ES U3 Notes
ES U3 Notes
ES U3 Notes
Unit- 3
Water pollution:
Water pollution is the contamination of water bodies (like oceans, seas, lakes, rivers, aquifers,
and groundwater) usually caused due to human activities. Water pollution is any change in the
physical, chemical or biological properties of water that will have a detrimental consequence of
any living organism.
3. Mining activities
Mining is the process of crushing the rock and extracting coal and other minerals from
underground. These elements when extracted in the raw form contain harmful chemicals and can
increase the number of toxic elements when mixed up with water which may result in health
problems. Mining activities emit a large amount of metal waste and sulphides from the rocks
which is harmful to the water.
4. Marine dumping
The garbage produced by each household in the form of paper, aluminum, rubber, glass, plastic,
food is collected and deposited into the sea in some countries. These items take from 2 weeks to
200 years to decompose. When such items enter the sea, they not only cause water pollution but
also harm animals in the sea.
HYDROSPHERE:
This includes all the surface and ground water resources such as oceans, seas, rivers, streams,
lakes, reservoirs, glaciers, polar ice caps, ground water and water locked in rock and crevices and
minerals lying deep below the earth's crust. Fig.2
1. Earth is called blue planet because 80 per cent of its surface is covered by water (97 per
cent of the earth's water resources is locked up in the oceans and seas, 2.4 per cent is
trapped is giant glaciers and polar ice caps.) Only 1% of the total water supply is available
as fresh water in the form of rivers, lakes, streams and ground water for human
consumption and other uses.
2. Water is universal solvent.
3. Water is also the main medium by which chemical constituents are transported from one
part of an ecosystem to others.
4. Water has high specific heat, latent heat and relatively high freezing point.
5. Surface water contains a lot of organic matter and mineral nutrients, which feed large
bacteria population and algae.
1 ORGANIC POLLUTANT
Organic pollutants can be further divided in following categories:
a) Oxygen Demanding wastes:
The wastewaters such as, domestic and municipal sewage, wastewater from food processing
industries, canning industries, slaughter houses, paper and pulp mills, tanneries, breweries,
distilleries, etc. have considerable concentration of biodegradable organic compounds either
in suspended, colloidal or dissolved form. These wastes undergo degradation and
decomposition by bacterial activity. The dissolved oxygen available in the water body will be
consumed for aerobic oxidation of organic matter present in the wastewater. Hence, depletion
of the DO will be a serious problem adversely affecting aquatic life, if they DO falls below
4.0 mg/L. This decrease of DO is an index of pollution.
c) Oil:
Oil is a natural product which results from the plant remains fossilized over millions of years,
under marine conditions. It is a complex mixture of hydrocarbons and degradable under
bacterial action, the biodegradation rate is different for different oils, tars being one of the
slowest. Oil enters in to water through oil spills, leak from oil pipes, and wastewater from
production and refineries.
Being lighter than water it spreads over the surface of water, separating the contact of water
with air, hence resulting in reduction of DO. This pollutant is also responsible for endangering
water birds and coastal plants due to coating of oils and adversely affecting the normal
activities.
It also results in reduction of light transmission through surface waters, thereby reducing the
photosynthetic activity of the aquatic plants.
Oil includes polycyclic aromatic hydrocarbons (PAH), some of which are known to be
carcinogenic.
2. PATHOGENS
The pathogenic microorganisms enter in to water body through sewage discharge as a major
source or through the wastewater from industries like slaughterhouses. Viruses and bacteria
can cause water borne diseases, such as cholera, typhoid, dysentery, polio and infectious
hepatitis in human.
3. NUTRIENTS
The agriculture run-off, wastewater from fertilizer industry and sewage contains substantial
concentration of nutrients like nitrogen and phosphorous. These waters supply nutrients to the
plants and may stimulate the growth of algae and other aquatic weeds in receiving waters.
• Thus, the value of the water body is degraded.
• In long run, water body reduces DO, leads to eutrophication and ends up as a dead pool of
water.
• People swimming in eutrophic waters containing blue-green algae can have skin and eye
irritation, gastroenteritis and vomiting. M.M. Ghangrekar, IIT Kharagpur 3
• High nitrogen levels in the water supply, causes a potential risk, especially to infants under
six months. This is when the methaemoglobin results in a decrease in the oxygen carrying
capacity of the blood (blue baby disease) as nitrate ions in the blood readily oxidize ferrous
ions in the hemoglobin.
5. INORGANIC POLLUTANTS
Apart from the organic matter discharged in the water body through sewage and industrial
wastes, high concentration of heavy metals and other inorganic pollutants contaminate the
water. These compounds are non-biodegradable and persist in the environment. These
pollutants include mineral acids, inorganic salts, trace elements, metals, metals compounds,
complexes of metals with organic compounds, cyanides, sulphates, etc. ¾ The accumulation
of heavy metals may have adverse effect on aquatic flora and fauna and may constitute a
public health problem where contaminated organisms are used for food. ¾ Algal growth due
to nitrogen and phosphorous compounds can be observed. ¾ Metals in high concentration can
be toxic to biota e.g. Hg, Cu, Cd, Pb, As, and Se. Copper greater than 0.1 mg/L is toxic to
microbes.
6. THERMAL POLLUTION
Considerable thermal pollution results due to discharge of hot water from thermal power
plants, nuclear power plants, and industries where water is used as coolant. Wastewater
Management 4 As a result of hot water discharge, the temperature of water body increases,
which reduces the DO content of the water adversely, affecting the aquatic life. This alters
the spectrum of organisms, which can adopt to live at that temperature and DO level. When
organic matter is also present, the bacterial action increases due to rise in temperature; hence,
resulting in rapid decrease of DO. The discharge of hot water leads to the thermal
stratification in the water body, where hot water will remain on the top.
7. RADIOACTIVE POLLUTANTS
Radioactive materials originate from the following: Mining and processing of ores Use in
research, agriculture, medical and industrial activities, such as I131, P32, Co60, Ca45, S35,
C14, etc. Radioactive discharge from nuclear power plants and nuclear reactors, e.g., Sr90,
Cesium Cs137, Plutonium Pu248, Uranium-238, Uranium-235, Uses and testing of nuclear
weapons.
• These isotopes are toxic to the life forms; they accumulate in the bones, teeth and can cause
serious disorders.
• The safe concentration for lifetime consumption is 1 x 10-7 micro-curies per ml.
Trace elements contamination of water:
What are trace contaminants?
Trace contaminants and residues are incredibly small particles or microorganisms that can
make their way into our food system. These particles or microorganisms can include
anything from bacteria to pesticides to minerals found in or on consumables like food and
water.
Trace elements (or trace metals) are minerals present in living tissues in small amounts.
This chapter is a summary of the role of the following essential trace elements in the
etiology and prevention of chronic diseases: iron, zinc, fluoride, selenium, copper,
chromium, iodine, manganese, and molybdenum.
DO (Dissolved Oxygen):
A DO test measures the concentration of oxygen dissolved in a water or wastewater
sample.
DO measurement most often takes place using an electronic meter fitted with a
specialized DO probe.
The concentration of DO in a water sample is significantly influenced by:
o Temperature: As water temperature increases, DO decreases (i.e., as water gets warmer,
it holds less oxygen) (Table 2).
o Salinity: As water salinity increases, DO decreases (i.e., as water gets saltier, it holds less
oxygen).
o Atmospheric Pressure: As pressure increases, DO also increases (i.e., water holds less
oxygen as you increase altitude).
Determination:
Specialized 300 mL BOD bottles designed to allow full filling with no air space and
provide an airtight seal are used. The bottles are filled with the sample to be tested or
dilution (distilled or demonized) water and various amounts of the wastewater sample are
added to reflect different dilutions. At least one bottle is filled only with dilution water as
a control or "blank."
A DO meter is used to measure the initial dissolved oxygen concentration (mg/L) in each
bottle, which should be a least 8.0 mg/L.
BOD (Biochemical oxygen demand):
BOD is the traditional, most widely used test to establish concentration of organic matter
in wastewater samples (i.e., relative strength).
BOD is based on the principle that if sufficient oxygen is available, aerobic biological
decomposition (i.e., stabilization of organic waste) by microorganisms will continue until
all waste is consumed.
Determination:
The BOD test is also known as "BOD5" since it is based on the accurate measure of DO
(dissolved oxygen) at the beginning and end of a five-day period in which the sample is
held in dark, incubated conditions (i.e., 20°C or 68°F).
The change in DO concentration over five days represents the "oxygen demand" for
respiration by the aerobic biological microorganisms in the sample.
The five-day completion window is an inherent disadvantage of the test because
wastewater treatment system personnel cannot use it to make real-time operational
adjustments.
An extended UBOD (ultimate BOD) test that measures oxygen consumption after 60
days or more is sometimes required in wastewater permits.
COD is the most popular alternative test to BOD for establishing the concentration of
organic matter in wastewater samples.
Significance:
1. It is useful in designing of treatment plants & calculation of waster load
2. The higher the BOD of a sample the higher will be pollution
3. It helps in pollution control.
Significance:
1. It measures the effect of pollutants on dissolve oxygen.
2. It helps in designing & calculation of efficiency of the water treatment plants.
3. It helps in deciding the disposal of domestic & industrial effluents in various types of
water streams.
Eutrophication:
Introduction:
Eutrophication is the process in which a water body becomes overly enriched with nutrients,
leading to plentiful growth of simple plant life. The excessive growth (or bloom) of algae and
plankton in a water body are indicators of this process.
Eutrophication is considered to be a serious environmental concern since it often results in
the deterioration of water quality and the depletion of dissolved oxygen in water bodies.
Eutrophic waters can eventually become “dead zones” that is incapable of supporting life.
Aquatic ecosystems are home to several plant and animal life forms – both simple and
complex. The process of eutrophication destroys the balance in these ecosystems by favoring
the growth of simple plant life. This greatly decreases the biodiversity of the ecosystem by
killing off several desirable species.
Causes of Eutrophication-
The availability of nutrients such as nitrogen and phosphorus limits the growth of plant life in an
ecosystem. When water bodies are overly enriched with these nutrients, the growth of algae,
plankton, and other simple plant life is favored over the growth of more complex plant life.
Phosphorus is considered one of the primary limiting factors for the growth of plant life in
freshwater ecosystems. Several sources also claim that the availability of nitrogen is an important
limiting factor for the growth of algae.
Phosphates tend to stick to the soil and are transported along with it. Therefore, soil erosion is a
major contributor to the phosphorus enrichment of water bodies. Some other phosphorus-rich
sources that enrich water bodies with the nutrient include:
Fertilizers
Untreated sewage
Detergents containing phosphorus
Industrial discharge of waste.
Among these sources, the primary contributors to eutrophication include agriculture and
industrial wastes.
The excessive growth of algae in eutrophic waters is accompanied by the generation of a large
biomass of dead algae. These dead algae sink to the bottom of the water body where they are
broken down by bacteria, which consume oxygen in the process. The overconsumption of
oxygen leads to hypoxic conditions (conditions in which the availability of oxygen is low) in the
water. The hypoxic conditions at the lower levels of the water body lead to the suffocation and
eventual death of larger life forms such as fish.
Grit Chamber:
Grit is removed from wastewater to minimize abrasion to pumps and equipment, and to prevent
the accumulation of grit in treatment units, particularly sludge treatment and storage units, which
would reduce the capacity of those units. Velocity of wastewater flow is controlled so that
material (coffee grounds, sand, eggshells, etc.) will settle out.
Grit is typically disposed of in sanitary landfills; however, other options include incineration and
land application. Grit Channels: o Hand-cleaned or mechanically cleaned horizontal channel.
Flow of wastewater is reduced to around 1 foot per second to allow grit to settle. Cleaning the
grit form the channel is important to maintain grit removal efficiency. Cleaning the channel helps
to keep the flow velocity of wastewater low. As more grit builds up, the velocity of wastewater
increases and removal efficiency decreases. Fig. 1, other grit removal technologies:
a) Aerated grit chambers
b) Centrifugal grit separators
Primary Treatment:
Primary Treatment is a physical (non-biological) treatment process that takes place in a tank and
allows substances to settle or float, and be separated from the water being treated.
Remove settleable and floating solids prior to secondary treatment.
Flow controlled (reduced) so that settle able solids fall to bottom of tank and lighter materials
rise to water surface. Primary Sedimentation tanks are also called primary clarifiers. The layer of
solids that settle out is sometimes referred to as the sludge blanket. Solids that settle out in the
primary clarifier must be removed (wasted) periodically to digestion. Floating material is
removed by a surface skimmer and conveyed to the digestion process. If sludge removed is
watery and not substantial, the removal rate may be too high. Sludge is settleable solids
separated from liquids during processing, or deposits of foreign materials on the bottoms of
streams or other bodies of water. Fig.2
Passage of the waste water over the media provides dissolved oxygen which the bio-film layer
requires for the biochemical oxidation of the organic compounds and releases carbon
dioxide gas, water and other oxidized end products. As the bio film layer thickens, it eventually
sloughs off into the liquid flow and subsequently forms part of the secondary sludge. Typically, a
trickling filter is followed by a clarifier or sedimentation tank for the separation and removal of
the sloughed film. Other filters utilizing higher-density media such as sand, foam and peat moss
do not produce a sludge that must be removed, but require forced air blowers and backwashing
or an enclosed anaerobic environment. Fig.4
Tertiary Treatment:
Chemical Precipitation of Phosphorus
Chemical addition process using aluminum or iron added to the aeration tank effluent ahead
of the secondary clarifier to chemically bond to phosphorus. Metal-phosphorus compound
settles out in secondary clarifier. Easy process to add on to existing activated sludge process.
Does not require anaerobic zone.
Chlorination
• Chlorine solution can be generated from mixing chlorine gas with treated effluent or
purchased commercially as sodium hypochlorite solution.
• Chlorine solution is added to clarified effluent from secondary clarifiers.
• Good initial mixing of chlorine solution and clarifier effluent is important to process
efficiency.
• Effluent after addition of chlorine solution passes through “chlorine contact tank”. Tank
provides detention time needed to insure contact of the disinfectant with the organisms.
• Contact tanks sized for a minimum of 30 minutes of hydraulic detention time at design
annual average daily flow.
Digestion -
Continued biological treatment of the sludge wasted from the primary and secondary
treatment processes to reduce volatile solids (organic) content.
• Digestion carried out by aerobic bacteria in an aerated tank.
• Capable of up to 50% reduction in volatile solids content.
• Volatile Solid Reduction efficiency depends on temperature and on length of time sludge
remains in the digester.
• Does not generate a usable gas end-product such as the methane gas produced by anaerobic
digestion process.
Anaerobic Digestion:
Digestion carried out by anaerobic bacteria in a heated, unaerated tank.
• Capable of up to 50% reduction in volatile solids content, depending on temperature and
length of time sludge remains in digestion.
• For best efficiency, sludge in tank should be heated to 95°F.
• Methane gas is generated by biological action of the bacteria. Acid forming bacteria
consume the volatile organic solids creating organic acids. Methane-forming bacteria then
convert the organic acids to methane gas.
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