DPP 2

CLASS : XIth SUBJECT : CHEMISTRY
DATE : DPP No. : 2
Topic :- THERMODYNAMICS
1. The enthalpy of formation of water from hydrogen and oxygen is ― 286 kJ mol―1. The enthalpy
of decomposition of water into hydrogen and oxygen is:
a) ― 286 kJ mol―1 b) ― 143 kJ mol―1 c) + 286 kJ mol―1 d) +143 kJ mol―1
2. An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system.
If 𝑇𝑖 is the initial temperature and 𝑇𝑓is the final temperature, which of the following
statements is correct?
a) (𝑇𝑓)irrev > (𝑇𝑓)rev
b) 𝑇𝑓 > 𝑇𝑖 for reversible process but 𝑇𝑓 = 𝑇𝑖 for irreversible process
c) (𝑇𝑓)rev = (𝑇𝑓)irrev
d) 𝑇𝑓 = 𝑇𝑖 for both reversible and irreversible processes
3. Heat of fusion of a molecular solid is :
a) Very high b) High c) Low d)None of these
4. Which plot represents for an exothermic reaction?
R
P
R P R P
a) H
b) H c) H
d) H
P R
Time Time Time Time
5. For a spontaneous chemical change the Gibbs energy change is:

a) Positive
b) Negative
c) Zero
d)Depends whether the reaction is exothermic or endothermic
6. An ideal gas undergoing expansion in vacuum shows:
a) ∆𝑈 = 0 b) 𝑊 = 0 c) 𝑞 = 0 d)All of these
7. Select the incorrect statement
a) 𝑃𝑉 work is usually negligible for solid and liquid
For a closed system with 𝑃 ― 𝑉 work only, an isobaric process that has 𝑞 = +ve must have
b)
∆𝑇 = + ve.
c) For a cyclic process 𝑞 = 0
d)Black phosphorus is most stable form of 𝑃 but 𝐻°𝑓 = 0 for white phosphorus.
8. Entropy decreases during:
a) Crystallization of sucrose from solution
b) Rusting of iron
c) Melting of ice
d)Vaporization of camphor
9. At 27℃ latent heat of I fusion of a compound is 2930 J/mol. Entropy change during fusion is:
a) 9.77 J/mol K b) 10.77 J/mol K c) 9.07 J/mol K d)0.977 J/mol K
10. The values of ∆𝐻 and ∆𝑆 for the reaction.
𝐶(graphite) + CO2(g)→2CO(g)
Are 170 kJ and 170 JK―1 respectively. this reaction will be spontaneous at:
a) 510 K b) 710 K c) 910 K d)1110 K
11. The temperature of 5 mL of a strong acid increases by 5℃ when 5 mL of strong base is added to
it. If 10 mL of each is mixed and complete neutralisation takes place then rise in temperature
will be
a) 20℃ b) 10℃ c) 5℃ d)2℃
12. When an ideal gas is compressed adiabatically and reversibly, the final temperature is:
a) Higher than the initial temperature
b) Lower than the initial temperature
c) The same as the initial temperature
d)Dependent on the rate of compression
13. In a closed insulated container, a liquid is stirred with a paddle to increase its temperature. In
this process, which of the following is true
a) ∆𝐸 = 𝑊 ≠ 0, 𝑄 = 0 b) ∆𝐸 ≠ 0, 𝑄 = 𝑊 = 0
c) ∆𝐸 = 𝑊 = 𝑄 = 0 d)∆𝐸 = 0, 𝑄 ≠ 0, 𝑊 = 0
14. If the bond dissociation energies of 𝑋𝑌, 𝑋2 and 𝑌2 (all diatomic molecules) are in the ratio of 1:
1: 05 and ∆𝐻 for the formation of 𝑋𝑌is ― 200 kJ mol―1. The bond dissociation energy of 𝑋2 will
be
a) 100 kJ mol―1 b) 800 kJ mol―1 c) 300 kJ mol―1 d)400 kJ mol―1
15. The dissociation energy of CH4 and C2H6 are respectively 360 and 620 kcal/mol. The bond
energy of C ― C bond is:
a) 260 kcal/mol b) 180 kcal/mol c) 130 kcal/mol d)80 kcal/mol
16. In a calorimeter, the temperature of the calorimeter increases by 6.12 K, the heat capacity of
the system is 1.23 kJ/g deg. What is the molar heat of decomposition for NH4NO3?
a) ―7.53 kJ/mol b) ―398.1 kJ/mol c) ―16.1 kJ/mol d) ―602 kJ/mol
17. The bond energies of F2, Cl2, Br2 and I2 are 155.4, 243.6, 193.2 and 151.2 kJ mol―1 respectively.
The strongest bond is :
a) F ― F b) Cl ― Cl c) Br ― Br d)I ― I
18. The enthalpy changes of formation of the gaseous oxides of nitrogen (N2O and NO) are positive
because of:
a) The high bond energy of the nitrogen molecule
b) The high electron affinity of oxygen atoms
c) The high electron affinity of nitrogen atoms
d)The tendency of oxygen to form O2―
19. If 900 J/g of heat is exchanged at boiling point of water then increase in entropy
a) 43.4 J/mol b) 87.2 J/mol c) 900 J/mol d)Zero
20. A reaction occurs spontaneously if:
a) 𝑇∆𝑆 = ∆𝐻 and both ∆𝐻 and ∆𝑆 are positive
b) 𝑇∆𝑆 > ∆𝐻 and both ∆𝐻 and ∆𝑆 are positive
c) 𝑇∆𝑆 < ∆𝐻 and both ∆𝐻 and ∆𝑆 are positive
d)𝑇∆𝑆 > ∆𝐻 and ∆𝐻 is positive and ∆𝑆 are negative

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CLASS : XIth SUBJECT : CHEMISTRY

DATE : DPP No. : 2

5. For a spontaneous chemical change the Gibbs energy change is:

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