TUT-Photoelectric Effect
TUT-Photoelectric Effect
TUT-Photoelectric Effect
Photoelectric Effect
To buy the goods, the incoming customer must have sufficient money to pay for the goods.
He can leave with change.
In a similar way, an incoming photon of light must have sufficient energy to "buy"
(eject) an electron from the metal.
All the excess energy ("change") becomes the kinetic energy of the ejected electrons
(photoelectrons). Easy!
Unrealistic values are used below, but the example is just to show you the names and
relationships between the various energies
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For electrons to be emitted, the incoming light (photon) must have sufficient energy to overcome
the work function of the metal to free the electrons.
What does the Photoelectric Effect tell us about the nature of light?
(What is the significance of the photoelectric effect?)
Quanta:
• packages of energy (energy unit)
• radiated energy is quantized
• it exists in multiples of a smallest possible value
Photons:
• quanta of electromagnetic radiation
• the incoming (incident) light
Photoelectrons:
electrons that are ejected from the metal
The PHOTO ELECTRIC EFFECT shows that light has a PARTICLE NATURE
• the particle nature of light is more pronounced at the high frequency end of the spectrum
• the wave nature of light is more pronounced at the low frequency end of the spectrum
Since light can behave both as a particle or as a wave, it is said that light has a dual nature.
(dual means 2)
It is said that light travels as a wave, but interacts as a particle when it strikes a substance.
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Work Function (Wo) is defined as the minimum amount of energy required to remove an electron
from the surface of a substance
Cut-off frequency (fo) (threshold frequency) is defined as lowest frequency of light that will eject
electrons from the surface of a metal.
Wo = hfo
If the frequency of the incident radiation is greater than the cut-off frequency (fo), then the energy of
each photon will be greater than the work function of the metal. This means that electrons at the
surface of the metal will be ejected with extra energy in the form of kinetic energy.
Different metals have different cut off frequencies and Work function.
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Photoelectric Equation
You would need this mass if you wanted to calculate the actual speed of a photoelectron from
kinetic energy:
The following diagram shows a dim light of frequency f being used to perform the photoelectric
effect.
What would happen if the light was made brighter, with the same frequency f?
There would be MORE electrons released since there would be more beams of light.
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It is important to note that if this was a solar cell, more current would flow due to the increased
number of electrons, i.e. the brighter light increases the current strength due to the increase in
the number of electrons.
In other words:
Brighter light:
• More photons (packets of energy) strike the surface of the metal per unit time.
• More (photo) electrons ejected per unit time.
• hence produces a greater current in a solar cell
• but does not increase the kinetic energies of each of the photoelectrons
FREQUENCY
The following diagram shows a light of frequency f being used to perform the photoelectric effect.
What would happen if the frequency was increased? (Not the intensity.)
The photons would now have greater energy (140J). But since the work function of the metal is
still the same, the kinetic energy of the photoelectrons would increase (60J).
(But the same number of electrons would be ejected since the photon was not made brighter.)
In other words:
Higher frequency light:
• Increase in frequency increases the energy of each photon of light
• This increases the kinetic energy of each ejected photoelectron.
• Increases the kinetic energy of each photoelectron would not change the number of
electrons ejected, number of electrons remain the same.
• The current remains the same
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ELECTROMAGNETIC SPECTRUM
Visible spectra
• Continuous Spectrum
• Line Emission Spectrum
• Line Absorption Spectrum
Spectrum
Different atoms, due to different arrangement of electrons, absorb (and emit) different frequencies
of light. The light that is emitted can be made to produce patterns (spectra) and this can be used to
identify the actual atoms involved.
Essentially, you shine white light through some atoms in the gaseous state, and observe how the
light gets affected. The picture formed by the light (spectrum), then tells about the structure of the
atom itself. It is the electron arrangement inside the atoms that actually absorbs the light when it
passes through
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This is a triangular piece of solid glass that is used to separate (disperse) light into different
directions thus making it possible to view each frequency separately. Otherwise all the frequencies
of the light will overlap, and cannot be identified individually. In other words, this prism refracts the
light into separate directions.
Here light is shone directly through the prism, and a Continuous Spectrum is formed.
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Since the light is affected (changed) because it went through the hot gas first, the spectrum
produced is different. Most of the light has disappeared! They have actually been absorbed by the
atoms of the gas!
Just a few lines are produced, hence this is called a Line Emission Spectrum
This is like a bar-code. Each gas through which the light passes, produces a unique pattern. So
these patterns can be used to identify an unknown gas!
Most of the spectrum is still there, just a few lines are missing. These lines of colour (frequencies)
have been absorbed by the gas, leaving the rest to come through to the prism. And hence form this
pattern. This is called a Line Absorption Spectrum
Emission spectrum
Absorption spectrum
The frequencies/wavelengths of light that are absorbed by cold the hydrogen gas correspond
exactly to the frequencies/wavelengths of light that are emitted by hot hydrogen gas.
Line absorption spectra are produced when specific photons of light are absorbed by electrons,
which then make transitions to higher energy levels within the atom.
The wavelengths missing in an absorption spectrum are those present in the line emission
spectrum of the same element.
Which a cold element will absorb the same frequencies/ wavelength it emits when hot.
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Source Produced by white hot dense Hot gases under low Produced when white ligh
substances. e.g. the Sun, the pressure. e.g. gas discharge passes through a cold gas
tungsten filament of a lamp. tube. at low pressure.
Transition of Many transitions between Electrons make transitions Electrons make transitions
electrons energy levels are possible; all from higher energy levels to from lower energy levels to
wavelengths of light are lower energy levels. higher energy levels.
emitted.
Photons Photons of all energies are Photons of specific energies Photons of specific energies
emitted/ emitted. are emitted. are absorbed.
absorbed
When an excited electron falls to a lower energy level it emits a photon. The energy of the emitted
photon (E = hf ) depends on the difference in energy between the two levels:
hf = Ef – Ei
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Recap
1. What is meant by the photoelectric effect?
This is the process whereby electrons are ejected from a metal surface when light of suitable
frequency is incident on that surface.
11. The frequency of a photon of light is 3 x 1015 Hz. It is shone onto nickel metal which has a work
function of 8 x 10-19J. 1.
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11.4. What would happen to the photo-electron speed if the same light was made brighter?
EXAMPLES
QUESTION 1
1.2 In an experiment on the photoelectric effect, a scientist shines red light on a metal surface
and observes that electrons are ejected from the metal surface. Later the scientist shines
blue light, with the same intensity as the red light, on the same metal surface.
Which ONE of the statements below will be the CORRECT observation as a result of this
change?
A The number of ejected electrons per second will increase.
B The number of ejected electrons per second will decrease.
C The speed of the ejected electrons will decrease.
D The maximum kinetic energy of the ejected electrons will increase. (2)
1.3 The possible atomic transitions in an excited atom of an element are shown below.
Which transition will produce the spectral line with the longest wavelength?
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A P
B Q
C R
D S (2)
1.4 The diagram below shows four energy levels of an atom. The transition of the atom from
higher energy levels to lower energy levels results in the emission of a photon.
Which ONE of the following transitions will lead to the emission of a photon with the
shortest wavelength?
A From energy level E2 to energy level E1
B From energy level E3 to energy level E0
C From energy level E3 to energy level E2
D From energy level E1 to energy level E0 (2)
1.5 When light of a certain wavelength is incident on a metal surface, no electrons are ejected.
Which ONE of the following changes may result in electrons being ejected from the metal
surface?
A Increase the intensity of the light.
B Use light with a much shorter wavelength.
C Use metal with a larger work function.
D Increase the surface area of the metal. (2)
[10]
QUESTION 1 (June 2015)
2.1 In the diagram below, green and blue light are successively shone on a metal surface. In
each case, electrons are ejected from the surface.
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2.2 The wavelength associated with the cut-off frequency of a certain metal is 330 nm.
2.2.1 Calculate the work function of the metal (4)
2.2.2 Calculate the maximum speed of an electron ejected from the surface of the metal
when light of frequency 1,2 x 1015 Hz is shone on the metal (5)
[12]
QUESTION 3 (Examplar 2014)
Graph P below shows how the maximum kinetic energy of electrons emitted from the cathode of a
photoelectric cell varies with the frequency of the incident radiation.
3.2.1 Work function of the metal used as cathode in the photocell (3)
3.2.2 Velocity of photoelectrons emitted when the frequency of the incident light is
8 x 1014 Hz (5)
3.3 The photocell is now replaced with another one in which the work function of the cathode is
TWICE that of the metal in the first cell.
The maximum kinetic energy versus frequency graph, Q, for this cathode is now drawn on
the same set of axes as graph P.
3.3.1 How will the gradient of graph Q compare to that of graph P? Write down GREATER
THAN, SMALLER THAN or EQUAL TO. Explain the answer. (2)
3.3.2 What will the value of the x-intercept of graph Q be? Explain how you arrived at the
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Answer. (2)
[14]
A graph is plotted of the maximum kinetic energy (Ek) against the frequency of the incident light.
When the straight line graph is extrapolated, it intercepts the x-axis at fo = 4,29 x 1014 Hz.
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4.5.1 Briefly explain how this type of spectrum is formed by referring to electron
transitions in atoms. (2)
4.5.2 Write down ONE important use of line emission spectra. (1)
[14]
Electrons in excited state fall back to ground state/ lower energy state.
Energy radiated as light.
To identify elements.
Accepted
To determine the temperature of stars/ Fluorescent lights/ Neon signs./
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___________________________________65 marks___________________________________
SOLUTIONS TO EXAMPLES
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EXAM TUTORIAL 6
QUESTION 1
1.1 In an experiment on the photoelectric effect, the frequency of the incident light is high
enough to cause the removal of electrons from the surface of the metal.
The number of electrons ejected from the metal surface is proportional to the …
A kinetic energy of the electrons.
B number of incident photons.
C work function of the metal.
D frequency of the incident light. (2)
1.2 A line emission spectrum is formed when an excited atom moves from a...
A higher to a lower energy level and releases energy
B higher to a lower energy level and absorbs energy
C lower to a higher energy level and releases energy
D lower to a higher energy level and absorbs energy (2)
1.3 Which ONE of the following graphs best represents the relationship between the maximum
kinetic energy of the emitted photoelectrons and the intensity of the incident radiation?
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1.4 When light of a certain frequency is incident on the cathode of a photocell, the ammeter in
the circuit registers a reading.
The frequency of the incident light is now increased while keeping the intensity constant.
Which ONE of the following correctly describes the reading on the ammeter and the reason
for this reading?
1.5 Light spectra help to identify elements. White light is passed through a cold gas and then
through a prism as shown in the sketch below.
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2.2 State how this increase in intensity will affect the reading on the ammeter. Choose from
INCREASE, DECREASE or REMAIN THE SAME.
When the frequency of the incident light is 5,9 x 1014 Hz, the maximum recorded kinetic energy of
photoelectrons is 2,9 x 10-19 J.
2.3 Calculate the maximum wavelength (threshold wavelength) of the incident light that will emit
an electron from the cathode of the photo-electric tube. (5)
The maximum kinetic energy of the photoelectrons ejected increases when light of a higher
frequency is used.
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3.6 White light shines through a cold diluted gas and photons with specific frequencies are
absorbed and appear as black lines in the continuous spectrum.
Differentiate between an absorption spectrum and a line emission spectrum. (2)
[14]
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In the experiment using one of the metals above, the maximum speed of the ejected
electrons was recorded as 4,76 x 105 m·s-1 for light of wavelength 420 nm.
5.1.3 Identify the metal used in the experiment by means of suitable calculations. (5)
5.2 The simplified energy diagrams showing the possible electron transitions in an atom are
shown
Using the letters P, Q, R and S, identify the lines that CORRECTLY show transitions that
will result in the atom giving off an EMISSION SPECTRUM.
Give a reason for the answer. (4)
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Q and S
Emission spectra occur when excited atoms /electrons drop from higher energy levels to lower
energy levels.
(Characteristic frequencies are emitted.)
QUESTION 6
During an experiment to determine the work function of a certain metal light of different frequencies
was shone on the metal surface and the corresponding kinetic energies of the photoelectrons were
recorded as shown in the table below.
6.2 Use the data in the table above to draw a graph of kinetic energy versus frequency on the
graph paper provided. (5)
6.4 Use your graph to determine the work function of the metal. (3)
[14]
Minimum amount of energy needed to remove an electron from the surface of a metal/conducting
material.
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fo = 5,4 x 1014 Hz
Threshold frequency
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MCQ (Recap)
1.1 What is meant by the photoelectric effect?
A emission of protons from the surface of a substance when light is shone onto it
B emission of electrons from the surface of a substance when light is shone onto it
C emission of neutrons from the surface of a substance when light is shone onto it
D emission of atoms from the surface of a substance when light is shone onto it (2)
1.2 What is the minimum amount of energy required to remove an electron from the surface of
a substance?
A photon energy
B kinetic energy
C potential energy
D work function (2)
1.5 Light reaching the Earth from a galaxy moving away is shifted towards …
A Greater velocities
B Higher frequencies
C Longer wavelengths
D Shorter wavelengths (2)
1.6 An atom in its ground state absorbs energy E and is excited to a higher energy state. When
the atom returns to the ground state, a photon with energy...
A E is absorbed.
B E is released.
C less than E is released.
D less than E is absorbed. (2)
1.7 Light of a certain frequency is incident on a metal surface and photoelectrons are emitted
from the surface.
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1.8 The spectrum of an element from a star shows some absorption lines. These lines are
produced because …
A atoms absorb energy when moving from an excited state to a lower energy state.
B a cold gas absorbs certain frequencies of light passing through it.
C atoms release energy when moving from an excited state to a lower energy state.
D a hot gas absorbs certain frequencies of light passing through it. (2)
1.10 The wavelength of a monochromatic light source P is twice that of a monochromatic light
source Q. The energy of a photon from source P will be … of a photon from source Q.
LONG QUESTIONS
QUESTION 2 (EC/SEPTEMBER 2016)
Different frequencies of light are shone onto the surface of a metal. The graph below shows the
relationship between the kinetic energy of photo-electrons and frequency of the incident light.
2.1 Refer to the graph and write down the threshold frequency of the metal. (1)
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2.2 Give a reason why no photo-electrons are released when light of frequency 45 × 10-19 Hz is
used. (2)
2.3 Calculate the velocity of the ejected electrons when a light with a frequency of 110 × 10-19
Hz is shone onto the metal. (5)
2.4 What effect will an increase in the intensity of radiation have on the velocity of ejected
electrons?
Explain your answer. (2)
2.5 The wavelength of the incident light is kept constant while the intensity is increased.
What effect will this change have on the following:
2. 5.1 the reading on the ammeter. Explain the answer. (2)
2. 5.1 the threshold frequency of the metal plate. (1)
[10]
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3.3 Calculate the maximum kinetic energy, EK, of an electron ejected from the sodium metal. (4)
3.4 The intensity of the incident ultraviolet light was then increased.
3.4.1 Give a reason why this change does NOT affect the maximum kinetic energy of the
ejected photoelectrons. (1)
3.4.2 How does the increased intensity affect the reading on the ammeter? Write down
only INCREASES, DECREASES or REMAINS THE SAME. (1)
3.4.3 Explain the answer to QUESTION 3.4.2. (2)
[14]
In the experiment, the brightness of the light incident on the metal surface is increased.
4.2 State how this change will influence the speed of the photoelectrons emitted.
Choose from INCREASES, DECREASES or REMAINS UNCHANGED. (1)
4.3 Show by means of a calculation whether the photoelectric effect will be OBSERVED or
NOT OBSERVED, if monochromatic light with a wavelength of 6 x 10-7 m is used in this
experiment. (5)
One of the radiations used in this experiment has a frequency of 7,8 x 1014 Hz.
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