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Activity-Quantum Numbers

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CARL GHIMBO S.

GUTIERREZ

BS CRIM 2-1

CHEM 5
ACTIVITY 5
QUANTUM NUMBERS WORKSHEET

1. State the four quantum numbers, then explain the possible values they may have and
what they actually represent.

PRINCIPAL QUANTUM NUMBER The principal energy level, or shell, that an electron
occupies.
SECONDARY QUANTUM NUMBER The electron's energy sublevel, or type of orbital, is
represented.
MAGNETIC QUANTUM NUMBER For each type of orbital, the number of possible
orientations in 3-D space is represented.
SPIN QUANTUM NUMBER In the presence of a magnetic field or in respect to another
electron occupying the same orbital, an electron can have two different orientations.

2. State the number of possible electrons described by the following quantum numbers
a. n = 3, l = 0 2
b. n = 3, l = 1 6
c. n = 3, l = 2, ml = -1 2
d. n = 5, l = 0, ml -2, ms -1/2 Not possible

3. Give the n and l values for the following orbitals


a. 1s n=1 l = 0
b. 3s n=3 l =0
c. 2p n= 2 l= 1
d. 4d n= 4 l=2
e. 5f n= 5 l= 3

4. What is the ml values for the following types of orbitals?


a. s ml= 0
b. p ml= -1, 0,1
c. d ml= -2, -1, 0, 1, 2
d. f ml= -3, -2, -1, 0, 1, 2, 3

5. Fill in the blanks with the correct response:


a. The number of orbitals with the quantum numbers n=3, l=2 and ml= 0 is ___1___.
b. The subshell with the quantum numbers n=4, l=2 is ___d__.
c. The ml values for a d orbital are ___2, 1, 0 , -1, -2_____.
d. The allowed values of l for the shell with n=2 are ____0, 1___.
e. The allowed values of l for the shell with n=4 are ___0, 1, 2, 3___.
f. The number of orbitals in a shell with n=3 is __1+3+5=9_(s, p, d)__.
g. The number of orbitals with n=3 and l=1 is __3____.
h. The maximum number of electrons with quantum numbers with n=3 and l=2 is __10__.
i. When n=2, l can be __0, 1__.
j. When n=2, the possible values for ml are __1, 0, -1____.
k. The number of electrons with n=4, l=1 is __6__.
l. The subshell with n=3 and l=1 is designated as the __ -1, 0, 1___ subshell.
m. The lowest value of n for which a d subshell can occur is n=___3__.
6. Write the values for the quantum numbers for the bold electron in the following
diagrams:

ANNSWER
a.n=3, l=1, ml =1, ms =+1/2
b. n=5, l=0, ml =0, ms = - ½
c. n=4, l=2, ml = - 2, ms = - ½
d. n=3, l=2, ml =0, ms =+1/2

7. How many electrons can occupy any single subshell orbital? ANSWER IS 2

8. a. What is the value of l for a 4 f electron? ANSWER IS 3


b. What is the orbital designation for an electron in the 3rd shell and p sublevel?
ANSWER IS 3P
c. What are the possible values of ml for a 5d electron? ANSWER IS 2,1,0,-1,-2
d. What is the maximum number of electrons in the 3rd energy level? ANSWER IS 18
e. How many orbitals have the following quantum numbers: n =4, l = 2, ml = -2?
ANSWER IS 1
f. How many electrons have the following quantum numbers: n =4, l = 2, ml = -2?
ANSWER IS 1

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