I - YEAR CHEMISTRY

TOP 10+ LAQ

TOTAL MARKS : 2 x 8 = 16

1. What are the postulates of Bohr’s Model of hydrogen atom? Discuss the importance of this
model to explain various series of line spectra in hydrogen atom.
2. What are the postulates of Bohr’s model of hydrogen atom? Write the limitations of Bohr’s
theory. Differentiate between emission and absorption spectra.
3. How are the quantum numbers n, l and ml arrived at? Explain the significance of these quantum
numbers.
4. Define atomic orbital. Explain the shapes of s,p,d orbitals with the help of diagrams.

5. What is periodic property? How the following properties vary in a group and a period?
Explain: (i) Atomic radius (ii) Electron gain enthalpy
(iii) Electro negativity (iv) Ionisation enthalpy
6. Define IE1 and IE2. Why is IE2 > IE1 for a given atom?
Discuss the factors that effect IE of an element.
7. Write an essay on s,p,d and f block elements.

8. What is hybridisation? Explain different types of hybridisation involving s and p orbitals.

9. Give an account of VSEPR Theory and its applications.
10. Given Molecular orbital Energy diagram of (a) N2 (b) O2.
Calculate the respective bond order. Write the magnetic nature of N2 and O2 molecules.

11. a) Describe the methods of prparation of ethane.

b) Explain the chemical properties of ethane with equations.
12. a) Describe 2 methods of preparaton of ethylene
b)Write the reactions fo ethylene with
i) Ozone ii) Hypohalous acid iii) Cold and dil.alk KMnO4 iv) O2
13. a) Give two methods of preparation of acetylene.
b) How does acetylene react with water and ozone?
14. a) How do we get benzene from acetylene? Give the corresponding equation.
b) Explain halogenation, alkylation, acylation, nitration and sulphonation of benzene.

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 TOP 25 SAQ

TOTAL MARKS : 6 x 4 = 24

1. Explain the structure of PCl5 molecule / sp3d hybridisation with an example.

2. Explain the structure of SF6 molecule / sp3d hybridisation with an exmaple.
3. Explain teh sturcture of Ethylene.
4. Explain the formaiton of coordinate covalent bond with example.
5. State Fajan’s rules iwth suitable examples.
6. Define dipole moment? Why the dipole moment of BF3 molecule is zero.

7. Give the important postulates of kinetic molecular theory of gases.

8. State and explain Graham’s law of diffusion.
9. Deduce (a) Boyle’s law (b) Charle’s law from kinetic gas equation
10. State Dalton’s law and derive Dalton’s law from kinetic gas equation.

11. State and explain “Hess law of constant heat summation” with example.
12. Define heat capacity? What are CP and CV ? Show that CP - CV = R.
13. State Le-Chatlier’s principle and apply the same to the following equilibrium
N2(g) + 3H2(g)  2NH3(g) : H = -192 KHJ
14. State and expalin Le Chatelier’s principle and apply it to following equilibrium
2SO2(g) + O2(g)  2SO3(g) H = 189 KJ
15. Derive the relation between KP & KC for the equilibrium reaction.
a) N2(g) + 3H2(g)  2NH3(g) b) 2SO2(g) + O2(g)  2SO3(g)
16. Explain the Bronsted Lwry acid - base theory with example.
17. State and explain Salt hydrolysis.

18. Write a few lines on the utility of hydrogen as a fuel.

19. What is Hardness of water? How is hardness of water removed by Permutit Process (or) ion
exchnge method or Calgon method?
20. Write any four reducing properties of hydrogen peroxide. Give equations.
21. Explain with suitable examples, the following
i) Electron deficient ii) Electron-precise and iii) Electron-rich hydrides

22. Explain the structure of diborane.

23. Write an essay on the preparation and chenmical activities of diborane.
24. Explain Borax bead test with a suitable examples.
25. Explain the differences in properties of diamond and graphite on the basis of their structures.

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 TOP 45 VSAQ
TOTAL MARKS : 9 x 2 = 18

1. State Graham’s lw of diffusion.

2. State Dalton’s law of partial pressures.
3. Which gas diffuses faster among N2, O2, CH4 gases? Why?

4. Describe the important uses of quick lime.

5. Why are alkali metals not found in the free state in nature?
6. Describe the important uses of Caustic Soda (or) Sodium Hydroxide.
7. Describe the important uses of sodium carbonate.
8. What is Plaster of Paris?
9. What is the improtance of Ca+2 in the funcitoning of the cell?
10. Why are IA group elements called as “alkali metls”?
11. What is plaster of paris? Mention its uses.
12. Why gypsum is added to cement.

13. Why does BF3 behave as a Lewis acid?

14. Explain intert pair effect.
15. Give the formula of borazine. What is its comomon name?
16. Give the formulae of (a) Borax (b) Colemanite

17. How does Graphite funciton as a lubricant?

18. Graphite is a good conductor. Explain.
19. Why is diamond hard?
20. What is allotropy? Give the crystalline allotropes of carbon.
21. What are silicones? Give the uses of silicones.
22. Namne any two man-made silicates.
23. Give the use of CO2 in photosynthesis.

24. Why is CO poisonous?

25. What is meant by Dry ice? Give tis application.
26. Give the hybridisation of carbon in diamon dand fullerene.
27. What is ‘producer gas’? How is producer gas prepared?
28. How is water gas prepared?
29. What is Synthesis gas?

30. What is Chemical oxygen Demand (COD)?

31. What is Biochemical Oxygen Demand (BOD)?
32. Which oxides cause acid rain? and What is its pH value?
33. Define Receptor, sink and speciation.
34. What happens when holes are fourmed in ozone layer?
(or) Mention the harmful effects caused due to depletion of ozone layer
35. Name two important sinks for carbon dioxide.
36. What is Green house effect?
37. Acid rains are harmful. Whhy? Name two adverse effects caused by acid rains.
38. What happens when Fluorides are present in water?
39. Define pollutant and Contaminent.

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40. Give two examples each for position and functional isomerism.

41. Give the structural formulae of the following compounds.

a) 2, 3-dimethyl butane b) 2-methyl but-1-ene

42. Write the structural formulae of the following compounds:

a) 3,4,4,5-Tetramethyl heptane b) 2-Methyl-1-butene

43. Write IUPAC names of the following:

CH3 CH3
| |
a) H3C - C - CH - CH2 - CH3 b) H3C - C - CH2 - CH2 - COOH
| | |
CH3 CH3 CH3

44. Write IUPAC names of the following :

CH3 CH3
| |
a) CH3 - C - CH2 - C - CH3 b) CH3 - CH - CH2 - CH2 - CH3
| | |
CH3 CH3 OH

45. Write the IUPAC names of the following compounds.

a) b)

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 TOP 20 PROBLEMS
4 & 2 M AR K S

1. A carbon compound contains 12.8% carbon. 2.1% hydorgen, 85.1% bromine. The molecular
weight of compund is 187.9. Calculate the molecular formula.
2. A carbon compound on analysis gave the following percentage composition, carbon 14.5%.
Hydrogen 1.8% CHlrine 64.46%. Oxygen 19.24%. Calculate the empirical formula.
3. Balance the follwoing redox equation in acidic medium of ion-electron method.
Fe2+(aq) + CO2O2-7(aq)  Fe3+(aq) + Cr3+(aq)
4. Balance following equation in Basic medium by ion-electron method.
MnO-4 + I-  MnO2 + I2
5. Calculate the oxidation numbers of oxygen in (i) O2F2 (ii) OF2
6. Calcualte the oxidation number of chromium (Cr) in Cr2O2-7 ion
7. Calculate the oxidation number of Cr in K2Cr2O7.
8. Calcualte the oxidation number of Mn in KMnO4, MnO-24.
9. How many number of moles of glucose are present in 540 grams of glucose.
10. Calculate the wright of 0,1 mole of Sodium carbonate.
11. How many no. of CaCO3 moles are present 200 grams of CaCO3?
12. The emprical formula of oa compound is CH2O. Its molecular weight is 90.
Calculate the molecular formula of the compound.

13. Calculate kinetic energy of three moles of CO2 at 270 (in calories only).
14. Find kinetic energy of 5 moles of an ideal gas in calories at 270C.
15. Calculate kinetic energy of 2 moles of Nitrogen at 270C.

16. Calculat ehte pH of 0.01 M HCl solution.

17. What is pH? Calculate the pH of 0.001 M HCl solution.
18. Calculate pH of a 1.0 x 10-8 M solution of HCl
19. Calculate the pH of 0.001M NaOH.
20. Calculate hte pH of 0.05 M H2SO4 solution.

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 VSAQ
SECTION - A
1. (i) What is Chemical Oxygen Demand (COD)?
(ii) What is Biochemical Oxygen Demand (BOD)?
(iii) Which oxides causes acid rain? and What is its pH value?
(iv) Define Receptor, sink and speciation.
(v) What happens when holes are formed in ozone layer?
(vi) What happens when carbon monoxide is increased in the air?
(vii) Name two important sinks for Carbon dioxide.
(viii) What are effects of acid rain?
(ix) What is Green house effect?

2. (i) Define Green house effect. Which gases are the cause for it?
(ii) Acid rains are harmful. Why? (or) Name two adverse effects caused by acid rains.
(iii) What happens when Fluorides are present in water?
(iv) What is the harm caused by CFCs?
(v) Name two important sinks for Carbondioxide.
(vi) Define Pollutant and Contaminent.
(vii) Mention the harmful effects caused due to depletion of ozone layer.

3. (i) State Graham’s law of diffusion.

(ii) State Dalton’s law of partial pressures.
(iii) Which gas diffuses faster among N2, O2, CH4 gases? Why?
(iv) How many times methane diffuses faster than sulphurdioxide?
(v) What is Boltzman’s Constant? Give its value.
(vi) What is most probable speed?
(vii) Find the kinetic energy of 5 moles of an ideal gas in calories at 270C.
(viii) Calculate kinietic energy of 3 moles of CO2 gas at 270C.
(ix) Find the RMS velocity of CO2 gas at 270C.

4. (i) How many number of moles of glucose are present in 540 grams of glucose.
(ii) Calculate the weight of 0.1 mole of Sodium carbonate.
(iii) The emperical formula of a compound is CH2O. Its molecular weight is 90. Calculate the
molecular formula of the compound.
(iv) Calcualte the volume of O2 at STP required to completely burn 100 ml of acetylene.
(v) What are dispropoortionation reactions? Give an example.
(vi) How many no. of CaCO3 moles are present 200 gms of CaCO3 ?
(vii) Determinie the oxidation number of sulphur in H2S2O8 (Marshall’s acid)
(viii) Calculate the oxidation numbers of oxygen in H2O2 and O2F2?
(ix) Calculate the oxidation number of Mn in KMnO4 , MnO-24 .

5. (i) What is homogeneous equilibrium? Write two homogenous reactions.

(ii) What is hetergeneous equilirbium? Write two heterogeneous reactions.
(iii) Write the relation between KP and KC.
(iv) All Bronsted bases are Lewis bases. Explain.
(v) Define PH of a solution. Write its significance.
(vi) What is conjugate acid - base pair? Give example.
(vii) Calculate the pHof 10-3 M HCl
(viii) Calculate the pH of 0.05 M NaOH solution.
(ix) Concentration of Hydrogen ion is 3.8 x 10-3 M. What is its pH?
(x) Derive the KP and KC relations for the reaction , PCl5(g) PCl3(g) + Cl2(g)
(xi) Calculate the pH of 0.05 M H2SO4 solution.

6
6. (i) Describe the important uses of quick lime.
(ii) Why are alkali metals not found in the free state in nature?
(iii) Describe the important uses of Caustic Soda (or) Sodium Hydroxide.
(iv) Describe the important uses of sodium carbonate.
(v) Describe the importance of Plaster of Paris.
(vi) What is the importance of Ca+2 in the functioning of the cell?
(vii) Lithium Iodide is the most covalent among the alkali metal halides. Give the reasons.
(viii) What is Baking soda? Give its uses.
(ix) Write the average composition of portland cement.

7. (i) Why are IA group elements called as “alkali metals”?

(ii) What is plaster of a paris? Mention its uses.
(iii) Why gypsum is added to cement.
(iv) Why does BF3 behave as a Lewis acid?
(v) Explain inert pari effect.
(vi) Give the formula of Borazine. What is its common name?
(vii) Give the formulae of (a) Borax (b) Colemanite
(viii) Sketch the structure of Boric acid.
(ix) What is a Banana bond?

8. (i) How does Graphite funciton as a lubricant?

(ii) Graphite is a good conductor. Explain.
(iii) Why is diamond hard?
(iv) What is allotropy? Give the crystalline allotropes of carbon.
(v) C-C bond length in graphite is shorter than C-C bond length in diamond. Explain.
(vi) What are silicones? Give the uses of silicones.
(vii) Name any two man-made silicates.
(viii) Give the use of CO2 in photosynthesis.

9. (i) Why is CO poisonous?

(ii) Write the use of ZSM-5.
(iii) What is meant by Dry ice? Give its applicaitons.
(iv) Give the hybridisation of carbon in
a) CO3-2 b) Diamond c) Graphite d) Fullerene
(v) What is “producer gas”? How is producer gas prepared?
(vi) How is water gas prepared.
(vii) What is Synthesis gas?

7
10. (i) Write the structural formulate of the following compunds:
(a) Trichloroethanoic acid (b) Neo-Pentane

(ii) Give the structural formulae of the following compounds.

(a) 2, 3-dimethyl butane (b) 2-methyl but-1-ene

(iii) Write the structural formulae of the following compounds.

(a) 3,4,4,5-Tetramethyl heptane (b)2-Methyl-1-butene

(iv) Draw the cis-trans isomers for the following compunds.

(a) CHCl = CHCl (b) C2H5 CH3C = CCH3 C2H5

(v) Write IUPAC names of the following:

CH3 CH3
| |
(a) H3C - C - CH - CH2 - CH3 (b) H3C - C - CH2 - CH2 - COOH
| | |
CH3 CH3 CH3

CH3 CH3
| |
(c) CH3 - C - CH2 - C - CH3 (d) CH3 - CH - CH2 - CH2 - CH3
| | |
CH3 CH3 OH

(vi) An Alkyne ‘A’ undergo cyclic polymeristation by passing through red hot iron tube to
give ‘B’. What are ‘A’ and ‘B’ ?

8
 SAQ
SECTION - B
11. (i) Give the important postulates of kinetic molecular theory of gases.
(ii) State and explain Grahm’s law of diffusion.
(iii) Deduce (a) Boyle’s law (b) Charle’s law from kinetic gas equation.
(iv) Derive the ideal gas equation from gas laws.
(v) Find RMS velocity, average velocity and most probable velocity of CO2 gas at 270C.
(vi) 360 cm3 of CH4 gas diffused through a porous membrane in 15 minutes. Under similar
conditions, 120 cm3 of another gas diffused in 10 minutes. Find the molar mass of the gas.
(vii) At 250C and 760 mm of Hg Pressure a gas occupies 600 ml volume. What will be its
pressure at a height where temperature is 100C and volume of hte gas is 640 ml.

12. (i) Balance the following redox equation in acidic medium by ion-electron method.
Fe2+(aq) + Cr2O2-2(g)  Fe3+(aq) + Cr3+(aq)
(ii) Balance the following redox reaction by ion-electron method in acid medium
MnO-4(aq) + SO2(g)  Mn+2(aq) + HSO-4(aq)
(iii) Balance the following equation in Basic medium byion-electron method.
MnO-4 + I-  MnO2 + I2
(iv) A carbon compound contains 12.8% carbon, 2% hydrogen, 85.1% bromine. The molecular
weight of the compound is 187.9. Calculate the molecular formula.
(v) Calculate the empirical formula of oa compound having percentage composition:
Potassium (K) = 26.57, chromium (Cr) = 35.36, Oxygen (O) = 38.07.
(Given the atomic weights of K, Cr and O as 39 ; 52 and 16 respectively)

13. (i) State and explain “Hess law of constant heat summation” with example.
(ii) Define heat capacity? What are Cp and CV? Show that CP - Cv = R.
(iii) Give the mathematical formulationof first law of thermodynamics.
(iv) State and explain the significance of second law of thermodynamics.

14. (i) Derive the relation between KP & KC for the equilibrium reaction.
a) N2(g) + 3H2(g)  2NH3(g) b) 2SO2(g) + O2(g)  2SO3(g)
(ii) Explain the Bronsted-Lowry acid-base theroy with example.
(iii) Explain Lewis acid base theroy with example.
(iv) State Le-Chatlier’s principle and apply the same to the following equilibrium
N2(g) + 3H2(g)  2NH3(g) ; H = -92 KJ (or)
State LeChatlier’s principle and apply it to the synthesis of ammonia by Haber’s process.
(v) Define pH of a solution. Write its significance.
(vi) State and explain Salt hydrolysis.

15. (i) Describe electrolyltic method for the preparation of H2O2.

(ii) What is Hardness of water? How is hardness of water removed by permutit process (or) ion
exchange method or Calgon method?
(iii) Write a few lines on the utility of hydrogen as a fuel.
(iv) Write a note on heavy water.
(v) Write any four reducing properties of hydrogen peroxide. Give equations.
(vi) Explain with suitable examples, the following
a) Electron deficient b) Electron-precise and c) Electron-rich hydrides

9
16. (i) How is diborane (B2H6) prepared? Explain its structure.
(ii) Write an essay on the preparaton and chemical activities of diborane.
(iii) Explain Borax bead test with a sutiable example.
(iv) What are electron deficient compounds? Is BCl3 an electron deficient species? Explain.

17. (i) Explain sp3d2 hybridisaton with an example.

(ii) Explain the structure of PCl5 molecule with hybridisation.
(iii) Explain the structure of Ethylene.
(iv) State Fajan’s rules with suitable examples.
(v) What is Hydrogen bond? Explain the different types of hydrogen bonds with example.
(vi) Explain the formation of coordinate covalent bond with one example.
(vii) What is meant by the term Bond order? Calculate the bond order of (a)N2 (b) O2

18. (i) Write two methods of preparation of Ethylene. Give the equations.
(ii) Explain (a) Position isomerism (b) Functional group isomerism with one example for each
(iii) Explain Wurtz reaction and Friedel Craft alkylation with one example for each.
(iv) How do you get Benzene from Acetylene?
Explain the halogenation and alkylation of Benzene.
(v) Write the corresponding equations for the following reactions and name products A,B,C.
CaC2 
H2O
 A 
hot Cu tube conc.HNO3  H2SO4
B  C
323  333K
(vi) Describe two methods of preparation of Ethylene. Give the equation for the reactions of the
ethylene with the following
(a) Ozone (b) Cold and alk. KMnO4
(vii) How the following are obtained from Benzene?
(a) Nitro Benzene (b) Methyl Benzene
Give the equations.
(viii) Write notes on the following (a) Distillation (b) Chromatography

10
 LAQ
SECTION - C
19. (i) What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this
model to explain various series of line spectra in hydrogen atom?
(ii) What are the postulates of Bohr’s model of hydrogen atom? Write the limitations of Bohr’s
theory. Differentiate between emission and absorption spectra.
(iii) How are the quantum number n, l and ml arrived at? Explain the significance of these
quantum numbers.
(iv) Define atomic orbital. Explain the shapes of s,p,d orbitals with the help of diagrams.
(v) Explain (a) Planck’s quantum theory (b) de Broglie’s wave hypothesis

20. (i) What is periodic property? How the following properties vary in a group and a period?
Explain(1) Atomic radius (2) Electron gain enthalpy
(3) Elecctro negativity (EN) (4) Ionisation potential (IE)
(ii) Define IE1 and IE2. Why is IE2 > IE1 for a given atom? Discuss the factors that effect IE on an
element.
(iii) Write an essay on s,p,d and f block elements.
(iv) Relate the electronic configuration of elements and their properties in the classification of
elelments (or) write on essay on classification of elemlents into type?
(v) Expalin (a) Valency (b) Diagonal relation (c) Varation of nature of oxides in the Group-I

21. (i) What do you understand by hybridisation? Explain different types of hybridisation involving
s and p orbitals.
(ii) Given the Molecular Orbital Energy diagram of (a) N2 (b) O2. Calculate the respective bond
order. Write the magnetic nature of N2 and O2 moelcules.
(iii) Give an account of VSEPR theory and its applications
(iv) How do you explain the geometry of the molecules on the basis of Valence bond theroy?
(v) Describe any two methods of preparation of benzene with corresponding equations. Explain
the following benznee reactions
(a) Halogenation (b) Alkylation (c) Acylaton (d) Nitraton
(vi) a) Write the prepartion of ethane using the following method
i) Wurtz reacton ii) Kolbe’s electrolytic method
(vii) Complete the following reactions and name the products A,B,C,D
conc.HNO3  H2SO4
i) CaC2 
H2O
 A 
hot Cu tube
B 
323  333K
C
ii) Ethylene 
Br2 /CCl4
D .

11
 GUESS PAPER - 1

JR. CHEMISTRY
SECTION - A

I. Answer ALL questions : [10 x 2 = 20]

1. What is Chemical Oxygen Demand (COD)?
2. What are effects of acid rain?
3. State Graham’s law of diffusion.
4. Calculate the oxidation number of Mn in KMnO4 , MnO-24 .
5. What is conjugate acid - base pair? Give example.
6. Describe hte important uses of sodium carbonate.
7. What is Plaster of Paris? Mention its uses.
8. How does Graphite funciton as a lubricant?
9. What is Synthesis gas?
10. Write the strucctural formulae of the following compunds
a) Trichloroethanoic acid b) Neo-Pentane

SECTION - B
II. Answer any SIX of the following Questions : [6 x 4 = 24]

11. Give the important postulates of kinetic molecular theory of gases.

12. Balance the following redox reaction by ion-electron method in acid medium
MnO-4(aq) + SO2(g)  Mn+2(aq) + HSO-4(aq)
13. State and explain “Hess law of constant heat summation” with example.
14. Derive the relation between KP & KC for the equilibrium reaction.
N2(g) + 3H2(g)  2NH3(g)
15. What is the cause for permanent hardness of water?
Explain the removal of hardness of water by Calgon method.
16. How is diborane (B2H6) prepared? Explain its structure.
17. Explain the structure of PCl5 molecule with hybridisation.
18. Explain (a) Position isomerism (b) Functional group isomerism with one example for each

SECTION - C

III. Answer any Two of the following Questions : [2 x 8 = 16]

19. What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this
model to explain various series of line spectra in hydrogen atom?
20. What is periodic property? How the following properties vary in a group and a period? Explain
(a) Ionisation potential (IE) (b) Elecctronegativity (c) Electron gain enthalpy
21. a) Write the prepartion of ethane using the following method
i) Wurtz reacton ii) Kolbe’s electrolytic method
b) Complete the following reactions and name the products A,B,C,D
i) CaC2     A    B    C
H O2 h o t C u tu b e A lC l 3
CH Cl3

ii) Ethylene 

Br2 /CCl4
D .

*****

12
 GUESS PAPER - 2

JR. CHEMISTRY
SECTION - A

I. Answer ALL questions : [10 x 2 = 20]

1. What is Biochemical Oxygen Demand (BOD)?
2. Define Receptor Sink.
3. Which gas diffuses faster among N2, O2, CH4 gases? Why?
4. The emperical formula of a compound is CH2O. Its molecular weight is 90. Calculate the molecular
formula of the compound.
5. Calculate the pH of 0.05 M H2SO4 solution.
6. Write the average composition of portland cement.
7. Give the formula and structure of Borazine (or Borzine).
8. What is allotropy? Give the crystalline allotropes of carbon.
9. What is meant by Dry ice? Give its applicaitons.
10. Write IUPAC names of the following:
CH3 CH3
| |
(a) H3C - C - CH - CH2 - CH3 (b) H3C - C - CH2 - CH2 - COOH
| | |
CH3 CH3 CH3

SECTION - B
II. Answer any SIX of the following Questions : [6 x 4 = 24]
11. State and explain Grahm’s law of diffusion.
12. A carbon compound contains 12.8% carbon, 2% hydrogen, 85.1% bromine. The molecular
weight of the compound is 187.9. Calculate the molecular formula.
13. Define heat capacity? What are Cp and CV? Show that CP - Cv = R.
14. State Le-Chatlier’s principle and apply it to the synthesis of ammonia by Haber’s process.
15. Write any four reducing properties of hydrogen peroxide. Give equations.
16. Explain Borax bead test with a sutiable example.
17. What is Hydrogen bond? Explain the different types of hydrogen bonds with example.
18. How is acetylene prepared form the following compounds:
a) Calcium carbide b) 1,2-dibromoethane

SECTION - C

III. Answer any Two of the following Questions : [2 x 8 = 16]

19. How are the quantum number n, l and ml arrived at? Explain the significance of these quantum
numbers.
20. Define IE1 and IE2. Why is IE2 > IE1 for a given atom? Discuss the factors that effect IE on an
element.
21. Describe any two methods of preparation of benzene with corresponding equations. Explain
the following benznee reactions
(a) Halogenation (b) Alkylation (c) Acylaton (d) Nitraton

*****

13
 GUESS PAPER - 3

JR. CHEMISTRY
SECTION - A

I. Answer ALL questions : [10 x 2 = 20]

1. Which oxides causes acid rain? and What is its pH value?
2. Define Green house effect. Which gases are the cause for it?
3. What is Boltzman’s Constant? Give its value.
4. Calculate the volume of O2 at STP required to completely burn 100ml of acetylene.
5. Calculate the pH of 0.05 M NaOH solution.
6. Write the important uses of Caustic Soda.
7. Why gypsum is added to cement.
8. Why is diamond hard?
9. What is Synthesis gas?
10. Give the structural formulae of the following compounds.
(a) 2, 3-dimethyl butane (b) 2-methyl but-1-ene

SECTION - B
II. Answer any SIX of the following Questions : [6 x 4 = 24]

11. Derive the ideal gas equation from gas laws.

12. Balance the following redox equation in acidic medium by ion-electron method.
Fe2+(aq) + Cr2O2-2(g)  Fe3+(aq) + Cr3+(aq)
13. Give the mathematical formulationof first law of thermodynamics.
14. Explain Lewis acid base theroy with example.
15. Write a few lines on the utility of hydrogen as a fuel.
16. What are electron deficient compounds? Is BCl3 an electron deficient species? Explain.
17. Explain the structure of Ethylene.
18. Write notes on the following (a) Distillation (b) Chromatography

SECTION - C

III. Answer any Two of the following Questions : [2 x 8 = 16]

19. Define atomic orbital. Explain the shapes of s,p,d orbitals with the help of diagrams.
20. Write an essay on s,p,d and f block elements.
21. What is hybridisation? Explain different types of hybridisation involving s and p orbitals.

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