CTM1
CTM1
10-08-20_Incoming.SR_CO-SUPER CHAINA_Jee-Adv_CTM-1_SYLLABUS
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Narayana IIT Academy 10-08-20_Sr.IIT_CO-SC/N-C_JEE-MAIN_CTM-1_Q’P
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A student performs an experiment to determine the Young’s modulus of a wire, exactly
2m long, by Searle’s method. In a particular reading, the student measures the extension in
the length of the wire to be 0.8mm with an uncertainty of ±0.05 mm at a load of exactly
1kg. The student also measures the diameter of the wire to be 0.4 mm with a uncertainty
of ±0.01 mm. The Young’s modulus obtained from the reading is [Take g = 9.8 m / s 2
exact].
2) A vernier calipers in which 10 vernier divisions coincide with 9 main scale divisions
3) A screw gauge in which 50 circular scale divisions equal to 1 main scale divisions
(1 msd=1mm)
4) A screw gauge in which 100 circular scale divisions equal to 1 main scale divisions
(1msd=1mm)
3. In a resonance tube experiment a student using a tuning fork vibrating at frequency 800
Hz produces resonance in a resonance column tube. The upper end is open and the lower
end is closed by the water surface which can be changed. Successive resonances are
observed at lengths 9.75 cm, 31.25 cm and 52.75 cm. the approximate speed of sound in air
from this data will be?
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4. The graph between object distance u and image distance v for a lens is given below. The
focal length of the lens is –
+11
+10
+9
10 division u
–9 –10 –11
4 M lg
5. In the determination of young’s modulus Y = by using Searl’s method, a wire of
π ld 2
length L = 2m and diameter 0.5mm is used. For a load of M = 2.5kg an extension of
l = 0.25mm in the length of the wire is observed. Quantities ‘d’ and ‘l’ are measured
using screw gauge and micrometer respectively. They have the same pitch of 0.5mm.
The number of divisions of their circular scale is 100. The contribution to the maximum
possible error of the Y measurement is
1) due to errors in the measurements of ‘d’ and ‘l’ are same
2) due to errors in the measurements of d is twice that due to the error in the
measurement of ‘l’
3) due to the error in the measurement of ‘l’ is twice that due to the error in the
measurement of ‘d’
4) due to the error in the measurement of ‘d’ is four times that the due to the error in the
measurement of ‘l’
6. A student is calculating the thickness of a single sheet of paper. She measures the
thickness of a stack of 80 sheets with vernier calipers, and find the thickness to be 1.27
cm. To calculate the thickness of a single sheet she divides the total thickness of sheets
with number of sheets. Which of the following answer has the correct number of
significant digits?
1) 0.15875 mm 2) 0.159 mm 3) 0.16 mm 4) 0.2 mm
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7. A screw gauge with a pitch of 0.5 mm and a circular scale with 50 divisions is used to
measure the thickness of a thin sheet of Aluminium. Before starting the measurement, it is
found that when the two jaws of the screw gauge are brought in contact, the 45th division
coincides with the main scale line and that the zero of the main scale is barely visible.
What is the thickness of the sheet if the main scale reading is 0.5 mm and the 25th division
coincides the main scale line?
1) 0.75 mm 2) 0.80 mm 3) 0.70 mm 4) 0.50 mm
8. A student measures the time period of 100 oscillations of a simple pendulum four times.
The data set is 90s, 91s, 95s and 92s. If the minimum divisions in the measuring clock is
1s, then the reported mean time should be:
1) 92 ± 2 s 2) 92 ± 5.0 s 3) 92 ± 1.8 s 4) 92 ± 3 s
9. A point object P moves along line AB passing through centre of curvature of concave
mirror as shown in figure. The object velocity is constant and it approaching the centre of
curvature of mirror. For the instant shown in figure the image is formed at I. At this
instant, the image is having velocity along:
1) v1 2) v2 3) v3 4) v4
10. A wire has a mass ( 0.3 ± 0.003) g radius ( 0.5 ± 0.005) mm and length ( 6 ± 0.06 ) cm . The
maximum percentage error in the measurement of its density is
1) 1 % 2) 2 % 3) 3 % 4) 4 %
11. A point source of light S is placed on the axis of a lens of focal length 20 cm as shown. A
screen is placed normal to the axis of lens at a distance x from it. Treat INCORRECT
statement.
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3) Intensity variation at the centre of the screen from (x = 90 cm to x = 100 cm) and (x =
100 cm and x = 110 cm) is same.
4) Radius of the bright circle obtained on the screen is equal to 4/5 cm for x = 20 cm.
12. Two full runs of the circular scale of a screw gauge cover a distance of 1 mm on its main
scale. The total number of divisions on the circular scale is 50. Further it is found that the
screw gauge has a zero error of – 0.03 mm. While measuring the diameter of a thin wire, a
student notes the main scale reading of 3 mm and the number of circular scale divisions in
line with the main scale as 35. The diameter of the wire is
1) 3.38 mm 2) 3.32 mm 3) 3.73 mm 4) 3.67 mm
13. The resistances of two metallic wires are R1 = ( 5 ± 0.2 ) Ω and R2 = (10 ± 0.1) Ω when these
two wires are connected in parallel, the equivalent resistance is found to be 3.3Ω with a
R1 R2
maximum percentage error is Req =
R1 + R2
1) 4 2) 3 3) 5 4) 2
14. One digital watch ‘A’ was showing 1 : 12 : 32 and an old watch ‘B’ not having seconds
hand was showing 1 : 10; at the moment actual time was 1 : 10 : 15.
1) ‘A’ is more precise but less accurate than ‘B’
2) ‘A’ is less precise but more accurate than ‘B’
3) ‘A’ is both more accurate and precise
4) ‘B’ is both more accurate and precise.
15. A student measures the focal length of a convex lens by putting an object pin at a distance
‘u’ from the lens and measuring the distance ‘v’ of the image pin. The graph between ‘u’
and ‘v’ plotted by the student look like
1) 2)
3) 4)
SR.IIT_CO-SC/ N-C Page. No. 5
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16. In a meter bridge circuit as shown, when one more resistance of 100 Ω is connected is
l1
parallel with unknown resistance x, then ratio become 2. If l1 is balance length of the
l2
uniform wire A B, then the value of x must be:
Copper strips
Copper strips
100 Ω x
•
A G Copper
B
•
l1 l2
• strips
E r
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SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. A potential difference of 220 volts is maintained across a 1200 Ω rheostat ( R h ) as
shown in figure. The voltmeter (V) has a resistance of 600 Ω and point C is at one
fourth of the distance from a to b. The reading of voltmeter is '10 x ' V . Find the value of
x.
b
220V c
Rh
V
a
22. The edge of a cube is measured using a vernier calipers. [9 divisions of the main scale
is equal to 10 divisions of vernier scale and 1 main scale division is 1 mm]. The main
scale division reading is 10 and 1 division of vernier scale was found to be coinciding
with the main scale. The mass of the cube is 2.736 g. Calculate the density in g / cm3
upto correct significant figures.
23. The radius of a sphere is 3.05 cm. Its volume using significant figures is
24. A calorimeter of negligible heat capacity contains 100 g waters at 400 C . The water
cools to 350 C in 5 minutes. If the water is now replaced by a liquid of same volume as
that of water at same initial temperature, it cools to 350 C in 2 minutes. Given specific
heats of water and that liquid are 4200 J / kg 0C and 2100 J / kg 0C respectively. Find the
density of the liquid in kg / m3 .
25. If Resistance R1 in resistance box is 300 Ω , then the balanced length is found to be 75.0
cm from end A. The diameter of unknown wire is 1 mm and length of the unknown
wire is 31.4 cm. Find the specific resistance of the unknown wire ( µ Ω − m ) .
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CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. Which is the most stable conformation of 1-chloro – 4 – Methyl cyclo hexane?
H H H H
H H CH3H CH3 H
H 3C H3C Cl Cl
H 3C H3C Cl Cl H 3C H Cl H H3C Cl
H H H H
1) 2) H
H
CH3 Cl Cl Cl
Cl
HH H ClH H H H
CH3 HCH3
3) 4) CH3
27. If pure ( + ) 2 − butanol has a boiling point of 990C & the optical ration of +360 then:
1) A pure ( + ) 2 − butanol will have a boiling point of 990C & optical rotation of -360
2) A racemic ( + / − ) 2 − butanol will have a boiling point of 990C and the optical rotation
of 00
3) A racemic (+/-) -2 butanol wil have a boiling point of 990C and an optical rotation
different
from of 00
4) (-) -2 – butanol will have a boiling point different from 990C and an optical rotation
of -360
28. Select the optically inactive compound among the following
1) 2)
3) 4)
SR.IIT_CO-SC/ N-C Page. No. 8
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29. Which of the following represent identical compounds?
H OHH H H
OH OH
OHH OHH
HO OH
HHO HO
HOH H
HHO HO
HH HH
OH
H OHH OH H
HO OH
HHO HHO
H HH
OH HOOHH OH
HHO HO
HOH H
HHO H
H OHH H H
OH OH
OHH HH
OH OH
OHH HOOHH OH
HHO HO
HOH H
HHO H
30.
COOH OH
CHO
and are
100ºC
32. It is an example of
1) Valence tautomerism 2) Ring-chain tautomerism
3) Lactum – lactim tautomerism 4) Aromatic – Non-aromatic tautomerism
33. Given compound shows which type of isomerism ?
O O
O O
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CH3 CH3 CH3 CH3
CH3 CH3
H OH
H ; HO OHH; HO H
H OH ; HO H
34. 1. A pair of anomers A)
CH
C2H35 H5CH
C2 3
CH H5C2
H C2HO5 OH ; HO 2H55C2 H
O O
CH3 C2HC5 COOHH;5C(–)CH
2 3 CH COOH
CH3 O
C CHCOOH C; (–)CHCOOH
3 CH ; COOH
(–)CH CH COOH
3 3
OH
2. Enolisation B) CH3 C
O COOH ; (–)CHOH
3 CH
OH COOH
OH
O OH
CH3 C CH3 ; O
CH3 C OH
CH2 OH
CH3 O
C CH3 ; CH3 OH CH2
C
CH C CH ; CH3 C CH2
3. Asymmetric synthesis CHH3 C)
CC OH3
CH3 ; CHHO
3 CC 3 H
CH2
H
H C
C OH
OH HO C
H C OH H
H
H C
C OH
OH H CC
HO OH
H O
HO C HHO C; HOOHC H HO C H
HO
H C
C H
OH O ; HO
H CC H
OH O
H C OH H C OH
H C OH H C OH
HO
H C H O ; HO
H C H O
H C
HO C HH C O ; HO C H O
H C OH
CH2OH H C OH
CH2OH
H CH
C 2OH
H C HOHCH
C 2OH
H C OH
CH
CH
CH333 CH3 CH33 CH3
CH CH3CH
CH
CHCl
CH 3 CH
33 CH3
1) 2) 33 3CH3) 4)
3 3
CH
CH
CH CH33 CH3
CH
3
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37. For which the following pairs of compounds are the incorrect notations given?
Ph Ph Ph
Ph N N Ph and Ph N N
N N and N N Ph
PhAnti - azobenzene
Ph Ph Syn - azobenzene Ph
1) AntiN - azobenzene
N and N - azobenzene
Syn N
Ph
H3CAnti - azobenzene CH
Syn3 - azobenzene OH
H33C CH33 OH
C N and C N
H3 C C N andCH3 C NOH
H OH HC
HSynC- acetaldoxime
N OH and HAnti- N
acetaldoxime
2) H Syn - acetaldoxime
OH H Anti- acetaldoxime
Syn -Hacetaldoxime COOH Anti- acetaldoximeH H
H COOH H H
C C C C
H C C COOH
H H C C H COOH
C C H and C C COOH
H and COOH
NH and NH
NH222
Trans-o-aminocinnamic acid NH222
Cis-o-aminocinnamic acid
NH2 NH2
3) Trans-o-aminocinnamic
Trans-o-aminocinnamic acid
acid Cis-o-aminocinnamic
Cis-o-aminocinnamic acid
acid
H3C CH2CH2CH3 ClCH CH
H33C CH22CH22CH33 ClCH222 CH333
H3 C C C CH2CH2CH3 and H C CCH2CH2CH3
C C and C C
H C C CH and BrCH2 C C CH
H CHCH333 BrCH CH CH333
H Z-isomer 3 CH3 2 2 E-isomer 3
4) Z-isomer
Trans isomer Cis E-isomer
isomer
H OH
H HOOH H
HO HH HCH2OH CH2OH
OH III)
OH OH OH IV)
OH OH
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39. Match List I with List II and select the answer from given codes:
List I List II
Structure of the compound Name of geometrical isomer
P. 1. S-cis
Q. 2. Trans
H
H C
H222C
C H
H
H H
H
H CH
CH
CH222
C
C
C C
C
C
C
C
C C
C
C
R. H
H
H CH
CH
CH222 H
H
H CH
CH
CH222 3. Cis
H 2C H H CH2
C C
C C
H CHS.
2 H CH2 4. S-trans
Codes:
P Q R S
1) 2 3 1 4
2) 4 2 3 1
3) 2 3 4 1
4) 3 2 1 4
40. Which species exhibits a plane of symmetry?
COOH COOHCOOH
COOH
CH3 CH3H CH3CH
H3 H H OH OH OH OH
Ph Ph PhPhPh Ph Ph
H H
H H H HCOOH
H COOH
H COOH
COOH
HH HH H
H H H CH
H CHH3 HCH 3
H CH
3 3
HOOC HOOCHOOC
HOOC
H HH H
H HH H OH OH OH OH
1) 2) 3) COOH COOH
COOH4)COOH
COOH COOH
COOH COOH
41. Which one of the following statement(s) is/are true for threo-butane-2,3-diol regarding
their population of different conformers ?
1) The most populated conformer will have the hydroxyl groups of the gauche position
2) The most populated conformer will have the hydroxyl groups at the anti position
3) All staggered conformations will be equally populated
4) Relative populations of different conformers is not predictable
SR.IIT_CO-SC/ N-C Page. No. 12
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42. Which of the following C6 H 4 Br2 is optically active?
Br Br Br Br
Br Br Br Br
Br Br Br Br BrBr Br Br
Br BrBr Br Br Br Br Br
1) Br Br Br 2) Br Br
Br
Br
3)Br 4)
CMe3 CMe
CMe3 3
CMe3
Me3C Me C
Me3C 3 CH3 CH
Me3C CH3 3 CH3 CH3
CH3 CH3
III) IV) CH3
1) III > II > IV > I 2) IV > I > III > II 3) IV > III > II > I 4) III > IV > II > I
Me MeMe Me Me
MeMe Me O – Me
O –OMe
– Me O – Me
(i) OH OHOH (ii)OH O – Me
O –OMe
– Me O(iii)
– Me OH OHOH (iv)
OH
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SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
46. The number of stereocentres in the given molecule given below is x
O
And number of stereogenic centers present in Amygdalin given below is ‘y’ , then the
value of y-x is
OH
HO
O
O O
HO O
HO CN
HO HO
HO
47. A sample of (+) – 2 –chlorpentane has an optical purity of 36% . What % age of this
sample is
(- ) -2-chlorpentane
48. 2 – chloropentane
hv
→ Monochlorination takes place. The mixture of products formed
Cl2
x
is subjected to fractional distillation. Find the value of , where x is the total number of
2
fractions obtained.
49. The compound whose stereo-chemical formula is written below exhibits ‘x’ geometrical
isomers and ‘y’ optical isomers:
H3C H
OH
C=C
Cl CH2– CH2– C– CH3
H
xy
The value of
x+ y
50. How many structures of [F] is possible?
CH3
+
H Br2/CCl4
[F] C4H8Br2
–H2O
}
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MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
51. If [ x ] is greatest integer function, the value of
1 1 1 2 1 3 1 999
2 + 1000 + 2 + 1000 + 2 + 1000 + ....... + 2 + 1000 is
1) (10, ∞ ) (
2) 1010 , ∞
10
) 3) (100, ∞ ) ( 1010
4) 1010 , ∞ )
1
54. The domain of f ( x ) = where {}
. denotes fractional part of the
{sin x} + {sin ( π + x )}
function
π nπ
1) [ 0, π] 2) ( 2n + 1) / n ∈ Z 3) ( 0, π ) 4) R −
/ n ∈ Z
2 2
x
55. If f : [ 0, ∞ ) → R defined by f ( x ) = is
x +1
π π 2π π 2π π π π
1) − , 2) − , 3) − , 4) − ,
3 3 3 3 3 6 6 6
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57. If { x} is fractional part of x and [ x ] is integral part of x and { x + 1} + 2 x = 4 [ x + 1] − 6 the sum
of all values of x is
log 2 ( x + 3)
59. Domain of f ( x ) = is
x 2 + 3x + 2
60. The number of functions defined from f : {1, 2,3, 4,5, 6} → {7,8,9,10} such that the sum
61. f : R → R defined by f ( x ) = 6 x + 6 is
x
63. If S = {a ∈ N , a ≤ 100} and tan 2 x − tan x = a has real roots then the number of distinct
elements of S is ([ x ] is G.I .F )
1) 10 2) 9 3) 50 4) 11
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64. Let f ( x ) = x ( 2 − x ) , 0 ≤ x ≤ 2 . If the domain of ‘f’ is extended over the set R − [ 0, 2] by
f ( x + 2 ) = f ( x ) then ‘f’ is
1) 2 2) 3 3) 1.4 4) 2.5
1) 0 2) n + 1 3) 2n + 1 4) 2n
68. The number of solutions of the equation 2 [ x ] = x + {x} , where [.] denotes G.I.F and {}
.
1) 1 2) 2 3) 3 4) 4
x + 1 if 0 ≤ x < 2
69. If f ( x ) = ( f ( x ))
2
the sum of all real solutions of + x = f ( x ) + x 2 is
x − 4 if x ≥ 2
1) 3 2) 0 3) 2 4) 1
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SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Answer to each
question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
10 + x 200 x
71. e f ( x) = ; −10 < x < 10 and kf 2 = f ( x ) then k=
10 − x x + 100
2
x + 59 f (11)
72. If 3 f ( x ) + 2 f = 10 x + 30 and x ≠ 1 then the value of is
x −1 f (7)
then f ( 0 ) =
1
75. f ( x ) is a polynomial of least degree such that f ( x ) = for x = 1, 2, 3,....9 then f (10 ) =
x
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Sec: SR.IIT_CO-SC CTM-1 Date: 10-08-20
Time: 3HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 2 2 4 3 1 4 2 5 3
6 2 7 2 8 1 9 2 10 4
11 1 12 1 13 2 14 1 15 3
16 2 17 3 18 2 19 1 20 1
CHEMISTRY
26 1 27 2 28 4 29 2 30 3
31 4 32 1 33 3 34 3 35 4
36 2 37 1 38 2 39 3 40 4
41 1 42 3 43 1 44 4 45 1
46 5 47 32 48 3.5 49 1 50 3
MATHEMATICS
51 1 52 2 53 2 54 4 55 3
56 2 57 4 58 2 59 4 60 1
61 3 62 1 63 2 64 2 65 1
66 3 67 4 68 2 69 3 70 2
71 0.5 72 121 73 132 74 -114 75 0.2
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SOLUTIONS
PHYSICS
FL 4 Mgl
1. Y= =
Al π d 2l
M=1.0 kg ( exact). g = 9.8ms −2 (exact)
L=2 m(exact) , 1=0.8 mm = 0.8 × 10 −3 m
∆l = ±0.05mm. d = 0.4mm = 0.4 ×10 −3 m
∆l = ±0.01mm
Substituting the values of M. g, L, d and I in Eq (i) we get
y = 2.0 × 1011 Nm-2
From Eq(1) the proportionate uncertainty in Y is given by
∆ Y ∆M ∆g ∆L 2 ∆L ∆ l
= + + + +
Y M g L d l
Since the value of M, g and L are exact, ∆M = 0 ∆g = 0 and ∆L = 0 , hence
∆Y 2∆d ∆l 2 × 0.01mm 0.05mm
= + = + = 0.05 + 0.0625 = 0.1125
Y d l 0.4mm 0.8mm
∆Y = 0.1125 × Y = 0.1125 × 2.0 × 1011
= 0.225 ×1011 Nm −2
2. Conceptual
nv
3. For the tube open at one end, the resonance frequencies are , where n is a positive odd integer. If
4ℓ
the tuning fork has a frequency f and f1, f2, f3 are the successive lengths of the tube in resonance with
it, we have
nv ( n + 2) v (n + 4) v
= f1 ; = f2 ; = f3
4ℓ 1 4ℓ 2 4ℓ 3
2v v
giving f3 – f2 = f2 – f1 = =
4ν 2ν
By question, f3 – f2 = 52.75 – 31.25 = 21.5 cm
and f2 – f1 = 31.25 – 9.75 = 21.75 cm
v
Thus = 21.50
2ν
v = 2f × 21.50 = 2 × 800 × 0.2150 = 344 m/s
4. We know that in case of a convex lens when object is placed is placed at C', the image is obtained at
C. This situation is represented in the graph by the point corresponding to u = – 10 cm, v = 10 cm.
R
Therefore R=10 ⇒ = 5 cm = f
2
v
10
u –10
Lens formula is
1 1 1 df dv du
= – ⇒ 2 = 2 + 2
f v u f v u
(for maximum error in f)
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df 0 .1 0 .1
⇒ = + ⇒ 25×0.1×2×0.01 =0.05
25 (10) 2 (10) 2
Therefore the focal length = (5.00 ± 0.05) cm
5. Conceptual
1.27
6. = 0.159 .
80
Pitch
7. Least count, LC =
No.of div.on circular scale
0.5 mm
⇒ LC = = 0.01 mm
50
When jaws are closed, the zero error will be
= Main scale reading + (Circular scale reading) (Least count)
= −0.5 mm + ( 45)( 0.01)
Hence, zero error, e = −0.05 mm
When the sheet is placed between the jaws
Measured thickness = 0.5 mm + ( 25 )( 0.01) = 0.75 mm
Hence actual thickness or true reading = observed reading + zero error
8. Measured time period of 100 oscillations are 90 sec, 91 sec, 95 sec and 92 sec.
90 + 91 + 95 + 92
Mean value of time = tm = = 92 sec
4
Absolute error in measurement
∆t1 = tm − t1 = 2sec
∆t2 = tm − t2 = 1sec
∆t3 = tm − t3 = 3sec
∆t4 = tm − t4 = 0sec
2 +1+ 3 + 0
Mean absolute error, ∆tmean = = 1.5sec
4
But the least count of the measuring clock is 1 second, so it cannot measure up to 0.5 second, so we
have to round it off.
So mean error will be 2 seconds.
Hence, mean time is ( 92 ± 2 ) seconds .
9. As the object approaches c, image is also approaching C, so velocity of image is along v ,
Aliter: Let us draw the ray diagram at two very close instants, among one of which is the given instant.
It is clear from the ray diagram that as object moves from P to P1 . The image moves from I to I1 and
hence velocity of image, when object is at P is along V2 .
m
10. Density ρ = 2 .
πr L
∆ρ ∆m ∆r ∆L 0.003 0.005 0.06
∴ × 100 = +2 + × 100 = + 2× + × 100 = 4% .
ρ m r L 0.3 0.5 6
After substituting the values, we get the maximum percentage error in density = 4%.
Hence, the correct option is (4).
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1 1 1 1 1 1 1
11. − = ⇒ ⇒ − = .
v u f v v ( −25 ) 20
1 1 1 1
= − = ⇒ V = 100 cm .
v 20 25 100
From O to I intensity increases and then decreases at x = 90 cm and 110 cm intensity is same (d)
Radius at x = 20 cm is equal to radius of lens.
0.5 mm
12. The least count of screw gauge is = 0.01 mm ;
50
The main scale reading is 3 mm.
The vernier scale reading is 35.
Observed reading = 3 + 0.35 = 3.35.
Zero error = - 0.03
Therefore, the actual diameter of the wire is 3.35 − ( −0.03) = 3.38 mm .
∆RP ∆R ∆R ∆R + ∆R2
13. ×100 = 1 + 2 + 1 ×100 = 3 .
RP R1 R2 R1 + R2
RR
Where RP = 1 2 .
R1 + R2
14. Precision of watch ‘A’ is high but upto known precision of ‘B’ ‘A’ is less accurate.
15. Conceptual
16. wheat stone bridge is in balanced condition
100 x
100 100 + x
So =
ℓ1 ℓ2
ℓ
∵ 1 =2 ⇒ x = 100Ω
ℓ2
17. Vernier constant (Least count)
= Value of 1 M.S.D – Value of 1 V.S.D
18. Conceptual
∆e 0.02
19. δ g = δl + 2 δt ; δe = × 120 = 1% ; δ t = ×100 = 4%
e 0.5
∴δ g = 9%
22 2
2 × ( 0.26 ) × 64
πr R 7
20. ρ= =
l 156
∆ρ 2 × ( 0.02 ) 2 0.1 ∆ρ
= + + , × 100 = 18.57%
ρ 0.26 64 156 ρ
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21.
Equivalent resistance
600 × 300
Req = 900 + = 900 + 200 = 1100 Ω
600 + 300
220 220
i= ⇒V = × 200
1100 1100
V = 40 volt
a 1 mm
22. Least count of vernier calipers = = = 0.1 mm = 0.01 cm
N + 1 10
Side of cube = (10 )(1 mm ) + (1)( LC )
Or a = 10 mm + 0.1 mm
Or a = 10.1 mm
Or a = 1.01 cm
mass m 2.736
ρ= = 3= 3
= 2.65553 g / cm3 = 2.66 g / cm3 .
volume a (1.01)
4 4 3
23. V = π r 3 = × 3.14 ( 3.05 ) = 118.71106 = 119 .
3 3
24. Using average form of Newton’s law of cooling, we use
40 − 35 k 40 + 35
For water = − Ts ….. (i)
5 0.1× 4200 2
40 − 35 k 40 + 35
For liquid = − Ts ….. (ii)
5 m × 2100 2
( ii ) gives 2 = m × 2100 ⇒ m = 2 × 420 = 0.08 kg = 80 g .
(i ) 5 0.1× 4200 5 × 2100
As volume of liquid is same that of water 100 cm3 , then density of liquid is
m 80 × 10−3
P= = −6
= 800 kg / m3 .
V 100 ×10
R l 100 − l 100 − 75
25. ( 250 ) = ⇒ X = R = ( 300 ) = 100 .
X 100 − l l 75
ρl ρl
Now, X = =
A (π d 2 / 4 )
( 22 / 7 ) (10−3 ) (100 )
2
πd2X
ρ= = = 2.5 × 10−4 Ω − m = 250 ×10 −6 Ω − m .
4l ( 4 )( 0.314 )
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CHEMISTRY
26. In trans (1, 4) diequitorial form groups are far apart and oriented in opposite sides.
27. Enantiomer’s possess same boiling point but opposite angle of relation so that racemic mixture passes
zero angle of specific rotation with same boiling point.
28. Optical in activity of ‘O’ is due to plane of symmetry.
29. Compounds I, IV are symmetrical, possess plane of symmetry and meso isomers so that they are
identical.
30. Due to difference in nature of functional groups.
31. Oximes & amides are functional groups.
32. Conceptual
33. Due to difference in nature of alkyl/aryl groups around polyvalent functional groups.
34. Conceptual
35. All the compounds are symmetrical and meso isomers so that they are identical.
36. Compound (IV) is asymmetric due to plane of symmetric.
37. Conceptual
38. Ertthreomer’s are having identical groups oriented same side of chiral carbons.
39. (1, 2) disubstituted cyclohexane isomers with (e,e) groups is trans form where as (a, e) groups is form,
in conjugated diene based on orientation of groups around single bond the geometrical isomers and
defined as S-cis and S-trans isomers.
40. Conceptual
41. Gauche form of butane-2, 3-diol is more stable due to intra molecular hydrogen bond.
42. Compounds A & B are having plane of symmetry where as D is having point of symmetry.
43. (1, 4) diequitorial form is the most stable transform in other cases always the conformer with bulky
group in equatorial orientations is more stable.
44. Alcohols and ethers are functional group isomers to each other.
45. Compounds “F” & “G” are inter convertible by transfer of protons hence they are tautomer’s but not
resonating structure.
46. x = 6, y = 16 ∴y – x = 5
47. Optical purity 36% means it is a mixture of 36% excess of pure (+) form and 64% racemic mxture
therefore resultant is a mixture of 32% (–) form and 65% (+) form.
48.
Cl Cl Cl Cl
Cl2/hv Cl
(1) (4)
*
Cl Cl
(2) Cl
(5)
Cl
Cl
(3)
*
Cl
(3) and (4) are also having their dia stereomers
So that no. of fractions = 7
x 7
∴ = = 3 .5
2 2
xy
49. x=2 y=2 ∴ =1
x+ y
50.
CH3
+
H and
H 2O
H3C OH
Hence x = 3
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MATHS
1 X 1 X
51. 1 ≤ X < 500 ⇒ + = 0 AND 500 ≤ X ≤ 999 ⇒ + = 1.
2 1000 2 1000
52. g ( x ) = x 3 − 3x + 2 ⇒ g1 ( x ) = 3x 2 − 3 = 0
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