CE22145
CE22145
CE22145
ENVIRONMENTAL SCIENCE
Given:
SO2 = 80𝜇g/m3
Problem 2
A sample of air contains 8.583 moles /m3 of oxygen and 15.93 T = 25C
moles/m3 of nitrogen at standard temperature and pressure P = 103.193 kPa
(STP). Determine the partial pressures of oxygen and nitrogen Required: SO2 concentration in ppm
in 1 m3 of the air.
Solution:
Solve for the GMW of SO2
GMW for S = 32.064
O = 32.00
GMW = 32.064 + 32 = 64.064 𝑔/𝑚𝑜𝑙𝑒 ◦ Cold air then pushes under the warmer air rising from the
valley, creating the inversion
Solve for ppm ◦ Normal or Thermal Lapse Rate | as temperature
80 25 + 273.15 101.325 decreases, the altitude increases
(22.414)( )( )
𝑝𝑝𝑚 = 64.064 273.15 103.193
𝐿
1𝑚3 (1000 3 ) Smog | Mix of smoke and fog. It is an effect of temperature
𝑚
inversion where warm air forms a layer over cold air.
𝒑𝒑𝒎 = 𝟎. 𝟎𝟑
Composition of Atmosphere
NOTE: (from lecture 4)
𝑔𝑚 𝜇𝑔
𝜇𝑔 1𝑚3 𝑝𝑜𝑙𝑙𝑢𝑡𝑎𝑛𝑡 𝑀𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 − 𝑤𝑒𝑖𝑔ℎ𝑡 ( ) ∙ 106
𝑚𝑜𝑙𝑒 𝑔
= × If the volume ratio
𝑚3 106 𝑚3 𝑎𝑖𝑟 𝑚3
22.4 × 10−3 of nitrogen and
𝑚𝑜𝑙𝑒
carbon dioxide is
AIR POLLUTION more than what is
Occurrence of Air Pollution indicated in the
Shanghai, China (2004) | table, meron nang
People in China wear masks air pollution
even without pandemic due to
severe air pollution
Sources of Air Pollution
Donora Smog in Natural Sources | Natural processes that create air
Pennsylvania (1948) | pollution
Caused by a factory that melted • Dust blown by wind
zinc
• Pollutants from wildfires and volcanoes
• Volatile organics released by plants
Santiago, Chile |
• Withdrawing groundwater
Photochemical smog; visible in
Human Sources | mostly in industrialized and/or
higher ground elevation
urban areas
• Stationary sources
◦ Manufacturing plant
• Mobile source
Air Pollution and Meteorology ◦ Vehicles and automobiles (75% of the pollution)
Meteorology | science of the atmosphere ◦ Tires | component of automobiles that
◦ Atmospheric processes (through wind and exchange of also causes air pollution
heat) dictate the fate of the pollutant • Areal source
◦ Pollutants go through Transport, Dispersion, and ◦ Unpaved roads (alikabok na galing don)
Transformation stages ◦ Industrial Park in one compound
Air Pollution Meteorology | the study of how these
atmospheric processes affect the fate of the Pollutants in the Atmosphere
pollutants Primary Pollutants | emitted directly from the source such
◦ Sunset looks better due to air pollution as manufacturing plants or vehicles
Temperature Inversion | Deviation from normal Secondary Pollutants | When the air pollutants that
change of an atmospheric property; Refers to an come from the manufacturing plants mix with the air from
inversion of the thermal lapse rate the atmosphere
◦ Occur most often when a warm, less dense air mass
moves over a dense, cold air mass.
Major Air Pollutants Effects of Air Pollution
*mentioned in lecture Health Effects
Soot | finer timber (part of
Short Term Effects Long Term Effects
the production of timber)
• Headache • Central Nervous System
Fly ash | like pulverized
• Coughing Diseases
charcoal (abo) • Pneumonia (could be • Cardiovascular Diseases
H2S – Hydrogen Sulfide | long term) • Respiratory Diseases
colorless gas known for its • Bronchitis (could be • Impacts on Liver
pungent “rotten egg” smell long term) • Impacts on
CO – Carbon Monoxide | • Skin irritation Reproductive System
harmful when inhaled Environmental Effects
because it replaces the
• Acid Rain | The precipitate has an elevated levels
oxygen in the body
of hydrogen ions (low pH). The normal pH level of
water ranges from 6.5 to 8.5. When there is an acid rain,
Some Gaseous Air Pollutants
the average pH level ranges from 4-5.
• Ozone Layer Depletion | It is the gradual
thinning of the ozone layer
• Global Warming | gradual increase in the overall
temperature of the Earth. It is caused by the
increased levels of carbon dioxide, CFCs, and other
pollutants.
ATMOSPHERIC DISPERSION
Factor Affecting Dispersion of Air Pollutants
Source Characteristics | describes the movement of the
effluent discharge from the stack
◦ Most industrial effluents are discharged vertically into the
open air through a stack or duct
◦ As the contaminated gas stream leaves the discharge point,
the plume tends to expand and mix with ambient air
◦ Horizontal air movement will tend to bend the discharge
plume toward the downwind direction
◦ While the effluent plume is rising, bending, and beginning
to move in a horizontal direction, the gaseous effluents are
being diluted by the ambient air surrounding the plume
Downward Distance | distance from the point of Powerplant Plumes
discharge to the ground
◦The greater the distance between the point of discharge
and a ground level receptor downwind, the greater the
volume of air available for diluting the contaminant
discharge before it reaches the receptor.
Wind Speed and Direction | determines the direction
in which, the contaminated gas stream will move across
local terrain. ◦ mas maganda ‘pag mataas ang smoke stack kasi
◦ The greater the distance between the point of discharge makakapag-disperse nang maayos ‘yong smoke
and a ground level receptor downwind, the greater the ◦ the smoke emitted must be a light color (bad indication if
volume of air available for diluting the contaminant
the smoke is dark)
discharge before it reaches the receptor.
◦ An increase in wind speed will decrease the plume rise by
bending the plume over more rapidly.
◦ The decrease in plume rise tends to increase the
pollutant’s ground level concentration.
◦ An increase in wind velocity will increase the rate of
dilution of the effluent plume, tending to lower the
downwind concentrations.
Stability | turbulence in the velocity of the atmosphere
◦ The turbulence of the atmosphere follows no other factor
in power of dilution.
◦ The more unstable the atmosphere, the greater the
diluting power.
◦ Inversions that are not ground based, but begin at some
height above the stack exit, act as a lid to restrict vertical
dilution.
Dispersion Modeling
Dispersion Model | mathematical description of the
meteorological transport and dispersion process that
is quantified in terms of source and meteorological parameters AIR POLLUTION PREVENTION
during a particular time. Ways to Mitigate Air Pollution
◦ Resultant Numerical Calculations | yield Renewable Fuel and Clean Energy | most basic solution
estimates of concentrations of the particular for air pollution is to move away from fossil fuels,
pollutant for specific locations and times. replacing them with alternative energies like solar,
◦ Meteorological Parameters | required for use of the
wind and geothermal.
models include wind direction, wind speed, and
◦ Wind Turbines (Rizal, Ilocos Norte, Guimaras)
atmospheric stability.
◦ Solar Power
◦ In some models, provisions may be made for including lapse
Energy Conservation Efficiency | most basic solution for
rate and vertical mixing height.
◦ Most models will require data about the physical stack air pollution is to move away from fossil fuels, replacing
height, the diameter of the stack at the emission point, the them with alternative energies like solar, wind and
exit gas temperature and velocity, and the mass rate of geothermal.
emission of pollutants. ◦ Wind Turbines (Rizal, Ilocos Norte, Guimaras)
◦ Solar Power
Eco-friendly Transportation | Shifting to electric Air Pollution Control of Mobile Sources
vehicles, hydrogen vehicles and promoting shared • Positive crankcase ventilation valves | To direct
mobility (i.e. carpooling, and public transports) crankcase blowby emissions into the engine
◦ Carpooling • Charcoal Canister | Sequester volatile
◦ Public transports hydrocarbons for later burning in the engine
Green Building | From planning to demolition, green building • Exhaust gas recirculation valves | reduce NOx
aims to create environmentally responsible and formation during fuel combustion
resource-efficient structures to reduce carbon footprint. • Catalytic Converters | designed to oxidize partially
◦ Rainwater harvesting combusted hydrocarbons and CO to CO2
◦ Reusing local materials ◦ walang catalytic converters ‘yong mga tricycles sa
◦ Taking advantage of natural lighting Philippines kaya isa ito sa mga main contributors ng
air pollution
Air Pollution Control of Stationary Sources
Different Types of Engines
Settling Chamber | Uses the force of gravity to
Gasoline Engine | One kg of gasoline can burn completely
remove solid particles. The large particles settle and
when mixed with about 15 kg of air (1:15 ratio of
recollect at the dust hoppers.
◦ Particle Size | remove large particles from air gasoline to fuel). However, for maximum power, the
(>10 µm). proportion of air to fuel must be less.
◦ Note | Not good for sticky pollutants because ◦ When combustion is incomplete, and substantial
it will stick to the walls of the chamber. amounts of material other than carbon dioxide and
Electrostatic Precipitators | The precipitators water are discharged.
electrostatically charge the air particles in the gas stream. ◦ One result of having an inadequate supply of air is
the emission of carbon monoxide instead of carbon
The charged particles are attracted to the plates.
dioxide. Other by-products are unburned gasoline
When the plates have accumulated enough particles (can
and hydrocarbons.
either be wet or dry), the plates are shaken off by
Diesel Engine | A diesel normally operates at a higher
mechanical rappers to fall into a hopper (at the
air-to-fuel ratio than does a gasoline engine.
bottom of a unit). ◦ The fuel is injected directly to the combustion
◦ Can tolerate an operating temperature of 700 ⁰K chamber, so no carburetor is required. The power
◦ Particle Size | Efficient in removing small output is changed by the rate of fuel injection.
particles (>0.01 µm) ◦ There is no spark ignition system. The air is heated by
◦ Note | can be utilized for dry and wet particles compression. That is, the air in the engine cylinder is
Inertial Separator or Cyclone | Works like a centrifuge squeezed until it exerts a pressure high enough to
(outward circular path) with continuous air flow raise the air temperature to about 540 ⁰C, which is
inside. The particles stick to the walls then fall at the enough to ignite the fuel oil as it is injected into the
cylinder.
bottom of the vessel
◦ A well-designed, well-maintained, and properly
◦ Particle Size | remove large particles from air
adjusted diesel engine will emit less CO and
Bag house and Filter | The air passes through fabric
hydrocarbons
filters or bag houses to remove dust or respirable ◦ Higher operating temperatures lead to substantially
particles from a gas stream higher NOx emissions
◦ Particle Size | Efficient in removing fine
particles (>0.01 µm diameter)
CLEAN AIR ACT Methods of Waste Disposal and Management
Republic Act No. 8749 | comprehensive air quality management • Biodegradable and Non-Biodegradable | Basic form of
policy and program which aims to achieve and maintain waste disposal and management; Widely used in the Philippines
healthy air for all Filipinos. • Paper, Plastic, Metal, Glass, Food, and Others | Proper
segregation of solid wastes; Done if you are serious in
Prohibited Acts (Mentioned in the quiz) managing solid waste
Incineration | defined as the burning of municipal,
bio-medical and hazardous wastes, which process Health Impacts of Solid Waste
emits toxic and poisonous fumes is prohibited. • Negative Impacts to Human Health | Due to exposure to
Open Burning | No person shall be allowed to burn any hazardous waste. Incinerators are the best way to treat
materials in any quantities which shall cause hazardous wastes
the emission of toxic and poisonous fumes. • Air Pollution | Due to improperly operated incineration plants
Smoking | Implement or enforce a ban on smoking • Spreading of Diseases | Due to improperly managed and
inside a public building or an enclosed public designed landfills, which can attract all types of insects and
place including public vehicles and other means of rodents
transport or in any enclosed area outside of one's private • Chronic Diseases | Due to direct handling of solid waste
residence, private place of work or any duly designated
smoking area which shall be enclosed. HIERARCHY OF WASTE MINIMIZATION
1. Prevention (Ideal) | Avoid consumption/use
2. Minimization | Limit consumption/use
LECTURE 10 3. Reuse | Does not alter physical attributes of materials (reuse of
SOLID WASTE MANAGEMENT containers, soda bottle plant pots)
Characteristics of Solid Waste 4. Recycle | Alter physical attributes and repurposes the
Point of Origin | Domestic, Institutional, Commercial, materials (chair out of plastic bottles)
Industrial, Street, Demolition or Construction 5. Energy Recovery | Production of energy out of the waste
Nature of Material | Organic, Inorganic, Combustible, (combustion, gasification, etc.)
Non-combustible, Putrescible, Non-Putrescible 6. Disposal | Doing nothing
Kinds of Material
• Garbage | Food Wastes; Biodegradable waste that has
PROCESS CARRIED OUT DURING SOLID WASTE
moisture content
MANAGEMENT
• Rubbish | Consists of both combustible and non-
1. Waste Collection | Collection and storage of solid waste
combustible solid wastes, but does not include garbage for transportation to a disposal or treatment site.
• Trash | Component of rubbish which consists of ◦ No treatment done yet
combustible materials such as paper, rags, cartons, boxes, 2. Segregation | Sorting and separation of waste types into
woods, furniture, tree branches, and yard trimmings degradable and non-degradable waste to facilitate recycling and
• Non-Combustible | Cannot be burned at ordinary proper onward disposal
incinerator temperatures of 700 – 1000 oC. In the meantime, ◦Tin cans are recycled, or biodegradable wastes are
incinerators are banned in the Philippines. composted, etc.
3. Recycling/Reusing | Repurposing an item into raw
ISWM - Integrated Solid Waste Management material to be used again, usually a completely new product
1. Source Reduction (targets point of generation) ◦ Tin and scrap material may be smelted to reform cans
2. Recycling ◦ Paper may be broken down to recreate paper products
3. Waste Combustion 4. Shredding/Pulverizing | Reducing the size of the solid
4. Landfilling waste, resulting in a uniform mass of material.
◦
Shredded and pulverized can be disposed of, or reused WASTE SEGREGATION
directly; glass smelted to form glass, materials for Material Recovery Facility & Transfer Station
composting, etc. MRF - Material Recovery Facility | Specialized plant
5. Composting/Decomposing | Process wherein organic that Recycles, Reuses, and Segregates recyclable
wastes is broken down by microorganisms into simpler materials for marketing to consumers
forms, which may be used to enrich soils ◦ Sec. 32 of RA 9003 (Ecological Solid Waste
Management Act of 2000) states that material recovery
WASTE COLLECTION facilities shall be established in every barangay
Transfer Station | A processing site for the temporary
Collection Methods
storage, unification, and gathering of waste. This allows
Curbside or Alley Pickup | Most Common, quickest,
greater quantities to be carried at once to the final
and economical; Household set their waste containers by the
disposal sites
curbside. Collectors empty the containers into the collection
vehicle.
RECYCLING / REUSING
Set-Out, Set-Back Collection | A collector group enters the
Recycling | altering the physical properties of a material to
property to collect waste, and another group returns the bins
create an entirely different object (chairs from PET bottles)
◦ Set-Out Crew | Carries full containers from
Reusing | Reusing the material for its intended purpose
residential storage location to curb before collection
vehicle arrives (water containers)
◦ Collection Crew | Loads refuse to vehicle
◦ Set-Back Crew | Returns empty cans to residences SHREDDING OR PULVERIZING
Backyard Pickup | Similar to “Set-Out, Set-Back Collection”, Benefits
but makes use of tote barrels to collect from multiple • Reduces overall volume by 40%
houses at once. Removes the need for Set-Back crew • Increases surface area availability for decomposition
• Facilitates easy handling of moisture content and aeration
Truck Routing Method
Daily Route Method | Simplest and most common method; COMPOSTING / DECOMPOSING
Crew has a definite route that must be finished before Composting | Process that converts organic materials into a
going home. compost through natural decomposition, resulting in a dark
◦ Homeowner knows when waste will be picked up. Route organic matter in soil called Humus
sizes can be adjusted to maximize crew and truck utilization Decomposing | General process of rotting; process by which
◦
Crew must work overtime if not finished. Resulting dead organic substances are broken into simpler organic and
additional expenses and tendency for crew to rush the job
inorganic matter
Large Route Method | Crew has a route that must be
completed in a week
Variations and Techniques
◦ Crew picks a time anytime within the week
Aerobic Composting | Decomposition of organic matter
◦ Only good for backyard pickup since pickup time is not set
using microorganisms that require oxygen
Single Load Method | Routes are planned to get a full truck
Vermicomposting | A natural process wherein
load. Each crew is assigned as many loads as it can collect
bacteria and earthworms are added and used to
per day
convert waste material with rigid structures into compost
◦ Planned routes minimize and optimize travel time
Pyrolysis | Chemical decomposition of organic
◦ Number of homes serviced before truck is filled is indefinite
Definite Working Day Method | Crew has assigned
materials by heating in the absence of oxygen or other
number of hours and quits
reagents, except possibly steam, only leaving carbon as
◦ Regularity is sacrificed. Residence has little idea when residue
pickup will occur
DUMPING AND DISPOSAL 4. Pipes are installed to collect and ventilate the methane
gas generated, which may also be used to generate
electricity
5. Once the landfill’s height exceeds its initial height and the
presence of methane gas is controlled, the land may be
repurposed
Payatas Dumpsite
• Payatas Tragedy/Landslide was a garbage disaster
that occurred on July 10, 2000
• The slope of accumulated garbage caused a large pile to
collapse and set to flame
• In 2004, the Payatas dumpsite was reconfigured as a • Monitors implementation of SWMP in cooperation with the
Controlled Disposal Facility, but was closed in private sector and NGOs
December 2010 • Recommends measures for preservation of ecosystem
• Suggests ways for the collection, transfer, storage,
HAZARDOUS WASTE DISPOSAL processing, recycling, or disposal of solid wastes (franchises
Hazardous Waste | A type of solid waste that contains or Build-Operate-Transfer agreements)
elements that may be dangerous to living things and SWMP - Solid Waste Management Plan | Includes
environment. These are characterized by its Toxicity, strategies and actions for reducing and managing all
Ignitability, and Corrosivity streams of solid waste. These include the following:
◦ Includes wastes used in Hospitals, X-ray rooms, etc. ◦ Waste Characterization | Categorized between
◦ A separate landfill for Hazardous waste is compostable, recyclable, non-recyclable, and special
recommended wastes
◦ Although banned, the use of incinerators in treating ◦ Proper Waste Collection and Transfer
Hazardous wastes is ideal ◦ Waste Processing
◦ Various accidents caused by hazardous wastes ◦ Waste Reduction at Source | Methods by which
include: Bhopal Incident, Payatas Tragedy, and Beirut LGUs can reduce enough waste within five
Explosion years, diverting at least 25% of solid waste to
recycling.
Types of Hazardous Wastes: ◦ Recycling | Involves the Department of Trade and
Radioactive Waste | A type of Hazardous Waste Industry as the market for recyclable materials,
and Department of Natural Environment and Natural
containing radioactive materials. Such as those found in
Resources which publishes all solid waste
Some of its categories include the following:
disposal facilities nationwide
◦ Low-Level Waste | Makes up 90% of all radioactive
◦ Source for Final Waste Disposal | The
wastes. Waste that has contacted with radioactive
Department of Agriculture shall publish an inventory
materials.
of existing markets and demands for
◦ High-Level Waste | Involves things related to Nuclear;
composts, updated annually
Includes used nuclear fuel from nuclear reactors and waste
generated from the reprocessing of nuclear fuel.
Medical or Biomedical Waste | Waste matter produced Other Trends in the Field of Waste Management
from health-related practice such as hospitals, laboratory, • Establishment of Material Recovery Facility (MRF) in
and dentist. Can transmit diseases such as: COVID-19, HIV, Barangay and City level
and Hepatitis B • Composting of biodegradable waste as organic fertilizer
◦ Infectious Waste | Biohazardous or biomedical waste • Innovative way of recycling non-biodegradable waste
that can cause infectious disease. Includes items • Innovative way of collecting segregated waste using dump
contaminated with blood, saliva, body substances, or trucks, tricycles, and pedicabs
those infected with pathogenic material • Construction of Sanitary Landfill