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    Rankers Group: (Organic Chemistry)

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    keshav
    The document contains information about organic chemistry reactions and compounds. It includes 13 multiple choice questions in Section 1 about the products of reactions, order of reagents, pKa values, IUPAC names and more. Section 2 provides 5 multi-step reaction problems asking to identify compounds A through E based on given reactions and properties. Section 3 shows a single reaction problem with unknowns to be identified. The answer key is provided for the 13 multiple choice questions in Section 1.

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    Rankers Group: (Organic Chemistry)

    Uploaded by

    keshav
    42 views7 pages
    The document contains information about organic chemistry reactions and compounds. It includes 13 multiple choice questions in Section 1 about the products of reactions, order of reagents, pKa values, IUPAC names and more. Section 2 provides 5 multi-step reaction problems asking to identify compounds A through E based on given reactions and properties. Section 3 shows a single reaction problem with unknowns to be identified. The answer key is provided for the 13 multiple choice questions in Section 1.

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    The document contains information about organic chemistry reactions and compounds. It includes 13 multiple choice questions in Section 1 about the products of reactions, order of reagents, pKa values, IUPAC names and more. Section 2 provides 5 multi-step reaction problems asking to identify compounds A through E based on given reactions and properties. Section 3 shows a single reaction problem with unknowns to be identified. The answer key is provided for the 13 multiple choice questions in Section 1.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    42 views7 pages

    Rankers Group: (Organic Chemistry)

    Uploaded by

    keshav
    The document contains information about organic chemistry reactions and compounds. It includes 13 multiple choice questions in Section 1 about the products of reactions, order of reagents, pKa values, IUPAC names and more. Section 2 provides 5 multi-step reaction problems asking to identify compounds A through E based on given reactions and properties. Section 3 shows a single reaction problem with unknowns to be identified. The answer key is provided for the 13 multiple choice questions in Section 1.

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    (Organic Chemistry) Rankers Group

    SECTION - 1
    1. The product " X " in the following reaction is

    (A) a racemic mixture of ester (B) an optically inactive ester


    (C) an optically active ester (D) a meso ester
    2. The sequence of reagents required for the following conversion is

    (A) (i) B2 H6 /H2 O2 /OH − (ii) Na (iii) C2 H5 I (B) (i) HCl (ii) C2 H5 ONa
    (C) (i) H3 O+ (ii) Na (iii) C2 H5 OH (D) (i) H3 O+ (ii) Na (iii) C2 H5 Cl
    3. Compound ' X ' in the following reaction is

    haloform

    (A) (B)

    (C) (D)
    4. The order of pK a values of the following acids is

    (A) IV > I > III > II (B) III > IV > I > II
    (C) II > I > III > IV (D) II > III > I > IV

    APNI KAKSHA 1
    5. The major product of the following reaction is
    if nh2 present in place
    of nme2 then para
    meta directing 51% ...as edg
    increses in form of
    ch3 ,,basicity
    increases.

    (A) (B)

    (C) (D)
    6. Compound X(pK a ∼ 15) and Y(pK a ∼ 10), both produce H2 one treatment with sodium metal
    and both yield a mixture of isomers on mononitration. X and Y respectively are:

    (A) IV, I (B) III, II (C) III, I (D) I, III


    7. The monosaccharide present in the following disaccharide is

    (A) (B) (C) (D)

    APNI KAKSHA 2
    8. The IUPAC name of the following compound is

    (A) 1 - Bromo - 4 − chloro -3 etheny ibutane


    (B) 4 - Bromon -1 - chloro -3 ethenylbutane
    (C) 3 − (Bromomethyl) -5 - chloropent - 1 - ene
    (D) 3 − ( Bromomethyl) −1 − chloropent -4 - ene
    9. The correct order of boiling points of the following compounds is

    (A) III < IV < II < I (B) I < III < IV < II
    (C) I < II < III < IV (D) IV < III < I < II
    10. Compound ' P ' that undergoes the sequence of reactions given below to give the product Q is

    (A) (B)

    (C) (D)

    APNI KAKSHA 3
    11. The correct sequence of reagents from those listed below for the following conversion is-

    (I) NaNH2 (II) Br2


    (III) H2 /Pd − C, quinoline (IV) H3 O+
    (A) IV - I – III (B) III −IV − I
    (C) II − I − III (D) I - II – III
    12. The compound ' X ' undergoing the following reaction is

    (A) (B)

    (C) (D)
    13. The major product of the following reaction is

    (A) (B)

    (C) (D)
    APNI KAKSHA 4
    SECTION - 2
    1. An organic compound (A) C5H9Br, which readily decolourise Br2 water and KMnO4 solution
    gives (B), C5H11Br on treatment with Sn/HCl. The reaction of [A] with NaNH2 produces [C]
    with evolution of ammonia. (C) neither reacts with Na nor forms any metal acetylide but reacts
    with lindlar catslyst to give [D] and on reaction with Na/liq, NH3 produces [E]. Both [D] and [E]
    are isomeric. Give structure of [A] to [E] with proper resonating.
    2. An organic compound (A), C7H7Cl gives two isomeric mononitro derivatives (B) and (C). (A)
    does not give a ppt with alcoholic AgNO3 but on oxidation with KMnO4 gives [D] C7H5O2Cl
    which on heating with sodalime gives C6H5Cl. On treatment with KNH2 in liquid NH3 (A) gives a
    mixture of isomeric products E (minor) and F (major) of formula C7H9N. Both [E] and [F] can be
    diazoxised and coupled with alk. naphtol. [E] but not [F] on diazotizationand warming with
    CuCl gives back (A). Give structures of all and explain the formation of [E] and [F] from [A].
    3. A hydrocabron (A) , of the formula C8H10, on ozonolysis gives compound (B) C4H6O2 only. The
    compound (B) can also be obtained from the alkyl bromide (C), C3H5Br upon treatment with Mg
    in dry ether followed by CO2 and acidification. Identify (A), (B) and (C) and also gives equations.
    4. An organic compound ‘A’ C10H12O gives red color when treated with cerric ammonium nitrate
    solution and also decolourizes bromine water in carbon tetra chloride to give an addition product
    ‘B’.C10H12OBr2 ‘A’ can show both geometrical and optical isomerism. ‘A’ on treatment with 12
    in NaOH gives iodoform and an acid ‘C’ after acidification. Give the structures of ‘A’ to ‘C’ and
    also all the stereoisomers of ‘A’.
    5. An organic compound ‘A’ (C15H13ON) decolourises Bayer’s reagent. On strong oxidation ‘A’
    given 2 acids ‘B’ and ‘C’ which are separated by fractional crystallization. ‘B’ provide bernzoic
    acid and ‘C’ is an important industrial product used for the manufacturing of terylene. Deduce the
    structures of ‘A’, ‘B’ and ‘C’.

    APNI KAKSHA 5
    SECTION - 3
    1. Find the unknowns.

    APNI KAKSHA 6
    ANSWER KEY
    SECTION - 1
    1. (C) 2. (D) 3. (C) 4. (D) 5. (C) 6. (D) 7. (A)
    8. (C) 9. (B) 10. (B) 11. (C) 12. (C) 13. (A)

    APNI KAKSHA 7

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