01 JEEMains 1

FIITJEE PRACTICE TEST PAPER
JEEMAINS PH1
1. 22.4 litre of H2S and 22.4 litre of SO2 both at STP are mixed together. The maximum amount
of sulphur precipitated as a result of chemical reaction is (S32)
(SO2 + H2S  S + H2O)
(A) 64 g (B) 23 g (C) 48 g (D) 96 g
2. Oxidation of Cu3P to CuSO4 and H3PO4 involve the loss of

(A) 5 electron (B) 8 electron (C) 3 electron (D) 11 electron
3. NaHC2O4 is neutralized by NaOH & also it is oxidized by KMnO4 (in acidic medium).
Equivalent wt is related to molecular wt (M) of NaHC2O4 in these two reaction respectively
are
M M
(A) M, M (B) 2 M, 2 M (C) ,M (D) M,
2 2
4. MnO4 oxidized X+n  XO2 in acidic medium. 2.68103 moles of X+n requires 1.61103
moles of MnO4. Value of n will be
(A) 0 (B) 1 (C) 2 (D) 3
5. 50 mL of a solution containing 1gm each of Na2CO3, NaHCO3 and NaOH was titrated with
1N–HCl. What will be the titre reading when only phenolphthalein is used as indicator?
(A) 45mL (B) 32.5mL (C) 24.5mL (D) 34.4mL
6. What volume strength of 100 ml H2O 2 required for complete reaction of 1.58 g of KMnO 4 in
acidic medium?
(A) 2.8 (B) 5.6 (C) 1.86 (D) 3.73
7. A solution of NaOH is prepared by dissolving 4.0 g of NaOH in 1 L of water. Calculate the

volume of the HCl gas at STP that will neutralize 50 mL of this solution
(A) 224 mL (B) 56 mL (C) 112 mL (D) 448 mL
8. onitrophenol can be easily steam distilled whereas pnitrophenol cannot be. This is
because of:
(A) strong intermolecular hydrogen bonding in onitrophenol
(B) strong intramolecular hydrogen bonding in onitrophenol
(C) strong intramolecular hydrogen bonding in pnitrophenol
(D) dipole moment of pnitrophenol is larger than that of onitrophenol
9. What is the compressibility factor(s) for two litres, 0.02 mole of a real gas at pressure of 0.1
atm. Assume the size of gas molecules is negligible.
[Given: RT=20L atm mol1 and a= 1000 L2 atm mol2]
(A) 2 (B) 1 (C) 0.5 (D) 0.01
10. A and B are two identical vessels. Vessel A contains 15 g of ethane(C2H6) at 298 K and 1
atm. Vessel B contains 75 g X2 gas at 400 K temperature & 2 atm pressure. The vapour
density of X2 is
(A) 75 (B) 150 (C) 37.5 (D) 50.33
11. The set representing the correct order of first ionization enthalpy is
(A) K > Na > Li (B) Be > Mg > Ca (C) B > C > N (D) Ge > Si > C
2
12. If the speed of electron in the Bohr’s first orbit of hydrogen atom is ‘a’, the speed of electron
in the third Bohr’s orbit is
(A) a/9 (B) a/3 (C) 3a (D) 9a
13. The number of radial nodes of 3s and 2p orbitals are respectively:

(A) 2, 0 (B) 0, 2 (C) 1, 2 (D) 2,1
14. What transition in the hydrogen spectrum would have the same wavelength as the Balmer
transition, n = 4 to n = 2 in the He+ spectrum?
(A) n = 4 to n = 2 (B) n = 3 to n = 2 (C) n = 3 to n = 1 (D) n = 2 to n = 1
15. A compound of vanadium has a magnetic moment () of 1.73 BM. If the vanadium ion in the
compound is present as Vx+, then, the value of x is?
(A) 1 (B) 2 (C) 3 (D) 4
16. The number of spectral lines that can be possible when electrons in 7th shell in hydrogen
atom return to 3rd shell
(A) 10 (B) 8 (C) 15 (D) 20
17. The total spin resulting from a d7 configuration is

(A) 1 (B) 2 (C) 5 2 (D) 3 2
18. Volume of He gas to diffuse in 20 sec is y 128 ml and 20 ml of O2 gas took 10 sec to
diffuse through the same orifice, at constant temperature and pressure. The value of y/2 is
(A) 3 (B) 5 (C) 7 (D) 9
19. Which of the following sets of quantum numbers is correct for an electron in 4forbital?
(A) n=4, l=3, m= + 4, s=+1/2 (B) n=4, l=4, m=4, s=1/2
(C) n=4, l=3, m=+1, s=+1/2 (D) n=3, l=2, m=2, s=+1/2
20. Calculate the % of free SO3 in an oleum that is labeled 118% H2SO4
(A) 40% (B) 60% (C) 80% (D) 85%
21. Which of the following arrangements of electrons is mostly likely to be stable? (z  30 for this
atom)
3d 4s 3d 4s
(A) (B)
3d 4s 3d 4s
(C) (D)
22. The probability of finding an electron in the dxy orbital is

(A) maximum at the nucleus
(B) the same on all the sides around the nucleus
(C) zero on the zaxis
(D) maximum in xz plane
23. 0.71 g of chlorine combines with certain weight of a metal giving 1.11 g of its chloride. The
equivalent weight of the metal is
(A) 40 (B) 20 (C) 80 (D) none of these
FIITJEE Ltd, East Delhi Centre, Roots Tower, 5th Floor, Laxmi Nagar District Centre,(Near Nirwan Vihar Metro Station), Delhi-92 Ph-43002500-501
3
24. This curve is for d–subshell. Then the principle
Radial Probability
quantum number is
(A) 2
(B) 6
(C) 5
(D) 4
25. Molecular mass of gas whose Maxwell probability curve for molecular speed given below is
fraction of
molecules
speed
RT
(A) 2 (B) 3 (C) 4 (D) 5
26. 25 ml of 12 N HCl and 50 ml of 10N H2SO4 and 40 mI of 5 N HNO3 were mixed together and
the volume of the mixture was made 1000 ml by adding H2O. The normality of H3O+ in the
resulting solution will be
(A) 1 N (B) 4 N (C) 3 N (D) 2 N
27. In which of the following compounds BF bond length is shortest?

(A) BF4 (B) BF3  NH3 (C) BF3 (D) BF3N(CH3)3
28. An element X has valence shell configuration ns2np1. The formula of its oxide is:
(A) XO3 (B) XO3 (C) X2O3 (C) X2O3
29. Number of waves in third Bohr’s orbit of hydrogen atom will be

(A) 3 (B) 6 (C) 9 (D) 12
30 Which of these gases will be most easily liquefied?

Gases van der Waals’ constant ‘a’
6 –2
A) CO2 p) 3.58 atm dm mol
B) CO q) 1.49 atm dm6 mol–2
C) NH3 r) 4.17 atm dm6 mol–2
D) SO2 s) 6.71 atm dm6 mol–2
(A) CO2 (B) CO
(C) NH3 (D) SO2
space for rough work
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FIITJEE PRACTICE TEST PAPER

2. Oxidation of Cu3P to CuSO4 and H3PO4 involve the loss of

7. A solution of NaOH is prepared by dissolving 4.0 g of NaOH in 1 L of water. Calculate the

13. The number of radial nodes of 3s and 2p orbitals are respectively:

17. The total spin resulting from a d7 configuration is

22. The probability of finding an electron in the dxy orbital is

27. In which of the following compounds BF bond length is shortest?

29. Number of waves in third Bohr’s orbit of hydrogen atom will be

30 Which of these gases will be most easily liquefied?

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