Differentiation and Evaluation of Standard Commercialized Papers and Papers Produced From Zea Mays Husk
Differentiation and Evaluation of Standard Commercialized Papers and Papers Produced From Zea Mays Husk
Differentiation and Evaluation of Standard Commercialized Papers and Papers Produced From Zea Mays Husk
Grade 12 Level
By:
Noralyn K. Maed
Grade 12 – STEM
Submitted to:
Science Teacher
A. ACKNOWLEDGEMENT:
With utmost respect, we formally give thanks to those people that have helped us in
order to complete this investigatory project successfully, and properly give credit for they
became a part of this investigatory project. Specially, to Saint Francis of Assisi College, Taguig
Campus principal, Sir. Gilbert C. Sibala, for initiating the creation of our investigatory project,
and for guiding and examining of our product. To our caring Grade 12 STEM adviser, Ma'am
Richell Cabanting, without her help we cannot think of this life changing product of ours that can
spark improvement and change for those who need help and to our dying nature. To Amir Julio,
a student of GAS-1, for helping us to find one of our ingredients and creating the wax paper that
is used to mold our paper. To our parents, that gaves us the inspiration to finish the investigatory
project and helping us financially to carry out our experimentation. Without them, we know that
we cannot handle the pressure and problems. Lastly, and most importantly, to God Almighty for
giving us spiritual guidance and enough knowledge as well as physical strength to cope with
every challenge in every day of our thesis journey. With Him, the success of our work became
possible. The accomplishment of this research study is truly a collection of time, efforts and hard
work of the authors, the names listed above, and other unnamed individuals.
B. ABSTRACT:
Trees serve as the main source for making paper pulp, a fibrous material that is
produced from chemically or physically separating the cellulose fibers from wood.
Nearly four billion trees worldwide are cut down each year for paper representing about
35 percent of all harvested trees (Sam, 2011). Alarming matters that revolve around raw-
material availability and wood consumption along with environmental and economical
issues has been the driving factor for finding alternatives of natural products filled with
cellulose. One way to utilize a more efficient and ecological production of paper is to use
non-timber products as an alternative (Majid et al., 2011). In this study, the researchers
searched for non-timber products that are available most of the time, can be a potential
economic solution and environmentally safe for undergoing all of the paper
manufacturing processes that it will undergo. The natural properties of the zea mays husk
contained enough fibrous material to produce paper. The zea mays husk paper resembled
most of the properties similar to commercialized paper. It was able to input ink and other
writing apparatuses applied to it. It was able to resist more water than commercialized
paper. Furthermore, zea mays husk paper can be an alternative for standard
commercialized papers.
C. TABLE OF CONTENTS:
TITLE PAGE
a. ACKNOWLEDGEMENTS
b. ABSTRACT
c. TABLE OF CONTENTS
d. INTRODUCTION
e. METHODOLOGY
1. Materials/equipment
2. General procedure
g. ANALYSIS OF DATA
h. CONCLUSION
i. RECOMMENDATION
j. BIBLIOGRAPHY
D. INTRODUCTION:
Paper, a flat sheet of crisscrossed fibers, is one of the most used products across the
globe. Traditionally, wood has been the most widely used paper resource. Most papers today are
made of forest woods which all contain cellulosic matter, component of wood which makes up
paper fibers (Casey, 2017).These woods undergo chemical and mechanical processes to turn
In line with this matter, increasing demand for paper leads to rapid environmental
destruction. Each year over four billion or 35% of the world’s trees are used to produce paper
pulp causing large scale depletion of forests (Sam, 2011). In the Philippines, the country lost a
third of its forest cover from 1990 to 2005 due to the paper industry (FAO Forestry Paper, 2010)
This industry is also considered a significant contributor to pollutant discharges and emissions to
the environment due to processes needed to turn timber resources into pulp. Heightened concerns
on increasing wood consumption and raw-material availability, together with economic and
This resulted in a renewed attention on the ecological and economic benefits of using non-timber
plant materials (Majid et al., 2011). Non-timber resources such as the Zea mays (corn) husk has
been proven to contain sufficient amount of fibers needed for paper production which makes
them possible to replace wood as raw material. Corn is the second most produced crop in the
Philippines making it a suitable and convenient development to procure corn husk papers. Corn
husks are considered as agricultural wastes which are sometimes used as animal feed form farms.
Due to disposal problems, some farmers tend to burn these wastes which worsen air pollution.
Corn husks are also used for food preparations as they become wrappers for steamed food which
are eventually thrown away after the food preparations are done since it doesn’t add any more
value other than encasing food. Corn husks are versatile and this is why within the situations
presented on the study, we are incorporating the value of corn husk into a widely commercially
used product which is paper. The researchers aim to produce a paper made from corn husk to
utilize this waste product’s properties and transform it into an economical surplus and an
environmental saver. Utilization of this non-timber resource may help resolve environmental as
well as economic problems arising from increased demand for paper production. The researchers
also aim to test and compare the basic material properties of the corn husk paper to pre-
determine if it will provide the same quality and utility as commercial papers.
Fast growth in population, urbanization, and industrialization led to increased demand for
paper production. Paper processes including its byproducts, and the raw materials, usually timber
resources, for its production causes rapid environmental destruction. On the other hand,
agricultural wastes such as corn husks create disposal difficulties which often lead farmers to
burn these wastes producing greenhouse gases which worsen global warming. This
environmental threat urged the researchers to utilize the Zea mays (corn) husk as raw material
The study aims to produce paper made from corn husk and compare to some basic material
properties. To achieve this general objective, the following specific objectives are done: (1)
production of paper from of corn husk using the IRRI method. (2) The determination and
comparison of basic material properties: ink injection, flexibilty and water absorption.
Corn is a widely used crop in the Philippines and utilizing its waste products, in this case,
the corn husk may benefit the economical state of the country. It will also provide a solution to
minimize deforestation for paper production requires the use of timber resources to be
manufactured. The demand for paper production is rapidly increasing and arguably the best way
to minimize tree loss and keep the constant production of papers is to use non-timber materials
for alternatives in cellulosic matter. Utilizing corn husks as raw material for paper production
may conceivably reduce environmental impact of paper production since it may lessen demand
for wood. It may possibly eliminate disposal problems such as pollution from burning corn husk
by having an alternative source of raw material for paper, production costs of paper may be
reduced benefitting paper industries as well as the consumers. It may also open the door for
small-scale paper producers and local group cooperatives producing handmade papers to
compete on the market. Lastly, the findings of the study may encourage other researchers to find
the other potential raw materials for paper production and study more ways in enhancing the
commercialized paper and paper produced from corn husk. A method for pulping of corn husk
was done using the chemical-mechanical pulping method based from the International Rice
Research Institute (IRRI). Basic material testing such as ink application, flexibility and water
absorption was done to compare the corn husk paper to the standard commercialized paper. The
physical and chemical properties of the paper were not tested officially by an expert due to lack
a. Paper
Paper is a flat sheet of crisscrossed fibers. It is used by almost every sector of the society.
It is produced from the lignocellulosic (cellulose, hemicellulose, and lignin) matter. The primary
resource for these is wood. Wood has holocellulose (cellulose and hemicellulose) fibers which
what paper fibers are made of (Bialkowski, 2018). Cellulose is a long-chain polymer of glucose
which serves as the building block of a plant’s cell wall. Cellulose is a complex carbohydrate
produced by plants by photosynthesis and the carbohydrate is used to build cell walls (Sinha,
2011). Hemicellulose present in wood is a polymer of other sugars such as pentose and hexose
with shorter chain and is connected to the cellulose by the lignin. Lignin, a phenolic polymer, is
basically the binding agent or cement for other wood fibers (Latib, Tamat & Kasim, 2014).
For the production of paper, logs are first converted into wood pulp by chemical-mechanical
process. These processes are called pulping – extraction or separation of cellulose fibers from the
In the mechanical process, the banks of the logs are sent to the grinders to break the wood down
into pulp. This process is also called the ground wood process (Woodford, 2018).
Figure 1. Simplified Structure of plant fiber showing cellulose, hemicelluloses, and
of-insoluble-plant-fiber-showing-the-crystalline-cellulose-in_fig1_)
The alkali-labile bond between the ferulic acid in the lignin and hemicellulose is highly
susceptible to alkali degradation, as the hydroxide ion increases the rate at which hydrolysis
reaction occurs as compared to water (Bruice, 2004). The result of this process is the irreversible
hydrolysis of the bond, weakening the structural integrity of the lignocellulose. Bleach and dye
can be added in the mixture for the color. After converting logs into pulp, the pulp is subjected
on a process called beating. In this process, different filler materials can be added like chalks and
clay. After being beaten, the pulp will be pumped into an automated machine which will squeeze
the pulp by the rollers on a moving belt of fine mesh screening to remove the excess water. Then
https://www.alfredmank.com/closer-look-paper-production-process/
b. Handmade papermaking
Most papers made today came from a self-operating machine and continuous production
system. However, the handmade paper became a traditional craft and an art form (Hubbe &
Bowden, 2009). The manual craft of papermaking started in China in A.D. 105. Subsequently, its
influence has spread through Asian countries such as Japan and Korea (Frialde, Hargove &
Ortega, 1998) In the Philippines; the International Rice Research Institute (IRRI) conducted a
study about producing handmade paper from rice straw. In line with this, basic materials and
procedures to make paper from rice straw are elaborated in their study. It also has instructions on
Pulping
beating. In the digestion process, the raw materials needs to be cut into 1 inch length then
screened to remove the dirt. Then, the raw materials are cooked in a cauldron with 20 L water
sodium hydroxide for three to four hours until the straw crumbles when pinched. The cooked
straw is washed under running water after cooking and crushed using a mortar and pestle. Again,
the straw is screened to remove dirt in which the remaining material is called the pulp (IRRI).
Bleaching
In the earliest years off papermaking, the bleaching process can only be done through
bleaching process (Pulliam, 1997). One of the alternatives for a pulping and bleaching agent is
sodium hypochlorite, commonly known as bleach. The process of bleaching uses several
chemicals to further treat fibers for the removal of residual lignin. Therefore, its main objective
is to remove lignin chromophores resulting to lighten the color of paper and whiten its pulp
Sheet Forming
Sheet forming is done using a mold and deckle usually with silkscreen or fine mesh
mounted on the mold. The removable deckle serves to catch pulp. In sheet forming, the pulp is
mixed with water then the mold and deckle is used to catch pulp to form sheets. Thicker paper
sheets require less water while thinner sheets require more water, Adding formation aid, a
thickening agent, may also help in producing thinner papers with much smoother surfaces. Also,
addition of formation aid and sizing agent makes the paper stronger (IRRI).
Formation Aid
Formation aid, also called neri, keeps the fibers from entangling and helps in forming
thin, translucent sheets. It is used in the making of thin papers from long-fibered pulps and is
also vital in the techniques of pulp painting and pulp spraying. In addition, the formation aid
slows down the drainage of the pulp, therefore, allowing the papermaker to form an even layer of
sheets (Bakre & Jaiyeoba, 2009). Formation aids can be synthetic or natural. One of the used
natural formation aids is Abelmoschus esculentus (okra) viscous juice. Okra plant grows very
fast, is grown in all soil types, and is among the most heat and drought-tolerant vegetables
(Bakre & Jaiyeoba, 2009). It has been studied as a binding agent for papers. Moreover, it has the
Sizing
High water resistance is one of the characteristics of good quality paper. In order to
achieve this, sizing treatment is used in the paper industry. Paper sizing describes the process of
adding chemicals to the aqueous mixture that contain cellulosic fibers. The resulting paper can
have better inhibition of water absorption (Hobbe, 2000). To increase water resistance, materials
such as animal glue, alum, gelatin, rosin size, synthetic resins, and starch are often used as a
sizing agent. The main function of a sizing agent is to increase the resistance to the penetration of
liquids into the paper so that the paper is suitable for printing and writing.
There are two types of sizing treatment: surface sizing (tub sizing) and internal sizing (engine
sizing or beater sizing). Surface sizing, also known as tub sizing, consists of sizing agents that
both have hydrophilic acid and hydrophobic ends (hagiopol 7 Johnston, 2011). The sizing agent
hoilds on to substrate fibers and forms a film. The hydrophilic tail faces the fiber and the
hydrophobic tail faces outwards, therefore resulting in a smooth finish that is water-repellant, In
addition, surface sizing treatment does not envelop individual fibers but add a protective coating
to the sheet that is used to prevent absorption and bleeding of inks. The most commonly used
surface sizing additives are modified starches, Styrene Maleic Anhydride (SMA), Styrene
Acrylic Emulsion (SAE), and gelation (Hubbe, Koukoulas & Palwak, 2008). In papermaking
process, internal sizing is the process of adding substances to the pulp which has the potential to
develop hydrophobicity and increases the paper’s resistance to penetration by aqueous liquids.
By making the paper hydrophobic, the sizing agents will influence dewatering and retaining of
fillers and fibers in the paper sheet. Some of the most used internal sizing agents by industries
are alum-rosin, wax rosin and Alkyl Ketene Dimers (AKD), while glue, and gelatin are usually
(a) (b)
https://www.seikopmc.co.jp/english/products/paper/ss_se.html)
Storing
making it unstable and vulnerable to humidity changes. To reach the equilibrium state of paper,
the fibers gather moisture from the environment. Hence, environmental factors such as
temperature and moisture can greatly affect the paper’s state. Moreover, the paper’s moisture
content changes with temperature, which then causes the sheet to curl and cause paper jams in
printing. For chemical stability, it is advised that the storage of paper should have lower relative
humidity and lower temperature since fluctuations in temperature increases the degradation rate
of paper relative to its storage (Gangwar, A., 2011). To avoid mold growth, the paper should be
stored at a relative humidity of 55% but for ordinary use, papers may be handled safely at a
c. Corn husk
Corn, scientifically known as Zea mays, is a cereal plant of the family Poaceae that was
first domesticated by Southern Mexico about 10,00 years ago (Kumar, D. 2013). Since its
introduction to Europe by Christopher Columbus, corn has spread to all areas of the world,
including the Philippines. One-third of Filipino farmers depend on corn as their source of
livelihodd (Gerpacio, Labios, J., Labios R., & Diangkinay, 2004). Corn production in the
Philippines last 2016 amounted to about 7.22 million metric tons as compared to 6.97 million
metric tons in 2011 (Statista, 2017). This became second to rice as the most important crop and
as a result, became one of the largest contributors of agricultuaral waste in the Philippines.
Corn husk or hull is the outer shell of a seed. It is often seen as a leafy covering of corns. The
husk is biodegradable and can be composted (Cote, 2013). After harvesting the corn, its husks
are often discarded and burned but are sometimes used for biofuel production. Farmers typically
leave husks and stalks behind in the fields as waste materials (Velasco, 2017). Corn husks may
cover a large area of landfill if not utilized. AS the husk contains several layers of papery tissue
that surrounds the flower organ, it is often used as natural material to make mats, figures, and
platters (Visperas, 2016). Aside from these handicrafts, corn husks are also studied to be an
alternative raw material in paper production. Its fibers are rich in cellulose that is considered as
major constituent in paper production (Klemm et al., 2005). Its tensile properties show that corn
fiber has the advantage of moderate strength but with higher toughness, low modulus and higher
elongation which makes it similar to fibers used for the production of paperboards (Reddy &
Yang, 2005).
Corn husks are proven to have fiber lengths similar to hardwood. Corn husk contains
approximately 15% of lignin content which is low making it one of the advantages of using non-
timber materials in the production of papers. The lower lignin content is, the easier the extraction
Raw materials were collected and bought from the local market of Bicutan, Taguig City.
Corn husks were bought from vegetable dealers in Bicutan Public Market. Sodium Hydroxide
▪ Corn Husk
decomposes proteins at ordinary ambient temperatures and may cause severe chemical burns.
▪ Zonrox Bleach
whitening, deodorizing, elimination of disease-causing germs, removal of tough stains and dirt,
become more slippery or gelatinous when cooked. It’s that mucilaginous texture that helps to
glue, is perhaps the most used and beloved glue of kids, crafters, makers, and pros. This glue
dries clear, is somewhat flexible, and can be bonded to just about any surface.
▪ Wax Paper
▪ Screen Wire
sectors to make woven screen mesh that can withstand impact and
abrasion.
This study consists of the paper production using IRRI Method. Paper production
involves three parts: (1) Delignification, (2) Bleaching, and (3) Sheet Forming, wherein there are
All papers that were produced are according to the method given by International Rice
Research Institute.
2.1 Delignification
The raw material was collected and bought from the local market of Bicutan, Taguig
City. Corn husk were bought from vegetable dealers in Bicutan Public Market. Sodium
The raw material, corn husk, was cut into 1 cm length using scissors then thoroughly
cleaned using distilled water to remove dirt and to separate them from other foreign materials. In
separate cauldrons, 0.66 kg of each raw material was cooked in a cauldron with 11 L distilled
water and 100 g of sodium hydroxide pellets for 1 hour at temperature of 100 Co - 110 Co. The
resulting fibrous material, called the pulp, was strained and temporarily stored in a plastic
container.
(a) (b)
(c) (d)
Figure 5. Pulping Process: (a) cutting, (b) washing, (c) cooking, (d) squeezing out excess water
2.2 Bleaching
Sodium hypochlorite was used as the bleaching agent and was bought from a local
market at Bicutan, Taguig City. The 0.66 kg of pulp was bleached in a different cauldron with
8.25 L of distilled water and sodium hypochlorite. Distilled water was heated until it reached
boiling point (100 Co). After reaching boiling point, the heat was turned off then 130 mL of
sodium hypochlorite and 0.66 kg of each pulp was added on each cauldron. It was covered and
left for 1 hour. The bleached pulp was then strained and washed.
Bleached pulp was grinded. Then it was mixed with 19.5 L of distilled water in a large
basin. 1.3 L of okra juice, as a thickening agent, and 156 ml of white glue, as a binding agent,
The screen wire was dipped into the basin to catch as much pulp to make paper of the
desired thickness. It is then tilted back and forth to spread pulp evenly. The molded flat sheet
pulp was laid on the wax paper. A sponge and cloth were used to remove excess water on the
pulp sheet. The pulp sheets were sun dried for 1 day.
As for the testing methods, the researchers tested if the paper made has flexibility properties
similar to standard paper. The researchers then tested different types of writing apparatuses on
the paper such as ballpen and permanent marker in three different kinds. Lastly, the researchers
For the paper production preparation, the materials used are zea mays husk (corn husk),
sodium hydroxide (NaOH), distilled water, sodium hypochlorite (bleach), okra juice, PVA Glue.
In delignification process the researchers observed that the corn husk is softer after the 3 hours
boiling in sodium hydroxide (NaOH) which results in separation of fibrous material and it is
called the pulp, therefore it can proceed unto the bleaching process. In the bleaching process,
using the sodium hypochlorite (bleach) the pulp has lightened and proceeded to combine to the
pulp and thickening agent when boiled. Afterwards, the outcome of the pulp became thicker and
more compactly bonded. In the sheet forming process, the pulp will be filtered using the screen
to remove excess water and put on wax paper for the pulp to flatten. After a period of time the
pulp will be dry. The pulp will then transform to a material distinguished as paper. The Zea mays
(corn) husk paper was tested to determine the basic material properties of corn husk and standard
commercialized paper. The first one to be tested is the application of ink. The researchers tried to
use a ball point pen and a permanent marker with three different variations to test if the paper
will be able to display the ink vividly. The results showed that both of the papers were able to
display the ink vividly but the corn husk paper didn’t have any ink leakages on the back when
the permanent markers were applied. The second test that the researchers have done measures
the flexibility of the product. The researchers crumpled a sample piece of the corn husk paper
and a commercialized paper. It was then unfolded to see if there are any breaks or tears, the
results showed that the both the corn husk paper and the commercialized paper didn’t have any
breaks or tears. However, the corn husk paper didn’t display any large folds even if it was
crumpled hard. The third test that the researchers conducted was the water absorption. The
researchers dampened the corn husk paper and commercialized paper with small droplets of
water. The results showed that the commercialized paper absorbed water faster than the corn
husk paper and the commercialized paper was able to tear up pretty easily.
G. ANALYSIS OF DATA
Paper samples were produced using chemical-mechanical process based from IRRI
method. Raw materials were converted into pulp through delignification. Pulp produced
was bleached using an oxidizing agent, sodium hypochlorite (5%). Bleached pulp was beaten
using a blender then sheets were formed using a screen wire. White glue was used as the binding
agent of the fibers. Excess paper procured from the sample were produced to have sufficient
Ink application, flexibility, as well as water absorption are factors that are necessary to
observe in paper quality for it determines the overall usage of the paper. Application of ink can
only be established with the help of an apparatus that can store and inject ink such as ballpoint
pens and pen markers. These tools have been used to scribble on the sample parts of the corn
husk paper and has proven that the paper can handle multitudes of scribbling without having ink
leakages throughout the whole piece while commercialized papers displayed the similar
Flexibility determines the strength of the paper when it is deformed from its original
shape. The researchers crumpled the commercialized paper and corn husk paper into ball. There
were no signs of tearing or breaking in both of the papers when the papers were unwrapped from
its deformity. This shows that the flexibilty of both of the papers are similar in durability.
Water absorption is similar to the methods of ink application. The researchers dampened
the two papers with droplets if water. The researchers tested if the corn husk paper can sustain
hydrophobicity features that were conditioned into the paper and if it will display similar
occurrences to that of a commercialized paper. The results indicated that the corn husk paper
absorbed less water and did not deconstruct after intaking liquid into its fibers while the
commercialized paper created few tears after the fibers were moved.
H. CONCLUSIONS
The researchers conclude that Zea mays (corn) husk paper can be an alternative to
standard commercialized paper for its properties and functionalities are the same as standard
paper. It can be applied with ink, can be folded into multiple sides and directions and has a better
water resistance than standard commercialized paper. The researchers also concluded that the
Zea mays (corn) husk paper may be a huge help for the economical and environmental
advancement of the Philippines for it is innovative and efficient in the way it is utilized as a
byproduct of corn.
I. RECOMMENDATIONS
For future researchers, the proponents recommend the following: (1) venture on different
kinds of non-timber materials for alternatives, (2) invite an expert to test the physical and
chemical properties of the product to ensure quality, (3) have varying compositions of non-
timber products for maximum efficiency and quality, (4) make sure every method you do must
J. BIBLIOGRAPHY
cornhusk.Retrievedfrom
https://www.academia.edu/29045496/Pulp_and_papermaking_potential_of_corn_h
usk?auto=download
IPPTAJ23(3161-164
Gerpacio, R., Labios, J., Labios, R., & Diangkinay, E. (2004). Maize in the Philippines:
https://ageconsearch.umn.edu/bitstream/7650/1/mp04ge01.pdf?fbclid=IwAR3AF0q
NOhbb8oRN6MQRQss_Rfk28G2nUyeTc4DvXHuIbIXHC4rBYMAJigo
onStructuralComponentsofBiomass,1-14
from
https://www.ncbi.nlm.nih.gov/Taxonomy/Browser/wwwtax.cgi
Popil,R., Ph.D. (2017) Physical Testing of Paper [PDF File] retrieved from
http://www.rbi.gatech.edu/sites/default/files/documents/Physical%20Testing%20of
%20Paper.pdf
Reddy, N., & Yang, Y. (2005). Properties and potential applications of natural cellulose
46
https://pubs.rsc.org/en/content/articlelanding/2005/gc/b415102j?fbclid=IwAR0t5tzY
UX39ucO9eYWNMHUzrwk8C3XKakX9-
ILN9t8al5OPyJXWFOIAWU0#!divAbstractFagmebigun
Statista (2017). Corn production in the Philippines from 2011 to 2016 (in 1,000 metric
tons).Retrievedfrom
https://www.statista.com/statistics/751372/philippinescornproduction/?
fbclid=IwAR0TdluPQpg4UV8GmRt1T530Umtclb8P6Pvi5peme2y7Yr2
xkPjgpOGP4lg
Technical Association of Pulp and Paper Industry (2013) Grammage of paper and
paperboard T41047
Technical Association of Pulp and Paper Industry (2006) Tensile properties of paper and
paperboard T494
Technical Association of Pulp and Paper Industry (2013) Water absorptiveness of sized
https://www.explainthatstuff.com/papermaking.html?fbclid=IwAR2kXAjEiVljfbgMP
0Vqt J1nxD-IE3zjULD3ytEdLKsowUm1U0Zi4sSdufw
https://www.bioenergyconsult.com/agricultural-resources-inphilippines/?
fbclid=IwAR2kTsYFxyEwS9Pde9-lrGH72TBfXa0x8TIuzj50IXWFrKgA_8tVTf3CQM
https://www.instructables.com/lesson/White-Glue/
https://www.fibre2fashion.com/industry-article/7884/corn-husk-fibre-for-production-of-
green-fabrics
https://www.libertygfg.com/steel/products-services/wire-products/screen-wire/
https://harvesttotable.com/okra_if_you_are_cajun/
https://greencross.com.ph/zonrox-bleach/
https://en.wikipedia.org/wiki/Sodium_hydroxide
https://www.yahoo.com/lifestyle/parchment-paper-same-wax-paper-100000225.html
dissolution in aqueous alkali solution. Cellulose Chem. and Tech., 39(3-4), 179-
188
Eronen, P., Osterberg, M., & Jaaskelainen, A. S. (2009). Effect of alkaline treatment on
43
http://dx.doi.org/10.1007/s10570-008-9259-8.
Fengel, D., Jakob, H., & Strobel, C. (1995). Influence of the alkali concentration on the
http://dx.doi.org/10.1515/hfsg.1995.49.6.505
Ishikura, Y., Abe, K., & Yano, H. (2010). Bending properties and cell wall structure of
009-9360-7.
Klemm, et al. (2005). Cellulose: Fascinating Biopolymer and Sustainable Raw Material.
Retrievedfrom
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200460587?fbclid=IwAR261JD
_ulAp9UWMnxtfR-KE_xESox77F17Ui-fICzvA5a4wI1RLXMkOrIQ&
Knill, C. J., & Kennedy, J. F. (2003). Degradation of cellulose under alkaline conditions.
8617(02)00183-2.
Paper with AKD and ASA Related to Surface Chemistry, Wettability and Friction.
Adler, E. (1977). Lignin chemistry: Past, present, and future. Wood Sci. and Tech.,
11(3), 169-218.
http://dx.doi.org/10.1007/BF00365615
degradability? A review of cell wall model studies. Crop Sci., 45(3), 820-831.
http://dx.doi.org/10.2135/cropsci2004.0191.