Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

Penguard FC Comp. A with LC

1. Identification of the preparation and of the company

Product name and/or code : Penguard FC Comp. A with LC
Label No. : 6480
Supplier/Manufacturer : Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England

Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
SDSJotun@jotun.no

Emergency telephone : Contact National Poison Centre via Hospital or Registered Medical Practitioner
number

2. Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Flammable.
May cause cancer. May cause harm to the unborn child.
Possible risk of impaired fertility. Also harmful by inhalation.
Irritating to eyes and skin. May cause sensitisation by skin
contact. Danger of cumulative effects. Toxic Dangerous for the
Toxic to aquatic organisms, may cause long-term adverse environment
effects in the aquatic environment.
Additional warning phrases : Contains lead. Should not be used on surfaces liable to be chewed or sucked by
children.

3. Composition/information on ingredients
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Chemical name* Notes CAS EC % by Classification
number number weight
epoxy resin (MW 700-1200) - 25036-25-3 10 - 25 Xi; R36/38
R43
lead sulfochromate yellow [This substance is identified 1 1344-37-2 215-693-7 10 - 25 Carc. Cat. 2;
in the Colour Index by Colour Index Constitution R45
Number, C.I. 77603.] Repr. Cat. 1;
R61
Repr. Cat. 3;
R62
R33
N; R50/53
xylene C 1330-20-7 215-535-7 2.5 - 10 R10
Xn; R20/21
Xi; R38
Solvent naphtha (petroleum), light arom. H-P 64742-95-6 265-199-0 2.5 - 10 R10
Xn; R20, R65
Xi; R37
R66
N; R51/53
butan-1-ol 6 71-36-3 200-751-6 2.5 - 10 R10
Xn; R22
Xi; R41, R37/38
R67
ethylbenzene - 100-41-4 202-849-4 1 - 2.5 F; R11
Xn; R20

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Penguard FC Comp. A with LC
See section 16 for the full text of the R-phrases
declared above

Occupational exposure limits, if available, are listed in section 8.

4. First-aid measures
First-aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.

5. Fire-fighting measures
Extinguishing media : Recommended: alcohol-resistant foam, CO 2, powders, water spray.
Extinguishing media not to : Do not use water jet.
be used
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required.
Cool closed containers exposed to fire with water. Do not release runoff from fire to
drains or watercourses.

6. Accidental release measures

Personal precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13).
Spill : Preferably clean with a detergent. Avoid using solvents.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapours in air and avoid vapour concentrations higher than the
occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep container tightly closed. Keep away from heat, sparks and flame. No sparking
tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.

When operators, whether spraying or not, have to work inside the spray booth,

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Penguard FC Comp. A with LC
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.
Storage : Store in accordance with local regulations. Observe label precautions. Store in a dry,
cool and well-ventilated area. Keep away from heat and direct sunlight.
Keep away from sources of ignition. Keep away from: oxidising agents, strong
alkalis, strong acids.
No smoking. Prevent unauthorised access. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not empty into drains.

8. Exposure controls/personal protection

Engineering measures : Provide adequate ventilation. Where reasonably practicable, this should be achieved
by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and solvent vapours below the
OEL, suitable respiratory protection must be worn.

Ingredient name Occupational exposure limits

lead sulfochromate yellow [This EH40/2005 WELs (United Kingdom (UK), 8/2007). Skin
substance is identified in the Colour sensitiser.
Index by Colour Index Constitution TWA: 0,05 mg/m, (as Cr) 8 hour(s).
Number, C.I. 77603.]
xylene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 441 mg/m 15 minute(s).
STEL: 100 ppm 15 minute(s).
TWA: 220 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
Solvent naphtha (petroleum), light EH40-WEL (United Kingdom (UK), 1/2005).
arom. TWA: 125 mg/m 8 hour(s). Form: All forms
TWA: 25 ppm 8 hour(s). Form: All forms
butan-1-ol EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 154 mg/m 15 minute(s).
STEL: 50 ppm 15 minute(s).
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 552 mg/m 15 minute(s).
STEL: 125 ppm 15 minute(s).
TWA: 100 ppm 8 hour(s).
TWA: 441 mg/m 8 hour(s).

Personal protective equipment

Respiratory system : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Skin and body : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Hands : Wear suitable gloves.

May be used, gloves(breakthrough time) 4 - 8 hours: neoprene, Viton, Barricade,

CPF 3, Responder, PVC, polyvinyl alcohol (PVA)
Not recommended, gloves(breakthrough time) < 1 hour: butyl rubber, PE
Recommended, gloves(breakthrough time) > 8 hours: 4H, Teflon, nitrile rubber
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Eyes : Use safety eyewear designed to protect against splash of liquids.

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Penguard FC Comp. A with LC

9. Physical and chemical properties

Physical state : Liquid.
Odour : Characteristic.
Colour : Various
Flash point : Closed cup: 28C (82,4F)
Density : 1.504 g/cm3
Explosion limits : 1.1 - 11.3%
Solubility : Insoluble in the following materials: cold water and hot water.

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong
acids.
When welding/cutting/burning on flat finish high concentrations of lead may develop.

11. Toxicological information

There is no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 2 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss
of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin,
resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and
chemical pneumonia.

Contains: epoxy resin (MW 700-1200). May produce an allergic reaction.

Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Reproductive toxicity : Can cause birth defects.
Product name List name Name on list Classification Notes
lead sulfochromate yellow UK Occupational chromium (VI) Carc.
[This substance is identified Exposure Limits EH40 compounds
in the Colour Index by Colour - WEL
Index Constitution Number,
C.I. 77603.]

12. Ecological information

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
lead sulfochromate yellow [This substance - Acute EC50 >100 mg/l Daphnia - 48 hours
is identified in the Colour Index by Colour Daphnia
Index Constitution Number, C.I. 77603.] magna straus
- Acute EC50 >100 mg/l Algae - 72 hours
Scenedesmus
subspicatus
- Acute LC50 2500 mg/l Fish - 96 hours
Leuciscus
idus
xylene Mortality Acute LC50 12000 to Fish - Bluegill 96 hours
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Penguard FC Comp. A with LC
16114 ug/L Fresh water - Lepomis
macrochirus -
1,1 g
Solvent naphtha (petroleum), light arom. - Acute EC50 <10 mg/L Daphnia 48 hours
- Acute IC50 <10 mg/L Algae 72 hours
- Acute LC50 <10 mg/L Fish 96 hours
ethylbenzene Population Acute EC50 7,2 mg/L Algae 48 hours
Intoxication Acute EC50 2,93 mg/L Daphnia 48 hours
Mortality Acute LC50 4,2 mg/L Fish 96 hours
Ecological information
Biodegradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
lead sulfochromate yellow [This - - Not readily
substance is identified in the Colour
Index by Colour Index Constitution
Number, C.I. 77603.]
xylene - - Readily
Solvent naphtha (petroleum), light - - Not readily
arom.

Bioaccumulative potential
Product/ingredient name LogKow BCF Potential
xylene 3,12 - high

13. Disposal considerations

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
European waste catalogue : 08 01 11* waste paint and varnish containing organic solvents or other dangerous
(EWC) substances. If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.

14. Transport information

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint
Marine pollutant : lead sulfochromate yellow this substance is identified in the colour index by colour
substances index constitution number c.i. 77603, Solvent naphtha (petroleum), light aromatic
UN Number : 1263
Class : 3
Packing group : III
Label :

Marking : The environmental hazardous / marine pollutant mark is only applicable

for packages containing more than 5 litres for liquids and 5 kg for
solids.

Additional information
ADR / RID : Tunnel restriction code: (D/E)
Hazard identification number: 30
Special provisions: 640E
IMDG : Emergency schedules (EmS): F-E, S-E
Marine pollutant: Yes.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

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15. Regulatory information

EU regulations : The product is classified and labelled for supply in accordance with the Directive
1999/45/EC as follows:
Hazard symbol or symbols :

Toxic Dangerous for the

environment

Risk phrases : R10- Flammable.

R45- May cause cancer.
R61- May cause harm to the unborn child.
R62- Possible risk of impaired fertility.
R20- Also harmful by inhalation.
R36/38- Irritating to eyes and skin.
R43- May cause sensitisation by skin contact.
R33- Danger of cumulative effects.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S53- Avoid exposure - obtain special instructions before use.
S23- Do not breathe vapour / spray.
S36/37- Wear suitable protective clothing and gloves.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Contains: : epoxy resin (MW 700-1200)
lead sulfochromate yellow [This substance is identified in the Colour Index by Colour
Index Constitution Number, C.I. 77603.]
Additional warning : Contains lead. Should not be used on surfaces liable to be chewed or sucked by
phrases children.
Restrictions on the : Restricted to professional users.
Marketing and Use
Directive
Industrial use : The information contained in this safety data sheet does not constitute the users
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.

16. Other information

CEPE Classification : 1
Full text of R-phrases : R11- Highly flammable.
referred to in sections 2 and R10- Flammable.
3 - United Kingdom (UK) R45- May cause cancer.
R61- May cause harm to the unborn child.
R62- Possible risk of impaired fertility.
R20- Also harmful by inhalation.
R22- Also harmful if swallowed.
R20/21- Also harmful by inhalation and in contact with skin.
R65- Also harmful: may cause lung damage if swallowed.
R41- Risk of serious damage to eyes.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R36/38- Irritating to eyes and skin.
R37/38- Irritating to respiratory system and skin.
R43- May cause sensitisation by skin contact.
R33- Danger of cumulative effects.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

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Penguard FC Comp. A with LC
This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.
Date of issue : 29.06.2010.
Version : 3.01
Indicates information that has changed from previously issued version.
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

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