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Material Safety Data Sheet: Section 1 Product and Company Identification

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Material Safety Data Sheet

Section 1 Product and Company Identification

Product Name: Petro45X


Product Type: Insulating Oil
Manufacturer: Lubricant Company of PetroChina Co. Ltd.
8th Floor of Beijing International Convention Center
No.8 BeiChenDong Road, ChaoYang District, Beijing, China
Telephone No. 86-10-84990771
Fax: 86-10-84990760

Section 2 Composition/Information of Ingredient

Chemical Name CAS No. Concentration%


Hydrotreated Naphthenic Distillate 64742-53-6 99.7%~100%
2,6-di-tert-butyl-paracresol 128-37-0 0~0.3%

Section 3 Hazards Identification

Human health: Inhalation of vapors and/or mists(Generate at high temperature


only) might irritate respiratory tract.
Prolonged or repeated skin contact will cause defatting and
possible irritation.
Eye contact might cause irritation.
Environment: Mineral insulating oil is slow biodegradation, the product
will remain for a period of time in the environment. Risk
existed for contamination of earth, soil and water.
Physical and At elevated temperature over the limitation of physical property,
Chemical Hazard flammable vapor or decomposition product will be released.

Section 4 First Aid measures

Inhalation: If inhalation of mists, fumes or vapors causing irritation, move


victim to fresh air, provide oxygen if breathing is difficult. If the
symptoms persist, get medical advice.
Skin Contact: Remove immediately contaminated clothing and adhering
matter, and wash with soap and plenty of water. If irritation
occurs, obtain medical advice.

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Eye Contact: Rinse with plenty of water. If irritation occurs, obtain medical
advice.
Ingestion: Clean mouth with water. Obtain medical advice if a large
amount has been swallowed. Do not induce vomiting.

Section 5 Fire Fight Measures

Extinguishing Extinguish with dry chemical, carbon dioxide (CO2) or foam.


Media Water mist or spray may be used.
Unsuitable Do not use a direct stream of water.
Extinguishing Media:

Section 6 Accidental Release Measures

Personal Precaution Using suitable protective equipment. In case of large spillage,


using suitable protective clothing, such as overall, gloves and
boots in cleaning procedure.
Remove contaminated clothes as soon as possible.
Environmental Prevent spill to enter and spread to drain, water resource and
Precautions: soil. Contact local environment protection authorities.
Cleaning Method: Absorb with clay, sand, earth or other suitable material. Collect
in a suitable container for proper disposal.

Section 7 Handling and Storage

Handling Handle with good industrial hygiene and safety practice. If


handled at elevated temperatures or with high speed mechanical
equipment, vapors or mists might be released and require a well
ventilated workplace.
Avoid heat, open flames, including pilot lights, and strong
oxidizing agents. Ground all handling equipment to prevent
sparking.
Storage Store at ambient temperature and with adequate ventilation
place. Keep away from open flames and high temperatures.

Section 8 Exposure Control/Personal Protection

Control Parameter Exposure via air and normal handling.

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Personal Protection
•Respiratory If the product is heated under manual handling, use suitable
protection: mask. Respirator selection, use and maintenance should be in
accordance with the requirements of the specific protection
Standard.
•Hand protection: Wear suitable oil-resistant protective gloves if there is a risk of
repeated skin contact.
•Eye protection: Wear safety goggles / safe shield if splashes may occur.
•Skin and body Wear protective clothing if there is a risk of skin contact and
protection: change them frequently, or when contaminated.
Hygienic Measures: Act in accordance with good industrial hygiene and safety
practice. Wash hand with soap and water before eating,
drinking, smoking or using toilet. Wash contaminated clothing
before reuse.

Section 9 Physical and Chemical Properties

Form Viscous liquid


Color <0.5
Odor Odorless
Pour Point <-45℃
Initial Boiling Point >280℃
Density at 20℃ 878kg/m3
Flash Point, PM 144℃
Auto ignition Point >270℃
Solubility in water Non Soluble
Solubility in Soluble
Organic Solvent
Viscosity at 40℃ 10.01 mm2/s
Decomposition >320℃
Temperature
DMSO Extractible <3%
Compounds (IP346)

Section 10 Stability and Reactivity

Stability: Stable at normal conditions. Start to decompose at 320°C or


higher.
Avoid: Excessive heating and highly oxidizing agents.
Hazardous Flammable gases which might also be noxious. With air
Decomposition Products: present, there is a risk for auto ignition at temperatures >270°C.

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Section 11 Toxicological Information

Acute toxicity: Studies available indicate oral and dermal LD50 s of >5 g/kg
which is considered as low acute toxicity.
Inhalation: Prolonged and repeated inhalation of mist of vapor generated at
elevated temperatures may irritate respiratory tract.
Oral: May cause nausea and eventually vomiting and diarrhoea.
Skin contact: Prolonged or repeated exposure may lead to defatting of the
skin and subsequent irritation.
Eye contact: May cause redness and transient pain.
Sensitization: Studies indicate no evidence of sensitization.

Section 12 Ecological Information

Summary: There is no ecological data for this product at present. However,


some conclusion could be drawn from its properties.
Mobility: Low, due to low water solubility.
Persistence The base oil is not readily biodegradable. Substances may not
/degradability meet criteria for ready biodegradability.
Bio-accumulation: Not bio-accumulated, The size of the hydrocarbon molecules
reduces the risk for bioaccumulation.

Section 13 Disposal Consideration

Residue of unused products is not regarded as hazardous waste. Dispose the residue of
products/packing in accordance with local regulations. The user of material has the
responsibility to determine at the time of disposal, whether the material meets the criteria of
hazardous waste.

Section 14 Transportation Information

The product is not classified as hazardous goods for land, sea and air transport according to
the respective regulations.

Section 15 Regulatory Information

Classified according to European directives on classification of hazardous substances and


preparations, not classified as hazardous. No statutory label required.
All components of this material are listed on the EPA/TSCA Inventory of Chemical
Substances.

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Section 16 Other Information

The information provided in this Safety Data Sheet is base on the data available at present,
and is believed to be correct to the best of our knowledge. The information given is designed
as a guidance for safe handling, use, processing, storage, transportation, disposal, and release
and is not to be considered as a warranty or quality specification. The information relates only
to the specific material designated.
For further information, please contact with our company.

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