Revision date: 02/05/2021 Revision: 3 Supersedes date: 11/02/2020

SAFETY DATA SHEET

NITOCOTE NT402 BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOCOTE NT402 BASE

Product number A1766220AE1, A1766240AE1, A1776010AE1, A1776074AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base component of two-part protective coating.

1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606

1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 1B - H360 STOT SE 3 - H335

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

Human health Contains a substance/a group of substances which may impair fertility. Contains a
substance/a group of substances which may damage the unborn child.

Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

2.2. Label elements

Hazard pictograms

Signal word Danger

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Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H360 May damage fertility or the unborn child.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
≤ 700), SILICA FLOUR, DIBUTYL PHTHALATE

Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 30-60%

(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

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SILICA FLOUR 10-30%

CAS number: 14808-60-7

Classification Classification (67/548/EEC or 1999/45/EC)

STOT RE 2 - H373 -

DIBUTYL PHTHALATE 5-10%

CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 10 M factor (Chronic) = 10
Substance of very high concern (SVHC).

Classification
Acute Tox. 3 - H331
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

XYLENE <1%
CAS number: 1330-20-7 EC number: 215-535-7 REACH registration number: 01-
2119488216-32-0000

Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315

ETHYLBENZENE <1%
CAS number: 100-41-4 EC number: 202-849-4

Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332
STOT RE 2 - H373
Asp. Tox. 1 - H304

IRON OXIDE BLACK PIGMENT <1%

CAS number: 1317-61-9

Classification
Not Classified

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ISO-BUTANOL <1%
CAS number: 78-83-1 EC number: 201-148-0

Classification
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
STOT SE 3 - H335, H336

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing. Get medical attention if any discomfort
continues.

Ingestion Get medical attention immediately. Rinse mouth thoroughly with water. Move affected person
to fresh air and keep warm and at rest in a position comfortable for breathing. Do not induce
vomiting. Never give anything by mouth to an unconscious person. Do not induce vomiting.

Skin contact Remove affected person from source of contamination. Get medical attention promptly if
symptoms occur after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information Get medical attention promptly if symptoms occur after washing.

Inhalation May cause respiratory irritation.

Ingestion Harmful if swallowed.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Eye contact Causes eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Toxic fumes Oxides of carbon.
products

5.3. Advice for firefighters

Protective actions during Cool containers exposed to flames with water until well after the fire is out.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective clothing, gloves and eye/face protection.Ensure adequate ventilation
/ exhaust.Keep unauthorized persons away. Avoid inhalation of vapours and contact with skin
and eyes.

6.2. Environmental precautions

Environmental precautions Prevent from entering into ditches, sewers, waterways and groundwater.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Absorb small quantities with paper towels and evaporate in
a safe place. Flush spilled material into suitable retaining areas or container with large
quantities of water.

6.4. Reference to other sections

Reference to other sections See Section 12 for additional information on ecological hazards.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Keep away from heat, sparks and open flame. Provide adequate ventilation.
Avoid inhalation of vapours. Use approved respirator if air contamination is above an
acceptable level. Avoid skin and eye contact. Do not eat, drink or smoke whilst using this
product. Wash hands thoroughly after handing this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
DIBUTYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
XYLENE
Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³
Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³
Sk
ETHYLBENZENE
Long-term exposure limit (8-hour TWA): WEL 100 ppm 441 mg/m³
Short-term exposure limit (15-minute): WEL 125 ppm 552 mg/m³
Sk
IRON OXIDE BLACK PIGMENT
Long-term exposure limit (8-hour TWA): 5 mg/m³ fume
Short-term exposure limit (15-minute): 10 mg/m³ fume
ISO-BUTANOL

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Long-term exposure limit (8-hour TWA): WEL 50 ppm 154 mg/m³

Short-term exposure limit (15-minute): WEL 75 ppm 231 mg/m³
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through the skin.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

DIBUTYL PHTHALATE (CAS: 84-74-2)

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³

Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l

- marine water; 1 µg/l

XYLENE (CAS: 1330-20-7)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³

Workers - Inhalation; Short term systemic effects: 289 mg/m³
Workers - Dermal; Long term systemic effects: 180 mg/kg/day

PNEC - Fresh water; 0.327 mg/l

- marine water; 0.327 mg/l
- STP; 6.58 mg/l

ETHYLBENZENE (CAS: 100-41-4)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³

Workers - Dermal; Long term systemic effects: 180 mg/kg bw/day

PNEC - Fresh water; 0.1 mg/l

- marine water; 0.01 mg/l

ISO-BUTANOL (CAS: 78-83-1)

DNEL Workers - Inhalation; Long term local effects: 310 mg/m³

PNEC - Fresh water; 0.4 mg/l

- marine water; 0.04 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

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Hand protection Wear protective gloves made of the following material: Rubber (natural, latex). Neoprene.
Polyvinyl chloride (PVC).

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Provide eyewash station. Use appropriate skin cream to prevent drying of skin. Wash at the
end of each work shift and before eating, smoking and using the toilet. Wash promptly with
soap and water if skin becomes contaminated. Promptly remove any clothing that becomes
contaminated. Do not smoke in work area. When using do not eat, drink or smoke.

Respiratory protection Respiratory protection may be required if excessive airborne contamination occurs.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Pigmented

Odour Slight.

Odour threshold Not determined.

pH Not determined.

Melting point Not determined.

Initial boiling point and range Not determined.

Flash point >160°C Pensky-Martens closed cup.

Evaporation rate Not determined.

Upper/lower flammability or Not determined.

explosive limits

Other flammability Not determined.

Vapour pressure Not determined.

Relative density 1.65 @ 20°C

Bulk density Not determined.

Solubility(ies) Insoluble in water.

Auto-ignition temperature Not determined.

Viscosity 300-500 P @ 20°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No additional information.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The following materials may react with the product: Amino, hydroxyl or carboxyl groups

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10.2. Chemical stability

Stability Stable under the prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous Hazardous polymerization will not occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Hazardous decomposition Fire creates: Thermal decomposition or combustion products may include the following
products substances: Acrid smoke or fumes. Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Reproductive toxicity
Reproductive toxicity - fertility Contains a substance/a group of substances which may damage fertility.

Inhalation Irritating to respiratory system.

Ingestion Toxic if swallowed.

Skin contact May cause sensitisation by skin contact. Irritating to skin.

Eye contact Irritating to eyes. Symptoms following overexposure may include the following: Redness.
Pain.

Route of exposure Ingestion. Skin and/or eye contact

Target organs Eyes Skin

Toxicological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)

Species Rat

Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,000.0

mg/kg)

Species Rabbit

Notes (dermal LD₅₀) LD₅₀ >1600 mg/kg, Dermal, Rat

ATE dermal (mg/kg) 20,000.0

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Skin corrosion/irritation

Animal data Rabbit Moderately irritating.

Skin sensitisation

Skin sensitisation May cause sensitisation by skin contact.

SILICA FLOUR

Carcinogenicity

IARC carcinogenicity IARC Group 1 Carcinogenic to humans.

DIBUTYL PHTHALATE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 8,000.0

mg/kg)

Species Rat

ATE oral (mg/kg) 8,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,860.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 20,860.0

Acute toxicity - inhalation

Acute toxicity inhalation 4.25

(LC₅₀ vapours mg/l)

Species Rat

ATE inhalation (vapours 4.25

mg/l)

Acute and chronic health INGESTION. May cause stomach pain or vomiting. Inhalation May cause
hazards respiratory system irritation. SKIN CONTACT. May cause skin irritation/eczema.
May cause sensitisation by skin contact. EYE CONTACT. Irritating to eyes.

XYLENE

Acute toxicity - dermal

ATE dermal (mg/kg) 1,100.0

Carcinogenicity

IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.

ETHYLBENZENE

Carcinogenicity

IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.

SECTION 12: Ecological information

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Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity The product contains a substance which is toxic to aquatic organisms.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Toxicity Ecotoxic to fish / daphnia / algae

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants

DIBUTYL PHTHALATE

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 1.6 mg/l, Salmo gairdneri

Acute toxicity - aquatic LC₅₀, 48 hours: 3.7 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 96 hours: 0.75 mg/l, Selenastrum capricornutum

plants

Chronic aquatic toxicity

M factor (Chronic) 10

XYLENE

Toxicity Not considered toxic to fish.

12.2. Persistence and degradability

Persistence and degradability This product is not expected to be readily biodegradable.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Persistence and The product is not readily biodegradable.

degradability

XYLENE

Persistence and Expected to be not readily biodegradable.

degradability

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12.3. Bioaccumulative potential

Bioaccumulative potential Not determined.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Partition coefficient log Pow: 3.242

12.4. Mobility in soil

Mobility The product is immiscible with water and will sediment in water systems.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Mobility The product has poor water-solubility.

Adsorption/desorption Water - Koc: 445 @ °C

coefficient

XYLENE

Mobility The product is insoluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
(ADR/RID) PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

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Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 02/05/2021

Revision 3

Supersedes date 11/02/2020

Hazard statements in full H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs (Lungs) through prolonged or repeated exposure.
H373 May cause damage to organs (Hearing organs) through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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