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Home Work #2

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HOME WORK #2

Anton Garcia Ferri


Ex. 7.35

a) Dissolved-oxygen déficit

𝑚𝑔
𝐷 = 𝐷𝑂!"# − 𝐷𝑂"$# = 9 − 5 = 4
𝑙

b) Critical point in time and distance

𝑚𝑔
𝐷% = 4
𝑙
1 𝑘+ 𝐷% ∗ (𝑘+ − 𝑘* )
𝑡&'() = ∗ ln 1 ∗ 21 − 67
𝑘* − 𝑘+ 𝑘* 𝑘* ∗ 𝐿%

𝑡&'() = 2.6 𝑑𝑎𝑦𝑠

c) Dissolved-oxygen decificit at critical point

𝑚𝑔
𝐿% = 25
𝑙

𝑘* ∗ 𝐿% , , .!
𝐷, = ∗ @𝑒 -.! ∗0 − 𝑒 -." ∗0 B + 𝐷% ∗ 𝑒 - , ∗0
(𝑘+ − 𝑘* )

𝐷, = 7.44 𝑚𝑔/𝐿

d) Dissolved-oxygen concentration

𝐷𝑂"$# = 𝐷𝑂!"# − 𝐷 = 9 − 7.44 = 1.56 𝑚𝑔/𝐿

Ex. 7.55

a) Time to reach the drinking-water well

𝑣 40 2 𝑚
𝑉1 = =I K∗I K = 1.6
𝑛 0.5 100 𝑑𝑎𝑦

𝐿 100
𝑡= = = 62.5 𝑑𝑎𝑦𝑠
𝑣 1.6
Ex. 7.57

a) Relation

𝑙𝑜𝑔𝐾2$ = 0.903 ∗ 𝑙𝑜𝑔𝐾23 + 0.094

For trichloroethylene

𝑙𝑜𝑔𝐾2$ = 0.903 ∗ 2.42 + 0.094 = 2.28


𝐾2$ = 10+.+5 = 190.55 𝑐𝑚6 /𝑔
Table 3.9

𝐾
𝐾2$ = ⟶ 𝐾7 = 𝑓2$ ∗ 𝐾2$ = 0.02 ∗ 190.6 = 3.81 𝑐𝑚6 /𝑔
𝑓2$
Eq. 7.22

𝑔6
𝜌9 2.3 6
𝑐𝑚 ∗ 3.81𝑐𝑚 = 30.2
𝑅8 = 1 + ∗ 𝐾7 = 1 +
𝜂 0.3 𝑔

We do the same for all the compounds

Compound 𝑙𝑜𝑔𝐾23 𝐾2$ (𝑐𝑚6 /𝑔) 𝐾7 (𝑐𝑚6 /𝑔) 𝑅8


trichloroethylene 2.42 190.6 3.8 30.2
hexachlorobenzene 5.8 10:.66 4,289.7 32,889
dichloromethane 1.31 18.92 0.38 3.9

Ex. 8.5

a) Alkalinity consumed as CaCo3

𝑚𝑔 𝑚𝑔
18 ∗ 0.5 = 9 𝑎𝑙𝑘𝑎𝑙𝑖𝑛𝑖𝑡𝑦 𝑎𝑠 𝐶𝑎𝐶𝑜3
𝐿 𝐿

Ex 8.9

a) Tank volume
50𝑚6 1𝑑𝑎𝑦 1𝑚𝑖𝑛
𝑉 =𝑄∗𝜃 = ∗ 60𝑠 ∗ ∗ = 0.035𝑚6
𝑑𝑎𝑦 1440𝑚𝑖𝑛 60𝑠

b) Power requeriment

𝑃 = 𝐺 + ∗ 𝑈 ∗ 𝑉 = 900 ∗ 0.035 ∗ 0.001307 = 37.05𝑊


Ex. 8.16

a) Lime and soda ash in kg

𝑚𝑔
𝐶𝑎(𝐻𝐶𝑂6 )+ = 200
𝐿
𝑚𝑔
𝑀𝑔(𝐻𝐶𝑂6 )+ = 270 − 200 = 70
𝐿
𝑚𝑔
𝑀𝑔𝑆𝑂; = 200 − 70 = 130
𝐿

Lime needed:

𝑔
𝑚𝑔 𝐶𝑎𝐶6 56 𝑚𝑜𝑙𝑒 𝐶𝑎𝑂
𝐿𝑖𝑚𝑒 𝑖𝑛 𝑘𝑔 = (40 + 200 + 30 + 130 + 2 ∗ 70) ∗ 𝑔
𝐿 100 𝑚𝑜𝑙𝑒 𝐶𝑎𝐶𝑂6
15 ∗ 10< 𝑔𝑎𝑙 3.78𝐿 𝑘𝑔 𝑙𝑖𝑚𝑒
∗ ∗ ∗ = 20,172 𝑘𝑔
𝑑𝑎𝑦 𝑔𝑎𝑙 0.85 𝑘𝑔 𝐶𝑎𝑂

Soda ash needed:

=>$1$2# *@< => B1" $2# /=%DE .> *:∗*@$ >1D 6.H5?
Soda ash in kg = 130 ?
)∗@ *@@ => $1$2# /=%DE
B ∗ @*@$ =>B ∗ @ F1G
B∗@ >1D
B∗
.> 90D. I%F1 1IJ
@@.K .> I%F(0= &1'9%L1)EB = 8,861 𝑘𝑔

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