Report
Report
Report
1. INTRODUCTION
With the growing environmental and economic concerns associated with conventional
concrete-based building materials such as reinforced concrete structures, researchers have been
actively involved in exploring possibilities in using alternative materials to address these
concerns. For instance, alternative concrete-making materials have been trialled in reinforced
concrete structures such as recycled concrete aggregate and agriculture waste materials, in an
attempt to reduce the dependency on conventional concrete constituent materials, which are
depleting at a fast rate.
members with existing design provisions should be ascertained in order to evaluate the
feasibility of using these design codes for geopolymer concrete members for the convenience
of structural design engineers. Due to the importance of the structural aspect of utilizing
geopolymer concrete in reinforced concrete structures, this report discusses the published
findings of research works involving geopolymer concrete structures such as beams, columns,
slabs and panels.
2. GEOPOLYMER CONCRETE
The name geopolymer was formed by a French Professor Davidovits in 1978 to represent a
broad range of materials characterized by networks of inorganic molecules. The geopolymers
depend on thermally activated natural materials like Meta kaolinite or industrial byproducts
like fly ash or slag to provide a source of silicon (Si) and aluminium (Al). These Silicon and
Aluminium is dissolved in an alkaline activating solution and subsequently polymerizes into
molecular chains and become the binder.
Professor B. Vijaya Rangan (2008), Curtin University, Australia, stated that, “the
polymerization process involves a substantially fast chemical reaction under alkaline
conditions on silicon-aluminium minerals that results in a three-dimensional polymeric chain
and ring structure”. The ultimate structure of the geopolymer depends largely on the ratio of Si
to Al (Si:Al), with the materials most often considered for use in transportation infrastructure
typically having a Si:Al between 2 and 3.5.
The reaction of Fly Ash with an aqueous solution containing Sodium Hydroxide and
Sodium Silicate in their mass ratio, results in a material with three dimensional polymeric chain
and ring structure consisting of Si-O-Al-O bonds.
The schematic formation of geopolymer material can be shown as described by
Equations (A) and (B).
3
(OH)2 O O O
Water is not involved in the chemical reaction of Geopolymer concrete and instead
water is expelled during curing and subsequent drying. This is in contrast to the hydration
reactions that occur when Portland cement is mixed with water, which produce the primary
hydration products calcium silicate hydrate and calcium hydroxide. This difference has a
significant impact on the mechanical and chemical properties of the resulting geopolymer
concrete, and also renders it more resistant to heat, water ingress, alkali–aggregate reactivity,
and other types of chemical attack.
Similarly the Geopolymer Concrete shows good workability compared to the ordinary
Portland Cement Concrete.
Due to the importance of bonding properties for structural members, researches have
been undertaken to evaluate the bond strength between reinforcement and geopolymer
concrete. Sofi et al. initiated the research on steel-geopolymer concrete bond behaviour through
beam-end testing and direct pull-out testing. It was found that on average, the bond strengths
of the fly ash-slag goepolymer concrete produced were 7.3–11.4 MPa and 10.5–14.7 MPa for
the beam-end and direct pullout testing, respectively. Based on the beam-end bond test results,
Sofi et al. concluded that the recommendations in standards such as AS 3600 , ACI 318 and
EC2 could be used to safely predict the development length of geopolymer concrete as these
codes were conservative in predicting the bond strength. Using results from lap-spliced beams,
Chang et al. also found that the code of provisions such as AS 3600 and ACI 318 gave
conservative prediction of the bond strength of the lap-spliced geopolymer concrete beams.
Kim and Park and Topark-Ngarm et al. suggested the following Eqs. (1) and (2), respectively
which would give closer match to the experimental bond strength of geopolymer concrete:
𝑐 𝜙
𝜎 = 𝑓𝑐′ (2.07 + 0.2 (𝜙) + 4.15 (𝑙 )) (1)
𝑑
σ = 2.12(ƒ'c)0.5 (2)
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The bonding behaviour between steel reinforcement with fly ash-based geopolymer
concrete and cement concrete in beam-end specimens was also later carried out in few
investigations. The obtained bond strengths of geopolymer concrete were between 10.6 and
19.4 MPa, the bond strength of geopolymer concrete was found to be higher than the cement
concrete. Similarly, in a separate investigation, Castel and Foster who conducted direct pull-
out test on fly ash-slag geopolymer concrete, found that the bond strength of geopolymer
concrete was on average 10% higher than cement concrete. Fernandez-Jimenez et al. observed
that the steel-geopolymer concrete bond was so strong that the failure mode observed in the
pull-out testing was through rupture of the steel bar, whereas pull-out failure was found in the
case of the steel bar bonded to normal cement-based concrete. Thus, Castel and Foster agreed
that existing bond models could be applied for the case of geopolymer concrete due to the
similarity in the bond-slip diagrams for both types of concrete.
Works on the structural behaviour of fly ash-based geopolymer concrete beams were
initiated by Sumajouw et al. where a total of six under-reinforced concrete beams with varying
reinforcement ratios (0.64–2.69%) were tested for flexural failure. As expected, the flexural
load-carrying capacity increased with increase in the tensile reinforcement ratio. In the
investigation by Sumajouw et al., sixteen reinforced geopolymer concrete beams (Fig. 1) with
varying tensile reinforcement ratio (0.64–2.69%) and concrete compressive strength (37–76
MPa) were tested. Sumajouw et al. reported that the general behaviour of the geopolymer
concrete beams was similar to conventional cement based concrete beams in terms of effect of
tensile reinforcement ratio on flexural capacity and ductility index.
Prachasaree et al. introduced equivalent stress block parameters meant for fly ash-
based geopolymer concrete which gave good agreement with experimental findings for
geopolymer concrete beams. Prachasaree et al. reported that the proposed design parameters
could be used with the design procedure in ACI 318 and AS 3600. In the proposed method,
firstly, a simplified stress-strain model was proposed for geopolymer concrete using modified
Popovics equation below:
𝑓𝑐 ′
𝜀𝑐 𝑛𝑘
= 𝜀𝑐 𝑛 [𝜀𝑐 [𝑛 − 1 + ( ) ]]
𝑓𝑐′ 𝜀𝑐′
where 𝑓𝑐 is the compressive stress (MPa), 𝜀𝑐 is the concrete strain, 𝜀𝑐′ is the strain corresponding
to the maximum compressive stress given by 𝜀𝑐′ = 0.0051 − 4(𝑓𝑐′ )/105 based on experimental
data, n is the curve fitting factor given by n = 0.5 + (𝑓𝑐′ /14.3) − [3(𝑓𝑐′ )2 /104 ] and k is a factor
𝜀
whereby k = 1 when 𝜀𝑐′ <1 and k > 1 otherwise.
𝑐
Secondly, based on the modified stress-strain equation, Prachasaree et al. proposed the
following flexural design parameters 𝑘1 , 𝑘2 and 𝑘3 for the determination of the equivalent
stress block for the case of geopolymer concrete and hence the nominal moment capacity of
geopolymer concrete beams could be determined through standard design procedures using
these proposed parameters.
𝑓𝑐′
𝑘2 = 0.384 − ( 3 )
10
𝑓𝑐′
𝑘1 𝑘3 = 1.070 − ( ) + 9(𝑓𝑐′ )2 /105
76.3
8
where k1 and k3 are the equivalent stress block parameter and the parameter k2 defines the
centroid of the compressive forces.
There are few research works carried out to evaluate the shear behaviour of reinforced
geopolymer concrete beams under flexural loading. Considering the similar crack shape and
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failure mode, Yost et al. reported that the shear force transfer is similar in both geopolymer and
cement-based concrete beams. The shear strength of the reinforced concrete beams were also
similar for both types of concrete. On the other hand, Mourougane et al. observed higher shear
strength for the reinforced geopolymer concrete beams than the corresponding conventional
cement-based concrete beams, in the range of 5–23%.
Ng et al. found that as steel fibres were added into the geopolymer concrete, the
shear cracking of the resulting reinforced concrete beams was delayed, and more but finer
cracks were formed in the specimens. In addition, use of straight steel fibres resulted in smaller
crack width compared to the addition of hooked-end steel fibres in the geopolymer concrete
beams and this was due to the smaller diameter of the straight steel fibres.
Sujatha et al. fabricated and tested 12 slender circular reinforced concrete columns
made of geopolymer and cement-based concretes of compressive strength grades 30 and 50
MPa. The reinforced concrete columns were tested under compressive axial loading without
eccentricity. It was found that the geopolymer concrete columns had up to 34% higher load-
carrying capacity as well as having greater rigidity compared to the corresponding cement-
based concrete columns. Ganesan et al. investigated the effect of steel fibre addition on the
behaviour of slender square geopolymer concrete columns with 2.01% reinforcement ratio. In
this research, the effects of different volume of steel fibres (up to 1.0%) as well as aspect ratio
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(l/d) of the slender columns were investigated. The slender columns were tested under
monotonic axial loading. It was found that the inclusion of steel fibres increased the load-
carrying capacity of the geopolymer concrete columns by up to 56%, and this was due to the
fibre-bridging effect which prevented early concrete cover spalling. Increase in strain at the
peak axial compressive stress and area under the stress-strain curve suggested that there was
considerable improvement in the ductility (up to 29% increase) of geopolymer concrete column
when steel fibres were added.
Research works were also carried out on slender fly ash-based geopolymer
concrete column under load eccentricity carried out in Curtin University of Technology in
Australia. The set-up of the column test are shown in Fig. 2. In these researches, the slender
columns tested had longitudinal reinforcement ratios of 1.47% and 2.95% and targeted concrete
strength grades of 40 and 60 MPa; the column specimens were tested at specified varying load
eccentricities from 15 to 50 mm (Table 1).
Concrete filled steel tubular (CFT) columns have been increasingly used in structures
such as bridges, high-rise buildings, transmission towers and warehouses etc. This is due to the
excellent structural behaviour of CFT columns such as high strength, high ductility, high
stiffness and full usage of construction materials. Shi et al. utilized geopolymer recycled
concrete as concrete fill in steel tubular columns and tested the structural behaviour of the CFT
columns. It was reported that in the geopolymer CFT columns, the load capacity was reduced
in the increased ratio of recycled concrete as coarse aggregates, and this reduction was more
significant compared to in cement-based CFT columns. On the other hand, the effect of
recycled concrete in geopolymer CFT columns was found to be more sensitive in enhancing
the ductility of the column compared to the corresponding cement-based CFT columns.
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Espinos et al. demonstrated that when geopolymer concrete was used as concrete infill in
conventional CFT columns, there was no particular effect; however, when used as outer core
concrete infill in an innovative double tube CFT (Fig. 4), the fire resistance time was
significantly delayed in comparison with using conventional concrete. The improvement in the
fire resistance was caused by the delay in the temperature rise in the inner core conventional
concrete as the outer core geopolymer concrete had lower thermal conductivity. On the other
hand, poorer performance was observed when geopolymer concrete was used as inner core and
conventional concrete in the outer core of the double tube CFT due to the quicker rise of
temperature in the outer tube.
even though the load-carrying capacity was similar. It was noted that ACI 318 gave
conservative prediction of the ultimate strength of the geopolymer concrete wall panels and
hence Ganesan et al. proposed the following equation to predict the ultimate strength of the
geopolymer concrete wall panels.
ℎ ℎ 2 ℎ
𝑃𝑢 = 0.585[𝑓𝑐′ 𝐿𝑡 + (𝑓𝑦 − 𝑓𝑐′ )𝐴𝑠𝑐 ] [1 + (40𝑡) − (30𝑡) ] [1 − (18𝑡)]
where 𝑃𝑢 is the ultimate load (kN), L is the length of panel (mm), t is the thickness of panel
(mm), 𝑓𝑦 is the strength of steel reinforcement (MPa), 𝐴𝑠𝑐 is the area of steel reinforcement
(mm2), h is the height of panel (mm).
Sarker and Macbeath evaluated the fire endurance performance of reinforced fly
ash-based geopolymer concrete panels and found that the heat transfer rate of the geopolymer
concrete panel was greater than the corresponding cement-based concrete panel when exposed
to high temperature of up to 1000 °C. However, the damage to the specimen after high
temperature exposure was less severe in the case of the geopolymer concrete panel. Because
of this, the residual-to-original strength ratios of the geopolymer concrete panels were higher
at 0.61–0.71 compared to those of the cement-based concrete panels which were about 0.50–
0.53. The results suggested superior fire endurance of reinforced geopolymer concrete panels
compared to the cement-based concrete specimens. The conformity of structural geopolymer
concrete panels towards fire resistance requirements in AS 1530 was also reported by Aldred
and Day.
Mohana and Nagan carried out flexural tests on geopolymer reinforced ferrocement
slabs and compared the performance with conventional ferrocement slabs. It was found that
the cracking load, yielding load and ultimate load of the geopolymer ferrocement slabs were
all higher compared to the corresponding conventional ferrocement slabs. Also, the
geopolymer ferrocement slabs could sustain larger deflection at yield and failure. In terms of
cracking behaviour, the number of cracks was observed to be more in the case of the
geopolymer ferrocement slab while the average crack width and spacing were higher in the
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When reinforced concrete pipes were tested under three-edge bearing test,
Shrestha found that the pipe made of geopolymer concrete exhibited more uniformly
distributed crack lines with smaller crack widths, as compared to the wider crack line of the
Fig. 5. Failure mode of (a) reinforced geopolymer concrete pipe and (b) conventional
reinforced concrete pipe
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that sewer pipes could be fabricated using reinforced geopolymer concrete and the pipes passed
the Australian Standard for load-carrying strength, with the ability to withstand considerable
internal hydrostatic pressures using geopolymer concrete with 7-day compressive strength of
40–60 MPa.
Gourley and Johnson highlighted that high load bearing precast railway sleepers
made of geopolymer concrete (compressive strength of 60–80 MPa) passed the requirements
of Australian Standard for static and cyclic loading with ease. An advantage observed in the
use of geopolymer concrete railway sleepers was that the steel-concrete bond was so great that
there was no steel slippage at the ultimate load whereas in conventional design, steel wire failed
in tension before slippage could occur. However, the geopolymer prestressed sleeper had
comparatively poorer demoulding performance compared to that for prestressed sleeper from
conventional cement-based concrete, thus requiring automatic demoulding machine with
additional hammering vibration.
Dhakal et al. fabricated a New Jersey type median barrier and tested the barrier to
failure. It was found that the performance of geopolymer median barrier was in compliance
with AASHTO and therefore could be used in most roads. In addition, the investigation showed
that the use of structural analysis and design approach for conventional cement-based concrete
structures can be adopted for geopolymer concrete structures.
9. FIELD APPLICATION
Reinforced geopolymer concrete application had been utilized for actual field
application, by using both precast geopolymer concrete elements and casting in-situ of the
geopolymer concrete. Examples of these include precast retaining wall, precast bridge decks
and boat ramp (Fig. 6).
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In 2013, being the first application of geopolymer concrete in multi-storey building, precast
geopolymer concrete floor beams were utilized as structural floor elements in the construction
of The University of Queensland’s Global Change Institute, Australia. (Fig. 7)
10. CONCLUSION
It is concluded that the geopolymer concrete members such as beams and columns
could be designed using design codes for conventional reinforced concrete members as most
of the codes gave conservative estimation of the ultimate load-capacity of the geopolymer
concrete members.
In addition, due to the similarity in the general structural behaviours such as load-
deflection, cracking characteristics and failure mode of the geopolymer concrete members with
conventional concrete members, it can be concluded that geopolymer concrete members could
be designed in the same way as conventional concrete members.
Although there are a number of design equations meant for geopolymer concrete
structures have been proposed, but still these are fairly limited and therefore there are still
opportunities in further researching the structural behaviour of geopolymer concrete in order
to develop a standard design method for reinforced geopolymer concrete member which are
more economic, effective and realistic. This is essential in order to fully introduce geopolymer
concrete for large-scale structural applications in the future, which would ultimately result in a
more environmental-friendly and sustainable construction industry.
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REFERENCES