Home Work #2
Home Work #2
Home Work #2
a) Dissolved-oxygen déficit
𝑚𝑔
𝐷 = 𝐷𝑂!"# − 𝐷𝑂"$# = 9 − 5 = 4
𝑙
𝑚𝑔
𝐷% = 4
𝑙
1 𝑘+ 𝐷% ∗ (𝑘+ − 𝑘* )
𝑡&'() = ∗ ln 1 ∗ 21 − 67
𝑘* − 𝑘+ 𝑘* 𝑘* ∗ 𝐿%
𝑚𝑔
𝐿% = 25
𝑙
𝑘* ∗ 𝐿% , , .!
𝐷, = ∗ @𝑒 -.! ∗0 − 𝑒 -." ∗0 B + 𝐷% ∗ 𝑒 - , ∗0
(𝑘+ − 𝑘* )
𝐷, = 7.44 𝑚𝑔/𝐿
d) Dissolved-oxygen concentration
Ex. 7.55
𝑣 40 2 𝑚
𝑉1 = =I K∗I K = 1.6
𝑛 0.5 100 𝑑𝑎𝑦
𝐿 100
𝑡= = = 62.5 𝑑𝑎𝑦𝑠
𝑣 1.6
Ex. 7.57
a) Relation
For trichloroethylene
𝐾
𝐾2$ = ⟶ 𝐾7 = 𝑓2$ ∗ 𝐾2$ = 0.02 ∗ 190.6 = 3.81 𝑐𝑚6 /𝑔
𝑓2$
Eq. 7.22
𝑔6
𝜌9 2.3 6
𝑐𝑚 ∗ 3.81𝑐𝑚 = 30.2
𝑅8 = 1 + ∗ 𝐾7 = 1 +
𝜂 0.3 𝑔
Ex. 8.5
𝑚𝑔 𝑚𝑔
18 ∗ 0.5 = 9 𝑎𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 𝑎𝑠 𝐶𝑎𝐶𝑜3
𝐿 𝐿
Ex 8.9
a) Tank volume
50𝑚6 1𝑑𝑎𝑦 1𝑚𝑖𝑛
𝑉 =𝑄∗𝜃 = ∗ 60𝑠 ∗ ∗ = 0.035𝑚6
𝑑𝑎𝑦 1440𝑚𝑖𝑛 60𝑠
b) Power requeriment
𝑚𝑔
𝐶𝑎(𝐻𝐶𝑂6 )+ = 200
𝐿
𝑚𝑔
𝑀𝑔(𝐻𝐶𝑂6 )+ = 270 − 200 = 70
𝐿
𝑚𝑔
𝑀𝑔𝑆𝑂; = 200 − 70 = 130
𝐿
Lime needed:
𝑔
𝑚𝑔 𝐶𝑎𝐶6 56 𝑚𝑜𝑙𝑒 𝐶𝑎𝑂
𝐿𝑖𝑚𝑒 𝑖𝑛 𝑘𝑔 = (40 + 200 + 30 + 130 + 2 ∗ 70) ∗ 𝑔
𝐿 100 𝑚𝑜𝑙𝑒 𝐶𝑎𝐶𝑂6
15 ∗ 10< 𝑔𝑎𝑙 3.78𝐿 𝑘𝑔 𝑙𝑖𝑚𝑒
∗ ∗ ∗ = 20,172 𝑘𝑔
𝑑𝑎𝑦 𝑔𝑎𝑙 0.85 𝑘𝑔 𝐶𝑎𝑂
=>$1$2# *@< => B1" $2# /=%DE .> *:∗*@$ >1D 6.H5?
Soda ash in kg = 130 ?
)∗@ *@@ => $1$2# /=%DE
B ∗ @*@$ =>B ∗ @ F1G
B∗@ >1D
B∗
.> 90D. I%F1 1IJ
@@.K .> I%F(0= &1'9%L1)EB = 8,861 𝑘𝑔