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    Chemistry Assignment 2023 2 1683714093

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    Tharun
    The document contains 10 chemistry problems involving conversions between organic compounds and redox reactions, as well as calculations involving cell potentials, conductivities, and thermodynamic properties. The problems cover topics including substitution reactions, oxidation-reduction reactions, electrochemical cells, conductance of electrolyte solutions, and calculation of standard cell potentials and Gibbs free energies.

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    Chemistry Assignment 2023 2 1683714093

    Uploaded by

    Tharun
    7 views2 pages
    The document contains 10 chemistry problems involving conversions between organic compounds and redox reactions, as well as calculations involving cell potentials, conductivities, and thermodynamic properties. The problems cover topics including substitution reactions, oxidation-reduction reactions, electrochemical cells, conductance of electrolyte solutions, and calculation of standard cell potentials and Gibbs free energies.

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    The document contains 10 chemistry problems involving conversions between organic compounds and redox reactions, as well as calculations involving cell potentials, conductivities, and thermodynamic properties. The problems cover topics including substitution reactions, oxidation-reduction reactions, electrochemical cells, conductance of electrolyte solutions, and calculation of standard cell potentials and Gibbs free energies.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    7 views2 pages

    Chemistry Assignment 2023 2 1683714093

    Uploaded by

    Tharun
    The document contains 10 chemistry problems involving conversions between organic compounds and redox reactions, as well as calculations involving cell potentials, conductivities, and thermodynamic properties. The problems cover topics including substitution reactions, oxidation-reduction reactions, electrochemical cells, conductance of electrolyte solutions, and calculation of standard cell potentials and Gibbs free energies.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    D.A.V.

    School
    (Affiliated to C.B.S.E. New Delhi)
    Sree Nandeeswarar Campus, Adambakkam, Chennai – 600 088

    CHEMISTRY
    STD : XII ASSIGNMENT 2023-2024
    How the following conversions can be carried out?
    1) Aniline to chlorobenzene
    2) But-1-ene to n- butyl iodide
    3) Ethanol to but-2-yne
    4) Chlorobenzene to p-nitro phenol
    5) Tert-butyl bromide to isobutyl bromide
    6) 1- Propanol to 2-bromopropane
    7) 2- Propanol to 1- bromo propane
    8) Propylene to propyne
    9) Ethane in to ethylene
    10) Propene to isopropyl alcohol

    Numericals:
    1) The resistance of a conductivity cell containing 10-3 MKCl solution at 25oC is
    1500 Ω . What is the cell constant if conductivity of 10-3 MKCl solution at 25oC is
    1.5x10-4 Scm-1 ?
    2) Two half –reactions of an electro chemical cell are given below:
    Mno4- (aq) + 8 H+ (aq) + 5 e- → Mn2+ (aq) + 4H2O (l) E0 = + 1.51 V
    Sn2+(aq)→ Sn4+(aq) + 2e- E0 = + 0.15 V
    Construct the redox equation from the standard potential of the cell and predict
    the reaction is reactant favoured (or) product favoured.
    3) Calculate the potential for half-cell containing 0. 10 M K2Cr2O7 (aq),
    0.20 M Cr3+ (aq) and 1.0 x 104 M H+ (aq) the half –cell reaction is
    Cr2 O7 2- (aq) + 14 H+ (aq) + 6 e- → 2Cr3+( aq) + 7 H2O (l)
    4.) One half -cell in a voltaic cell is constructed from a silver wire dipped in silver
    Nitrate solution of unknown concentration. The other half - cell consists of a Zinc
    electrode in a 0.10 M solution of Zn (NO3)2 . A voltage of 1.48 V is measured for
    this cell . Use this information to calculate the concentration of Silver Nitrate
    solution
    (Given E0 Zn 2+ / Zn = 0.76 V , E0Ag+ / Ag = 0.80 V)

    5.) Calculate the emf of the following cell at 298 K.


    2 Cr (s) + 3 Fe2+ (0.1 M) → 2Cr3+(0.01M) + 3Fe (s)

    Given E0(Cr 3+ / Cr) = -- 0.74 V , E0 (Fe 2+ /Fe ) = --0.44 V


    Type equation here .

    6.) The conductivity of 0.1 mol L-1 solution of NaCl is 1.06 x 10 -2 Scm-1 .
    Calculate its molar conductivity and degree of dissociation.
    Given λ ο(Na +) = 50.1 Scm2 mol-1 and λ ο(Cl- )= 76.5 Scm2 mol-1.

    7.) Equilibrium constant (Kc ) for the given cell reaction is 10. Calculate E0 cell
    A (s) + B 2+ (aq) → A 2+ (aq) + B(s)

    8.) The molar conductivity of a 1.5 M solution of an electrolyte is found to be


    138.9 Scm 2 mol-1 . Calculate the conductivity of the solution.

    9.) In the button cell, widely used in watches and other devices , the following
    reaction takes place.
    Zn (s) + Ag 2 O (s) + H2O (l) → Zn2+ (aq) + 2Ag (s) + 2 OH – (aq)
    Determine E0 and ∆ G0 for the reaction .
    (Given E0 Ag+ /Ag = + 0.80 V , E0 Zn2+ /Zn = -- 0.76 V

    10.) Calculate the cell potential E , at 25 ° C for the cell if the initial concentration
    of Ni (NO 3) 2 is 0.100 molar and initial concentration of AgNo3 is 1.00 molar.
    ( E0 Ni2+ / Ni = -0.25 V ; E0 Ag+ /Ag = 0.80 V; Log 10 -1 = -1 )..

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