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Alkene Preparation

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9 PYROLYSIS OF ESTERS

R – C – OR' WITTIG REACTION


CLEAVAGE OF ETHERS 8
Dehydrohalogenation O C=O Ph3P = C KOLBE'S REACTION
1 7
H 10
C–C COO–Na+
C–C CH2
H OR
X CH2
D COO–Na+
is
Al lys

R'N
c. tro
KO ec
el

a
H
a
C=C CH2 = CH2
BIRCH REDUCTION
H Na/liq NH3
Dehydration 13 C=C C C
H
H
2 C–C H+
C=C C C
OH H
C=C
H

o ne
c et
/A
r

Pd
I
e

–R3N, –H2O
Na
th

her

/B
/E

a D

aS
H 2 /Qu
Zn

t
Ele

Zn/E

O4
C–C b
b
C C

inl
X X
mi

c 6

on
C–C

e/S
R3N O
3
na

X X H
De C–C X 5 Cope Reaction
ha C–C
tio

log X
R
en N R3 Å
ati
n

ea
on OH
Hoffmann Elimination
cti
on 4

3. PREPARATION OF ALKENES

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