PV 3942
PV 3942
PV 3942
Issue 2016-08
Class. No.: 55116
Preface
The test results are evaluated as per Volkswagen standard VW 50180, section 5.
The test results are not suitable for the following:
– Making assessments regarding an adverse effect of the emitted substances on the health of
vehicle occupants;
– Serving as the basis for estimating the concentrations that may be found in the vehicle interior
when a vehicle is at a standstill, being driven, or in any state similar to that of vehicle opera‐
tion;
– Establishing correlations to the test methods to be applied as specified in VW 50180 (Test
Specifications PV 3341, PV 3015, PV 3900, and PV 3925) or substituting these material tests.
Previous issues
PV 3942: 2000-12
Changes
The following changes have been made to PV 3942: 2000-12:
– New title
– New technical responsibility
– Standard completely revised
All rights reserved. No part of this document may be provided to third parties or reproduced without the prior consent of one of the Volkswagen Group’s Standards departments.
© Volkswagen Aktiengesellschaft VWNORM-2015-07d
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PV 3942: 2016-08
Contents
Page
1 Scope ......................................................................................................................... 2
2 Designation ................................................................................................................ 3
3 Definitions .................................................................................................................. 3
4 Test method ............................................................................................................... 4
4.1 Basis of the method ................................................................................................... 4
4.2 Emission test bed ....................................................................................................... 4
4.3 DUT chamber ............................................................................................................. 4
4.3.1 General requirements ................................................................................................ 4
4.3.2 Materials ..................................................................................................................... 5
4.3.3 Leak tightness ............................................................................................................ 5
4.3.4 Air mixture .................................................................................................................. 5
4.3.5 Cleaning ..................................................................................................................... 5
4.4 Test space temperature ............................................................................................. 5
4.5 Humidification ............................................................................................................. 5
4.6 Clean air supply ......................................................................................................... 6
4.7 Measurement of total concentration of hydrocarbon compounds .............................. 6
4.8 Flow diagram of the DUT chamber ............................................................................ 6
5 Quality assurance measures ...................................................................................... 7
5.1 General information .................................................................................................... 7
5.2 Leak tightness ............................................................................................................ 7
5.3 Air speed .................................................................................................................... 7
5.4 Supply airflow ............................................................................................................. 7
5.5 Blank values ............................................................................................................... 7
5.6 Temperature and relative humidity ............................................................................. 7
6 DUT ............................................................................................................................ 8
6.1 General notes ............................................................................................................. 8
6.2 Sampling of the DUT .................................................................................................. 8
6.3 Packaging, transport, and storage of the DUT ........................................................... 8
7 Test procedure ........................................................................................................... 9
7.1 General notes ............................................................................................................. 9
7.2 Cleaning of the test space .......................................................................................... 9
7.3 Test .......................................................................................................................... 10
7.3.1 Packaging and storage of the DUTs ........................................................................ 10
7.3.2 Test preparation ....................................................................................................... 10
7.3.3 Insertion of the DUT ................................................................................................. 10
7.3.4 Conditioning phase and sampling ............................................................................ 11
7.3.5 End of the test .......................................................................................................... 12
8 Computation and presentation of the test results ..................................................... 12
9 Inspection report ...................................................................................................... 13
10 Applicable documents .............................................................................................. 13
Appendix A Example laboratory report used to document the test sequence ............................. 15
1 Scope
This standard provides the option of determining the quantity of organic chemical substances
which are released by parts used in the vehicle interior under the described conditions.
A test chamber method for determining volatile organic emissions from parts, components, or
semi-finished products of the vehicle interior is described.
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PV 3942: 2016-08
This standard describes the requirements for a 1-m³ test chamber used to carry out emission tests.
In addition, the procedure for emission testing is described, from preparing the device under test
(DUT) to the end of DUT chamber measurement.
2 Designation
DUT chamber test as per PV 3942
3 Definitions
The following definitions are provided as part of this Test Specification (PV):
Outlet airflow: The airflow escaping the test space through a designated opening
DUT: Semi-finished product, component, or part
Carbonyl: Chemical substance group with a C=O double bond (e.g., formaldehyde,
acetaldehyde)
Emissions: Organic substances escaping from the DUT under the particular test condi‐
tions
FID: Online analyzer with flame ionization detector (detector for organic substan‐
ces)
GC-MS: Gas chromatograph with mass spectrometric detector
HPLC: High-performance liquid chromatograph
Air exchange: Quotient of supply airflow and test space volume (value for air exchange
per time unit)
Air speed: Average speed of the airflow induced by recirculation within the test space,
measured in the center of the test space
Air sample: The extraction of a representative, specified volume of the test space at‐
mosphere
Ideal mixture: In an ideally mixed room, an added substance is distributed completely and
evenly throughout the entire room without a time delay.
Concentration in the The concentration of one or more chemical substances in an air sample,
test chamber: which was sampled at a representative location in the test space, deter‐
mined using a chemical-analytical or physical method
Test space: Chamber that can be sealed in an airtight manner, used to determine vola‐
tile organic emissions under defined climatic conditions
Test space volume: Volume of the test space, minus the volumes of all technical fixtures and
devices being used in the test space
VOC: Volatile organic compound that is emitted from the DUT and detected in the
air at the outlet of the DUT chamber
Supply airflow: Total of all gaseous volumetric flows fed into the test space per time unit
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4 Test method
4.3.2 Materials
The wall surfaces of the test space and the rack used to support the DUT must be made of stain‐
less steel or glass.
For fixtures or parts inside the test space for which neither of the two designated materials can be
used for technical reasons, materials must be selected which have the lowest possible emission
and adsorption of organic substances.
If these parts are in contact with the test space atmosphere, the sum of their surface areas must
not exceed 5% of the test space wall surface area.
4.3.5 Cleaning
A suitable cleaning method (e.g., thermal desorption at high temperatures) must be used to ensure
that thorough cleaning is carried out between the tests. A detailed description can be found in
section 7.2.
The success of cleaning must be verified before the start of a test by means of a blank-value sam‐
ple.
4.5 Humidification
The humidification of the test chamber supply air must be carried out in such a way that precludes
the formation of vapor and aerosols. The humidification unit must enable a relative humidity of 5%
in the supply airflow at 65 °C. This is equivalent to a dew point of 10.4 °C.
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Figure 1 – Flow diagram of a 1-m³ emission test chamber (e.g., VCE 1000 by Vötsch Industrietech‐
nik GmbH, Balingen, Germany; or a technically equivalent product from another manufacturer)
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6 DUT
7 Test procedure
Test space
The test space is first rid of particles or similar residues of the DUTs using mechanical cleaning
methods (e.g., industrial dust remover) or, for stubborn contaminants, using volatile solvents. It
must be ensured that the chamber surface is not damaged or scratched during cleaning.
If the test space is cleaned thermally by heating it up with purge air, a temperature of ≥ 165 °C
must be reached on all surfaces that are in contact with the test space atmosphere. The cleaning
process is finished after the heating temperature has been reached and then 10 air exchanges
have been performed.
If cleaning of the test space surfaces takes place by washing them off with alkaline cleaning
agents, this must be followed by two washing processes using deionized water. Afterward, the test
chamber must be dried at test temperature with a purge airflow.
All parts coming into contact with the test space atmosphere that are not directly integrated in the
cleaning method of the test space must undergo a separate cleaning process that is comparable
from a technical standpoint.
This also applies, in particular, to the sampling lines that are used. If the sampling lines are conta‐
minated, they must be replaced.
7.3 Test
The actual test extends from the unpacking of the DUTs to removal from the DUT chamber after all
conditioning and sampling processes have been completed.
Air sampling
The extraction of air samples must be carried out at a specified point in time for standardized emis‐
sion tests. Therefore, the duration and sequence of the air-sampling processes must always be
kept identical during an air-sampling phase of several constituents being analyzed.
The procedure for air sampling is as specified in ISO 16000-3 and ISO 16000-6. For air sampling
for more extensive analyses, the determination methods applicable in each case must be used.
NOTE 2: The number of simultaneously occurring air sampling processes (including FID) is limi‐
ted by the set air exchange to a maximum of 6 l/min (65 °C, ambient pressure).
9 Inspection report
The inspection report must contain an evaluation of the examined DUTs as per VW 50180, sec‐
tion 5. For this, the test results that were actually determined must be compared with the limits lis‐
ted therein.
In addition, the following information must be included:
– Name and address of the test laboratory
– Name of the person responsible for testing
– Name and address of the purchaser
– Reference to this PV (see section 2)
– Unambiguous designation of the tested DUT for identification purposes
– Detailed description of the DUT
– Weight of the DUT
– Date of manufacture, time of sampling and of packaging
– Details concerning packaging, storage, and transport
– Date of receipt of the DUT and type of packaging in as-received condition
– Any modifications made to the DUT (disassembly, etc.)
– Time, type, and duration of the test and of sampling
– Test parameters (temperature, relative humidity, and air exchange) over the entire test dura‐
tion
– Analysis method used
– Deviations from the test method and irregularities during the test
– Progression of the FID value
– Chromatogram of the GC-MS overview analysis
– Photo documentation of the examined DUT
– Date and signature
It is recommended that most of the details listed above are listed in a laboratory report used to
document the test sequence (see figure A.1 for an example) and are attached to the inspection re‐
port.
10 Applicable documents
The following documents cited in this standard are necessary to its application.
Some of the cited documents are translations from the German original. The translations of Ger‐
man terms in such documents may differ from those used in this standard, resulting in terminologi‐
cal inconsistency.
Standards whose titles are given in German may be available only in German. Editions in other
languages may be available from the institution issuing the standard.
Appendix A (informative) Example laboratory report used to document the test sequence
See figure A.1.
Figure A.1