UNIVERSITY OF MYSORE *30*

Postgraduate Entrance Examination July-2019

QUESTION PAPER QUESTION PAPER

BOOKLET SERIES BOOKLET NO.
X
W
Entrance Reg. No.
SUBJECT CODE : 3 0
0
QUESTION BOOKLET
(Read carefully the instructions given in the Question Booklet)

Chemistry / English
Organic Chemistry
COURSE : M.Sc.
M.A. SUBJECT :

MAXIMUM MARKS : 50 MAXIMUM TIME : 1.15 HOURS

(Including time for filling O.M.R. Answer sheet)
INSTRUCTIONS TO THE CANDIDATES
1. The sealed question paper booklet containing 50 questions enclosed with O.M.R. Answer Sheet is given to you.
2. Verify whether the given question booklet is of the same subject which you have opted for examination.
3. Open the question paper seal carefully and take out the enclosed O.M.R. Answer Sheet outside the question
booklet and fill up the general information in the O.M.R. Answer sheet. If you fail to fill up the details in the form
as instructed, you will be personally responsible for consequences arising during evaluating your Answer
Sheet.
4. During the examination:
a) Read each question carefully.
b) Determine the Most appropriate/correct answer from the four available choices given under each
question.
c) Completely darken the relevant circle against the Question in the O.M.R. Answer Sheet. For
example, in the question paper if “C” is correct answer for Question No.8, then darken against Sl. No.8 of
O.M.R. Answer Sheet using Blue/Black Ball Point Pen as follows:
Question No. 8. A B D (Only example) (Use Ball Pen only)
5. Rough work should be done only on the blank space provided in the Question Booklet. Rough work should
not be done on the O.M.R. Answer Sheet.
6. If more than one circle is darkened for a given question, such answer is treated as wrong and no mark will
be given. See the example in the O.M.R. Sheet.
7. The candidate and the Room Supervisor should sign in the O.M.R. Sheet at the specified place.
8. Candidate should return the original O.M.R. Answer Sheet and the university copy to the Room Supervisor
after the examination.
9. Candidate can carry the question booklet and the candidate copy of the O.M.R. Sheet.
10. The calculator, pager and mobile phone are not allowed inside the examination hall.
11. If a candidate is found committing malpractice, such a candidate shall not be considered for admission to
the course and action against such candidate will be taken as per rules.
12. Candidates have to get qualified in the respective entrance examination by securing a minimum of
8 marks in case of SC/ST/Cat-I Candidates, 9 marks in case of OBC Candidates and 10 marks in case
of other Candidates out of 50 marks.
INSTRUCTIONS TO FILL UP THE O.M.R. SHEET
1. There is only one most appropriate/correct answer for each question.
2. For each question, only one circle must be darkened with BLUE or BLACK ball point pen only. Do not try to
alter it.
3. Circle should be darkened completely so that the alphabet inside it is not visible.
4. Do not make any unnecessary marks on O.M.R. Sheet.
5. Mention the number of questions answered in the appropriate space provided in the O.M.R. sheet
otherwise O.M.R. sheet will not be subjected for evaluation.

M-7122/X
1) The 3p orbitals are completely filled by the electrons, then the new electron
will enter into
(A) 4s (B) 4p
(C) 4d (D) 3d

2) The correct order of radii is

(A) N < Be < B (B) F–< O2–< N3–
(C) N < Li < K (D) Fe3+ < Fe2+ < Fe4+

3) Which of the following does not conduct electricity?

(A) Molten NaOH (B) Molten KOH
(C) Solid NaCl (D) Aqueous NaCl

4) Caustic soda is
(A) Effluorescent (B) Oxidant
(C) Reductant (D) Deliquescent

5) Which of the following is not correct one?

(A) Diborane has two three centred B-H-B bonds
(B) Tetraborane has four three centred B-H-B bonds and one B-B bonds
(C) Diborane has one three centred B-H-B bond
(D) Boron forms electron deficient compounds

6) In laboratory, nitrogen is prepared by heating an aqueous solution of

(A) Sodium nitrite
(B) Sodium nitrite and ammonium chloride
(C) Sodium nitrate and ammonium sulphate
(D) Ammonium sulphate

M-7122/X [2]
7) The shapes of XeF2 and XeO3 are, respectively
(A) Pyramidal and linear (B) Linear and pyramidal
(C) Linear and planar (D) Planar and linear

8) Which of the following is diamagnetic?

(A) Fe2+ (B) Cr3+
(C) Cu2+ (D) Zn2+

9) Ligand-SCN is an example of a
(A) Bidentate ligand (B) Monodentate ligand
(C) Ambidentate ligand (D) Tridentate ligand

10) The IUPAC name of [Co(NH3)5Cl]Cl2 is

(A) Chloropentammine cobalt(III) chloride
(B) Chloropentammine cobalt(II) chloride
(C) Chloropentammine cobalt(I) chloride
(D) Pentammine chloro cobalt chloride

11) In tetrahedral field, five d-orbitals are split into a

(A) t2g and eg (B) t2g and a1g
(C) t2 and e (D) a1g and t2g

12) Carbon cannot be used in the reduction of Al2O3 because

(A) The enthalpy of formation of CO2 is more than that of Al2O3
(B) Pure carbon is not easily available
(C) The enthalpy of formation of Al2O3 is very high
(D) It is an expensive proposition

M-7122/X [3] (P.T.O.)

13) Identify the statement that is not correct for Ellingham diagrams
(A) These are the plots of fG° Vs T
(B) Each plot is a straight line unless phase change occurs
(C) These plots signify the kinetics of reduction process
(D) These plots are based on thermodynamic concepts

14) Standard deviation is described as

(A) The spread of the data
(B) The middle value
(C) Measuring the value that occurs most frequently
(D) Regression analysis

15) Which one of the following material is not used in the hardness of abrasive?
(A) Fluorite (B) Apatite
(C) Haematite (D) Calcite

16) Name the products formed in the following reaction :

(A) 1, 2-Dinitrobenzene (B) 1, 3-Dinitrobenzene

(C) 1, 4-Dinitrobenzene (D) 4-Nitrobenzene sulfonic acid

17) Choose the increasing order of acidity

(A) Alkyne < Alkane < Alkene (B) Alkane < Alkyne < Alkene
(C) Alkene < Alkane < Alkyne (D) Alkane < Alkene < Alkyne

18) According to Bayer’s strain theory, which of the following molecule is more
stable?
(A) Cyclopentane (B) Cyclohexane
(C) Cyclopropane (D) Cyclobutane

M-7122/X [4]
19) Which of the following is the Huckel’s rule?
(A) 2n+2 (B) 4n+1
(C) 2n+1 (D) 4n+2

20) Name the reaction product of glycerol with HI?

(A) n-Propane (B) Propene
(C) Isopropyl iodide (D) n-Propyl iodide

21) Chlorobenzene is obtained by the reaction of benzene diazonium chloride with

(A) Cu2Cl2 (B) NaCl
(C) KCl (D) CuCl2

22) o-Nitroaniline is less polar than p-nitroaniline because of

(A) Intermolecular hydrogen bonding (B) Ionic bond
(C) Covalent bond (D) Intramolecular hydrogen bond

23) Heptane-2,6-dione is obtained from the ozonolysis of

(A) 2,3-dimethyl cyclopentene
(B) 1 ,2-dimethyl cyclopentane
(C) 1 ,2-dimethyl cyclopentene
(D) 2,3-dimethyl cyclopentane

24) Ketonic hydrolysis of ethyl acetoacetate yields,

(A) Two moles of acetic acid
(B) One molecule of acetone
(C) One mole of acetoacetic acid
(D) One molecule of acetone and one molecule of ethyl acetate
M-7122/X [5] (P.T.O.)
25) Table sugar is a disaccharide consists of
(A) Glucose and glycose
(B) Glucose and galactose
(C) Fructose and fructose
(D) Fructose and glucose

26) Based on the principle, chromatography can be classified as

(A) Adsorption and partition chromatography
(B) Planar and column chromatography
(C) Paper and partition chromatography
(D) Radial and planar chromatography

27) Which one of the following is monocyclic monoterpene?

(A) -Pinene (B) Menthol
(C) Camphor (D) Borneol

28) Which of the biomolecule contain non-transition metal?

(A) Vitamin B12 (B) Haemoglobin
(C) Chlorophyll (D) Insulin

29) Paracetamol is an

(A) Analgesic (B) Antipyretic

(C) Antimalarial (D) Both antipyretic and analgesic

M-7122/X [6]
30) max for the following compound is,

(A) 295nm (B) 298nm

(C) 301nm (D) 293nm

31) The pH of the blood is maintained by the buffer system is

(A) NaCl and HCl (B) NH4Cl and NH4OH
(C) Sodium citrate and citric acid (D) HCO3– and H2CO3

32) If the activity of a solution is given by 1.08 and concentration is 1.2 M, the
activity co-efficient is,
(A) 1.296 (B) 0.12
(C) 0.9 (D) 1.111

33) The example of emulsion is

(A) Soap (B) Butter
(C) Cheese (D) Starch

34) The vapour pressure of a dilute aqueous solution of glucose is 740 mm of

mercury at 298 K. The mole fraction of the solute is
(A) 1/20 (B) 1/38
(C) 1/76 (D) 1/740

35) The osmotic pressure of a sugar solution at 24°C is 2.5atm, Then the
concentration of the solution in moles per litre is given by
(A) 10.26 mol/lit (B) 1 .026 mol/lit
(C) 0.1026 mol/lit (D) 0.0126 mol/lit

M-7122/X [7] (P.T.O.)

36) Which of the following sets of conditions makes a process spontaneous at all
temperatures?
(A) H = 0;S > 0 (B) H = 0;S < 0
(C) H > 0;S > 0 (D) H < 0;S < 0

37) How many kinds of space lattices are possible in a crystal?

(A) 23 (B) 7
(C) 230 (D) 14

38) The vapour phase of the metastable phase is always _______ than that of the
stable phase at the same temperature
(A) Lower (B) Higher
(C) Constant (D) Neither low nor high

39) The Clausius-Clayperon equation helps to calculate

(A) Latent heat of vaporization (B) Melting point of the solvent
(C) Heat of neutralization (D) Molecular weight of solute

40) In some photochemical reactions low quantum yield is obtained due to

(A) Deactivation of the reacting molecules
(B) Dissolution of the reacting molecule
(C) Fragmentation of the products
(D) Formation of stable products

41) The solubility 's' of a sparingly soluble salt is related to its equivalent conductance
at infinite dilution by the relation (k in specific conductance)
k  1000 c  1000
(A) s     (B) s    
 

k  1000 c  1000
(C) s   (D) s  

M-7122/X [8]
42) Borax (Na2B4O7) on hydrolysis produces a solution which is
(A) Acidic
(B) Basic
(C) Neutral
(D) Sometimes acidic, sometimes basic

43) In the lead acid accumulate, PbO2 is

(A) the anode in the charging period
(B) the cathode in the charging period
(C) the anode in the discharging period
(D) a depolarizer

44) The alkali hydrolysis of an ester represented by

This reaction is,

(A) bimolecular and second-order
(B) bimolecular but first-order
(C) bimolecular but not second -order
(D) second-order but not bimolecular

45) How many kinds of protons are there in the NMR spectrum of CH3CH2CH3?
(A) 2 (B) 3
(C) 6 (D) 8

46) Iodine value is used for the determination of

(A) Molecular weight (B) Unsaturation
(C) Number of hydroxyl groups (D) Number of fatty acids

M-7122/X [9] (P.T.O.)

47) Electrical conductivity of an electrolyte depends upon,
(A) The number of molecules in the electrolytes
(B) The number of ions present in the electrolytes
(C) The number of molecules present in the solvent
(D) The number of ions present in the solution

48) Which of the following can be used to measure pH?

(A) Glass electrode
(B) Hydrogen electrode
(C) Quinhydrone electrode
(D) All of these

49) A colourless salt gives violet colour in Bunsen flame, it may be

(A) K2CO3
(B) Na2CO3
(C) Na2CrO4
(D) BaCO3

50) Ions of Ca, Ba and Sr precipitate in fifth group as their

(A) Oxides
(B) Sulphides
(C) Carbonates
(D) Sulphates



M-7122/X [10]
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Note : English version of the instructions is printed on the front cover of this booklet.