Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC - Germany

SAFETY DATA SHEET

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1. Identification of the preparation and of the company

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Product name and/or code : HEMPATHANE TOPCOAT 55219

5521910000
Company details : HEMPEL (GERMANY) GmbH Emergency phone:
Hindenburgdamm 60 (0 41 01) 70 70
25421 Pinneberg See section 4 First aid
Tel. (0 41 01) 70 70 measures.
Fax. (0 41 01) 70 71 31
Product type : polyurethane enamel (base for 2-component product)
Field of application : metal industry, ships and shipyards.
ready-for-use mixture : 55219 8,75 LI / 95370 1,25 LI
Date of issue : 05-02-2007.
Date of previous issue : 17-01-2007.
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2. Composition/information on ingredients
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Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive
67/548/EEC.
Ingredient name CAS no. % EC number Classification

solvent naphtha (petroleum), light arom. 64742-95-6 25 - 50 265-199-0 R10

Xn; R20, R65
Xi; R36/37/38
N; R51/53
xylene 1330-20-7 5 - 10 215-535-7 R10
Xn; R20/21
Xi; R38
ethylbenzene 100-41-4 1-3 202-849-4 F; R11
Xn; R20
diamide wax mixture 0.5 - 1 R43
N; R51/53
bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 41556-26-7 0.3 - 0.5 255-437-1 R43
N; R50/53
n-butyl acrylate 141-32-2 0.15 - 0.3 205-480-7 R10
Xi; R36/37/38
R43
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Notes
(*) See full text of phrases under chapter 16. Occupational exposure limits, if available, are listed in section 8.
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3. Hazards identification
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Harmful Dangerous for the

environment.
Flammable. Harmful by inhalation. Irritating to eyes, respiratory system and skin. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment. Contains diamide wax mixture, bis (1,2,2,6,6-
pentamethyl-4-piperidyl) sebacate, n-butyl acrylate. May produce an allergic reaction.

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4. First aid measures

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General : In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If unconscious, place in recovery
position and get medical attention immediately.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek
immediate medical attention.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do not use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do not induce vomiting unless directed to do so by
medical personnel. Lower the head so that vomit will not re-enter the mouth and
throat.
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5. Fire-fighting measures
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Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training. Fire will produce dense black smoke. Exposure to
decomposition products may cause a health hazard. Cool closed containers exposed to fire with water. Do not release
runoff from fire to sewers or waterways. Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used : waterjet.
Fire degradation products : Decomposition products may include the following materials: carbon oxides metal
oxide/oxides
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6. Accidental release measures

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Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard.
Ventilate the area. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8.
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous
earth, and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains
or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers, or
sewers, inform the appropriate authorities in accordance with local regulation.
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7. Handling and storage

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Handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the
creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the
occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No
sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should
be prohibited in area where this material is handled, stored and processed. Appropriate personal protective
equipment: see Section 8. Always keep in containers made from the same material as the original one.
Storage
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from
incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents,
strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully
resealed and kept upright to prevent leakage.
VbF class (A) : A II
Very dangerous flammable liquid.

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8. Exposure controls/personal protection

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Engineering measures : Arrange sufficient ventilation by local exhaust ventilation and good general
ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before
eating, smoking, using lavatory, and at the end of day.
Ingredient name Occupational exposure limits

xylene MAK-Werte Liste (Germany, 7/2005). Skin

PEAK: 880 mg/m³, 4 times per shift, 15 minute(s).
PEAK: 200 ppm, 4 times per shift, 15 minute(s).
TWA: 440 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
TRGS900 (Germany, 1/2006). Skin
PEAK: 880 mg/m³ 15 minute(s).
PEAK: 200 ppm 15 minute(s).
TWA: 440 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
ethylbenzene TRGS900 (Germany, 1/2006). Skin
PEAK: 880 mg/m³ 15 minute(s).
PEAK: 200 ppm 15 minute(s).
TWA: 440 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
n-butyl acrylate MAK-Werte Liste (Germany, 7/2005).
PEAK: 22 mg/m³, 4 times per shift, 15 minute(s).
PEAK: 4 ppm, 4 times per shift, 15 minute(s).
TWA: 11 mg/m³ 8 hour(s).
TWA: 2 ppm 8 hour(s).
TRGS900 (Germany, 1/2006).
PEAK: 22 mg/m³ 15 minute(s).
PEAK: 4 ppm 15 minute(s).
TWA: 11 mg/m³ 8 hour(s).
TWA: 2 ppm 8 hour(s).

Personal protective equipment

General : Gloves must be worn for all work that may result in soiling.
Apron/coveralls/protective clothing must be worn when soiling is so great that
regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.
Where personal protection equipment is required this shall be chosen in
accordance with German BGR regulations of the "Berufsgenossenschaften".
Respiratory protection : If working areas have insufficient ventilation: When the product is applied by
means that will not generate an aerosol such as, brush or roller wear half or totally
covering mask equipped with gas filter of type A, when grinding use particle filter
of type P. When the product is applied by spraying and for continuous or
prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an
approved/certified respirator or equivalent.

Skin protection : Wear suitable protective clothing. Always wear protective clothing when spraying.
Hand protection : Wear suitable gloves. For prolonged or repeated handling, use gloves. Barrier
creams may help to protect the exposed areas of the skin, but should not be
applied once exposure has occurred. Barrier creams may not be used under or
instead of gloves.
Since the actual work situation is unknown. Supplier of gloves should be
contacted in order to find the appropriate type.

Eye protection : Use safety eyewear designed to protect against splash of liquids. Safety glasses
with side shields.

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9. Physical and chemical properties

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Physical state : Liquid.

Density : Weighted average: 1.28 g/cm3
Solubility : Very slightly soluble in the following materials: cold water and hot water.
Flash point : Closed cup: 33°C (91,4°F)
Explosion limits : 0.5 - 8 vol %
Solvent(s) % by weight : Weighted average: 38 %
Water % by weight : Weighted average: 0 %
VOC content : Weighted average: 481 g/l (Calculated value for the mixture)
TOC Content : Weighted average: 428 g/l (Solvent.)
Solvent Gas : 0.103 m3/l
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10. Stability and reactivity

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Stable under recommended storage and handling conditions (see section 7).
Highly reactive or incompatible with the following materials: oxidizing materials and metals.
Reactive or incompatible with the following materials: reducing materials and acids.
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides metal oxide/oxides
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11. Toxicological information

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Effects and symptoms

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane
and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may
cause some of the above effects by absorption through the skin. Symptoms and signs include headaches, dizziness,
fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged
contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis
and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage.
Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the
lungs via vomiting.
Sensitization : Contains diamide wax mixture, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate,
n-butyl acrylate. May produce an allergic reaction.
Acute toxicity
Ingredient name Result Dose Species
solvent naphtha (petroleum), light arom. LD50 Oral 8400 mg/kg Rat
xylene LD50 Oral 4300 mg/kg Rat
LD50 Skin >1700 mg/kg Rabbit
LDLo Oral 50 mg/kg Human
LC50 Inhalation Gas. >6700 ppm Rat
ethylbenzene LD50 Oral 3500 mg/kg Rat
LD50 Skin 17800 uL/kg Rabbit
n-butyl acrylate LD50 Oral 900 mg/kg Rat
LDLo Skin 1700 mg/kg Rat
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12. Ecological information

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Do not allow to enter drains or watercourses. Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Ingredient name Result Species Exposure
xylene Acute LC50 12 mg/L Mortality Fish 96 hours
ethylbenzene Acute EC50 2,97 mg/L Intoxication Daphnia 48 hours
Acute LC50 9,09 mg/L Mortality Fish 96 hours

Hazard class for water : 2 Appendix No. 4

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13. Disposal considerations

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The generation of waste should be avoided or minimized wherever possible.

Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable
regulations.
Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.
European waste catalogue no. (EWC) and national waste group, catalouge, code or number is given below.
European waste catalogue : 08 01 11
(EWC)
Empty containers or liners may retain some product residues.
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14. Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train,
IMDG for transport by sea, IATA for transport by air. The transport classification is according to ADR 2007, IMDG
edition 2006 (incl. Amdt. 33-06).
UN no. Proper shipping name Class PG* Label Additional information

ADR/RID UN1263 PAINT 3 III Remarks

Class H-14
3

IMDG UN1263 PAINT 3 III Emergency schedules

Class (EmS)
3 F-E, S-E

IATA Class UN1263 PAINT 3 III -

PG* : Packing group

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15. Regulatory information

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Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC (including
amendments) and take into account the intended product use.
Product use : Industrial applications, Used by spraying.
Symbol : Harmful, Dangerous for the environment.
Contains : solvent naphtha (petroleum), light arom.
Risk phrases : R10- Flammable.
R20- Harmful by inhalation.
R36/37/38- Irritating to eyes, respiratory system and skin.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S23- Do not breathe vapor or spray.
S51- Use only in well-ventilated areas.
Additional warning phrases : Contains diamide wax mixture, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate,
n-butyl acrylate. May produce an allergic reaction.
Hazardous incident ordinance : Applicable. Category: 9b Dangerous for the environment.
Technical instruction on air : TA-Luft Number 5.2.5: 40,6%
quality control TA-Luft Class I - Number 5.2.5: 1,8%
VOC content : 37.2 (w/w%)
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16. Additional information

Full text of R-phrases referred to in : R11- Highly flammable.
the Safety Data Sheet R10- Flammable.
R20- Harmful by inhalation.
R20/21- Harmful by inhalation and in contact with skin.
R65- Harmful: may cause lung damage if swallowed.
R38- Irritating to skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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Notice to reader
Modified data or content compared with the previous version are maked with a triangular marker in the upper-left
corner within the Safety Data Sheet.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national
legislation. It provides guidance on health, safety and environmental aspects for handling the product in a safe way
and should not be construed as any guarantee of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the
national regulations.

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