1434-Decaltec 50
1434-Decaltec 50
1434-Decaltec 50
1 EN
Dated 11/03/2021
First compilation
Printed on 11/03/2021
Pagen. 2/12
1.2. Relevant identified uses of the substance or mixture and uses advised against
Name
TECNODERMA S.R.L.
Full address
SEDE OPERATIVA: VIA CIOPPO SAN VITO
District and
83029 SOLOFRA (AV)
Country
ITALY
tecnodenna@tecnoderma.com
e-mail address of the competent person
responsible for the Safety Data Sheet
Not available
For urgent inquiries refer to
The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP).
Hov,.,ever, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety
data sheet with appropriate information, compliant to (EU) Regulation 2015/830.
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Hazard pictograms:
Signal words:
Hazard statements:
EUH210
Safety data sheet available on request.
EUH208
Contains: 1,2-Benzoisothiazol-3(2H)-one
Subtilisin
amylase, a-
May produce an allergic reaction.
Precautionary statements:
TECNODERMA S.R.L. Revision nr.1
Dated 11/03/2021
First compilation
EN
On the basis of available data, the product does not contain any PST or vPvB in percentage than O,1 %.
3.2. Mixtures
Contains:
1,2-PROPANEDIOL
GAS 57-55-6 0,62 s x < 1,26
EC 200-338-0
INDEX
Reg. no. 01-2119456809-23-XXXX
amylase, a
CAS 9000-90-2 0,09 S X < 0,26 Resp. Sens. 1 H334
EC 232-565-6
INDEX 647-015-00-4
Reg. no. 01-2119938627-26-
Subtilisin
GAS 9014-01-1 0,08 S: X < 0,126 Acute Tox. 4 H302, Eye Dam. 1 H318, Skin lrrit. 2 H315, STOT SE 3 H335,
Resp. Sens.1 H334, Aquatic Acute 1 H400 M=1, Aquatic Chronic 2 H411
EC 232-752-2
INDEX 647-012-00-8
Reg. no. 01-2119480434-38-XXXX
1,2-Benzoisothlazol-3(2H)-one
CAS 2634-33-5 0,01 s x < 0,041 Acute Tox. 4 H302, Eye Dam. 1 H318, Skin lrrit. 2 H315, Skin Sens. 1 H317,
Aquatic Acute 1 H400 M=1
EC 220-120-9
INDEX 613-088-00-6
Reg. no. 01-2120761540-60-
The full wording of hazard (H) phrases is given in section 16 of the sheet.
EYES: Remove contact lenses. if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shovwer immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any Immediate medical attention and special treatment needed
Specific information on symptoms and effects caused by the product are unknown.
In the event of disease, exposure or possible exposure: consult a physician or an antipoison centre.
Extinguishing media
HAZARDS CAUSED BY EXPOSURE I THE EVENT OF FIREDo not breathe combustion products.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 1o. Absorb the
remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
Any information on personal protection and disposal is given in sections a and 13.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the
environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering
places in which people eat.
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away
from any incompatible materials, see section 10 for details.
Regulatory References:
POL
Polska ROZPORl,\DZENIE MINISTRA RODZINY, PRACY I POLITYKI SPOlECZNEJ z dnia 12 czerwca
2018 r
GBR
United Kingdom EH40/2005 Workplace exposure limits (Third edition, published 2018)
EN
TECNODERMA S.R.L.
Revision nr 1
Dated 11/03/2021
First compilation
Printed on 11/03/2021
-·: : ! i ; :W!'•;:; ;··'.f mtJ (:f W.& i l;F m};,: ••[.bi.il?"" r. t -'t i;.' ;_ f 1r1&?1 fW'j, :i ., :;-:·. ;·
Predicted no-effect concentration - PNEC
Normal value in fresh water 5200 mg/I
Normal value in marine water 520 mg/I
Normal value for fresh water sediment NEA
Normal value for marine water sediment NEA
Normal value of STP microorganisms 6500000 mg/I
0
Normal value for the food chain (secondary poisoning) NPI
Legend:
(C) = CEILING ; INHAL = lnhalable Fraction ; RESP= Respirable Fraction ; THORA= Thoracic Fraction.
VND = hazard identified but no DNEUPNEC available ; NEA = no exposure expected ; NPI = no hazard identified.
As the use of adequate technical equipment must always take priority over personal protective equipment. make sure that the workplace is
well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.
HAND PROTECTION
Protect hands with category Ill work gloves (see standard EN 374).
The follo'Ning should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on
the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footv.Jear (see Regulation 2016/425 and standard EN ISO 20344). Wash
body 'Mith soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type
A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases
or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, v.iear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing
apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment. should be checked to ensure
compliance with environmental standards.
Properties
Value Information
Appearance
limpid
Colour
liquid
Odour
yellowish bro\r\111 Method:expert judgment on the olfactory
mild
.
TECNODERMA S.R.L. Revision nr.1 EN
Dated 11/03/2021
First compilation
10.1. Reactivity
There are no particular risks of reaction with other substances in normal conditions of
use. 1,2-PROPANEDIOL
Hygroscopic.Stable in normal conditions of use and storage.
At high temperatures it tends to oxidate to form propionaldehyde and lactic and acetic acid.
storage. 1,2-PROPANEDIOL
May react dangerously with: acid chlorides.acid anhydrides,oxidising agents.
10.4. Conditions to avoid
None in particular. Hov,,.,ever the usual precautions used for chemical products should be respected.
1,2-PROPANEDIOL
May develop: carbon oxides.
In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate
the
toxicological effects of exposure to the product.
•
Information on likely routes of exoosure
Information not available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Interactive effects
ACUTE TOXICITY
1,2-PROPANEDIOL
LDS0 (Oral) > 20000 mg/kg Rat
LDS0 (Dermal) > 2000 mg/kg Rabbrt
•
Subtilisin
LDS0 (Oral) 1BOO mg/kg rat
at the concentration of 95%
Does not meet the classification criteria for this hazard class
CARCINOGENICITY
Does not meet the classification criteria for this hazard class
TECNODERMA S.R.L. Revision nr.1 EN
Dated 11/03/2021
First compilation
Does not meet the classification criteria for this hazard class
ASPIRATION HAZARD
Does not meet the classification criteria for this hazard class
Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or
contaminate soil or vegetation.
12.1. Toxicity
1,2-Benzoisothiazol-3(2H)-one
LC50 - for Fish
2 mg/l/96h Oncorhynchus mykiss
EC50 - for Crustacea
> 2 mgll/48h Daphnia magna
ECS0 - for Algae I Aquatic Plants
> 0,1 mg/l/72h
Subtilisin
LC50 - for Fish
8,2 mg/l/96h Troia Arcobaleno
ECSO - for Crustacea
0,868 mg/l/48h Daphnia
ECS0 - for Algae/ Aquatic Plants
Magna
Chronic NOEC for Algae I Aquatic
> 1,44 mg/l/72h Pseudokirchnerella subcapitata
Plants
0,041 mg/l Pseudokirchneriella subcapitata
amylase, a
LC50 - for Fish
> 100 mgn/96h OECD 203
EC50 - for
212 mg/l/48h OECD TG 202
Crustacea
49 mg/l/72h OECD TG 201
EC50 - for Algae I Aquatic Plants
1,2-PROPANEDIOL
1000 - 10000 mgn
Solubility in water
Rapidly degradable
Subtilisin
> 10000 mg/I
Solubility in water
102% degradation by the end of the 29-day test period.
Rapidly degradable
amylase, a
100000 mg/I
Solubility in water
Rapidly degradable
1,2-PROPANEDIOL
Partition coefficient: n-octanol/water -1,07
0,09
BCF
amylase, a-
< O Log Kaw
Partition coefficient: n-octanol/water
1,2-PROPANEDIOL
Partition coefficient: soil/water 0,46
Firat compilation
Printed on 11/03/2021
Pagen. 9/12
On the basis of available data, the product does not contain any PST or vPvB in percentage than 0,1%.
Reuse, when possible. Neat product residues should be considered special non hazardous waste.
Disposal must be perfonned through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance 'Mth national waste management regulations.
The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by
Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA)
regulations.
14.1. UN number
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006
None
Healthcare controls
Information not available
A chemical safety assessment has been performed for the following contained
substances 1.2-PROPANEDIOL
amylase. a-
Subtilisin
1.2-Benzoisothiazol-3(2H)-one
LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goads by Road
- GAS NUMBER: Chemical Abstract Service Number
- CES0: Effective concentration (required to Induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: ImmobilizationConcentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO. International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50· Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
L----------------------------------------------------
TECNODERMA S.R.L. Revision nr.1
Dated 11/03/2021
EN
. DECALTEC 50
First compilation
Printed on 11/03/2021
Pagen. 11/12
- REACH: EC Regulation 1907/2006- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA $TEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
-voe: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (Gem,an).
GENERAL BIBLIOGRAPHY
1. Regulation (EC) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 127212008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Alp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (111 Atp. CLP) of the European Parliament
•
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Par1iament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP)
13. Regulation (EU) 2017/776 (X Atp. CLP)
14. Regulation (EU) 2018/669 (XI Atp. CLP)
15. Regulation (EU) 2018/1480 (XIII Atp. CLP)
16. Regulation (EU) 2019/521 (XII Atp. CLP)
•
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
2.Centre Antipoisons, c/o HOpital Militaire Reine Astrid, Rue Bruyn 1, 1120 Bruxelles, Belgium, +320226496363. National Toxicology
Information Center, Hospital for Active Medical Treatment and Emergency Medicine 'N.I.Pirigov', Bui. Totleben 21, 1606 Sofia Center, Sofia,
Bulgaria, +359 2 9154 409
4. Croatian Institute for Toxicology and Anti-doping, Borongajska c. 83g, 10000 Zagreb, Croatia, +38514686917
5. Ministry of Labour, Welfare and Social Insurance, Department of Labour Inspection, P.O.Box 24855, 1304 Nicosia, Cyprus, +35722405611
6. Ministry of Helalth of the Czech Republic, Palackeho nam. 4,128 01 Praha 2. Czech Republic, +420267082257
7. Danish Environmental Protection Agency, Haraldsgade 53, 2100 K0benhavn 0, Denmark, +45 72 54 40 00
8. Health Board, Poisoning Information Centre, Paldiski road 81,10617 Tallinn, Estonia, +3726943884
9. Finnish Safety and Chemicals Agency (Tukes), P.O.Box 66 / Opastinsilta 12 B, 00521 Helsinki, Finland, +358 5052 000
10. French National Products and Composition Database (B.N.P.C.); French Poison and toxicovigilance Centre Network, Centre Antipoison
de Nancy, CHU de Nancy, HOpital Central, 29 avenue du Marechal de Lattre de Tassignyl, 53035 NANCY Cedex France,+ 33 3 83 85 21 92
11. BfR Bundesinstitut tor Risikobewertung / German Federal Institute for Risk Assessment, Max-Dohrn-Str. 8-10, 10589 Berlin,
+49-30-18412-0
12. Hellenic Republic Independent Authority for Public Revenue D.G. of the General Chemical State Laboratory Directorate of Energy,
Industrial and Chemical Products, 16 An. Tsocha Str., Athens, 11521, Greece, +302106479250, +302106479450
13. Ministry of Human Capacities, Department for Chemical Safety, Albert Fl6rian Street 2-6, H-1097 Budapest, Hungary,
bejelentes(at)emmi.gov.hu
14. Poisons lnformaiton Center- Icelandic University Hospital, Fossvogur, Reykjavik, Iceland, +354 543 22 22
15. National Poisons Information Centre, Beaumont Hospital, Beaumont, Dublin 9., Ireland, +35318092566
16. lstituto Superiore di Sanita (ISS), Viale Regina Elena 299, Rome, Italy, +390649906140
17. Latvian Environment, Geology and Meteorology Centre. Maskavas Street 165, Riga, LV-1019, Latvia, +371 67032600
18. Environmental Protection Agency, Juozapavicius st. 9, LT-09311 Vilnius, Lithuania, +370 70662008
19. Ministere-Direction de la Sante, Villa Louvigny, Allee Marconi, L-2120 Luxembourg, Luxembourg, +352 24785551
20. Matta Competition and Consumer Affairs Authority (MCCAA), Mizzi House, National Road, Blata I-Bajda i=tMR9010, Malta, +356
2395 2000
21. National Poisons Information Center/ University Medical Center Utrecht, PO Box 85500, 3508 GA Utrecht, The Netherlands, +31 88 75
585 61
22. Norwegian Environment Agency, Postboks 5672 Torgarden, 7485 Trondheim, Norway, +4573580500
23. Bureau for Chemical Substances, 30/34 DowborczykowStreet, 90-019 Lodz, Poland, +48 42 2538 400
24. Centro de informayao antivenenos, Rua Almirante Barroso, 361000-013 Lisboa, Portugal, +351213303271
25. National Institute for Public Health, Str. Dr. Leonte Anastasievici Nr.1-3, Sector 5 Bucuresti, 050463, Romania, +40213183606
26. National Toxicological Information Centre, Limbova 5, 833 05 Bratislava, Slovakia, +421 2 5465 2307
27. Chemicals Office of the Republic of Slovenia (CORS), Ministry of Health, AjdovSCina 4 1000 Ljubljana, Slovenia, +38614006051
28. Institute Nacional de Toxicologfa y Ciencias Forenses (INTCF), Calle Jose Echegaray 4, 26032 Las Rozas de Madrid, Madrid, Spain, +34
917689800
29. Swedish Poisons Information Centre, Giftinformationscentralen 171 76 Stockholm, Sweden, +46104566750
30. National Poisons Information Service, City Hospital, Birmingham B187QH, United Kingdom, +44 121 507 4123