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A732A732M

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Designation: A 732/A732M – 05

Standard Specification for


Castings, Investment, Carbon and Low Alloy Steel for
General Application, and Cobalt Alloy for High Strength at
Elevated Temperatures1
This standard is issued under the fixed designation A 732/A732M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (e) indicates an editorial change since the last revision or reapproval.

1. Scope* E 139 Practice for Conducting Creep, Creep-Rupture, and


1.1 This specification covers carbon and low-alloy steel and Stress-Rupture Tests of Metallic Materials
cobalt alloy castings made by the investment casting process. 3. Ordering Information
1.2 Fifteen grades of steel and two cobalt alloy grades are
covered. 3.1 Orders for castings under this specification should
1.3 Supplementary requirements of an optional nature are include the following information:
provided for use at the option of the purchaser. The supple- 3.1.1 Quantity,
mentary requirements shall apply only when specified indi- 3.1.2 ASTM designation and issue date,
vidually by the purchaser in the purchase order or contract. 3.1.3 Grade designation (Tables 1 and 2), and
1.4 This specification is expressed in both inch-pound units 3.1.4 Description of casting by part, pattern, or drawing
and SI units; however, unless the purchase order or contract number. (Dimensional tolerances and machined surfaces shall
specifies the applicable M specification designation (SI units), be indicated on the casting drawing.).
the inch-pound units shall apply. The values stated in either 3.2 The purchaser should specify any of the following
inch-pound units or SI units are to be regarded separately as information to describe adequately the desired material:
standard. Within the text, the SI units are shown in brackets. 3.2.1 Heat-treat condition (see 5.1 and 5.2),
The values in each system may not be exact equivalents; 3.2.2 Repair welding (see Section 8 and Specification
therefore, each system shall be used independently of the other. A 957),
Combining values from the two systems may result in noncon- 3.2.3 Source inspection, if any (see Specification A 957),
formance with this standard. and
3.2.4 Supplementary requirements required (marking, certi-
2. Referenced Documents fication, mechanical properties, NDT, and the like).
2.1 ASTM Standards: 2 4. General Requirements
A 941 Terminology Relating to Steel, Stainless Steel, Re-
lated Alloys, and Ferroalloys 4.1 Material furnished to this specification shall conform to
A 957 Specification for Investment Castings, Steel and the requirements of Specification A 957, including any supple-
Alloy, Common Requirements, for General Industrial Use mentary requirements that are indicated on the purchase order.
A 994 Guide for Editorial Procedures and Form of Product Failure to comply with the requirements of Specification A 957
Specifications for Steel, Stainless Steel, and Related Alloys constitutes nonconformance with this specification. In case of
A 997 Practice for Investment Castings, Surface Accepted conflict of this specification and Specification A 957, this
Standards, Visual Examination specification shall prevail.
E 21 Test Methods for Elevated Temperature Tension Tests 5. Heat Treatment
of Metallic Materials
5.1 Steel castings shall be heat treated either by full anneal-
ing, normalizing, normalizing and tempering, or quenching and
1
This specification is under the jurisdiction of ASTM committee A01 on Steel, tempering to obtain the specified properties or other properties
Stainless Steel and Related Alloys and is the direct responsibility of Subcommittee that have been agreed upon within each grade. In this latter
A01.18 on Castings.
Current edition approved Jan. 1, 2005. Published January 2005. Originally
instance, Supplementary Requirement S23 shall be used.
approved in 1976. Last previous edition approved in 2002 as A 732/A 732M – 02. 5.1.1 Heat treatment shall be performed after the castings
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or have been allowed to cool below the transformation range.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.

*A Summary of Changes section appears at the end of this standard.


Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

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A 732/A732M – 05
TABLE 1 Chemical Requirements
Grade 1A 2A,2Q 3A,3Q 4A,4Q 5N 6N 7Q 8Q
Type Low Carbon Medium Medium Medium Vanadium Manganese Chromium Chromium
Carbon Carbon Carbon Molybdenum Molybdenum Molybdenum
IC 1020A IC 1030 IC 1040 IC 1050 IC 6120 IC 4020 IC 4130 IC 4140
Carbon 0.15 to 0.25 0.25 to 0.35 0.35 to 0.45 0.45 to 0.55 0.30 max 0.35 max 0.25 to 0.35 0.35 to 0.45
Manganese 0.20 to 0.60 0.70 to 1.00 0.70 to 1.00 0.70 to 1.00 0.70 to 1.00 1.35 to 1.75 0.40 to 0.70 0.70 to 1.00
Phosphorus, max 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04
Sulfur, max 0.045 0.045 0.045 0.045 0.045 0.045 0.045 0.045
Silicon 0.20 to 1.00 0.20 to 1.00 0.20 to 1.00 0.20 to 1.00 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80
Nickel
Chromium 0.80 to 1.10 0.80 to 1.10
Molybdenum 0.25 to 0.55 0.15 to 0.25 0.15 to 0.25
Vanadium 0.05 to 0.15
Residual Elements:
Copper 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50
Nickel 0.50 0.50 0.50 0.50 0.50 0.50
Chromium 0.35 0.35 0.35 0.35 0.35
Molybdenum + Tungsten 0.25 0.25
Tungsten 0.10 0.10 0.10 0.25 0.10 0.10
Total content of these 1.00 1.00 1.00 0.60 1.00 1.00 0.60 1.00
residual elements
Grade 9Q 10Q 11Q 12Q 13Q 14Q 15A
Type Chrome Nickel Chrome Nickel Nickel Molyb- Chromium Chrome Nickel Chrome Nickel Chromium
Molybdenum Molybdenum denum Vanadium Molybdenum Molybdenum
IC 4330 IC 4340 IC 4620 IC 6150 IC 8620 IC 8630 IC 52100
Carbon 0.25 to 0.35 0.35 to 0.45 0.15 to 0.25 0.45 to 0.55 0.15 to 0.25 0.25 to 0.35 0.95 to 1.10
Manganese 0.40 to 0.70 0.70 to 1.00 0.40 to 0.70 0.65 to 0.95 0.65 to 0.95 0.65 to 0.95 0.25 to 0.55
Phosphorus, max 0.04 0.04 0.04 0.04 0.04 0.04 0.04
Sulfur, max 0.045 0.045 0.045 0.045 0.045 0.045 0.045
Silicon 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80 0.20 to 0.80
Nickel 1.65 to 2.00 1.65 to 2.00 1.65 to 2.00 0.40 to 0.70 0.40 to 0.70
Chromium 0.70 to 0.90 0.70 to 0.90 0.80 to 1.10 0.40 to 0.70 0.40 to 0.70 1.30 to 1.60
Molybdenum 0.20 to 0.30 0.20 to 0.30 0.20 to 0.30 0.15 to 0.25 0.15 to 0.25
Vanadium 0.15 min
Residual Elements:
Copper 0.50 0.50 0.50 0.50 0.50 0.50 0.50
0.50 0.50
Chromium 0.35
Molybdenum + Tungsten 0.10
Tungsten 0.10 0.10 0.10 0.10 0.10 0.10
Total content of these 0.60 1.00 1.00 1.00 1.00 1.00 0.60
residual elements
A
Investment Casting (IC) numbers are to be used only for nomenclature comparison.

TABLE 2 Chemical Requirements-Cobalt Alloys 7. Quality


Grade 21 31 7.1 The surface of the casting shall be examined visually to
Carbon 0.20–0.30 0.45–0.55 meet the requirements of Practice A 997. Acceptance criteria to
Manganese, max. 1.00 1.00
Silicon, max 1.00 1.00
be mutually agreed upon between supplier and purchaser.
Phosphorus, max 0.040 0.040 7.2 The castings shall not be peened or plugged or impreg-
Sulfur, max 0.040 0.040 nated.
Chromium 25.0–29.0 24.5–26.5
Nickel 1.7–3.8 9.5–11.5 8. Repair by Welding
Cobalt remainder remainder
Molybdenum 5.0–6.0 ... 8.1 Welding shall be accomplished with a filler metal that
Tungsten ... 7.0–8.0 produces a weld deposit with a chemical composition similar to
Iron, max. 3.00 2.00
Boron 0.007 max 0.005–0.015 the casting. Castings ordered in the annealed condition or for
subsequent hardening shall be annealed after weld repairs.
Castings ordered heat treated shall be post weld heat treated in
5.2 Cobalt alloy castings shall be supplied in the as-cast accordance with the qualified welding procedure after weld
condition unless otherwise agreed upon by supplier and pur- repairs with the exception of Grades 1A and 2A where post
chaser. weld heat treatment is optional.
5.3 Definitions of terms relating to heat treatment shall be in 8.2 Welds shall be inspected to the same quality standards
accordance with Terminology A 941. as are used to inspect the castings.
6. Chemical Composition 9. Keywords
6.1 The castings shall conform to the requirements for 9.1 alloy steel; carbon steel; cobalt alloys; investment cast-
chemical composition specified in Table 1 and Table 2. ings; steel castings

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A 732/A732M – 05

SUPPLEMENTARY REQUIREMENTS

The following supplementary requirements shall not apply unless specified in the purchase order. A
list of standardized supplementary requirements for use at the option of the purchaser is included in
Specification A 957. Those ordinarily considered suitable for use with this specification are given
below, together with additional supplementary requirements that are applicable only to this
specification. Other supplementary requirements enumerated in Specification A 957 may be used with
this specification upon agreement between supplier and purchaser.

S1. Magnetic Particle Inspection upon, and shall be reported to the purchaser or his representa-
tive. See Specification A 957 for additional details and require-
S2. Radiographic Inspection ments.
S3. Liquid Penetrant Inspection
S25. Tension Test (Castings Heat Treated by Purchaser)
S6. Certification S25.1 The supplier shall heat treat a tension specimen from
a re-melted heat of same primary heat to determine whether the
S7. Prior Approval of Major Weld Repairs castings are capable of being heat treated to the specified
properties. The results shall conform to the requirements
S8. Marking
specified in Table S24, or to properties agreed upon, and shall
S13. Unspecified Elements be reported to the purchaser or his representative. See Speci-
ficatioin A 957 for additional details and requirements.
S16. Weld Repair Charts
S26. High Temperature Tension Test
S19. Decarburization
S26.1 High-temperature tension tests shall be required when
S23. Mechanical Properties specified in the inquiry, contract, or order. When so specified,
S23.1 Mechanical properties other than those specified in the properties obtained shall be reported to the purchaser or his
Table S24 may be ordered for each of the grades. The representative and shall conform to the requirements pre-
properties shall be agreed upon between the supplier and the scribed in Table S26. The tension test shall be performed in
purchaser. accordance with Test Methods E 21.

S24. Tension Test (Castings Heat Treated by Supplier) S27. Stress Rupture Test
S24.1 Tensile properties shall be determined from material S27.1 Stress rupture tests shall be required when specified
representing each re-melted heat. The results shall conform to in the inquiry, contract, or order. When so specified, the
the requirements specified in Table S24, or to properties agreed properties obtained shall be reported to the purchaser or his

TABLE S24 Tensile Requirements


Grade Tensile strength, min Yield strength, min Elongation, in 2-in. Heat
[50-mm] or 4 Treatment
ksi [MPa] ksi [MPa] diameters
1A 60 [414] 40 [276] 24 AA
2A 65 [448] 45 [310] 25 A
2Q 85 [586] 60 [414] 10 QtB
3A 75 [517] 48 [331] 25 A
3Q 100 [689] 90 [621] 10 Qt
4A 90 [621] 50 [345] 20 A
4Q 125 [862] 100 [689] 5 Qt
5N 85 [586] 55 [379] 22 NtC
6N 90 [621] 60 [414] 20 Nt
7Q 150 [1030] 115 [793] 7 Qt
8Q 180 [1241] 145 [1000] 5 Qt
9Q 150 [1030] 115 [793] 7 Qt
10Q 180 [1241] 145 [1000] 5 Qt
11 120 [827] 100 [689] 10 Qt
12Q 190 [1310] 170 [1172] 4 Qt
13Q 105 [724] 85 [586] 10 Qt
14Q 150 [1030] 115 [793] 7 Qt
15AD ... ... ... ... ... A
A
Annealed.
B
Quenched and tempered.
C
Normalized and tempered.
D
Hardness Rockwell B, 100 max.

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A 732/A732M – 05
TABLE S26 Elevated-Temperature Tensile Requirements representative and shall conform to the requirements pre-
Grade 21 31 scribed in Table S27. The stress rupture test shall be performed
Condition as cast as cast in accordance with Practice E 139.
Test temperature:
°F 1500 1500
°C 820 820
Tensile strength, min:
ksi 52.0 55.0
MPa 360 380
Elongation in 4D, min , % 10 10

TABLE S27 Stress Rupture Requirements


Grade 21 31
Condition as cast as cast
Test temperature:
°F 1500 1500
°C 820 820
Stress:
ksi 23.0 30.0
MPa 160 205
Rupture life, min, h 15 15
Elongation in 4D, min, % 5 5

APPENDIX

(Nonmandatory Information)

X1. GUIDE TO CLASSIFICATION OF COBALT ALLOY CASTINGS

X1.1 This guide is appended to the specification as a source X1.3 Grade 21 (Cobalt-base—27 % Cr, 5.5 % Mo, 2.8 %
of information; it is not mandatory and does not form a part of Ni):
the specification. X1.3.1 This grade is resistant to oxidizing and reducing
X1.1.1 This specification itself is intended to provide both atmospheres at temperatures up to 2100°F [1150°C]. The alloy
the manufacturer and the purchaser of alloy castings with a has good strength at elevated temperatures and is used in many
means of production control on the basis of acceptance through applications where resistance to thermal shock is important.
mutually acceptable, sound, standard requirements. The alloy can be produced as sand, shell, or investment
castings.
X1.1.2 This guide has been prepared as an aid to prospec-
X1.3.2 Composition—This grade is of the austenitic, solid
tive users of alloy castings covered by the specification in
solutioning type and possesses its basic strength characteristics
determining the classification best suited for a particular
without the need of heat treatment. However, the alloy is so
application with due consideration to the particular require- designed that aging occurs in the 1300 to 2100°F [700 to
ments for that application. 1150°C] range by the formation of carbides, thus strengthening
the alloy in service. The high chromium imparts the excellent
X1.2 Stress for Design—The old method of basing design oxidation resistance of the alloy and contributes, along with the
calculations on 50 % of the limiting creep stress is conserva- molybdenum, to the strength of the alloy.
tive, but it is relatively crude and has the disadvantage that the X1.3.3 Mechanical Properties—This grade can be used for
resulting stress values do not have a consistent relation to life applications of high stress up to 1500°F [815°C] and moderate
expectancy. Design with the stress that should produce rupture strength requirements to 2100°F [1150°C]. The average as-cast
in 100 000 h is frequently satisfactory, though it should be tensile strength at 1500°F is 62 000 psi [430 MPa] with 16 %
recognized that this is an extrapolated value and provides no elongation. The alloy exhibits good impact strength even in the
assurance that the installation will actually endure for this time. age-strengthened condition. The average charpy V-notch im-
Among the factors that can result in shorter life are reduction pact strength after aging is above 20 ft·lb [27 J] in the 1200 to
of the effective cross-sectional area by hot-gas corrosion, 1800°F [650 to 980°C] range. Table X1.1 contains typical
thermal stresses superimposed on the normal working stresses, stress-rupture data for this alloy.
and overheating. Usually overheating is the most serious of X1.3.4 Applications—This grade can be used for applica-
these, since in general a 200°F [110°C] increase in temperature tions of high stress up to 1500°F and for moderate strength
will cut the rupture strength in half. requirements up to 2100°F. In the past, it has been used

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A 732/A732M – 05
TABLE X1.1 Typical Stress-Rupture Data for Grade 21
Test Temperature Average Initial Stress for Rupture
°F °C 10 h 100 h 500 h 1000 h
Psi MPa Psi MPa Psi MP[a Psi MPa
1400 760 42 000 290 24 000 165 18 000 124 15 000 103
1500 815 27 500 189 19 000 131 15 000 103 13 500 93
1700 925 17 000 117 13 000 90 10 800 74 10 000 69
1800 980 12 500 86 9 400 65 7 700 53 7 000 48

TABLE X1.2 Typical Stress-Rupture Data for Grade 31


Test Temperature Average Initial Stress for Rupture
°F °C 10 h 100 h 500 h 1000 h
Psi MPa Psi MPa Psi MPa Psi MPa
1350 730 49 000 338 44 000 303 40 000 276 39 000 269
1500 815 33 000 228 27 000 159 23 000 159 22 000 152
1700 925 20 000 138 17 000 117 15 400 106 14 500 100
1800 980 13 000 90 11 300 78 10 200 70 9 800 68

successfully for gas turbine blades and vanes, as well as for employ a solution heat-treatment for heavy sections of castings
turbosupercharger blading applications. to develop optimum strength.
X1.4.3 Mechanical Properties—Until the introduction of
X1.4 Grade 31 (Cobalt-base—25.5 % Cr, 10.5 % Ni, 7.5 % the vacuum-melted nickel-base, precipitation-hardening alloys,
W): the solid solution cobalt-base alloys were considered the
X1.4.1 This grade has been one of the most useful high- stronger of the available engineering materials for high tem-
temperature alloys in the past. The alloy is used for high- perature applications. At 1500°F [815°C] this grade has an
strength applications to about 1500°F [815°C] and moderate- average as-cast tensile strength of 63 200 psi [43.5 MPa] and
strength applications to 1800°F [980°C]. It has excellent an elongation of 15 %. The combination of strength with high
oxidation resistance, thermal shock resistance, and fatigue life. ductility is an advantage over other alloys which exhibit
The alloy can be produced as a sand, shell, or investment ductilities in the order of 5 % or less. Table X1.2 contains
casting. typical stress-rupture data for this alloy.
X1.4.2 Composition—This grade is the austenitic, solid X1.4.4 Applications—This grade can be used for applica-
solutioning type and possesses its basic strength characteristics tions of high stress up to 1500°F [816°C] and for moderate
without the need of heat treatment. However, the alloy is so strength requirements up to 2100°F [1149°C]. In the past, it has
designed that aging and strengthening occur in service through been used extensively for blading and vanes for gas turbine and
the precipitation of carbides. Also, it is sometimes necessary to turbosuperchargers.

SUMMARY OF CHANGES

Committee A01 has identified the location of selected changes to this standard since the last issue
(A 732/A 732M - 02) that may impact the use of this standard. (Approved Jan. 1, 2005.)

(1) This specification has been completely revised and updated requirements of Investment Casting Visual Examine of Prac-
to meet the requirements of Form and Style of Guide A 994, to tice A 997. Other than minor additions from the visual speci-
incorporate the requirements of Investment Casting Common fication, the technical requirements of this specification have
Requirements of Specification A 957, and to incorporate the not changed.

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A 732/A732M – 05

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