk Øe gS&
CO > CN– > NO2– > en > NH3 > H2O > OH– > F– > Cl– > Br– > I–
çcy {kS=k nqcZy {kS=k
fyxs.M fyxs.M
(vf/kdre) (U;wure)
28.
Sol. Reducing power of hydride of alkali metal increases down the group
{kkjh; /kkrqvksa ds gkbMªkbM dh vipk;d {kerk oxZ esa uhps dh vksj c<rh gS
29.
Sol.` Mn2  S2O82  H2O MnO4  SO24  H
30.
Pb
Sol. Z=1+ (high pressure) mPp nkc
RT
dZ b 1
= =
dP RT 2.8
RT 22.4 4 3
b= = = 4(NA × r )
2.8 2.8 3
4 3 5.6
(NA × r ) =Volume of 1 mol gas molecules (1 eksy xSl v.kqvksa dk vk;ru½ = =2
3 2.8
31.
Sol. In chemical adsorption, monolayer is formed on adsorbent.
jklk;fud vf/k'kks"k.k esa] ,dyijr vf/k'kks"kd (adsorbent) ij cu ldrh gSA
32.
Sol. In order to refine ‘blister copper' it is melted in furnace and is stirred with green logs of wood. The
purpose is to reduce the metallic oxide impurities with hydrocarbon gases liberated from the wood
^QQksysnkj dkWij* dks 'kksf/kr djus ds fy, bldks HkV~Vh esa xyk;k tkrk gSa ,oe~ ydM+h ds gjs yV~Bksa ds lkFk fgyk;k
tkrk gaSA bldk m)s'; ydM+h ds yV~Bksa ls fudyus okyh gkbMªksdkcZu xSlksa ds }kjk /kkfRod vkWDlkbM v'kqf);ksa dks
vipf;r djuk gSA
33.
Sol: In 0.7% solution no osmosis was there. Here the exerted extra pressure is osmotic pressure.
0.7% foy;u esa ijklj.k ugha gksrkA ;gk¡ vkjksfir vfrfjDr nkc ijklj.k nkc gSA
NaCl Na+ + Cl–
Here van’t Hoff factor i = 1+ (2–1)  = (1 + )
;gk¡ okUVgkWQ xq.kkad i = 1+ (2–1)  = (1 + )
K W 1000
 Tf = f 1 (1  )
M1W2
ΔTf M1W2 0.418  58.5  W2
or, ;k (1 + ) = 
K f W11000 1.86  1000  W1
W2 99.3
as it is 0.7% solution of NaCl  
W1 0.7
W2 99.3
D;ksafd ;g NaCl dk 0.7% foy;u gSA  
W1 0.7
 (1 + ) = 1.86
assuming dilute solution 100 gm H2O = 100 mL H2O
ruq foy;u ekurs gq, 100 gm H2O = 100 mL H2O
(1  )  nRT (1  )W1RT
 V = inRT or ;k  = 
V M1V
1.86  0.7  0.08  298
or ;k  = = 5.30 atm
58.5  0.1
34.
Sol. SO2 + Br2 + 2H2O 2HBr + H2SO4
35.
Sol. E belongs to visible region when n1 = 2 and n2 = 3. B, C and D lines belongs to Infrared region.
E n`'; Hkkx ls lEcfU/kr gS tgka n1 = 2 rFkk n2 = 3. B, C rFkk D vojdÙk Hkkx ls lEcfU/kr gSA
36.
–
Sol. For the buffer solution of CH3COOH & CH3COO
[CH3COOH] (100  0.1)
pH = pKa + log   4.04 = 4.74 + log 
[CH3COO– ] m.moles of CH3COO–
–
  m. moles of CH3COO = 50   moles of (CH3COO)2Ba required = 0.025.
–
gy. CH3COOH o CH3COO ds cQj foy;u ds fy,
[CH3COOH] (100  0.1)
pH = pKa + log   4.04 = 4.74 + log 
[CH3COO– ] CH3COO– ds feyheksy
–
  CH3COO ds feyh eksy = 50   (CH3COO)2Ba ds vko';d eksy = 0.025
37.
—
Sol. [B4O5(OH)4]2– + 5H2O 2B(OH)3 + 2[B(OH)4]
38.
Sol. O22–(M.O.T)1s2 1s2 2s2 2s2 (2p)2 (2p)4(*2p)4
1
Bond order (caèk Øe) (O22–) = (10 – 8) = 1
2
1
Similarly (blh izdkj), Bond order (caèk Øe) (O2–) = (10 – 7) = 1.5
2
1
Similarly (blh izdkj), Bond order (caèk Øe) (O2) = (10 – 6) = 2
2
1
Similarly (blh izdkj), Bond order (caèk Øe) (O2+) = (10 – 5) = 2.5
2
1
( Bond order  )
Bond length
1
( caèk Øe  )
caèk yEckbZ
39.
CHO
H OH
lkUnz HNO3
  
conc.HNO3
Sol.   
H OH
CH2OH
CHO
lkUnz HNO
  
conc.HNO3
   3
CH2OH
40.
Sol. (1), (3) & (4) all are aromatic while (2) is nonaromatic.
(1), (3) & (4) ;s lHkh ,sjksesfVd gSA tcfd (2) ukWu,sjksesfVd gSA
41.
Sol. Correct name is
2-Amino-3-formyl-1, 4-butane dinitrile
lgh uke gSa

2-,ehuks-3-QkWfeZy-1,4-C;wVsu MkbZukbVªkby
42.
H
N N
Sol. has Guanidine like structure.
N
H
N N
;g N
xqokfuMhu tSlh lajpuk j[krk gSA
43.
Sol. The ozonolysis products are Ph–CHO & CH3–CHO. Ph–CHO shows positive test with tollen's reagent &
2,4-D.N.P. while CH3–CHO shows positive tests with fehling solution, tollen's reagent 2,4-D.N.P.
Sol. vkstksuhvi?kVu mRikn Ph–CHO o CH3–CHO gSA Ph–CHO VkWysu vfHkdeZd rFkk 2,4-D.N.P. ds lkFk /kukRed
ijh{k.k n'kkZrk gS tcfd CH3–CHO Qsgfyax foy;u] VkWysu vfHkdeZd 2,4-D.N.P. ds lkFk /kukRed ijh{k.k nsrk gSA
44.
Sol.
CH3CHO + N2 +
Sol. ty vi?kVu 

(2)
CH3CHO + N2 +
45.
Sol. (1) Bithionol is used as antiseptic.
(2) Norethindrone is used as antifertility drug.
(3) Alitame is used as artificial sweetener.
(4) Equanil is used as antidepressant.
Sol. (1) ckbFkk;ksukWy dk iz;ksx iwfrjks/kh dh HkkWfr gksrk gSA
(2) ukWj,fFkuMªku dk iz;ksx izfrtuu{kerk vkS"k/k dh HkkWfr gksrk gSA
(3) ,sfyVse dk iz;ksx Ñf=ke e/kqje dh HkkWfr gksrk gSA
(4) bDoSfuy dk iz;ksx iz'kkard dh HkkWfr gksrk Gsa
46.
Ans. 10.50
Sol. Eºcell lsy = 0.76 volt

Applying nernst equation uuZLV lehdj.k ykxw djus ij
2
0.059 [ Zn ] [PH2 ]
Ecell lsy = Eºcell – log [H ]2
2
(0.1) (1)
0.059
0.169 = 0.76 – log [H ]2
2
0 .1 2  0.59
log  2 =
[H ] 0.059
;k or log 0.1 –log [H+]2 = 20
;k or 2pH = 20 – log 0.1
21
pH = = 10.5
2
47.
Ans. 57.85
Sol. –25 = 36a + 5a – (84 + 27a + 103)
162 = 14a
 a = 11.57
 ECl–Cl = 5 × 11.57 = 57.85 k.cal
48.
Ans. 40.00
Sol. X(s) A(g) + B(s) + C(g)
p1 + p2
Y(s) D(g) + A(g) + E(s)
p2 p2 + p1
(p1 + p2)p1 = 500 ...(i)
(p1 + p2)p2 = 2000 ...(ii)
(i)
eq.
(ii)
p1 1
=  p2 = 4p1
p2 4
pT = (p1 + p2) + p1 + p2
= 10 + 40 + 10 + 40 = 100 atm
p D 100
= = 40 atm
25 25
49.
Ans. 02.00
Sol. (Q) & (T) are not cleaved by HI due to double bond character in C–O bond.
(Q) rFkk (T) HI ds }kjk fonfyr ¼fo[kf.Mr½ ugha gksrs gS D;ksafd C–O ca/k esa vkaf'kd f}cU/k y{k.k gksrk gSA
50.
Ans. 04.00
NH2
NH–C=NH
O (CH2)3 O COOH
Sol. NH2–CH–C–NH–CH––C–N H
CH–CH2–CH3 CH2
CH3
sp2 carbon atoms are represented by C

C sp2 dkcZu ijek.kqvksa dks n'kkZrk gSA
51.
x2 y2 xx1 x2
Sol. Equation of chord of –  1 whose mid point is (x1, y1) is – yy1  1 – y12
2 1 2 2
x2 y2 xx1 x12
thok dk lehdj.k –  1 ftldk e/; fcUnq (x1, y1) gS – yy1  – y12
2 1 2 2
2 2
 It is tangent to circle x + y = 4
 ;g o`Ùk x2 + y2 = 4 dh Li'kZ js[kk gS
 x2 
–  1 – y12 
 2   x2 
2
  – y 2  = 4  x  y 2 
2
 = 2  locusfcUnqiFk 
x12 2   4 
 y12
4
 (x – 2y ) = 4(x + 4y )
2 2 2 2 2
=4
52.
  1
Sol. .  1
2 1
 2   2
 2   2  0
 {1, 2}
A:(0, 
)
(1, 1)C
B:(-2,
0)
Equation of BC
BC dk lehdj.k
1 1
y–1=  x  1    1 
3 3
2

3
53.
Sol. The given two tangents are perpendicular and intersect at (1, 1)
nh xbZ nks Li'kZ js[kk,a yEcor~ gS rFkk (1, 1) ij izfrPNsn djrh gSA
 (1,1) lies on directors circle.
  (1,1) fu;ked o`Ùk ij fLFkr gksxkA
Let (h, k) be the centre of an ellipse
ekuk (h, k) nh?kZo`Ùk dk dsUnz gSA
 (h – 1)2  (k – 1)2 = a2  b2 = 42  32
(x + y) + (y – 1) = 25  
2 2
54.
y
Sol. tan =  y = x tan
x
x cos( -2) + x=
x=
1  cos 2
1 sin  1
A=
2
 A
2 cos  .4.sin 
4
8 sin  .cos 
3
dA  2

1

.  sin 4   3sin 2  .cos 2  
d  
2
8 sin 3  .cos 
 2
=  
 sin 2  . 3cos 2   sin 2  =   60
o
 
2
8 sin 3  cos 
56.
10 10
m
Sol    tan 1
n 1 m 1 n
10 10
n
   tan 1
n 1 m 1 m
10 10
 m n
2    tan 1  tan 1 
n 1 m 1  n m
10 10

2  
n 1 m 1 2
2  50
  25
57.
4 5
Sol.   
A    x  6 x  5  x  4 x  3 dx    x 2  6 x  5  3x  15 dx
2 2

1 4
4 5

   2 x  2  dx    x 2  3x  10 dx 
1 4
5
24   x3 3x 2 
 = x[x –2 x2x ]1  
2 2
  10 x 
 3 2 
1
4
3 1
 9  10  .9  .61
2 3
65 61 73
  
2 3 6
(1,0) (4,0) (5,0)
(4,-3)
58.
 f (x) = 4cos 2x + 3sin 2x – (a + a – 7)  0  x  R
2
Sol.
 – (a + a – 7) + (4 cos 2x + 3 sin 2x)  0  x  R
2
 –(a + a – 7) – 5  0
2
 a + a – 7+ 5  0
2
a +a–20
2
a  [–2, 1]  |p + q| = 1
59.
1 1 1 1 1
Sol. , , ,..... , are in AP lekUrj Js.kh esa gSA
a H1 H 2 Hn b
1 1 1 1
 d  d
H1 a Hn b
a b
H1  Hn 
1  ad 1  bd
H1  a H n  b

H1  a H n  b
a b
a b
=
1  ad  1  bd
a b
a b
1  ad 1  bd
2  ad 2  bd
= 
ad bd
21 1
= 2      2   n  1 2 = 2n
d b a
60.
Sol. |A| = 6
(n–2)
 adj(adj A) = |A| A = |A| A = 6A
 tr(adj(adj A)) = tr(6A) = 6 tr(A) = 6 × 6 = 36
61.
Sol. Pre multiply by A
A ls xq.kk djus ij
A 2  A.adj A  I 2
A 2  A .I 2  I 2
A 2  1  A  I 2
| A |2   A - 1
2
1
A   A - 1  | A |
2
–1
Determinant (2A ) = 8
lkjf.kd (2A – 1) = 8
62.
Sol. E, I, I, O RVSN
CasefLFkfr-1 : E I I V, O, R, S, N = 5! × 2! = 240
CasefLFkfr-1 : E I O V, I, R, S, N = 5! × 2! × 2! = 480
 total dqy = 720
63.
sin 2   2 cos   3
Sol. P  
1 4  4
1
 1  cos 2   2 cos   3
3
1
 cos 2   2 cos   2
3
 cos   1  1
1 2
3
64.
Sol. 
d   ab 
1= |  |1.1.sin 30o
  2
d
  ab
2
 
 a  b    c  d    12 d  c  d 
=  c   c.d  d 
1
2
c i  2 j  2k  i  2 j  2k 
=    c   
2 6  3 
65.
Sol. let ekuk  = a,  = a + d,  = a + 2d,  = a + 3d
  +  = 2p  2a + d = 2p &  +  = 2r  2a + 5d = 2r
 2d = (r – p) & 4a = (5p – r)
 s – q =  –  = (a + 2d)(a + 3d) – (a)(a + d) = 4ad + 6d = r – p
2 2 2
66.
1 3 o
Sol. .c.BD.sin = .a.sin(45 – ) BD
2 2
c 3 sin  45   
o

a sin 
3
3
 cos   sin  
2  2
3 1 sin 
2 2
6 3
  cot   1
 3 1  2
2 3
 cot   1
3 1
cot   3
A
D
 o
45 -
B C
67.
  x  2
2
Sol.
i
 18 ….(1
n
  xi  2
2
 10 ….(2
n
8 xi  xi  1
8
n n
2  xi  4 
2
 xi 2
 28   10
n n
Var = 9
68.
Sol. Let equation of tangents ekuk dh Li'kZ js[kkvksa ds lehdj.k gSA
B
y=-1
A
(0,-3)
2
y = mx – m
–3 = – m  m =
2
3
y= 3x–3
y=– 3x–3
 2 
B:  , 1
 3 
 2 
A:  , 1
 3 
3 2
.a
 4 3
r=   .a
s  3a  6
 
 2 
3 4 2
r=  
6 3 3
69.
Sol.  A : Word selected contains two like letters together
 A : nks leku v{kjksa ds 'kCn dks pquk tkrk gSA
1
E1 : set w1 is selected P(E1) =
2
1
E1 : leqPp; w1 dks pquk tkrk gS P(E1) =
2
1
E2 : set w2 is selected P(E2) =
2
1
E2 : leqPp; w2 dks pquk tkrk gS P(E2) =
2
8! 8!
A  – 7! 8!– 7! 4(8  7!– 7!)
P   = 2! 2! = =
 1
E 9! 9! 9!
2! 2! 4
4  7!  7 7
= =
9  8  7! 18
 A  7! 2 1
P  = = =
 2
E 8! 8 4
2!
A  A  23
P(A) = P(E1). P   + P(E2) . P   =
 E1   E2  72
 (q – 3p) = 3
70.
Sol. Let z = cos + i sin and z is a root of equation

n n-1 n-2
x + a1x + a2 x + …. + an = 0 Hence
= 1/z = cos – i sin is also root of above equation
 1 + a1z + a2 z2 + ………. + an z = 0
n
 Re (1 + a1 z + a2 z + …. an z ) = 0
2 n
 a1 cos + a2 cos 2 + ….. an cosn  = -1

Sol. ekuk z = cos + i sin vkSj z lehdj.k dk ,d ewy gS
n n-1 n-2
x + a1x + a2 x + …. + an = 0
= 1/z = cos – i sin Hkh lehdj.k dk ,d ewy gSA
 1 + a1z + a2 z2 + ………. + an z = 0
n
 Re (1 + a1 z + a2 z + …. an z ) = 0
2 n
 a1 cos + a2 cos 2 + ….. an cosn  = -1

71.
Ans. 12.00

Sol. f x  is minimum at x
2

f x  , x  ij U;wure eku gSA
2

 sin 1 x  tan x 
1
2
1 1
tan x  cos x
 1 x2 
tan 1 x  tan 1  
 x 
 
1 x 2
 x2  2
x
x4  x2 1  0
1  5
x2 
2

x  2 sin 180  2 sin
10
 12 = k  
72.
Ans. 00.00
x2 – 1
1
dx + 2  1– x dx
1
Sol. I= x
0
2
1 0 1– x
= 2  x 2 1– 2 dx + 2  1– x dx
1 2 1
0 x 1 0 1– x 2
1 1 1 1
1 1
= 2  1 dx – 4  dx + 2  dx +  (1– x )
2 –1/ 2
(–2x) dx
0 0 1  x 2
0 1– x 2 0
 
+ 2 [ 1– x ]0
2 1
= 2 – 4× + 2×
4 2
= 2 –  +  + 2[0 – 1] = 0
73.
Ans. 08.50
 4  3 5  4 
Sol. Point m the line p  3  2, , 
 2 3 
Direction Ratios of line join p and (–2, 3, –4)
 4  9 5  8 
 3 , , 
 2 3 
12  6  4  9   5  8  0
31  62  0    2
1 17
Distance  36   36 
4 2
4  3 5  4 
Sol. fcUnq m js[kk p  3  2, , 
 2 3 
p vkSj (–2, 3, –4) dks feykus okyh js[kk ds fnd~ vuqikr gS
 4  9 5  8 
 3 , , 
 2 3 
12  6  4  9   5  8  0
31  62  0    2
1 17
nwjh  36   36 
4 2
74.
Ans. 42.50
Sol. px = (x – 2) (x – 4) = (x2 – 6x + 8)
p(x) = (x3/3 – 3x2 + 8x) + 
75.
Ans. 10.00
Sol. –101  20p + 35  101
– 6.8  p  3.3
 Number of integral values of p is 10
 p ds iw.kk±d ekuksa dh la[;k 10 gSA

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® P6A-19

CODE TARGET : JEE (MAIN)

[kaM–2 ¼vf/kdre vad : 20½ | SECTION – 2 : (Maximum Marks : 20)

ijh{kkFkhZ dk uke : ………………………………………………………………jksy uEcj : ………………………..…………………

Resonance Eduventures Limited

Resonance Eduventures Limited

The minimum value of force to cause m 2 to move with respect to m 1 is:

(1) h1 = h2 (2) h1 < h2 (3) h1 > h2 (4) h2 = 2 h1

(1) f0 (2) 2 f0 (3) 2f0 (4) 2 2 f0

17. The combination of the gates in figure produces

4d2 d2 2d2 8d2

SECTION – 2 : (Maximum Marks : 20)

[kaM 2 ¼vf/kdre vad% 20)

4 2 1F

2F 4 5mH

SECTION – 1 : (Maximum Marks : 80)

[kaM 1 : (vf/kdre vad : 80)

26. Decomposition of A follows first order kinetics by the following equation.

29. Mn2  S2O82  H2O X  SO24  H

31. Which of the following statements are correct ?

34. Bromine water reacts with SO2 to form :

37. When borax is dissolved in water, then :

tc cksjsDl dks ty esa ?kksyk tkrk gS] rc&

CH2OH CH2OH CH2OH CH2OH

(1) i,ii (2) i,iii (3) ii, iii (4) ii,iv

40. Which of the following is not aromatic cation ?

(1) (2) (3) (4)

41. Which of the following is not correctly matched?

(1) Ethyl 2-methyl-2-phenyl propanoate

(2) 1,1,1-Trichloro-2,2-diphenyl ethane

(3) 6-Ethyl-3,3-dimethyl cyclohex-1-ene

(4) 3-Amino-2-formyl-1, 4-butane dinitrile

(1) ,fFky 2-esfFky-2-Qsfuy izksisukW,V

(2) 1,1,1-VªkbZDyksjks-2,2-MkbZQsfuy ,Fksu

(3) 6-,fFky-3,3-MkbZesfFky lkbDyksgsDl-1-bZu

(4) 3-,ehuks-2-QkWfeZy-1,4-C;wVsu MkbZukbVªkby

42. Which of the following is strongest base?

44. The end product of following reaction is

fuEu vfHkfØ;k dk vfUre mRikn gS &

tyh; NaOH ( ty vi?kVu ) 

(1) (2) (3) (4)

SECTION – 2 : (Maximum Marks : 20)

46. The e.m.f. of a cell corresponding to the reaction :

vfHkfØ;k % Zn + 2H+ (aq)  Zn2+ (0.1M) + H2(g) (1 bar)

Find equilibrium partial pressure of gas D (in atm).

xSl D dk lkE; ij vkaf'kd nkc (atm esa) Kkr dhft;s&

49. Which of the following ethers are not cleaved by HI

(P) —O—CH3 (Q) —O—

(1) 20 (2) 100 (3) 50 (4) 25

If , are roots of x – 2px + q = 0 and ,  are roots of x – 2rx + s = 0 where , , , , are in

In a ABC C = 60 , A = 75 . If D is a point on AC such that area of the BAD is 3 times the

{ks=kQy dk 3 xq.kk gS rc ABD =

SECTION – 2 : (Maximum Marks : 20)

vr% NM+ dh yEckbZ L o nzO;eku m ds fy,

when bottom half of the stick is cut off

tc NM+ dk fupyk vk/kk fgLlk dkV fn;k tkrk gSA

  overall efficiency = 0.4 x 0.8 = 0.32

Requirement of house in one year

= 10 × 365 units = 3650 kwh = 3650 × 3600 kJ

3650  3600 Input