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    Problem 1A.4

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    NI PUTU AGNES SUARI
    This document discusses calculating the viscosity of gas mixtures using equations 1.4-15 and 1.4-16. It provides data on the viscosities of hydrogen and dichlorodifluoromethane mixtures at different mole fractions. The equations are used to calculate the viscosities at three intermediate compositions, yielding values of 127.2, 131.5, and 135.4 poise, in excellent agreement with the provided data.

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    Problem 1A.4

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    NI PUTU AGNES SUARI
    234 views2 pages
    This document discusses calculating the viscosity of gas mixtures using equations 1.4-15 and 1.4-16. It provides data on the viscosities of hydrogen and dichlorodifluoromethane mixtures at different mole fractions. The equations are used to calculate the viscosities at three intermediate compositions, yielding values of 127.2, 131.5, and 135.4 poise, in excellent agreement with the provided data.

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    BSLTPCh1p1A4

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    This document discusses calculating the viscosity of gas mixtures using equations 1.4-15 and 1.4-16. It provides data on the viscosities of hydrogen and dichlorodifluoromethane mixtures at different mole fractions. The equations are used to calculate the viscosities at three intermediate compositions, yielding values of 127.2, 131.5, and 135.4 poise, in excellent agreement with the provided data.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    234 views2 pages

    Problem 1A.4

    Uploaded by

    NI PUTU AGNES SUARI
    This document discusses calculating the viscosity of gas mixtures using equations 1.4-15 and 1.4-16. It provides data on the viscosities of hydrogen and dichlorodifluoromethane mixtures at different mole fractions. The equations are used to calculate the viscosities at three intermediate compositions, yielding values of 127.2, 131.5, and 135.4 poise, in excellent agreement with the provided data.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    BSL Transport Phenomena 2e Revised: Chapter 1 - Problem 1A.

    4 Page 1 of 2

    Problem 1A.4
    Gas-mixture viscosities at low density. The following data2 are available for the viscosities
    of mixtures of hydrogen and Freon-12 (dichlorodifluoromethane) at 25°C and 1 atm:

    Mole fraction of H2 : 0.00 0.25 0.50 0.75 1.00


    µ × 106 (poise): 124.0 128.1 131.9 135.1 88.4

    Use the viscosities of the pure components to calculate the viscosities at the three intermediate
    compositions by means of Eqs. 1.4-15 and 16.

    Sample answer: At 0.5, µ = 0.01317 cp.

    Solution1

    Eqs. 1.4-15 and 16 in the text are a pair of formulas that allow us to compute the viscosity of a
    mixture with N chemical species.
    N
    X x α µα
    µmix = N
    , (1.4-15)
    α=1
    X
    xβ Φαβ
    β=1

    where Φαβ is
     −1/2 "  1/2  1/4 #2
    1 Mα µα Mβ
    Φαβ =√ 1+ 1+ . (1.4-16)
    8 Mβ µβ Mα
    The gas mixture has two chemical species, dichlorodifluoromethane (CCl2 F2 ) and hydrogen (H2 ).

    Species 1: CCl2 F2 Species 2: H2


    g g
    M1 = 12.01 + 2(35.45) + 2(19.00) = 120.91 M2 = 2(1.008) = 2.016
    mol mol
    µ1 = 124.0 × 10−6 poise µ2 = 88.4 × 10−6 poise

    As a result, Eq. 1.4-15 becomes


    2
    X xα µα
    µmix = 2
    α=1
    X
    xβ Φαβ
    β=1
    x1 µ 1 x2 µ 2
    = 2 + 2
    X X
    xβ Φ1β xβ Φ2β
    β=1 β=1
    x 1 µ1 x 2 µ2
    = + .
    x1 Φ11 + x2 Φ12 x1 Φ21 + x2 Φ22

    1
    Special thanks to GESE on Twitter for pointing out my mistake.
    2
    J. W. Buddenberg and C. R. Wilke, Ind. Eng. Chem. 41, 1345–1347 (1949).

    www.stemjock.com
    BSL Transport Phenomena 2e Revised: Chapter 1 - Problem 1A.4 Page 2 of 2

    Use Eq. 1.4-16 to determine Φ11 , Φ12 , Φ21 , and Φ22 .


    "  #2
    M1 −1/2
     1/2 
    M1 1/4
     
    1 µ1
    Φ11 =√ 1+ 1+ =1
    8 M1 µ1 M1
    "  #2
    M1 −1/2
     1/2 
    M2 1/4
     
    1 µ1
    Φ12 =√ 1+ 1+ ≈ 0.092017
    8 M2 µ2 M1
    "  #2
    M2 −1/2
     1/2 
    M1 1/4
     
    1 µ2
    Φ21 =√ 1+ 1+ ≈ 3.93432
    8 M1 µ1 M2
    "  #2
    M2 −1/2
     1/2 
    M2 1/4
     
    1 µ2
    Φ22 =√ 1+ 1+ =1
    8 M2 µ2 M2

    µmix has to be calculated for three situations: (1) when x1 = 0.75 and x2 = 0.25,

    (0.75)µ1 (0.25)µ2
    µmix = + ≈ 127.2 × 10−6 poise
    (0.75)Φ11 + (0.25)Φ12 (0.75)Φ21 + (0.25)Φ22

    (2) when x1 = 0.50 and x2 = 0.50,

    (0.50)µ1 (0.50)µ2
    µmix = + ≈ 131.5 × 10−6 poise
    (0.50)Φ11 + (0.50)Φ12 (0.50)Φ21 + (0.50)Φ22

    and (3) when x1 = 0.25 and x2 = 0.75.

    (0.25)µ1 (0.75)µ2
    µmix = + ≈ 135.4 × 10−6 poise
    (0.25)Φ11 + (0.75)Φ12 (0.25)Φ21 + (0.75)Φ22

    Therefore,
    Mole fraction of CCl2 F2 (x1 ): 0.75 0.50 0.25
    Mole fraction of H2 (x2 ): 0.25 0.50 0.75
    .
    µmix × 106 (poise): 127.2 131.5 135.4
    µ × 106 (poise): 128.1 131.9 135.1
    These numbers are in excellent agreement with the data.

    www.stemjock.com

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