MSDF - Xylan 1070 - 2023

Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758
SAFETY DATA SHEET

Date of issue/Date of revision : 20 March 2023 Version : 1.07
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : XYLAN® 1070/F2079 AZURE BLUE
Product code : F2079-PD20K
Product description :
Product type : Liquid.
Other means of : Not available.
identification
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Not applicable.
mixture
Uses advised against : Product is not intended, labelled or packaged for consumer use.
1.3 Details of the supplier of the safety data sheet

Whitford Ltd., 11 Stuart Road, Manor Park, Runcorn, Cheshire WA7 1TH England
Whitford s.r.l, Via Verziano 127, 25131 Brescia, Italy
Technical Contact Number:
[44] (0) 1928-571000
e-mail address of person : Product.Stewardship.EMEA@ppg.com

responsible for this SDS
Whitford Ltd., 11 Stuart Road, Manor Park, Runcorn, Cheshire WA7 1TH England Tel 01928-571000
1.4 Emergency telephone number
Supplier
+44 1928 571000 (0900-1700)
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to UK CLP/GHS
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Dam. 1, H318
Repr. 1B, H360D
STOT SE 3, H335
Aquatic Chronic 3, H412
The product is classified as hazardous according to UK CLP Regulation SI 2019/720 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Danger
English (GB) United Kingdom (UK) 1/16

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Code : F2079-PD20K Date of issue/Date of revision : 20 March 2023
XYLAN® 1070/F2079 AZURE BLUE
SECTION 2: Hazards identification

Hazard statements : Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation.
May damage the unborn child.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention : Wear protective gloves, protective clothing and eye or face protection. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : IF exposed or concerned: Get medical advice or attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
P280, P210, P308 + P313, P305 + P351 + P338, P310, P501
Supplemental label : Warning! Hazardous respirable droplets may be formed when sprayed. Do not
elements breathe spray or mist.
Annex XVII - Restrictions : Restricted to professional users.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.
2.3 Other hazards
Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Prolonged or repeated contact may dry skin and cause irritation. Contains a
not result in classification substance that may emit formaldehyde if stored beyond its shelf life and/or during
cure at curing temperatures greater than 60C/140F.
SECTION 3: Composition/information on ingredients

Mixture
3.2 Mixtures :
Product/ingredient name Identifiers % Classification Type
N-methyl-2-pyrrolidone REACH #: ≥25 - ≤50 Skin Irrit. 2, H315 [1] [2]
01-2119472430-46 Eye Irrit. 2, H319
EC: 212-828-1 Repr. 1B, H360D
CAS: 872-50-4 STOT SE 3, H335
Index: 606-021-00-7
xylene REACH #: ≥10 - ≤25 Flam. Liq. 3, H226 [1] [2]
01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
Asp. Tox. 1, H304
γ-butyrolactone REACH #: ≥10 - <20 Acute Tox. 4, H302 [1]

SECTION 3: Composition/information on ingredients

01-2119471839-21 Eye Dam. 1, H318
EC: 202-509-5 STOT SE 3, H336
CAS: 96-48-0
ethylbenzene REACH #: ≥1.0 - ≤5.0 Flam. Liq. 2, H225 [1] [2]
01-2119489370-35 Acute Tox. 4, H332
EC: 202-849-4 STOT RE 2, H373
CAS: 100-41-4 (hearing organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
Aquatic Chronic 3,
H412
trizinc bis(orthophosphate) REACH #: ≥0.30 - <2.5 Aquatic Acute 1, H400 [1]
01-2119485044-40 (M=1)
EC: 231-944-3 Aquatic Chronic 1,
CAS: 7779-90-0 H410 (M=1)
Index: 030-011-00-6
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
This mixture contains ≥ 1% of titanium dioxide. The Annex VI classification of titanium dioxide does not apply to this
mixture according to Note 10.
Occupational exposure limits, if available, are listed in Section 8.
SUB codes represent substances without registered CAS Numbers.
SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
In case of accidental eye contact, avoid direct exposure to the sun or other sources
of UV light as severe irritation including burns may result. These reactions can be
delayed – get medical attention if pain, irritation or blistering occurs after contact.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.

SECTION 4: First aid measures

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced foetal weight
increase in foetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
5.2 Special hazards arising from the substance or mixture

Hazards from the : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. This material is harmful to aquatic life with long
lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion : Decomposition products may include the following materials:
products carbon oxides
nitrogen oxides
phosphorus oxides
halogenated compounds
metal oxide/oxides
Formaldehyde.

SECTION 5: Firefighting measures

The fluoropolymer resins used in this coating begin to decompose, very slowly, at
temperatures above 625°F (330°C). Thermal decomposition is more rapid at
temperatures above 750°F (400°C). Above 800°F (425°C) fluoropolymer resins
give off small amounts of tetrafluoroethylene / hexafluoropropylene /
perisofluorobutylene / carbonyl fluoride / hydrogen fluoride. These are toxic and if
inhaled, in sufficient quantities, may be harmful. The actual decomposition products
depend on temperature and the amount of oxygen.
5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.
6.3 Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in
eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid
release to the environment. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities

Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in a
segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all
ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
7.3 Specific end use(s)

See Section 1.2 for Identified uses.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
N-methyl-2-pyrrolidone EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 80 mg/m³ 15 minutes.
STEL: 20 ppm 15 minutes.
TWA: 40 mg/m³ 8 hours.
TWA: 10 ppm 8 hours.
xylene EH40/2005 WELs (United Kingdom (UK), 1/2020). [xylene, o-,m-,p-
or mixed isomers] Absorbed through skin.
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.


Biological exposure indices
Product/ingredient name Exposure indices
xylene XYLENES
Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to

procedures national guidance documents for methods for the determination of hazardous
substances will also be required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
N-methyl-2-pyrrolidone DNEL Long term Inhalation 40 mg/m³ Workers Local
DNEL Long term Dermal 4.8 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 3.6 mg/m³ General population Systemic
DNEL Long term Inhalation 4.5 mg/m³ General population Local
DNEL Long term Dermal 2.4 mg/kg bw/day General population Systemic
DNEL Long term Oral 0.85 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 14.4 mg/m³ Workers Systemic
DNEL Long term Dermal 4.8 mg/kg bw/day Workers Systemic
xylene DNEL Short term Inhalation 260 mg/m³ General population Systemic
DNEL Short term Inhalation 260 mg/m³ General population Local
DNEL Long term Dermal 125 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 221 mg/m³ Workers Systemic
DNEL Short term Inhalation 442 mg/m³ Workers Systemic
DNEL Long term Inhalation 221 mg/m³ Workers Local
DNEL Short term Inhalation 442 mg/m³ Workers Local
DNEL Long term Dermal 212 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 65.3 mg/m³ General population Local
DNEL Short term Inhalation 260 mg/m³ General population Local
DNEL Short term Inhalation 260 mg/m³ General population Systemic
DNEL Long term Inhalation 221 mg/m³ Workers Local
γ-butyrolactone DNEL Long term Dermal 19 mg/kg bw/day Workers Systemic
ethylbenzene DNEL Long term Oral 1.6 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 15 mg/m³ General population Systemic
DMEL Long term Inhalation 442 mg/m³ Workers Local
DMEL Short term Inhalation 884 mg/m³ Workers Systemic
trizinc bis(orthophosphate) DNEL Long term Oral 0.83 mg/kg bw/day General population Systemic
PNECs


Product/ingredient name Compartment Detail Value Method Detail
N-methyl-2-pyrrolidone Fresh water 0.25 mg/l -
Marine water 0.025 mg/l -
Fresh water sediment 1.09 mg/kg -
Marine water sediment 0.109 mg/kg -
Soil 0.0701 mg/kg -
Sewage Treatment Plant 10 mg/l -
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Sewage Treatment Plant 6.58 mg/l -
Fresh water sediment 12.46 mg/kg dwt -
Marine water sediment 12.46 mg/kg dwt -
Soil 2.31 mg/kg -
ethylbenzene Fresh water 0.1 mg/l Assessment Factors
Marine water 0.01 mg/l Assessment Factors
Sewage Treatment Plant 9.6 mg/l Assessment Factors
Fresh water sediment 13.7 mg/kg dwt Equilibrium Partitioning
Marine water sediment 1.37 mg/kg dwt Equilibrium Partitioning
Soil 2.68 mg/kg dwt Equilibrium Partitioning
Secondary Poisoning 20 mg/kg -
trizinc bis(orthophosphate) Fresh water 20.6 μg/l Sensitivity Distribution
Marine water 6.1 μg/l Sensitivity Distribution
Sewage Treatment Plant 100 μg/l Assessment Factors
Fresh water sediment 117.8 mg/kg dwt Sensitivity Distribution
Marine water sediment 56.5 mg/kg dwt Equilibrium Partitioning
Soil 35.6 mg/kg dwt Sensitivity Distribution
8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles and face shield.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. When prolonged or
frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended.
When only brief contact is expected, a glove with a protection class of 2 or higher
(breakthrough time greater than 30 minutes according to EN 374) is recommended.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of use,
as included in the user's risk assessment.
polyethylene


Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use with adequate ventilation. In case of insufficient ventilation, wear suitable
respiratory equipment. Wear a respirator conforming to EN140. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator. Mask type: full-face mask half-face
mask Filter type: organic vapour filter (Type A) particulate filter P3 Use a properly
fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Not available.
Odour : Not available.
Odour threshold : Not available.
Melting point/freezing point : May start to solidify at the following temperature: -24.4°C (-11.9°F) This is based on
data for the following ingredient: N-methyl-2-pyrrolidone. Weighted average:
-53.08°C (-63.5°F)
Initial boiling point and : >37.78°C (>100°F)
boiling range
Flammability (solid, gas) : liquid
Upper/lower flammability or : Greatest known range: Lower: 0.3% Upper: 16% (γ-butyrolactone)
explosive limits
Flash point : Closed cup: 29°C (84.2°F)
Auto-ignition temperature :
Ingredient name °C °F Method
N-methyl-2-pyrrolidone 245 473
Decomposition temperature :
pH : Not applicable.
Not applicable. insoluble in water.
Viscosity : Kinematic (40°C): >21 mm2/s
Solubility(ies) :
Media Result
cold water Partially soluble
Miscible with water : No.

Partition coefficient: n-octanol/ : Not applicable.
water
Vapour pressure :

SECTION 9: Physical and chemical properties

Vapour Pressure at 20˚C Vapour pressure at 50˚C
Ingredient name mm Hg kPa Method mm Hg kPa Method
ethylbenzene 9.3 1.2
Relative density : 1.13

Vapour density : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.41 (Air = 1)
Explosive properties : The product itself is not explosive, but the formation of an explosible mixture of
vapour or dust with air is possible.
Oxidising properties : Product does not present an oxidizing hazard.
Particle characteristics
Median particle size : Not applicable.
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Depending on conditions, decomposition products may include the following
decomposition products materials: carbon oxides nitrogen oxides phosphorus oxides halogenated
compounds Formaldehyde. metal oxide/oxides
The fluoropolymer resins used in this coating begin to decompose, very slowly, at
temperatures above 625°F (330°C). Thermal decomposition is more rapid at
temperatures above 750°F (400°C). Above 800°F (425°C) fluoropolymer resins give
off small amounts of tetrafluoroethylene / hexafluoropropylene / perisofluorobutylene /
carbonyl fluoride / hydrogen fluoride. These are toxic and if inhaled, in sufficient
quantities, may be harmful. The actual decomposition products depend on
temperature and the amount of oxygen. Proper ventilation should be used at all curing
temperatures.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
N-methyl-2-pyrrolidone LC50 Inhalation Dusts and Rat >5100 mg/m³ 4 hours
mists
LD50 Dermal Rabbit 8 g/kg -
LD50 Oral Rat 3.914 g/kg -
xylene LD50 Dermal Rabbit 1.7 g/kg -
γ-butyrolactone LC50 Inhalation Dusts and Rat >5.1 mg/l 4 hours
mists
LD50 Dermal Rabbit >5.6 g/kg -
LD50 Oral Rat 1580 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -


trizinc bis(orthophosphate) LC50 Inhalation Dusts and Rat >5.7 mg/l 4 hours
mists
LD50 Oral Rat >5000 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)
XYLAN® 1070/F2079 AZURE BLUE 10023.3 8549.6 N/A 49.9 N/A
N-methyl-2-pyrrolidone 3914 8000 N/A N/A N/A
xylene 4300 1700 N/A 11 N/A
γ-butyrolactone 1580 N/A N/A N/A N/A
ethylbenzene 3500 17800 N/A 17.8 N/A
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Conclusion/Summary : Not available.
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitisation
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Carcinogenicity
It has been observed that the carcinogenic hazard of this product arises when respirable dust is inhaled in quantities
leading to significant impairment of particle clearance mechanisms in the lung.
Reproductive toxicity
Teratogenicity
Conclusion/Summary :
There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
N-methyl-2-pyrrolidone Category 3 - Respiratory tract
irritation
xylene Category 3 - Respiratory tract
irritation
γ-butyrolactone Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
Aspiration hazard

Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.


Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : May damage the unborn child.
Other information : Not available.
SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
γ-butyrolactone Acute EC50 >500 mg/l Daphnia 48 hours
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
trizinc bis(orthophosphate) Acute LC50 0.112 mg/l Fish 96 hours
Chronic NOEC 0.026 mg/l Fish 30 days
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
ethylbenzene - 79 % - Readily - 10 days - -
Product/ingredient name Aquatic half-life Photolysis Biodegradability
N-methyl-2-pyrrolidone - - Readily
xylene - - Readily
γ-butyrolactone - - Readily
ethylbenzene - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
N-methyl-2-pyrrolidone -0.46 3.16 low
xylene 3.12 7.4 to 18.5 low
γ-butyrolactone -0.566 - low
ethylbenzene 3.6 79.43 low
12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects : No known significant effects or critical hazards.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product

SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN1263 UN1263 UN1263 UN1263
14.2 UN proper PAINT PAINT PAINT PAINT

shipping name
14.3 Transport 3 3 3 3
hazard class(es)
14.4 Packing III III III III
group
14.5 No. Yes. No. No.
Environmental
hazards
Marine pollutant Not applicable. Not applicable. Not applicable. Not applicable.
substances
Additional information
ADR/RID : None identified.
Tunnel code : (D/E)
ADN : The product is only regulated as an environmentally hazardous substance when transported in tank
vessels.
IMDG : None identified.
IATA : None identified.
14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
14.7 Transport in bulk : Not available.

according to IMO
instruments

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB)/REACH
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
Intrinsic property Ingredient name Status Reference Date of
number revision
Toxic to reproduction 1-methyl-2-pyrrolidone Candidate - 6/20/2011
Ozone depleting substances

Not listed.
Annex XVII - Restrictions : Restricted to professional users.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms GB CLP = UK CLP (EC No 1272/2008) on the Classification, Labelling and
Packaging of Substances and Mixtures as amended by (EU Exit) Regulations 2019
No. 720 and amendments
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = GB CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Irrit. 2, H315 Calculation method
Eye Dam. 1, H318 Calculation method
Repr. 1B, H360D Calculation method
STOT SE 3, H335 Calculation method
Aquatic Chronic 3, H412 Calculation method
Full text of abbreviated H statements

SECTION 16: Other information

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360D May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 1
Aquatic Chronic 1 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 1
Aquatic Chronic 3 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 1B REPRODUCTIVE TOXICITY - Category 1B
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 3
History
Date of issue/ Date of : 20 March 2023
revision
Date of previous issue : 15 March 2023
Prepared by : EHS
Version : 1.07
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by us, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary
measures described in this data sheet or for any misuse of the products.

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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/

1.3 Details of the supplier of the safety data sheet

e-mail address of person : Product.Stewardship.EMEA@ppg.com

SECTION 2: Hazards identification

2.2 Label elements

Signal word : Danger

English (GB) United Kingdom (UK) 1/16

SECTION 2: Hazards identification

SECTION 3: Composition/information on ingredients

English (GB) United Kingdom (UK) 2/16

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

English (GB) United Kingdom (UK) 3/16

SECTION 4: First aid measures

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

English (GB) United Kingdom (UK) 4/16

SECTION 5: Firefighting measures

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.3 Methods and material for containment and cleaning up

6.4 Reference to other : See Section 1 for emergency contact information.

English (GB) United Kingdom (UK) 5/16

SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

English (GB) United Kingdom (UK) 6/16

SECTION 8: Exposure controls/personal protection

Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to

English (GB) United Kingdom (UK) 7/16

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

English (GB) United Kingdom (UK) 8/16

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Miscible with water : No.

English (GB) United Kingdom (UK) 9/16

SECTION 9: Physical and chemical properties

Relative density : 1.13

SECTION 10: Stability and reactivity

10.2 Chemical stability : The product is stable.

SECTION 11: Toxicological information

English (GB) United Kingdom (UK) 10/16

SECTION 11: Toxicological information

SECTION 11: Toxicological information

Information on likely routes : Not available.

Symptoms related to the physical, chemical and toxicological characteristics

English (GB) United Kingdom (UK) 12/16

SECTION 11: Toxicological information

Other information : Not available.

SECTION 12: Ecological information

12.2 Persistence and degradability

12.3 Bioaccumulative potential