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    Tabla#1 Parametros Del Modelo de Wilson Mezcla v1 (Cm3/mol) v2 (Cm3/mol) A12 (Cal/mol) A21 (Cal/mol) 1-Propanol (1) /agua

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    Juan Monterroza
    The document contains parameters and calculations for modeling the vapor-liquid equilibrium of a 1-propanol/water mixture using the Wilson model. It provides constants for the Antoine equation for each pure component, parameters for the Wilson model including interaction energies, and calculations of vapor pressures, temperatures, mole fractions and activity coefficients at different pressures and temperatures. The results are used to calculate saturated vapor pressures and temperatures as well as the composition of coexisting liquid and vapor phases.

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    Tabla#1 Parametros Del Modelo de Wilson Mezcla v1 (Cm3/mol) v2 (Cm3/mol) A12 (Cal/mol) A21 (Cal/mol) 1-Propanol (1) /agua

    Uploaded by

    Juan Monterroza
    32 views6 pages
    The document contains parameters and calculations for modeling the vapor-liquid equilibrium of a 1-propanol/water mixture using the Wilson model. It provides constants for the Antoine equation for each pure component, parameters for the Wilson model including interaction energies, and calculations of vapor pressures, temperatures, mole fractions and activity coefficients at different pressures and temperatures. The results are used to calculate saturated vapor pressures and temperatures as well as the composition of coexisting liquid and vapor phases.

    Original Title

    PUNTOS C y D (1)

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    The document contains parameters and calculations for modeling the vapor-liquid equilibrium of a 1-propanol/water mixture using the Wilson model. It provides constants for the Antoine equation for each pure component, parameters for the Wilson model including interaction energies, and calculations of vapor pressures, temperatures, mole fractions and activity coefficients at different pressures and temperatures. The results are used to calculate saturated vapor pressures and temperatures as well as the composition of coexisting liquid and vapor phases.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    32 views6 pages

    Tabla#1 Parametros Del Modelo de Wilson Mezcla v1 (Cm3/mol) v2 (Cm3/mol) A12 (Cal/mol) A21 (Cal/mol) 1-Propanol (1) /agua

    Uploaded by

    Juan Monterroza
    The document contains parameters and calculations for modeling the vapor-liquid equilibrium of a 1-propanol/water mixture using the Wilson model. It provides constants for the Antoine equation for each pure component, parameters for the Wilson model including interaction energies, and calculations of vapor pressures, temperatures, mole fractions and activity coefficients at different pressures and temperatures. The results are used to calculate saturated vapor pressures and temperatures as well as the composition of coexisting liquid and vapor phases.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 6

    C P(mmHg) y T(°K)

    constantes
    sustancia a b c
    1-propanol 17.5439 3166.38 -80.15 t1
    agua 18.3036 3816.44 -46.13 t2
    𝑡_0=∑▒ 〖𝑥 _𝑖∗𝑡_𝑖
    〗

    Tabla#1 Parametros Del modelo de Wilson


    Mezcla v1(cm3/mol) v2(cm3/mol) a12(cal/mol)a21(cal/mol)
    1-propanol(1)/Agua(2) 75.14 18.07 755.48 1351.9

    Psat1 64.30797994 63.67790051 63.66454641


    Psat2 64.70146184
    Tnueva 316.7963991 316.6223852 316.6186812

    ∧_12= 0.074657657 0.072419785 0.072372032 0.072371015


    ∧_21= 0.512679125 0.485505485 0.48493276 0.48492057
    𝑙𝑛𝛾_1= 0.771416528 0.790510695 0.790916978 0.790925627
    𝛾_(1=) 2.16282779 2.204521977 2.205417818 2.205436893
    𝑙𝑛𝛾_2= 0.274611723 0.27793247 0.278002399 0.278003888
    𝛾_2= 1.316019596 1.320397027 1.320489365 1.320491331

    D P(mmHg) y T(°K)
    constantes
    sustancia a b c
    1-propanol 17.5439 3166.38 -80.15 t1
    agua 18.3036 3816.44 -46.13 t2
    t0=∑yi*ti

    Tabla#1 Parametros Del modelo de Wilson


    Mezcla v1(cm3/mol) v2(cm3/mol) a12(cal/mol)a21(cal/mol)
    1-propanol(1)/Agua(2) 75.14 18.07 755.48 1351.9

    Psat1 100.8986332 65.56924286 66.87626859 69.01784042


    Psat2 101.5153127 68.124506 69.37538969 71.42186413
    Tnueva 325.0404091 317.1404193 317.4910352 318.0531278

    ∧_12= 0.074658145 0.07251413 0.072610199 0.072764035


    ∧_21= 0.512685128 0.486637883 0.487792175 0.489643067
    x1= 0.301282575 0.184277439 0.115647038 0.080278389
    x2= 0.698717425 0.815722561 0.884352962 0.919721611
    𝑙𝑛𝛾_1= 0.922615825 1.368778044 1.702299513 1.914651961
    𝛾_(1=) 2.515862847 3.930544807 5.486549288 6.784577087
    𝑙𝑛𝛾_2= 0.276188556 0.143532142 0.074338782 0.043137599
    𝛾_2= 1.318096376 1.154343913 1.07717167 1.044081549
    temp saturadas p. saturada fracciones
    (K) kPa x1 0.3 y1 0.41
    325.12123649 p1 13.45006633 x2 0.7 y2 0.59
    325.00317135 p2 13.53236339
    325.03859089 p1n
    p2n 𝑇_𝑖^𝑠𝑎𝑡=𝐵_𝐼/(𝐴_𝐼−𝑙𝑛𝑃_𝐼 )−𝐶_𝐼

    𝐿𝑁(𝑃)=𝐴−𝐵/(𝑇+𝐶)
    R(cal/molK)
    1.987
    𝑙𝑛𝑦1=−ln⁡(𝑥1+𝐴12𝑋2)+𝑋2(𝐴12/(𝑋1+𝐴12𝑋2)−𝐴21/(𝐴21𝑋1+𝑋2))
    63.664262145

    316.61860239 𝑙𝑛𝑦2=−ln⁡(𝐴21𝑋1+𝑋2)+𝑋1(𝐴21/(𝐴21𝑋1+𝑋2)−𝐴12/(𝑋1+𝐴12𝑋2)

    𝑃_𝑖^𝑠𝑎𝑡=𝑃/(∑▒(𝑥_𝑖 𝛾_𝑖 𝜙_𝑖


    )((𝑃_𝑖^𝑠𝑎𝑡)/(𝑃_𝑗^𝑠𝑎𝑡 )) )

    𝑇=𝐵_𝑖/(𝐴_𝑖− 〖𝑙𝑛𝑃〗 _𝐼^𝑠𝑎𝑡 )−𝐶_𝑖

    temp saturadas p. saturada fracciones


    (K) kPa y1 0.3 x1 0.05
    325.12123649 p1 13.45006633 y2 0.7 x2 0.95
    325.00317135 p2 13.53236339
    325.03859089

    𝑙𝑛𝑦1=−ln⁡(𝑥1+𝐴12𝑋2)+𝑋2(𝐴12/(𝑋1+𝐴12𝑋2)−𝐴21/(𝐴

    R(cal/molK)
    1.987 𝑙𝑛𝑦2=−ln⁡(𝐴21𝑋1+𝑋2)+𝑋1(𝐴21/(𝐴21𝑋1+𝑋2)−𝐴12/(

    70.130167571 70.586999 70.7631412 70.831832 70.859355


    72.48332025 72.918973 73.08690587 73.152389 73.178625
    318.3392517 318.45565 318.5003545 318.51776 318.52474
    𝑇=𝐵_𝑖/(𝐴_𝑖− 〖𝑙𝑛𝑃〗 _𝐼^𝑠𝑎𝑡 )−𝐶_𝑖

    0.0728422591 0.0728741 0.072886278 0.072891


    0.4905854075 0.4909688 0.491116046 0.4911734 𝐴𝑖𝑗=𝑉𝑗/𝑉𝑖 𝑒𝑥𝑝 (−𝑎𝑖𝑗)/𝑅𝑇
    0.0638898163 0.0567196 0.053666575 0.0523822
    0.9361101837 0.9432804 0.946333425 0.9476178
    2.0271990683 2.0800364 2.103289235 2.1132148
    𝑃_𝑖^𝑠𝑎𝑡=𝑃∑_𝑖▒ 〖 (𝑦_1 𝜙_𝑖)/𝛾_𝑖 ((𝑃_𝑖^𝑠𝑎𝑡)/(𝑃_𝑗^𝑠𝑎𝑡 )) 〗
    7.5927896623 8.0047599 8.193074592 8.2748
    0.0302498817 0.0250267 0.022892146 0.0220113
    1.0307120579 1.0253425 1.023156182 1.0222553
    presion(kPa)
    101.33

    2/(𝑋1+𝐴12𝑋2)−𝐴21/(𝐴21𝑋1+𝑋2))

    21/(𝐴21𝑋1+𝑋2)−𝐴12/(𝑋1+𝐴12𝑋2))

    presion(kPa)
    101.33

    𝑋2)+𝑋2(𝐴12/(𝑋1+𝐴12𝑋2)−𝐴21/(𝐴21𝑋1+𝑋2))

    +𝑋2)+𝑋1(𝐴21/(𝐴21𝑋1+𝑋2)−𝐴12/(𝑋1+𝐴12𝑋2))

    − 〖𝑙𝑛𝑃〗 _𝐼^𝑠𝑎𝑡 )−𝐶_𝑖

    −𝑎𝑖𝑗)/𝑅𝑇
    𝛾_𝑖 ((𝑃_𝑖^𝑠𝑎𝑡)/(𝑃_𝑗^𝑠𝑎𝑡 )) 〗

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