Ch02 3
Ch02 3
Ch02 3
A refrigerator
operating with its
door open in a well-
sealed and well-
insulated room
2
FORMS OF ENERGY
Energy can exist in numerous forms such as thermal, mechanical, kinetic,
potential, electric, magnetic, chemical, and nuclear, and their sum
constitutes the total energy, E of a system.
Thermodynamics deals only with the change of the total energy.
Macroscopic forms of energy: Those a system possesses as a whole
with respect to some outside reference frame, such as kinetic and potential
energies. It is related to motion and the influence of some external effects
such as gravity, magnetism, electricity, and surface tension.
Kinetic energy, KE: The energy that a system possesses as a result
of its motion relative to some reference frame.
Potential energy, PE: The energy that a system possesses as a result
of its elevation in a gravitational field.
Microscopic forms of energy: Those related
to the molecular structure of a system and the
degree of the molecular activity.
Internal energy, U: The sum of all the
microscopic forms of energy 3
• Thermodynamics provides no information about the absolute value of the
total energy.
• It deals only with the change of the total energy, which is what matters in
engineering problems.
• Thus the total energy of a system can be assigned a value of zero at some
convenient reference point.
• The change in total energy of a system is independent of the reference
point selected.
• Closed systems whose velocity and elevation of the center of gravity
remain constant during a process are frequently referred to as stationary
systems.
• The change in the total energy ΔE of a stationary system is identical to the
change in its internal energy ΔU.
Total energy
of a system
Energy of a system
per unit mass
Total energy
per unit mass
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Mechanical Energy
Mechanical energy: The form of energy that can be converted to
mechanical work completely and directly by an ideal mechanical device such
as an ideal turbine.
Kinetic and potential energies: The familiar forms of mechanical energy.
𝑷 Flow energy due to
Mechanical energy of a 𝝆 pressure difference
flowing fluid per unit mass
9
Any other example of turbine working on pressure difference?
Steam turbines
11
ENERGY TRANSFER BY HEAT
Heat: The form of energy that is transferred between two systems (or a
system and its surroundings) by virtue of a temperature difference.
12
ENERGY TRANSFER BY HEAT
• Energy transfer in form of heat (Q) takes place between the body
and the surrounding medium until thermal equilibrium is established.
− An energy interaction is heat only if it takes place because of a
temperature difference.
− There cannot be any heat transfer between two systems that are at
the same temperature.
13
Heat transfer
per unit mass