Dododo
Dododo
Dododo
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Stanley A. Greene, in International Resources Guide to Hazardous Chemicals, 2003
Potassium hydroxide
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Olin Corp.
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Synthesis: Carbon with Two Heteroatoms, Each Attached
by a Single Bond
Peter D. Kennewell, ... Nicholas J. Westwood, in Comprehensive Organic Functional Group
Transformations, 1995
4.17.1.4.4 Miscellaneous reactions
Potassium hydroxide in methanol dehydrobrominated (138) to give (139) in 57% yield
<91JCS(P1)2575> whilst potassium t-butoxide gave a 30% yield of 1,1-dibromo-2-fluorostyrene
(140) from (141) <93JA5430>. Similar dehydrobrominations of the steroids (142) and (143)
gave (144) and (145), respectively, in high yields <60T149, 65RTC904>. The dibromothiolane
1,1-dioxide (146) condenses with bromoform under basic conditions to give 53% of (147)
<89AJC1307>. Bromination with loss of trimethylsilyl bromide from 1-bromo-1-trimethylsilyl-
2-ethylhex-1-ene (148) gives 92% of (149) <86MI 417-01>.
Potassium hydroxide is a strong base. In an aqueous solution, it decomposes into hydroxide ions and
potassium cations. A strong acid has the ability to neutralize it with water and salt. The products will
be a salt of potassium and water.
Salt may or may not be soluble in that salt. This type of reaction is called neutralization. The
indicator used is phenolphthalein.