Msds Safety: (Material

MSDS (Material Safety Data Sheet)
T . CHEMICAL PRODUCT & COMPANY IDENTIFICATION

Product Name : SPU-5303S
Product description : Skin
Manufactory : SAMHO CHEMICAL CO., LTD.
Address - 6, ¥EDANGSANDAN3GIL, GODUEK-M¥UN, YESAN
—GUN, CHEUNGCHEONGNAM—DO. KOREA
Telephone Number : 82—3 \ -355-42 T 5
Oftice . Technical LAB
Urgency phone Nurrfer - 82-31-355-4215
2. HAZARDS IDENTIFICATION
A. Classification of the substance and mixture

Flammable liquid Category 2.
Acute toxicity Cat. 4(inhalation—vapor)
Specification target organ toxicity following single exposure ” Cat.1
Specific targef organ toxicity following repeat exposure Cat. 3
B. Label elements and precautionary statement

Pictogram
Signal Word Dangerous

Hazard statement
H225 Highly flammable liquid and vapor
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H370 Causes damaee to oreans
Precautionary statement(Prevention)
P210 Keep away from heat/sparks/open flames/hot surfaces
P233 Keep container tightly closed
P240 Ground/Bond container and receivin0 equipment
P241 Use explosion—proof electrical/lighting
P242 Use only non-sparking tools
Precautionary statement(Response)
P303*P361+P353 IF ON SKIN : Take off immediately all contaminated clothing, wash with
plenty of soap and water
P370+P378 In case of fire use water/water spray/carbon dioxide/sand/foam/alcohol resistant
foam/chemical powder for extinction.
P307+P3 11 If exposed call a Poison center or doctor/physician
P304+P340 Remove person to fresh air and keep comfortable for breathing
P312 Call a Poison center or doctor/physician
Precautionary statement(Storage)
P403+P235 Store in well—ventilated place. Keep container tiehtly closed. Store locked up.
P405 Store locke p.
P403+P233 Store in well—ventilated Dlace. Keeo the container tightly closed.
Precautionary statement(Disposal)
P501 Disposal of contents/container in accordance with IOcaI, re8ional, national and
international regulations.
C. Other
NFPA
- Health 2
- F-lammability -3
Reactivity 0
3. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Name Include (%) Chemical structure CAS No.

Polyurethane resin 28 — 32 27083—55—2
Methyl ethyl ketone 23 — 27 C2H5COCH3 78—93—3
Dimethylformamide 43 — 47 HCON(CH3)2 68—12-2
4, FIRE AID MEASURES

General advice Immediately remove contaminated clothing
If inhaled - keep patient calm. remove to fresh air, seek medical attention
On skin contact : Remove contaminated clothing, shoes immediately. Wash with soap of large
amount water
On contact with eyes Washed eyes immediately with penty of water and until no evidence of
chemical remains. consult an eye specialist.
On ingestion . Immediately rinse mouth and then drink plenty of water, do not induce vomiting,
seek medical attention
5. FIRE FIGHTING MEASURES

Suitable extinguish media : Dry Dowder, carbon dioxide, alcohol—resistant foam, water spray
Specific hazards
carbon dioxide, carbon monoxide, hydrogen cyanide, nitrogen oxides, isocyanate
The substances/groups of substances mentioned can be released in case of fire
Special protective equipment
wear self contained breathing apparatus and chemical—pfotective clothing
6. ACCIDENTAL RELEASE MEASURES

Personal precautions Use personal protective clothing. Ensure adequate ventilation. Use
breathing apparatus if exposed to vapours/aerosol.
Environmental precautions Do not empty into drains. Do not discharge into the subsol/soil
Method for cleaning up or taking up
For large amounts : Pump off product
For residues : Pick up with absorbent material
7. Handling and Storage
Handling
Provide suitable exhaust ventilation at the processing machines. Ensure through ventilation of
stores and work areas. Avoid aerosol formation. Protect against moisture.
Storage
Keep in cool. ventilated storage in closed containers
Avoid contact with strong oxidizes
Storage of materials in accordance with applicable Government and Local government regulations
8. Exposure controls and personal protection

Components with workplace control parameters
Ethylacetate basis
TWA value 400 ppm(ACGIH)
Biological : No data
Personal protective equipment
Respiratory protection
Combination filter for gases/vapours of organic compounds and solid and liquid particles
Hand protection
Chemical resistant protective gloves
Eye protection
Safety glasses with side-shields(frame 8oggles)
Body protection
safety shoes
9. Physical and chemical properties

Appearance liquid
color pale yellow
Odor : mild characteristic alcohol odor
Ph not applicable
Melting point —
Boiling point 82 'C
flash point . 7 V
Flammability - not applicable
Ignition temDerature +427 V
Vapor pressure : 10kpa at 20 ”C
Decomposition temperature No data
Oensity : 0.90—1.00
Solubility -
Viscosity : 60,000 80,000cps
10. Stability and Reactivity

Chemical stability Stable at ambient & atmosphere conditions
Hazardous polymerization ” Will not occur
Substances to avoid : acids, alcohols, amines, eater, akalines
Corrosion to metals No corrosive effect on metal
Hazardous decomposition Carbon dioxide, nitrogen oxide.
11. Toxicological Information

Acute toxicity
Experimental/calculated data
LD50 rat(oral) >5,000 me/kg
LD50 rat(by inhalation) . +18,000mg/Kg
LC50 rabbit(dermal) 14,600 ppm
Skin corrosive or irritation No irritated

Respiratory/skin sensitization
The substance may cause sensitization of the respiratory tract.
Germ cell mutagenicity
No data
Carcinogenicity ACGIH Group 4
Reproductive toxicity
No data
Specific target organ toxicity (single exposure) -'
Cause respiratory irritation. Exposed to lethal concentration, may cause anesthesia and lung
damages
Repeated dose toxicity and specific target organ toxicity (repeated exposure) No data
Assessment of repeated dose toxicity : No data
Aspiration hazard No data
1 2. Ecological information
A. Acuaatic/Terrestrial/ecoloeical toxicity
Fish No data
Shellfish : No data
Birds No data
B.Persistence and Biodegradability
Persistence No data
Biodegradability No data
C. Bioaccumulation
Biodegradability . No data
Bioacc umulation No data
O. Soil mobility No data
E. Other Hazardous No data
13. Disposal Considerations

A. Method of disposal
Disposal requied in compliance with all waste management related law stated.
B. Contaminated packaging
Consider the notice law stated prior to dispose.
14. Transport Information
A. UN Number
B. UN Shipping Name
C. ADR/RID class 3
D. Packing group 3
E. Marine Pollutant No data
F. EmS CODE
- Fire F-— E
— Spill : S— D
15. Regulatory information

A. Occupation Safety and health Acts ” Working environment measurement materials
B. Harmful chemical substance acts : Accident precaution chemical, Toxical chemical
C. Hazardous safety control acts : 4 class petroleum
D. Waste control acts : No data
E. Other regulation and foreign re0ulation
—Persistent Organic Pollutants Control Not application
—EU Regulation : Not application
—US Regulations
OSHA Regulation : Not application
CERCLA 1 03 Regulation 2267.
995kg
—Rotterdam Convention Not application
—Montreal Protocol : Not application
16. Other information
The data contained in this safety data sheet are based on our cunent knowledge and
experience and describe the product only with re8 ard to safety requirement. The data do not
describe the product s properties (product specification). Neither should any agreed property nor
the suitability of the product for any specific purpose be deduced from the data contained in the
safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary
rights and existing laws and legislation are observed.

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MSDS (Material Safety Data Sheet)

T . CHEMICAL PRODUCT & COMPANY IDENTIFICATION

A. Classification of the substance and mixture

B. Label elements and precautionary statement

Signal Word Dangerous

3. COMPOSITION, INFORMATION ON INGREDIENTS

Chemical Name Include (%) Chemical structure CAS No.

4, FIRE AID MEASURES

5. FIRE FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

8. Exposure controls and personal protection

9. Physical and chemical properties

10. Stability and Reactivity

11. Toxicological Information

Skin corrosive or irritation No irritated

13. Disposal Considerations

15. Regulatory information

16. Other information

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