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Mitsubishi Diesel Engine Technical Information: Quality of Water Used As Engine Coolant

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ITEM NO.

T54-0040-E (1/3)
MITSUBISHI DIESEL ENGINE
TECHNICAL INFORMATION DATE December, 1998

Quality of water used as engine coolant

1. The water in service coolant in diesel engine may appear, under visual observation, normal but such
appearance is no insurance that it will not foul up the cooling system. This is because water can contain
may substances, which are not visible but are harmful to the cooling circuit of the engine. Here lies the
reason why the harmful chemical properties and substances need to be identified and their limits of
tolerance be specified.
2. Coolant specifications are tabulated in Table 1.
3. Undesirable coolant quality factors and their effects are shown in Table 2.
4. The specifications (Table 1) are not different in substance from the LESR 3003 Standard-1985.

First Edition : Dec.1998 Engine Engineering Department


Large Engine Design Section
Revision

Approved by Checked by Drawn by

MITSUBISHI HEAVY INDUSTRIES, LTD.


GENERAL MACHINERY & SPECIAL VEHICLE HEADQUATERS
ITEM NO. T54-0040-E (2/3)

Table 1 Coolant Specifications


Main malign effect
Item Chemical Unit Recommended
symbol limit Corrosion Scale
and rust formation

pH (25°C) — — 6.5 to 8.5 ⃝ ⃝

Electrical conductivity — µ /cm < 400 ⃝ ⃝


(25°C)

Total hardness CaCO3 PPM < 100 — ⃝

M alkalinity CaCO3 PPM < 150 — ⃝

Chlorine ion Cl- PPM < 100 ⃝ —

2-
Sulfuric acid ion SO 4 PPM < 100 ⃝ —

Total iron Fe PPM < 1.0 — ⃝

Silica SiO2 PPM < 50 — ⃝

Residue from evaporation — PPM < 400 — ⃝

MITSUBISHI HEAVY INDUSTRIES, LTD.


GENERAL MACHINERY & SPECIAL VEHICLE HEADQUATERS
ITEM NO. T54-0040-E (3/3)

Table 2 Undesirable Coolant Quality Factors and Their Effects

Main malign effect


No. Item Symbol Unit Explanatory note Corrosion Scale
and rust formation
The pH scale (from 0 to 14) refers to
the concentration of hydrogen ions in
aqueous solutions. The solution is
1 pH (25°C) — — neutral if its pH is 7. The pH of 7 is ⃝ ⃝
dividing point between acidic
(corrosive to metals) and basic (scale
forming) property. In pure water, the
pH is 6 to 8.
High conductivity of solution means
Electrical that it contains large amounts of
2 conductivity — µ /cm electrolytic ions and undissolved solid, ⃝ ⃝
(25°C) and that it tends to attack metals and
also to promote scale formation.
Amounts of Ca and Mg ions in the
3 Total hardness CaCO3 PPM solution are expressed in PPM as — ⃝
equivalents of calcium carbonate
(CaCO3). Hard water produces scale.
The alkali contents (hydroxides,
carbonates and bicarbonates) are repre-
4 M alkalinity CaCO3 PPM sented by this term. Their amounts are — ⃝
expressed in PPM as CaCO3. Scale
formation is often caused by high M
alkalinity.
A high Cl concentration makes the
- solution very corrosive. For example,
5 Chlorine ion Cl PPM tap water in Japan has chlorine in an ⃝ —
amount of 10 to 40 PPM.
A high SO 2-
4 concentration attacks
copper and copper alloys. If the
6 Sulfuric acid SO 4
2-
PPM solution contains Ca, SO2 reacts with ⃝ —
ion
Ca2+ to form CaSO4, a substance that
readily gives rise to scale.
Fe in the solution in excess of 3.0 PPM
7 Total iron Fe PPM settles out and turns to coloring deposit. — ⃝
A high Fe concentration contributes to
scale development.
Silica combines with Ca and Mg to
8 Silica SiO2 PPM produce very hard scale. Water — ⃝
moderately hard does not present this
problem.
Undissolved solids, contributory to
conductivity of the solution as stated
Residue from above, remain as solid residue when the
9 — PPM solution is evaporated. The higher this — ⃝
evaporation PPM value, the stronger is the scale
forming tendency (and also the corro-
siveness) of the solution.

MITSUBISHI HEAVY INDUSTRIES, LTD.


GENERAL MACHINERY & SPECIAL VEHICLE HEADQUATERS

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