Chemistry Pmc-1-36 (Paid) Paper

PMC (PAID TEST - 01)
CHEMISTRY >> Solids

1. Which type of movement is shown by the atoms of the solid?
A. Translational motion
B. Vibrational motion
C. Rotational motion
D. Linear motion
CHEMISTRY >> Introduction to Fundamental Concepts of Chemistry
2. The mass of one mole of electron is
A. 1.8mg
B. 0.184mg
C. 0.55 mg
D. 0.64 mg
CHEMISTRY >> Gases
3. Which of the following term is constant in Boyle's law?
A. Pressure
B. Temperature
C. Volume
D. Density
CHEMISTRY >> Chemical Equilibrium
4. Equilibrium constant for Ideal gases in terms of partial pressure in denoted by
A. Kc
B. K
C. Kp
D. None of these
CHEMISTRY >> Aldehydes and ketones
5. What is the Hybridization of carbon atom in Aldehyde group?
A. Sp2
B. Sp3
C. Sp
D. dsp2
CHEMISTRY >> Carboxylic Acids
6. Acetic acid is soluble in;
A. Water, Alcohol, Ether
B. HCl, HBr, HI
C. Bromine water
D. All of these
CHEMISTRY >> Alkyl Halides
7. Which of the following gives primary alcohol with Grignard reagent ?
A. Acetaldehyde
B. Epoxide
C. Acetone
D. Carbon dioxide
CHEMISTRY >> Chemistry of Hydrocarbons
8. Which of the following reactions are not given by benzene?
A. Elimination
B. Addition
C. Substitution
D. Dehydration
CHEMISTRY >> Atomic Structure
9. The e/m value is maximum for ____gas because of ____value of "m" for positive rays obtained from it.
A. Oxygen gas, lowest
B. hydrogen gas, highest
C. hydrogen gas ,lowest
D. helium gas ,highest
Chemistry PMC (Paid Test-1-36) Paper (1) Composed By: M. Hanif Mahar
CHEMSTRY >> Alcohol and Phenols
10. How ethanoic acid is formed from ethanol?
A. By reduction
B. By oxidation
C. By alkylation
D. By dehydration
11. The radius of an electron orbit in a hydrogen atom is of the order of
A. 1 -8 m
B. 1 -1 m
C. 1 -11 m
D. 1 -13 m
CHEMISTRY >> S and P Block elements
12. Binary compounds of halogens with alkali metals are called
A. Oxides
B. Hydrides
C. Halides
D. Nitriles
CHEMISTRY >> Macromolecules
13. Which of the following is protein digesting enzyme?
A. Trypsin
B. Pepsin
C. Protease
D. All of these
CHEMISTRY >> Solids
14. This is not a molecular solid
A. sugar
B. ice
C. boron nitride
D. solid iodine
CHEMISTRY >> Reaction Kinetics
15. Type of reactants or product decides the nature of method adapted for finding
A. Rate constant
B. Enthalpy
C. Temperature
D. Rate of a Reaction
CHEMISTRY >> Liquids
16. soap and detergents show cleansing action because of the presence of __of molecules
A. opposite poles
B. polar part
C. non polar part
D. positive end
17. Structure of ice is similar to which of the following ?
A. Liquid water
B. Diamond
C. Graphite
D. Sucrose
18. In SN₂ reactions, the hybridization of carbon in moving from substart to transition state changes from ?
A. Sp² to sp³
B. sp to sp²
C. sp³ to sp²
D. sp to sp³
19. Which of the following compounds can be prepared by using grignard reagents?
A. Alkanes
B. Alcohols
C. Carboxylic acids
D. All of these
CHEMISTRY >> Transition Elements
20. Geometry of the complex compounds usually depends upon
A. type of ligands
B. types of hybridization in the elements of ligands
C. hybridization of central metal
D. All of above
CHEMISTRY >> Chemical Bonding
21. Electron affinity of an atom is the energy released when an electron _to an empty or partially
filled orbital of an atom to form___
A. removed,cation
B. added,cation
C. added, anion
D. removed, anion
22. In an Irreversible reaction the tendency of it to go in reverse direction is
A. High
B. low
C. negligible
D. none Of these
23. Atomicity is determined by number of ______present in a molecule
A. dots
B. atoms
C. sub particles
D. electrons
CHEMISTRY >> Alcohol and Phenols
24. An aromatic compound that can obtained from coal tar is
A. benzene
B. toluene
C. phenol
D. diphenylmethane
25. How acetic acid is commercially synthesized;
A. from acetylene hydrogenation
B. from oxidation of ethyl alcohol
C. from oxidation of benzaldehyde
D. all of these
26. In case of HOCH₂CH₂CH₂COOH, from were numbering is started ?
A. OH group is given number 1
B. Carboxylic acid is given Number 1 position
C. COOH is given number 3 position
D. COOH is given number 4 position
27. The species which donates electrons to the central metal atom in the coordination sphere is called:
A. Anion
B. Cation
C. The ligand is positively charged
D. Acid
28. The rate equation is an
A. Experimental expression
B. Theoretical expression
C. based on Hit and Trail
D. All Of these
CHEMISTRY >> Fundamental Principles of Organic Chemistry
29. Which of the following is called as refined form of mineral oil?
A. Coal tar
B. Petroleum
C. Crude oil
D. Kerosine oil
30. Which of the following undergoes cannizzaro reaction_____?
A. Benzaldehyde
B. Acetone
C. Benzophenone
D. Benzyl alcohol
31. The products of SN₁ reactions are formed with______?
A. Retention in configuration
B. Inversion in Configuration
C. 50% retention and 50% inversion in configuration
D. All of these
32. Heavy water contain isotope of Hydrogen
A. protium
B. deuterium
C. tritium
D. both A & C
CHEMISTRY >> Gases
33. In Hydrogen bonding, the O-atom of water molecule forms a ____bond with H-atom of other
molecule by sharing its ____ of electron
A. ionic, one
B. coordinate covalent, one lone pair
C. covalent,2 lone pair
D. all of these
34. How many hydrogen atoms are attached to tertiary carbon in tertiary butyl alcohol?
A. 3
B. 2
C. 1
D. 0
35. Which of the following oxide is formed by alkali metals?
A. Basic oxides
B. Acidic Oxides
C. Amphoteric oxides
D. Both b and c
36. If n = 4 it will contain sub shells
A. s
B. p
C. s,p,d
D. s,p,d,f
CHEMISTRY >> Solids
37. Energy in formation of a crystal lattice is
A. Absorbed
B. Released
C. Dependent on Crystal Size
D. None of these
38. The covalent radius of an element is __of the single bond length b/w two similar atoms
covalently bonded in a molecule
A. one third
B. one fourth
C. half
D. quarter
39. ______is used to measure atomic radii
A. Gamma rays
B. alpha rays
C. X-rays
D. beta rays
40. Which of the following is Bayer's reagent ?
A Br₂/H₂O
B Dilute alkaline KMnO₄
C ZnCl₂/HCl
D Br₂/CCl₄
41. In aldol condensation, nucleophile is_______?
A. Hydroxyl ion
B. Carbocation
C. Carbanion
D. Water
CHEMISTRY >> Thermochemistry and Energetic of Chemical Reactions
42. Strong acid can be involved in a spontaneous reaction which is termed as
A. Addition Reaction
B. Substitution Reaction
C. Neutralization Reaction
D. Reversible Reaction
43. Which of the following has greater polarizability?
A. N2
B. Cl2
C. O₂
D. I2
44. If no of moles of products are more than those of reactants, volume in the equilibrium
expression appears in
A. denominator
B. Numerator
C. As Exponent
D. None of these
CHEMISRY >> Alcohol and Phenols
45. In which of the following reaction C-O bond of alcohol breaks?
A. Reaction with SOCl₂
B. Dehydration
C. Esterification
D. All of these
CHEMSTRY >> Fundamental Principles of Organic Chemistry
46. Organic compounds obtained from
A. living things
B. Non living
C. fossils
D. sea's water
47. Acetic acid is used in making ______?
A. Neoprene
B. Chloroprene
C. Silk
D. Polystyrene
CHEMSTRY >> Electrochemistry
48. Electrolysis is a
A. Spontaneous Reactions
B. Oxidation-reduction reaction
C. Reduction Reaction
D. Oxidation Reaction
49. The number of molecules taking part in rate determining step of a reaction is called
as________?
A. Order of reaction
B. Molecularity
C. Intermediate
D. Substrates
CHEMISTRY >> Solids
50. The electrical conductivity of metal sometimes decreases with the
A. increase in pressure
B. increase in temperature
C. decrease in temperature
D. decrease in pressure
51. Which one of the following alkali metals forms only normal oxide when it reacts with O2?
A. Lithium
B. Sodium
C. Potassium
D. Rubidium
52. The only thing which can predict that reaction will be spontaneous or nonspontaneous is
A. Enthalpy Change
B. Free Energy of the system
C. Energy Change
D. Temperature Change
CHEMISTRY >> Gases
53. If pressure is reduced to one half and temperature of a gas is doubled, what will be volume
A. reduced 4 times
B. increased 4 times
C. remains same
D. gets doubled
54. When are the prefixes ortho, para, and para used?
A. In alkynes to identify the position of triple bond
B. In arenes to identify the position first substitution
C. In arenes to identify the position second substitution
D. In all hydrocarbons to identify the position functional group
55. If anyone of the products concentration is plotted against time instead of reactants the curve
obtained will be
A. Parabolic
B. Rising
C. Falling
D. Elliptical
56. _________conducts nerve impulse in brain
A. serotonin
B. aspartame
C. ascorbic acid
D. hydrazine
1. Following is termed as hydroxyl derivative of alkanes
A. carboxylic
B. Aldehydes
C. Phenols and ethers
D. Alcohols
CHEMISTRY >> Solids
2. Melting Point of Non Polar Molecular solids are
A. High
B. Low
C. Sharp
D. None of these
CHEMISTRY >> Gases
3. The density of liquids are _than gases but _______to solids
A. lesser, closer
B. greate,closer
C. smaller, greater
D. lesser, greater
4. H-bonding is a type of____________?
A. Chemical bonding
B. Ion dipole force
C. Dipole-dipole force
D. Polar force
5. Which of the following properties are associated with transition metals ?
A. Color
B. Complex formation
C. Use as catalyst
D. All of these
6. How much percentage of reactants is converted into products during half life period
A. 40%
B. 70%
C. 50%
D. 30%
CHEMISTRY >> Electrochemistry
7. Salt Bridge is used for the purpose of:
A. Producing Electrons
B. Circuit Completion
C. Increasing speed of electrons
D. All of these
8.The breakdown of molecular ions from natural products give important information about
A. size
B. position
C. shape
D. structure
9. Quantum numbers specify the _______of electron.
A. shape
B. energy
C. position
D. all of these
10. Which of the carboxylic acid in diluted form is used as vinegar?
A. Formic acid
B. acetic acid
C. benzoic acid
D. amino acid
11. In Thermodynamic terms boundary separates___________?
A. Surrounding from the environment
B. Reactants from contamination
C. System from surrounding
D. Products from the surrounding
12. Which of the following is an example of free radical?
A. Br⁺
B. Br⁻
C. Br
D. Cl₂
13. Elements of group 7A are called:
A. good loser
B. good gainer
C. energetic
D. stable
14. Which one is not member of Alkali metals?
A. Na
B. K
C. Cs
D. Mg
15. In Haber’s process the final product ammonia is converted into
A. solid state
B. Liquid state
C. gaseous state
D. None of these
16. SN₂ reactions are ________?
A. 2 step reactions
B. Multistep reactions
C. Single step reactions
D. None of these
17. The specific site at which substrate is attached on the enzyme and converted into product is
called as___?
A. Reaction site
B. Active site
C. Binding site
D. None of these
18. Aldol condensation takes place in the presence of ____?
A. H₂SO₄
B. K₂Cr₂O₇
C. NaOH
D. H₂O/H+
19. Evaporation is a ________process?
A. Exothermic
B. Spontaneous
C. Non-Spontaneous
D. None of these
20. Nucleoprotein are______ proteins which transfer heredity information from one generation
to other.
A. Transport proteins
B. Structural proteins
C. Genetic proteins
D. Regulatory proteins
21. The rate of formation of ammonia is not economical at
A. Low temperature
B. Very high pressure
C. Both A and B
D. None of these
22. SN₁ reactions have which of the following specie formed and consumed in the reaction ?
A. Transition state
B. Intermediate
C. Carbanion
D. Carbene
23. Which of the following has least polarizability ?
A. NH3
B. H₂O
C. HF
D. CH₄
24. Large hydrocarbons are converted into smaller hydrocarbons by a process called as?
A. Reforming
B. Distillation
C. Cracking
D. Decomposition
25. An atom is composed of electrons, protons, neutrons and
A. hyprone
B. neutrino
C. anti neutrino
D. all of these
26. Enzymes are ______?
A. Non-specific in action
B. Very reactive
C. Highly specific
D. Volatile
27. In stoichiometry, we follow law of ___________ while doing calculations.
A. conservation of mass
B. definite proportion
C. both A & B
D. none of these
28. Decomposition of Water into Hydrogen and oxygen is a
A. Reversible Reaction
B. Endothermic Reaction
C. Exothermic Reaction
29. Which is the correct order of decreasing acidity of Lewis acids?
A. BBr3 > BCl3 > BF3
B. BF3 > BCl3 > BBr3
C. BCl3 > BF3 > BBr3
D. BBr3 > BF3 > BCl3
CHEMISTRY >> Solids
30. Which of the following solids shows hydrogen bonding
A. ionic
B. metallic
C. covalent
D. molecular
31. Alkyl iodides can not be prepared directly by the halogenation of alkanes because ?
A. Iodine reacts slowly
B. Iodine reacts reversibly
C. HI formed reduces alkyl iodide again to starting material
D. All of these
32. Electron affinity is the measure of ____ for extra electron
A. repulsion of electron
B. attraction of electron
C. attraction of nucleus
D. repulsion of nucleus
33. Which of the following test is not given by Aldehyde ?
A. Benedict test
B. Tollen's test
C . Nitroprusside test
D. Fehling's test
34. Standard Reduction potential is found by dipping the electrode in its own Ion with molarity
equals to
A. 0.1
B. 1
C. 1.5
D. 0
35. The compounds which have -CN group are called as______?
A. Aldehydes
B. Imines
C. Amines
D. Nitriles
36. The bonding pair of electron are equally shared b/w the atoms in
A. HF
B. HCl
C. H2O
D. H2
37. Evaporation of water is an example of?
A. Endothermic reaction
B. Exothermic reaction
C. Spontaneous reaction
D. Chemical; reaction
38. Which one of the following is common name of Butanoic acid ?
A. Butyric acid
B. Barbaric acid
C . Iso-butyric acid
D. Iso-Barbaric acid
39. What is the other name of 2,4,6-trinitrophenol?
A. Picric acid
B. Nitrophenol
C. TNT
D. Benzophenone
40. Which of the following reaction takes place when alkyl halide react with KOH in water ?
A. Substitution reaction
B. Elimination reaction
C. Addition reaction
D. None of these
41. The method which is used on industrial scale for production of alcohol from alkene ?
A. Hydrohalogenation of alkenes
B. Dehydration of alkenes
C. Hydration of alkenes
D. Hydroxylation of alkenes
42. Hydrolysis means reaction with:
A. Oxygen
B. Hydrogen
C. Water
D. Air
43. The strongest acid among the following is:
A. carbolic acid
B. H2O
C. Methanol
D. Butanoic acid
44. Pressure cooker works on which principle?
A. Decrease in external pressure increase the boiling point
B. Increase in external pressure decrease the boiling point
C. Increase in external pressure increase the boiling point
D. None of these
45. Who discovered positive rays also called protons and when?
A. Chadwick,1895
B. Goldstein,1886
C. Rutherford,1885
D. J.Perrin,1885
46. What is the Hybridization of carbon in ethene?
A. sp²
B. sp³
C. sp
D. None of these
47. The general name of ore CaSO4. H2O is
A. Gypsum
B. Dolomite
C. Calcite
D. Plaster of Paris
48. Which of the following ester give Jasmine Flavour ?
A. Ethyl acetate
B. Octyl Acetate
C. Amyl Butyrate
D. Benzyl Acetate
49. What is the enthalpy of solution of NH4Cl?
A. 15 Kj/mol
B. -17kJ/mol
C. 16.2 kJ/mol
D. -16.5kJ/mol
50. Total number of neutron in 5g of D2O ( D is H)
A. .25 NA
B. 1.1 NA
C. 2.5 NA
D. .5 NA
CHEMISTRY >> Solids
51. Sodium metal shows metallic luster is explained by
A. diffusion of Na+
B. oscillation of loose electrons
C. excitation of free protons
D. strong crystal lattice
52. Order of reaction can be determined
A. Theoretically
B. Experimentally
C. Summing up the exponents of rate equation
D. All of these
53. The conversion of n-hexane to benzene by heating is called:
A. Deformation
B. Rearrangement
C. Reformation
D. Aromatization
54. Which of the following is slow step in SN1 reactions?
A. Ionization
B. Formation of carbocation
C. Formation of Double bond
D. Formation of Alkyl halide from Carbocation
55. Oxygen is not released on heating which of the compounds?
A. (NH4)2Cr2O7
B. K2Cr2O7
C. Zn(ClO3)2
D. KClO3
56. An orbital can accommodate at the most _electrons
A. 2
B. 14
C. 1
D. 6
1. Liquids have_________?
A. Definite volume
B. Indefinite volume
C. Irregular volume
D. Changing volume
2. Which of the following give silver mirror test ?
A. Butanal
B. Methanal
C. Ethanal
D. All of these
3. Activated complex is formed due to
A. Pressure
B. Temperature
C. Effective collision
D. Ineffective collision
4. The smallest alkane that shows isomerism is_______?
A. Ethane
B. Butane
C. Pentane
D. Isopropane
CHEMISTRY >> Solids
5. Amorphous solids turns into glass like state from rubber like state, this is called
A. transition
B. crack transition
C. glass transition
D. all of these
6. Methanol is prepared by compressing water gas mixture at pressure
A. 3 atm
B. 2 atm
C. 45 atm
D. 25 atm
7. Which of these are coinage metals ?
A. Au
B. Ag
C. Cu
D. All of these
8. As reaction starts instantaneous rate is
A. Higher than Average rate
B. Lower Than average rate
C. equal to average rate
D. None of these
9. Which of the following gives Markovnikov's product with Propene?
A. HBr
B. H₂SO₄/H₂O
C. HBr
D. All of these
10. Globulin proteins are found in:
A. Animals
B. Plants
C. Human beings
D. None
11. The bond formed b/w NH3 and BF3 is co-ordinate bond because NH3 ____ due to presence of one lone pair.
A. acceptor
B. donor
C. neutral
D. negatively charged
12. The relative abundance of isotopes of elements is measured by
A. atomic spectroscopy
B. ionic spectroscopy
C. mass spectroscopy
D. mass spectrometry
13. Which of the following centers are present in the carbonyl compounds?
A. Electrophilic
B. Nucleophilic
C. Electron deficient
D. All of these
14. Ethene react with Oxygen in the presence of Silver oxide to produce_______?
A. Ethylene oxide
B. Ethylene epoxide
C. Methylene oxide
D. Both a and b
15. With which of the following Grignard reagents react to form Alkanes ?
A. Ammonia
B. Water
C. Methanol
D. All of these
16. In SN₂ reaction, Nucleophile attacks on the electrophilic carbon ?
A. From the side of leaving group
B. Opposite to leaving group
C. In front of leaving group
D. Below leaving group
17. Which one of the following is not an example of fatty acid?
A. Palmitic acid
B. Stearic acid
C. Acetic acid
D. Linolenic acid
18. Which one of the following is not a organic compound?
A. Urea
B. Methane
C. Carbon dioxide
D. Coal
CHEMISTRY >> Gases
19. Steam causes more severe burns than boiling water because it has
A. latent heat of fusion
B. latent heat of vaporization
C. latent heat of sublimation
D. all of these
20. Non-stoichiometric compounds of transition elements are called
A. Hydrates
B. Hydrides
C. Interstitial compounds
D. Binary compounds
21. First Law of thermodynamics is
A. ΔE=ΔH
B. ΔE=q + p
C. ΔE=q + w
D. ΔE=-PΔV
22. Aluminum, has 3 electrons in its valence shell, therefore it has the ability to form ion
A. monovalent
B. divalent
C. trivalent
D. tetravalent
23. Which of the following is an example of good leaving group?
A. Cl⁻
B. ⁻OH
C. ⁻OR
D. ⁻NH₂
24. Three dimensional folding of polypeptide chain results in formation of______.
A. Primary structure
B. Secondary structure
C. Tertiary structure
D. Quaternary structure
25. Salt bridge are used to give
A. Highly conductive path
B. To balance amount of - and + ion in both half cells
C. Both A and B
D. to increase resistivity
26. Which of the following compounds can show metamerism?
A. Aldehydes
B. Carboxylic acids
C. Alcohols
D. Ketones
27. Which catalyst are used in catalytic cracking?
A. Silica, lime
B. Silica,alumina
C. Silica,Soda ash
D. Alumina,Pt
28. In acid catalyzed nucleophilic addition reactions, which of the following property of carbonyl system
enhance ?
A. Electrophilicity
B. Nucleophilicity
C. Basicity
D. Acidity
29. More energy to remove an electron from_______?
A. Half filled subshell
B. Completely Filled Subshell
C. Partially filled subshell
D. Both a and b
30. Kekule's formula shows benzene _______?
A. Highly saturated
B. Highly unsaturated
C. Give Substitution reaction
D. Give elimination reaction
31. Formamint is made up of_________?
A. Formaldehyde + maltose
B. Formaldehyde + lactose
C. Formaldehyde + Galactose
D. Formaldehyde + fructose
CHEISTRY >> Thermochemistry and Energetic of Chemical Reactions
32. What pressure of Oxygen is maintained inside the bomb calorimeter?
A. 200 atm
B. 25 atm
C. 20 atm
D. 75 atm
33. The E.m.f of a Cell is equals to
A. Emf(oxidation) - Emf(Reduction)
B. Emf(oxidation) + Emf(Reduction)
C. Emf(oxidation) x Emf(Reduction)
D. None of these
34. Lactoglobulin a simple protein is found in muscles as well as in _______ too.
A. Fish
B. Liver
C. Brain
D. Plants
35. Glucose is converted into ethanol by the ______ enzyme present in yeast.
A. Invertase
B. Urease
C. Glycolysis
D. Zymase
36. Greater the amount of negative charge on an atom, the size of ion will also be
A. smaller
B. greater
C. higher
D. lower
CHEMISTRY >> Solids
37. symmetry is repetition of ___ when a crystal rotates at 36 along its axis
A. faces
B. edges
C. angles
D. all of these
38. Acetic acid can be used in_________?
A. In synthesizing pickles
B. In paints
C. In pesticides
D. all of these
CHEISTRY >> Atomic Structure
39. According to Bohr's theory Electron should move _nearer to nucleus in an orbit of _radii
A. slower, smaller
B. faster, smaller
C. faster, bigger
D. slower, bigger
40. Nucleophilic reactions of carboxylic acids are due to________?
A. Presence of OH bond
B. Presence of C-O single bond
C. Presence of C-O double bond
D. None of these
41. The properties of liquid crystals are intermediate b/w crystals and
A. anisotropic liquids
B. nematic liquids
C. isotropic liquids
D. liquids
42. Rate constant is denoted by?
A. k
B. kr
C. kv
D. ks
43. In cannizzaro’s reaction, Benzyl alcohol is obtained from
A. benzaldehyde
B. benzene
C. picric acid
D. benzyl chloride
CHEMISTRY >> Gases
44. A real gas obeying Van der Waals equation will resemble to ideal gas if both a & b are
A. small
B. large
C. equal
D. none of these
45. Dalton's law of partial pressure is used to derive the relation between Kc and
A. Temperature
B. Universal Gas constant
C. Δn
D. Kp
46. Calculate mass in grams of 8.694 moles of Ag2CO3
A. 1417.53g
B. 2399.544g
C. 3456.78g
D. 1231.98g
CHEMISTRY >> Solids
47. What are the basic particles of ice crystals
A. atoms
B. anions
C. cations
D. molecules
48. Kekule structure of benzene failed to explain:
A. Benzene reactivity
B. That benzene has dual character
C. That benzene has less heat of formation
D. All
49. What is the correct order of reactivity of alkyl halides ?
A. R-Cl>R-Br>R-F>R-I
B. R-I>R-Br>R-Cl>R-F
C. R-I>R-Cl>R-Br>R-F
D. None of these
50. During oxidation of unsymmetrical ketones which atom is oxidized?
A. Carbonyl carbon
B. Carbon attach to smaller number of hydrogen atom
C. Carbon attach to larger number of Hydrogen atoms
D. Hydrogen
51. The four C-H bond of methane are formed by overlap of
A. sp3-s
B. sp2-s2
C. sp3-s2
D. sp3-sp3
52. LDH-1 is raised in which disease:
A. Rickets
B. Anemia
C. Heart disorders
D. Stroke
53. Aldehydes and ketones can be obtained by the
A. reduction of alcohol
B. oxidation of alcohol
C. dehydration of alcohol
D. hydrolysis of alcohol
54. ∆H and ∆E have same values for the reaction in______?
A. Solid phase
B. Gases phase
C. Liquids, solids and solution
D. None of these
55. S-S bond is present in which of the ion pairs
A. S2O72-, S2O32-
B. S4O62-, S2O72-
C. S2O72-, S2O82-
D. S4O62-, S2O32-
56. H-Bonding act as a bridge between _______?
A. Two electronegative atoms
B. Electronegative and H atoms
C. Two H atoms
D. None of these
PMC TEST-04CHEMISTRY >> Transition Elements
1. What is the coordination number of Cu metal in [Cu(NH₃)₄]SO₄?
A. 3
B. 4
C. 6
D. 1
2. What is the nature of Carbon present in Aldehyde is?
A. Nucleophilic
B. Electrophilic
C. Neutral
D. all of these
3. When rate of reaction is measured by the amount of radiation absorbed it is called
A. Optical Rotation method
B. Electrical Conductivity method
C. Refractometry Method
D. Spectrometry
4. Concentration of reactants and products are expressed as Moles per unit
A. Area
B. length
C. Volume
D. None of these
5. Which of the uranium isotope have larger mass.
A. 6. 22 x 1 23 atoms of U - 235
B. 6. 22 x 1 23 atoms of U - 238
C. 6. 22 x 1 23 atoms of U - 234
D. all of these
6. The radius of Bohr's atom depends on the following
A. 1/n
B. n2
C. 1/n2
D. n
7. The phenomenon in which compounds have same molecular formula but different structural formula
is called as_________?
A. Reforming
B. Isomerism
C. Polymorphism
D. Hybridization
8. Iodine has greater heat of sublimation then its family members due to presence of stronger?
A. H-bonding
B. London dispersion forces
D. Chemical bonding

9. How many pi bonds are present in ethene?
A. 3
B. 2
C. 1
D. 0
10. The group which leaves from the substrate in a nucleophilic substitution reaction is called as___?
A. Leaving group
B. Electrophile
C. Substrate
D. Weak nucleophile
11. During industrial preparation of methanol, the catalyst is heated upto
A. 4 - 5 'C
B. 5 - 55 'C
C. 45 - 5 'C
D. 35 - 4 'C
12. Two compartments of a galvanic cell are connected by
A. A battery
B. Electrical Wires
C. A pipe
D. Salt Bridge
13 Which of the following law explains that net heat change in a reaction is same whether it takes
place through two or more different ways?
A. Born Haber cycle
B. Joule's principle
C. Hess's law
D. Law of conservation of energy
CHEMISTRY >> Gases
14. The ratio of PV to T is a constant quantity I-e
A. k
B. R
C. n
D. K
15. State function is the _________property of system.
A. Microscopic
B. Dependent
C. Macroscopic
D. Constant
16. Phenol is stronger acid then?
A. Carboxylic acids
B. Water
C. Acetic acid
D. None of these
17. The name protein is derived from ___________ word proteios meaning______.
A. Greek, Important.
B. French, Prime Importance
C. Greek, Functional
D. Greek, Prime Importance
18. In proteins the H bonding is present between _____?
A. C-H
B. N-H
C. O-H
D. Cl-H
19. The specie which is in search of Positive charge is called as_________?
A. Electrophile
B. Nucleophilic
C. Nucleophile
D. Cation
20. When CH₃CH₂MgBr reacts with CO₂ which of the following product is formed?
A. CH₃CH₂CH₂CH₂OH
B. CH₃CH₂CH₂OH
C. CH₃CH₂COOH
D. CH₃CH₂CH₂Br
21. By which reaction benzene is prepared from cyclohexane?
A. Hydrogenation
B. Dehydrogenation
C. Dehydration
D. None of these
22. At equilibrium the reaction mixture contains
A. Only Products
B. Reactants
C. Both
D. None of these
CHEMISTRY >> Gases
23. The unit for Van der Waals constant 'b' is
A. mol dm–3
B. dm3
C. m3 mol−1
D. m3 mol
24. Which one of the following is a strong acid ?
A. HF
B. HI
C. HBr
D. HI
25. NaBH₄ causes reduction of aldehyde and ketones into_____?
A. Alcohols
B. Alkenes
C. Phenols
D. Alkanes
26. Carbonates of sodium are stable but carbonates of lithium are less stable because of
A. Low electronegativity
B. Low electro positivity
C. Low charge density
D. Not known yet
27. The species which donate two electron pairs in a coordination compound is called
A. Ligand
B. Monodentate ligand
C. Polydentate ligand
D. Bidentate ligand
28. Which one of the following has more unpaired electrons?
A. Mn
B. Cr
C. Cu
D. Zn
29. What one is the correct geometry of acetal?
A. Trigonal
B. Linear.
C. Tetrahedral
D. Square planer
30. Metals have ionization energy value
A. Low
B. high
C. intermediate
D. neutral
31. Compounds having atoms of more than one kind are called as?
A. Homocyclic compounds
B. Alicyclic Compounds
C. Heterocyclic compounds
D. None of these
32. If temperature of reaction medium increases above optimum temperature then_____?
A. It increases the enzyme activity
B. Stops the reaction
C. Decreases the enzyme activity
D. Both b and c
33. What is the color of iodoform precipitates?
A. White
B. Black
C. Reddish
D. Yellow
34. Melting and Boiling points depends on______?
A. Number of electrons
B. Number of Unpaired electrons
C. Number of Paired electrons
D. Number of Protons
CHEMISTRY >> Solids
35. Isomorphism is exhibited by
A. Molecular crystals
B. covalent solids
C. Ionic Crystals
D. Metallic solids
36. Electrons in a Voltaic Cell flow from
A. Cathode to Anode
B. Anode to Cathode
C. Right to left
D. None of these
37. What is the color of silver acetylide, AgCΞCAg ?
A. Red
B. White
C. Brown
D. Pinkish
38. Which of the following group is present in carboxylic acids?
A. a carboxyl group
B. a hydroxyl group
C. a hydroxyl and carboxyl group
D. a carbonyl and aldehyde group
39. For higher yields of ammonia increase in temperature is replaced by
A. Increasing pressure
B. decreasing volume
C. Using catalyst
D. All of these
40. After adding two half reactions in ion electron method
A. Net charge should be same on each side
B. Total number of atoms should be same
C. Total number of Ions should be same
D. Both A and B
CHEMISTRY >> Solids
41. When water freezes to ice, it occupies ___ more space
A. 0.9 g/cm3
B. 0.1 g/cm3
C. 0.12 g/cm3
D. 0.13 g/cm3
42. What is the value of molecularity and order of SN₁ reactions?
A. 2,1
B. 1,1
C. 0,1
D. 0,2
43. Which of the following derivative of carboxylic acid is used as flavoring agent ?
A. Acid halides
B. Acid carbonyls
C. Esters
D. Acid amides
CHEMISTRY >> Gases
44. The amount of heat required to vaporize ONE mole of liquid at its ____is called molar heat of
vaporization
A. melting point
B. boiling point
C. freezing point
D. cooling point
45. Rate of a reaction is dependent on
A. Reactant's Concentration
B. Product Concentration
C. Slowest Step
D. All of these
46. In H-F bond formation, The fluorine atom complete its _____by acquiring a share of electron
from hydrogen.
A. 2s orbital
B. 2p orbital
C. 1s orbital
D. all of these
47. Formation of Grignard reagent from alkyl halide and Mg metal takes place in________?
A. Water
B. Alcohol
C. Anhydrous ether
D. Carbon tetrachloride
48. The measurement of the extent to which electron cloud is distorted is termed as?
A. Polarizability
B. Molecularity
C. Induction
D. Dispersion
49. Non-typical transition elements belong to?
A. 2B
B. 3B
C. 221B
D. 1B
50. Glacial acetic acid is_______?
A. Pure liquid acetic acid at 17℃
B. Pure solid acetic acid at 17℃
C. Pure solid acetic acid at 118℃
D. Pure solid acetic acid at -20 ℃
51. Which of following shows maximum boiling point
A. primary alcohol
B. secondary alcohol
C. tertiary alcohol
D. all of above
52. For aldol condensation, carbonyl system must have_____?
A. Beta hydrogen
B. Beta carbon
C. Alpha carbon
D. Alpha hydrogen
53. Hydroxide Ions are combine to give
A. Alcohols
B. Aldehydes
C. Oxygen
D. Hydrogen
54. Which of the following is not a mixture of hydrocarbons
A. candle wax
B. kerosine oil
C. paraffin oil
D. vegetable ghee
55. Dehydrogenase is example of which class of enzyme.
A. Oxidoreductase
B. Hydrolases
C. Ligases
D. Transferases
CHEMISTRY >> Solids
56. The nature of amorphous solid is
A. isotropic
B. anisotropic
C. mesotrophic
D. neotropic
1. A reaction with a tendency of occurring in forward and backward direction simultaneously is
termed as:
A. Irreversible
B. Unidirectional
C. Multidirectional
D. Reversible
2. Organic compounds are______?
A. Inorganic
B. Polar
C. Ionic
D. Non-Polar
3. Any specie which carry a positive charge and can accept electrons is called as_____?
A. Electrophile
B. Anion
C. Nucleophile
D. Electrophobic
CHEMISTRY >> Solids
4. The solids which does not possess the regular arrangement of atoms are called as____?
A. Amorphous solids
B. Crystalline solids
C. Polymorphic solids
D. Isomorphic solids
5. Oxidation number of an ion with single element is same as
A. Ionic radius
B. Charge on Ion
C. Number of electrons in ion
D. Number of protons in ion
6. [Fe(CN)₆]⁴⁻ is called as____?
A. Complex compound
B. Transition element ion
C. Anion
D. Complex anion
7. A mole of a substance contains ______particles
A. 6.2x1022
B. 6.22 x1022
C. 6.02x1023
D. 6.5 x1022
8. When a liquid is heated in a closed container, equilibrium is established between ?
A. Liquid and Solid
B. Liquid and Vapour
C. Liquid solid and vapour
D. Liquid and vapour solid
9. The isomerism in which compounds have different number of carbon atoms on both sides of the
functional group is called as?
A. Tautomerism
B. Metamerism
C. Geometrical Isomerism
D. Position isomerism
10. Which of the following give free radical reaction when react with alkanes?
A. Nitric acid
B. Oxygen
C. Halogen
D. All of these
11. Cyclic compounds consist of except?
A. Alicyclic
B. Aromatic
C. Acyclic compounds
D. Carbocyclic compounds
CHEMISTRY >> Solids
12. Independent Molecules of NaCl exist as:
A. Solid
B. liquid
C. Vapours
D. Gas
13. Kc and Kp have the same value when reactants and products have same number of
A. Atoms
B. Molecules
C. Ions
D. Moles
14. Rate of reaction can have a value which is:
A. in fraction
B. Negative
C. Positive
D. All Of these
CHEMISTRY >> Gases
15. Which pair shows hydrogen bonding among them:
A. ammonia & carbon
B. acetone and Ker
C. acetone and chloroform
D. water & Neon
16. Non polar covalent bond is formed b/w:
A. homonuclear diatomic molecules
B. heteronuclear diatomic molecules
C. similar atoms
D. dissimilar atoms
17. If two amino acids are joined by peptide bond than the molecule is called as_______?
A. Polypeptide
B. Peptide
C. Dipeptide
D. Tripeptide
18. Work done on the system is
A. Negative
B. depends upon Boundary Conditions
C. Positive
D. Zero
19. Ethanol obtained by the process of fermentation never exceeds to________?
A. 0.12
B. 0.14
C. 0.2
D. 0.32
20. In benzene, carboxylic acids exist as_____?
A. Polymers
B.. Dimers
C. Individually
D. Trimers
21. The intermolecular forces brings the molecules close together and give them particular
A. chemical properties
B. physical properties
C. composition
D. nature
CHEMISTRY >> Gases
22. The strength of H-bond is less than covalent bond
A. 1 times
B. 2 times
C. 3 times
D. 5 times
23. Addition of ammonia and its derivative catalyze by________?
A. Acid
B. Base
C. Oxidizing agents
D. Pd/C
24. The SI unit for work is:
A. Newtons
B. Joule
C. Newton/metre
D. All of these
25. In the gaseous state, the distance between the molecules is _________ times _____ than their
diameters.
A. 2 ,lesser
B. 3 ,lesser
C. 3 ,greater
D. 2 ,greater
26. Which of the following reaction does acetylene give due to its acidic hydrogens?
A. Ozonolysis
B. Hydroxylation
C. Acetylide formation
D. Kolbe's electrolysis
27. Greater the value of principal quantum number n', the distance of electron from nucleus will
be________.
A. lower
B. greater
C. higher
D. moderate
28. Which of the following is a strong acid?
A. Ethane
B. Ethyl Chloride
C. Ethanol
D. Phenol
29. Compounds having benzene ring are called as______?
A. Alicyclic
B. Aliphatic compounds
C. Aromatic compounds
D. Acyclic compounds
30. The reaction in which a nucleophile replaces another atom present in a compound is called
as_______?
A. Nucleophilic elimination reaction
B. Nucleophilic addition reaction
C. Nucleophilic substitution reaction
D. All of these
31. In Chemistry the work is generally
A. Done by Temperature change
B. Pressure - Temperature Work
C. Pressure Volume Work
D. None of these
32. As far as nuclear charge increases, the decrease in ionic radii will also
A. larger
B. smaller
C. remains same
D. moderate
33. In electrochemical series reduction potential relates to only
A. Real Conditions
B. Standard Conditions
C. Positive Values
D. Negative Values
34. The correct electronic configuration of Cr is
A. [Ar]4s23d4
B. [Ar] 4s23d4
C. [Ar]4s 3d5
D. [Ar]4s13d5
35. Which of the following intermolecular forces are present between octane molecules ?
A. London dispersion forces
B. Dipole dipole forces
C. Debye forces
D. H-Bonding
CHEMISTRY >> Solids
36. Number of Valence Electrons in Cl- Ion are:
A. 18
B. 10
C. 17
D. 8
37. Rate = k [ NO2] , the order of this reaction is:
A. Zero
B. Two
C. Three
D. One
38. Salt Bridge contains
A. Aqueous Calcium Chloride
B. Molten zinc powder
C. KCl in a Gel
D. NaCl in a gel
39. Which of the following is best method to prepare alkyl halides from alcohols?
A. Reaction of alcohol with HX
B. Reaction of alcohol with SOCl₂
C. Reaction of Alcohol with PCl₃
D. Reaction of Alcohol with PCl₅
40. Rayon is______?
A. Acetyl chloride
B. Alkene
C. Alkyne
D. Acetic acid
CHEMISTRY >> Solids
41. NaNO3 and CaCO3 are
A. allotropes
B. amorphous
C. isomorphous
D. polymorphous
42. Which of the following are the products of catalytic oxidation of methane?
A. CO₂ , H₂O
B. CO, H₂O
C. CO₂,H₂
D. CH₃OH
43. Which one is least ionic in nature and decompose on heating
A. LiOH
B. NaOH
C.. KOH
D. CsOH
44. The deliquescence is a property in which a solid
A. Absorbs moisture and remains solid
B. Absorbs moisture and turns to liquid form
C. Loses water of crystallization
D. Increases the number of water of crystallization
CHEMISTRY >> Gases
45. Kinetic molecular theory was proposed by
A. Berzelius
B. Boltzmann
C. Bernoulli
D. Maxwell
46. Optimum pH of salivary amylase is:
A. 7-7.5
B. 6-6.5
C. 6.4-6.9
D. 6.3-6.7
47. A sample so .7 mol of metal M reacts completely with excess of fluorine to form 45 g of MF2
,how many moles of F are present in it.
A. 1.4 moles
B. 2.4 moles
C. 2 moles
D. 1.2 moles
48. In Which of the following reaction of carboxylic acids only C=O group involved in bonding and OH
group is replaced ?
A. Reaction of carboxylic acid with NaOH
B. Reaction of carboxylic acids with Carbonate
C. Formation of anhydride
D. Reaction of carboxylic acids with SOCl₂
49. Which of the following bond has highest bond energy value ?
A. C-I
B. C-H
C. C-Cl
D. C-F
50. In organic chemistry, we deal with
A. carbon
B. Hydrogen
C. Hydrocarbons
D. potassium
51. If a graph is plotted with concentration data of a reactant in a chemical reaction the curve is
A. Rising
B. Falling
C. U shaped
D. None of these
52. The alkenes can be formed by alcohols in the presence of
A. acidified KMnO4
B. acidified K2Cr2O7
C. acidified CuCl2
D. pyridine
CHEMISTRY >> Solids
53. The identical number of layers in cubic and hexagonal closest packing are
A. First three
B. first two
C. only one
D. first four
54. H3O+ ions act as
A. Base
B. Catalyst
C. Buffer
D. Acid
55. Change in volume of a system depends only upon
A. Initial conditions
B. Final Conditions
C. Initial and final conditions
D. Path of the reaction
56. The simplest hydrocarbon to have structural isomer is:
A. Butane
B. Butanone
C. Butene
D. Butyne
1. Why transition metals have strong metallic bonding?
A. Because of high melting point
B. Because d-electrons of outer shell take part in bonding
C. Because s-electrons of outer shell take part in bonding
D. Both s and d electrons takes part in bonding
2. In secondary alkyl halides how many H atoms are attached to Carbon atom which is attached with
halogen?
A. 2
B. 1
C. 3
D. 4
3. Metallic character depends on_________?
A. Electron Affinity
B. Ionization energy
C. Electronegativity
D. All of these
4. The sequence of amino acids combined in a peptide chain is called_______.
5. In general Photochemical reactions are of order
A. 1
B. 3
C. 2
D. 0
6. The sum of potential and kinetic energy of a system is called
A. Entropy
B. Enthalpy
C. Internal Energy
D. Heat Energy
7. Ethanol is prepared on a large scale by
A. hydration of alkanes
B.. distillation of wood
C. fermentation
D. williamson's synthesis
8. The precipitation of weaker electrolyte follows
A. Law of Mass Action
B. Law of energy Conservation
C. Le chatelier's Principle
D. None of these
9. Ethene is prepared from alcohol by______?
A. Decomposition
B. Dehydration
C. Dehydroxylation
D. Dehalogenation
CHEMISTRY >> Gases
10. Which of the following properties does not belong to Gases?
A. Indefinite volume
B. Indefinite shape
C. Low density
D. Strong interactions
11. BF3 is an electron pair acceptor and complete its octet by accepting
A. an electron
B. pair of electron
C. 3 electron
D. 4 electron
12. How meta directing groups affect the Electrophilic substitution of benzene ring?
A. Increase electron density at ortho,para position
B. Decrease electron density at ortho and para positions
C. Make benzene less reactive
D. Both b and c
13. A polymer called Bakelite is formed by reaction of phenol with
A. hydrogen
B. ethers
C. carboxylic acid
D. formaldehyde
14. What is the IUPAC name of; ClCH₂CH₂COOH ?
A. 3-Chloropropanoic acid
B. 2-Chloropropanoic acid
C. 2-Chloro-1-propanoic acid
D. Propyl carboxylic acid chloride
15. Which of the following product is formed when aldol product is heated?
A. Rearrangement
B. Dehydration
C. Decomposition
D. All of these
16. On which factor boiling point of a liquid does not depends?
A. External pressure
B. Vapour pressure
C. Amount of liquid
D. Intermolecular forces
17. In Al2S3 ,the valency of Al is
A. 2
B. 3
C. -3
D. -2
18. The decrease in atomic radii is very prominent in
A. second group
B. second period
C. higher groups
D. higher periods
CHEMISTRY >> Gases
19. Who attributed the deviation of real gases from ideal behavior
A. Boyle's law
B. Charles's law
C. Avogadro's law
D. Van der Waals
20. The formation of acid anhydride from carboxylic acid is a______?
A. Dehydration reaction
B. Condensation reaction
C. Both a and b
D. None of these
21. Hydrolsis of Tertiary Butyl bromide is a
A. First order reaction
B. Zero Order Reaction
C. Pseudo Second Order
D. Pseudo First Order
22. With impurities like P and S the open hearth furnace is lined with
A. SiO2
B. Fe2O3
C. FeO
D. CaO, MgO
23. Which of the following acid solution is used for the seasoning of food ?
A. Butyric acid
B. Phthalic acid
C. Lactic acid
D. Acetic acid
24. A structural formula shows_____?
A. Arrangement of atoms in the compound
B. Arrangement of electrons in the compound
C. Arrangement of Orbitals that involved in bonding
D. Lewis structure of compounds
25. What will be the product at cathode during the electrolysis of brine in Nelsonâ€™s cell?
A. H2
B. Na
C. CO2
D. O2
26. In SN₂ reaction, which of the following specie is formed?
A. Transition state
B. Intermediate
C. Carbocation
D. Carbanion
27. Who was able to determine the distance b/w K+ and Cl- in potassium chloride crystal`
A. Bohr's
B. Pauling
C. Berzelius
D. Rutherford
28. In SN₂ reaction, rate of reaction is directly proportional to concentration of_______?
A. Substrate only
B. Nucleophile
C. Substrate and nucleophile
D. All of these
29. The self Linkage ability of Carbon is called as_______?
A. Polymerization
B. Substitution
C. Sequential Carbonation
D. Catenation
30. In Electrochemical Cells Reduction takes place at
A. Anode
B. Cathode
C. At the surface of electrolyte
D. None of these
31. Adhesive nature of honey and glue id due to presence of______?
A. H-bonding
C. Ionic forces
D. Debye force
32. The probability of finding an electron _________ even at large distances from the nucleus.
A. becomes one
B. becomes zero
C. never becomes zero
D. varies from to 1
33. The substances which reduces the activity of enzyme action are called as______?
A. Reducers
B. Activators
C. Promotors
D. Inhibitors
34. Isoenzymes catalyze______?
A. Catalyze different reaction
B. Catalyze same reaction
C. Catalyze any reaction
D. Catalyze reactions that are from different reactions
35. Which is un1 for phenols
A. a colourless crystalline solid
B. more reactive to electrophilic attack
C. form pink solution at room temperature
D. dissolves readily in acids
36. Which of the following group is ortho-para directing group_____?
A. –COOH
B. –COR
C. –CN
D. –OH
37. Which instrument is used to measure the vapour pressure of a liquid?
A. Barometer
B. Manometer
C. Thermometer
D. Sphygmometer
CHEMISTRY >> Solids
38. The Extension of structure in a crystalline solid is not
A. Regular
B. Geometrical
C. Three-Dimensional
D. None of these
39. As Reaction proceeds the concentration of reactants
A. decreases
B. Remain unchanged
C. increases
D. cannot be predicted
40. What is the sum of all the energies present in a reaction mixture or system called as ?
A. Thermal energy
B. Total heat content
C. Internal energy
D. Enthalpy
41. In Which of the following reaction rate of reaction is not affected by increasing concentration of
nucleophile ?
A. SN₂
B. E₂
C. SN₁
D. None of these
CHEMISTRY >> Solids
42. Which of the following is not an Ionic Solid
A. NaCl
B. KBr
C. MgCl2
D. CO
43. Which of the following products are formed from cannizzaro reaction?
A. Aldol product
B. Alcohol and carboxylate salt
C. Alcohol and carboxylic acid
D. Unsaturated reaction
44. 2 moles of octane ( C8H18) burns with 25 moles of oxygen (O2) and produced _____moles of carbon
dioxide along with 18 moles of water
A. 14
B. 16
C. 18
D. 2
45. urea belong to which class of compound
A. imides
B. amides
C. amines
D. carboxylic acid
46. Unavailability of methods to find out heat of reactions accurately makes thermochemistry
A. Widely applicable in science
B. A Limited field of study
C. A Useful aspect of Industrial research
D. None of these
47. Calcium carbide is prepared by heating lime with coke at:
A. 25 °C
B. 26 °C
C. 27 °C
D. 28 °C
CHEMISTRY >> Gases
48. Critical temperature of ammonia is _____ C.
A. 31.14
B. 13.24
C. 132.44
D. 1.11
49. According to________ theory, atoms were the ultimate particles that cannot be divided . further.
A. Bohr's
B. Rutherford's
C. Dalton's
D. cannizzaro's
50. Ice occupies more space than liquid water by________?
A. 0.1
B. 0.09
C. 0.05
D. 0.06
51. Grignard reagent is produced by the reaction of Alkyl halides with_______?
A. Ca in anhydrous ether
B. Mg in dry ether
C. Mg in hydrous ether
D. Ca in dry ether
52. In electrolysis of NaNO3, Nitrate ions are not discharged but
A. Hydroxide Ions are discharged
B. Hydrogen Ions are Discharged
C. Sodium Ions are Discharged
D. None of these
53. Enzymes that catalyze the addition of ammonia, water or carbon dioxide to double bond or their
removal are called_______.
A. Lyases
B. Hydrolases
C. Ligases
D. Transferases
54. What is the boiling point of acetic acid ?
A. 120℃
B. 118℃
C. 110℃
D. 87℃
55. Tertiary alcohols upon reaction with oxidizing agents give ________as major product?
A. Carboxylic acids
B. Alkene
C. Alkyne
D. Ester
1. The formation of coordination complex compounds formed by transition metals is explained by:
A. Ligand field theory
B. crystal field theory
C. molecular orbital theory
D. both A & B
HEMISTRY >> Alcohol and Phenols
2. Methanol is also called as
A. liquor
B. grain alcohol
C. wood spirit
D. fuel
3. How many products of mono-substituted benzene are possible?
A. Two
B. One
C. Three
D. None of these
4. During bond formation d orbitals splits into _____of orbitals ?
A. 3 sets
B. 4 sets
C. 5 sets
D. 2 sets
5. Manufacturing of Ammonia by Haber’s process is an
A. endothermic reaction
B. exothermic reaction
C. irreversible
D. Slow
6. In the rate equation R=k[A]â [B]^b, a and b as exponents decides
A. Direction of reaction
B. Extent of Reaction
C. Order of Reaction
D. Temperature of Reaction
7. Exothermic Reactions heat is
A. Taken in
B. Give out to surroundings
C. Neither given nor lost
D. None of these
8. Which one is natron?
A. Na2CO3
B. Na2CO3.1 H2O
C. Na2CO3.H2O
D. NaHCO3
9. Which of the following method is used to prepare acetic acid ?
A. Distillation
B. Fermentation
C. Dehydration
D. Ozonolysis
10. After digestion proteins change into:
A. Amino acids
B. Starch
C. Glycogen
D. Lipids
11. The total energy of products in a chemical reaction is:
A. equal to reactants
B. More than reactants
C. always zero
D. Less Than Reactants
12. Which one can form complex?
A. Na
B. Cr
C. Li
D. K
CHEMISTRY >> Gases
13. On earth, plasma occurs in few limited places like
A . auroras'
B. flames
C. bolts
D. all of these
14. Alkyl halide react with Sodium lead alloy, which of the following is correct formula of
tetramethyl lead?
A. (C₂H₅)₄Pb
B. (CH₃)₄Pb
C. (CH₄)₄Pb
D. (CH₃)₄Pd
15. Carboxylic acid reduction to alcohol can be achieved by using?
A. H₂/Ni
B. Pd/C
C. NaBH₄
D. LiAlH₄
16. Which of the following can not be prepared directly from acetic acid ?
A. Ethyl acetate
B. Acetamide
C. Acetyl Halide
D. Acetic anhydride
17. The half-life of Uranium is:
A. 700 Million years
B. 706 Million years
C. 89 days
D. 710 million year
18. Which of the following compound is an amide?
A. NH₄CNO
B. NH₂COCH₃
C. NH₂CONH₂
D. NH₂COONH₂
19. Phenol gives electrophilic substitution reactions due to?
A. OH group
B. Phenoxide ion
C. Benzene ring
D. All of these
CHEMISTRY >> Solids
20. Boiling Points of Polar Molecular solids are:
A. Low
B. Moderate
C. High
D. Cannot be predicted
CHEMISTRY. >> Introduction to Fundamental Concepts of Chemistry
21. If number of molecules of different gases are same at S.T.P ,the occupied volume will be
A. greater
B. same
C. smaller
D. twice
22. The value of Principal quantum number "n" represent:
A. energy of electron
B. location of electron
C. shells or energy levels
D. all of these
23. Carbonyl system having no alpha hydrogen undergoes _______?
A. Aldol condensation
B. Cannizzaro reaction
C. Haloform reaction
D. Oxidation reaction
24. In oxidation number method the final step to balance equation is
A. Hit and Trial Method
B. Inspection method
C. Identifying the reducing participants
D. Identifying the oxidized participants
25. Oxidation Number of all the elements in free state is:
A. unity
B. Positive
C. Zero
D. Negative
26. Which of the following is an example of Nucleophile?
A. Br⁺
B. CH₃⁺
C. NH₃
D. CH₄
27. Water is considered as a Universal solvent because of which properties?
A. Polar nature of water
B. H-bonding
C. Electronegativity difference
D. All are correct
28. By increasing the concentration of substance on reactant side shifts the equilibrium to
A. Backward direction
B. Forward Direction
C. higher concentration
D. None of these
29. The ionic radius is always _____than the atomic radius from which t is derived.
A. higher
B. larger
C. moderate
D. smaller
30. On which of the following factors rate of enzyme action is directly proportional ?
A. Concentration of products
B. Time
C. Concentration of substrate
D. Concentration of solvent
31. Which of the following reaction can be used to prepare Symmetrical alkanes?
A. Reduction reaction
B. Kolb's reaction
C. Clemmensen Reaction
D. Hydrogenolysis
32. Melting and boiling point of liquids depend upon ____-?
A. Motion of liquid molecules
B. Intermolecular forces between the molecules
C. Kinetic energy of the molecules
D. Mass of the molecules
33. What is the octane number of Iso-octane?
A. 40
B. 100
C. 0
D. 2
34. Who introduce the concept of macromolecules?
A. Runge
B. MaxWell
C. Staudinger
D. None of these
CHEMISTRY >> Solids
35. CuSO4.5H2O is an example of crystal system:
A. triclinic
B. tetragonal
C. cubic
D. rhombohedral
36. The elements with intermediate value of ionization energy value are called
A. metals
B. non metals
C. metalloid
D. transition elements
37. When we dissolve a compound of transition element in a solution of salt then it will form
A. Simples ions
B. Strong anions
C. Double salts
D. Complex ions
38. Which of the following causes the inactivation of enzymes ________?
A. Concentration of substrate
B. Optimum temperature
C. Beta radiation
D. Optimum pH
39. What is optimum temperature for the process of fermentation?
A. 10-15 degrees
B. 25-30 degrees
C. 25-35 degrees
D. 25-40 degrees
CHEMISTRY. >> Carboxylic Acids
40. Which of the following causes complete reduction of carboxylic acid into alkanes?
A. H₂/Ni
B. Pd/C
C. HI/P
D. LiAlH₄
41. Conversion of straight chain hydrocarbons into branched chain is called as______?
A. Reforming
B. Cracking
C. Isomers
D. Decomposition
CHEMISTRY >> Solids
42. An example of nonpolar molecular crystal is:
A. Ice
B. Iodine
C. Sugar
D. Salt
CHEMISTRY >> Gases
43. The molecule of water has structure:
A. cubic
B. tetrahedral
C. trigonal
D. hexagonal system
44. Formaldehyde polymerizes to form ?
A. Bakelite
B. Paraldehyde
C. Metaformaldehyde
D. All of these
45. Which one of the following is the correct IUPAC name of 2-Chloro,3-methylpentane ?
A. CH₃-CH₂-CH(Cl)-CH(CH₃)
B. CH₃-CH₂-CH(CH₃)-CH(Cl)-CH₃
C. CH₃-CH₂-CH(Cl)-CH(Cl)-CH₃
D. CH₃-CH₂-CH(Cl)-CH(CH₃)-CH₃
46. The catalyst used for ether formation by dehydration of alcohols:
A. Cons HN3 at 14 C
B. Cons H2SO4 at 14 C
C. Hot H3PO4 at 18 C
D. ZnCl2 at 45 C
47. In Electrochemical Cell Positive Ions are migrated towards:
A. Anode
B. Cathode
C . Toward the bottom of the cell
D. Towards the walls of the cell
48. At equilibrium if the concentration of product is increased reaction will proceed to:
A . Forward Direction
B. Backward Direction
C. Remain Undisturbed
D. None of these
49. The transition elements belongs to Group VIB are:
A. Zn ,Cd, Hg
B. Fe, Ru, Os
C. Mn, Te, Re
D. Cr, Mo, W
50. Ethane and hexane both are nonpolar molecules, but ethane has lower Boiling point than
Hexane due to?
A. Strong london forces in ethane due to smaller size
B. Weak london forces in hexane due to larger size
C. Strong london forces in hexane due to smaller size
D . Strong london forces in hexane due to larger size
CHEMISTRY >> Gases
51. Values of Van der Waalâ€™s constant 'b' in correct order is:
A. CO2<SO2<O2<H2
B. CO2>SO2>O2>H2
C. O2<H2<CO2<SO2
D. O2>H2>CO2>SO2
52. Which of the following does not contain COOH group?
A. Acetone
B. Propanoic acid
C. Formic acid
D. Picric acid
53. Due to the formation of protective layer of oxides at Aluminum oxide surface, it is hard to burn it:
A. completely in air
B. completely in oxygen
C. with carbon
D. with nitrogen
54. Enzymes speed up the reaction upto:
A. 10¹⁰
B. 20¹⁰
C. 10²⁰
D. 15¹⁰
55. In one second if the concentration changes from 0.1 to 0.25 then the rate will be:
A. 0.02 Moles/dm3s-1
B. 0.03 Moles/dm3s-1
C. 0.15 Moles/dm3s-1
D. 0.11Moles/dm3s-1
55. In one second if the concentration changes from 0.1 to 0.25 then the rate will be:
D. 0.11Moles/dm3s-1
56. Self-oxidation reduction reaction is also called as______?
A. Dehydration
B. Condensation reaction
C. Disproportionation reaction
D. Proportionation reaction
CHEMISTRY >> Gases
125. Ethyl alcohol is a non polar solvent but can dissolve in water because of formation of:
A. polar bond
B. non-polar bond
C. H-bond
D. all of these
126. The compounds which belongs to same functional group forms a_________?
A. Class
B. Group
C. Homologous series
D. None of these
127. Which of the following element is present in all proteins ?
A. S
B. C
C. N
D. O
128. Suppression of ionization means
A. Decreasing Ionization
B. Increasing Ionization
C. Maintaining Ionization
D. None of these
129. Which of the following suffix is used for the common naming of alkene?
A. -ene
B. -ylene
C. -yne
D. –eylene
130. Formula mass is considered for ___compounds instead of their molecular mass
A . metallic
B. ionic
C. covalent
D. polar covalent
CHEMISTRY >> Solids
131. In Powdered form the angles and faces in a crystal are
A. Ruptured
B. Changed
C. Unchanged
D. None of these
132. Specific Rate constant changes its value with
A. Time Constant
B. Change in Temperature
C. Change in Concentration
D. Change in Pressure
133. A _______ bond may be polar or nonpolar
A. Ionic bond
B. covalent bond
C. metallic bond
D. co-ordinate bond
134. K.E of the liquids is directly proportional to_____?
A. Pressure
B. Temperature
C. Mass
D. Nature
135. Reduction of ethanoic acid with LiAlH4 produces _________?
A. Propanol
B. Ethanal
C. Ethanol
D. Ethane
136. For a Voltaic Cell containing Zn and Copper electrodes the cell potential at standard
conditions is
A. 2 Volts
B. 2.2 Volts
C. 1 Volt
D. 1.1 Volt
137. What is IVPAC name of isopropyl alcohol
A. 2 - propanol
B. 1 - propanol
C. 2 - ethanol
D. 2 - propane-1-ot
CHEMISTRY >> Solids
138. The study of crystalline solids determines the
A. mole
B. Avogadro's number
C. atomic mass
D. atomic number
139. Which one of the following is not a secondary alkyl halide?
A. 2-Chloropropane
B. 3-Bromobutane
C. 2,3,dichloropentane
D. 2-chloro,2-methylpentane
CHEMISTRY >> Gases
140. Which inert gas is mixed with oxygen gas by deep sea divers to adjust the partial pressure of
oxygen gas
A. Neon
B. Helium
C. Argon
D. Krypton
141. Dipole dipole forces are stronger between the molecule when?
A. Electronegativity difference is higher
B. Electronegativity difference is less
C. Molecules are far from each other
D. Electronegativity difference is zero
CHEMISTRY >> Solids
142. In a cubic close packed system, the number of octahedral void per atom is/are
A. 1
B. 3
C. 8
D. 5
143. Platinum Foil is coated with finely divided platinum black in SHE to give larger
A. Mass
B. Volume
C. Surface Area
D. Temperature difference
144. During combustion analysis MgClO4 is used to absorb ______________
A. oxygen gas
B. hydrogen gas
C. water vapors
D. alcohol
145. A full stop may have_______ atoms present in it
A. one million
B. two millions
C. one billion
D. two billions
146. Why oxidation of ketones is not easy _________?
A. Because they involve breaking of C-O bond
B. Because it involve breaking of C-C bond
C. Because it involve breaking of C-H bond
D. Because it involve breaking of C=C bond
147. The shapes of subshells is _if value of azimuthal quantum number 'l' is 2
A. spherical
B. dumbbell
C. complicated
D. all of these
148. The bond formed b/w homonuclear diatomic molecule is ___in nature
A. polar
B. non-polar
C. may be polar or nonpolar
D. ionic
149. SI unit for energy change in a chemical reaction is
A. Joule/mole
B. KJ/mole
C. KJ mol^-1
D. All of these
150. To avoid long reaction time and to get equilibrium mixture quickly we add
A. More reactants
B. catalyst
C. inhibitors
D. enzymes
151. The hydrocarbon in which all the 4 valencies of carbon are fully occupied is called as:
A. Alkene
B. Alkyne
C. Alkane
D. Cycloalkane
152. Reaction of Aldehydes with Tollen's reagent results in formation of ______?
A. Red precipitate
B. Yellow precipitate
C. Silver mirror
D. Brick red precipitate
153. The reactivity of alkenes is due to the presence of?
A. Sigma bond
B Two Pi bond
C. One Pi bond
D. Due to electrophilic nature
154. Which oxidation is possessed by all the elements of group III B ?
A. 2
B. 3
C. 5
D. 7
155. Formyl group belongs to which class of compounds ?
A. Aldehydes
B. Ketones
C. Alkanals
D. Both a and c
156. Which of the following is not aromatic?
A. Anthracene
B. Naphthalene
C. Phenol
D. None of these
157. In nature fatty acids occur as _______of glycerol?
A. Acid halides
B. Binary compounds
C. Esters
D. Alkanes
158. For 3rd order reactions the half-life is
A. inversely proportional to square of concentration
B. directly proportional to cube of concentration
C. inversely proportional to concentration
D. directly proportional to concentration
159. Boiling point of carboxylic acids are high due to?
A. Polarity of carbonyl group
B. Due to methyl group
C. Due to H-Bonding
D. Due London forces
160. Activator of phosphatase enzyme is_____.
A. Mn²⁺
B. Mg²⁺
C. Zn²⁺
D. None of these
161. Propanoic acid is produced when ______?
A. Methyl MgBr react with CO₂
B. Isopropyl MgBr react with CO₂
C. Ethyl MgBr react with CO₂
D. Propyl MgBr react with CO₂
162. Carboxylic acids turn ?
A. Red litmus blue
B. Blue litmus red
C. Neutral to litmus
D. No effect
163. What is the relationship between boiling point and External pressure?
A. Boiling point increases if external pressure is increased
B. boiling point increases if external pressure decreases
C. Boiling point is not affected by external pressure
D. Boiling point decreases if external pressure increased
164. The 'm' quantum number describes the _______of electron
A. energy level
B. orbital or subshell
C. orientation of orbital
D. Spin of electron
165 .Who first extracted phenol?
A. Wohler
B. Runge
C. Wittig
D. Wurtz
166. dx/dt is rate of reaction expression where dx is
A. Concentration
B. Change in Concentration
C. Very small change in Concentration
D. All of these
167. The last subshell of alkaline earth metals
A. 2s
B. 1s
C. 2d
D. 3d
168. The oxidation state of transition elements is usually
A. Variable
B. Constant
C. Single
D. Infinite
169. Effect of Change in Pressure for a reaction with different number of moles at reactant and
product side are
A. Irreversible Reactions
B. Reversible reactions
C. Reversible gaseous reactions
D. All of these
170. 2-hydroxy propanoic acid is also called as_____?
A. Stearic acid
B. Butyric acid
C. Maleic acid
D. Lactic acid
171. When O-H bond breaks in alcohol is the order of reactivity
A. Primary alcohol ) secondary alcohol ) tertiary alcohol
B. methyl alcohol ) primary alcohol ) secondary alcohol ) tertiary alcohol
C. Primary alcohol ( secondary alcohol ( tertiary alcohol
D. ethanol ) primary alcohol ) secondary alcohol ) tertiary alcohol
172. In which of the following benzene is isolated?
A. Naphthalene
B. Diphenyl ethane
C. Phenanthrene
D. Anthracene
173. The slope determined by drawing a right angled triangle drawn with tangent as
hypotenuse will be same
A. with different sizes of triangles drawn
B. at different point on curve
C. at the start and end of curve
D. All of these
174. Energy change is governed by
A. Heat
B. Work
C. Enthalpy
D. None of these
175. At which temperature water boils at Murree Hills?
A. 50℃
B. 100℃
C. 98℃
D. 67℃
176. Number of Electrons added on both sides of oxidation and reduction half reactions are
balanced:
A. At the start of procedure
B. Somewhere in the middle of balancing
C. After Adding two Half reactions
D. Before Adding two Half Reactions
177. The order of size of 's' orbital is as follows:
A. ...4s<3s<2s<1s
B. …4s>3s>2s>1s
C. constant
D. none of these
178. Lighter the Oxidation state of Metal more will be_______?
A. Acidity of metal
B. Polarization power
C. Basicity of metal
D. None of these
179. Glucose(C6H12O6) is the most important nutrient in a cell for generating chemical potential
energy, what is the mass percent of carbon in 1.5g of sample:
A. 33%
B. 40%
C. 53.3%
D. 6.67%
180. Which one of the following does not give iodoform test ?
A. Acetaldehyde
B 3-hexanone
C. Butanone
D. Acetone
125. Kinetic energy of the molecule may be all of the following except?
A. Vibrational
B. Translational
C. Rotational
D. Static
127. Which of the following enzyme is not used during fermentation process for making ethanol?
A. Diastase
B.. Zymase
C. Protease
D. Maltase
128. Strong Electrolytes are those which ionizes
A. Slowly
B. Do not ionize
C. Ionize rapidly
D. None of these
129. Transition elements for complexes because______?
A. They have empty d orbitals
B. They show variable oxidation states
C. Both a and b
D. They have strong bonding
130. Enzymes that catalyze hydrolysis:
A. Oxidoreductase
B. Hydrolases
C. Ligases
D. Transferases
131. The equation En=-2.17x1 -18 [1/n2] J gives the energy associated with electron in nth orbit of
hydrogen atom. Its negative sign shows that electron is
A. away from nucleus
B. bound by nucleus
C. closer to nucleus
D. all of these
132. The reaction in which one of the group of a compound is replaced by another group of atoms
is called as______?
A. Substitution
B. Elimination
C. Addition
D. Condensation
133. What is the order of SN₂ reactions?
A. 1st order
B. zero order
C. 2nd order
D. 3rd order
134. H-bonding is stronger then_______?
A. Dipole dipole forces
B. Debye forces
C. London forces
D. All of these
135. The organic compounds having all C-C single bonds are called as____?
A. Alkanes
B. Alkenes
C. Alkynes
D. All of these
136. In Balancing Redox equation the first thing is to
A. balance out all the Reactants
B. Write the skeleton Equation
C. Calculate the oxidation Number
D. Identify the elements
137. Any process of chemical decay of metals due to the action of the surrounding medium is
called
A. Activation
B. Enamelling
C. Corrosion
D. Coating
138. In the reaction of NaBH₄ with aldehyde and ketones, which of the following act as Nucleophile ?
A. B⁻
B. H⁻
C. BH₂⁻
D. NaBH₃⁻
139. Voltaic Cell can be converted into a Reverse galvanic Cell by
A. Changing positions of electrodes
B. Replacing Salt Bridge with a Wire
C. Providing an External Source of electricity
D. All of these
140. Hess law is a simple application of
B. Law of conservation of energy
C. Law of conservation of mass
D. Dalton's Law of partial pressure
141. There are just only a few stable compounds, formed by noble gases like
A. XeF2
B. XeOF2
C. XeO3
D. all of these
142. Which sulphates is not soluble in water?
A. Sodium sulphate
B. Potassium sulphate
C. Zinc sulphate
D. Barium sulphate
143. Formation of picric acid by phenols is called
A. Decomposition
B. Halogenation
C. Sulphonation
D. Nitration
144. Which of the following compounds are added to ethanol to make it unfit for drinking?
A. Pyridine
B. Methanol
C. Acetone
D. All of these
145. Which of the following alcohol undergoes dehydration fastly?
A. Primary alcohol
B. Secondary alcohol
C. Dihydric alcohol
D. Tertiary alcohol
146. Acetaldehyde oxidation will lead to formation of
A. Acetic acid
B. Butanoic acid
C. Propanoic acid
D. Ester
147. Presence of Process of diffusion in liquids is due to________?
A. Definite volume
B. Strong intermolecular forces
C. Smaller distance
D. Constant motion
148. In the reaction; Zn + CuSO4 → ZnSO4 + Cu, Which of the following change shoes that redox
reaction takes place at once ?
A. Blue color appears
B. Blue color disappears
C. Temperature of the surrounding decreases
D. None of these
CHEMISTRY >> Solids
149. The size and shape of a crystal depends upon some crystallographic elements which are
A. 3
B. 4
C. 6
D. 8
150. The group 1 elements are named as alkali metals because
A. Their oxides are basic
B. Their oxide and hydroxides are water soluble
C. Both a & b
D. They are found in the earth
151. The average and instantaneous rate can be equal
A. Throughout the reaction
B. Near Reaction Completion
C. At one instant Only
D. At start of reaction
CHEMISTRY >> Gases
152. Liquid is ______ to release the entrapped air in liquid in manometric method
A. melted
B. boiled
C. condensed
D. freeze
153. When the central atom of coordination compound is sp3d2 hybridization the expected
geometry will be
A. Tetrahedral
B. Square planar
C. Trigonalbipyramidal
D. Octahedral
154. Which of the following reaction of carbonyl system is used to distinguish between carbonyl
system from alcohols?
A. Cyanohydrin formation
B. Bisulfite adduct formation
C. Haloform formation
D. None of these
155. Octane number of n-heptane is________?
A. 0
B. 100
C. 40
D. 98
CHEMISTRY >> Gases
156. London forces are present in
A. ammonia
B. water
C. kerosene oil
D. HCl
Q 157. Ketones can be oxidized by ______?
A. Dil.HNO₃
B. Tollen's reagent
C. Benedict reagent
D. Fehling's reagent
158. Enthalpy of a system is also called as____?
A. Entropy
B.. Work function
C. Total heat content
D. Internal energy
159. The minimum amount of energy required to remove an electron from its gaseous atom to form
an ion is known as
A. electron affinity
B. ionization energy
C. electronegativity
D. potential energy
160. The arrangement of sub shells or orbitals is according to _rule
A. 2(l+1)
B. l+1
C. n+l
D. 2(n+l)
161. What is the empirical formula for the following molecular formula C5H12
A. C5H12
B. C5H6
C. CH2
D. C2.5H6
162. Which of the carboxylic acid is used in medicine as local irritant;
A. formic acid
B. acetic acid
C. benzoic acid
D. amino acid
163. All are aliphatic carboxylic acid except ?
A. Benzoic acid
B. Methanoic acid
C. Ethanoic acid
D. Acetic acid
164. Fuels with higher octane number can be produce by______?
A. Cracking
B. Reforming
C. Decomposition
D. Isomerisation
CHEMISTRY >> Solids
165. in solid iodine, I-I bond distance is
A. 77.1 pm
B. 271.5 pm
C. 11 pm
D. 166.7 pm
166. Suppression in ionization is done for
A. Weak Electrolyte
B. Strong Electrolyte
C. Only Reactants
D. Dissociated Ions
167. Reaction which are completed in steps must contain
A. Rate determining Step
B. Slowest step
C. fastest step
D. Both A and B
168. Protein part attached with non-protein part in enzymes belongs to which class of proteins?
A. Simple
B.. Conjugated/compound
C. Derived
D. All of these
169. What is the value of enthalpy of neutralization when one mole of base reacts with one mole of
acid?
A. - 60.5 kJ/mol
B. -46.5kJ/mol
C. -70.5 kJ/mol
D. -57.4kJ/mol
170. propene exhibit
A. Cis-isomerism
B. Trans-isomerism
C. geometric isomerism
D. none
171. First step in the SN₁ reaction is_____?
A. Dehydration
B. Protonation
C. Ionization
D. Attack of nucleophile and departure of leaving group
172. Hydrolysis of Tertiary Butyl bromide gives
A. Carboxylic Acid
B. Alcohol
C. Aldehyde
D. Ketone
CHEMISTRY >> Gases
173. Which gas among them shows maximum ideal behavior
A. Ammonia
B. Hydrogen
C. Helium
D. Radon
174. Caustic Soda is made by electrolysis of concentrated solution of NaCl in
A. Nelson's Cell
B. Hg - Cell
C. CastnerKellner Cell
D. All of these
CHEMISTRY >> Solids
175. It consist of discrete molecules
A. sodium chloride
B. dry ice
C. copper
D. CaCl2
176. The _study of composition of pure substance in 17th century clearly shows that few elements
are components of many substances
A. qualitative
B. quantitative
C. both A & B
D. extensive
177. The enzyme which is used in treatment of cancer in children?
A. Thrombin
B. L- asparaginase
C. Both
D. None of these
178. Isoelectronic species have same
A. electronic configuration
B. Ionic size
C. Reactivity
D. PH
179. The valence electron pairs are arranged around the central atom to remain at maximum
distance apart to keep repulsion
A. maximum
B. moderate
C. zero
D. minimum
180. When Number of moles of reactants and products are same Equilibrium constant will have
A. negative value
B. Large value
C. No units
D. Units
57 When an electron remains between orbit, its momentum is
A. dequantized
B. quantized
C. emitted
D. changes always
58 The conversion of Nitrogen to ammonia or nitrogenous compounds is called
A. Nitrification
B. Nitrogen Fixation
C. Denitrification
D. Assimilation
59 Compounds having C and H atoms and their derivatives are called as_____?
A. Inorganic compounds
B. Organic compounds
C. Biochemical compounds
D. Carbohydrates
60 Which will evaporate faster; hot water in cup or cold water in a cup ?
A. Cold water
B. Hot water
C. Both evaporate at the same rate
D. Both evaporate slowly
61 The compounds which are formed by the replacement of one of the H of water by a alkyl group
are called as_____?
A. Ethers
B. Phenols
C. Alcohols
D. Carboxylic acids
62 Specific Rate constant is also known as
A. Time Constant
B. relative rate constant
C. Instantaneous rate constant
D. velocity constant
63 The negative ions having group of atoms is/are
A. OH-
B. CO32-
C. Cr2O72-
D. all of these
64 Alkanes are called as______?
A. Olefines
B. Paraffins
C. Reactive
D. All of these
65 In which phase SN₂ reactions are favored?
A. Solid
B. Liquid
C. Gas
D. All of these
66 The reactions that needs energy are called as___?
A. Endothermic reactions
B. Exothermic reactions
C. Exergonic reactions
D. Heat releasing reactions
CHEMISTRY >> Solids
67 grey and white tin co-exist at temperature
A. 128 C
B. 13.2 C
C. 32-38 C
D. 95.5 C
68 The solubility of alcohols is due to
A. dipole moment
B. covalent bonds
C. hydrogen bonding
D. electronegativity
69 The condition of a system is called as___?
A. Reaction conditions
B. Concentration
C. State of system
D. All of these
70 Heat of solution for NaCl is
A. High
B. low
C. Zero
D. One
71 SN₁ reactions are favored by which of the following reactions?
A. Water
B. Benzene
C. Carbon Tetrachloride
D. Carbon disulphide
CHEMISTRY >> Gases
72 One atmosphere is the force of ______long column of mercury on an area of 1cm2 at c
A. 76cm
B. 76mm
C. 76dm
D. 76pm
73 Carboxylic acids form dimer dur to______?
A. Small sizes
B. Polarity of C-O bond
C. H-bonding
D. Dipole-Dipole interactions
74 Which of the following compound is a Alcohol?
A. CH₃-O-CH₃
B. CH₃-OH
C. CH₃COOH
D. CH₃COCH₃
75 Which is not a heterocyclic compound?
A. Furan
B. Pyrrole
C. Pyridine
D. Ethane
76 Acetic acid is also named as______?
A. Propanoic acid
B. Butanoic acid
C. Ethanoic acid
D. Methanoic acid
77 Enzymes are _____ in nature.
A. Proteins
B. Carbohydrates
C. Lipids
D. Nucleic acid
78 Coal tar contains many organic compounds that can be separated by______?
A. Destructive distillation
B. Fractional distillation
C. Vacuum distillation
D. Partial distillation
79 In a pressure cooker, boiling point of water is______?
A. Raised than the normal
B. Lower than the normal
C. Lower than the freezing point
D. All of these
CHEMISTRY >> Solids
80 Atoms arranged in regular and repeating manner is the characteristic of
A. ionic solids
B. molecular solids
C. crystalline solids
D. covalent solids
CHEMISTRY >> Solids
81 The shape of crystal in which it usually grows is called its
A. size
B. capacity
C. habit
D. property
82 Protein component of enzyme is called______.
A. Coenzyme
B. Cofactor
C. Apo-enzyme
D. Prosthetic group
83 Find the amphoteric oxide
A. CaO2
B. CO2
C. SnO2
D. SiO2
84 Before giving condensation product , ammonia and its derivatives produces _______when react
with carbonyls?
A.. Alcohols
B. Carboxyl alcohol
C. Amino alcohol
D. None of these
85 Which one of the following has highest number of unpaired electrons?
A. Fe²⁺
B. Mn²⁺
C. Cr⁵⁺
D. Zn²⁺
86 A _______ is the force, which holds together two or more atoms or ions to form a large variety
of compounds
A. Ionic bond
B. chemical bond
C. covalent bond
D. metallic bond
87 Polymerization of ethene produces which of the following polymer?
A. Polyvinyl
B. Polethyl
C. Polyethylene
D. Polyethoxy
88 Which of the following catalyst is used for the preparation of acidic anhydrides ?
A. K₂Cr₂O₇
B. P₂O₅
C. H+/H₂O
D. H₂SO₄
89 Which of the following alcohol give iodoform test?
A. Propanol
B. Methanol
C. Ethanol
D. Butanol
90 Zero order reactions do not depend upon concentration of
A. products
B. reactants
C. Ions
D. radicals
91 Which of the following is true about the kinetics of bimolecular elimination reactions?
A. 1st order reaction
B. 2nd order reaction
C. Zero order reaction
D. 3rd order reaction
Q 92 The products of SN₁ reactions are formed with______?
D. All of these
93 Rate determining step is also called
A. Critical step
B. Rate Limiting step
C. Final Step
D. None of these
94 Which of the following product is obtained from the Chlorination of acetylene?
A. 1,2,3,4-tetrachloroethylene
B. 1,1,2,2-tetrachloroethylene
C. 1,1,2,2-Tetrachloroethane
D. 1,2,3,4-Tetrachloroethylene
95 The atoms of hemoglobin is heavier than H-atoms
A. 67,000 times
B. 68,000 times
C. 65,000 times
D. 69,000 times
96 In chemical combination of H-atom with sodium. It gains an electron but in case of HF,H-atom
A. gains 2 e-
B. lose 1e-
C. lose 2e-
D. gain 2e-
97 Electrolysis of bauxite is done by
A. Haber's Process
B. Born Haber cycle
C. Ion Exchange Method
D. Hall-Heroult Process
98 Electrolysis is carried out in
A. A beaker
B. Flask
C. Evaporating Dish
D. Electrolytic Cell
99 For the reaction; NaOH + HCl → NaCl + H₂O the change in enthalpy is called as_________?
A. Enthalpy of formation
B. Enthalpy of neutralization
C. Enthalpy of Sublimation
D. Enthalpy of reaction
100 Shifting the position of equilibrium can be used to Increase
A. Temperature
B. pressure
C. yield of reaction
D. All of these
Q 101 Which of the following is directional bond?
A. Ionic bond
B. Metallic bond
C. H-bond
D. None of these
102 Dehydration of alcohols at low temperature and high acid concentration results in?
A. Alkene
B. Ether
C. Carboxylic acid
D. Aldehydes
103 Ammonia may be prepared by heating ammonium chloride with
A. Water
B. NaCl
C. Aqueous sodium hydroxide
D. H2SO4
CHEMISTRY >> Solids
104 The type of hybridization in diamond is
A. spherical
B. sp2
C. sp3
D. sp-sp
105 First step in the SN₁ reaction is_____?
A. Dehydration
B. Protonation
C. Ionization
D. Attack of nucleophile and departure of leaving group
106 Which type of carboxylic acid is produced from the hydrolysis of nitriles?
A. Beta-hydroxy carboxylic acids
B. Acids having one carbon more than the starting material
C. Acids having one carbon less than the starting material
D. Alpha-hydroxy acids
107 What are Kekule structures?
A. The two isomers of benzene
B. The isomers of arenes
C. The two-resonance structure of benzene
D. The two-resonance structure of phenols
108 Which one of the following H-bond is strong?
A. O-H
B. N-H
C. F-H
D. Cl-H
109 During preparation of Acetaldehyde from ethanol in laboratory, why acetaldehyde is distilled
off quickly after formation?
A. To avoid decomposition of product
B. To avoid reduction
C. To avoid further oxidation to acetic acid
D. None of these
110 The peaks forms in a mass spectrograph shows number of __________ of an element
A. electrons
B. isotopes
C. protons
D. neutrons
111 Carbon is
A. trivalent
B. Tetravalent
C. Monovalent
D. Pentavalent
112 Phenol is ________liquid ?
A. Dense
B. Hard
C. Deliquescent
D. intermittent
57 If Water is present on a cup placed on a table, what will be the system in this case?
A. Water
B. Water in cup
C. Whole table
D . All of these
58 Which of the statement is incorrect for XeO4 ?
A. four p𝜋-d𝜋 bonds are present
B. four sp3 – p 𝜎 bonds are present
C. It has a tetrahedral shape
D. It has a square planar shape
59 Standard electrode Potential is denoted by
A. E
B. E^-1
C. E^0
D. ∂
60 The organic compounds having close resemblance in structure as well properties are
A. Glycol and cyclohexanol
B. Formaldehyde and benzol
C. Diethyl ether and ethyl alcohol
D. methanal and acetone
61 _____cathode is used in discharge tube experiment for discovery of protons
A. flat
B. round
C. perforated
D. oval
62 The temperature at which enzyme activity is maximum is called as_____?
A. Maximum temperature
B. Absolute temperature
C. Critical temperature
D. Optimum temperature
CHEMISTRY >> Gases
63 The unit_ is commonly used by meteorologist
A. Bar
B. centibar
C. millibar
D. kilobar
64 The unit used to express the relative atomic mass is called
A. gram unit
C. atomic mass
D. atomic mass unit
65 Which of the following forces have no relation with valence electrons?
A. Ionic Bond
B. Chemical bond
C. Intermolecular forces
D. Intramolecular forces
66 The change in concentration of reactants or products per unit time is
A. rate constant
B. reaction speed
C. Rate of a reaction
D. All of these
67 Which of the following Halogen react fast with alkanes in substitution reactions?
A. Cl₂
B. F₂
C. I₂
D. Br₂
68 The outermost s and p orbitals of Noble gases are completely filled that why they are
A. stable, reactive
B. stable ,uncreative
C. unstable, reactive
D. unstable ,uncreative
69 Le Chatelier Principle is about
A. Reaction Mixture
B. Reactants
C. Equilibrium Mixture
D. Products
70 In IUPAC nomenclature, aldehydes are named as________?
A. Alkanol
B. Alkanal
C. Alkanone
D. Alkaldehyde
71 The oxidation number in [MnO4]-2
A. 7
B. -7
C. 6
D. -6
72 In which of the following body part protein is not present ?
A . Skin
B. Hair
C. Nails
D. Bones
CHEMISTRY >> Gases
73 25 cm3 of the sample of H2 gas effuses four times as rapidly as 25 cm3 of an unknown gas
what will be the molar mass of unknown gas?
A. 16g mol-1
B. 32g mol-1
C. 72g mol-1
D. 48 gmol-1
74 Which one of the following is correct about heat energy?
A. Path function
B. State function
C. Move from cold to hot body
D. Property of a system
75 Which of the following alkyl halide give SN₁ reactions?
A. 1-chloropropane
B. 2-chloropropane
C. n-butyl chloride
D. 2-methyl,2-chloropropane
76 Masses of enzymes is between____?
A. Thousands
B. Millions
C. Hundreds
D. Billions
77 Intervening electrons have a negative charge which repulses other electrons and ___attraction
b/w nucleus and electrons
A. blocks
B. reduces
C. increases
D. enhances
78 An exothermic reaction is allowed to reach equilibrium, if heat energy is then removed, the
equilibrium will shift
A. to the product side
B. to reactant side
C. toward the middle
D. None of these
79 Reaction of vinyl acetylene with HCl produces?
A. Polyvinyl polymer
B. Polyvinyl Acetylene
C. Neoprene
D. Chloroprene
80 Which one of the following is called as marsh gas?
A. Methane
B. Ethane
C. Propane
D. Butane
81 Which of the substance has the highest melting point?
A. CO2
B. H2O
C. NaCl
D. MgO
82 The first ionization potential of alkaline earth metal is greater than alkali metals because
A. They are more reactive
B. They have greater atomic radii
C. They have smaller atomic sizes
D. All
83 Avogadro's hypothesis is applicable to ______only.
A. all gases
B. inert gases
C. ideal gases
D. light gases
84 Which one of the following is not an example of state function?
A. Temperature (T)
B. Volume (V)
C. Enthalpy (E)
D. Heat (q)
CHEMISTRY >> Gases
85 ______are estimated to constitute more than 99% of the visible universe
A. solids
B. liquids
C. gases
D. plasmas
86 The electrolysis of aqueous solutions of salt is complex because of the ability of water
A. to vaporize
B. to be oxidize and reduce simultaneously
C. to form hydrogen bonds
D. All of these
87 The elements of which group show abnormally very low values of electron affinity in every
period of periodic table
A. group 2A
B. group 5A
C. both A & B
D. none of these
88 In complex compounds the oxidation number is written in
A. English
B. Greek
C. Roman numeral
D. Hebrew
CHEMISTRY >> Solids
89 The boiling point of water is lower that HF because of ___hydrogen bonding
A. strong
B. moderate
C. weak
D. constant
90 Catalytic activity of enzyme is enhanced by:
A. Activator
B. Coenzyme
C. Co-factor
D. Both A and B
90 Catalytic activity of enzyme is enhanced by:
A. Activator
B. Coenzyme
C. Co-factor
D. Both A and B
91 Which of the following enzymes present in yeast helps out in fermentation
A. Diastase
B. Maltase
C. Zymase
D. all of above
92 Which of the following is an example of Monocarboxylic acid ?
A. Oxalic acid
B. Methanoic acid
C. Glutaric acid
D. Adipic acid
93 In IUPAC nomenclature, Carboxylic acids are named as_______?
A. Alkoxy acid
B. Alkanoic acid
C. Alkyl carboxylic acid
D. Alkoxylate acid
94 Which of the following compound does not give cannizzaro reaction?
A. Benzaldehyde
B. Trimethyl acetaldehyde
C. Formaldehyde
D. Acetaldehyde
95 Due to which of the following forces present in water aquatic life is protected in Cold climate ?
B. Debye forces
C. H-bonding
D. London dispersion forces
96 Which one of the following is correct structure of benzene?
A. Tetrahedral
B. Hexagonal planer
C. Hexagonal irregular
D. Trigonal planar
97 Formalin solution contains how much water?
A. 52%
B. 8%
C. 40%
D. 30%
98 Reduction of ketones produce______?
A. Aldehydes
B. Methanol
C. Primary alcohols
D. Secondary alcohols
99 The amount of heat required to form vapors of one mole of a liquid at its boiling point is called
as?
A. Molar heat of fusion
B.. Molar heat of vapourization
C. Molar heat of sublimation
D. Molar heat of Evaporation
100 Decomposition of Ozone has a very low value of equilibrium constant because of its
A. stability
B. reactivity
C. compressibility
D. Instability
101 When atoms share their electrons to complete its valence shell and attains nearest noble gas
configuration, the bond formed is
A. Ionic bond
B. covalent bond
C. metallic bond
D. dative bond
102 By which of the following way acetamide can be prepared?
A. Hydrolysis of ethyl chloride
B. Heating methyl cyanide
C. Heating ammonium acetate
D. Heating ethyl acetate
103 Ethyne has which hybridization?
A. sp³
B. sp²
C. sp
D. sp²d
104 Alkyl halides generally give which type of elimination reactions?
A. alpha-elimination
B. gamma-elimination
C. beta-elimination
D. syn-elimination
105 At which temperature water has maximum density?
A. 2℃
B . 4℃
C. 0℃
D. <0℃
106 One of them is not an alkali metal, Mark it
A. Francium
B. Caesium
C . Rubidium
D. Radium
107 K2 (Cu(CN)4) which one is correct
A. Potassium tetra cyano recuperate
B. Coordination number is 2
C. The ligand is positively charged
D. Central atom is present in the avionic sphere
108 Which of the following alcohol does not converted into carboxylic acid when react with
K₂Cr₂O₇/H₂SO₄ ?
A. CH₃C(CH₃)₂OH
B. CH₃CH(CH₃)OH
C. CH₃OH
D. C₂H₅OH
109 Spectrum is the visual display or ________of component of white light when it is passed
through prism
A. rarefaction
B. radiation
C. collection
D. dispersion
110 If 9.8 g of sulfuric acid dissolved in excess quantity of water, it will yield _______moles of
hydrogen ion ( H+) and _____mole of sulphate ions (SO4 -2)
A. 0.1, 0.2
B. 0.1, 0.3
C. 0.2, 0.4
D. 0.2,0.1
111 If a certain atom gains electrons its oxidation number will be
A. Negative
B. Positive
C. zero
D. Unity
112 Higher order reactions has half-life
A. same as first order
B. Different from first order reactions
C. Directly proportional to Concentration of reactants
D. None of these
CHEMISTRY >> Solids
1. The smallest part of crystal lattice showing all the properties of a crystal is called
as_____?
A. Crystallite
B. Unit cell
C. Unit crystal
D. Monomer
2. A voltaic cell produces electrical energy from:
A. Potential energy
B. Chemical energy of Ions
C. Kinetic Energy
D. Free Electrons
3. The value of Planck's constant 'h' is:
A. 6.626 x 1 -3 KJs
B. 6.262 x 1 -3 Js
C. 6.626 x 1 -3 Js
D. 6.262 x1 -3K Js
4. Thermochemistry is very important to learn about
A. Chemical Equilibrium
B. Chemical Bonding
C. Heat contents of a compound
D. All of these
5. Rate of chemical reactions helps in designing industrial process which is:
A. Completed instantaneously
B. Slow
C. Economical
D. None of these
6. Which alkali metal only combine with Nitrogen?
A. Li
B. Fr
C. Cs
D. K
CHEMISTRY >> Gases
7. Joule-Thomson effect is used to _the temperature of a gas to liquefy it:
A. raise
B. higher
C. equalize
D. lower
8. Buffer solutions resist change in their:
A. temperature
B. solubility
C. volatility
D. pH
9. The chemical reactivities of elements, depend upon their characteristics electronic_____.
A. shields
B. forces
C. configurations.
D. shells
10. Reaction of carboxylic acids with base is a _________ reaction?
A. Neutralization
B. Esterification
C. Oxidation
D. All of these
11. Which of the following are product of following reaction in the presence of sunlight? CH₄ +
Cl₂→ ?
A. CHCl₃
B. CCl₄
C. CH₂Cl₂,CH₃Cl
D. All of these
12. Give IUPAC name of following compound Tert-Butanol:
A. 3 - methyl-2-propanol
B. 3-methyl-1-propanol
C. 2-hydroxy-1-propanol
D. 2-methyl-2-propanol
13. Isopentane is an example of________?
A. Aromatic compounds
B. Branched chain compound
C. Alicyclic compounds
D. None of these
14. In aluminum oxide ,ions are present in the ratio 2:3, its formula in:
A. AlO
B. Al2O
C. Al2O3
D. Al3O2
CHEMISTRY >> Gases
15. PV/nRT for an ideal gas is called:
A. expansion factor
B. depression factor
C. compressibility factor
D. diffusion factor
16. In which direction Cathode rays deflected in the presence of magnetic field?
A. Moves upward
B. Moves downward
C. Move randomly
D. Moves in straight li
17. Enzymes are also called as_____?
A. Catalyst
B. Lipoproteins
C. Conjugated molecules
D. Biocatalyst
18. Instantaneous rate of reaction is the rate at any:
A. At Equilibrium
B. one instant
C. Given Temperature
D. Given Pressure
19. Base catalyzed reaction of carbonyl group takes place in presence of:
A. Weak electrophile
B. Strong nucleophile
C. Week nucleophile
D. Strong electrophile
20. Which of the following has anti knocking properties?
A. Tetramethyl lead
B. Tetraethyl lead
C. Iso-octane
D. All of these
21. Formic acid is obtained from _______?
A. Apples
B. Butter
C. Ant's sting
D. Foam
22. What does thermodynamics means?
A. Study of change in state of the system
B. Study of energy changes during a process
C. Study of material content of a system
D. All of these
23. Ionic Salts of Group 1 elements can conduct Electricity when they are in____?
A. Solid form
B. Molten form
C. Aqueous form
D. Both b and c
24. What is the general formula of Aldehyde?
A. RCOR
B. RCOOR
C. RCHO
D. RCOOH
CHEMISTRY >> Gases
25. 1 Pascal is equal to:
A. 1 Nm-2
B. 76 t rr
C. 1 1325 pa
D. all of these
26. Human body contains _________kind of proteins?
A. 60000
B. Almost 10000
C. 5000
D. 200
CHEMISTRY >> Solids
27. when water freezes at C, spaces occur between its molecules which results in its ___
A. decrease in volume
B. decrease in density
C. increase in density
D. increase in volume
28. Which one of the following is correct value of resonance energy of benzene?
A. 155.5kJ/mol
B. 150.5kJ/mol
C. 170 kJ/mol
D. 140.5kJ/mol
29. An electron in an atom is completely described by its:
A. 2 quantum numbers
B. only one quantum number
C. four quantum numbers
D. 3 quantum numbers
CHEMISTRY >> Solids
30. which one of them can conduct electricity in solid state:
A. diamond
B. graphite
C. Nail
D. iodine
31. What is the reason for the reactivity of Grignard reagent?
A. Presence of Mg atom
B. Polarity of C-H bond
C. Polarity of C-Mg bond
D. Presence of electrophilic carbon
32. The alcohols in which the carbon which is attach to the OH group is further attach with two
carbon atoms is called as?
A. Primary alcohols
B. Secondary alcohols
C. Tertiary alcohols
D. None of these
33. In CCl4 ,all C-CL bonds are _________ but molecule is __ overall:
A. polar,nonpolar
B. nonpolar.neutral
C. polar. Neutral
D. neutral, on polar
34. Lanthanides and actinides are also called as______?
A. Rare earth elements
B. Outer transition elements
C. Non typical elements
D. Typical transition elements
35. In a voltaic cell ,two half cells actually separates:
A. Two electrolytes
B. Anode and Cathode
C. Oxidation Half cell and Reduction half Cell
D. All of these
36. In non-polar molecules ,the strength of London forces depends on number of:
A. moles
B. molecules
C. atoms
D. all of these
37. Benzophenone is also known as :
A. Diphenyl ketone
B. Ethyl Phenyl ketone
C. Tri Phenyl ketone
D. None of these
38. The statement; energy of system and surrounding is conserved, is related to which law of
thermody~namic?
A. 1st law
B. 2nd law
C. 3rd law
D. None of these
39. Evaporation is reverse of______?
A. Sublimation
B. Freezing
C. Melting
D. Condensation
40. Ethane is obtained by electrolyzing __________.
A. Potassium formate
B. Potassium succinate
C. Potassium acetate
D. Potassium fumarate
41. Dalton's atomic theory couldn't explain the concept about:
A. isomers
B. protons
C. isotopes
D. nucleus
42. Which one of the following is not the property of a system?
A. Enthalpy
B. Internal energy
C. Thermal energy
D. Temperature
43. Freezing point of acetic acid;
A. 16.6℃
B. 18℃
C. -20℃
D. 10℃
44. Which is sold as fertilizer:
A. CaSiO3
B. Na2SiO3
C. Ca3(PO4)2
D. MnSiO3
45. Which of the following shows H-bonding?
A. CH₃CH₂OH
B. CH₃-O-CH₃
C. CH₃CH₂Cl
D. All of these
46. The element caesium bears resemblance with:
A. Ca
B. Cr
C. Both of the above
D. None of the above
47. Which of the following is a dihydric alcohol?
A. Ethanol
B. Methanol
C. Glycerol
D. Glycol
48. If in a solution of alkyl halide in a nonpolar solvent, base is added which of the following
reaction takes place?
A. SN₂
B. E₁
C. SN₁
D. E₂
49. It is not possible for us to measure exact position and exact momentum of electron
simultaneously is the statement of:
A. de-Broglie
B. Mosley
C. Heisenberg
D. Neil Bohr
50. The catalyst in the formation of ester from alcohol and a weak acid is:
A. A base
B. Palladium
C. Nickel
D. A mineral Acid
CHEMISTRY >> Gases
51. The least value of Van der Waals constant is of:
A. H2
B. N2
C. CO2
D. Cl
52. Cyanohydrins when reacted with mineral acid produces ________?
A. Beta Hydroxy carboxylic acids
B. Alpha hydroxy carboxylic acids
C. Carboxylic acids
D. Unsaturated acids
53. The smallest number of molecules are present in:
A. 3.6g of H2
B. 4.8g of C2H5OH
C. 2.8 g of CO
D. 5.4 g of N2O5
54. Shape of benzene molecule is:
A. Hexagonal planar
B. Square planar
C. Trigonal planar
D. linear
55. A bonding electron pairs of is attracted by ________of atoms.
A. one nucleus
B. both nuclei of atoms
C. lone pair
D. shared pair of electron
56. In Ion electron method, while balancing oxygen and Hydrogen atoms:
A. First balance Hydrogen
B. First balance oxygen
C. balance both at the same time
D. order doesn't matter
125. How many isomers of C₄H₁₀ are possible?
A. 4
B. 3
C. 2
D. 1
126. Which one of the following is an electrophile?
A. Br⁺
B. CH₄
C. NH₃
D. H₂O
127. Limiting reactant controls the amount of :
A. reactant
B. products
C. both A & B
D. none of these
128. Which of the following is weaker acid?
A. HCl
B. H₂SO₄
C. CH₃COOH
D. H3PO4
129.What is the coordination number of Pt in [PtCl(NO₂)(NH₃)₄]
A. 2
B. 4
C. 6
D. 7
CHEMISTRY >> Aldehydes and Ketones
130. Aldehydes are present in natural oils that are used as?
A. Flavours
B. Fragrances
C. Both a and b
D. Sugars
131.Which of the following element is not usually present in all proteins?
A. Carbon
B. Hydrogen
C. Nitrogen
D. Sulphur
132. In general, atomic radii decreases from left to right in a period, due to increase in
A. number of shells
B. nuclear charge
C. shielding effect
D. bond length
133. dx/dt is rate of change of concentration with respect to
A. Temperature
B. Pressure
C. time
D. None of these
134. Which of the following reaction is used in the preparation of vegetable ghee from oil?
A. Hydration
B. Sulphonation
C. Hydrogenation
D. Dehydrogenation
135. Which element has completely filled d subshell in both atomic and ionic form?
A. Cr
B. Fe
C. V
D. Zn
136. Sulphur-16 gets its stabilization by gaining 2 electron to become equal to
A. neon
B. argon
C. helium
D. krypton
137. Reduction of carboxylic acids into alkanes in the presence of HI/P, COOH is reduced to_____?
A. CH₄
B. C₂H₆
C. CH₂
D. None of these
138. The valency of an atom will be one if there is a sufficient gap b/w first and second
D. none of these
139. Which one of the following is neutral to litmus?
A. Phenol
B. Ethanol
C. Carboxylic acid
D. NaOH
140. Which of the following solvent favor SN₂ reactions?
A. Water
B. Ammonia
C. Carbon tetrachloride
D. Acetic acid
141. In a carboxylic acid dimer how many H-bonds are present ?
A. Three
B. Two
C. Five
D. One
142. How many isomers of a disubstituted benzene are possible?
A. Two
B. Three
C. Four
D. One
143. Heat absorbed by a substance at constant pressure is equal to_______?
A. ΔG
B. ΔH
C. ΔE
D. ΔH-ΔE
144. In Electrochemical Cell Negative Ions are migrated towards
A. Anode
B. Cathode
C. Toward the bottom of the cell
D. Towards the walls of the cell
CHEMISTRY >> Solids
145. Which of the following solids is isotropic?
A. ionic solids
B. molecular solids
C. amorphous solids
D. metallic solids
146. Spectrometry is used when reactants and products absorb:
A. Ultraviolet radiations
B. Visible radiation
C. Infrared radiation
D. All of these
147. Protein is a polymer of________?
A. Nitrogen atoms
B. Amino acids
C. Glucose
D. Nitrogenous base
148. Which of the following is not a fraction of refined oil?
A. Naphtha
B. Kerosene
C. Petroleum ether
D. Dioxal
CHEMISTRY >> Gases
149. The molar volume of CO2 is maximum at:
A. 273 C & 2 atm
B. c and 1 atm
C. STP
D. 127 C & 1 atm
150. Which of the following forces has ability to form clusters and large molecules?
A. Ionic bond
B. Induced dipole forces
C. H-bond
D. All of these
151. Which of the following does not show metamerism?
A. Ethers
B. Secondary amines
C. Ketones
D. Aldehydes
152. A chemical reaction has reached has reached to a state of dynamic equilibrium at certain
temperature, Which of the statement is incorrect
A. Concentration of the reactants remains constant
B. Products are continuously being formed
C. The rate of forward and backward reactions are same
D. The reaction has stopped completely
CHEMISTRY >> Solids
153. The temperature at which one crystalline form changes to other is called _temperature
A. critical
B. absolute
C. transition
D. none of these
154. When product formed act as a catalyst phenomena is called:
A. Biocatalyst
B. Autocatalysis
C. Heterocatalysis
D. Homocatalysis
CHEMISTRY >> Solids
155. The small orderly arranged crystalline parts of amorphous solids are called:
A. isotrope
B. crystals
C. crystallite
D. Bakelite
CHEMISTRY >> Gases
156. This gas cannot be liquefied by Linde's method:
A. methane
B. carbon dioxide
C. hydrogen
D. helium
157. In which of the following reagent Cupric citrate complex is formed?
A. Fehling's solution test
B. Benedict's solution test
C. Silver mirror test
D. sodium nitroprusside test
158. Enthalpy is the sum of internal energy:
A. Work done
B. Entropy
C. Potential Energy
D. Kinetic Energy
159. 27 g of Al will react with how much mass of O2 to produce Al2O3
A. 8 g of oxygen
B. 16 g of oxygen
C. 32 g of oxygen
D. 24 g of oxygen
160. The rate of SN₁ reaction become doubled if______?
A. Concentration of Nucleophile doubled
B. Concentration of Substrate doubled
C. Concentration of Substrate Tripled
D. Concentration of substrate remain same
161. The method used for preparation of phenol is:
A. Kolbe's method
B. Dow's method
C. Nitration
D. Williamsons synthesis
162. BeO is___ in nature.
A. Acidic
B Basic
C. Amphoteric
D. Neutral
163. Tautomerism involves the transfer of______?
A. Electron
B. Carbon atom
C. Functional group
D. H-atom
164. Which enzyme is used for diagnosis of Jaundice ?
A. LDH-1
B. Protease
C. Alkaline phosphatase
D. None of these
165. If a hydrogen atom remains in its first excited level, how many times will its radius be greater
than Bohr's radius.
A. twice
B. four times
C. same, same
D. eight times
CHEMISTRY >> Gases
166. Plasma 'the fourth state of matter was identified by:
A. Berzelius
B. William Crooks
C. Dalton
D. Rutherford
167. In which manner H-Bond is formed in HF molecule ?
A. Random
B. Zigzag
C. Tetrahedral
D. Linear
168. Which enzyme is raised in rickets:
A. Alkaline phosphatase
B. LDH-1
C. Acidic phosphatase
D. None
169. Which of the following is a carboxylic acid derivative ?
A. Alcohol
B. Acetic acid
C. Acyl halide
D. Methyl halide
170. What is the correct relation between ΔH and intermolecular forces ?
A. Higher ΔH weaker intermolecular forces
B. Higher ΔH, higher intermolecular forces
C. Lower ΔH , higher intermolecular forces
D. None of these
170. What is the correct relation between ΔH and intermolecular forces ?
A. Higher ΔH weaker intermolecular forces
B. Higher ΔH, higher intermolecular forces
C. Lower ΔH , higher intermolecular forces
D. None of these
CHEMISTRY >> Gases
171. The sum of mole fraction of the gases in a mixture of gases is
A. always greater than 1
B. always smaller than 1
C. may be equal or less than 1
D. always 1
172. Iodoform test is performed to distinguish between
A. alcohols and phenols
B. methanol and ethanol
C. primary and secondary alcohols
D. phenols and ethers
173. If any two sub shells have same (n+l) values, the sub shells of ______value will placed first
A. higher
B. smaller
C. equal
D. moderate
174. Which is an aromatic Aldehyde?
A. Propanone
B. Pentanol
C. Benzaldehyde
D. Hexanol
175. A molecule of water has two bond, so 1 mole of water will contain ____moles of bonds
A. 1
B. 2
C. 3
D. 4
176. As the hydrolysis of ester proceeds more and more acid is formed giving a:
A. Rising curve
B. Falling Curve
C. Straight line
D. None of these
177. The central atom along with ligands is called:
A. Complex ion
B. Coordination sphere
C. Ligand
D. Complex compound
178. Which of the following alkyl halide is most reactive towards Mg atom?
A. Alkyl bromide
B. Alkyl fluoride
C. Alkyl chloride
D. Alkyl iodide
CHEMISTRY >> Solids
179. Which one of them is a good conductor of electricity?
A. ionic solids
B. molecular solids
C. network covalent solids
D. metallic solids
180. In the presence of KF, AlF3 is soluble in HF, find the complex formed:
A. K3[AlF6]
B. AlH3
C. K[AlF3H]
D. K3[AlF3H3]
(PMC PAID TEST-14)

57. Fossil fuels are produced due to_______?
A. Fast decomposition of organic matter
B. Decomposition of plants
C. Decomposition of animals
D. Biochemical decomposition of dead organic matter
58. In a Voltaic Cell Zinc Electrode is dipped in:
A. Copper Sulphate
B. Copper chloride
C. Zinc Chloride
D. Zinc Sulphate
59. In IUPAC nomenclature alkyl halides are named as_________?
A. Alkyl Halogens
B. HalogenoAlkanes
C. Haloalkanes
D. Alkyl halides
59. In IUPAC nomenclature alkyl halides are named as_________?
A. Alkyl Halogens
B. HalogenoAlkanes
C. Haloalkanes
D. Alkyl halides
60. Positive rays are produced when ________strike the molecules of a gas in a discharge tube
A. low speed neutrons
B. high speed neutrons
C. low speed electrons
D. high speed electrons
61. The densities of liquids are much ________than gases but ____ to solids.
A. smaller, closer
B. greater, closer
C. smaller, far away
D. greater, far away
62. Hess law states that the total enthalpy change of a reaction remains same regardless of:
A. Route reaction takes for completion
B. Temperature of reactants
C. concentration of products
D. concentration of reactants
63. BH3 has a geometry with H-B-H bond angles of 12
A. linear
B. trigonal planar
C. tetrahedron
D. bent
63. BH3 has a geometry with H-B-H bond angles of 12:
A. linear
B. trigonal planar
C. tetrahedron
D. bent
65. Which of the following element can form interstitial alloy with transition elements?
A. Zn
B. Mg
C. H
D. All of these
66. In aromatic carboxylic acids -COOH group is named as________?
A. Substituent
B. Parent
C. Benzoic acid
D. Both b and c
CHEMISTRY >> Gases
67. The value of Van Der Waals constant 'b' for Hydrogen gas is:
A. 266
B. 366
C. 318
D. 562
68. On reacting with metals carboxylic acid produces which of the following products ?
A. Salt + water
B. Salt
C. Salt + H₂ gas
D. Salt + Alcohol
69. Phenolic resins are produce by________?
A. Formaldehyde
B. Acetaldehyde
C. Acetone
D. Butyraldehyde
70. Reduction of alkyl halides in the presence of Zn and mineral acid produces______?
A. Alkenes
B. Alkanes
C. Alkynes
D. Alcohols
71. The most common positive ions are formed by the atoms:
A. non metals
B. metals
C. noble gases
D. Hydrogen
72. Cyclic bromonium ion is formed when ethene reacts with________?
A. HBr
B. HCl
C. Br₂
D. None of these
73. Isotopes are the atoms of same element having different number of :
A. electron
B. proton
C. positron
D. neutron only
74. If the concentration of reactants in a chemical reaction is Unity the rate is called:
A. Unit rate constant
B. specific rate constant
C. Relative rate constant
D. Average rate constant
75. Legumine & collagen protein are present in which type of body tissues:
A. Cardiac
B. Epithelial
C. Connective
D. Epidermis
76. SN₁ reactions are favored by which of the following reactions?
A. Water
B. Benzene
CHEMISTRY >> Gases
77. Plasma is difficult to maintain at
A. low temperature
B. high temperature
C. low pressure
D. high pressure
78. When an atom shares more than one electrons, the bond formed is:
A. single bond
B. double bond
C. triple bond
D. both B & C
79. Near completion of a chemical reaction average rate is:
A. Lower than instantaneous rate
B. higher than instantaneous rate
C. Equal to instantaneous rate
D. None of these
80. Acyclic hydrocarbons are also called as______?
A. Closed chain hydrocarbons
B. Open chain hydrocarbons
C. Ring compounds
D. Alicyclic compounds
C.HEMISTRY >> Transition Elements
81. Ist series of transition elements start from?
A. Sc
B. Y
C. La
D. Cd
82. Gasoline produced by the Fractional distillation is_____?
A. 80%
B. 5%
C. 65%
D. 20%
83. Tollen's reagent is ammonical solution of_______?
A. Silver nitrate
B. Silver acetate
C. Cupric tartrate
D. Cupric citrate
84. Temperature and volume in an experiment are part of:
A. Surroundings
B. System
C. State of a system
D. All of these
85. Carboxylic acids are produced by the oxidation of______?
A. Alcohol
B. Aldehyde
C. Ketone
D. All of these
CHEMISTRY >> Gases
86. Greater the mass of gas taken, greater will be slope of straight line. Because greater the ______greater
will be volume occupied.
A. pressure
B. temperature
C. number of moles
D. all of these
87. Proteins are _________in structure ?
A. Two dimensional
B. Three dimensional
C. Uni-dimensional
D. None of these
88. What is the common name of 2-methyl-2-chloropropane ?
A. secondary propyl chloride
B. Tertiary butyl chloride
C. Secondary butyl chloride
D. Isobutyl Chloride
89. Electrons can revolve only in those orbits having _______-angular momentum which depends on its
______ number.
A. variable, quantum
B. fixed, principal
C. fixed, quantum
D. variable, principal
90. Which of the following isomerism is shown by alkynes?
A. Positional isomerism
B. Geometrical isomerism
C. Cis-trans isomerism
D. Functional group isomerism
91. When does it mean, when a reaction is exothermic?
A. Energy content of product is more
B. Energy content of reactant is less
C. Heat is transferred from the system to surrounding
D. Heat is transferred from the Surrounding to the system
92. Alcohol oxidation gives carboxylic acid through:
A. Amide
B. Carbonic acid
C. Ketone
D. Aldehyde
93. Temperature for maximum yield at an appropriate reaction rate is:
A. 200C
B. 250C
C. 450C
D. 400C
94. Methylated spirit is formed by the addition of:
A. acetone
B. pyridine
C. 1 % methanol
D. all of above
95. On which factors the vapour pressure of a substance does not depend?
A. Physical state of matter
B. Intermolecular forces
C. Surface area
D. Temperature
96. In nomenclature, aldehyde group in all aldehydes are given position 1 and its position is not mentioned
in the name because?
A. Aldehyde is given priority
B. Aldehyde is parent
C. Aldehyde group is present at terminal
D. None of these
97. Li is different from its family members due to:
A. Small size
B. High charge density
C. Less electro positivity
D. All of the above
CHEMISTRY >> Solids
98. Sulphate ion is:
A. Triangular Planner
B. Cubic
C. Cubic Face Centred
D. Tetrahedral
99. How carboxylic acid group attached to benzene ring affect its reactivity?
A. Make it reactive
B. Makes ortho position of benzene more reactive than others
C. Makes meta position of benzene more reactive than others
D. Makes para position of benzene more reactive than others
100.The side of the manometer in which mercury rises faces the:
A. atmosphere
B. liquid
C. container
D. gas
101.The unhybridized p orbitals of benzene are present in the form of______?
A. Between the C-C bonds of benzene
B. Above and below the carbon bonds
C. In the form of cloud above and below the benzene ring
D. None of these
102.Brass and bronze have one metal in common?
A. Zn
B. Hg
C. Cu
D. Fe
103._______ enzyme catalyses the conversion of hexoses to 6- phosphate derivatives.
A. Hexokinase
B. Glucokinase
C. Fructokinase
D. Malonic acid
104.Which of the following has six isotopes:
A. palladium
B. tin
C. cadmium
D. carbon
105.The Addition of Hydrogen cyanide in Formaldehydes give which product?
A. 2- Hydroxypropanoic acid
B. 2- methylpropanenitrile
C. Hydroxyacetonitrile
D. 2- Hydroxypropanenitrile
106.Which of the following reactions have first step similar with each other?
A. E₁,S₂
B. E₂,S₁
C. E₂,S₂
D. E₁,S₁
CHEMISTRY >> Solids
107.In Rhombohedral system, all three angles lies between _________degree.
A. 9 & 45
B. 9 & 2
C. 9 & 12
D. 12 & 18
108.Fused Bauxite is electrolyzed to get.
A. Sodium
B. Magnesium
C. Aluminum
D. Iron
109.Which of the following is the heterocyclic compound?
A. thiophene
B. phenol
C. aniline
D. touline
110.Kp=Kc (RT)Δn , T stands for:
A. Temperature
B. Absolute Temperature
C. Critical Temperature
D. All of these
111.Formation of ZnSO4 from blue copper sulphate solution is a spontaneous:
A. Oxidation reaction
B. Addition Reaction
D. Redox reaction
CHEMISTRY >> Gases
112.Ammonia can form only one H-bond because of presence of:
A. 3 free electron
B. one lone pair of electron
C. 5 electron in outer shell
D. none of these

57. Which enzyme causes the hydrolysis of fats ?
A. Urease
B. Lipase
C. Maltase
D. Protease
58. The region where probability of finding the electron is maximum is called as:
A. Nucleus
B. Atom
C. Orbital
D. Nodal plane
59. The compounds in which similar groups are present on the same side of double bond are
called as____?
A. Trans isomers
B. Positional isomers
C. Cis isomer
D. None of these
60. Following are example of Intramolecular forces except?
A. Ionic bond
B. Covalent bond
C. Metallic bond
D. Dipole Dipole forces
61. Nyholm & Gillespie explains the shapes of molecules for:
A. transition elements
B. non transition elements
C. only alkali metals
D. Alkaline earth metals
62. The formula of Chile Saltpeter is:
A. NaNO3
B. CaCO3
C. Ba (NO3)2
D. NH4Cl
63. SN₂ reactions are ________?
A. Nucleophilic unimolecular addition reactions
B. Nucleophilic bimolecular substitution reactions
C. Nucleophilic bimolecular addition reactions
D. Nucleophilic unimolecular substitution reactions
64. Rate of reaction can be calculated by calculating:
A. Change in temperature
B. Change in pressure
C. Change in volume
D. Change in concentration
65. In Ion Electron Method of Balancing, equations are:
A. Written with Oxidation numbers of Constituents
B. Split into two half reactions
C. only oxidation part is written
D. Only Reducing part is written
66. The elements having partially filled d and f orbitals are called as______?
A. Transition elements
B. d-Block elements
C. f-block elements
D. All of these
67 Nucleophilic addition reactions of carbonyl compounds can be catalyzed by____?
A. Acid
B. Base
C. Water
D. Both acid and base
68. The efficiency of a chemical reactions can be checked by calculating itâ€™s _yields
A. percentage
B. actual
C. theoretical
D. all of these
69. Wholar prepare urea from______?
A. Ammonium cyanate
B. Ammonium acetate
C. Ammonium urease
D. Ammonium Carbonate
CHEMISTRY >> Gases
70. when P and T are kept constant, V = R nT/P this is called
A. Boyle's law
B. Charles's law
C. Avogadro's law
D. Pascal's law
71. Fruity smell of organic compounds is because of _______?
A. Alcohols
B. Carboxylic acid
C. Ester
D. Acidhalids
72. In order to get absolute alcohol following is added to absorb moisture
A. MgO
B. CaO
C. Co2
D. Cl2
73. Alkanes mostly give______?
A. Addition reactions
B. Elimination reactions
C. Reduction reactions
D. Substitution reactions
74. Wave packet or quantum is often called photon in case of __________
A. energy
B. brightness
C. light
D. darkness
75. Which of the following shows isomerism?
A. Methane
B. Ethane
C. Propane
D. Butane
76. The energy of photons related to
A. frequency
B. wave length
C. wave number
D. all of these
77. Which one of the following pairs shown the diagonal relationship in the periodic table?
A. Sodium and Lithium
B. Lithium and magnesium
C. Lithium and beryllium
D. Boron and Beryllium
CHEMISTRY >> Gases
78. The magnetic fields create low energy plasma which further create molecules in a______ state
A. stable
B. metastable
C. parastable
D. prestable
79. The volume at S.T.P occupied by .8 g of N2
A. 2.24 dm3
B. 6.44 dm3
C. 1.12 dm3
D. 112 dm3
CHEMISTRY >> Gases
80. The density of a gas X is 6 times the density of a gas Y. If the molecular mass of X is M then
what will be molecular mass of Y:
A. M/6
B. 2M
C. 6M
D. 6/M
81. In Metal Hydrides the Oxidation number of Hydrogen is:
A. 1
B. –1
C. zero
D. 2
82. Arrangement of metals on the basis of their electrode potentials on standard hydrogen scale is
called:
A. Reactivity Series
B. Potential Difference
C. Activated Potential
D. Electrochemical Series
83. Which of the following isomerism is present in CH₃CH₂OH and CH₃OCH₃ ?
A. Metamerism
B. Chain isomerism
C. Tautomerism
84. Calcium carbide on reaction with water gives?
A. Methane
B. Ethane
C. propane
D. Acetylene
85. During the nomenclature of Alkyl halides, halogens are named as______?
A. Substituents
B. Parent name
C. Ligand
D. Longest chain
CHEMISTRY >> Solids
86. Metals look shiny as light falls on metal surface collide with mobile electrons and make them
______ these electron gives light when _________.
A. neutral. Excited
B. excited, de-excited
C. de-excited, excited
D. none of these
87. With the passage of time rate of reaction always
A. Increases
B. Remains constant
C. Decreases
D. Increases exponentially
88. The rate expression have a negative sign for:
A. Disappearance of Reactants
B. Formation of Products
C. a given time
D. All of these
89. The hydrolysis of urea is catalyzed by:
A. Amylase
B. Urease
C. Pectin
D. None
90. There is one lone pair present in H₃O⁺, it cannot act as_____?
A. Electrophile
B. Lewis acid
C. Nucleophile
D. Strong acid
91. For a reaction that can takes place through more than one ways, the enthalpy of that reaction
is______?
A. Same for all the routes of that reaction
B. Different for different routes of that reaction
C. Depends up on the reactants present in each route
D. None of these
92. If the difference of electro negativity is 1.7 or more than that, the bond formed is said to be
A. Ionic bond
B. covalent bond
C. metallic bond
D. chemical bond
93. Which of the following is the correct IUPAC name of acetone?
A. Propanone
B. 3-Propanone
C. 2-Butanone
D. 2-Propanone
94. In diaphragm cell, hydrogen is discharged by the reduction of:
A. Water
B. HCI
C. Na+
D. NaCl
95. According to modern theory of chemical bonding, atoms forms bond to ____
A. increase energy
B. decrease energy
C. higher energy
D. none of these
96. Which product is obtained by Distillation of calcium acetate ?
A. Acetone
B. Acetaldehyde
C. Formaldehyde
D Carboxylic acid
97. The number of atoms present in a molecule determines its
A. shape
B. size
C. molecularity
D. atomicity
CHEMISTRY >> Solids
98. The nature of Binding Force in Ionic Crystals is
A. Magnetic
B. Repulsive
C. Electrostatic
D. Weak
99. The forces which are most prominent in mixture of Non-polar molecule are ______?
B. Debye forces
C. H-bonding
D. London dispersion forces
100. By Increasing temperature in Ammonia synthesis the value of Kc:
A. decreases
B. increases
C. remain constant
D. None of these
101. Which of the following compound is formed when NACl reacts with CH₃MgBr?
A. CH₃CN
B. CH₃Cl
C. CH₃CH₂NH₂
D. None of these
CHEMISTRY >> Gases
102. The critical volume of O₂ is ___cm3/ mol.
A. 95.56g/dm3
B. 64.51g/dm3
C. 74.42g/dm3
D. 99.9g/dm3
103. When C -O bond breaks in alcohol, the most reactive is
C. tertiary alcohol
D. methanol
104. When an electron jumps from n = 5 to n = 2 having wavenumber equal to 2.3 x16 m -1. In
which spectral series will it fall?
A. Layman
B. Balmer
C. visible
D. infrared
105. Slope of the curve can be determined by:
A. Area under the curve
B. calculating length of curve
C. Drawing a tangent to the curve
D. All of these
106. At which of the following temperature standard enthalpies are measured?
A. 373K
B. 298K
C. 350K
D. All of these
107. Fumaric acid is converted into______ in the presence of fumarase enzyme.
A. Oxalic acid
B. Phthalic acid
C. Maleic acid
D. Malonic acid
108. Half-life period for a first order reaction is independent of:
A. Conditions of temperature
B. Initial Concentration of the compound
C. Presence of Catalyst
D. All of these
109. Boiling point of hydrides of 4th period is larger than _______?
A. 5th period
B. 3rd period
C. 6th period
D. 7th period
110. Which of the following product is formed when Alkyl halide reaction with KOH in the presence
of alcohol?
A. Alkane
B. Alcohol
C. Halohydrin
D. Alkene
111. Ethyne molecule is formed when:
A. When two sp hybridized orbitals combine
B. When two sp2 hybridized orbitals combine
C. When two sp3 hybridized orbitals combine
D. When two sp2d hybridized orbitals combine
CHEMISTRY >> Solids
112. The lattice energy of KBr is ________KHz/ mol
A. -833
B. -665
C. -895
D. -728
57. Both ketones and aldehyde are present in_______?
A. Sugars
B. Menthone
C. Camphor
D. Formamint
58. Temperature of the surrounding falls during_______?
C. Exergonic reactions
D. None of these
59. Downs Cell is used for the electrolysis of:
A. Aqueous NaCl
B. Aqueous NaNO3
C. Fused NaCl
D. Fused NaNO3
60. The separation of components of liquid on the basis of their boiling points is called as?
D. Partial distillation
61. Compounds attracted by applied strong magnetic field are called:
A. Diamagnetic
B. Paramagnetic
C. Good conductor
D. Ferromagnetic
62. Amino acids in proteins are held together by:
A. Peptide bond
B. Phosphodiester linkage
C. H-bonding
D. Ether linkage
63. Formation of Hydrogen molecule according to VBT theory involves overlap of:
A. 1s orbital
B. 2s orbital
C. 2p orbital
D. 2px orbital
64. Empirical formula and molecular formula of covalent molecule is:
A. different
B. same
C. variable
D. equal
65. H bonding is not present in which of the following______?
A. DNA
B. Proteins
C. Carbohydrates
D. Lipids
66. The slope of the curve obtained by plotting concentration change with time is actually:
A. Reaction time
B. Reaction Speed
C. Rate of reaction
D. All of these
67. The wavelength of radiation that have been absorbed by an element appear as ______ lines
and background is _________ in an atomic absorption spectrum.
A. dark. bright
B. bright, dark
C. dark, light
D. bright, light
68. In IUPAC naming alcohols are named as______?
A. Alkanal
B. Alkyl alcohols
C. Alkanol
D. Alkenol
69. How many resonance structures of benzene are possible?
A. 2
B. 3
C. 6
D. 4
70. SN₁ reaction is a ________?
A. Multistep reaction
B. Two step reaction
C. Concerted reaction
D. 3 step reaction
71. How many d-block elements are present in the periodic table?
A. 40
B. 23
C. 37
D. 30
72. Which of the following give methanol upon hydrogenation/reduction?
A. HCHO
B. CH₃CHO
C. CH₃CN
D. CH₃CH₂CHO
73. In the formation of HF,________ donates the major of its electron among hydrogen atom or
fluorine atom.
A. H-atom
B. F-atom
C. both A & B
D. none of these
CHEMISTRY >> Gases
74. There are very strong attractive forces due to close packing in:
A. solids
B. liquids
C. gases
D. all of these
75. Actual yield is always less than theoretical yield due to:
A. operational losses
B. reaction reversibility
C. side reaction
D. all of these
76. Which of the following reaction takes place when acetone reacts with HCN ?
A. Electrophilic addition
B. Nucleophilic elimination
C. Nucleophilic addition
D. Electrophilic addition
77. Hemoglobin is example of which protein.
C. Genetic proteins
78. Liquid crystal is discovered by
A. Friedrich Reinitzer
B. William crooks
C. Bravis
D. J J Thomson
79. Bond Formation are associated with
A. Loss of Energy
B. Gain of Energy
C. No energy Change
D. Sharing Nucleus
80. Change in Pressure will only affect the substances which are in:
A. Liquid state
B. Solid State
C. Plasma state
D. Gaseous State
81. The order of reaction for which half-life is inversely proportional to the concentration of
reaction is:
A. Second Order
B. Zero Order
C. First Order
D. Third Order
82. The ionization energy of group ________shows abnormal trend.
A. 3A & 4A
B. 5A & 6A
C. 6A & 4A
D. 3A & 6A
83. A peptide having up to 10000 amino acids is called as_______?
A. Dipeptide
B. Protein
C. Polypeptide
D. Peptide
84. Planck's constant is defined as the _________ of energy and frequency of a photon.
A. product
B. sum
C. ratio
D. none of these
85. What will be the value of work done at constant pressure in a pressure-volume system?
A. w=PV
B. w=ΔPV
C. w=PΔV
D. w=P + ΔV
CHEMISTRY >> Solids
86. Molecular Solids are held together by weak intermolecular forces called.
A. Van der Waal forces
B. Dipole Dipole Interaction
C. Both A and B
D. Electrostatic Forces
CHEMISTRY >> Solids
87. Which one the characteristic of Ionic solids ?
A. high vapor pressure
B. good conductivity
C. low melting point
D. solubility in polar solvents
88. In Which of the following reaction rate of reaction is not affected by increasing concentration
of nucleophile?
A. SN₂
B. E₂
C. SN₁
D. None of these
CHEMISTRY >> Gases
89. What will be density of CH4 at C and 1 atm?
A. 7138 g/cm3
B. 0.7138g/dm3
C. 0.7138g/cm3
D. 71.38g/dm3
90. Which of the following reaction is used to produce symmetrical alkanes from alkyl halides?
A. Wittig reaction
B. Kolbe's electrolysis
C. Reduction of alkyl halide
D. Wurtz reaction
91. Which element is required for making Chlorophyll in Leaf?
A. Si
B. Ba
C. Mg
D. Ca
92. Which one of the following is the formula of stearic acid?
A. C₁₇H₃₃COOH
B. C₁₇H₃₅COOH
C. C₇H₃COOH
D. C₁₅H₃₀COOH
93. Who proved that no Vital Force theory is involved I synthesis of organic compounds?
A. Lewis
B. Wohler
C. Greek Philosophers
D. Berzillus
CHEMISTRY >> Solids
94. Crystalline Solids can be converted into amorphous solids by:
A. Sublimation
B. Evaporation
C. abrupt cooling
D. Hammering
95. Bisulfite addition product when heated with mineral acid yield?
A. Carboxylic acid
B. Alpha hydroxy acid
C. Starting material from which it is formed
D. Alpha beta unsaturated compound
96. Au³⁺ has _______configuration.
A. 5d⁶
B. 4d⁹
C. 5d⁷
D. 5d¹⁰
97. Denaturing of protein is ______ process.
A. Reversible
B. Irreversible
C. Equilibrium
D. all of these
98. ∆Hᵣ֯ is the standard enthalpy change of which of the following process?
A. When 1 mol of compound formed from its elements
B. When 1 mole of substance is dissolved to make a solution
C. When 1 mole of Reactants are converted into products
D. When 1 mole of salt is formed
99. Which isomer of hydroxy benzene sulphonic acid is formed in greater ratio when phenol
reacts with sulphuric acid at 20 ℃?
A. Ortho
B. Para
C. Both ortho and para in equal ratio
D. ortho-para product
100. Metals are ________?
A. Reducing agents
B. Oxidizing agents
C. Both a and b
D. Dehydrating agents
101.In oxidation number method of Balancing the first step is to write.
A. Oxidation number on Reactants
B. Oxidation number on products
C. Oxidation number for both reactants & Products
D. None of these
102.Which of the following compound shows more H-Bonding?
A. CH₃OH
B. CH₃CH₂OH
C. C₆H₅OH
D. C₆H₁₁OH
CHEMISTRY >> Gases
103.Linde's Method is based on:
A. joule-Thomson effect
B. Hess effect
C. graham's effect
D. none of these
104.When acetylene react with ammoniacal solution cuprous chloride which color of acetylide is
formed ?
A. White
B. Red
C. Brown
D. Pink
105.How many electrons can occupy in 7th energy level of an atom. Calculate by using 2n2 formula:
A. 24
B. 5
C. 72
D. 98
106.Dipole forces has direct relation with the _______?
A. Chemical properties of a substance
B. Kinetic properties of substance
C. Thermodynamic properties of substance
D. Nature of substance
107.Those elements in which d or f orbitals are in the process of completion are called
B. Typical transition elements
C. Outer transition elements
D. Inner transition elements
108.If Kp and Kc have same values Δn will be:
A. Maximum
B. Minimum
C. Zero
D. Negligible
109.Potential Energy of a system comes from the:
A. Van der Waal forces
B. Bonds between molecules
C. Ionic Bonds
D. All of these
CHEMISTRY >> Gases
110.Which gases are used as mixture for breathing in sea?
A. Oxygen and nitrogen
B. Carbon dioxide and oxygen
C. Helium and oxygen
D. Helium and hydrogen
CHEMISTRY >> Solids
111.Percentage of free space in a body centered cubic unit cell is:
A. .32
B. .34
C. .28
D. .3
112.The electronegativity difference of the elements can be related to the following property of bonds:
A. dipole moment
B. bond energies
C. both A & B
D. none of these

1. The presence of several fine lines in line spectrum shows the presence of:
A. shells
B. energy levels
C. sub shells
D. all of these
2. Which of the following is the function of formalin?
A. Antiseptic
B. Disinfectant
C. Germicide
D. All of these
3. Alcohol having 5% water is called as________?
A. Absolute alcohol
B. Methylated alcohol
C. Rectified spirit
D. Pure spirit
4. The presence of double bond in a compound shows that the compound has______?
A. Saturation
B. All single bonds
C. Unsaturation
D. Substitution
5. Molecules that have high molecular mass and consist of large number of atoms are called as____?
A. Micro molecules
B. Macromolecules
C. Polypeptides
D. Carbohydrates
6. Specific Rate constant changes its value with:
A. Time Constant
7. Pure metal:
A. Corrode slowly
B. Does not corrode easily
C. Corrode rapidly
D. None of these
CHEMISTRY >> Solids
8. Energy released when one mole of an ionic crystal is formed is
A. Activation energy
B. Potential energy
C. Energy of formation
D. Lattice Energy
9. The concept of _______of gases helps to relate solids and liquids in a quantitative manner.
A. density
B. molar volume
C. pressure
D. temperature
10. Hess law is known as:
A. Law of heat summation
B. Law of constant heat capacity
C. Law of mass action
D. Law of conservation of mass
11. In which phase SN₂ reactions are favored?
A. Solid
B. Liquid
C. Gas
D. All of these
12. Which one of the following is formula of iodoform ?
A. CH₃I
B. CHI₃
C. CH₂I₂
D. CI₄
13. In Industry Caustic Soda is formed by electrolysis of:
A. Dilute NaCl Solution
B. Fused NaCl
C. Concentrated NaCl Solution
D. NaCl Solution
14. According to 'n+l' rule ,the value of 6f is 9 while 7s orbital has '7' value, it shows:
A. 6f filled first
B. 7s placed first
C. 7s placed later
D. 6f placed later
15. How much amount of methane does Natural gas contains?
A. 0.8
B. 0.85
C. 0.7
D. 0.98
16. In which of the following reaction steps free radical is formed?
A. Initiation, termination
B. Termination, propagation
C. Only initiation
D. Initiation, propagation
CHEMISTRY >> Gases
17. If a gas is warmed by 1 C, it will _____by 1/273 of its original volume.
A. contracts
B. expands
C. shrink
D. squeezed
18. At the start of a reaction, Concentration of reactants decreases.
A. slowly
B. At constant rate
C. rapidly
D. exponentially
19. Both Hydrogen and Halogens form:
A. Ionic compounds mostly
B. Unipositive ion
C. Diatomic molecule
D. Stable bond with water
20. Heat supplied at constant pressure equals to:
A. Activation Energy
B. Internal energy change
C. Entropy
D. Enthalpy
21. Why phenol is more acidic than Alcohol?
A. Due to presence of resonance in phenol
B. Due to absence of resonance of in alcohol
C. Both a and b
D. Because in phenol H is attach to O
22. The melting points and boiling points up to the middle of 3d- series:
A. Increases
B. Decreases
C. Remain same
D. No regular trend
CHEMITRY >> S and P Block elements
23. Graphite has a structural similarity with:
A. B2H6
B. B4C
C. B
D. BN
24. The reaction in which benzene is reacted with alkyl or acyl halide in the presence of AlCl₃ is called
as______?
A. Aldol condensation
B. Wolf kishner reaction
C. Wittig reaction
D. Friedel and craft reaction
25. Proteoses enzyme & peptones belong to which type of protein?
A. Simple protein
B. Derived proteins
C. Conjugated proteins
D. All of these
26. In energy terms, the elements at high energy state are:
A. electronegative elements
B. electropositive elements
C. neutral elements
D. charged elements.
27. I⁻ is an example of________?
A. Electrophile
B. Nucleophile
C. Leaving group
D. Both nucleophile and leaving group
28. Which of the following reaction is used to locate the position of double bond in the compound?
A. Dehydration
B. Ozonolysis
C. MarkovniKov's addition
D. Oxidation with KMnO4
CHEMISTRY >> Solids
29. The shape of KNO3 above 128 C is:
A. cubic
B. orthorhombic
C. rhombohedral
D. tetragonal
30. X-ray work in 2th century shows that diameter of the atoms are of the order:
A. .1nm
B. .2nm
C. .3nm
D. .4nm
31. Which of the following alkyl halide give SN₁ reactions?
A. 1-chloropropane
B. 2-chloropropane
C. n-butyl chloride
D. 2-methyl,2-chloropropane
32. OH-is added when reaction is in:
A. Acidic Medium
B. Basic Medium
C. Neutral solution
D. All of these
33. Which one is an index to metallic character?
A. ionization energy
B. electron affinity
C. atomic radius
D. electronegativity
CHEMISTRY >> Solids
34. Cleavage Plane appears when a crystal is:
A. Melted
B. Broken
C. Heated
D. Cooled
35. Which of the following is used as disinfectant?
A. Phenylhydrazone
B. Phenol
C. Acetic acid
D. Vinegar
36. The mechanism of reaction can be understood by:
A. Experimental details
B. Balanced chemical equation
C. Molar Ratio
D. All of these
37. Sc is mostly exist in which of the following oxidation state?
A. 2
B. 1
C. 3
D. 0
CHEMISTRY >> Solids
38. It is amorphous:
A. wax
B. plastic
C. glass
D. all of these
39. In a reaction having both alkyl halide and base, the base will attack on______?
A. Electrophilic carbon
B. Nucleophilic carbon
C. beta-hydrogen
D. None of these
40. The solution of phenol in water has a pH of about?
A. 4-5
B. 3-5
C. 2-4
D. 5-6
41. Conversion of water into steam is a:
B. Exothermic Reaction
C. Reversible Reaction
D. Combustion Reaction
42. Work done by the system is always:
A. Positive
B. Zero
C. Negative
D. Equals to Unity
43. Which one of the following in correct molecular mass of protein ?
A. 9000
B. Less than 10000
C. 10000
D. More than 10000
44. On Hydrolysis with dilute HCl, ethanenitrile gives acetic acid through:
A. Formamide
B. Acetamide
C. Benzoic acid
D. Acetaldehyde
45. octane number of 2,2,4-trimethylpentane is:
A. 100
B. 95
C. 9
D. 89
46. Which catalyst is used when ethanol react with ammonia to produce ethyl amine?
A. ZnCl₂
B. C₆H₅N
C. Al₂O₃
D. ThO₂
47. Which of the following is succinic acid?
A. Ethanoic acid
B. Hexanedioic acid
C. Butanedioic acid
D. Propanoic acid
48. After the hydrolysis of ester the change in concentration of acid at different intervals is calculated by:
A. Titration with KMnO4
B. Titration With Standard Alkali
C. Distillation
D. Evaporation of mixture
49. For balancing oxygen and hydrogen atoms in acids or neutral solutions
A. Water can be added
B. H+ ions can be added
C. Both A and B
D. OH- ions can be added
50. Which of the following is formed during SN₁ reactions?
A. Secondary carbocation
B. Primary carbocation
C. Tertiary carbocation
D. Methyl carbocation
51. The bond b/w the two atoms is non polar ,if the E.N difference is:
A. 1.7
B. zero
C. 1
D. 2
52. What is the correct equation to find Heat of neutralization using glass calorimeter?
A. q=m s ΔT
B. E=q m ΔT
C. E=m s ΔT
D. q=m c ΔT
CHEMISTRY >> Gases
53. If a graph is plotted between pressure on x- axis and volume on y- axis for Boyle's law verification, the
curve obtained is called:
A. pseudotherm
B. isotherm
C. biotherm
D. all of these
54. A compound has an empirical (simple) formula, C2H2O. If the experimental molecular weight is found to
be in the range 16 -17 , the molecular formula of this compound is:
(Atomic wt.: C = 12. 1, H = 1. 8, O = 16. )
A C3H6O3
B C4H4O2
C C8H8O4
D C6H6O3
CHEMISTRY >> Solids
55. The most symmetrical crystal system:
A. triclinic
B. tetragonal
C. cubic
D. rhombohedral
56. Location of transition elements is in between?
A. S and p block
B. d and f block
C. s and f block
D. None
1. Joule is the unit of ?
A. Heat
B. Energy
C. Work
D. All of these
2. Nitrogen N2 molecule has 3 unpaired electron on each atom therefore it shows three bond that are
A. 2 sigma & 1 pi bond
B. 1 sigma & 2 pi bond
C. 3 sigma
D. 3 pi bond
3. Which type of organic compounds are present in natural gas?
A. High molecular mass
B. Low molecular mass
C. Low boiling point
D. Both b and c
4. According to Bohr, the orbits in which electrons revolve around the nucleus are
A. oval
B. elliptical
C. cylindrical
D. circular
CHEMISTRY >> Gases
5. The intermolecular forces are very weak in
A. solids
B. liquids
C. gases
D. all of these
6. Aldehydes can be oxidized by______?
A. K₂Cr₂O₇
B. HNO₃
C. Tollen's reagent
D. All of these
7. The alcohols having one hydroxyl group attached to the alkyl group are called as____?
A. Monohydric alcohols
B. Dihydric alcohols
C. Trihydric alcohols
D. Polyhydric alcohols
8. The forces present within a molecule are called as________?
A. Intermolecular forces
B. Van der Waal forces
C. Chemical bond
D. Weak forces
9. The number of neutrons in H2SO4 are
A. 5
B. 49
C. 48
D. 44
10. High molecular mass organic compounds, upon hydrolysis yield amino acids are called_______.
A. Carbohydrates
B. Lipids
C. Proteins
D. DNA
11. Why Cr shows 3d⁵4s¹ configuration instead of 3d⁴4s²?
A. Because it is transition element
B. Because it shows different oxidation states
C. Because of extra stability of half filled d⁵ system
D. Because it is typical transition element
12. Which of the following is a Unsaturated fatty acid?
A. Palmitic acid
B. Stearic acid
C. Oleic acid
D. Ethanoic acid
13. On heating egg albumin_____?
A. Solubilize
B. Decompose
C. Over cook
D. Coagulate
CHEMISTRY >> Gases
14. The molecules of solids possess kinetic energy
A. translational
B. vibrational
C. both A & B
D. none of these
15. Which of the following is used in silvering of mirror in industries _______?
A. Acetone
B. Propanol
C. Ethanal
D. Butanone
16. When ethyl alcohol is oxidized with potassium dichromate, which product is formed?
A. Acetic acid
B. Butanoic acid
C. Benzoic acid
D. No reaction takes place
17. When two atoms bonded to form a stable compound, the attractive forces will __repulsive forces and
the potential energy of the system will be ___-
A. recessive, higher
B. dominate, minimum
C. dominate,maximum
D. recessive, lower
18. A substance formed by reduction of phenol with Zn is
A. picric acid
B. benzene
C. cresol
D. carbolic acid
CHEMISTRY >> Solids
19. NaCl and CsF have same geometry because they have same
A. Ionization energy
B. Ionic radius ratio
C. electron affinity
D. bond length
20. Representing Reaction in Voltaic cell symbol used for salt bridge is
A. ∩
B. ⋮⋮
C. ≡
D. II
21. Tetraethyl lead added to fuel to________?
A. Decrease boiling point
B. Prevent heating
C. Prevent freezing of fuel
D. Prevent knocking
22. Disruption of the protein structure by heating, changing and by chemicals is called as______?
A. Coagulation
B. Dehydration
C. Denaturation
D. None of these
23. Lower boiling point of ether then water is due to the reason?
A. Ether has strong intermolecular forces
B. Water has weak H-bonding
C. Ether has weak intermolecular forces
D. Water has lower vapour pressure
24. If we are given with the mass of a substance ,we can calculate ________ of other substance with the
help of a balanced chemical equation.
A. mass
B. volume
C. moles
D. all of these
25. Which one of the following carbonate is water-insoluble?
A. Na2CO3
B. K2CO3
C. (NH4)2CO3
D. CaCO3
26. How phenol is produced from the Chlorobenzene ?
A. Using Kolb's method
B. Using Dow's method
C. Using Zn dust
D. All of these
CHEMISTRY >> Solids
27. Brittleness of Ionic solids is due to the fact that Ions arrange themselves in way to,
A. Attract each other
B. Compress
C. Repel
D. overlap each other
28. How many times a covalent bond is stronger than H-Bond?
A. 10
B. 12
C. 20
D. 2
29. Which of the following can form a chelate
A. Ammine
B. Oxalate
C. Carbonyl
D. Cyano
30. The rate of SN₁ reaction become doubled if______?
31. Aldehydes are obtained by the oxidation of which of the following ?
A. Secondary alcohols
B. Tertiary alcohols
C. Dihydric alcohol
D. Primary alcohols
CHEMISTRY >> Solids
32. Which one of them is known as super cooled liquids?
A. glass
B. diamond
C. silica
D. carbon
33. The increase in size of an anion is due to increase in repulsion of
A. electron-proton
B. electron-electron
C. electron-nucleus
D. proton-nucleus
34. Rate of reaction has
A. No units
B. unit of Moles/dm3
C. Unit as Moles / litre
D. Unit as Moles/dm3s-1
35. Which one of the following shows that iodoform test for a compound is positive?
A. Formation of carboxylate salt
B. Brick red precipitate formation
C. Yellow crystals
D. Formation of water
36. The rate of reaction between two specific time intervals is
A. Instantaneous rate
B. constant rate
C. Average Rate
D. All of these
37. During SN₁ mechanism, nucleophile can attack on the halogen carbon?
A. From opposite side of leaving group
B. From front of leaving group
C. From both sides
D. None of these
38. If uncertainty in momentum of electron is zero, the uncertainty in its position would be___?
A. Less than zero
B. more then zero
C. One
D. infinite
39. Sum of oxidation numbers of all the molecules in a neutral atom is
A. Unity
B. negative
C. 1
D. Zero
40. What is the name of this compound?
A. Ethyl chloride
B. Ethene chlorine
C. Chloro ethane
D. Vinyl chloride
CHEMITRY >> Introduction to Fundamental Concepts of Chemistry
41. Out of 28 natural isotopes, how many have even atomic number and mass number
A. 152
B. 153
C. 154
D. 155
41. Out of 28 natural isotopes, how many have even atomic number and mass number
A. 152
B. 153
C. 154
D. 155
42. In a carboxylic acid dimer, how many oxygens are present in the ring?
A. 4
B. 2
C. 3
D. 5
43. A sample so .7 mol of metal M reacts completely with excess of fluorine to form 45g of MF 2, how
many .moles of F are present in it.
A. 1.4 moles
B. 2.4 moles
C. 2 moles
D. 1.2 moles
44. Gypsum is applied to the soil as a source of
A. Ca and P
B. S and P
C. Ca and S
D. We could not apply
45. On industrial scale which catalyst is used for the preparation of methanol?
A. K₂Cr₂O₇
B. PdCl2
C. FeO,Mo2O3
D. CuCl2
46. Which of the following would not mix with each other easily ?
A. Water, ethanol
B. Water ,acetone
C. Water, pentane
D. Water ,chloroform
47. Reaction of ethylmagnesium bromide with acetone produces?
A. Primary alcohol
C. Tertiary alcohol
D. Methyl alcohol
48. The value of heat of neutralization of strong acid with a strong base is always_______?
A. Constant
B. Variable
C. Depends on the strength of acid
D. Depends on the strength of base
CHEMISTRY >> Solids
49. All the three axes and three angles are of unequal length and none of the angle is 9 O
A. cubic system
B. triclinic system
C. tetragonal system
D. monoclinic system
Q50 Which of the following is formed during SN₁ reactions?
51. The total number of transition elements are?
A. 48
B. 32
C. 58
D. 28
52. Different type of hybridization takes place depending upon _____of orbital's participating in
hybridization
A. number
B. nature
C. structure
D. both A & B
53. In Down Cell anode is made up of
A. Graphite
B. Copper
C. Iron
D. Silver
54. Tetra ethyl addition to petrol is example of:
A. Positive catalysis
B. Negative catalysis
C. Both a & b
D. None
55. line spectrum of sodium contains ____ colored lines separated by a definite distance
A. one yellow
B. two yellow
C. two brown
D. two golden
56. Conductivity of a solution changes with change in
A. Reactant Ions Concentration
B. Temperature of mixture
C. Adding an Impurity
D By catalyst
69. The change in concentration of reactants or products per unit time is
A. rate constant
B. reaction speed
D. All of these
70. Which enzyme causes the hydrolysis of fats ?
A. Urease
B. Lipase
C. Maltase
D. Protease
71. Which of the following reaction is concerted(single step) ?
A. SN1,E1
B. SN2,E1
C. SN2,E2
D. None of these
A. Class
B. Group
D. None of these
73. During catalytic reduction of carbonyl compounds, hydrogen adds across?
A. C=C
B. C-H
C. C=O
D. All of these
74. The region where probability of finding the electron is maximum is called as
A. Nucleus
B. Atom
C. Orbital
D. Nodal plane
75. All elements get their stabilization to attain nearest ____configuration
A. alkali metals
B. noble metals
C. alkaloids
D. Noble gases
76. Only those substances are written in Ion Electron Method
A. which are oxidizing
B. which are reducing
C. which are not taking part in reaction
D. Which will take part in reaction
77. If energy of reactants is less than that of products then ___________ during the reaction?
A. Heat is gained
B. Heat is lost
C. Heat is absorbed
D. No heat gain or lose takes place
78. The biochemical process used in the synthesis of alcohol in the presence of yeast is called
as_______?
A. Respiration
B. Photosynthesis
C. Fermentation
D. Aerobic respiration
CHEMISTRY >> Gases
79. In Boyle's law, the relationship between pressure and volume is
A. directly proportional
B. inversely proportional
C. constant
D. none of these
80. When light is exposed to transition element then electrons jump from lower orbital's to higher orbitals in:
A. Orbitals of f-subshell
B. Orbital's of d-sub shell
C. Orbitals of p-subshell
D. Both A & B
81. When CH₃CH₂MgBr reacts with CO₂ which of the following product is formed?
A. CH₃CH₂CH₂CH₂OH
B. CH₃CH₂CH₂OH
C. CH₃CH₂COOH
D. CH₃CH₂CH₂Br
82. The geometrical isomers in which similar groups on double bond carbon atoms are present on
opposite sides are called as___?
A. Trans isomers
B. Alkanes
C. Cis isomer
D. Positional isomers
83. It is very _--to remove electron from a positively charged ion than a neutral atom due to increase in
nuclear charge
A. easy
B. difficult
C. moderate
D. none of these
CHEMITRY >> Introduction to Fundamental Concepts of Chemistry
84. Molecular ions are produced by passing high energy electron beam or X-rays beam through:
A. atoms
B. molecules
C. gas
D. solid
85. The ionic radii appeared to be a/an property
A. associative
B. multiplicative
C. additive
D. all of these
86. In industries, methanol is prepared from?
A. Marsh gas
B. Carbon dioxide and water
C. Water gas
D. Methane + H₂
87. Which of the following ion is stable ?
A. Ethoxide ion
B. Tertiary Alkoxide ion
C. Secondary anion
D. Phenoxide ion
88. Hemoglobin is example of which protein.
C. Genetic proteins
89. In a homologous series, adjacent members differ by a ______unit?
A. CH₃
B. CH₂
C. CH
D. CH₄
90. In diaphragm cell level of brine in the anode compartment is kept slightly higher which prevents
A. Hydroxide ions to reach the anode
B. Chlorine gas to mix
C. Cathode to decay
D. All of the above
91. Which of the following has one acidic hydrogen in it?
A. Acetylene
B. 2-propene
C. 2-pentyne
D. 1-pentyne
92. Rate of reaction increases with increase by increasing temperature because
A. The concentration of the reaction increases
B. The activation energy for reaction increases
C. Collision frequency increases
D. All of these
93. Glucose is converted into ethanol by the ______ enzyme present in yeast.
A. Invertase
B. Urease
C. Glycolysis
D. Zymase
94. Decrease in Oxidation number is
A. Oxidation
B. Reduction
C. Both A and B
D. None of these
95. How many organic compounds are known_____?
A. 850000
B. Over 6 million
C. 6 million
D. 5 million
96. A system is the __________ part of universe ?
A. Real
B. Unreal
C. Imaginary
D. Both real or imaginary
97. Greater heat of vapourization of water is due to the presence of which forces?
A. H-bonding
B. Dipole Dipole forces
C. Polar covalent bond
D. All of these
98. Which type of forces are present between acetone and chloroform?
A. H-bonding
B. Dipole-Dipole forces
C. London dispersion forces
D. Debye forces
99. Which molar heat has higher ΔH value?
A. Heat of fusion
B. Heat of vapourization
C. Heat of sublimation
D. Heat of evaporation
CHEMISTRY >> Gases
100.Which one is for evaporation
A. surface phenomena
B. cause cooling
C. exothermic
D. continuous
101.Half-life can be found out for a reaction of
A. first order
B. Second Order
C. Any Order
D. Zero Order
102.Sodium is not observed in +2 oxidation state because of its
A. high first ionization potential
B. high second ionization potential
C. high ionic radius
D. high electronegativity
103.Which one of the following benzene molecule have?
A. Two double bonds
B. Delocalized pi-electron charge
C. Three double bonds
D. One sigma bond
CHEMISTRY >> Solids
104.The energy is __when oppositely charged ions brought close to each other
A. released
B. absorbed
C. remain same
D. constant
105.Reaction of Sodium with water is an example of
A. Reversible reaction
B. Endothermic
C. Irreversible
D. Slow
106.How many electrons can an atom accommodate in L-shell
A. 2
B. 18
C. 8
D. 32
CHEMISTRY >> Solids
107.Glass is an example of
A. ionic solid
B. covalent solid
C. pseudo solid
D. semisolid
108.How many classes of enzymes are there according to International union of Biochemistry ?
A. Four
B. Six
C. Five
D. Two
109.What is the range of Azimuthal Quantum number(l)?
A. to n
B. to s
C. to n-1
D. to s-1
110.Acetaldehyde in the presence of Con.H₂SO₄ undergoes _______?
A. Dehydration
B. Polymerization
C. Condensation
D. Oxidation reaction
CHEMISTRY >> Gases
111.Which unit of pressure is commonly used by meteorologist
A. atm
B. pascal
C. mm of Hg
D. millibar
CHEMITRY >> Atomic Structure
112.Which character of p-orbital determines the geometry of molecules
A. planar
B. axial
C. non directional
D. directional
113.Activator of carbonic anhydrase enzyme is_____.
A. Mn²⁺
B. Mg²⁺
C. Zn²⁺
D. None of these
114.The value of heat of neutralization of strong acid with a strong base is always_______?
A. Constant
B. Variable
115.The oxidation number of Nickel in [Ni(CO)4] is
A. 2
B. 8
C. 6
D. 4
116.The ionic radius of an ion is the radius of the ion while considering it to be _in shape
A. oval
B. round
C. rectangular
D. spherical
117.Higher order reactions has half-life
D. None of these
118. Which color of precipitates are formed when carbonyl compounds react with 1,2
dinitrophenylhydrazine?
A. Yellow or red
B. Orange or blue
C. Green or red
D. Yellow or orange
119.The catalyst in the formation of ester from alcohol and a weak acid is:
A. A base
B. Palladium
C. Nickel
D. A mineral Acid
120.In Down Cells Cathode is made up of
A. Graphite
B. Copper
C. Iron
D. Inert material
121.Depending upon the nature of ordering ,liquid crystals are divided into types
A. more than 1
B. two
C. three
D. four
122.Which of the following flavour is due to Amyl acetate ?
A. Jasmine
B. Pineapple
C. Banana
D. Orange
123.Pentene has how many isomers?
A. 2
B. 1
C. 5
D. 3
Q 124 A sample so .7 mol of metal M reacts completely with excess of fluorine to form 45 g of MF2 ,how
many moles of F are present in it.
A. 1.4 moles
B. 2.4 moles
C. 2 moles
D. 1.2 moles
57. The unit used to express the relative atomic mass is called
A. gram unit
C. atomic mass
D. atomic mass unit
58. Free radial reactions takes place in the presence of______?
A. Heat
B. Sun light
C. Catalyst
D. Oxygen
59 If both alkyl groups attached to carbonyl in ketone are same then it is called as_____?
A. Mixed
B. Unsymmetrical
C. Symmetrical
D. None of these
60. Quantum numbers specify the _of electron
A. shape
B. energy
C. position
D. all of these
61. According to VBT, the essential condition for chemical bonding is that the orbitals of atoms
participating in bond formation must
A. added
B. multiply
C. overlap
D. divide
62. Specific Rate constant is also known as
A. Time Constant
B. relative rate constant
C. Instantaneous rate constant
D. velocity constant
63. Butyric acid is derived from the word butyrum which means_______?
A. Milk
B. Butter
C. Cheese
D. None of these
64. The temperature at which vapor pressure of a liquid becomes equal to external pressure or
atmospheric pressure is called as ?
A. Melting point
B. Boiling point
C. Freezing point
D. Sublimation point
65. The elements having partially filled d and f orbitals are called as______?
B. d-Block elements
C. f-block elements
D. All of these
A. Class
B. Group
D. None of these
67. Ionization energy depends on which of the following factors?
A. Size of atoms
B. Nuclear Charge
C. Number of shells
D. All of these
A. Amino acids
B. Starch
C. Glycogen
D. Lipids
69. Which of the following is more soluble in water_______?
A. Ethanol
B. Phenol
C. Hexanol
D. Dimethyl ether
70. The simplest member of organic compounds is?
A. Methanol
B. Methane
C. Formaldehyde
D. Formic acid
71. Reaction intermediate
A. Cannot be Separated from reaction mixture
B. Contain normal bonds
C. can be isolated from reaction mixture
D. Both B and C
72. Acetic acid is also named as______?
A. Propanoic acid
B. Butanoic acid
C. Ethanoic acid
D. Methanoic acid
CHEMISTRY >> Gases
73. The strength of London forces depends on size of
A. electrons
B. electronic cloud
C. lone pair on an atom
D. poles of atoms
74. Which of the following are weakest intermolecular forces ?
B. Debye forces
D. H-bonding
75. In a galvanic cell ,ZincSulphate left beaker acquires a
A. A negative charge
B. A net positive charge
C. Neutral
D. None of these
76. Which of the following conditions must be possessed by a compound to have geometrical
isomerism?
A. Double bond
B. Different groups attach to same carbon of double bond and a double bond
C. Terminal double bond
D. Same groups attach to carbon atom of double bond
77. Which of the following is an example of Tricarboxylicacids ?
A. Maleic acid
B. Citric acid
C. Butyric acid
D. None of these
78. Which of the following remains the same in a period
A. nuclear charge
B. number of electrons
C. shielding effect
D. ionization energy
79. In IUPAC nomenclature , ketones are named as_____?
A. Alkanol
B. Alkanal
C. Alkanone
D. Alkyl halides
80. According to coulomb's law ,the electrostatic forces of attraction between electron and nucleus are
_____ to its square of radius
C. equal
D. none of these
CHEMISTRY >> Solids
81. Ancient glass becomes milky due to
A. refraction
B. crystallization
C. volatilization
D. dispersion
82. On which of the following factors rate of enzyme action is directly proportional ?
A. Concentration of products
B. Time
C. Concentration of substrate
D. Concentration of solvent
CHEMISTRY >> Gases
84. vapor pressure is measured by calculating difference in liquid pressure and
A. mercury pressure
B. glass pressure
C. atmospheric pressure
D. container pressure
85. Phenol is changed into cyclohexanol by the following method
A. Hydrogenation
B. Reaction with formaldehyde
C. Nitration
D. Halogenation
86. Boiling needs ________?
A. Supply of heat in the start
B. Supply of heat constantly
C. Supply of heat at the end
D. Supply of heat variably
CHEMISTRY >> Gases
87. For Boyle's law verification, If a graph is plotted between 1/V on x-axis and P on y-axis, _______
graph will be obtained
A. curved
B. straight line
C. zigzag
D. none of these
88. Oxidation Number can be
A. Positive
B. zero
C. Negative
D. All of these
89. Which of the these reactions occur at a moderate rate
A. Rusting Of Iron
B. Fermentation of sugar
C. Hydrolysis of Ester
D. Chemical weathering of stone work by acid.
90. All the halogens are ______diatomic molecules
A. polar
B. non polar
C. reactive
D. non reactive
91. Aldoleconsist of which functional group?
A. Aldehyde
B. Alcohol
C. Both a and b
D. Ketone
92. The compound or complex ion which has a ring in its structure
A. Polydentate ligand
B. Chelate
C. Monodentate ligand
D. Hydrate
CHEMISTRY >> Solids
93. Anisotropy is a property of crystal based on its
A. Chemical Properties
B. Lattice Structure
C. Physical Properties
D. Density
94. According to Le chatelier's Principle Exothermic reactions are favored by
A. Increase in Pressure
B. Increase in Volume
C. decrease in Temperature
D. All of these
95. Kinetic Energy is the sum of
A. Rotational & Vibrational
B. Translation & Rotational
C. Rotational, Vibrational and Translation
D. All of these
96. Knowledge obtain through thermodynamics is used to Explain which of the following property?
A. Boiling point
B. Chemical bonding
C. Quantum study
D. Physical properties
97. When an electron changes its orbit from outer to inner level, energy is
A. no change
B. absorbed
C. released
D. remains constant
98. Addition of 2% gypsum in cement
A. Triggers hydration
B. Triggers hydrolysis
C. Prevents rapid hardening
D. All of the above
99. The geometry of butane is:
A. octahedral
B. Tetrahedral
C. Trigonal planar
D. Square planar
100.Non-typical transition elements belong to?
A. 2B
B. 3B
C. 221B
D. 1B
101.The value of heat of neutralization of strong acid with a strong base is always_______?
A. Constant
B. Variable
102. When two carboxylic acids are strongly heated in the presence of P₂O₅, which product is formed?
A. Acid halides
B. Dimer
C. Acid anhydride
D. None of these
103.During base catalyzed reactions, which property of nucleophile increases?
A. Basicity
B. Nucleophilicity
C. Electrophilicity
D. Both b and c
104.the crude petroleum is separated in fraction by
A. filtration
B. fractional distillation
C. steam distillation
D. fractional sublimation
CHEMISTRY >> Solids
105.The transition temperature of all allotropic forms of an element are always less than its
A. freezing point
B. melting point
C. boiling point
D. none of these
106.The alcohols which are resistant to oxidation reactions are
A. primary alcohols
C. tertiary alcohol
D. all of above
107. When Number of moles of reactants and products are same Equilibrium constant will have:
A. negative value
B. Large value
C. No units
D. Units
108. Which of the following product is formed when Alkyl halide reaction with KOH in the presence of
alcohol?
A. Alkane
B. Alcohol
C. Halohydrin
D. Alkene
109.Isoelectronic species have same
B. Ionic size
C. Reactivity
D. PH
110.For balancing oxygen and hydrogen atoms in acids or neutral solutions
C. Both A and B
111.The molecular geometry of SO2 is
A. annular
B. ring
C. angular
D. linear
112.The lobes of d-orbitals lie between the axis
A. first two
B. first three
C. in all axis
D. none of these
PMC (PAID TEST -22)
CHEMISTRY >> Gases
69. What is the S.I. unit of pressure?
A. Nm^-2
B. Nm^2
C. mm of Hg
D. atm
70. the transfer of electron from an atm of ______ I.E to other atom with ___E.A is called ionic bond by
Lewis:
A. high, low
B. low, low
C. low, high
D. high,high
71. Positive rays are produced when ________strike the molecules of a gas in a discharge tube
A. low speed neutrons
B. high speed neutrons
C. low speed electrons
D. high speed electrons
72. The second ionization potential of alkali metals are very high due to
A. Being s-block elements
B. Inert gas configurations
C. ns1 electronic configuration
D. Being metals
73. Free radial reactions takes place in the presence of______?
A. Heat
B. Sun light
C. Catalyst
D. Oxygen
CHEMISTRY >> Solids
74. Angles in a Unit Cell are denoted by
A. x,y,z
B. a,b,c
C. α, ϐ, ϒ
D. i,j,k
D. None of these
76. Which of the following element is not usually present in all proteins?
A. Carbon
B. Hydrogen
C. Nitrogen
D. Sulphur
77. Electrode Potential is developed when a metal is dipped into
A. An Acid
B. A base
C. In its own ions
D. Water
78. Rate of chemical reactions helps in designing industrial process which is
A. Completed instantaneously
B. Slow
C. Economical
D. None of these
79. Change in concentration per unit time is called
A. Equilibrium constant
B. rate constant
C. Rate of reaction
D. All of these
80. During benedict's solution test Brick red precipitates are formed due to formation of_____?
A. CuO
B. RCOONa
C. Cu₂O
D. Cu(OH)₂
81. At higher altitudes water boils at __________ Boiling point?
A. Higher
B. Lower
C. 100℃
D. 0℃
82. Density of ice is_________?
A. Higher than water
B. Lower than water
C. Similar to water
D. Higher the 1.59/cm 3
83. Aldehyde react with Ammonia and form________?
A. Amine
B. Imine
C. Nitrile
D. Hydrazones
84. What is the pH of human blood?
A. 7.45
B. 7.35
C. 7
D. 7.53
85. Aldehydes are converted into _______when undergoes Wolff Kishner reduction?
A. Alkenes
B. Alkanes
C. Alkynes
D. Alcohols
CHEMISTRY >> Solids
86. London force of interaction forms crystals
A. covalent crystals
B. ionic crystals
C. molecular crystals
D. metallic crystals
87. Which of the following does not react with bases?
A. Carboxylic acids
B. Phenol
C. Ethanol
D. HCl
88. Proteoses enzyme & peptones belong to which type of protein?
A. Simple protein
B. Derived proteins
D. All of these
89. The probability of finding an electron between s-orbital is zero. This place is called _____plane
A. nodal
B. antinodal
C. non nodal
D. erect
90. Fractions of Crude petroleum can be obtained by using______?
D. Distillation
91. The second ionization energy value of magnesium ion after the removal of second electron is
A. 135 KJ/mol
B. 145 KJ/mol
C. 155 KJ/mol
D. 773 KJ/mol
CHEMISTRY >> Gases
92. Liquids can be converted into solids by decreasing their
A. potential energy
B. kinetic energy
C. both A & B
D. none of these
93. Which forces makes the liquefaction of He possible?
A. London Dispersion forces
B. Debye forces
D. H-bonding
94. Optimum temperature range for the process of fermentation is
A. 2 - 3 'C
B. 25 - 35 'C
C. 27 - 33 'C
D. 4 - 45 'C
95. Which of the following process is an example of exothermic reaction?
A. Evaporation
B. Fusion
C. Sublimation
D. Respiration
96. Half Life α 1/a^(n-1) where n is
A. Number of reactant molecules
B. Number of moles of reactants
C. Number of moles of products
D. Order of Reactions
CHEMISTRY >> Gases
97. The gas is at 3 atm, what will be the pressure of a gas if it expands three times
A. 1 atm
B. 3atm
C. 6atm
D. 9atm
98. Left handed helix in proteins secondary structure is called as____?
A. Alpha helix
B. Beta helix
C. Spiral
D. Concentrate
99. When we move from left to right in transition elements, the decrease is ___due to intervening electrons.
A. large
B. very large
C. small
D. very small
100.Hydrocarbons are organic compounds with element __________
A. Hydrogen
B. Oxygen
C. Carbon
D. Both hydrogen and carbon
101.On Hydrolysis with dilute HCl, ethanenitrile gives acetic acid through;
A. Formamide
B. Acetamide
C. Benzoic acid
D. Acetaldehyde
102.Which of the following alcohol is most reactive in the reaction where O-H bon breaks?
A. Primary alcohol
B. Tertiary alcohol
C. Methyl alcohol
D. Secondary alcohol
CHEMISTRY >> Solids
103.Thermal conductivity of graphite is greater when mobile electron are moving _to its layers
A. perpendicular
B. right angle
C. parallel
D. all of these
CHEMISTRY >> Solids
104.Ice is an example of
A. Polar Molecular Solid
B. Non-Polar Molecular Solid
C. Ionic Solid
D. Covalent Solid
105.In the production of wrought iron Mg Si and P are removed in the form of
A. Oxides
B. Silicates
C. Slag
D. Carbonates
106.An enthalpy cycle used to calculate the lattice energy is
A. Hess Law
B. Carnot Cycle
C. Born haber Cycle
D. Haber's Process
CHEMISTRY >> Solids
107.The molecules of CO2 in dry ice form
B. ionic crystals
C. metallic crystals
D. molecular crystals
108.In case of oxidation of symmetrical ketone, which of the following products are formed ?
A. One Carboxylic acid
B. Mixture of different carboxylic acids
C. Same type of carboxylic acids
D. None of these
109.Which of the following are soluble in water?
A. Small alcohols
B. Small carboxylic acids
C. Acetone
D. Butane
110.Which of the following is formed during SN₁ reactions?
111.If n = 4 then what can be value of 'magnetic quantum number
A. 4,3,2,1
B. 3,2,1
C. infinity
D. none of these
112.NAD contains which vitamin as cofactor.
A. B1
B. B2
C. C
D. B3
113. The slope determined by drawing a right angled triangle drawn with tangent as hypotenuse will be
same:
D. All of these
114. Hydroxide Ions are combine to give
A. Alcohols
B. Aldehydes
C. Oxygen
D. Hydrogen
115. AB4 type with no lone pair shows geometry
A. Tetrahedral
B. trigonal
C. bent
D. linear
116. Which of the following is an example of Tertiary alcohols?
A. 2 methyl-3-ethylpentane
B. 3-ethyl-3-hexanol
C. 2-methyl-4-hexanol
D. isopropyl alcohol
117. Alkenes show geometrical isomerism due to:
A. Resonance
B. Asymmetry
C. Rotation around single bond
D. Restricted rotation around a double bond
118.Organic compounds are
A. Volatile
B. Non-volatile
C. fissible
D. None
119. The transition elements belongs to Group VIB are
A. Zn ,Cd, Hg
B. Fe, Ru, Os
C. Mn, Te, Re
D. Cr, Mo, W
120. The element caesium bears resemblance with
A. Ca
B. Cr
C. Both of the above
D. None of the above
CHEMISTRY >> Gases
121. What is the value of One calorie in joule ?
A. 4.98J
B. 7.98J
C. 4.18J
D. 8.21J
122. Oxidative cleavage of alkenes takes place in the presence of______?
A. Acidic cold KMnO₄
B. Warm Acidic KMnO₄
C. Warm alkaline KMnO₄
D. Alkaline cold KMnO₄
123. The catalyst in the formation of ester from alcohol and a weak acid is
A. A base
B. Palladium
C. Nickel
D. A mineral Acid
124. _________conducts nerve impulse in brain
A. serotonin
B. aspartame
C. ascorbic acid
D. hydrazine
69. dx/dt is rate of change of concentration with respect to
A. Temperature
B. Pressure
C. time
D. None of these
70. The smallest alkane that shows isomerism is_______?
A. Ethane
B. Butane
C. Pentane
D. Isopropane
A. Br⁺
B. CH₄
C. NH₃
D. H₂O
72. Nyholm& Gillespie explains the shapes of molecules for
A. transition elements
B. non transition elements
C. only alkali metals
D. Alkaline earth metals
73. Each half reaction in ion electron method is balanced by adding
A. Electrons on left hand side
B. Electron on ride hand side
C. Both left or right hand side
D. None of these
74. What is the hybridization of carbon in -COOH group?
A. sp²
B. Sp³
C. Sp
D. None of these
75. The presence of several fine lines in line spectrum shows the presence of
A. shells
B. energy levels
C. sub shells
D. all of these
CHEMISTRY >> Solids
76. Definite Shape of NaCl crystal is its
A. Characteristic
B. Symmetry
C. Habit
D. All of these
77. A piston in a cylinder is a part of
A. System
B. Surroundings
C. Boundary
D. None of These
78. Tetraethyl lead added to fuel to________?
A. Decrease boiling point
B. Prevent heating
C. Prevent freezing of fuel
D. Prevent knocking
79. In SN₂ reaction, which of the following specie is formed?
A. Transition state
B. Intermediate
C. Carbocation
D. Carbanion
80. Ethanol having 10% methanol in it is called as______?
A. Absolute alcohol
B. Methylated alcohol
C. Rectified spirit
D. Pure alcohol
81. Chemical reactions involve change in heat energy and the study is called
A. Electrochemistry
B. Biochemistry
C. Thermochemistry
D. Analytical Chemistry
CHEMISTRY >> Solids
82. Hydrogen bonding is involved in
A. cleansing action of soap
B. biological molecule
C. solubility
D. all of these
83. Production of Ammonia by Haber process is made economical by using
B. Catalyst
D. All of these
84. Electrolyte can be in
A. Plasma state
B. Solution or Fused state
C. Solid form
D. Gaseous State
85. The property of the system which does not depend upon the path followed by the system is called
as____?
A. State function
B. Path function
C. Dependent function
D. Independent function
86. Catalytic activity of enzyme is enhanced by:
A. Activator
B. Coenzyme
C. Co-factor
D. Both A and B
CHEMISTRY >> Solids
87. The atomic ratio of isomorphs of ZnSO4, and NiSO4 is
A. 2:1
B. 2:01:04
C. 1:01:04
D. 1:1
88. The unit of electron affinity is
A. J/mol
B. KJ/mol
C. KJ/atom
D. J/atom
89. Reduction of ketones produce______?
A. Aldehydes
B. Methanol
C. Primary alcohols
A. Water
B. Benzene
CHEMISTRY >> Gases
91. The existence of matter in our surrounding in different states is due to the difference of
A. repulsive force
B. interacting force
C. creative force
D. none of these
CHEMISTRY >> Solids
92. Ionic solids exist in three dimensional array which is called
A. unit cell
B. lattice
C. system
D. all of these
93. How much amount of methane does Natural gas contains?
A. 0.8
B. 0.85
C. 0.7
D. 0.98
95. Which ion will have a maximum value of the heat of hydration?
A. A1+3
B. Cs+
C. Ba+
D. Mg+2
96. Which of the following properties is not related to transition metals ______?
A. Complex formation
B. Color
C. Fixed valency
D. d-orbital
97. How many molecules of H₂adds in acetylene to form ethane?
A. 1
B. 3
C. 4
D. 2
98. The compounds which have -CN group are called as______?
A. Aldehydes
B. Imines
C. Amines
D. Nitriles
99. Rayon is______?
A. Acetyl chloride
B. Alkene
C. Alkyne
D. Acetic acid
CHEMISTRY >> Gases
100.If pressure and volume of a gas are variable while temperature remains constant, this belongs to
A. Charles's law
B. Boyle's law
C. Avogadro's law
D. Pascal's law
CHEMISTRY >> Gases
101.Plasma includes ions
A. protons
B. electrons
C. neutrons
D. all of these
102.Ethanol react which of the following reagent to form ethyl alcohol?
A. H₂SO₄/H₂O
B. NaOH
C. PCl₃
D. All of these
103.To remove an electron from an atom is always________?
A. Exothermic process
B. Endothermic Process
C. Neutral
D. Energy wasted
104.Instantaneous dipole is produced when __________?
A. Two polar molecules comes closer
B. Two non polar molecules comes closer
C. Polar and nonpolar molecule comes closer
D. All of these
105.The rate of reaction
A. Increases as the reaction proceeds
B. Decreases as the reaction proceeds
C. Remains unchanged
D. None of these
106.Phenol is also called as?
A. Carbonic acid
B. Carbolic acid
C. Acetic acid
D. Hydroxy acid
107.If temperature of reaction medium increases above optimum temperature then_____?
A. It increases the enzyme activity
B. Stops the reaction
C. Decreases the enzyme activity
D. Both b and c
108.Alkynes are soluble in_______?
A. Water
B. Benzene
C. Toluene
D. Both b and c
109.Which one of the following is formula of iodoform ?
A. CH₃I
B. CHI₃
C. CH₂I₂
D. CI₄
110. When NaCl dissolves in water, positive end of water surround the Cl- ion and Negative end of water
surrounds the Na+ end of salt, which forces are present between these ions and water molecule ?
A. Dipole Dipole forces
B. Ion dipole forces
C. H-bond
D. Debye force
111.The value of energy obtained for the electron in the nth orbit of hydrogen atom is in
A. Joules
B. Joules/atom
C. Kilojoules
D. Kilojoules/atom
112.For a sub shell l=2 and m = -2,-1, ,+1,+2,it implies that it has _________ space orientation
A. one
B. two
C. three
D. five
113.In balancing it is very important to identify the substance whose
A. Physical state is changed
B. oxidation number is changed
C. Enthalpy is changed
D. All of these
114. The tendency of atoms to attain a maximum of ___ electron in the valence shell is called octet rule
A. 6
B. 16
C. 8
D. 18
115. If a graph is plotted with concentration data of a reactant in a chemical reaction the curve is
A. Rising
B. Falling
C. U shaped
D. None of these
116. Who rejected vital force theory
A. Wohler
B. Berzelius
C. Wallis
D. Lyll
117. The peaks forms in a mass spectrograph shows number of __________ of an element
A. electrons
B. isotopes
C. protons
D. neutrons
118. Isoelectronic species have same
B. Ionic size
C. Reactivity
D. PH
119. The enzyme which is used in treatment of cancer in children?
A. Thrombin
B. L- asparaginase
C. Both
D. None of these
120. Which one of the product is obtained when acetic acid reacts with Ethyl alcohol in the presence of
mineral acid ?
A. CO
B. CH₃COOCH₃
C. CH₃CH₂COOH
D. CH₃COOCH₂CH₃
121. Which of the following is slow step in SN1 reactions?
A. Ionization
B. Formation of carbocation
C. Formation of Double bond
D. Formation of Alkyl halide from Carbocation
122. During base catalyzed reactions, which property of nucleophile increases?
A. Basicity
B. Nucleophilicity
C. Electrophilicity
D. Both b and c
123. Which metal is paramagnetic?
A. Cr
B. Mn
C. Fe
D. All of these
124.The two pi bonds in ethyne molecule are:
A. Parallel to the sigma bond
B. At 1 9.5° to the sigma bond
C. At 45° to the sigma bond
D. Perpendicular to the sigma bond
(PMC PAID TEST-24)
125.Addition of second Electron to a uni-negative ion always______?
A. An endothermic process
B. An exothermic process
C. Neutral process
D. Energy wasted
126.The product of the nucleophilic addition of aldehyde and ketones is called as_____?
A. Alkanolone
B. Adduct
C. Cyanohydrin
D. Nucleophilic product
127.A voltaic cell produces electrical energy from
A. Potential energy
B. Chemical energy of Ions
C. Kinetic Energy
D. Free Electrons
128.A state function depends upon the________?
A. Initial condition of the system
B. Final condition of the system
C. Path of the system
D. Both initial and final condition of the system
129.an element or its compound is first _____ to get its _________ spectrum by spectrometer
A. freezed, continuous
B. freezed, line
C. volatilized, line
D. volatilized, continuous
130.After digestion proteins change into:
A. Amino acids
B. Starch
C. Glycogen
D. Lipids
131.Which of the following Halogen react fast with alkanes in substitution reactions?
A. Cl₂
B. F₂
C. I₂
D. Br₂
132.Which functional group does amino acid contains;
A. carbonyl group
B. ester and alkyl halide
C. carboxylic acid
D. carboxylic acid and amine functionality
133.In Haber’s process the final product ammonia is converted into
A. solid state
B. Liquid state
C. gaseous state
D. None of these
134.How many isomers of C₄H₁₀ are possible?
A. 4
B. 3
C. 2
D. 1
135.When an electron is added, energy is released, so electron affinity is given the
A. positive sign
B. negative sign
C. neutral
D. delta sign
CHEMISTRY >> Solids
136.To conduct electricity through Ionic Solid, ions should be
A. Excited
B. Energized
C. Free
D. In random Motion
CHEMISTRY >> Solids
136.To conduct electricity through Ionic Solid, ions should be
A. Excited
B. Energized
C. Free
D. In random Motion
137.In Haber’s process volume percentage of ammonia in equilibrium mixture is
A. 30%
B. 32%
C. 35%
D. 33%
138.What is the formula of ammonium cyanate?
A. CH₃CONCH₃
B. NH₂CONH₂
C. NH₄CNO
D. NH₄CHO
CHEMISTRY >> Gases
139. Calculate the mass of I dm3 of NH3 gas at 3 C and 1 mm hg pressure, considering that NH3 is ideally
behaving
A. 0.99g
B. 0.89g
C. 0.9kg
D. 0.78g
140.For the reaction; 1/2 H₂ → H , the change in enthalpy is called as______?
B. Enthalpy of neutralization
C. Enthalpy of atomization
D. Enthalpy of Reaction
141.d-block elements are present _______ in the periodic table?
A. Right of the periodic table
B. Left of the periodic table
C. Bottom of periodic table
D. Between s and p block elements
142.Energy is absorbed
A. In Bond Breaking
B. In endothermic reactions
C. In Bond Formation
D. Both A and B
143.Which one of the following is common name of Butanoic acid ?
A. Butyric acid
B. Barbaric acid
C. Iso-butyric acid
D. Iso-Barbaric acid
144.SN₁ reactions are favored by which of the following reactions?
A. Water
B. Benzene
145.80% of the coal is used in________?
A. lime kiln
B. Domestic purposes
C. Fuel
D. Motor bikes
146.Which of the following acid solution is used for the seasoning of food ?
A. Butyric acid
B. Phthalic acid
C. Lactic acid
D. Acetic acid
147.Proteins are _________in structure.
A. Two dimensional
B. Three dimensional
C. Uni-dimensional
D. None of these
CHEMISTRY >> Solids
148.Cl-Cl Bond distance is is 5.63 A, While Na-Cl bond distance is
A. Half of 5.63
B. double to 5.63
C. 5.63
D. None of these
149.Reduction of ketones produce______.
A. Aldehydes
B. Methanol
C. Primary alcohols
CHEMISTRY >> Gases
150. Boyle's law is stated as:"The product of pressure and volume of a fixed amount gas at constant
temperature is a _____ quantity.
A. variable
B. constant
C. discreet
D. decreasing
151.Energy can be transferred to a system by
A. Heat
B. Work
C. Heat & Work
D. Force
152.Which of the following compound is formed when NACl reacts with CH₃MgBr
A. CH₃CN
B. CH₃Cl
C. CH₃CH₂NH₂
D. None of these
153.A substance which does not appear in balanced chemical reaction is called
A. Buffer
B. Spectator Substance
C. Reaction Intermediate
D. None of these
154.Due to less polarizability of Fluorine, it boils at _____ C
A. -188.1
B. 188.1
C. 184.4
D. 184.4
155.The reaction in Galvanic Cell is:
A. Spontaneous
B. nonspontaneous
C. Irreversible
D. endothermic
156.What is the formula of chloroform?
A. CH₃Cl
B. CH₂Cl₂
C. CHCl₃
D. CH₂Cl
157.The most abundant elements in earth's crust are
A. B & AI
B. Ca & Mg
C. Si & AI
D. All
158. The group formed by removal of one H atom from the benzene ring is called as__________?
A. Alkyl group
B. Benzyl group
C. Phenyl group
D. Ethyl group
159. The electron affinity of fluorine is less than chlorine as we move down the group, this deviation in
behavior is due to its.
A. small size
B. seven electron
C. thick electronic cloud
D. all of these
160. Which of the following reaction takes place when alkyl halide react with KOH in water ?
D. None of these
161.The gap in first, second and third ionization energy values helps to guess
A. atomic number of an element
B. valency of an element
C. charge on an atom
D. atomic mass of an element
162.For the identification of isotopes of elements having solid state
A. Aston spectrometer
B. dempster's mass spectrometer
C. Soddy mass spectrometer
D. atomic spectrometer
163.If a double bond is present between two carbons then this class of compounds in called as______?
A. Alkanes
B. Alkynes
C. Carbonyl
D. Alkenes
164.Ethanol is used as
A. a drink
B. a fuel
C. a preservative
D. all of above
165.In a carboxylic acid dimer how many H-bonds are present ?
A. Three
B. Two
C. Five
D. One
166.Which of the following is correct relationship between Boiling point and Intermolecular forces?
A. Boiling point increases if intermolecular forces increases
B. Boiling point decreases if intermolecular forces increases
C. Boiling point increases if intermolecular forces decreases
D. Boiling point is not affected by intermolecular forces
167.An element becomes paramagnetic if it has_____?
A. Electric field
B. Paired valence electrons
C. Magnetic moment
D. None of these
168.Phenol was obtained from ___________ first time?
A. Coke
B. Pitch
C. Aromatic compounds
D. Coal tar
CHEMISTRY >> Solids
169.The covalent crystals having giant molecules are insoluble in all the solvents.
A. Silicone carbide
B. diamond
C. both A & B
D. none of these
170.In a vacuum distillation the boiling point of glycerin is reduced to_____?
A. 290℃
B. 110℃
C. 156℃
D. 210℃
171.The oxidation number of Nickel in [Ni(CO)4] is
A. 2
B. 8
C. 6
D. 4
CHEMISTRY >> Gases
172.What is the value of universal gas constant in S.I. units?
A. 8.314Jmol–1K–1
B. 8.314 dm³ atm mol–1K–1
C. 0.0821dm³ atm mol–1 K–1
D. 0.0821Jmol–1K–1
173 What is the enthalpy of solution of NH4Cl?
A. 15 Kj/mol
B. –17kJ/mol
C. 16.2 kJ/mol
D. –16.5kJ/mol
174.Decomposition of Ozone has a very low value of equilibrium constant because of its:
A. stability
B. reactivity
C. compressibility
D. Instability
175. The peaks forms in a mass spectrograph shows number of _____ of an element.
A. electrons
B. isotopes
C. protons
D. neutrons
176.Which of the following catalyst is used in the industrial preparation of methanol?
A. Zinc oxide and alumina
B. Alumina and silica
C. Silica and Chromium oxide
D. Zinc oxide and Chromium oxide
177.Enzymes which bring about exchange of functional group is called:
A. Oxidoreductase
B. Hydrolases
C. Ligases
D. Transferases
C. Both A and B
D. OH– ions can be added
179.Which of the following evolve Carbon Dioxide with sodium bicarbonate?
A. CH₃COOCH₃
B. CH₃CH₂OH
C. CH₃CH₂COOH
D. CH₃COOOCH₃
180. Spectrum is the visual display or ______of component of white light when it is passed through prism.
A. rarefaction
B. radiation
C. collection
D. dispersion
(PMC PAID TEST-25)
1. Reagent like K₂Cr₂O₇ and H₂SO₄ lead to______?
A. Reduction
B. Hydrolysis
C. Dehydration
D. Oxidation
2. Nucleophilic addition reactions of carbonyl compounds can be catalyzed by____?
A. Acid
B. Base
C. Water
3. Compounds attracted by applied strong magnetic field are called
A. Diamagnetic
B. Paramagnetic
C. Good conductor D. Ferromagnetic
4. The substance that is attached to the enzyme at specific place and converted into product is called as?
A. Co-factor
B. Iso-zyme
C. Active site
D. Substrate
5. In Balancing Redox equation the first thing is to
A. balance out all the Reactants
B. Write the skeleton Equation
C. Calculate the oxidation Number
D. Identify the elements
6. The value of Planck's constant 'h' is
A. 6.626 x 1 -3 KJs
B. 6.262 x 1 -3 Js
C. 6.626 x 1 -3 Js
D. 6.262 x1 -3K Js
7. The value ionization energy of magnesium required to form magnesium ion is
A. 738J/mol
B. 738 KJ/mol
C. 783J/mol
D. 783 KJ/mol
8. Which of the following forces are strongest?
A. Debye forces
C. Induced dipole forces
D. Metallic bond
CHEMISTRY >> Gases
9. The spreading of a fragrance of a rose or a scent is due to the process called
A. Effusion
B. Diffusion
C. mixing
D. none of these
10. The word Alkali means
A. Base
B. Basic salt
C. Ashes
D. Spirit
11. In Haber’s process the final product ammonia is converted into
A. solid state
B. Liquid state
C. gaseous state
D. None of these
12. How much percentage of reactants is converted into products during half life period
A. 40%
B. 70%
C. 50%
D. 30%
CHEMISTRY >> Solids
13. Melting point of crystalline solids are
A. Fixed
B. Variable
C. have a range of value
D. None of these
14. Instantaneous dipole-Induced dipole forces are also named as?
A. Debye forces
B. Dipole-dipole forces
C. London Dispersion forces
D. H-bonding
15. In which of the following reagent Cupric citrate complex is formed?
A. Fehling's solution test
B. Benedict's solution test
C. Silver mirror test
D. sodium nitroprusside test
CHEMISTRY >> Gases
16. The rate of diffusion or effusion is ___-proportional to square root of its density at constant T and P
A. directly
B. inversely
C. equally
D. highly
17. The rate of reaction for the hydrolysis of ester is
A. High
B. Low
C. Moderate
D. Zero
18. The half-life for first order reaction is independent of initial
A. temperature
B. pressure
C. concentration
D. all of these
CHEMISTRY >> Solids
19. Solidified Noble gases contains
A. Polar molecules
B. Polar atoms
C. Non Polar atoms
D. None of these
20. Which one of the following pair shows abnormal electronic configuration?
A. Sc,Zn
B. Ni,Hg
C. Mn,Cd
D. Cu,Cr
21. The hydrogen gas bubbling into one molar solution of HCl has a pressure of
A. 2atm
B. 780 mmHg
C. 19 Psi
D. 1 atm
22. Which of the following is formed when phenol reacts with acetyl chloride?
A. Alcohol
B. Carboxylic acids
C. Ester
D. Amines
23. Which catalyst are used in catalytic cracking?
A. Silica, lime
B. Silica,alumina
C. Silica,Soda ash
D. Alumina,Pt
C. Dihydric alcohol
D. Primary alcohols
25. At 0℃ what is the physical state of water?
A. Ice
B. liquid
C. Vapour
D. Both ice and liquid
26. Law of conservation of energy is actually
A. Second law of thermodynamics
B. Third Law of Thermodynamics
C. First Law of Thermodynamics
D. Zeroth law of Thermodynamics
27. If two substituents are present at 1,4 positions then the isomer is called as______?
A. Ortho
B. Meta
C. Para
D. None of these
28. The concept of atoms was given by ______
A. Democritus
B. Berzelius
C. Bohr
D. Dalton
29. Equilibrium curve can be drawn by plotting
A. Time and Speed
B. Temperature and Pressure
C. Time & Concentration
D. Pressure & Concentration
30. Formyl group belongs to which class of compounds ?
A. Aldehydes
B. Ketones
C. Alkanals
D. Both a and c
31. Which one of the following enthalpy change is always exothermic in nature?
A. Enthalpy of combustion
B. Enthalpy of solution
C. Enthalpy of formation
D. Enthalpy of atomization
32. Space among the liquids is ______?
A. Lower than gases
B. Higher than solids
C. Lower than solids
D. Both A and B
33. The deliquescence is a property in which a solid
A. Absorbs moisture and remains solid
B. Absorbs moisture and turns to liquid form
C. Loses water of crystallization
D. Increases the number of water of crystallization
34. Ortho directing groups ____________on benzene ring?
A. Increases electron density
B. Decrease electron density on benzene
C. Make benzene less reactive
D. None of these
35. In the enthalpy relation, ΔH=(q)p + Δ(PV) the value Δ(PV) can be neglected for the reactions involving ___?
A. Gases
B. Liquids
C. Liquids and solids
D. Liquids and Gases
36. Boiling point of carboxylic acids are high due to?
A. Polarity of carbonyl group
B. Due to methyl group
C. Due to H-Bonding
D. Due London forces
CHEMISTRY >> Gases
37. It is the brown colored gas
A. N2
B. NO2
C. H2
D. O2
38. What is the Optimum temperature for working of enzyme in human body?
A. 40ºC
B. 35ºC
C. 37ºC
D. 32ºC
CHEMISTRY >> Gases
39. Effusion is the movement of a gas through extremely small opening of molecular size Into region of ____pressure.
A. high
B. low
C. moderate
D. same
40. 1,4-dimethyl benzene is called as_______?
A. Ortho xylene
B. Para-xylene
C. Para-methyl toluene
D. Meta-methyl toluene
41. Which of following is trihydric alcohol
A. Glycol and cyclohexanol
B. glycerol
C. ethylene glycol
D. resorcinol
42. On Hydrolysis with dilute HCl, ethanenitrile gives acetic acid through;
A. Formamide
B. Acetamide
C. Benzoic acid
D. Acetaldehyde
CHEMISTRY >> Solids
43. A crystal is made up of
A. atoms
B. ions
C. molecules
D. all of these
44. During SN₁ mechanism, nucleophile can attack on the halogen carbon?
C. From both sides
D. None of these
45. Energy is __when an electron is added to the isolated gaseous atom
A. increased
B. released
C. decreased
D. absorbed
46. A naphthol has
A. Alcoholic OH
B. -CHO
C. -COOH
D. Phenolic - OH
47. In the presence of KF, AlF3 is soluble in HF, find the complex formed
A. K3[AlF6]
B. AlH3
C. K[AlF3H]
D. K3[AlF3H3]
48. During reduction of aldehydes with NaBH₄, which of the following intermediate is formed ?
A. Carbanion
B. Carbocation
C. Carbene
D. Alkoxide ion
49. A double bond consist of
A. one sigma one pie
B. 2 sigma
C. 2 pie
D. half pie half sigma
50. Which of the following reactions have first step similar with each other?
A. E₁,S₂
B. E₂,S₁
C. E₂,S₂
D. E₁,S₁
CHEMISTRY >> Gases
51. Which gases are used as mixture for breathing in sea?
A. Oxygen and nitrogen
B. Carbon dioxide and oxygen
C. Helium and oxygen
D. Helium and hydrogen
52. In sp2 hybridization the orbital orientation is:
A. 109.5⁰
B. 180⁰
C. 90⁰
D. 120⁰
CHEMISTRY >> Solids
53. The existence of an element in more than one crystalline forms called
A. isomerism
B. allotropy
C.. anisotropy
D. all of these
A. Ethanol
B. Methanol
C. Glycerol
D. Glycol
55. What is the boiling point of Glycerine at 1 atm?
A. 280℃
B. 150℃
C. 290℃
D. 110℃
56. lanthanides and actinides resemble in?
A. ionization state
B. Oxidation state
C. electronic configuration
D. Formation of complexes
(PMC PAID TEST-26)
57. Concentration of reactants and products are expressed as Moles per unit
A. Area
B. length
C. Volume
D. None of these
58. Following is termed as hydroxyl derivative of benzene
A. Benzyl chloride
B. Benzyl alcohol
C. Phenols
D. Carboxylic acids
59. Change in concentration of reactants and products can only be found by
A. Physical methods
B. Chemical Methods
C. Physical and Chemical methods
D. None of These
60. The shielding effect _______ from left to right in a period
A. decreases
B. increases
C. remains same
D. no change
61. Nucleophilic addition reactions of carbonyl compounds can be catalyzed by____?
A. Acid
B. Base
C. Water
62. The compounds in which similar groups are present on the same side of double bond are called
as____?
A. Trans isomers
B. Positional isomers
C. Cis isomer
D. None of these
63. The Oxidation state of Alkali metals is?
A. 1
B. 2
C. 3
D. 0
64. Which of the following properties are associated with transition metals?
A. Color
B. Complex formation
C. Use as catalyst
D. All of these
65. Formula mass is considered for _______ compounds instead of their molecular mass.
A. metallic
B. ionic
C. covalent
D. polar covalent
66. Which one of the following is a Cyano group?
A. -SH
B. -COOH
C. -CN
D. -COOR
67. NaOH is named as caustic soda because
A. It corrodes the organic tissues
B. It is used in soda water
C. It reacts with chlorine gas
D. It reacts with fats to form soap
68. Which of the species has a permanent dipole moment?
A. SF4
B. SiF4
C. BF3
D. XeF4
69. What is the emf of Zn-Cu cell ?
A. 1.01V
B. 1.23V
C. 1.1V
D. 1.44V
70. The turbid liquid were also called liquid crystals due to presence of some degree of
A. heat
B. order
C. hotness
D. coldness
71. Which of the following product formed when ethyl chloride react with alcoholic KOH?
A. C₂H₄
B. C₂H₅OH
C. C₂H₄ClOH
D. C₂H₆
72. The coefficients of balanced equation are a part of Equilibrium constant value as
A. denominator
B. numerator
C. powers of concentration
D. All of these
73. Benzene is extra stable because of______?
A. Cyclic structure
B. Three alternating double and single bonds
C. Delocalization of pi-electrons
D. All of these
74. Which of following has higher boiling and melting point
A. acetone
B. 2 - butanol
C. propane
D. 2 - methylpropene
CHEMISTRY >> Solids
75. Cholesteryl Benzoate turns milky at
A. 123°C
B. 135°C
C. 145°C
D. 179°C
76. Masses of atoms ranges from
A. 1x10-28 kg to 1x10-22 kg
B. 1x10-26 kg to 1x10-23 kg
C. 1x10-27 kg to 1x10-24 kg
D. 1.6373x10-27 kg to 1x10-25 kg
CHEMISTRY >> Gases
77. Critical pressure of Argon(Ar) is
A. 48 atm
B. 33.5atm
C. 111.5atm
D. 73. atm
78. Which of the following compound does not give cannizzaro reaction?
A. Benzaldehyde
B. Trimethyl acetaldehyde
C. Formaldehyde
D. Acetaldehyde
A. Amylase
B. Urease
C. Pectin
D. None
80. Homocyclic compounds are also called as__________?
A. Heterocyclic compounds
B. Alicyclic Compounds
C. Aliphatic compounds
81. 18 g of glucose (C6H12O6) and 342 g of sucrose (C12H22O11) has same number of molecules but
_________ number of atoms+B96
A. different
B. same
C. greater
D. lesser
82. When an electrophilic reagent attack on alcohol
A. O - H bond formed
B. O - H bond breaks
C. C- O bond breaks
D. rise in boiling point
83. Which of the following Shows tautomerism?
A. Amino acids
B. Ketones
C. Carboxylic acids
D. All of these
84. The total of all the possible kind of energies in a system is called
A. Total energy
B. Kinetic Energy
C. Potential Energy
D. Internal Energy
A. Water
B. Benzene
86. When a molten salt is electrolyzed the products are
A. Complex
B. Predictable
C. Unpredictable
D. All of these
87. In this compound [Pt Cl NO2 (NH3)4]2- the coordination number of transition element is
A. 6
B. 2
C. 8
D. 4
CHEMISTRY >> Gases
88. London dispersion forces are the only forces present among
A. atoms of helium in gaseous state at high temperature
B. molecules of water
C. molecules of solid iodine
D. molecules of HCl gas
89. In which of the following dipoles are not present ?
A. Water
B. HCl
C. Noble gases
D. Chloroform
C. Dihydric alcohol
D. Primary alcohols
91. Enzymes are _____ in nature.
A. Proteins
B. Carbohydrates
C. Lipids
D. Nucleic acid
92. Physical methods of finding the rate of reaction always involve
A. A catalyst
B. A graph
C. A calculating software
D. None of These
93. The increase in atomic radii in _-----is due to increase in the number of shells and the screening effect
A. groups
B. periods
C. both A & B
D. none of these
94. As the time interval approaches Zero the average and instantaneous rate become
A. Negative
B. Zero
C. Negligible
D. Positive
95. The maximum number of electron accommodated in a shell or energy level is calculated by formula:
A. n2
B. 2n2
C. 2n
D. 3n
96. Which one of the following is a state function that describe both the internal energy and product of
pressure and volume ?
A. Entropy
B. Heat
C. Enthalpy
D. Temperature
98. The amount of energy evolved during the formation of hydrogen molecule is
A. 436.45 KJ/mol
B. 444.45 J/mol
C. 436.45 J/mol
D. 444.45 KJ/Mol
99. The most electropositive element among the following is:
A. Li
B. Ca
C. Cs
D. Ca
100.Acetaldehyde oxidation will lead to formation of
A. Acetic acid
B. Butanoic acid
C. Propanoic acid
D. Ester
101.If at equilibrium state temperature is increased, it will favor
A. Exothermic Reactions
B. Endothermic Reactions
C. Reversible gaseous reactions
D. Irreversible reactions
102.Fluorine has highest electronegativity value that is
A. 3.4
B. 4
C. 1.2
D. 2.6
103.Organic compounds are soluble in
A. polar solvents
B. water
C. Ammonium cyanate
D. Non-polar solvents
104.Which catalyst is used when ethanol react with ammonia to produce ethyl amine?
A. ZnCl₂
B. C₆H₅N
C. Al₂O₃
D. ThO₂
CHEMISTRY >> Solids
105.Diamond is a bad conductor because of
A. high density
B. no free electron
C. tight structure
D. transparent to light
106.How many unhybridized orbitals are there in ethyne molecule?
A. 1
B. 2
C. 3
D. 4
107.Condensation involve which of the following reactions?
A. Elimination + addition
B. Elimination + Substitution
C. Addition + substitution
D. None of these
108.If in a solution of alkyl halide in a nonpolar solvent, base is added which of the following reaction takes
place?
A. SN₂
B. E₁
C. SN₁
D. E₂
109.Electrolysis is a
B. Oxidation-reduction reaction
110.Hydrolysis of Tertiary Butyl bromide gives
A. Carboxylic Acid
B. Alcohol
C. Aldehyde
D. Ketone
CHEMISTRY >> Gases
111.Which gas among them shows maximum ideal behavior
A. Ammonia
B. Hydrogen
C. Helium
D. Radon
112.Which of the following ester give Jasmine Flavour ?
A. Ethyl acetate
B. Octyl Acetate
C. Amyl Butyrate
D. Benzyl Acetate
(PMC PAID TEST-27)
CHEMISTRY >> Gases
125.Molecules of liquids are in constant state of motion, it causes
A. diffusion
B. evaporation
C. melting
D. both A & B
126.Downs Cell is used for the electrolysis of
A. Aqueous NaCl
B. Aqueous NaNO3
C. Fused NaCl
D. Fused NaNO3
127.In Pakistan ethanol is prepared commercially by
A. Distillation
B. Fermentation
C. molasses
D. all of above
128.Which of the following is correct general formula of aliphatic carboxylic acid ?
A. RCOOH
B. ArCOOH
C. PhCOOH
D. None of these
129.Suppression of ionization means
D. None of these
130.In tertiary alkyl halides, carbon atoms is attached to how many carbon atoms?
A. 2
B. 3
C. 4
D. 1
131.The sequence of amino acids combined in a peptide chain is called_______.
132.Aldehydes are present in natural oils that are used as?
A. Flavours
B. Fragrances
C. Both a and b
D. Sugars
133.According to vital force theory organic compounds were only produce in._________?
A. Animals
B. Plants
C. Bacteria
D. All of these
134.A mole of a substance contains ______particles
A. 6.2x1022
B 6.22 x1022
C. 6.02x1023
D. 6.5 x1022
135.According to Bohr, the orbits in which electrons revolve around the nucleus are
A. oval
B. elliptical
C. cylindrical
D. circular
136.Which one is radioactive?
A. Cs
B. Fr
C. Li
D. K
137.Pure metal
A. Corrode slowly
C. Corrode rapidly
D. None of these
138.In the rate equation R=k[A]â [B]^b, order of reaction is
A. a x b
B. a-b
C. b-a
D. a+b
CHEMISTRY >> Solids
139.if 2 axes are of equal length and third is either shorter or longer than other two, all angles are 9
A. cubic system
B. tetragonal system
C. triclinic system
D. hexagonal system
140.Formaldehyde polymerizes to form ?
A. Bakelite
B. Paraldehyde
C. Metaformaldehyde
D. All of these
141.Wholar first time prepare urea in laboratory in_____?
A. 1900
B. 1829
C. 1850
D. 1828
142.What is the value of C-C bond length in benzene?
A. 154 pm
B. 120 pm
C. 134 pm
D. 139 pm
143.During the nomenclature of Alkyl halides, halogens are named as______?
A. Substituents
B. Parent name
C. Ligand
D. Longest chain
CHEMISTRY >> Solids
144.Which of the following is an Isomorph of Copper
A. Zn
B. Cd
C. Ag
D. Mn
145.The bond formed by the complete transfer of electron is called
A. ionic bond
B. covalent bond
C. metallic bond
D. polar covalent bond
CHEMISTRY >> Gases
146.At high altitudes, the pilots feel uncomfortable breathing because the partial pressure of oxygen is
lower than
A. 16 torr
B. 159 torr
C. 158torr
D. 157 torr
147.Energy changes in cyclic process is always
A. Unity
B. Zero
C. Positive
D. Negative
148.When NaCl dissolves in water, positive end of water surround the Cl- ion and Negative end of water surrounds the
Na+ end of salt, which forces are present between these ions and water molecule ?
A. Dipole Dipole forces
B. Ion dipole forces
C. H-bond
D. Debye force
149.The sum of cationic and anionic radius in a crystal lattice is equal to
A. inter-titian distance R
B. inter ionic distance R
C. inter- cationic distance R+
D. inter-anionic distance R-
150.Acetaldehyde oxidation will lead to formation of
A. Acetic acid
B. Butanoic acid
C. Propanoic acid
D. Ester
151.The expression for the radius of nth orbit of hydrogen atom was derived by
A. Planks
B. Bohr
C. Rutherford
D. Einstein
152.Crystals of Na2CO3. 1H2O when exposed to air
A. Lose water and remain solid
B. Gain water and remain solid
C. Gain water and become liquid
D. Remains unchanged
153.Which of the following solvent favor SN₂ reactions?
A. Water
B. Ammonia
D. Acetic acid
154.Which of these have a positive value of enthalpy
A. Combustion
B. Neutralization
C. Atomization
D. All of these
155.In a rate expression the Bracket [ ] indicates,
A. Rate
B. Time Concentration
C. Reaction yield
D. Concentration
CHEMISTRY >> Gases
156.Gases are ideal at high ___and become non ideal at high _____
A. pressure, volume
B. pressure, temperature
C. temperature. Pressure
D. volume, pressure

157.A peptide having up to 10000 amino acids is called as_______?
A. Dipeptide
B. Protein
C. Polypeptide
D. Peptide
158.Rate of diffusion of liquids is ______than gases
A. Lower
B. Higher
C. Equal to
D. All of these
CHEMISTRY >> Gases
159.The strength of intermolecular forces in liquids, solids and gases depends directly on.
A. speed of atoms
B. motion of particles
C. distance b/w molecules
D. all of these
160.Which phenol is most acidic in nature
A. salicylic acid
B. picric acid
C. cresol
D. O - nitrophenol
161.Which of the following process is used to improve the quality of Gasoline?
A. Steam cracking
B. Reforming
C. Catalytic cracking
D. Distillation
162.Why aldehydes are more reactive than ketones?
A. Electronic reasons
B. Steric hindrance
C. Both a and b
D. None of these
163.Activator of phosphatase enzyme is_____.
A. Mn²⁺
B. Mg²⁺
C. Zn²⁺
D. None of these
164.Each electron in an atom must have its own unique set of quantum number is a statement of :
A. Aufbau principle
B. Pauli exclusion principle
C. Hund’s rule
D. none of these
165.Which of the following compound is formed as a result of polymerization of acetylene?
A. Benzene
B. 1,3,5-cyclohexatriene
C. Hexene
D. Butane
166.The enthalpy change of a reaction which involve the formation of atom from its elements at S.T.P is
called as
B. Enthalpy of combustion
C. Enthalpy of neutralization
D. Enthalpy of sublimation
167.Which of the following can not be prepared directly from acetic acid ?
A. Ethyl acetate
B. Acetamide
C. Acetyl Halide
D. Acetic anhydride
168.Production of Ammonia by Haber process is a
A. Endothermic Reaction
B. Exothermic Reaction
C. Irreversible Reaction
D. Redox Reaction
169.If Ammonia is not withdrawn continuously from equilibrium mixture its yield will be
A. increased
B. decreased
C. remain unchanged
D. None of these
170.In a galvanic cell Copper compartment get net negative charge due to arrival of
A. Free charge from zinc sulphate solution
B. Electron
C. Protons
D. Zinc Ions
171._________conducts nerve impulse in brain
A. serotonin
B. aspartame
C. ascorbic acid
D. hydrazine
172.In Which of the following reaction of carboxylic acids only C=O group involved in bonding and OH
group is replaced?
173.The total number of bond angles in methane are
A. 2
B. 3
C. 5
D. 4
174.Organic compounds are
A. Ionic
B. Non ionic
C. Non covalent
D. Covalent
175.Decomposition of Ozone has a very low value of equilibrium constant because of its.
A. stability
B. reactivity
C. compressibility
D. Instability
CHEMISTRY >> Solids
176.which one of them belongs to tetragonal system
A. Bi
B. Sn
C. Fe
D. Zn
178.The only thing which can predict that reaction will be spontaneous or nonspontaneous is
A. Enthalpy Change
B. Free Energy of the system
C. Energy Change
D. Temperature Change
179.Reaction of ethylmagnesium bromide with acetone produces?
A. Primary alcohol
C. Tertiary alcohol
D. Methyl alcohol
CHEMISTRY >> Gases
180.Number of molecules in one dm3 of water will be almost
A. 18x6.02x1023
B. 55.6x6.022x1023
C. 18x6.2x1023
D. 2x6.2x1023
(PMC PAID TEST-29)
125.The unit of electronegativity is
A. Joule
B. Kilojoules
C. watt
D. no unit
CHEMISTRY >> Solids
126.Allotropes are of same
A. Compounds
B. Molecules
C. Ions
D. Element
127.Which of the following gives Markovnikov's product with Propene?
A. HBr
B. H₂SO₄/H₂O
C. HBr
D. All of these
128.The sequence of amino acids combined in a peptide chain is called_______.
129.Molten sodium burns with brilliant yellow flame in a chlorine atmosphere to form____?
A. NaCl
B. NaOH
C. NaBr
D. ClO
130.In the rate equation R=k[A]â [B]^b, a and b as exponents decides
131.Geometrical isomerism arises due to_____?
A. Rotation around a double bond
B. Restriction of rotation around a single bond
C. Restriction of rotation around a double bond
D. Due to double bond
132.The Diameter of DNA is maintained due to_______?
C. Chemical bond
D. H-bond
CHEMISTRY >> Gases
133.The vapor pressure of water at 8⁰C is
A. 4.579 torr
B. 23 torr
C. 8.1 torr
D. 17.54 torr
134.The e/m value is maximum for __gas because of ___value of "m" for positive rays obtained from it.
A. Oxygen gas, lowest
B. hydrogen gas, highest
C. hydrogen gas ,lowest
D. helium gas ,highest
135.Conversion of Electrical energy into chemical energy is
A. Mechanical Energy
B. Electromechanical Energy
C. Electrochemistry
D. Chemical Energy
136.Glycerol can also be termed as
A. 1 - butanol
B. 1, 2, 3 - propanetriol
C. 2 - methyl - propanol
D. ISObutyl alcohol
137.______is a macromolecule found in blood
A. Hemoglobin
B. plasma
C. creatinine
D. plasmids
138.The precipitation of weaker electrolyte follows
B. Law of energy Conservation
D. None of these
139.Those elements ,with electronic configuration of valence shell ns2np6 show little tendency to react
chemically, are called
A. lanthanides
B. Actinides
C. Alkali metals
D. Noble gases
140.Atomic radii can be determined by measuring the distance b/w centers of ____atoms
A. opposite .
B. adjacent
C. parallel
D. equal
141.Which of the following forces are developed only for few moments ?
B. Debye forces
D. H-bonding
142.Which of the following product is formed when Alcohol is added to acetaldehyde ?
A. Acetal
B. Ketal
C. Carboxylic acid
D. Alcohol
143.Which one of the following is larger in size than oxygen atom______?
A. Fluorine
B. Nitrogen
C. Hydrogen
D. Neon
CHEMISTRY >> Gases
144.Maximum Hydrogen bonding is found in
A. HI
B. HF
C. HCl
D. HBr
CHEMISTRY >> Gases
145.Proteins also contain bonding
A. covalent
B. ionic
C. hydrogen
D. metallic
146.On reacting with which of the following carboxylic acids produce CO₂?
A. Carbonate
B. Bicarbonate
C. Bisulphites
D. Both a and b
147.What is the mass of one mole aspartame having formula C14H18N2O5
A. 4g
B. 40g
C. 50g
D. 1g
148.Hardness of transition metals is due to_______?
A. More melting point
B. More electrons
C. Variable oxidation state
D. Higher binding energies
149.Non protein part which is conjugated with protein is called_______.
A. Coenzyme
B. Co-factor
C. Prosthetic group
D. None
150.The value of Principal quantum number is _integers up to infinity
A. zero, positive
B. non zero, positive
C. non zero, negative
D. positive
151.Which of the following properties belong to acetic acid?
A. colourless liquid, odourless, sour taste
B. bright colour bitter taste
C. colourless solid, sour taste, pungent smell
D.. all are incorrect
152.Which of the following catalyst is used in Friedel craft reaction?
A. ZnCl₂
B. KMnO₄
C. AlCl₃
D. V₂O₅
153.Rate equation for the hydrolysis of Tertiary Butyl Bromide is independent of concentration of water
as a reactant because
A. It's in excess
B. A solvent
C. Solute
D. Both A and B
154.The region where probability of finding the electron is negligible is called as
A. Nucleus
B. Atom
C. Orbital
D. Nodal plane
155.Which one of the following substances conduct electricity by the movement of ions?
A. Graphite
B. Copper
C. Molten sodium chloride
D. Mercury
156.Unit for rate of reaction is
A. Mole / litre
B. Moles / gram
C. Moles / Second
D. moles/dm^3 s^-1
157.Globulins protein upon hydrolysis yield amino acids or their derivatives, so they belong to which type
of protein
A. Derived proteins
B. Compound proteins
D. Simple proteins
159.Most abundant protein in animals forming 25%-35% of body protein is which type of protein?
A. Simple proteins
B. Conjugated proteins
C. Derived proteins
D. None
160.Order of discharge of ions depends upon
A. Their temperature
B. Their concentration
C. Their Activation Energy
D. All of these
A. chlorine
B. Ammonia
C. water
D. hydrochloric acid
162.The rate of SN₁ reaction become doubled if______?
CHEMISTRY >> Solids
163.Crystal are obtained by Saturated Solution through
A. Sedimentation
B. Drying
C. Heating
D. Cooling
164.Which one of the following is a strong electrophile on which benzene electrons attack fastly?
A. FeBr₃
B. FeCl₄⁻
C. Cl⁺
D. Cl⁻
165.Enthalpy of a system is given as____?
A. ΔH= qv+ w
B. H=E + PV
C. H=qp + PV
D. H= E
166.Rectified spirit is converted into the absolute alcohol by______?
A. Crystallization
B. Distillation
C. Re-distillation
D. Fractional distillation
167.How enthalpy changes of reactions can be measured?
A. By spectrometry
B. By conductometry
C. By calorimetry
D. By refractometry

168.The energy released during the formation of crystal lattice of KCl is
A. 39 KJ/mol
B. 49 KJ/mol
C. 59 KJ/mol
D. 69 KJ/mol
169.Δn is the difference in number of moles of reactants and products in a reaction which is
A. Solid Phase
B. Liquid phase
C. Gaseous Phase
D. Plasma Phase
170.In Peroxides the Oxidation number of Oxygen is
A. -1
B. 2
C. -2
D. 1
171.Which of the following has more evaporation rate at same temperature?
A. Gasoline
B. Water
C. Honey
D. Ethanol
172.After the hydrolysis of ester the change in concentration of acid at different intervals is calculated by
A. Titration with KMnO4
B. Titration With Standard Alkali
C. Distillation
D. Evaporation of mixture
173.Alkenes have which type of hybridization?
A. sp²
B. sp³
C. sp²d
D. sp
174.Which metal is paramagnetic?
A. Cr
B. Mn
C. Fe
D. All of these
175.Which one of the following is not a heterocyclic compound
A. thiophene
B. anthracene
C..furan
D. pyrrole
176.Carboxylase are example of which type of enzyme:
A. Hydrolases
B. Lyases
C. Transferases
D. Ligases
177.A compound has an empirical (simple) formula, C2H2O. If the experimental molecular weight is
found to be in the range 16 -17 , the molecular formula of this compound is: (Atomic wt.: C = 12. 1, H =
1. 8, O = 16. )
A. C3H6O3
B. C4H4O2
C. C8H8O4
D. C6H6O3
178.∆Hf֯ of which of the following can not be measured directly?
A. Al₂O₃
B. B₂O₃
C. CO
D. All of these
179.Aldehydes and ketones react with hydroxyl amine and produce?
A. Imine
B. Oxime
C. Aldole
D. Nitrile
180.The tendencies of elements to have relation with each other can be understand by
A. Lowry concept
B. Pauling concept
C. Lewis concept
D. Arrhenius concept
(PMC PAID TEST-30)
1. Each half reaction in ion electron method is balanced by adding
A. Electrons on left hand side
B. Electron on ride hand side
C. Both left or right hand side
D. None of these
2. Which one contain non polar covalent bond
A. H2
B. Cl2
C. N2 and O2
D. All of these
3. an element or its compound is first _____ to get its _________ spectrum by spectrometer
A. freezed,continuous
B. freezed,line
C. volatilized, line
D. volatilized,continuous
4. Intermolecular distance is larger in ______?
A. Ionic compounds
B. Solids
C. Covalent compounds
D. Liquids
5. Any thing under study during a chemical reaction in thermodynamics is called as_______?
A. Analyte
B. System
C. Surrounding
D. Boundary
CHEMISTRY >> Solids
6. Arrangement of atoms in Molecular Solids can be studied with the help of
A. Gamma Rays
B. X Rays
C. Spectrometry
D. Electron Microscope
7. Which of the following test distinguish between 2-butanol and 1-butanol?
A. Baeyer's test
B. Lucas Test
C. Benedict's test
D. 2,4-DNPH test
8. Which of the following element is present in all proteins ?
A. S
B. C
C. N
D. O
9. The compounds which are formed by the replacement of a hydrogen atom by a halogen is called as___?
A. Alcohol
B. Alkyl halide
C. Carbonyl halide
D. Ethers
10. Aldehydes and ketones are _________?
B. Acidic compounds
C. Carbonyl compounds
D. Electrophiles
11. Standard Oxidation potential has a
A. Negative sign
B. Positive Sign
C. a whole number value
D. None of these
CHEMISTRY >> Solids
12. metals are malleable and ductile because their layers _____ on applying pressure
A. remain fixed
B. slip past each other
C. rotate
D. twist
13. Which of the following Compound is not reduced by NaBH₄ ?
A. Acetaldehyde
B. Acetone
C. Carboxylic acid
D. Alkene
14. The reaction in which a molecules is removed from a compound but no addition takes place is called
as_____?
D. Replacement reaction
15. Boiling point of halogens ___________down the group?
A. Increases
B. Decreases
C. Remain same
D. Shows abnormal behaviour
16. Standard Electrode potential is measured at
A. 273K
B. 293K
C. 298K
D. 292K
17. Equilibrium constant has
A. Units
B. No Units
C. Both A and B
D. A negative value
18. Volume factor can appear in equilibrium constant expression in
A. denominator
B. Numerator
C. Both A and B
D. Only in Numerator
19. The imaginary surface separating system and surroundings is called
A. Buffer
B. Transition Zone
C. Boundary
D. Intermediate state
20. Albumin is water ______?
A. Soluble
B. Insoluble
C. Slightly soluble
D. Highly insoluble
CHEMISTRY >> Gases
21. The density of an ideal gas falls as its temperature ___and pressure ______
A. decrease, increase
B. increase, decrease
C. falls. Constant
D. constant ,constant
22. Potassium has electronic configuration (2,8,8,1)and become ion by attaining configuration
A. 2.8.8,2
B. 2,8,8,
C. 2,8,1
D. 2,8,8,8
23. Polyvinyl acetate is polymer of______?
A. Acetyl acetate
B. Vinyl acetate
C. Chloro acetate
D. Benzyl acetate
CHEMISTRY >> Gases
24. The partial pressure exerted by the water vapors is called
A. tension
B. aqueous tension
C. aqueous pressure
D. all of these
CHEMISTRY >> Solids
25. Crystalline Solids are made up of
A. Atoms
B. Molecules
C. Ions
D. All of these
26. For the study of particles, discharge tube is filled with
A. gas
B. air
C. vapours of a substance
D. all of these
27. Sucrose is converted into glucose & fructose by:
A. Invertase
B. Urease
C. Glycolysis
D. None
28. Non- protein part cofactor includes organic & metallic organic molecule & sometimes______.
A. Vitamins
B. DNA
C. Coenzyme
D. None
29. Alicyclic compounds are similar in properties to______?
A. Heterocyclic compounds
B. Aliphatic compounds
D. Aromatic compounds
30. Alcohol is dehydrated by the following reaction
A. elimination reaction
B. oxidation reaction
C. combustion
D. decomposition
31. Acetaldehyde undergoes polymerization with conc.H₂SO₄ and form____?
A. Acetylides
B. Paraldehyde
C. Bakelite
D. Meta Acetaldehyde
32. Rate = k [ NO][O3] , the order of this reaction is
A. 2
B. 0
C. 1
D. 3
33. Which one of the following is an example of transition element?
A. Na
B. Co
C. Ba
D. Ra
34. Which of the following method is used to prepare alcohols from alkenes?
A. Reaction of alkenes with X₂/water
B Reaction of alkene with water
C. Reaction of alkene with H₂SO₄/water
D. temperature
35. The addition of HBr to an unsymmetrical alkenes follows?
A. Direct addition
B. Markovnikov's addition
C. Anti Markovnikov's addition
D. Dehydration
CHEMISTRY >> Gases
36. Which forces are very significant in non-polar molecules like Cl2,H2 and noble gases
A. dipole-dipole
B. induced dipole
C. London
D. spontaneous induced dipole
37. Heat of combustion is always a______?
A. Exothermic reaction
B. Endothermic reaction
D. nonspontaneous reaction
38. From which of the following ketone can be prepared?
A. Propyne
C. Ca Acetate
D. All of these
39. When heat is provided to a liquid it causes it to______?
A. Contract
B. Decompose
C. Expand
D. Become Non volatile
40. Electrolysis of a dilute solution of NaCl results at the anode
A. Sodium
B. Hydrogen
C. Chlorine
D. Oxygen
41. Rate of reaction can be studied graphically by plotting time and
A. temperature
B. Concentration
C. Pressure
D. Activation Energy
42. Alkali and alkaline earth metals impart colours when heated over the burner, it is due to
A. Smaller electronegativity of alkali metals
B. The smaller ionic radius of these metals
C. De-excitation of electrons from higher energy levels to low energy level
D. Excitation of electrons from low energy levels to higher energy levels
43. Vital force theory proposed by
A. Wohler
B. Berzelius
C. lanthanides and actinides resemble in?
D. Lyll
44. Which of the following test can detect presence of both Aldehydes and ketones ?
A. Tollen's test
B. Reaction with hydrazine
C. Reaction with 2,4-dinitrophenylhydrazine
D. Reaction with Ammonia
45. Which of the following is an example of aromatic carboxylic acid?
A. Ethanoic acid
B. Butanoic acid
C. Adipic acid
D. Phthalic acid
46. By changing Pressure at equilibrium which value is changing
A. Kc
B. Kp
C. Equilibrium Position
D. All of these
47. d-block elements are called
A. coinage metals
B. noble metals
C. transition metals
D. alkali metals
48. Heat is the energy that flows across the
A. Surroundings
B. Boundaries of the system
C. only within the system
D. All of these
49. When the two substitution are different in arenes, they are put in which of the following order?
A. Numerically
B. Alphabetically
C. Alphanumerically
D. None
50. Quantum number values for 2p orbitals are
A. n = 2,l= 1
B. n = 1 ,l = 2
C. n = 1 ,l =
D. n = 2 , l=
51. Ethanol forms yellow crystal with iodine in the presence of
A. Zncl2
B. Cons H2SO4 at 14 C
C. NaoH
D. KoH
52. Conductivity of a solution changes with change in
A. Reactant Ions Concentration
B. Temperature of mixture
C. Adding an Impurity
D. By catalyst
53. Which of the following reactions have first step similar with each other?
A. E₁,S₂
B. E₂,S₁
C. E₂,S₂
D. E₁,S₁
54. Most of the enzyme reactions are______?
A. Reversible
B. Irreversible
C. Condensation
D. Oxidation
CHEMISTRY >> Gases
55. If we decrease temperature of a gas 2 times, its volume will
A. increase 4 times
B. decrease 4 times
C. decrease 2 times
D. increase 2 times
CHEMISTRY >> Solids
56. Cesium in cesium chloride has coordination number
A. 6
B. 8
C. 4
D. 5
(PMC PAID TEST-31)
1. The unit used to express the relative atomic mass is called
A. gram unit
C. atomic mass
D. atomic mass unit
CHEMISTRY >> Gases
2. Molecules of ____ can collide among themselves and exchange energy
A. solids
B. liquids
C. gases
D. both B & C
3. The phenomenon in which compounds have same molecular formula but different structural formula
is called as___?
A. Reforming
B. Isomerism
C. Polymorphism
D. Hybridization
4. Two compartments of a galvanic cell are connected by
A. A battery
B. Electrical Wires
C. A pipe
D. Salt Bridge
5. Transition elements for complexes because______?
A. They have empty d orbitals
B. They show variable oxidation states
C. Both a and b
D. They have strong bonding
6. BH3 has a geometry with H-B-H bond angles of 12
A. linear
B. trigonal planar
C. tetrahedron
D. bent
7. Manufacturing of Ammonia by Haber’s process is an
A. endothermic reaction
B. exothermic reaction
C. irreversible
D. Slow
8. Aldehydes and ketones are _________?
B. Acidic compounds
C. Carbonyl compounds
D. Electrophiles
9. From which of the following sources acetic acid was first isolated ?
A. Butter
B. Milk
C. Cheese
D. Vinegar
10. Ionization energy depends on which of the following factors?
A. Size of atoms
B. Nuclear Charge
C. Number of shells
D. All of these
11. Ethene is prepared from alcohol by______?
A. Decomposition
B. Dehydration
C. Dehydroxylation
D. Dehalogenation
12. Intermolecular forces are also called as_________?
A. Chemical bond
B. Intramolecular force
C. Van der waal forces
D. Strong forces
D. None of these
A. Br⁺
B. CH₄
C. NH₃
D. H₂O
15. ΔH for exothermic reaction is______?
A. More than 1
B. Positive
C. Negative
D. Neutral
16. I elements have high ionization energy value then it means they belongs to
A. metals
B. non metals
C. metalloid
D. noble gases
17. Fuels with higher octane number can be produce by______?
A. Cracking
B. Reforming
C. Decomposition
D. Isomerisation
18. The first ionization potential of alkaline earth metal is greater than alkali metals because
A. They are more reactive
B. They have greater atomic radii
C. They have smaller atomic sizes
D. All
19. What is the IUPAC name of; ClCH₂CH₂COOH ?
A. 3-Chloropropanoic acid
B. 2-Chloropropanoic acid
C. 2-Chloro-1-propanoic acid
D. Propyl carboxylic acid chlorid
D. All of these
CHEMISTRY >> Gases
21. How will the conditions be changed to prevent the volume of the given gas from expanding when its
mass is increased?
A. temperature and pressure increased
B. temperature is lowered and pressure decreased
C. temperature and pressure increased
D. temperature is lowered and pressure increased
22. In pig iron the concentration of C-atom is
A. 12 — .25%
B. 2.5 — 4.5%
C. 2. — 4. %
D. .25 — 2.5%
23. Standard Electrode Potential for Hydrogen is taken as
A. Standard
B. Zero Volts
C. Unity
D. Both A and B
24. There is one lone pair present in H₃O⁺, it cannot act as_____?
A. Electrophile
B. Lewis acid
C. Nucleophile
D. Strong acid
25. Which of the following intermolecular forces are present between octane molecules ?
A. London dispersion forces
C. Debye forces
D. H-Bonding
26. Which of the following is an example of Monocarboxylic acid ?
A. Oxalic acid
B. Methanoic acid
C. Glutaric acid
D. Adipic acid
27. Which one of the following is not an example of state function?
A. Temperature (T)
B. Volume (V)
C. Enthalpy (E)
D. Heat (q)
28. The products of SN₁ reactions are formed with______?
D. All of these
29. Why oxidation of ketones is not easy _________?
A. Because they involve breaking of C-O bond
B. Because it involve breaking of C-C bond
C. Because it involve breaking of C-H bond
D. Because it involve breaking of C=C bond
30. Rate of reaction can be studied graphically by plotting time and
A. temperature
B. Concentration
C. Pressure
CHEMISTRY >> Solids
31. Coordination number of Na in NaCl is
A. 4
B. 6
C. 8
D. 3
CHEMISTRY >> Solids
32. Chloride Ion in NaCl are placed at the corner of regular
A. Pentagon
B. Cuboid
C. Octahedron
D. Cube
33. Space among the liquids is ______?
A. Lower than gases
B. Higher than solids
C. Lower than solids
D. Both A and B
34. When a catalyst is added to a reversible reaction, at equilibrium state the value of equilibrium constant.
A. decreases
B. Increases
C. Remains unchanged
D. First decrease then increase
35. Which of the following compound shows strong H-Bonding with water?
A. C₂H₆
B. CH₃Br
C. CH₃OCH₃
D. C₂H₅OH
36. As the force of attraction b/w the valence electron and the nucleus _____with the increase in atomic
radius, the electron affinity usually.
A. decreases, increases
B. decreases, remains same
C. increases, decreases
D. decreases,decreases
37. Which of the following is most reactive of all?
A. Alkanes
B. Alkenes
C. Alkynes
D. Benzene
38. In electrochemical series reduction potential relates to only
A. Real Conditions
B. Standard Conditions
C. Positive Values
D. Negative Values
39. Why aldehydes are more reactive than ketones?
A. Electronic reasons
B. Steric hindrance
C. Both a and b
D. None of these
40. Which of the following is not a derivative of carboxylic acid?
A. Alkyl Halide
B. Acetamide
C. Ester
D. Anhydride
41. When we react an active metal like Al with less active element like Cu ,it will form
A. Dry cell
B. Galvanic cell
C. Electrolytic cell
D. A and B
42. Nitrates of which pair of elements gives different products on thermal decomposition?
A. Na, K
B. Mg, Ca
C. Li ,Na
D. Li ,Ca
43. What is the hybridization state of carbon in benzene?
A. sp²
B. sp³
C. sp
D. All of these
44. If a double bond is present between two carbons then this class of compounds in called as______?
A. Alkanes
B. Alkynes
C. Carbonyl
D. Alkenes
45. Slope of the curve can be determined by
A. Area under the curve
B. calculating length of curve
C. Drawing a tangent to the curve
D. All of these
46. Which of the following bond has highest bond energy value ?
A. C-I
B. C-H
C. C-Cl
D. C-F
47. Which one of the following is the correct value for the enthalpy of formation of CO?
A. -110kJ/mol
B. -210kJ/mol
C. -111kJ/mol
D. None of these
48. Calculate mass in grams of 8.694 moles of Ag2CO3
A. 1417.53g
B. 2399.544g
C. 3456.78g
D. 1231.98g
49. Which of the following test can detect presence of both Aldehydes and ketones ?
A. Tollen's test
B. Reaction with hydrazine
C. Reaction with 2,4-dinitrophenylhydrazine
D. Reaction with Ammonia
50. At Mount Everest what would be the boiling point of water?
A. 100℃
B. 69℃
C. 98℃
D. 102℃
CHEMISTRY >> Solids
51. The identical number of layers in cubic and hexagonal closest packing are
A. First three
B. first two
C. only one
D. first four
52. Flavour of Orange is due to the presence of _______ester?
A. Benzyl acetate
B. Octyl Acetate
C. Amyl Butyrate
D. Ethyl butyrate
53. Half-life period for a first order reaction is independent of
D. All of these
54. The alcohols which are resistant to oxidation reactions are
A. primary alcohols
C. tertiary alcohol
D. all of above
55. in groups, the removal of electrons from valence shell is easy due to
A. addition of electrons
B. addition of shells
C. increase in nuclear charge
D. strong attractive forces
CHEMISTRY >> Gases
56. Kinetic molecular theory was proposed by
A. Berzelius
B. Boltzmann
C. Bernoulli
D. Maxwell
(PMC PAID TEST-32)
125.After digestion proteins change into:
A. Amino acids
B. Starch
C. Glycogen
D. Lipids
126.Which of the following are product of following reaction in the presence of sunlight? CH₄ + Cl₂→ ?
A. CHCl₃
B. CCl₄
C. CH₂Cl₂,CH₃Cl
D. All of these
127.Which one is not member of Alkali metals?
A. Na
B. K
C. Cs
D. Mg
128.Liquids have_________?
A. Definite shape
B. Indefinite shape
C. Definite volume
D. None of these
129.Standard electrode Potential is denoted by
A. E
B. E^-1
C. E^0
D. ∂
130.The mass of one mole of electron is
A. 1.8mg
B. 0.184mg
C. 0.55 mg
D. 0.64 mg
CHEMISTRY >> Solids
131.Atoms in solids are
A. Loosely Packed
B. In random motion
C. Excited
D. Closely packed
132.Specific Rate constant changes its value with
A. Time Constant
133.The product of the nucleophilic addition of aldehyde and ketones is called as_____?
A. Alkanolone
B. Adduct
C. Cyanohydrin
D. Nucleophilic product
134.During bond formation d orbitals splits into _____of orbitals ?
A. 3 sets
B. 4 sets
C. 5 sets
D. 2 sets
135.The compounds having -COOH group are called as_______?
A. Aldehydes
B. Ketones
C. Carboxylic acids
D. Alcohols
CHEMISTRY >> Gases
136.In Charles's Law, volume of gas is directly related to which factor?
A. Pressure
B. Temperature
C. Volume
D. Number of moles
137.Which phenol is most acidic in nature
A. salicylic acid
B. picric acid
C. cresol
D. O - nitrophenol
138.In oxidation number method of Balancing the first step is to write
A. Oxidation number on Reactants
B. Oxidation number on products
C. Oxidation number for both reactants & Products
D. None of these
139.Which one of the following is most reactive ?
A. Benzene
B. Ethane
C. Ethene
D. Ethyne
140.Urease in present in:
A. Yeast
B. Grapes
C. Soya sauce
D. Soya bean
141.Which of the following is typical transition element?
A. Zn
B. Cd
C. Cu
D. Hg
142.Rate of reaction can be studied graphically by plotting time and
A. temperature
B. Concentration
C. Pressure
143. While calculating vapor pressure of a liquid in manometer, the column of mercury facing the vapors
of a liquid is _____due to pressure on surface of liquid in flask
A. compressed
B. depressed
C. rises
D. lowers
144.the tendency of of an atom to attract a shared electron pair towards itself is called
D. polarity
145.Which one is the major product when ethene react with Br2 in H₂O?
A. Dibromoethane
B. Bromoethane
C. Hydroxy Bromoethane
D. Hydroxy Bromoethane
146.Which one of the following is a strong acid ?
A. HF
B. HI
C. HBr
D. HI
CHEMISTRY >> Solids
147.which one of them can conduct electricity in solid state
A. diamond
B. graphite
C. Nail
D. iodine
148.An atom or group of atom that gives specific properties to the Compound is called as_____?
A. Functional groups
B. Homologous series
C. Alkane
D. Atoms
149.On reacting with which of the following carboxylic acids produce CO₂?
A. Carbonate
B. Bicarbonate
C. Bisulphites
D. Both a and b
A. chlorine
B. Ammonia
C. water
D. hydrochloric acid
151.80% of the coal is used in________?
A. lime kiln
B. Domestic purposes
C. Fuel
D. Motor bikes
152.Which of the following Compound is not reduced by NaBH₄ ?
A. Acetaldehyde
B. Acetone
C. Carboxylic acid
D. Alkene
CHEMISTRY >> Solids
153.The atomic ratio of isomorphs of ZnSO4, and NiSO4 is
A. 2:1
B. 2:01:04
C. 1:01:04
D. 1:1
154.Acetic acid is also named as______?
A. Propanoic acid
B. Butanoic acid
C. Ethanoic acid
D. Methanoic acid
155.The formula for calculating electron in subshells or sub energy levels is
A. 2l+1
B. 2(l+1)
C. 2(2l+1)
D. 2(2l-1)
156.Nucleoprotein are______ proteins which transfer heredity information from one generation to other.
C. Genetic proteins
157.Oxidation Number can be
A. Positive
B. zero
C. Negative
D. All of these
158.What are the products of destructive distillation of coal?
A. Coal tar
B. Coke
C. Coal gas
D. All of above
159.Which of the following enzymes present in yeast helps out in fermentation
A. Diastase
B. Maltase
C. Zymase
D. all of above
160.Which of the following is typical transition metal?
A. Sc
B. Y
C. Cd
D. Co
161.There is one lone pair present in H₃O⁺, it cannot act as_____?
A. Electrophile
B. Lewis acid
C. Nucleophile
D. Strong acid
162.During SN₁ mechanism, nucleophile can attack on the halogen carbon?
C. From both sides
D. None of these
163.Quantum numbers are set of numerical values which give solution to the equation
A. planks
B. Heisenberg
C. Schrödinger
D. all of these
164.Heat of a solution for the substance whose solubility decrease with increase in temperature is
A. Positive
B. Zero
C. High
D. Negative
165.Protein part attached with non-protein part in enzymes belongs to which class of proteins?
A. Simple
B. Conjugated/compound
C. Derived
D. All of these
166.The increase in atomic radii in _-----is due to increase in the number of shells and the screening effect
A. groups
B. periods
C. both A & B
D. none of these
CHEMISTRY >> Solids
167.Which of the following is an Isomorph of Copper
A. Zn
B. Cd
C. Ag
D. Mn
168.Hydrogenation of alkenes takes place in the presence of____?
A. Nickel
B. Gold
C. Palladium
D. Raney Nickel
169.Which of the following reaction takes place when alkyl halide react with KOH in water ?
D. None of these
170.Which one of the following pairs shown the diagonal relationship in the periodic table?
171.number of isomers of C4H1 is:
A. 2
B. 4
C. 6
D. 5
172.The molecules like CH4,CCl4 or SiH4 show attitude of non-polarity due to
A. structure
B. symmetry of structure
C. nature of structure
D. charges on structure
CHEMISTRY >> Solids
173.Percentage of free space in a body centered cubic unit cell is
A. 32
B. 34
C. 28
D. 3
174.What is the enthalpy of solution of NH4Cl?
A. 15 Kj/mol
B. -17kJ/mol
C. 16.2 kJ/mol
D. -16.5kJ/mol
175. In Which of the following reaction of carboxylic acids only C=O group involved in bonding and OH
group is replaced ?
176.S-S bond is present in which of the ion pairs
A. S2O72-, S2O32-
B. S4O62-, S2O72-
C. S2O72-, S2O82-
D. S4O62-, S2O32-
177.Which of the following is formed during SN₁ reactions?
178.A molecule of water has two bond, so 1 mole of water will contain ____moles of bonds
A. 1
B. 2
C. 3
D. 4
179.Drawing a graph between concentration change with time gives a
A. Straight line
B. parabola
C. Curve
D. Scattered graph
180.Activator of carbonic anhydrase enzyme is_____.
A. Mn²⁺
B. Mg²⁺
C. Zn²⁺
D. None of these
(PMC PAID TEST-33)
125.Acetic acid derived from the word 'Acetum' which means_______?
A. Acetic acid
B. Bitter
C. Citric
D. Vinegar
126.The classification of monohydric alcohols is due to
A. hydrogen atom
B. carbon atom
C. hydroxyl group
D. carbonyl group
127.Which alkyl halide give SN₂ reactions?
A. Secondary
B. Primary
C. Tertiary
D. All of these
128. The specific site at which substrate is attached on the enzyme and converted into product is called
as___?
A. Reaction site
B. Active site
C. Binding site
D. None of these
129.During bond formation d orbitals splits into _____of orbitals ?
A. 3 sets
B. 4 sets
C. 5 sets
D. 2 sets
CHEMISTRY >> Solids
130.Number of Electron in Na+ Ion are
A. 11
B. 9
C. 10
D. 12
131.In general, atomic radii decreases from left to right in a period, due to increase in
A. number of shells
B. nuclear charge
C. shielding effect
D. bond length
132.Compounds having C and H atoms and their derivatives are called as_____?
A. Inorganic compounds
B. Organic compounds
C. Biochemical compounds
D. Carbohydrates
133. The equation En=-2.17x1 -18 [1/n2] J gives the energy associated with electron in nth orbit of
hydrogen atom. Its negative sign shows that electron is
A. away from nucleus
B. bound by nucleus
C. closer to nucleus
D. all of these
134.In the rate equation R=k[A]â [B]^b, a and b as exponents decides
135.Nucleophilic addition reactions of carbonyl compounds can be catalyzed by____?
A. Acid
B. Base
C. Water
136.Oxidation number of an ion with single element is same as
A. Ionic radius
B. Charge on Ion
C. Number of electrons in ion
D. Number of protons in ion
137.The second ionization potential of alkali metals are very high due to
A. Being s-block elements
B. Inert gas configurations
C. ns1 electronic configuration
D. Being metals
138.In a voltaic cell ,two half cells actually separates
A. Two electrolytes
B. Anode and Cathode
C. Oxidation Half cell and Reduction half Cell
D. All of these
139.Which of the following compound shows strong H-Bonding with water?
A. C₂H₆
B. CH₃Br
C. CH₃OCH₃
D. C₂H₅OH
140.Cyclic compounds consist of except?
A. Alicyclic
B. Aromatic
141.The ionization energy increases from left to right in a period due to increase in
A. nuclear charge
C. atomic number
D. all of these
142.When a nucleophilic reagent attacks on alcohols
A. C - O bond breaks
C. increase in acidity
D. Dehydration occurs
143.Falling water of a waterfall is an example of
A. Reversible Reaction
B. Spontaneous Reactions
C. Endothermic Reactions
D. All of these
144.Which of the following causes the inactivation of enzymes ________?
A. Concentration of substrate
B. Optimum temperature
C. Beta radiation
D. Optimum pH
145.Nitrogen N2 has ____number of electrons, protons and neutrons
A. 7,8,9
B. 7,7,7
C. 14,14,14
D. 14,14,15
146.The number of reacting molecules which changes their concentration in chemical change is called
A. Extent of a Reaction
B. Order of a Reaction
C. Specific rate of a reaction
D. Enthalpy of reaction
CHEMISTRY >> Solids
147.Ice is an example of
A. Polar Molecular Solid
B. Non-Polar Molecular Solid
C. Ionic Solid
D. Covalent Solid
148.Enthalpy of a system is given as____?
A. ΔH= qv+ w
B. H=E + PV
C. H=qp + PV
D. H= E
149.Ionization energies of atoms depends upon the factors
A. atomic radius of atoms
B. nature of orbital
C. shielding effect of inner electrons
D. all of these
CHEMISTRY >> Solids
150.An example of nonpolar molecular crystal is
A. Ice
B. Iodine
C. Sugar
D. Salt
151.Which product is obtained by Distillation of calcium acetate ?
A. Acetone
B. Acetaldehyde
C. Formaldehyde
D. Carboxylic acid
152.The simplest member of organic compounds is?
A. Methanol
B. Methane
C. Formaldehyde
D. Formic acid
153.Reduction of carboxylic acids into alkanes in the presence of HI/P, COOH is reduced to_____?
A. CH₄
B. C₂H₆
C. CH₂
D. None of these
154.In a carboxylic acid dimer how many H-bonds are present ?
A. Three
B. Two
C. Five
D. One
155.Human body contains _________kind of proteins ?
A. 60000
B. Almost 10000
C. 5000
D. 200
156.Alkyl iodides can not be prepared directly by the halogenation of alkanes because ?
A. Iodine reacts slowly
B. Iodine reacts reversibly
C. HI formed reduces alkyl iodide again to starting material
D. All of these
157.Reaction intermediate
A. Cannot be Separated from reaction mixture
B. Contain normal bonds
C. can be isolated from reaction mixture
D. Both B and C
Q 158. Empirical formula of glucose C6H12O6 is same with
A. acetaldehyde
B. formaldehyde
C. ethanol
D. acetone
159.Which of the following are weakest intermolecular forces ?
B. Debye forces
D. H-bonding
160.All the halogens are ______diatomic molecules
A. polar
B. non polar
C. reactive
D. non reactive
161.What is the hybridization state of carbon in benzene?
A. sp²
B. sp³
C. sp
D. All of these
162.80% of ammonia produced by Haber’s process is used in manufacturing
A. Explosives
B. polymers
C. fertilizers
D. All of these
163.Which of the following is protein digesting enzyme?
A. Trypsin
B. Pepsin
C. Protease
D. All of these
164.Which one of the following pairs shown the diagonal relationship in the periodic table?
165.Order of discharge of ions depends upon
A. Their temperature
B. Their concentration
C. Their Activation Energy
D. All of these
166.Hardness of transition metals is due to_______?
A. More melting point
B. More electrons
C. Variable oxidation state
D. Higher binding energies
167.According to VSEPR theory ,the repulsions are called
A. joule repulsion
B. planks repulsion
C. Van der waals repulsion
D. J.J.Thomson repulsion
CHEMISTRY >> Solids
168.The molecules of CO2 in dry ice form
B. ionic crystals
C. metallic crystals
D. molecular crystals
169.Grignard reagent is produced by the reaction of Alkyl halides with_______?
A. Ca in anhydrous ether
B. Mg in dry ether
C. Mg in hydrous ether
D. Ca in dry ether
170.The peaks forms in a mass spectrograph shows number of __________ of an element
A. electrons
B. isotopes
C. protons
D. neutrons
171.Benzene molecule contains:
A. Three triple bonds
B. Two double bonds
C. Three double bonds
D. No multiband
172.If n = 4 then what can be value of 'magnetic quantum number
A. 4,3,2,1
B. 3,2,1
C. infinity
D. none of these
173.When C -O bond breaks in alcohol, the most reactive is
C. tertiary alcohol
D. methanol
C. Both A and B
176. Among halogens iodine is solid at room temperature while Br2 is liquid and Cl.F are gases at room
temperature, why?
A. Due to stronger dipole forces
B. Due to polarity
C. Due to stronger London forces
D. Due to stronger Debye forces
177.Aldehydes and ketones react with hydroxyl amine and produce?
A. Imine
B. Oxime
C. Aldole
D. Nitrile
178.Tetra ethyl addition to petrol is example of:
C. Both a & b
D. None
179.∆Hf֯ of which of the following can not be measured directly?
A. Al₂O₃
B. B₂O₃
C. CO
D. All of these
CHEMISTRY >> Gases
180.Number of molecules in one dm3 of water will be almost
A. 18x6.02x10^23
B. 55.6x6.022x10^23
C. 18x6.2x10^23
D. 2x6.2x10^23
(PMC PAID TEST-34)
CHEMISTRY >> Solids
1. Crystallites are a part of
A. Ores
B. Crystalline Solids
C. Amorphous Solids
D. None of these.
CHEMISTRY >> Gases
2. The unit for pressure used in engineering work is
A. torr
B. atm
C. pounds per square inch
D. Nm-2
3. Enthalpy change of solution of Na2CO3 is a _______reaction?
A. Exothermic reaction
B. Endothermic reaction
C. Spontaneous reaction D. nonspontaneous reaction
4. The forces present between the molecules are called as ?
A. Chemical bond
B. Intermolecular forces
C. Intra molecular forces
D. Strong forces
A. oval
B. elliptical
C. cylindrical
D. circular
D. None of these
7. What is the order of SN₂ reactions?
A. 1st order
B. zero order
C. 2nd order
D. 3rd order
A. Class
B. Group
D. None of these
9. Alkanes are called as______?
A. Olefines
B. Paraffins
C. Reactive
D. All of these
10. The word Alkali means
A. Base
B. Basic salt
C. Ashes
D. Spirit
11. Pure metal
A. Corrode slowly
C. Corrode rapidly
D. None of these
12. The substance that is attached to the enzyme at specific place and converted into product is called as?
A. Co-factor
B. Iso-zyme
C. Active site
D. Substrate
13. An atom or group of atom that gives specific properties to the Compound is called as_____?
A. Functional groups
B. Homologous series
C. Alkane
D. Atoms
CHEMISTRY >> Solids
14. An example of nonpolar molecular crystal is
A. Ice
B. Iodine
C. Sugar
D. Salt
CHEMISTRY >> Solids
15. Energy in formation of a crystal lattice is
A. Absorbed
B. Released
C. Dependent on Crystal Size
D. None of these
16. Denaturing of protein is ______ process.
A. Reversible
B. Irreversible
C. Equilibrium
D. all of these
17. Which one of the following is not the property of a system?
A. Enthalpy
B. Internal energy
C. Thermal energy
D. Temperature
18. Which of the following forces has ability to form clusters and large molecules?
A. Ionic bond
C. H-bond
D. All of these
19. According to Le chatelier's Principle Exothermic reactions are favored by
A. Increase in Pressure
B. Increase in Volume
C. decrease in Temperature
D. All of these
20. On which of the following factors Hydration Energy depend?
A. Charge to size ratio
B. Polarizability of anions
C. Polarization power of Cations
D. All of these
21. In the addition of sodium bisulfite to carbonyl system, which of the following is nucleophile?
A. Sulphide ion
B. Sulfite ion
C. Hydride ion
D. Sodium ion
22. Phenol gives electrophilic substitution reactions due to?
A. OH group
B. Phenoxide ion
C. Benzene ring
D. All of these
23. The minimum amount of energy required to remove an electron from its gaseous atom to form an ion
is known as
D. potential energy
CHEMITRY >> Alcohol and Phenols
24. Which isomer of hydroxy benzene sulphonic acid is formed in greater ratio when phenol reacts with
sulphuric acid at 20 ℃?
A. Ortho
B. Para
C. Both ortho and para in equal ratio
D. ortho-para product
25. What does thermodynamics means?
A. Study of change in state of the system
B. Study of energy changes during a process
C. Study of material content of a system
D. All of these
26. Isoenzymes comes from_____?
A. Same sources
B. Different organisms
C. Same organisms
D. None of these
27. Which of the following catalyst is used for the preparation of acidic anhydrides ?
A. K₂Cr₂O₇
B. P₂O₅
C. H+/H₂O
D. H₂SO₄
CHEMISTRY >> Gases
28. One atmosphere is the force of ______long column of mercury on an area of 1cm2 at c
A. 76cm
B. 76mm
C. 76dm
D. 76pm
29. The most electropositive element among the following is:
A. Li
B. Ca
C. Cs
D. Ca
30. Which one of the following is the formula of stearic acid?
C. C₇H₃COOH
31. The maximum probability of finding an electron is at distance of
A. 0.53mm
B. 0.53nm
C. 0.153nm
D. 1.53mm
32. Which one of the following is larger in size than oxygen atom______?
A. Fluorine
B. Nitrogen
C. Hydrogen
D. Neon
33. The platinum in SHE act as a
A. Buffer
B. Salt Bridge
C. Electrical Conductor
D. All of these
34. The formation of negative ion is a/an ____process
A. exothermic
B. endothermic
C. both A & B
D. none of these
35. Greater heat of vapourization of water is due to the presence of which forces?
A. H-bonding
C. Polar covalent bond
D. All of these
36. Which of the following isomerism is shown by alkynes?
A. Positional isomerism
B. Geometrical isomerism
C. Cis-trans isomerism
D. All of these
38. Decrease in Oxidation number is
A. Oxidation
B. Reduction
C. Both A and B
D. None of these
39. How phenol is produced from the Chlorobenzene ?
A. Using Kolb's method
B. Using Dow's method
C. Using Zn dust
D. All of these
40. Formamint is made up of_________?
A. Formaldehyde + maltose
B. Formaldehyde + lactose
C. Formaldehyde + Galactose
D. Formaldehyde + fructose
41. The energy released during the formation of crystal lattice of KCl is
A. 39 KJ/mol
B. 49 KJ/mol
C. 59 KJ/mol
D. 69 KJ/mol
42. Which of the following properties belong to acetic acid?
A. colourless liquid, odourless, sour taste
B. bright colour bitter taste
C. colourless solid, sour taste, pungent smell
D. all are incorrect
CHEMISTRY >> Solids
43. which one of them can conduct electricity in solid state
A. diamond
B. graphite
C. Nail
D. iodine
44. Tetra ethyl addition to petrol is example of:
C. Both a & b
D. None
45. which of the following does not have sp2 hybridized orbital
A. acetone
B. acetonitrile
C. acetic acid
D. acetamide
46. The slope determined by drawing a right angled triangle drawn with tangent as hypotenuse will be
same:
D. All of these
47. Calcium carbide is prepared by heating lime with coke at
A. 25 °C
B. 26 °C
C. 27 °C
D. 28 °C
CHEMISTRY >> Solids
48. Sodium metal shows metallic luster is explained by
A. diffusion of Na+
B. oscillation of loose electrons
C. excitation of free protons
D. strong crystal lattice
49. In some cases during atomic orbital hybridization, ground state electrons promoted to excited states
, as a result __increases
A. number of shells
C. number of unpaired electrons
D. number of bonds
50. What is the boiling point of Glycerine at 1 atm?
A. 280℃
B. 150℃
C. 290℃
D. 110℃
CHEMISTRY >> Gases
51. The rate of diffusion of a gas having molar mass 32 as compared to H2 gas will be
A. 6 times
B. 4 times
C. one fourth
D. one eighth
52. A compound has an empirical (simple) formula, C2H2O. If the experimental molecular weight is found
to be in the range 16 -17 , the molecular formula of this compound is: (Atomic wt.: C = 12. 1, H = 1. 8,
O = 16. )
A. C3H6O3
B. C4H4O2
C. C8H8O4
D. C6H6O3
53. By which of the following way acetamide can be prepared?
A. Hydrolysis of ethyl chloride
B. Heating methyl cyanide
C. Heating ammonium acetate
D. Heating ethyl acetate
54. Kp=Kc (RT)^Δn , T stands for
A. Temperature
B. Absolute Temperature
C. Critical Temperature
D. All of these
55. Which of the following is true about arenes?
A. Low melting, and low boiling points
B. High melting, and high boiling points
C. Low melting, and high boiling points
D. High solubility in polar solvents
56. According to________ theory, atoms were the ultimate particles that cannot be divided further.
A. Bohr's
B. Rutherford's
C. Dalton's
D. cannizzaro's
(PMC PAID TEST-35)
69. The force which holds the atoms within the molecule is called as_____?
A. Intermolecular force
B. Chemical bond
C. London force
D. Polar force
70. According to vital force theory organic compounds were only produce in_________?
A. Animals
B. Plants
C. Bacteria
D. All of these
71. Organic compounds that are considered as derivatives of water are
A. Aldehydes & ketones
B. Alcohols and phenols
C. Phenols and ethers
D. Carboxylic acids
CHEMISTRY >> Gases
72. when sudden expansion of gases takes place, cooling occurs. This is called
A. freezing effect
B. Joule Thomson effect
C. Boyles effect
D. J.Perrin effect
73. Specific Rate constant changes its value with
A. Time Constant
CHEMISTRY >> Solids
74. Classification of Solids is based upon the arrangement of
A. Molecules
B. Atoms
C. Ions
D. All of these
75. Standard electrode Potential is denoted by
A. E
B. E^-1
C. E^0
D. ∂
76. Albumin is present in____?
A. Milk
B. Eggs
C. Beans
D. Muscles
77. What is the nature of Carbon present in Aldehyde is?
A. Nucleophilic
B. Electrophilic
C. Neutral
D. all of these
D. None of these
79. According to VBT, the essential condition for chemical bonding is that the orbitals of atoms participating in
bond formation must
A. added
B. multiply
C. overlap
D. divide
80. Which of the following carboxylic acid is used as solvent in the labs ?
A. Butanoic acid
B. Hexanedioic acid
C. Phthalic acid
D. Acetic acid
81. The mass of one mole of electron is
A. 1.8mg
B. 0.184mg
C. 0.55 mg
D. 0.64 mg
82. The compounds which are formed by the replacement of a hydrogen atom by a halogen is called
as___?
A. Alcohol
B. Alkyl halide
C. Carbonyl halide
D. Ethers
83. The reaction in which one of the group of a compound is replaced by another group of atoms is
called as______?
A. Substitution
B. Elimination
C. Addition
D. Condensation
84. Density of ice is_________?
A. Higher than water
B. Lower than water
C. Similar to water
D. Higher the 1.59/cm 3
CHEMISTRY >> Solids
85. when water freezes to ice, it occupies ___ more space
A. 0.9 g/cm^3
B. 0.1 g/cm^3
C. 0.12 g/cm^3
D. 0.13 g/cm^3
A. 2-Chloropropane
B. 3-Bromobutane
A. 2-Chloropropane
B. 3-Bromobutane
87. In IUPAC nomenclature, Carboxylic acids are named as_______?
A. Alkoxy acid
B. Alkanoic acid
C. Alkyl carboxylic acid
D. Alkoxylate acid
88. The group formed by removal of one H atom from the benzene ring is called as__________?
A. Alkyl group
B. Benzyl group
C. Phenyl group
D. Ethyl group
CHEMISTRY >> Gases
89. Charles's law is not being obeyed when temperature is measured on Celsius scale. Thatâ€™s why
new scale called______ has been developed
A. zero Fahrenheit
B. zero Kelvin
C. absolute Fahrenheit
D. all of these
90. When we move from left to right in transition elements, the decrease is ___due to intervening electrons
A. large
B. very large
C. small
D. very small
CHEMISTRY >> Gases
91. PV/nRT for an ideal gas is called
A. expansion factor
B. depression factor
C. compressibility factor
D. diffusion factor
92. With impurities like P and S the open hearth furnace is lined with
A. SiO2
B. Fe2O3
C. FeO
D. CaO, MgO
93. What will be the value of work done at constant pressure in a pressure-volume system?
A. w=PV
B. w=ΔPV
C. w=PΔV
D. w=P + ΔV
94. Evaporation of water is an example of?
A. Endothermic reaction
B. Exothermic reaction
D. Chemical; reaction
95. The amount of heat required to form vapors of one mole of a liquid at its boiling point is called as?
A. Molar heat of fusion
B. Molar heat of vapourization
C. Molar heat of sublimation
D. Molar heat of Evaporation
96. In a homologous series, adjacent members differ by a ______unit?
A. CH₃
B. CH₂
C. CH
D. CH₄
98. 1 amu is equal to
A. ..666x1 -27kg
B. 1.661x1 28kg
C. 1.661x1 27kg
D. 1.661x1 -27 kg
99. Which of the following solvent favor SN₂ reactions?
A. Water
B. Ammonia
D. Acetic acid
100.The ionization energy of group __shows abnormal trend
A. 3A & 4A
B. 5.A & 6A
C. 6A & 4A
D. 3A & 6A
101.The unit of electron affinity is
A. J/mol
B. KJ/mol
C. KJ/atom
D. J/atom
103.What is the color of silver acetylide, AgCΞCAg ?
A. Red
B. White
C. Brown
D. Pinkish
104. Globulins protein upon hydrolysis yield amino acids or their derivatives, so they belong to which type of
protein:
A. Derived proteins
B. Compound proteins
D. Simple proteins
105. Which of the following is used as disinfectant?
A. Phenylhydrazone
B. Phenol
C. Acetic acid
D. Vinegar
106. In a carboxylic acid dimer how many H-bonds are present ?
A. Three
B. Two
C. Five
D. One
107.Formaldehyde is used in vat dyeing as?
A. Coloring agent
B. Dehydrating agents
C. Decolorizing agent
D. Solubilizing agent
108.In the reaction of NaBH₄ with aldehyde and ketones, which of the following act as Nucleophile ?
A. B⁻
B. H⁻
C. BH₂⁻
D. NaBH₃⁻
109.Electrolysis is carried out in
A. A beaker
B. Flask
C. Evaporating Dish
D. Electrolytic Cell
110.More energy to remove an electron from_______?
A. Half filled subshell
B. Completely Filled Subshell
C. Partially filled subshell
D. Both a and b
111.In SN₂ reaction, which of the following specie is formed?
A. Transition state
B. Intermediate
C. Carbocation
D. Carbanion
112.Which of the following is correct about octane number?
A. Higher the octane number,higher will be knocking
B. Higher the octane number, efficiency of fuel will be lower
C. Higher the octane number, lower the knocking
D. Lower the octane number, lower the knocking
113.As Reaction proceeds the concentration of reactants
A. decreases
B. Remain unchanged
C. increases
D. cannot be predicted
114.Which one of the following is the formula of stearic acid?
C. C₇H₃COOH
115.During base catalyzed reactions, which property of nucleophile increases?
A. Basicity
B. Nucleophilicity
C. Electrophilicity
D. Both b and c
116.Half-life period for a first order reaction is independent of
D. All of these
117.Energy change is governed by
A. Heat
B. Work
C. Enthalpy
D. None of these
118.Tertiary alcohols can change into alkenes by
A. combustion reaction
B. oxidation
C. elimination reaction
D. addition reaction
119.Which of the following alkyl halide is most reactive towards Mg atom?
A. Alkyl bromide
B. Alkyl fluoride
C. Alkyl chloride
D. Alkyl iodide
120.2-hydroxy propanoic acid is also called as_____?
A. Stearic acid
B. Butyric acid
C. Maleic acid
D. Lactic acid
C. Both A and B
122.Enzymes which bring about exchange of functional group is called_____.
A. Oxidoreductase
B. Hydrolases
C. Ligases
D. Transferases
123.which of the following has neither secondary nor tertiary hydrogen
A. isobutane
B. pentane
C. neo-pentane
D. isopentane
124.Higher order reactions has half-life
D. None of these
(PMC PAID TEST-36)
125. Which of the following is weaker acid?
A. HCl
B. H₂SO₄
C. CH₃COOH
D. H3PO4
126. Liquids have_________?
A. Definite shape
B. Indefinite shape
C. Definite volume
D. None of these
127. Fossil fuels are produced due to_______?
A. Fast decomposition of organic matter
B. Decomposition of plants
C. Decomposition of animals
D. Biochemical decomposition of dead organic matter
A. Amino acids
B. Starch
C. Glycogen
D. Lipids
129. The equilibrium Constant is always written as a ratio of
A. Reactants over products
B. Products over reactants
C. Product times Reactants
D. None of these
130. Melting and boiling point of transition elements is higher due to________?
A. Higher binding energies
B. Strong metallic bonding
C. Hardness
D. All of these
131. How many resonance structures of benzene are possible?
A. 2
B. 3
C. 6
D. 4
132. The difference in the E.N values of the bonded atoms b/w two atoms is an index to __of
covalent bond
A. polar nature
B. non-polar nature
C. strength
D. nature
A. oval
B. elliptical
C. cylindrical
D. circular
134. The change in concentration of reactants or products per unit time is
A. rate constant
B. reaction speed
D. All of these
135. The reactions that release heat are called as__________?
C. Endergonic reactions
D. Heat gaining reactions
CHEMISTRY >> Solids
136. Definite Shape of NaCl crystal is its
A. Characteristic
B. Symmetry
C. Habit
D. All of these
137. Aldol condensation takes place in the presence of ____?
A. H₂SO₄
B. K₂Cr₂O₇
C. NaOH
D. H₂O/H+
138. What is the reason for the reactivity of Grignard reagent?
A. Presence of Mg atom
B. Polarity of C-H bond
C. Polarity of C-Mg bond
D. Presence of electrophilic carbon
139. The bond formed by the complete transfer of electron is called
A. ionic bond
B. covalent bond
C. metallic bond
D. polar covalent bond
140. Which of the following is a Unsaturated fatty acid?
A. Palmitic acid
B. Stearic acid
C. Oleic acid
D. Ethanoic acid
141. What is the common name of the compound? CH₃-(CH₂)₂-CH₂-Cl
A. Chlorobutane
B. Chloropentane
C. n-Chloropentane
D. n-pentyl chloride
E. 1-chloropentane
142. Which one of the following pairs shown the diagonal relationship in the periodic table?
143. In the production of wrought iron Mg Si and P are removed in the form of
A. Oxides
B. Silicates
C. Slag
D. Carbonates
144. Aldehydes are converted into _______when undergoes Wolff Kishner reduction?
A. Alkenes
B. Alkanes
C. Alkynes
D. Alcohols
145. Electrons in a Voltaic Cell flow from
A. Cathode to Anode
B. Anode to Cathode
C. Right to left
D. None of these
146. Unit for rate of reaction is
A. Mole / litre
B. Moles / gram
C. Moles / Second
D. moles/dm^3 s^-1
147. Which of the following is directional bond?
A. Ionic bond
B. Metallic bond
C. H-bond
D. None of these
148. Who proved that no Vital Force theory is involved I synthesis of organic compounds?
A. Lewis
B. Wohler
C. Greek Philosophers
D. Berzillus
149. In chemical combination of H-atom with sodium. It gains an electron but in case of HF,H-atom
A. gains 2 e-
B. lose 1e-
C. lose 2e-
D. gain 2e-
150. a photon of wavelength 1 2.7 x1 5 m-1 is emitted when it jump from higher to n = 1,what will
be higher orbit
A. n = 2
B. n = 3
C. n = 4
D. n = 5
151. Ketones can be oxidized by ______?
A. Dil.HNO₃
B. Tollen's reagent
C. Benedict reagent
D. Fehling's reagent
152. Presence of Process of diffusion in liquids is due to________?
A. Definite volume
B. Strong intermolecular forces
C. Smaller distance
D. Constant motion
CHEMISTRY >> Gases
153. In Boyle's law, the relationship between pressure and volume is
C. constant
D. none of these
A. Amylase
B. Urease
C. Pectin
D. None
155. Most abundant protein in animals forming 25%-35% of body protein is which type of
protein?
A. Simple proteins
B. Conjugated proteins
C. Derived proteins
D. None
CHEMISTRY >> Solids
156. Crystalline Solids are made up of
A. Atoms
B. Molecules
C. Ions
D. All of these
157. The probability of finding an electron _________ even at large distances from the nucleus
A. becomes one
B. becomes zero
C. never becomes zero
D. varies from to 1
158. Which of the carboxylic acid is used in medicine as local irritant;
A. formic acid
B. acetic acid
C. benzoic acid
D. amino acid
159. On reacting with metals carboxylic acid produces which of the following products ?
A. Salt + water
B. Salt
C. Salt + H₂ gas
D. Salt + Alcohol
CHEMISTRY >> Gases
160. vapor pressure is measured by calculating difference in liquid pressure and
A. mercury pressure
B. glass pressure
C. atmospheric pressure
D. container pressure
161. Organic compounds in which tetravalency of carbon atom is satisfied are called as___?
A. Saturated
B. Unsaturated
C. Alkenes
D. Alkynes
162. When an electrophilic reagent attack on alcohol
A. O - H bond formed
C. C- O bond breaks
D. rise in boiling point
163. Which of the following compound is formed when NACl reacts with CH₃MgBr
A. CH₃CN
B. CH₃Cl
C. CH₃CH₂NH₂
D. None of these
164. a liquid crystalline state exist between two temperatures I-e melting temperature and
____temperature
A. boiling
B. freezing
C. clearing
D. all of these
165. The method used for preparation of phenol is
A. Kolbe's method
B. Dow's method
C. Nitration
D. Williamsons synthesis
166. In the addition of sodium bisulfite to carbonyl system, which of the following is
nucleophile?
A. Sulphide ion
B. Sulfite ion
C. Hydride ion
D. Sodium ion
167. Which of the following compounds are added to ethanol to make it unfit for drinking?
A. Pyridine
B. Methanol
C. Acetone
D. All of these
168. What is the pH of human blood?
A. 7.45
B. 7.35
C. 7
D. 7.53
169. 2 moles of octane ( C8H18) burns with 25 moles of oxygen (O2) and produced _____moles
of carbon dioxide along with 18 moles of water
A. 14
B. 16
C. 18
D. 2
170. At which temperature water has maximum density?
A. 2℃
B. 4℃
C. 0℃
D. <0℃
A. Ethanol
B. Methanol
C. Glycerol
D. Glycol
172. In one second if the concentration changes from 0.1 to 0.25 then the rate will be
D. 0.11Moles/dm3s-1
173. Half-life period for a first order reaction is independent of
D. All of these
174. When an electron jumps from n = 5 to n = 2 having wavenumber equal to 2.3 x 1 6 m-1. In
which spectral series will it fall?
A. Layman
B. Balmer
C. visible
D. infrared
175. What is the correct equation to find Heat of neutralization using glass calorimeter ?
A. q=m s ΔT
B. E=q m ΔT
C. E=m s ΔT
D. q=m c ΔT
176. If a certain atom gains electrons its oxidation number will be
A. Negative
B. Positive
C. zero
D. Unity
177. Which of the following does not contain COOH group?
A. Acetone
B. Propanoic acid
C. Formic acid
D. Picric acid
178. If in a solution of alkyl halide in a nonpolar solvent, base is added which of the following
reaction takes place?
A. SN₂
B. E₁
C. SN₁
D. E₂
179. Which of the following products are formed from cannizzaro reaction?
A. Aldol product
B. Alcohol and carboxylate salt
C. Alcohol and carboxylic acid
D. Unsaturated reaction
180. Which one of the following alkali metals forms only normal oxide when it reacts with O2?
A. Lithium
B. Sodium
C. Potassium
D. Rubidium

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PMC (PAID TEST - 01)

CHEMISTRY >> Solids

CHEMISTRY >> Chemistry of Hydrocarbons

(PMC PAID TEST-14)

PMC (PAID TEST - 16)

PMC (PAID TEST - 18)

CHEMISTRY >> Macromolecules

B. Reaction of carboxylic acids with Carbonate

D. Reaction of carboxylic acids with SOCl₂

CHEMISTRY >> Chemical Bonding

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