2012 Kcse Chemistry Paper 2 MS Word

5.4.
2 Chemistry Paper 2 (233/2)
1. (a)
Cl Cl Cl H
I ! H-C-C-H
Cl — C — C -H ©
H Cl ✓
Cl H
(b) Bubble each through acidified potassium dichoromate (VI) V1 with ethene the
solution changes from orange to green 4/ while in ethane the solution remains
orange. vx
Bubble each through acidified Potassium manganate(VII) a 1 with ethene the

solution changes from purple \o\ V- colourless while in ethane the solution
remains purple. ^ /
Add a few drops of bromine water a 1 with ethene the solution changes from orange/
brown vZ to colourless, while in ethane the solution remains orange / brown, v'/
Ethene burns with yellow or sooty flame. Ethane

bums with non-luminous or blue flame.
Choose any 2
(c) (i) Concentrated sulphuric (VI) acid or ALO or H PO . Vl
(ii) - CH-CHr
1
✓
-CH,
(iii) 2CH3CH2COOH + Na2C03 -*2CH3CH2COONaaq)+ C02(g) + H20 (1)
(iv) 2CH3CH2CH2OH + 902 6CO, + 8H O (1)
Moles of CO 2 =
QA)
Moles of CRCH„CH„OH IB ^
22 = 1 24 3
R.M.M. of CH3CH2CH2OH = 60 (V2)
24 Mass
X
3 = _L». x 4- x 60 = 15 g (1/z)
(a) C V ( l ) has the smallest atomic radius and is the most electronegative element in the
periodic table. Vl / as one traverses the period number of protons increases hence the
nuclear attraction increases.
(b) (i) AB2/AB/C02 or CO Vl (ii) Covalent

bond V1
296
D
(0 |
D j ✓
(a) (i) Concentrated Vl sulphuric (VI) acid.
(ii) Potassium nitrate Vl
(iii) To condense the fumes or vapour of nitric (V) acid into liquid Vl
(b) (i) Nitric acid (V) will corrode the rubber Vl
(ii) The reaction produces nitrogen monoxide (colourless) 4/ which is oxidised by oxygen
from the air to form nitrogen(IV) oxide. 4/
(c) (i) •
•
•
Water
Alkanes
Biogas
V 'A
any 2
• Water gas
(ii) NH + HNO, ->NH„N(X Vl
Mass of NH4N03 = 80 VX either
Moles of NH4NO = 4800 x 10s = 6

xlO4
80
.4 J/
Moles of NH3 = 6 x 1 0
Mass of NH. 6
x
= 1020 kg
(iii) Explosives eg. T.N.T. *\J
Production of polymers (terylene)
Textile dyes. any 2
?
Manufacture of drugs
297
Surface area/particle size Vl. (i)
(iii) PbCO, + 2HNO ^ Pb(NO ) Vl + CO + HO

J
(S)
3
(aq) (g)
322 2
(0
With hydrochloric acid an insoluble lead chloride is formed, which coats the
lead carbonate VX preventing the reaction between the acid and the carbonate from
proceeding. Vl
The reaction would shift to the left changing the solution from colourless to yellow/
orange Vl. Addition of HC1 creates excess H+ which disturbs the equilibrium so it
shifts to the left to get rid of the excess H+ ions. Vl
(i) The anode is X. Vl Since hydrogen is liberated at the cathode which is Y. Vl
40H
(aq) -> 2H O + O, +4e.Vl
2
W 2(g)
The hydrogen ions and hydroxide ions which form water (1) are discharged at the
electrodes leaving MgS04 concentrated. The amount of water electrolysed is more than the
amount of water formed at the anode. Vl
298
(iv) Blue litmus remains VV2 blue while the red litmus remains redVVz. Indicating that the
solution is neutral. Vl
(b) Quantity of electricity - 0.3 x 30 x 60

= 540 Vl
Oxygen requires 4 Faradays VX of electricity
24 dm3 = 4 x 96500 4/
? = 540
24 X 540
- = 0.32 dm3
4 x 96500
(c) Electroplating
Purification of metals
(a) (i) Cu2+Vl
(ii) CuC03 Vl / ZnS04 Vl
(b) Ba2+ + SO.2" - BaSO. Vl

(aq)
4
(aq) (s)
(c) The solution changes from blue to colourless Vl and a brown solid is formed. Vl The
magnesium which is above copper in the reactivity series displaces the copper ions Vl
from the solution. Apparatus become warm. The reaction is exothermic.
(d (i) Add nitric (V) acid to lead oxide, filter//^, add a soluble sulphate/ sulphuric acid to the
) filtrate 4/. Filter VX, and wash residue with distilled water VV 2 to remove traces of
the filterate, then dry residue between VX filter papers /oven.
(ii) Determine the melting Vl point, if it is pure the melting point will be
constant. Vl
(a) (i)
299
Cl O
Mas 0.07 1.12
s
RA 35.5 16
M
Mol 0.07 1.12
es 35.5 16
0.02 0.07
0.02 0.02
1 7
2
2 7
piric formu C1207 NaCIO

al la Vi (aq)
Sterilising drinking water supplies V Manufacture of hydrochloric

acid V Manufacture of plastics V Manufacture of chloroform V
Manufacture of bleaching agents V
(Any 2)

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5.4.

2 Chemistry Paper 2 (233/2)

Bubble each through acidified Potassium manganate(VII) a 1 with ethene the

Ethene burns with yellow or sooty flame. Ethane

(c) (i) Concentrated sulphuric (VI) acid or ALO or H PO . Vl

(iii) 2CH3CH2COOH + Na2C03 -*2CH3CH2COONaaq)+ C02(g) + H20 (1)

(iv) 2CH3CH2CH2OH + 902 6CO, + 8H O (1)

R.M.M. of CH3CH2CH2OH = 60 (V2)

(b) (i) AB2/AB/C02 or CO Vl (ii) Covalent

(a) (i) Concentrated Vl sulphuric (VI) acid.

(ii) Potassium nitrate Vl

(b) (i) Nitric acid (V) will corrode the rubber Vl

(ii) NH + HNO, ->NH„N(X Vl

Mass of NH4N03 = 80 VX either

Moles of NH4NO = 4800 x 10s = 6

(iii) PbCO, + 2HNO ^ Pb(NO ) Vl + CO + HO

(i) The anode is X. Vl Since hydrogen is liberated at the cathode which is Y. Vl

(b) Quantity of electricity - 0.3 x 30 x 60

(a) (i) Cu2+Vl

(ii) CuC03 Vl / ZnS04 Vl

(b) Ba2+ + SO.2" - BaSO. Vl

piric formu C1207 NaCIO

Sterilising drinking water supplies V Manufacture of hydrochloric

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