Re-Refining of Used Lubricating Oils
Re-Refining of Used Lubricating Oils
Re-Refining of Used Lubricating Oils
A PROJECT REPORT
Submitted by
HARSHAL BABAR
Roll no-01
JAYDEEP TAYADE
Roll no-55
SUMEDH INAMDAR
Roll no-12
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Re-Refining Of Used Lubricating Oils
SE CHEMICAL
MUMBAI UNIVERSITY
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DECLARATION
I declare that this written submission represents my ideas in my own words and
where others' ideas or words have been included, I have adequately cited and
referenced the original sources. I also declare that I have adhered to all
principles of academic honesty and integrity and have not misrepresented or
fabricated or falsified any idea/data/fact/source in my submission. I understand
that any violation of the above will be cause for disciplinary action by the
Institute and can also evoke penal action from the sources which have thus not
been properly cited or from whom proper permission has not been taken when
needed.
: Signature
Harshal Babar
Jaydeep Tayade
Sumedh Inamdar
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ACKNOWLEDGEMENT
Secondly I would also like to thank my parents and friends who helped
me a lot in finalizing this project within the limited time frame.
Jaydeep Tayade
Sumedh Inamdar
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TABLE OF CONTENTS
ABSTRACT
1.1 Background
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b. Future Aspects
REFERENCES
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CHAPTER ONE
INTRODUCTION
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1.1 Background
The term ‘lubricating oil’ refers a wide range of products that are
characterized by hundreds of base chemicals and
additives. Lubricating oils may be either mineral-based or synthetic.
Lubricating oil is a generic name for a wide range of products that are
characterized by hundreds of base chemicals and additives. The most
common lubricating oils are crude oil distillate fractions although both
synthetic and plant-based lubricating oils are used. Lubricating oils are
composed of 80–90% petroleum hydrocarbon distillate with 10–20%
additives to impart specific properties to the oil. The petroleum
hydrocarbon distillate generally consists of paraffinic or naphthenic
compounds.
1. Viscosity
This is one of the most important properties of the oil and used to
grade lubricants. The viscosity of the oil is measure of its fluid
resistance to flow. It should be able to maintain an oil film between the
bearing surfaces for desired load and speed to provide hydrodynamic
lubrication conditions.
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2. Viscosity index
This is the measure of how much the viscosity of an oil changes with
temperature. All the oils don`t become less viscous at the same rate as
the temperature rises.
3. Pour point
The pour point indicates the temperature below which the oil loses its
fluidity and will not flow or circulate in the lubricating system.
1.Anti-Oxidants
Oxidation is the general attack of the weakest components of the base
oil by oxygen in the air. It occurs at all temperatures all of the time but
is accelerated at higher temperatures and by the presence of water,
wear metals and other contaminants.
2.Viscosity Improvers
Viscosity index improvers are very large polymer additives that
partially prevent the oil from thinning out (losing viscosity) as the
temperature increases. These additives are used extensively when
blending multi-grade engine oils.
3.Detergents
Detergents perform two functions. They help to keep hot metal
components free of deposits (clean) and neutralize acids that form in
the oil. Detergents are primarily used in engine oils and are alkaline or
basic in nature.
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CHAPTER TWO
LITERATURE REVIEW
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Fig.1
a. Extraneous Contaminants
Extraneous contaminants are introduced from the surrounding air and by
metallic particles from the engine. Contaminants from the air are dust, dirt,
and moisture. Air itself may be considered as a contaminant since it might
cause foaming of the oil. The contaminants from the engine are:
(1)Metallic particles resulting from wear of the engine,
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The first option in the waste oil management hierarchy is reducing the amount
of Waste oil generated by using efficient engines, improving the quality of
lubricating oil Etc. Second option is re-refining the used oil, which means
upgrading the quality of Used oil so that it can again be used as lubricating oil.
Re-refining is given second Preference because it is environment friendly
practice and results in saving of Valuable foreign exchange. Re-refining is
especially useful in our country as we are Totally dependent on import for
virgin lubricating oil. Third option is reprocessing the used oil so that it can be
used fuel oil. Normally, used oils for use as fuel need to be subjected to
treatments involving settlement to remove sludge and suspended matter.
CHAPTER THREE
PROCESSES OF RE-REFINING
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Fig.2
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1. Dehydration
Dehydration is almost always the first step. The temperature is of the order of
160-180°C at atmospheric pressure. Heat is supplied by steam or heated fluid
through a heat exchanger. The dehydration column is in two sections: in the
lower section, oil is pumped at a high flow rate to avoid formation of deposits
and oil cracking by ensuring a good heat transfer. A part of the oil is injected
at the top of the upper section where dehydration is achieved. This column
helps to eliminate variable amounts of water in the lower section and, finally,
dehydrate the oil in the upper section. The lighter fractions removed at the top
are used as fuels.
2. Acid treatment and clay adsorption
Dehydrated oil is cooled to about 30°C before reacting with sulphuric acid.
Settling time is of the order of 24 h. Decanted oil is mixed with clay before
injection into the high temperature vessel, (high-speed flash boiler), heated at
270°C by a heated fluid to avoid superheating of the oil. During clay
treatment, small acid droplets as well as sulphonic acids and oxidized or
sulphurized products resulting from acid action in suspension are coalesced
and adsorbed. Diesel and spindle oils are removed at the top and the oil at the
bottom is cooled to a maximum of 120°C before filtration. The pressure in the
vessel is 80 mmHg. According to this process, clay consumption is of the
order of 3.5 wt % of the settled oil.
Advantages
1. Acid-Clay process is old and popular. This is a proven technology
worked for many years worldwide. This can be set-up for very small
capacity.
2. Low capital investment makes it most cost effective for small and tiny
scale plants.
3. Non sophisticated, very simple process, simple to operate, no advanced
instruments, low energy input.
Disadvantages
1. Causes Environmental pollution due to generation of acid sludge and
acid gas Emission. Disposal of acid sludge is a problem.
2. Causes corrosion of equipments reducing its life.
3. Gives lower yield, due to loss of oil in sludge as well as clay since
higher Dosage of clay is required.
4. As most of the government has adopted stringent pollution control
regulations, this process is on its way out.
5. Unable to treat modern multi-grade oils
6. Difficult to remove asphaltic impurities.
b. Solvent Extraction
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The solvent extraction technology has the potential to produce oil products
that are superior to those produced by the low-temperature distillation process
currently in use. Figure shown below presents a simplified, conceptual process
flow diagram for the solvent extraction technology. Used oil is mixed in the
reactor column with an aliphatic solvent such as liquefied propane (butane,
heptanes or hexane may also be used). In this unit, the solvent acts selectively,
dissolving the oil fraction and leaving the less soluble impurities. The oil-
laden solvent is transported from the top of the reactor column to the solvent
still (a distillation column) where the solvent fraction is separated from the oil
for recycling within the process. The impurities (bottoms) slowly settle and
coalesce in the bottom of the reactor column where they are pumped to the
bottoms still (a second distillation column). Residual solvent is also separated
in this unit. The recovered solvent is liquefied through a compressor and
cooling system and re-injected into the reactor column through the solvent
recycle tank to repeat the cycle.
Solvent extraction is reported to be well suited for re-refining multi-grade
motor oils formulated with high concentrations of pour point improvers,
viscosity index improvers, and other additives; and containing large amounts
of varnish, gums, and other asphaltic compounds generated by heat and
friction in their use. The solvent removes the mineral portion (phase) of the
Fig.3
Advantages
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Disadvantages
1. Has to operate at higher pressure (10 atm.) at ambient temperature (270
0C) Require high pressure sealing systems (making system expensive and
Complicated).
2. Involves operational solvent losses and highly skilled operating and
Maintenance personnel and system is required.
3. Economical only for high capacity plants.
4. Propane being very hazardous, fire & explosion hazard is associated with
this process.
c. Vacuum Distillation
Fig.4
In this process the used oil is passed through three distillation column viz;
dehydration column, light distillation column, lubricating oil distillation column
after centrifugation. The lube oil distillate is finally treated with 2-3 % clay.
This process involves the following steps:
1. Centrifuging/Filtration
The used oil passed through filters and centrifuge under high centrifugal force to
remove suspended impurities and moisture in the form of sludge and water.
2. Preparation of feed stock
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Sample of used oil is tested in lab and based on this sample the contamination
quality is determined and the process cycle is formulated.
3. Dehydration column
In the dehydration column the used oil is heated at 110° C by circulating thermic
fluid from the boiler which is made to flow in the internal coil.
4. Light distillate column
The dehydrated oil is heated at 250° C in this column. The entire light distillate
content is distilled and converted into vapours.
5. Lube Oil distillation column
The vapours condensed are collected in receiver and heated to the maximum
temperature of 300° to 350° C under 1 Torr vacuum so that the lube oil is
condensed.
6. Bottom Residue Collection
After the entire lube oil distillate is distilled, it leaves behind some residue.
7. Clay finishing/Polishing
The lube distillate oil recovered need partial clay treatment which is around 2 % to
saturate.
8. Filtration
The clay treated oil is then passed through cloth filter pass under pressure where
the Cloth filter of 5 micron filter traps the clay particles.
9. Percolation
In certain oils this process is carried out to make the product odourless and
colorless.
10. Blending
Based on the analysis of base oil, the suitable additive blending is carried out on
the Base oil to get the finished product.
d. Hydrogenation
To avoid formation of harmful products and environmental issues based on above
methods, some modern processes have been used and the best one is
hydrotreating. This method follows vacuum distillation. In this process, the
distillate from vacuum distillation is hydrotreated at high pressure and temperature
in the presence of catalyst for the purpose of removing chlorine, sulphur, nitrogen
and organic components. The treated hydrocarbons resulted in products of
improved odour, chemical properties and colour.
Another important aspect of this method is that, this process has many advantages:
Produces of high Viscosity Index lube oil with well oxidation resistance and a
good stable colour and yet having low or no discards. At the same time, it
consumes bad quality feed. In addition to that, this method has advantage that all
of its hydrocarbon products have good applications and product recovery is high
with no (or very low) disposals. Other hydrocarbon products are: In oil refinery
the light–cuts can be used as fuel in plant itself. Gas oil may be consumed after
being mixed with heating gas oil and the distillation residue can be blended with
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bitumen and consumed as paving asphalt, because it upgrades a lot its rheological
properties. Also, it can be used as a concentrated anti-corrosion liquid coating, for
vehicles frames.
These are advance methods that combines two or more generic methods in its
process. Due to the complex nature of contaminants removal in used lube oils,
using a single method may not give you the desired standard emission-controlled
process. Therefore, some companies have developed specific processes for
treatment and contaminants removal in used lube oils these methods require
sophisticated technologies, equipment and processes. Some of these complex
processes are briefly discussed below.
a. Vaxon Process
This process contains chemical treatment, vacuum distillation and solvent
refining units. The advantage of Vaxon process is the special vacuum
distillation, where the cracking of oil is strongly decreased. The chemical
final stage does not, however allow the high-quality base oils production;
although in Spain the Catalonia refinery produces base stocks accepted by
an original equipment manufacturer (OEM). In connection with this fact,
the lube distillate obtained from Vaxon process (Denmark) or North
Refining (Netherlands) are precursors for Avista Oil base.
b. Ecohuile Process
The re-refining process was based on vacuum distillation and acid-clay
treatment steps until the end of 2000 [51]. Clay adsorption was bannedon 1
January 2001 and the plant was modified and upgraded to the Sotulub
process. Moreover, the addition of injection facilities of so-called Antipoll-
additive (1–3 wt% of pure sodium hydroxide) has been provided and has
allowed solving the following basic problems:
• Corrosion of dehydration column and cracking column top section due to
organic acidity of used oil.
• Plugging of equipment and piping due to polymer formation in cracking
section.
• High losses of base oil in oily clay due to high consumption of clay.
c. Cyclone Process
This process combines the technology of vacuum distillation and
hydrofinishing. The process licence belongs to Kinetic Technology
International (KTI). In this process, used oils taken from storage tanks are
dewatered and the light hydrocarbons are removed by distillation. The
heavier fraction is sent to high vacuum distillation, where the majority of
base oil components are evaporated from the heavy residue. The oils in
residues are extracted with propane in de-asphalting unit and sent to
hydroprocessing unit where other oils are processed. Then they are treated
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with hydrogen and fractionated based on desired base oil features. The re-
refined base oil products obtained are of high quality due to hydrogenation
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CHAPTER FOUR
ECONOMIC AND FUTURE ASPECTS
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of heavy metals makes oil a very hazardous pollutant commodity, such as Zn, Cu, Ni,
Pb, Cr, Cd. These metals are very harmful for environment. Spillage of used oil onto
soil can induce a drastic change in the environment. It ends up in sites where surface
and groundwater may be contaminated. These changes can have an effect on the
biological cycles in soil. In aquatic environments, oil film on water can minimize light
penetration in water and thus reduce the photosynthesis rate. The production of
oxygen is also limited if photosynthesis is reduced. The decline of oxygen dissolved
in water stresses animals that live in water. Also, by means of inhalation, aspiration,
ingestion or skin contact, used oil can induce lipid pneumonia, oil acne, cancer of the
skin and lung cancer in humans. Used lubricating oils are re-refined through a method
that efficiently eliminates pollutants and restores oils to the equivalent of oil extracted
from virgin stocks. As a result, used oil is a pollutant and has the ability to be recycled
safely and by re-refining, thereby minimizing environmental emissions.
4.2 Future Aspects
a. Need for Used Oil Re-Refining
Used oil are one of the greatest source of pollution worldwide mainly because of the
high quantity generated, their high toxicity level and mostly because of their
mismanagement. Well organized waste oil management system will result in positive
economical and environmental impacts.
Future Aspects
The production facilities within the refining industry have become increasingly
diverse; process configuration varies from plant to plant according to its size,
complexity, and product slate. Refining technology has evolved considerably over the
last century in response to stimuli such as increasing demand for gasoline and diesel
fuel as well as fuel oil, higher demand for petrochemicals as building blocks for
clothing and consumer goods, and the need to for more environmentally friendly
processes and products. To cope with changing feedstocks, refinery technology has
had to change. This has caused a movement away from conventional means of
refining heavy feedstocks using (typically) coking technologies, to more innovative
processes that will produce the required liquid fuels from the feedstock and maintain
emissions within the limits of environmental legislation. The main thrust of
development in the refinery layout will be primarily on process modification, with
some new innovations coming on-stream. The industry is likely to be more involved
in deep conversion of heavy feedstocks, have higher hydrocracking and hydrotreating
capacity, and also will use more efficient processes.
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CHAPTER FIVE
ENVIRONMENTAL EFFECTS
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CHAPTER SIX
CONCLUSION AND RECOMMENDATIONS
Conclusion
Mismanagement of use lubricating oil results in severe environmental hazard. Thus, proper
management of used oil is necessary. Re-refining is best alternative among possible
management option of used oil for country like Nepal which solely depends on import of the
lubricating oil.
Rerefining of waste lubricants could result in both environmental and economic benefits.
Rerefining of waste oil to manufacture base oil conserves more energy than reprocessing the
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waste oil for use as fuel. The energy required to manufacture rerefined oil from used oil is
only one-third of the energy required to refine crude oil to produce virgin base oil. Therefore,
rerefining is considered by many as a preferred option in terms of conserving as well as
minimizing waste and reducing damage to the environment.
Currently applied technologies can be compared in terms of their operating and capital costs,
quality of feedstock and products obtained. These advance combine technology processes
and/or methods are mainly found in developed countries but not available in developing
countries. These methods when applied generates reduced concentrations of pollutant but
require complex and expensive equipment which are rarely found in developing countries.
Under increasing environmental pressure of conventional treatment method such as acid-clay
treatment, which was the first oil regeneration process used, it was substituted in majority of
European countries with new technologies based on solvent extraction, pyrolysis, membrane
etc. The modern technologies based on solvent extraction, pyrolysis, membrane etc. are
environmentally controllable but their operating and capital costs are high, low yields and
requires highly skilled personnel (compared to conventional method)is the major drawback.
Also, the challenge of cost reduction resulting from vacuum distillation and hydroprocessing
technique. The combined treatment methods have shown remarkable well with high treatment
efficiency, environmentally friendly. However, the problem of high cost and season skilled
operating personnel remains a major gap in used lube oil treatment. Therefore, there is the
need to developed viable, efficient, environmentally friendly, affordable treatment and high
yield technique such as solvent extraction coupled with adsorption process to remove
contaminants in used lube oil.
Recommendations
Government should bring proper rules and regulations for proper management of used oil as
soon as possible.
Public awareness programs should be launched to make people aware about the harmful
effect of mismanagement of used lubricating oil and to encourage them to use re-refined
lubricating oil.
Collection system should be set up to collect the used lubricating oil.
Study of possibility of used lubricating oil re-refining should be performed for whole country.
Detail design of the plant should be formed.
References
Study on Re-refining of Used Lubricating Oil in Bagmati Zone By Guru Prasad
Chaudhari,Rabin Basnet,Rudra Mani,Ghimire Sudeep and Raj Subedi.
A Review of Methods for Removal of Contaminants in Used Lubricating Oil By K. O.
Boadu1,2,3*, O. F. Joel1, D. K. Essumang2 and B. O. Evbuomwan3.
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