Textile Processing Guide
Textile Processing Guide
Textile Processing Guide
4 INTRODUCTION
5 AN OVERVIEW OF PROCESSING
8 INCREMENTAL INNOVATION
29 APPENDIX
33 KEY TERMS
LEAD AUTHORS
GEORGIA PARKER
INNOVATION MANAGER
FASHION FOR GOOD
ACKNOWLEDGEMENTS
The authors would like to thank the following stakeholders who contributed to this report: Alchemie
Technologies, AlgaeingTM, Colorifix, Deven Supercriticals, Dimpora, Dryfiber, ecO2Dye, Graviky Labs,
GRINP, Huue, Indidye, Indigo Mill Designs, imogo, Jeanologia, KBCols Sciences, Kornit, Living Ink, MTIX,
Nano Dye, Nature Coatings, Nordshield, Novozymes, NTX: Cooltrans, Officina +39:Recycrom, OSM Shield:
ZERO, Sonovia, Tonello, Stony Creek Colors, We aRe SpinDye.
Additionally, thanks to the Fashion for Good team: Katrin Ley (Managing Director), Earl Singh
(Communications Manager), Lana Miller (Digital Marketing Manager), Camilla Rama (Digital Marketing
Coordinator) and Simon Bernasovsky (Innovation Platform) for the edit and design of this report.
Fashion for Good is a global platform for innovation, made possible through collaboration and community.
At the core of Fashion for Good is their innovation platform. Based in Amsterdam with a satellite programme
in Asia, the global accelerator programmes gives promising start-up innovators the expertise and access
to funding they need to grow. The platform also supports innovators through its scaling programme and
foundational projects, driving pilots and supply chain implementation with partner organisations. The
Good Fashion Fund catalyses access to finance to shift at scale to more sustainable production processes.
As a convener for change, Fashion for Good houses the world’s first interactive museum dedicated to
sustainable fashion and innovation, a Circular Apparel Community co-working space, and creates open-
source resources and reports.
Fashion for Good’s programmes are supported by founding partner Laudes Foundation, co-founder
William McDonough and corporate partners adidas, C&A, CHANEL, BESTSELLER, Kering, Levi Strauss
& Co., Otto Group, PVH Corp., Stella McCartney, Target and Zalando, and affiliate and regional partners
Arvind, Birla Cellulose, HSBC, Norrøna, Pangaia, Teijin Frontier, vivobarefoot, Welspun and W. L. Gore &
Associates.
Introduction
The impact of today’s fashion industry has far reaching environmental consequences. And while raw
material production and end of use may spring to mind, the processing stage of the supply chain, including
pre-treatment, colouration (dyeing and printing) and finishing, is often overlooked and a critical area for
pivotal and positive change. This guide, based on industry and Fashion for Good research, is designed to
provide an overview and deeper understanding of the processing stage, including innovative technologies
that would help drastically reduce the water, energy and chemistry used, as well as replacing hazardous
chemistry currently used1. A list of the defintions of key terms used in the report can be found in the
appendix.
The textile industry’s supply chain is commonly represented in four Tiers, this is used to describe the
production process from raw material extraction to the finished product. Tier 4 includes the cultivation
and extraction of raw materials from the earth, plants or animals. Tier 3, the processing of raw materials
into yarn and other intermediate products. The processing stage, discussed in this report, falls into Tier
2, which is often referred to as material production. Tier 1 is the assembly and manufacturing of the final
products2.
Tiers 3 and 4 are often cited as the main cause of the fashion industry’s high environmental impact but
actually make up 39% of all greenhouse gas (GHG) emissions in the fashion supply chain. Whilst Tier 2
equates to 52% of the GHG emissions, whilst also using a significant amount of chemistry and water3.
Four Tier Supply Chain Model. Source: WRI and Aii (2021)
As a result, there is ample opportunity to reduce impact in this stage of the supply chain. Fashion for Good
works with brands, manufacturers and innovators to orchestrate collaborative projects and pilots aimed
at accelerating innovation and implementation. The D(R)YE Factory of the Future, consortium project for
example, was launched and orchestrated by Fashion for Good together with partners adidas, Kering, PVH
Corp., Arvind Limited, and Welspun India and several innovators in textile pre-treatment, colouration and
finishing. The project brings together several novel technologies with the aim of disrupting the current
processing of textiles in the fashion supply chain.
4
An Overview of Processing
During the processing stage, the fibres, yarns, fabrics or garments go through multiple steps to achieve
the performance and aesthetic properties desired by brands and their consumers. These steps can be
broadly categorised into pre-treatment, colouration and finishing treatments and make up most of the
impact and processes taking place in Tier 2.
Traditionally pre-treatment, colouration and finishing are referred to as wet processes as they take place
in large tanks or baths filled with water that is constantly kept at a high temperature4. Alongside the pre-
treatment, colouration and finishing steps, a significant amount of water and chemistry is wasted as the
fabrics also have to be washed off to remove excess dyes. Approximately 10-50% of dyes are washed out
in this process, ending up in the effluent water5.
5
An Overview of Processing
Fashion for Good divides the processing stage in two categories to help differentiate between the chemical
applied ie: chemistry and the process by which this chemistry is applied ie: machinery. An overview is
outlined below in Figure 2.
What are Durable Water and Oil Repellency (DW(O)R) and perfluorochemicals (PFCs)?
A number of solutions exist that would help reduce the use of water, energy and harmful chemistry
in this stage of the supply chain. Some of these are incremental solutions whilst others are disruptive
innovations. The next section briefly touches on some of these incremental solutions, you can learn more
about these solutions in Fashion for Good x Apparel Impact Institute (Aii)’s report ‘Unlocking the Trillion
- Dollar Fashion Decarbonisation Industry’. The report charts a trajectory for the industry to meet its net-
zero ambition, breaking down the funding needed and mapping the integral levers across existing and
innovative solutions.
7
Incremental Innovation
MACHINERY
There are opportunities to reduce GHG emissions by switching to renewable energy as well as implementing
process efficiency improvements, including better insulation, heat recovery and metering. The Apparel
Impact Institute focuses on implementing these improvements through their Clean by Design Programme.
A recent case study from a facility who had implemented the Clean by Design Programme showed up to
10% CO2 reduction (10% includes 4% reduction in natural gas, 5.8% in electricity, 5% in coal and 8% in
steam use) can be achieved14. An advantage of this approach is that the projects are low risk, meaning the
workflows of the textile mills are not disrupted and the performance of these technologies has already
been proven.
CHEMISTRY
A significant amount of effort from all supply chain stakeholders has been put into phasing out harmful
chemistry. Many brands have implemented restricted substances lists (RSLs) defined by organisations
like ZDHC and AFIRM and chemical manufacturers have developed chemistries that are non-hazardous
and less harmful.
Certifications from organisations such as Bluesign and OEKO-TEX help verify the content of these products
and are often a requirement of brands. Alongside this compliance with REACH (Registration, Evaluation,
Authorization and Restriction of Chemicals) legislation (European Union’s legislation on chemicals) is
required in order to be able to sell products in Europe.
However, there is still a long way to go to phase out all harmful chemicals as innovations need to also meet
the necessary performance requirements. In order to achieve a real step change, the industry needs the
disruptive innovations discussed later in this report.
8
Disruptive Innovation -
Machinery
The key solution to drastically reducing water and energy use in the processing stage of the fashion
supply chain lies within moving from wet processes to mostly dry processes. In other words, moving
away from processing in heated baths and tanks filled with water to machinery that require very little
to no water, as well as significantly less energy and chemistry. An additional benefit to most of these
technologies is that little to no wash off is needed.
Figure 3 and 4 below, show the potential impact this shift could have. Given wet processes’ significant
contribution to total CO2 emissions and water consumption, transitioning to mostly dry processes has
the potential to reduce emissions by up to 89%, and to cut water consumption by between 83% and 95%.
9
Disruptive Innovation - Machinery
10
Disruptive Innovation - Machinery
Figure 5 below illustrates some of these disruptive machinery innovations, including some of the innovative
companies working in this space.
11
Disruptive Innovation - Machinery
Plasma / Laser
Plasma, the fourth state of matter, is formed when gas is ionised and becomes more reactive. When
this ionised form of gas is applied to a substrate aka surface or fabric, it is able to alter its properties
i.e. activating its surface, removing impurities, depositing a coating. It is a waterless technology, has low
energy consumption and is effluent free.
MTIX*
MTIX has developed a multiplexed laser surface enhancement (MLSE®) system for textiles. The MLSE®
system creates a unique quantum mechanical energy milieu with laser plasma that enables durable
technical functionalities, finishes and pre-treatments on all fabric types in a high volume and continuous
process.
GRINP*
GRINP develops and produces machines using their proprietary atmospheric plasma technology. Their
industrial machines can replace traditional pre-treatments such as bleaching. The technology is fibre
agnostic.
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Disruptive Innovation - Machinery
Alchemie*
Alchemie has developed a digitally enabled spray/jetting technology which in combination with their
proprietary airflow technology is able to deeply penetrate the fibre. Their dyeing machine is called
Endeavour and their finishing machine is called Novara. In addition to these two machines, Alchemie has
developed a proprietary fixation process consisting of infrared radiation/heat which fixes the dyes to the
fabric. Their high precision means they can dye to shape as well as simple patterns. The technology is
compatible with traditional dyes and chemistry and can be used on polyester and cotton fabrics.
imogo*
imogo has developed a digitally enabled spray dyeing and finishing technology, which is used in their
Dye-max (dyeing) and F-max (finishing) machines respectively. They use the capillary forces in the
materials and the fibre’s natural absorption to get deep penetration. Both machines are compatible with
traditional dyes and chemistry and they are currently focusing on cellulosics. Fixation is done by traditional
methods such as cold batching.
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Disruptive Innovation - Machinery
eCO2Dye*
eCO2Dye has developed a dyeing technology using scCO2. The equipment is designed to dye a variety of
yarns and threads on conventional cones or packages using scCO2. Traditional dyes which are compatible
with scCO2 have been identified. The process uses existing CO2 which is recycled after each dyeing
process cycle. Pre-treatment (e.g scouring) and dye removal from waste textiles with supercritical CO2 is
in research and development (R&D). The technology can be used to dye polyester and wool yarns.
Deven Supercriticals*
Deven Supercriticals has developed a dyeing and finishing technology using scCO2. Rather than only
introducing the dye in the dyeing vessel, they precoat the fabric with dyes and chemicals before it enters
the dyeing vessel, using the scCO2 to improve their solubility in scCO2 with it before it enters the dyeing
vessel. This makes their technology compatible with traditional dyes and can be used to dye polyester,
cotton and cotton-polyester blends.
Sonovia*
Sonovia has developed a compact ultrasonic finishing machine and process that embeds Sonovia’s
customised chemistries for finishing applications directly into the fabric. To date, Sonovia has developed
antimicrobial and viral finishes as well as DWR, their technology is fabric agnostic.
Indidye*
Indidye uses sound waves to bind their proprietary natural plant based dyes to cellulosic fibres. The dyes
are extracted with a water based extraction process and then applied using the ultrasonic technology.
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Disruptive Innovation - Machinery
Foam Dyeing
Large foam bubbles carry dyestuff and when the bubbles burst, the pressure deposits the dye on the
fabric/yarn. This results in lower water and chemistry usage and as a result it is a more efficient process
than traditional dyeing.
Dope Dyeing
Dope dyeing is where pigments are added to the liquid solution before the fibres are spun or extruded into
yarn. It can be used for synthetic fibres like polyester and acrylic as well as for cellulosics. This process
uses less chemicals and energy and as the process is short, less wastewater is generated.
We aRe SpinDye*
We aRe SpinDye orchestrates the dope dyeing of polyester yarns for fashion brands. Brands get a quality,
compliance & traceability We aRe SpinDye®-certificate for all products they take off. This certificate also
states Life Cycle Assessment (LCA)-based impact savings compared with traditional dyeing processes.
Gravure Printing
Gravure is different from other printing processes as it prints from depressed, ink-filled cells that are
produced on the surface of a cylinder that is copper plated. The ink in these cells is transferred onto the
fabric. The process is digitally controlled to engrave the roller and therefore highly efficient. Traditionally
the gravure roller requires a transfer of the artwork onto a paper or film which is then transferred onto
the material substrate. It is a mostly waterless process that uses less energy than conventional dyeing.
NTX: Cooltrans*
NTX: Cooltrans provides a digitally enabled gravure printing method for both artworks and block colours.
Their technology is faster and more precise than other printing technologies and they use proprietary
inks (material restricted substance list (mRSL), ZDHC and RSL compliant) that are manufactured in-
house. Alongside this, for solid colour applications, their technology transfers from gravure to the material
without paper or film. It can be used on all fibre types except polyolefins.
Digital Printing
Digital textile printing is an inkjet-based printing method which enables printers to print high-quality
designs from a digital data file onto different fabrics. The ink is deposited in the form of minuscule droplets
by the digitally controlled printing heads. It is a mostly waterless process and reduced energy use as no
dye bath is needed.
Kornit
Kornit is an established digital printing technology company. They are classified as an innovator/innovative
company as they have developed a single step printing solution which combines fixation, dry softening
and full curing. It is fabric agnostic.
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Disruptive Innovation - Machinery
Ozone
Ozone, which is an alternative form of oxygen and a strong oxidising agent, can be used to clean / bleach
the garment, it’s most effective when used inside a washing machine to prevent the gas escaping and
to allow for its correct neutralisation. At the end of the process, any remaining ozone is converted back
into oxygen. Ozone pre-treatment and finishing reduces water, chemistry and energy consumption and
as a result there is also less effluent. Ozone is often used for finishing jeans and also has enhanced
performance benefits such as achieving the right shade of blue faster and with lower costs.
Laser
Laser technology is most commonly used as an alternative to manual scraping in denim production; it can
also be used to create vintage effects, whiskers, patterns, patches, and even intentional holes and tears in
a (denim) garment. Used in combination with other technologies such as ozone, it can replace traditional
processes like sandblasting and bleaching which are hazardous to workers’ health.
16
Disruptive Innovation - Machinery
The impact savings mentioned above raise the question as to why more textile mills have not switched to
mostly dry processes yet. Below we will elaborate on the challenges of this transition.
That said, while initial capex for some technologies are high, payback times can be as short as 1 to 2 years
as variable costs, from water, energy, and chemistry, are reduced15.
Performance
As with all new technologies, there are risks around the technology’s ability to meet minimum performance
requirements for different applications at scale. In addition, mostly dry technologies can impact the
handfeel of materials differently than wet technologies. Therefore it is important that the technologies
are optimised to achieve the same handfeel as the industry is accustomed to after wet processing.
17
Disruptive Innovation -
Chemistry
Although great progress has been made when it comes to innovation in sustainable chemistry there are
still a number of hazardous chemicals which can be found on ZDHC’s RSL and mRSL lists to which no
similar performing, less harmful alternative has yet been found. As such, disruptive innovation in this
space mostly focuses on finding competitive alternatives that could either replace a specific chemical in
a solution or by replacing a solution with a new formulation. Examples of this could include formulations
that are bio-based or based on a non-harmful chemistry like silicone. Figure 6 shows an overview of the
disruptive technologies and innovators. Below an overview of some of the most used processes in the
pre-treatment, dyeing, printing and finishing.
18
Disruptive Innovation - Chemistry
Cationic treatment
Chemistry innovations in pre-treatment are more limited than in dyeing and finishing. An example of
an incremental innovation in this space is cationic treatment. With this treatment, cotton is modified to
have a permanent cationic, or positive charge, making the cotton “friendlier” to dye and so increases its
dye uptake. Cationic treatments have the opportunity to enhance the dyeability of cotton but require
advanced effluent treatment as they can cause eutrophication.
Nano Dye
Nano dye has a salt-free cationic treatment that potentially does not result in high eutrophication. Salt is
commonly used in the pre-treatment process which then ends up in the effluent water, impacting the local
environment. Nano Dye’s technology is a drop-in solution that changes the charge of a cotton molecule
to the opposite charge of the dye to enhance dye uptake. It is used with cotton, other cellulosic fibres and
blends.
Enzyme treatment
Conventional scouring is harsh on fabrics and the environment. Enzymes can be used to modify the fabric
to become more receptive to dyes through processes such as bioscouring, they can be used in both pre-
treatment and finishing16. It is a more sustainable solution that allows savings in water, time and energy as
well as a reduction in the usage of harmful chemicals which improves worker safety.
Novozymes
Novozymes produces and develops biological solutions for textiles including enzymatic scouring, also
known as biopreparation or bioscouring.
NATURAL DYES/PIGMENTS
Natural dyes and pigments, from sources like algae and plants, have existed for centuries but have
historically been overlooked by the fashion industry due to inferior performance, limited colour palette
and higher prices than synthetic dyes. However, new disruptive cultivation, extraction and application
processes have the potential to overcome these barriers and enable the (re)implementation of natural
dyes at scale. Using natural dyes and pigments enables a shift away from synthetic chemistry and in some
instances the feedstock used ie: plants, algae or waste means the dyes and pigments have the potential
to be carbon negative.
19
Disruptive Innovation - Chemistry
DYES VS PIGMENTS
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Disruptive Innovation - Chemistry
Algae-based pigment
Living Ink*
Living Ink transforms waste microalgae material into a bio-based carbon black that can replace petroleum
derived carbon black. The pigment is jet black and UV stable. It can be used for screen printing on cotton,
cellulosics, blends, leather and polyester. Dope dyeing applications are in Research & Development (R&D).
AlgaeingTM*
Algaeing uses microalgae to manufacture dyes and inks in a closed system that can be used with existing
production machinery. It can be used to dye and print all types of fibre.
MICROALGAE VS MACROALGAE
• Macroalgae is a term used for seaweed and marine algae attached to the sea
bed. Outside of the textile industry, it has been used in other areas to produce
biofuels, cosmetics and soil fertilisers to name a few.
Macroalgae • It can only be grown in certain locations with specific conditions and usually
grows in coastal areas
• There are three types of macroalgae: brown, red and green
Source: Khan et al. (2018); FAO (2009), Usher et al. (2014), Campbell et al. (2019)
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Disruptive Innovation - Chemistry
Woodwaste-based pigment
Nature Coatings*
Nature Coatings transforms Forest Steward Council (FSC) certified wood waste into high performing and
cost competitive black pigments. Their pigments are a direct replacement for petroleum-based carbon
black pigments. The pigments and 100% bio-based dispersions can be used for screen printing on cotton,
cellulosics, blends, leather and polyester. Dope dyeing applications are in R&D.
Microbial pigments
Microbial pigments are either naturally occurring in organisms or artificially grown in genetically modified
organisms (GMO). Once the naturally occurring microbe is identified or a genetically modified microbe
strain has been engineered, the microbes get multiplied via fermentation by feeding them sugars and
other feedstock. After this process the pigments are extracted to be used in traditional dyeing processes.
Microbial pigments can replace synthetic pigments, and thereby reduce GHG emissions as well as the
amount of potentially harmful chemistry used.
Colorifix*
Colorfix uses microbial pigment technology to produce, deposit, and fix colour onto textiles. They
genetically modify microbes to produce a wide range of naturally-occurring pigments and ferment
them using renewable feedstocks. Rather than extract the dye from the bacteria, a costly downstream
processing step, Colorifix uses the broth the bacteria are fermented in as dye liquor. The technology can
be used to dye all fibres and fibre blends.
Huue*
Huue uses microbial pigment technology to produce dyes and pigments (GMO), with indigo dye as its
first product. After extracting the pigment from the bacteria and processing it, the bio-based dye can be
used as a drop-in replacement for synthetic Indigo, with high purity and with the same performance. The
pigments can be used to dye cotton fibres and any other substrates typically dyed with indigo.
KBCols Sciences*
KBCols Sciences use microbial pigment technology, using non-GMO naturally occurring coloured microbes
sourced from the soil, water and air, to extract different natural colours that can be applied in textiles and
other applications. The pigments can be used to dye most natural and synthetic fibres.
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Disruptive Innovation - Chemistry
ALTERNATIVE DYES/PIGMENTS
There are many alternative more sustainable dyes and pigments on the market or in development. These
include pigments made from captured carbon and recycled dyes made from old textiles.
Graviky Labs*
Graviky’s first product AIR-INK® is a range of inks and dyes made by end-of-use carbon emissions. The
black pigment can be used for different printing processes such as screen, sublimation and digital. Graviky
has tested AIR-INK on different surfaces such as paper, polyester and textiles. Dope dyeing applications
are in R&D.
Recycled dyes
Recycled dyes can either be produced through creating a very fine crystallised powder out of textile
waste and dyeing with this or chemically recovering dyes from fashion waste and redyeing other fabrics
with it. Using textile waste as a feedstock reduces the amount of syntetic chemistry used and allows for
a more circular process.
* Fashion for Good Alumni - Fashion for Good have supported over 135 innovators through our projects and programmes. 23
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Disruptive Innovation - Chemistry
Dryfiber*
Dryfiber provides a completely fluorine free, and hence also PFC-free DW(O)R textile finish. The solution
is silicon-based and can be applied through traditional finishing processes. The current focus is on
synthetic fabrics.
* Fashion for Good Alumni - Fashion for Good have supported over 135 innovators through our projects and programmes. 24
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Disruptive Innovation - Chemistry
Dimpora*
Dimpora creates more sustainable, highly breathable and waterproof membranes. Based on polymers, the
technology is PFC free and uses no Dimethylformamide (DMF) solvent. The company is further developing
recyclable, bio-based and biodegradable membranes to close the loop for high performance gear.
• The effective DW(O)R ingredient is applied via a liquid by running the fabric
through and immersing all its surface in the active substances. The chemistry
binds to the surface of the fibres. DW(O)R finishes make fabric water repellent,
meaning that water landing on fabric will form drops that can be easily wiped
off. However, longer contact with water or at a high pressure means the fabric
DW(O)R finish will likely absorb the water and/or let it pass through.
• One can think of a DW(O)R finish as a form of protection, like sunscreen
applied to human skin to protect it from the sun. The finish wears off over time
through movement, dirt and water, and therefore needs to be reapplied from
time to time to remain effective.
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They continue to be a part of our alumni network with Fashion for Good providing continued ongoing support
Disruptive Innovation - Chemistry
Nordshield*
Nordshield creates antibacterial, antiviral, antimould and insect repellent finishes based on waste from the
forestry industry. Nordshield forms a physical barrier on surfaces treated with their finish and therefore
prevents microbial growth at the sources. The finish can be applied to cotton, viscose and blends.
As seen in the previous chapter, there are many more sustainable chemistry solutions available. Some of
the reasons these have not yet been implemented in the supply chain relate to the following challenges.
Performance
Finding innovations in chemistry with the same performance characteristics as traditional chemistry is
challenging. If the performance of the more sustainable chemistry does not meet that of its traditional
counterpart, it will in most cases not be adopted on a large scale. Some of the key performance
characteristics challenging the fashion industry are listed below:
• Colour fastness of natural dyes - Performance of most natural dyes has often not met that of
synthetic dyes. In addition, due to common impurities in natural dyes it has shown to be difficult to
consistently reproduce a shade particularly across batches. As with synthetic dyes, natural dyes often
need other chemicals to bond with the substrate and usually more dye is required to achieve the same
depth of colour. As a result, ‘natural’ does not automatically equal better. Aside from challenges around
colour fastness, natural dyes are generally available in fewer colours and shades than synthetic dyes.
• Durability - Some treatments meet performance requirements immediately after application but lose
their effectiveness after wear and washing. Maintaining effectiveness after dry cleaning is especially
challenging.
• Durable Water and Oil Repellency - DW(O)R is a key property for textile materials, especially for
the outdoor industry. Historically, high performance has been achieved with the use of hazardous
PFCs. The non-hazardous or bio-based solutions currently available have not shown to yet meet this
performance across multiple testing criteria. Securing high oleophobicity scores has been particularly
challenging.
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Disruptive Innovation - Chemistry
COLOUR FASTNESS
To rate the washing, rubbing/crocking, and perspiration fastness the Grey Scale for Colour and/or the
Grey Scale for Staining, Rated from 1 (very poor) to 5 (excellent), are used. For light fastness, the Blue
Wool Scale, rated from 1 (very poor) to 8 (excellent), is to be used17.
Supply Chain
The supply chain for the chemical formulations currently available is well established and allows for large
scale production, while the supply chain of more innovative formulations is less developed and does often
not yet allow for large scale production Therefore, although performance on a pilot scale has been proven,
it can sometimes still be timely and challenging to scale these new technologies. This can cause difficulties
when working with brands and manufacturers as they need large quantities (in the thousands of tonnes)
for mass adoption. One potential solution to this is for innovators to collaborate with established chemical
manufacturers or toll blenders with large production capacities and expertise in scaling.
27
Driving the Transition
This document provides a snapshot in the processing innovation landscape, touching briefly on incremental
solutions and diving into the disruptive technologies that exist in both chemistry and machinery.
It is evident that there are a number of solutions that have the potential to save significant amounts of
water, energy and chemistry which results in a positive environmental impact as well as long term cost
savings. It is an area that is constantly evolving and one in which it is clear that collaboration is key to
success. Fashion for Good is pleased to be working together with our brand and manufacturing partners
as well as our global network of innovators to accelerate the adoption of these technologies into the
apparel and footwear supply chain.
If you would like to learn more about our current projects in this space please visit our website -
www.fashionforgood.com
28
Appendix
Below an overview of commonly used processes in pre-treatment, dyeing, printing and finishing can be
found.
Pre-treatment
Sources: Textile learner Jan 2022, Textile Engineering an Introduction By Yasir Nawab, Clothing Technology, 6th edition, Hannelore Eberle, Europa Lehrmittel
2013, Proprietary research with privileged access, contact Fashion for Good for more details if needed
29
FIGURE 9: OVERVIEW OF DIFFERENT PRE-TREATMENTS AND FUNCTIONALITIES
Appendix
Colouration
Dyeing is the application of dyestuff on textile materials such as fibres, yarns and fabrics
with the goal of achieving colour with desired colour fastness.
The dyestuff used is either a dye or pigment. The key difference between these two is
that dye chemically binds to the substrate while pigment does not. In Figure 11 below an
overview of the most commonly used dye types can be found.
Textile printing is the controlled process of applying defined areas of colour onto fabric.
While the main feature is pattern creation, it can also be applied for solid, all-over colours.
Sources: Textile Engineering an Introduction By Yasir Nawab, Environmental aspects of textile dyeing, Clothing Technology, 6th edition, Hannelore Eberle,
Europa Lehrmittel 2013, Proprietary research with privileged access, contact Fashion for Good for more details if needed
30
Appendix
Colouration
Most common, ~35% of all dyes used. Dye unites with fibre through a coupling agent
with heat. Excellent fastness to light and washing, brilliant shades. Requires soaping to
Reactive
remove unfixed dyes. Mostly used for dyeing cotton and linen and sometimes wool and
silk.
Added to water with a surface active agent since they are insoluble. Heat is applied
Dispersion to allow the fibre to swell and dye to penetrate. Mostly used for dyeing polyester and
sometimes viscose.
Usually applied under acidic conditions. Dissolve in water. Good light and heat fastness,
Acid poor washing fastness. Brilliant colours on silk and sometimes also used for dyeing
viscose and polyester.
Basic in character, can neutralise acids. Used on cellulosics with the help of a mordant.
Alkaline
Poor light fastness, good pressing fastness. Mostly used with acrylics.
From old-fashioned indigo dyeing: insoluble compounds that cause accelerated
Vat degradation of cotton. Resistant to light, acids and bleaches. Mostly used for dyeing
denim and sometimes also wool and silk.
Also called substantive colours. Applies through absorption rather than chemical
Direct reaction. Salt is added as an electrolyte. Poor fastness unless treated. Mostly used for
cotton and linen and sometimes wool and silk.
Insoluble and must be used with the help of caustic soda and sodium sulphide. Done at
Sulfur
high temperatures and large salt quantities. Only used for dyeing cotton and linen.
Sources: Textile Engineering an Introduction By Yasir Nawab, Environmental aspects of textile dyeing, Proprietary research with privileged access, contact
Fashion for Good for more details if needed
31
Appendix
Finishing
Sources: Textile Engineering an Introduction By Yasir Nawab, Proprietary research with privileged access, contact Fashion for Good for more details if
needed
32
Key Terms
• AATCC - The American Association of Textile Chemists and Colorists develops the test methods the
textile industry uses to ensure product quality.
• AFIRM - the Apparel and Footwear International RSL Management Group is a brand driven membership
organisation of apparel and footwear companies collaborating to promote chemicals management in
the global supply chain. AFIRM’s focus is on the continuous advancement of chemicals management
including phasing out or limiting restricted substances to established limits in apparel, footwear, and
accessories.
• Apparel Impact Institute - (Aii) is a collaboration of brands, manufacturers and industry associations
– including the Sustainable Apparel Coalition (SAC), the Sustainable Trade Initiative (IDH), Target,
PVH Corp., Gap and HSBC Holdings plc. - that have come together to select, fund and scale high
impact projects that dramatically and measurably improve the sustainability outcomes of the apparel
and footwear industry.
• Low pressure vs atmospheric plasma - Cold plasma technologies can be divided into low pressure
plasma and atmospheric plasma. The former happens in a vacuum chamber and therefore provides
higher performance and reproducibility, while the latter is more compatible with the textile industry as
it does nor require a vacuum chamber and thus allows for continuous processing
• Azo dyes - a large class of synthetic dyes whose molecules contain two adjacent nitrogen atoms
between carbon atoms. Studies have shown there are harmful effects of azo dyes on humans and
aquatic life which has aroused calls for effluents containing azo dyes to be treated to eliminate them
or convert them into useful and safe products.
• Bio-based - wholly or partly derived from materials of biological origin, excluding materials embedded
in geological formations and/or fossilised.
• Bioscouring - application of living organisms and their components to remove natural and added
impurities.
• Binder - add or stick to something any substance that causes the components of a mixture to hold
together.
• Bluesign - Bluesign eliminates harmful substances at each step of the supply chain. It certifies that
textile products are safe for the environment, workers, and customers. The Bluesign certification
applies to chemicals, processes, materials, and products.
• Capillary force - Capillary force is the process of a liquid flowing in a narrow space without the
assistance of, or even in opposition to, any external forces like gravity.
• Chemical Manufacturer - a workplace where chemicals are produced for use or distribution. A
chemical manufacturer has a legal obligation to evaluate the hazards of chemicals that they produce
or distribute.
• Chitosan - an environmentally friendly agent that is used to achieve the antimicrobial properties of
textiles. Nowadays, the binding of chitosan to the textiles has been thoroughly researched due to the
increasing demands on the stability of achieved properties during the textile care processes.
• Chromophores - the part of a molecule responsible for its colour.
• Clean by Design Programme - Clean by Design is a programme to use the buying power of
multinational corporations as a lever to reduce the environmental impacts of their suppliers abroad.
Clean by Design focuses on improving process efficiency to reduce waste and emissions and improve
the environment.
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Key Terms
• Colour Fastness - The ability of a dye to preserve the original colour during industrial processing and
subsequent customer use.
• Curing - the process by which resins or plastics are set in or on textile materials, usually by heating.
• Dimethylformamide (DMF) solvent - a colourless, water soluble liquid with a faint ammonia like
odour that is readily absorbed through the skin, inhaled, or ingested; a potent liver toxin.
• Drop-in solution - solution that is easily integratable or requiring only insertion to be ready for use.
• Drying - liquid is vaporised from a product by the application of heat. Heat may be supplied by
convection (direct dryers), by conduction (contact or indirect dryers), radiation or by placing the wet
material in a microwave or radio frequency electromagnetic field.
• Dry softening - softening process that does not require water or produce waste.
• Durability - How long and in what conditions a treatment stays effective on the garment.
• Effluent - liquid waste or sewage discharged into a river or the sea.
• Energy Milieu - In the context of MLSE®, Energy Milieu refers to the highly reactive molecular soup
created by quantum mechanical forces acting within specific reaction zones, where fabric gets treated.
This milieu consists of photons (a particle representing a quantum of light), bosons (a subatomic
particle), gluons (a hypothetical massless subatomic particle) and quarks (any of a number of
subatomic particles carrying a fractional electric charge) mixed with nano sized constituent particles,
virtually instantaneously, ablated from the fabric substrate itself and reconstituted within the fabric.
• Enzymes - An enzyme is a substance produced by a living organism which acts as a catalyst to bring
about a specific biochemical reaction.
• Eutrophication - Eutrophication is when there are too many nutrients in a body of water which can
then disrupt the ecosystem.
• Fermentation - The chemical breakdown of a substance by bacteria, yeasts, or other microorganisms,
typically involving effervescence and the giving off of heat.
• Fixation (dye) -crosslinking between fabric and dye molecules. Fixer is used on the textile to hold the
unfixed dye molecules on fabric through polymerisation between fabric and dyes.
• Forest Stewardship Council (FSC) - FSC is a non-profit organisation that promotes responsible
management of the world’s forests. FSC certifies forests all over the world to ensure they meet the
highest environmental and social standards. Products made with wood and paper from FSC forests
are marked with their ‘tick tree’ logo.
• Full Curing - a process during which a chemical reaction (such as polymerisation) or physical action
(such as evaporation) takes place, resulting in a harder, tougher or more stable linkage (such as an
adhesive bond) or substance.
• High Frequency Electric Discharge - electrical conduction through a gas in an applied electric field.
• Hydrolysing - break down (a compound) by chemical reaction with water.
• Ionised - converted (an atom, molecule, or substance) into an ion or ions, typically by removing one
or more electrons.
• ISO - International Organization for Standardization is an independent, non governmental international
organisation with a membership of 165 national standards bodies.
• Joint Venture - a business arrangement in which two or more parties agree to pool their resources
for the purpose of accomplishing a specific task.
• Metering - Accurate measurement of on-site energy and water use, which is critical in accounting for
current costs and recognising the benefits of efficiency measures.
• Microbe - A microorganism or microbe is a microscopic organism, which may be single-celled or
multicellular. The microbes most commonly associated with the production of materials for consumer
textiles include yeast, bacteria, fungi and algae.
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Key Terms
• Microporous - characterised by very small pores or channels with diameters in the micron or
nanometre range.
• Mordant - a chemical that fixes a dye in or on a substance by combining with the dye to form an
insoluble compound.
• Neutralisation - the act of making a substance neutral.
• Nozzle - an attachment to the end of a spray rod or hose that causes the liquid to be delivered finely
and evenly as a spray.
• OEKO-TEX - International Association for Research and Testing in the Field of Textile and Leather
Ecology consists of 17 independent research and test institutes in Europe and Japan. They are
responsible for the joint development of test methods and limit values which form the basis for our
standards.
• Oleophobicity - refers to the physical property possessed by a material that is characterised by a
lack of affinity to oils.
• PFAS - Per- and polyfluoroalkyl substances are a diverse group of human-made chemicals used in
a wide range of consumer and industrial products. Many PFAS are resistant to grease, oil, water, and
heat.
• PFC - Perfluorochemicals (PFCs) are a group of chemicals used to make fluoropolymer coatings and
products that resist heat, oil, stains, grease, and water
• Quantum Mechanical Energy - quantum mechanics, science dealing with the behaviour of matter
and light on the atomic and subatomic scale. It attempts to describe and account for the properties of
molecules and atoms and their constituents—electrons, protons, neutrons, and other more esoteric
particles such as quarks and gluons. These properties include the interactions of the particles with
one another and with electromagnetic radiation(i.e., laser light, X-rays, and gamma rays).
• Polymeric material/polymer - materials made of long, repeating chains of molecules. The materials
have unique properties, depending on the type of molecules being bonded and how they are bonded.
• REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals is a European Union
regulation which addresses the production and use of chemical substances, and their potential
impacts on both human health and the environment.
• Reactive - capacity of an atom or molecule to undergo a chemical reaction with another atom,
molecule, or compound.
• Substrate - the surface or material
• Supercritical/pressurised gas - A supercritical fluid is a highly compressed fluid that combines the
properties of gases and liquids.
• Surface Activation - alter the chemistry of surface introducing chemical groups or charges on the
surface.
• Toll Blender - a service whereby the production of (complex) chemical products is outsourced to a
third party company (blender).
• Wash off - With traditional wet processing, regardless of the dye type chosen, all dyeing ends with
washing baths to remove excess dyes not fixed to the fibre.
• ZDHC - Zero Discharge of Hazardous Chemicals Foundation oversees implementation of the Roadmap
to Zero Programme and is a global multi-stakeholder initiative of more than 160 contributors within
the fashion and footwear industry.
35
Notes & References
1 Note, it is not possible to dive into all technologies in great detail and Fashion for Good
acknowledges that this is a complex space
2 WRI and Aii (2021). Roadmap to Net Zero: Delivering Science-Based Targets in the Apparel
Sector. Available at: https://apparelimpact.org/wp-content/uploads/2021/11/21_WorkingPaper_
RoadmapNetZero_.pdf
3 WRI and Aii (2021). Roadmap to Net Zero: Delivering Science-Based Targets in the Apparel
Sector. Available at: https://apparelimpact.org/wp-content/uploads/2021/11/21_WorkingPaper_
RoadmapNetZero_.pdf
4 Except for printing
5 IntechOpen Textile Dyes: Dyeing Process and Environmental Impact
6 ZDHC Impact Report
7 ZDHC Roadmap to Zero, Jan 2022
8 ZDHC Roadmap to Zero, Jan 2022
9 ZDHC Impact Report
10 ‘What Brands Need to Know About Antimicrobial Fabrics and Textiles’, ‘Disinfecting for Covid-19:
The role of the US EPA’ ,’Hand Sanitisers and face masks’
11 ‘What Brands Need to Know About Antimicrobial Fabrics and Textiles’, ‘Disinfecting for Covid-19:
The role of the US EPA’ ,’Hand Sanitisers and face masks’
12 Antimicrobial Textiles from Natural Resources: Common and nano-antimicrobial textile finishes
13 NanoImpact: In vitro skin toxicity of CuO and ZnO nanoparticles: Application in the safety
assessment of antimicrobial coated textiles
14 Fashion for Good and Apparel Impact Institute ‘UNLOCKING THE TRILLION-DOLLAR FASHION
DECARBONISATION OPPORTUNITY: Existing and innovative solutions’
15 Innovator Reported
16 Enzymes for biopreparation, Nozoymes
17 Chapter 31 ‘The Care of Apparel Products’, Rin Textile Fashion; Materials, Design and Technology,
.K.NayakR.Padhye, 2015, Pages 799-822
18 Proprietary research with privileged access, contact Fashion for Good for more details if needed
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All rights reserved
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