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    Backtitration

    Uploaded by

    Chris
    This document provides 8 practice problems involving back-titration calculations. The problems involve titrating solutions of various substances such as ammonia, potassium carbonate, calcium carbonate, and hydroxides of various metals with acids and base solutions of known concentrations. The calculations require determining unknown concentrations or identities of metals from the titration data provided such as the volumes of titrants used.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Backtitration

    Uploaded by

    Chris
    355 views2 pages
    This document provides 8 practice problems involving back-titration calculations. The problems involve titrating solutions of various substances such as ammonia, potassium carbonate, calcium carbonate, and hydroxides of various metals with acids and base solutions of known concentrations. The calculations require determining unknown concentrations or identities of metals from the titration data provided such as the volumes of titrants used.

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    This document provides 8 practice problems involving back-titration calculations. The problems involve titrating solutions of various substances such as ammonia, potassium carbonate, calcium carbonate, and hydroxides of various metals with acids and base solutions of known concentrations. The calculations require determining unknown concentrations or identities of metals from the titration data provided such as the volumes of titrants used.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    355 views2 pages

    Backtitration

    Uploaded by

    Chris
    This document provides 8 practice problems involving back-titration calculations. The problems involve titrating solutions of various substances such as ammonia, potassium carbonate, calcium carbonate, and hydroxides of various metals with acids and base solutions of known concentrations. The calculations require determining unknown concentrations or identities of metals from the titration data provided such as the volumes of titrants used.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    Back-titration Practice Problems

    1. A student was asked to determine the concentration of ammonia,a volatile substance,in a


    commercially available cloudy ammonia solution used for cleaning.
    First the student pipetted 25cm3 of the cloudy ammonia solution into a conical flask.50
    cm3 of 0.100 mol dm-3 HCl(aq) was immediately added to the conical flask which reacted
    with the ammonia in solution. The unreacted HCl was then titrated with 0.050moldm-3
    Na2CO3(aq). 21.50cm3 of Na2CO3(aq) was required. Calculate the concentration of the
    ammonia in the cloudy ammonia solution.(0.114)

    2. A 1.0000 gram sample of K2CO3 (138.2055 g/mol) is dissolved in enough water to make
    250.0 mL of solution. A 25.00 mL aliquot is taken and titrated with 0.1000 M HCl:

    K2CO3(aq) + 2HCl(aq) 2KCl(aq) + H2O(l) + CO2(g)

    How many mL of HCl are used? (14.47)

    3. A 0.6000 g sample of K2CO3 (138.2055 g/mol) is dissolved in enough water to make


    200.0 mL of solution A. A 20.00 mL aliquot of solution A is taken and put into an
    Erlenmeyer flask. To the flask is added 20.00 mL of 0.1700 M HCl:

    K2CO3(aq) + 2HCl(aq) 2KCl(aq) + H2O(l) + CO2(g)

    The resulting solution is then titrated with 0.1048 M NaOH.

    NaOH(aq) + HCl(aq) H2O(l) + NaCl(aq)

    How many mL of NaOH are used? (24.16)

    4. A 0.4108 gram sample of CaCO3 (100.087 g/mol) is added to a flask along with
    15.00 mL of 2.000 M HCl.

    CaCO3(aq) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)

    Enough water is then added to make 250.0 mL of solution A. A 20.00 mL aliquot of


    solution A is taken and titrated with 0.1160 M NaOH.

    NaOH(aq) + HCl(aq) H2O(l) + NaCl(aq)

    How many mL of NaOH are used? (15.03)


    5. A 0.6181 gram sample of M2CO3 was taken and dissolved in enough water to make
    100.0 mL of solution A. A 10.00 mL aliquot of solution A was taken and 25.00 mL of
    0.1842 M HCl added.

    M2CO3(aq) + 2HCl(aq) 2MCl(aq) + H2O(l) + CO2(g)

    It took 19.90 mL of 0.1473 M NaOH to titrate the resulting

    solution. NaOH(aq) + HCl(aq) H2O(l) + NaCl(aq)

    What is the metal, M? (Li)

    6. A 0.9030 gram sample of M(OH)2 was mixed with 20.00 mL of 2.000 M HCl and
    enough water added to make 100.0 mL of solution A.

    M(OH)2(aq) + 2HCl(aq) 2H2O(l) + MCl2(aq)

    A 10.00 mL aliquot of solution A was taken and titrated with 17.64 mL of 0.05121 M
    NaOH.

    NaOH(aq) + HCl(aq) H2O(l) + NaCl(aq)

    What is the metal, M? (Mg)

    7. A 1.0101 gram sample of Fe(OH)n was missed with 20.00 mL of 2.000 M HCl and
    enough water added to make 200.0 mL of solution A.

    Fe(OH)n(s) + nHCl(aq) FeCln(aq) + nH2O(l)

    A 25.00 mL aliquot of solution A was taken and titrated with 14.56 mL of 0.1000 M
    KOH.

    KOH(aq) + HCl(aq) H2O(l) + KCl(aq)

    What is the value of n? (3)

    8. 1.25g of crushed limestone was added to 50.0 cm3 of 1.00 mol dm-3 hydrochloric acid (an
    excess).The mixture was left until all bubbling stopped and was then made up carefully to
    250cm3 with pure water. A 25 cm3 sample of this was pipette into a conical flask and some
    methyl orange indicator was added. Sodium hydroxide solution of concentration 0.100 mol
    dm-3 was added from the burette.30 cm3 were added to reach the end point of the indicator.
    Calculate the percentage of calcium carbonate in the lime stone.(C=12,O=16,Ca=40)
    (80%)

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